CN201716522U - Black carbon powder - Google Patents

Black carbon powder Download PDF

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Publication number
CN201716522U
CN201716522U CN2010202176049U CN201020217604U CN201716522U CN 201716522 U CN201716522 U CN 201716522U CN 2010202176049 U CN2010202176049 U CN 2010202176049U CN 201020217604 U CN201020217604 U CN 201020217604U CN 201716522 U CN201716522 U CN 201716522U
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CN
China
Prior art keywords
carbon powder
resin
styrene
black
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2010202176049U
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Chinese (zh)
Inventor
刘江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN ASCEND TECHNOLOGY Co Ltd
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Individual
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Priority to CN2010202176049U priority Critical patent/CN201716522U/en
Application granted granted Critical
Publication of CN201716522U publication Critical patent/CN201716522U/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model discloses black carbon powder, which comprises a carbon powder particle main body. A UV film is additionally arranged on the outer surface of the carbon powder particle main body. The surface of the UV film is covered with a flowable agent layer. The flowable agent layer is hexamethyl dichlorosilane or silicon dioxide. After adopting the technical scheme, by increasing the UV film on the surface of the carbon powder particles, the utility model can stop the carbon powder from being contacted with the outside and prevent the carbon powder from being subjected to action of light, air and materials to cause ageing and spalling, so that a pattern printed on paper can be stored for a long time and be always new.

