Environment-friendly type compound package material and packaging bag or packing box
One, technical field:
The utility model relates to the packing field, specifically relates to a kind of environment-friendly type compound film packing material and the packaging bag or the packing box that utilize this material.
Two, background technology:
The packaging bag of stock production and use shading, barrier excellence in the market, mainly be mould/paper/aluminium foil or mould/aluminium foil is the MULTILAYER COMPOSITE film package bag of main base material, as PE/ paper/PE/ aluminium foil/PET/PE, PE/ paper/PE/ aluminium foil/PE that the square brick type Tetra Pak of packing fruit drink etc. is used etc.This packaging bag is difficult to recycle, major cause has: the one, owing to adopted aluminium foil in the material, the recycling of waste and old packaging bag needs aluminium foil and plastic film are separated, and it all is quite difficult adopting sour molten method or adopting plastics clinkering hot melt together, also can bring new source of pollution.Though someone is processed into plastics after proposing it is pulverized because that aluminium foil wherein is crushed to is very tiny very difficult, thereby the goods that mold be the presentation quality inwardness all difficulty reach operating needs; Secondly, the packaging bag ply of paper is clipped between the two layers of plastic thin films, paper be separated also very difficult.In addition, generally use the polyurethane adhesive of ethyl acetate in the multilayer complex films production process as solvent, so not only wasted a large amount of ethyl acetates, and the volatilization of organic solvent also can cause environmental pollution and have problem such as disaster hidden-trouble in the production process, and residual micro-organic solvent in packaging bag also might endanger the healthy of people.
By retrieval; the patent No. is that the utility model of CN00217475.8 discloses a kind of disposable foodstuff packaging box; mainly constitute by box body and capping; capping is fitted on the lip flange of box body and makes the box body inner chamber become seal cavity; the clad aluminum foil layer that constitutes box body is followed successively by polypropylene layer, adhesive phase, aluminium foil, protective paint layer from the inside to the outside, and the clad aluminum foil layer that constitutes capping is followed successively by polypropylene layer, dope layer, aluminium foil, protective paint layer from the inside to the outside.This packing box can be used for packaging for foodstuff, has used aluminium foil in the material, uses the back to be difficult to aluminium foil is separated, and can not recycle fully.
Three, summary of the invention:
The technical problems to be solved in the utility model is: a kind of good barrier property, durable, nontoxic, non-environmental-pollution and the environment-friendly type compound package material that is easy to recycle and packaging bag or packing box are provided.
The technical solution of the utility model is:
A kind of environment-friendly type compound package material is composited by four tunics, and outermost layer is the protective film that oil polish forms, and inferior skin is a printing paper, and the 3rd layer is barrier layer, and innermost layer is a co-extrusion metallocene PE hot sealing layer.
Described oil polish is the water lustering oil of ultraviolet light polymerization; The water lustering oil of ultraviolet light polymerization is selected from a kind of in the ester modified polyurethane oil polish of water polyacrylic acid oil polish, aqueous polyurethane oil polish, water soluble acrylic acid; Barrier layer is polyester film that applies polyvinylidene chloride or the vacuum aluminum-coated polyester film that applies polyvinylidene chloride; Preferred three~five layers of the number of plies of co-extrusion metallocene PE hot sealing layer.
Described printing paper adopts alcohol-soluble printing ink print or water color ink printing, and described printing paper is white board, craft paper or art paper; The packing interlayer adopts adhesion agent bonding, and used adhesion agent is a solventless adhesive; Solventless adhesive is a solvent-free polyurethane adhesive.
Described environment-friendly type compound package material is made into packaging bag or packing box.
Positive beneficial effect of the present utility model:
1. outermost layer of the present utility model replaces polyethylene (PE) film with oil polish; the protective film that forms not only has certain binding power to printing paper; bright, transparent; play a protective role; and because thickness, the toughness of oil polish protective film are lower than PE film; help washing with water method printing paper is separated from waste and old packing, be convenient to recycle.
2. of the present utility model time skin is a paper, plays interception, and paper sheet stiffness is good simultaneously, is easy to moulding, improves the class and the visual impression of packing, and shelf display effect is preferably arranged, and paper is a green material simultaneously, is easy to recycle.
3. the 3rd layer of barrier layer of the present utility model has higher barrier for VMPET that applies PVDC or the PET that applies PVDC, can substitute aluminium foil, is convenient to recycle.If paper is separated, be aided with auxiliary agent, can be processed into and mould/plastic composite materials; If do not separate paper, be aided with auxiliary agent, can be processed into and mould/paper composites.
