CN201648206U - Sludge treatment equipment - Google Patents

Sludge treatment equipment Download PDF

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Publication number
CN201648206U
CN201648206U CN2010290920037U CN201029092003U CN201648206U CN 201648206 U CN201648206 U CN 201648206U CN 2010290920037 U CN2010290920037 U CN 2010290920037U CN 201029092003 U CN201029092003 U CN 201029092003U CN 201648206 U CN201648206 U CN 201648206U
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China
Prior art keywords
sludge
mud
reaction tank
sludge treatment
equipment
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Expired - Lifetime
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CN2010290920037U
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Chinese (zh)
Inventor
李志光
何纯莲
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Hunan Kinghood Environmental Protection Technology Co., Ltd.
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HUNAN XIANGRUN ENVIRONMENT PROTECTING AND ENERGY SAVING CO Ltd
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Abstract

The utility model relates to equipment which is used to process sludge in urban sewage, in particular to the equipment how to separate water and the sludge in watery sludge. The equipment comprises a reaction tank, a coagulation pond which is connected with the reaction tank, a pressure filter which is connected with the coagulation pond. Wherein an output pipe of an ozone generator and a stirrer are connected on the reaction tank. In the utility model, in order to adapt with normal temperature sludge treatment process, a simple sludge treatment equipment is provided, the aim of low cost, good effect and meeting the national standard of processing the sludge is achieved.