Description

Black carbon powder
Technical field:
The utility model relates to a kind of black carbon powder.
Background technology:
Recently, the development trend of office automation and file colorize attracts people's attention.For the file that comprises picture (such as the chart of making of PC) by printer prints with duplicate the demand of the data that these print file are used to demonstrate with making subsequently, and growing for the demand of the full text part that duplicates routine.Because the image that printer produced generally comprises solid image, string diagram picture and half tone image, so need printer to produce high-quality solid image, string diagram picture and half tone image.
Electrophotographic image forming apparatus is meant and a kind ofly is used to utilize a kind of electric photographic imaging method to form the equipment of image on recording medium.The example of electrophotographic image forming apparatus comprises electricity photography duplicating machine, electrographic printer (for example, laser printer, LED printer etc.), facsimile recorder, word processor etc.
Handle box is meant the casket module in a kind of master component that is installed in imaging device removably, and wherein integrally be furnished with at least one and electric camera photosensitive photosensitive drums in charging device, developing apparatus and the cleaning device as treating apparatus, thereby they can be removably mounted in the master component of imaging device.
Be positioned at by a plurality of points on the circumferential surface of the electro-photographic light-sensitive drum of charging equipment uniform charging by exposure selectively such as the electrophotographic image forming apparatus of duplicating machine, laser printer, facsimile recorder etc. and form electrostatic latent image.Then, this equipment utilization developing apparatus, be visual image (image that forms by carbon dust), and provide autotype with required image by the carbon dust image being transferred on the recording medium such as paper by carbon dust is attached on the electrostatic latent image and with latent electrostatic image developing.After the transfer printing of carbon dust image, utilize cleaning equipment to remove to remain in the carbon dust on the circumferential surface of electro-photographic light-sensitive drum, making photosensitive drums is that ensuing imaging is prepared.
Present employed carbon dust in photographic fixing after on the recording mediums such as paper, because carbon dust is in naked state, after after a while, owing to be subjected to the scraping of light, air and other object, will fade and separate peeling phenomenon, have a strong impact on the permanance of carbon dust image.
Summary of the invention:
The purpose of this utility model is in order to overcome the shortcoming of above-mentioned prior art, to provide a kind of durable for a long time, and stability is high, not the black carbon powder that peels off of fugitive color.
For achieving the above object, the technical scheme that the utility model provides is: black carbon powder includes the carbon powder particle body, at outside surface increase one deck UV of carbon powder particle body paint film.
In order further to improve this carbon dust, the applicant has also done following improvement:
Surface coverage at the UV paint film has the flowable layer.
Affiliated flowable layer is hexamethyl dichlorosilane or silicon dioxide.
After adopting technique scheme, increase one deck UV paint film by surface at carbon powder particle, can intercept carbon dust and extraneous contacting, prevent that it is subjected to the effect of light, air and material and causes aging peeling off, but make the pattern long preservation that is printed on the paper, Chang Xin for a long time.
Description of drawings:
Fig. 1 is the structural representation of the utility model black carbon powder.
Embodiment:
Black carbon powder includes carbon powder particle body 1, at outside surface increase one deck UV of carbon powder particle body 1 paint film 2.Surface coverage at UV paint film 2 has hexamethyl dichlorosilane or silicon dioxide 3.
UV lacquer be a kind of can be in seconds under ultraviolet irradiation the coating of film-forming rapidly.It is by the automatic roller coat of machinery and equipment, sprays on the carrier, impels decomposition of initiator under the irradiation of ultraviolet light (wavelength is 320-390nm), produces free radical, causes the resin reaction, the instantaneous solidification film forming.
UV paint is different from common PU commonly used lacquer, PE lacquer and NC lacquer, is the paint of real environmental protection, does not contain any volatile substance, uses Product Green, health, the environmental protection of UV paint production.The UV paint film is the stereo structure structure, and hardness is big, and wearing quality is good, and transparency is good, and the product scratch resistance is bumped, rub resistance, stands the test of time.In the manufacturing process, handle by the oven dry of ultraviolet photo-curing machine, product is health environment-friendly more, does not produce objectionable impurities.
UV lacquer be a little: 1, solid content is high 2, hardness is good, and transparency is high by 3, yellowing resistance is good 4, long by 5, the efficient height of pot-life, and painting cost is low.
The carbon dust principal feature that has sprayed the UV lacquer has: handle through the intensive ultraviolet photocuring, the carbon dust color and luster that sticks on the paper is stable, and Chang Xin for a long time solves effectively that carbon dust fades and the aging problem of peeling off; Scratch resistance is drawn, and acid and alkali-resistance is not yielding.
Introduce the manufacture process of this carbon dust below
A. polymerization macromolecule resin, carbon black, charge control agent, the polypropylene wax with set component joins in the molten-bath, adds heat mixture to complete fusion and finely dispersed state under stirring;
B. the fused solution after being uniformly dispersed is through after having the pipeline of heat-insulation layer, under 160 ℃, the pressure of 1Mp, be atomized into droplet by atomizer, utilize the air-flow air that the droplet of atomizing shape is carried out drying then, the moisture content in the dry run droplet is evaporated, and then forms the black powder of graininess;
C. then spray the UV lacquer to the black powder of graininess, the carbon dust projection ultraviolet ray that scribbles the UV lacquer to the surface makes UV lacquer instantaneous solidification then, and the black powder of graininess drops in the gatherer;
D. black powder particles is carried out high-speed stirred, add hexamethyl dichlorosilane flowable in the time of stirring and carry out the toner surface modification;
E. after sieving, last mistake 100 eye mesh screens make the toner particles of diameter between 4~10 microns.
The content of carbon black is unrestricted, and can suitably select based on purposes.Preferably accounting for 1% to 15% qualitatively, and more preferably accounting for 3% to 10% qualitatively.When content qualitatively less than 1% the time, the colouring power of ink powder may reduce.When content qualitatively greater than 15% the time, carbon black can not scatter in ink powder, colouring power may reduce, and the electrical characteristics of ink powder may reduce.
Carbon black also can be used as masterbatch with resin combination.Resin is unrestricted and can select from known resin based on purposes.Its example comprises the polymkeric substance of styrene and its substitution product, styrol copolymer, plexiglass, polybutyl methacrylate resin, Corvic, vinylite, polyvinyl resin, acrylic resin, polyester resin, epoxy resin, the epoxy polyol resin, urethane resin, polyamide, polyvinyl butyral resin, polyacrylic resin, rosin, modified rosin, terpene resin, aliphatic series or alicyclic hydrocarbon resin, aromatic petroleum resin, chlorinated paraffin and paraffin.These can be by separately or be used in combination.
The example of the polymkeric substance of styrene and substitution product comprises polyester resin, polystyrene resin, poly-(to chlorostyrene) resin and polymethylstyrene resin.The example of styrol copolymer comprises styrene-to chloro-styrene copolymer, styrene-propylene copolymer, styrene-vinyl toluene copolymer, styrene-vinyl naphthalene multipolymer, styrene-methyl acrylate copolymer, styrene-ethyl acrylate copolymer, styrene-butyl acrylate copolymer, styrene-2-ethyl hexyl acrylate multipolymer, styrene-methylmethacrylate copolymer, styrene-ethyl methacrylate copolymers, styrene-butyl methacrylate copolymer, styrene-methacrylic acid α-chloromethyl ester multipolymer, styrene-acrylonitrile copolymer, styrene-ethenyl methyl ketone multipolymer, styrene-butadiene copolymer, styrene-isoprene copolymer, and styrene-vinyl cyanide-indene copolymer, styrene-maleic acid, and styrene-maleate copolymer.
By under high shear mixing or mediating masterbatch, can prepare masterbatch with resin and carbon black.In this step, for interaction higher between carbon black and the resin, organic solvent is preferably used.In addition, preferred adopt " water squeezing phase conversion method ", the aqueous slurry that wherein contains carbon black and water is mixed with resin and organic solvent or is mediated, thereby described colorant is transferred to described resinous principle, then except that anhydrating and organic solvent.According to this method, the wet piece of carbon black not drying directly is used.High shear diverting device for example three-roll grinder can be optimized for mixing or mediate.
Charge control agent
Charge control agent is not limited particularly, and can select from the known charge controlling agent according to purpose.Described charge control agent is preferably formed by the material preparation that has near transparent and/or white color, because carbon black can make charge control agent become black.
The example of charge control agent comprises the product that is obtained commercially: and the salicylic acid metal complex of the quaternary ammonium salt of trade mark BontronP-51 by name, the oxynaphthoic acid metal complex of Bontron E-82, Bontron E-84, the phenolic condensates of Bontron E-89 (Orient Chemical Industries, Ltd.); The quaternary ammonium salt molybdenum complex of TP-302 and FP-415 (Hodogaya Chemical Co.): the quaternary ammonium salt (Hoechst Ltd.) of the triphenylmethane derivative of the quaternary ammonium salt of CopyCharge PSY VP2038, Copy Blue PR and CopyCharge NEG VP2036 and Copy Charge NXVP434; The boron complexes of LRA-901 and LR-147 (Japan Carlit Co., Ltd.); Quinacridone, AZO pigments; Has for example high-molecular weight compounds of sulfonic acid group, carboxylic group and quaternary ammonium salt of functional group with other.
With the masterbatch melt kneading after, described charge control agent can be dissolved and/or be dispersed in the ink powder material.Described charge control agent directly is added into described ink powder material when can also and/or be dispersed in the organic solvent in dissolving.In addition, described charge control agent can be added on the surface of described toner particles after toner particles is produced.
According to the kind of adhesive resin, in view of the above the existence of the adjuvant that uses whether and the method for producing ink powder comprise process for dispersing, determine the content of charge control agent in the ink powder, and described content is not limited clearly.The content of charge control agent is preferably 0.1 part to 10 parts by mass by mass based on 100 parts adhesive resin by mass, and more preferably 0.2 part to 5 parts by mass.When the content of charge control agent less than 0.1 part by mass, electric charge may not controlled suitably.When the content of charge control agent greater than 10 parts by mass, the effect of charge control agent is weakened, and the electrostatic attraction of developing roller is increased, reason is the too much charging ability of ink powder, this can cause the flowability of developer or image density to reduce.
The above; it only is the preferable embodiment of the utility model; but protection domain of the present utility model is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the utility model discloses; the variation that can expect easily or replacement all should be encompassed within the protection domain of the present utility model.

