CN201722191U - Vehicle-mounted manganese sewage treatment device - Google Patents

Vehicle-mounted manganese sewage treatment device Download PDF

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Publication number
CN201722191U
CN201722191U CN2010201937216U CN201020193721U CN201722191U CN 201722191 U CN201722191 U CN 201722191U CN 2010201937216 U CN2010201937216 U CN 2010201937216U CN 201020193721 U CN201020193721 U CN 201020193721U CN 201722191 U CN201722191 U CN 201722191U
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CN
China
Prior art keywords
manganese
reaction vessel
sewage
vehicle
sewage treatment
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Expired - Fee Related
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CN2010201937216U
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Chinese (zh)
Inventor
孙永善
方刚
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QINGDAO KESHENG ENVIRONMENTAL TECHNOLOGY ENGINEERING Co Ltd
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QINGDAO KESHENG ENVIRONMENTAL TECHNOLOGY ENGINEERING Co Ltd
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Priority to CN2010201937216U priority Critical patent/CN201722191U/en
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  • Water Treatment By Electricity Or Magnetism (AREA)
  • Removal Of Specific Substances (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The utility model discloses vehicle-mounted manganese sewage treatment equipment comprising a frame, a hydraulic system, a reaction container and a sewage sludge pump, wherein the reaction container is provided with a water inlet and a water outlet. The vehicle-mounted manganese sewage treatment equipment is characterized in that the reaction container is internally provided with a magnetic disc which can interacts with a high field-strength polar carrier; the reaction container is internally filled with the sewage to be treated; and the reaction container is internally provided with a feeding device with a flocculating agent and the polar carrier. The vehicle-mounted manganese sewage treatment equipment can achieve the aim of treating the electrolytic manganese sewage with high efficiency and low consumption by feeding, mixing and quickly settling the polar carrier and flocculating agent, subsequently separating the contamination under the action of high field strength, and finally reclaiming the polar carrier automatically for repeated and circulated use. By utilizing the characteristics of the high field-strength polar carrier, the Mn2+ and Cr6+ in the electrolytic manganese sewage can be quickly decomposed, settled and decontaminated so as to change the water quality. The vehicle-mounted manganese sewage treatment equipment has compact structure, smart volume and attractive appearance, and is convenient for maintenance. The vehicle-mounted manganese sewage treatment equipment can be controlled by PLC programs, can be operated simply, has low running charge, is vehicle-mounted and modularized, is easy to move, and has high efficiency.