Description

Sludge treatment device
Technical field
The utility model relates to the equipment of handling to mud in the municipal effluent, specifically how with water in the water-containing sludge and the isolating equipment of mud.
Background technology
Mud is the residues such as floating foam of sedimentable matters such as the organic matter that produces in sewage treatment process of sewage work, microbial bacteria micelle and sewage surface flotation, wherein contain toxic heavy metals such as a large amount of pathogenic bacterias, parasite, pathogenic microorganism, dioxin and arsenic, copper, mercury, chromium, even poisonous, the objectionable impurities that have radionuclide etc. to be difficult to degrade.The mud how further treatment and disposal sewage work is produced is a great problem in environmental protection field, the world today.Because the colloid of mud is inhaled bag water characteristic, causes the moisture percentage in sewage sludge height, volume is big, brings difficulty for stacking and transportation etc.Municipal sludge as arbitrarily throwing aside hill farmland or landfill lack of standardization, will cause huge potential threat as dealing with improperly or processing lack of standardization to ecotope.
Developed country disposes the emphasis of listing efforts at environmental protection in sludge treatment since nineteen nineties, and the traditional method of handling mud is mainly sanitary landfill, burning and heat energy utilization, soil utilization, aerobic-anaerobic digestion etc.Wherein sanitary landfill is simple relatively to equipment requirements, but needs a large amount of landfill places and the trucking costs of mud, easily produces secondary pollution problems such as groundwater pollution and foul smell dissipation; Burning and heat energy utilization technology make full use of the biogas of generation and set up the power house, and its power self-support rate can reach more than 50%, but burning method equipment and working cost costliness easily cause topsoil, and still residual a small amount of belongs to hazardous substance and handles class solid inorganic thing; It is one of main path of disposing of excess sludge that the soil utilizes technology, but and along with the scope of landfill is dwindled gradually, the soil utilization will be a main development trend, also be the comprehensive difficult problem of sludge disposal simultaneously; Since phase late 1980s, developed some new technologies and technology again, carried out sludge digestion, can shorten the residence time of mud in digester, strengthened the stability of mud as ultrasonic wave in developed countries such as Europe, the United States; Utilize earthworm to handle mud; Utilize the high pressure pyrolysis to destroy the jelling structure of mud, mud is carried out mummification, disinfection, this method can reduce the volume of mud, and dried excess sludge can become a kind of valuable agricultural fertilizer, the disadvantage of this method be the initial investment expense and every day institute's energy requirement expense too high.Make a general survey of external sludge treatment method of disposal and comprehensive utilization, general trend from burning and drying progressively be transformed into behind the high-efficiency dehydration again the utilization of resources take method as the leading factor.
China is because the sludge treatment dynamics of investment is little for a long time, early stage sewage work owing to there is not strict mud discharging supervision, generally peels away sewage and sludge treatment unit, pursue wastewater treatment rate unilaterally, simplify as much as possible even ignored the sludge treatment disposal unit; What have is also idle for a long time in order to save the sludge treatment facility that working cost will build up, with the wet mud of not doing any processing arbitrarily transport outward, simple landfill or stacking, cause many big cities the phenomenon in mud besieged city to occur, and begun to spread to small and medium-sized cities, brought totally unfavorable influence to ecotope.
Though China begins to pay close attention to the mud problem at present, but still it is low to rest on the hierarchy of skill, sludge treatment is in the state of serious hysteresis, and main method has concentrated landfill, macerates system compost, anhydration and incineration etc., and wherein concentrating landfill is the main method that sludge treatment is disposed.But for a long time owing to do not have the outer polymkeric substance of bag, mud micelle structure suction Bao Shui and the mud cenobium cellular water of breaking sludge effectively in the sludge treatment disposal process, cause Sewage Plant to handle the back moisture percentage in sewage sludge still up to 78-83%, transportation cost height when causing the mud landfill, landfill land seizure rate is huge, and very easily cause mud return molten, the secondary pollution that causes landfill such as ooze out, influence peripheral ecotope.
Comprehensive above-mentioned treatment process is found: owing to do not crack ECP (wrapping outer polymkeric substance), water-in-oil structure well and form sizeable mud granule, the sludge dewatering index is difficult to drop to below 78%, has influenced the application and the popularization of this Technology.Therefore, preparation NEW TYPE OF COMPOSITE sludge treatment reagent, development of new sludge treatment technique technology becomes the key issue that will solve the sewage plant sludge advanced treatment.
Oxidation technology and coagulation technology are the research focuses of sludge treatment in recent years.Its research contents relates generally to two aspects: promptly mud anticipates and coagulation technology and technology.Its key is to adopt the coagulation flocculation agent to form the suitable mud granule of size on the basis of using controlled wet oxidation technology destruction suction bag water structure, makes it to reach the purpose that removes easily with separate easily suction Bao Shui.But the technical matters of this respect is still immature at present, does not have technological breakthrough in minimizing, stabilization and innoxious each link.For the existing report of the research of this problem, from present research, selection is basic unit, is that skeleton, multilayer shape resin are initiator with the polyamines polyene with the crude phenols resin, and carrying out block polymerization with propylene oxide and epoxy hexane under the effective catalyst effect, to obtain many aromatic rings polyphenol amine stratiform resin type tridimensional network emulsion splitter OX-9 etc. be main.As the influence of research such as Chen Yinguang acid and tensio-active agent to activated sludge dehydration performance, settling property and ESP.Investigate the influence of medicament by the content of measuring polysaccharide, protein, DNA in the dehydration clear liquid to flocculating settling.Thereby experimental result shows surface properties by change mud flco of acid and tensio-active agent, has reduced mud flco content, discharges dewatering and settling property that water-in-oil has improved mud.Novak etc. studied iron ion in decision flco structure and dehydration characteristic effect, especially iron ion and biological enzyme in protein interactions.They point out that protein is removed in the solution when iron ion increases.This also causes mud CST to reduce, and helps sludge dewatering.In the coagulation technology of sludge treatment, the use composite flocculation agent/or claim that the research of coagulation agent is more, its kind mainly contains: 1) inorganic flocculating agent mainly contains molysite (FeCl 3, FeSO 4Deng and polymkeric substance) and aluminium salt (Al 2(SO 4) 3, AlCl 3Deng and polymkeric substance such as polymerize aluminum chloride, polyaluminium sulfate etc.); 2) synthetic organic polymer flocculation agent is as polyamine class, sodium polyacrylate, polypropylene phthalein amine etc.; 3) natural macromolecule flocculating agent; 4) microbial flocculant, it can degrade wastewater containing phenol, organophosphorus pesticide wastewater, contain the domestic water of greasy dirt and HOM such as protein, starch.But because the shortcoming of aspect such as expensive, the independent result of use of price is not obvious has influenced the industrial application and the popularization of these technology.