Claims (3)

1. black carbon powder includes the carbon powder particle body, it is characterized in that: the outside surface at the carbon powder particle body increases one deck UV paint film.
2. black carbon powder according to claim 1 is characterized in that: the surface coverage at the UV paint film has the flowable layer.
3. black carbon powder according to claim 2 is characterized in that: affiliated flowable layer is hexamethyl dichlorosilane or silicon dioxide.
CN2010202176049U 2010-06-03 2010-06-03 Black carbon powder Expired - Fee Related CN201716522U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010202176049U CN201716522U (en) 2010-06-03 2010-06-03 Black carbon powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010202176049U CN201716522U (en) 2010-06-03 2010-06-03 Black carbon powder

Publications (1)

Publication Number Publication Date
CN201716522U true CN201716522U (en) 2011-01-19

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010202176049U Expired - Fee Related CN201716522U (en) 2010-06-03 2010-06-03 Black carbon powder

Country Status (1)

Country Link
CN (1) CN201716522U (en)

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Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: FOSHAN ASCEND TECHNOLOGY CO., LTD.

Free format text: FORMER OWNER: LIU JIANG

Effective date: 20120326

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 528200 FOSHAN, GUANGDONG PROVINCE TO: 528500 FOSHAN, GUANGDONG PROVINCE

TR01 Transfer of patent right

Effective date of registration: 20120326

Address after: Foshan City, Guangdong province 528500 city streets Gaoming District Fuwan Industrial Zone (two factory SETRA electric company)

Patentee after: Foshan Ascend Technology Co., Ltd.

Address before: Unit 601602, No. 1 Tian Town Nanhai Tianyou wealth building 528200 Guangdong digital city in Foshan province Guicheng in Nanhai District Ping Road

Patentee before: Liu Jiang

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110119

Termination date: 20130603