Description

Vehicular manganese sewage disposal device
Technical field
The utility model relates to sewage disposal device, a kind of specifically a kind of vehicular sewage disposal device that is used to handle the sewage that contains heavy metal ion.
Background technology
China's manganese ore reserves are abundant, occupy the 4th in the world, and it is the current main method that adopts that electrolytic process is produced manganese metal, but one ton of manganese metal of every production can produce the waste water about 100 cubic metres, the Mn in these waste water bath the presents 2+, Cr 6+Pollutent toxicity is readily biodegradable greatly and not, if the ecosystems such as water body, soil are worked the mischief without handling direct discharging meeting, and handle this type of waste water is a difficult problem, is not that floor space is exactly greatly the running cost height, can't adapt to the requirement of manganese metal manufacturing enterprise.
China's utility model patent 87210733 discloses a kind of high concentration chrome wastewater treatment facility, is specially adapted to handle continuously pH value and is 2~5 high concentration chrome wastewater, also can be used for handling continuously contain other heavy metal ion (as nickel, copper, zinc, cadmium, etc.) sewage.This device adopts the tank body of making through antiseptic metal sheet or other impregnating material, and dress iron powder being equipped with between tank body in twines the processing post of magneticfield coil outward, and the winding wire of handling on the post is connected with the controller that seethes with excitement.
China's utility model patent 200810236221.3 discloses a kind of magnetic flocculation reactor, and this magnetic flocculation reactor mainly is made up of coil and reaction vessel two portions of producing magnetic field, and coil is divided into horizontal and vertical two covers, by the running of time schedule controller.This magnetic circuit is connected to pulse dc power, and the sense of current constantly changes in the coil, and two cover coils can produce opposite both direction magnetic field again.At the coil overcoat yoke and condensing works are arranged, yoke is used for fixing coil and prevents that magnetic from leaking outside; Temperature when the logical water of condensation of condensing works comes control coil work.Reactor mainly is divided into reaction zone, buffer zone and settling region, and the outside is furnished with medicine system, adds flocculation agent.
Though above-mentioned various sewage disposal device and device have purification efficiency height, the fast advantage of processing speed, though but the iron powder isopolarity carrier after handling is direct and heavy metal ion generation chemical reaction energy precipitation of heavy metals ion, but can not be with the polar support recycling, and handle and totally very easily do not cause secondary pollution, and adopting the electro permanent magnetic of hot-wire coil to adsorb, complex structure and energy consumption are bigger.
Summary of the invention
Deficiency at the prior art existence, technical problem to be solved in the utility model is, provides that a kind of one-piece construction is simple, magnetizing time weak point, physical adsorption sedimentation, recycles and reuses polar support as the sedimentation main body, avoids the vehicular manganese sewage disposal device of secondary pollution.
For solving the problems of the technologies described above, technical solution adopted in the utility model is: a kind of vehicular manganese sewage disposal device, it comprises frame, hydraulic efficiency system, reaction vessel, sludge pump, described reaction vessel is provided with water-in and water port, be provided with and the interactional disk of high field intensity polar support in the described reaction vessel, inject treatment sewage in the reaction vessel, be provided with the throwing device of flocculation agent and polar support in the described reaction vessel.
Above-mentioned vehicular manganese sewage disposal device, described reaction vessel is the inverted cone shape, and bottom apex is provided with water port, and disk circumferentially is located on the inverted cone inwall.
Above-mentioned vehicular manganese sewage disposal device, described reaction vessel connects a back-purge system, and described back-purge system one end connects water port, the other end ligation container.
Above-mentioned vehicular manganese sewage disposal device, described reaction vessel connects a magnetic separator, and the high-speed separation pump is set between reaction vessel and magnetic separator, and the described magnetic separator the other end connects sludge pump.
Above-mentioned vehicular manganese sewage disposal device, described flocculation agent are polymerization iron class flocculation agent or polymeric aluminum class flocculation agent.
The advantage of the utility model vehicular manganese sewage disposal device is: this vehicular electrolytic manganese sewage treatment equipment, mix by adding polar support and flocculation agent, rapid precipitation, under the effect of high field intensity, isolate pollutent and reclaim polar support automatically, heavy burden recycles, thereby reaches purpose quick, efficient, that electrolytic manganese waste water is handled in low consumption.Utilize the characteristic of high field intensity polar support, make Mn2+, Cr6+ decomposition fast in the electrolytic manganese waste water, sedimentation, remove and dye blowdown, change water quality.Compact construction, the volume exquisiteness, aesthetic in appearance, easy to maintenance.The PLC time variable control, simple to operate, working cost is cheap.Vehicular, modularization easily moves the efficient height.
Description of drawings
Fig. 1 is the front view of the utility model vehicular manganese sewage disposal device;
Fig. 2 is the vertical view of the utility model vehicular manganese sewage disposal device.
Embodiment
Below in conjunction with drawings and the specific embodiments the utility model is described in further details;
As shown in Figure 1, front view for a kind of vehicular manganese sewage disposal device, it comprises frame 1, hydraulic efficiency system 2, reaction vessel 3, sludge pump 4, described reaction vessel 3 is provided with water-in 31 and water port 32, be provided with and the interactional disk 5 of high field intensity polar support in the described reaction vessel 3, inject treatment sewage in the reaction vessel 3, be provided with the throwing device 13 of flocculation agent 6 and polar support 7 in the described reaction vessel 3.
This flocculation agent 6 is polymerization iron class flocculation agent or polymeric aluminum class flocculation agent.The polymeric aluminum hydrolysis produces high valence ion, forms various types of hydroxyl polynuclear complexes.They are in metastable condition by carbonyl formula bridge linking effect.And the ratio of OH-and Al3+ [2] (generally claiming basicity or base degree) is very big to the flocculating effect influence.Usually basicity is high more, and flocculating effect is strong more, but the too high then aluminum hydroxide precipitation that easily generates indissoluble own causes flocculating effect to reduce.Studies show that basicity is the best when 75%-85%, this moment, flocs unit produced soon, and particle weighs greatly, and sedimentation function is good.Polymeric aluminum has that dosage is few, settling velocity is fast, particle is closely knit, turbidity removal, remove characteristics such as chromatic effect is obvious.[3] are widely used in Treatment of Industrial Water.By improving the coagulating condition, prolong the coagulation time at a slow speed, can effectively reduce the content of aluminium in the water.
As shown in Figure 2, be the vertical view of Fig. 1, for the ease of making disk 5 and contacting of polar support 7 finish flocculation precipitation reaction and increasing plane of action, reaction vessel is set to the inverted cone shape, bottom apex is provided with water port 32, and disk 5 circumferentially is located on the inverted cone inwall.Described reaction vessel 3 connects a back-purge system 8 by pipeline, and described back-purge system 8 one ends connect water port 32, the other end ligation container 3.After reaction sedimentation one time, can repeat to get back in the reaction vessel 3 and repeatedly handle, guarantee that the water that discharges after the sewage disposal reaches standard.
Reaction vessel 3 connects a magnetic separator 9, between reaction vessel 3 and magnetic separator 9 high-speed separation pump 10 is set, and described magnetic separator 9 the other ends connect sludge pump 11; With the connecting pipeline of magnetic separator 9 on also be provided with one and drain pump 12, carry out the cleaning of whole piping system after being used for sedimentation and finishing.
The know-why of this project institute foundation is: high field intensity polar support (HGMS) and Stokes'theorem.(according to Stokes'theorem, utilize disk to attract magnetic-particle, the big more suffered magnetic force of particle is big more, easy more removed) by the disk sorption
The know-why of this project self is: utilize traditional flocculation process, add polar support, make it to become the core of flco, the ionization characterization of adsorption of polar support can be strengthened the flocculation binding ability to suspended substance in the water greatly, form highdensity as body and add the proportion of big flocculating body because the proportion of polar support is up to 5.0 * 10 3Kg/M 3, approximately be the twice of sandstone, so the settling velocity of flco is accelerated, speed can reach more than 20 meters/hour, can finish at 10-15 minute according to the processing of flow process polluted water.At post precipitation polar support and floss and Mn 2+, adopt mechanical system to force to separate, utilize polar support and floss and Mn again 2+The field intensity sensitivity differences, reclaim polar support through the effect of high field intensity rotator, get rid of floss and Mn 2+, reduction back polar support, reciprocation cycle is used, and realizes the processing to pollution by manganese water.This sewage disposal device can directly be loaded on the cargo truck, conveniently carries out sewage disposal whenever and wherever possible, flexibly, fast.
Its concrete working process is: at first treatment sewage is injected in the reaction vessel 3 by the water-in 31 that reaction vessel 3 is provided with, add flocculation agent 6 and polar support 7 to treatment sewage through throwing device 13, mix and rapid subsidence, ferromagnetism attraction principle through disk 5, sediment is to the bottom of reaction vessel 3, spiral through high-speed separation pump 10 adsorbs at a high speed, enter magnetic separator 9 and separate, obtain polar support 7, have the flocculation agent sedimentation of pollutent and arrive sludge pump 11, discharge by the road, the sewage of handling carries out wash cycles and returns in the reaction vessel 3 in the water port 32 arrival recoil washing units 8 of reaction vessel 3, after repeatedly handling, after the allow compliance with emission standards, the leakage fluid dram 14 through being communicated with recoil washing unit 8 discharges after testing.
This equipment is through the continuous operations on the spot of electrolytic manganese factory, by former water Mn 2+Content is that 1486.48mg/l reduces to not 50.23mg/l (getting final product qualified discharge through handling again) of water outlet; By former water Cr 6+Content is that 16.235mg/l reduces to not 0.012mg/l of water outlet, equipment performance stable and, work well, obtain the approval in client and market.
The base conditioning method of the world, domestic electrolytic manganese production waste water is at present: little electrolysis lime emulsion process; Aeration oxidation-SSFe facture; Ion exchange technique; The dull technology of chemical precipitation/coagulation; Micro-filtration combined films technology etc.And the high field intensity polar support, vehicular electrolytic manganese wastewater processing technology equipment still belongs to initiative, has promotional value and vast market space.
Certainly, above-mentioned explanation is not to be to restriction of the present utility model, and the utility model also is not limited to above-mentioned giving an example; those skilled in the art; in essential scope of the present utility model, the variation of making, remodeling, interpolation or replacement all should belong to protection domain of the present utility model.