In the prior art with treatment process together along with, the equipment with those processing method couplings is also disclosed.
Usually sewage work is an excess sludge at the mud that sewage treatment process need carry out advanced treatment.So-called excess sludge is the active sludge outside secondary sedimentation basins (or settling region) discharge system in (excess activated sludge) Sludge System.
The utility model content
The purpose of this utility model provides a kind of equipment in normal temperature, usual pressure condition processing excess sludge.
The sludge treatment device that the utility model provides comprises reaction tank, the coagulation pond that is connected with reaction tank, and the pressure filter that is connected with the coagulation pond wherein, is connected with the output tube and the agitator of ozonizer on the reaction tank.
It is the purpose of reaction tank that oxidation directed agents, conditioning agent, ozone are fully contacted with mud.Therefore, need fully stir mud.Simultaneously, ozone adopts the aerating apparatus input from the bottom of reaction tank.
The top of reaction tank is provided with exhaust gas processing device, excess sludge feeding unit, liquid charging opening and solid feed inlet.
When using the utility model, at first in reaction tank, inject pending excess sludge, add oxidation directed agents and conditioning agent, under agitation feed ozone, after reaction finishes, add the coagulation agent; Be input to then in the coagulation pond, be input to filter-press dehydration in the pressure filter through pump again.
When using the utility model, owing to adopt O 3Combine with oxidation initiator (this what is called oxidation initiator is oxidation directed agents and the reaction product of CaO in the aqueous solution), form hydroxyl radical free radical, collaborative high-energy state electronics e *MOFe makes up energy state and the symmetric interface s-g of track with initiation mass transfer body, s-l microelectronics transfering system, make organic sludge organism film and cellularstructure generation redox processes, breaking sludge zoogloea structure, smash phenyl amines, organic macromole gauze bio membrane structures such as the outer polymkeric substance of phenol and bag, generate organic free radical (R), the further oxidation of organic free radical makes organism hydration layer membrane structure, destroy protein, the organic plasma membrane feature structure of macromole such as polysaccharide, discharge zoogleic suction Bao Shui and combination water, by organic micellar structure in oxidation and the degraded mud, discharge and inhale Bao Shui and water of constitution, under coagulation agent effect, through the coalescent granulating of organic mud of rupture of membranes, toxic heavy metal ion chelating coagulation, water of constitution in the separated sludge effectively, structure cell water, hapteron water.
The utility model is handled mud technology for adapting to normal temperature, and a kind of simple sludge treatment device is provided, and has reached the purpose that cost is low, effective, processing mud is up to state standards.
Description of drawings
Fig. 1 is the sketch of equipment among the utility model embodiment; I reaction tank wherein, II ozonizer, III air compression system, IV press filteration system, V coagulation pond.
Embodiment
Embodiment 1
As shown in Figure 1, the sludge treatment device that the utility model provides comprises that sludge treatment device provided by the invention comprises reaction tank I, ozonizer II, air compression system III, press filteration system IV and coagulation pond V.Wherein, also be connected with agitator 1 on the reaction tank I, exhaust gas processing device 2, excess sludge feeding unit 3, liquid charging opening 10 and solid feed inlet 11; Bottom in reaction tank I and coagulation pond all is provided with emptying pipe 8, also is provided with the aerating apparatus 4 that is communicated with ozonizer II in the bottom of reaction tank; Press filteration system IV communicates with air compression system III, and, by providing oxygen-rich air to ozonizer II; Coagulation pond V is communicated with press filteration system IV by dehvery pump 9.
Operating process:
1, off-response pond mud valve 12 is opened 3 chargings of reaction tank excess sludge feeding unit, and adds the oxidation directed agents and the CaO of metering by solid feed inlet 11;
2, during mud sample introduction 60%, start air compression system, cooling system, air compression system and oxygen enrichment system are formed air compression system.When treating that air compressor machine pressure of storage tank in the air compression system reaches to 0.4-0.8MPa, open cooling system, behind air compression system and the cooling system operation 6~10min, start oxygen enrichment system and ozone generation system;
When 3, the mud sample reached metering in the I of question response pond, stirrer 1 was opened and is stirred, and behind the 5min, opened oxygen enrichment system and ozone generation system II, and mud carries out interface transfer transport and oxidising process;
4, after oxidation finishes, stop ozone generation system earlier and stop oxygen enrichment system again, stop refrigeration system again, stop air compressor machine at last, behind 5~10min, under agitation condition, add the coagulation agent, after 6~8 minutes reaction tank mud valve 12 is opened, the mud sample enters storage basin V and treats press filtration;
5, open pressure filter, treat that filter plate compresses after, open all filtrate outlets 7; Open feed valve 13 and pump discharge valve 14 again, closing volume valve 15 is opened dehvery pump 9 at last, enters the common press filtration stage;
When 6, treating that the pressure filter water flow diminishes, when the quiet counterpressure of pressure filter reached to 2.52Mpa, feeding was full to the press filtration frame for pump at this moment.Stop dehvery pump 9 then, open reverse flow valve 15, the 3~10min that refluxes keeps quiet counterpressure in 2.60MPa.
7, open air compressor machine, when regulating pressure of storage tank 0.80MPa, occlusion pressure filter air outlet valve 16 and feed valve 13 are opened pressure filter gas squeezing system.After air pressure rose to 0.80MPa, static pressure 5min~20min closed intake valve 5, closes air compressor machine.Open feed valve 13, open air outlet valve 16, the gas in the slow emptying air bag unclamps oil-pressure pump after the balance, automatically dump.(the about 30mm of mud cake mean thickness)
8, detecting processing back moisture percentage in sewage sludge is below 55%, and the mean value fuel value is 2380 kilocalorie/kilograms.
Mud after the method that the utility model provides is handled can reach following technical indicator:
Table 1
Sequence number Test item Technical indicator Detect data
1 Primary sludge excrement colibacillus group number 10 4Individual/L 10 4Individual/L
2 The primary sludge water content 99.1%
3 Handle back mud excrement colibacillus group number 800/L 225/L
4 Handle the back sludge moisture content ≤55% ≤55%
5 Handle after-filtration colority of water (extension rate) 300mg/L
6 Handle after-filtration water excrement colibacillus group number 500/L 230/L
7 Handle after-filtration water phenyl amines content 0.5mg/L ≤0.3mg/L
8 Handle after-filtration water volatile phenol content 0.5mg/L ≤0.2mg/L
9 Handle after-filtration water benzene content 0.1mg/L ≤0.1mg/L
10 Handle after-filtration water total chrome content 1.5mg/L ≤1.0mg/L
11 Handle after-filtration water total mercury content 0.05mg/L 0.038mg/L
12 Handle the total lead content of after-filtration water 1.0mg/L 0.32mg/L
13 Handle back mud organic substance degradation rate ≥50% ≥75%
Table 2 (toxic heavy metal is the result after solidification treatment)
Sample number into spectrum Sample type Chemical oxygen demand (COD) Plumbous Arsenic Mercury Cadmium
Water sample Filtrate 72 0.1(L) 0.0024 0.06×10 -3 0.01(L)
Leach toxicity (mg/L) Handle back mud / 0.2 0.0573 2.6×10 -3 0.06
Full dose (mg/kg) Handle back mud / 71.2 25.95 4.191 5.6