4. innermost layer hot sealing layer of the present utility model is a co-extrusion MPE layer, and heat-sealing temperature is low, intensity is high, can make the packing that obtain durable in use.
5. interlayer of the present utility model adopts solvent-free polyurethane adhesive bonding, and water color ink or alcohol-soluble printing ink are adopted in printing, saves resource, and can not pollute the environment generation.
6. packing purposes of the present utility model is wider, is not only applicable to the packing of general article, more can be used for the packing of most of food, as is suitable for the packing of solid kind food such as milk powder, bean powder, also is applicable to the packing of liquid type drinks such as milk, fruit juice.These packing have high barrier, low oxygen permeability, and resistance tocrocking is good, and this material is used for packing, transportation and the storage of sterile food, can effectively prolong effective period of food quality.
7. packing of the present utility model are easy to recycle, and can economize on resources, and are beneficial to environmental protection, are a kind of real environmentally friendly packing materials, will have fabulous economic and social benefit, are suitable for applying.
Four, description of drawings:
Fig. 1: the generalized section of the utility model packing structure
Five, the specific embodiment:
Embodiment 1:: a kind of environment-friendly type compound package material, referring to Fig. 1, this material is composited by four tunics; outermost layer is the protective film 1 that oil polish forms; inferior skin is that printing paper is a barrier layer 3 for 2, the three layers, and innermost layer is co-extrusion metallocene PE (MPE) hot sealing layer 4.
Wherein outermost layer oil polish protective film 1 is the water polyacrylic acid oil polish; barrier layer 3 is for applying the vacuum aluminum-coated polyester film (VMPET) of polyvinylidene chloride (PVDC); innermost layer co-extrusion metallocene PE hot sealing layer 3 is three layers; printing paper 2 adopts the alcohol-soluble printing ink print, and the packing interlayer adopts solvent-free polyurethane adhesive.
Packing preparation method of the present utility model:
1. printing ATTACH LABEL and relevant literal, pattern on the paper of choosing print and adopt alcohol-soluble printing ink;
2. the water lustering oil of coating ultraviolet light curing on printing paper forms the very thin protective film of one deck;
3. on VMPET, apply certain thickness PVDC, as barrier layer;
4. it is compound successively with solvent-free polyurethane adhesive to be compounded with the printing paper (inferior skin) of protective film (outermost layer), the barrier layer (the 3rd layer) that applies the VMPET of PVDC, three-layer co-extruded metallocene PE (MPE) hot sealing layer (innermost layer), promptly makes the packing with four layers of complex film.
Above-mentioned packing are cut out according to a conventional method, handled, heat-sealing food prepared therefrom packaging bag or packing box.
Embodiment 2: and embodiment 1 is basic identical, and difference is:
The environment-friendly type compound package material is composited by four tunics; outermost layer oil polish protective film 1 is the aqueous polyurethane oil polish; inferior outer printing paper 2 is a white board; adopt the alcohol-soluble printing ink print; the 3rd layer of barrier layer 3 is for applying the vacuum aluminum-coated polyester film of polyvinylidene chloride, and innermost layer metallocene PE hot sealing layer 4 adopts three-layer co-extruded.These packing are made square brick type milk pack box.
Embodiment 3: and embodiment 1 is basic identical, and difference is:
The environment-friendly type compound package material is composited by four tunics; outermost layer oil polish protective film 1 is the ester modified polyurethane oil polish of water soluble acrylic acid; inferior outer printing paper 2 is a craft paper; the printing of employing water color ink; the 3rd layer of barrier layer 3 is for applying the vacuum aluminum-coated polyester film of polyvinylidene chloride, and innermost layer metallocene PE hot sealing layer 4 adopts four layers of co-extrusion.
Embodiment 4: and embodiment 1 is basic identical, and difference is:
The environment-friendly type compound package material; be composited by four tunics; outermost layer oil polish protective film 1 is the aqueous polyurethane oil polish; inferior outer printing paper 2 is an art paper; the printing of employing water color ink; the 3rd layer of barrier layer 3 is for applying the polyester film of polyvinylidene chloride, and innermost layer metallocene PE hot sealing layer 5 adopts five-layer co-squeezing.
Embodiment 5: and embodiment 1 is basic identical, and difference is:
The environment-friendly type compound package material; be composited by four tunics; outermost layer oil polish protective film 1 is the aqueous polyurethane oil polish; inferior outer printing paper 2 is a white board; adopt the alcohol-soluble printing ink print; the 3rd layer of barrier layer 3 is for applying the polyester film of polyvinylidene chloride, and innermost layer metallocene PE hot sealing layer 5 adopts four layers of co-extrusion.