Claims (5)

1. vehicular manganese sewage disposal device, it comprises frame, hydraulic efficiency system, reaction vessel, sludge pump, described reaction vessel is provided with water-in and water port, it is characterized in that: be provided with and the interactional disk of high field intensity polar support in the described reaction vessel, inject treatment sewage in the reaction vessel, be provided with the throwing device of flocculation agent and polar support in the described reaction vessel.
2. vehicular manganese sewage disposal device according to claim 1, it is characterized in that: described reaction vessel is the inverted cone shape, and bottom apex is provided with water port, disk circumferentially is located on the inverted cone inwall.
3. vehicular manganese sewage disposal device according to claim 2, it is characterized in that: described reaction vessel connects a back-purge system, and described back-purge system one end connects water port, the other end ligation container.
4. vehicular manganese sewage disposal device according to claim 3, it is characterized in that: described reaction vessel connects a magnetic separator, and the high-speed separation pump is set between reaction vessel and magnetic separator, and the described magnetic separator the other end connects sludge pump.
5. vehicular manganese sewage disposal device according to claim 4 is characterized in that: described flocculation agent is polymerization iron class flocculation agent or polymeric aluminum class flocculation agent.
CN2010201937216U 2010-05-18 2010-05-18 Vehicle-mounted manganese sewage treatment device Expired - Fee Related CN201722191U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103011486A (en) * 2012-12-07 2013-04-03 常州大学 Method for removing gallium in sewage

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103011486A (en) * 2012-12-07 2013-04-03 常州大学 Method for removing gallium in sewage

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Granted publication date: 20110126

Termination date: 20110518