Claims (3)

1. a sludge treatment device comprises reaction tank, the coagulation pond that is connected with reaction tank, and the pressure filter that is connected with the coagulation pond wherein, is connected with the output tube and the agitator of ozonizer on the reaction tank.
2. sludge treatment device according to claim 1 is characterized in that the output tube of ozonizer is communicated with the aerating apparatus of reaction tank bottom.
3. sludge treatment device according to claim 1 is characterized in that the top of reaction tank is provided with exhaust gas processing device, excess sludge feeding unit, liquid charging opening and solid feed inlet.
CN2010290920037U 2010-02-05 2010-02-05 Sludge treatment equipment Expired - Lifetime CN201648206U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102145974A (en) * 2010-02-05 2011-08-10 湖南湘牛污泥深度处理有限公司 Method and equipment for treating sludge in normal state
CN104136382A (en) * 2012-02-29 2014-11-05 三菱综合材料株式会社 Sludge treatment facility
CN106630378A (en) * 2016-10-20 2017-05-10 浙江工商职业技术学院 Sludge reduction method by using ozone
CN106807028A (en) * 2016-12-05 2017-06-09 中海油能源发展股份有限公司北京安全环保工程技术研究院 A kind of oil-based drill cuttings oxidation and stabilization processes device and method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102145974A (en) * 2010-02-05 2011-08-10 湖南湘牛污泥深度处理有限公司 Method and equipment for treating sludge in normal state
CN104136382A (en) * 2012-02-29 2014-11-05 三菱综合材料株式会社 Sludge treatment facility
CN104136382B (en) * 2012-02-29 2015-12-02 三菱综合材料株式会社 Sludge treatment device
CN106630378A (en) * 2016-10-20 2017-05-10 浙江工商职业技术学院 Sludge reduction method by using ozone
CN106807028A (en) * 2016-12-05 2017-06-09 中海油能源发展股份有限公司北京安全环保工程技术研究院 A kind of oil-based drill cuttings oxidation and stabilization processes device and method

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C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: HU'NAN XIANGNIU ADVANCED SLUDGE TREATMENT CO., LTD

Free format text: FORMER OWNER: HU'NAN XIANGRUN ENVIRONMENTAL PROTECTION AND ENERGY SAVING CO., LTD.

Effective date: 20110602

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 410205 ROOM 303, LUYUAN BUILDING 3, NO. 636, LUGU AVENUE, HIGH-TECH. ZONE, CHANGSHA CITY, HU'NAN PROVINCE TO: 410000 20004, BUILDING 1, BOBO TIANXIACHENG, NO. 368, FURONG SOUTH ROAD, CHANGSHA CITY, HU'NAN PROVINCE

TR01 Transfer of patent right

Effective date of registration: 20110602

Address after: 410000, 368 Furong Road, Hunan, Changsha, first BOBO, 20004 world city

Patentee after: Hunan Xiangniu Sludge Advanced Treatment Co., Ltd.

Address before: 410205 Hunan province Changsha City Lugu high tech Zone Road No. 636 building third Room 303 Yuan Lu

Patentee before: Hunan Xiangrun Environment Protecting and Energy Saving Co., Ltd.

C56 Change in the name or address of the patentee

Owner name: HU'NAN QINGHE SLUDGE RESOURCES CO., LTD.

Free format text: FORMER NAME: HU'NAN XIANGNIU ADVANCED SLUDGE TREATMENT CO., LTD.

CP03 Change of name, title or address

Address after: 410005, No. 20004, Furong world road, No. 368 Furong Road, Hunan, Changsha Province, No. first, BOBO

Patentee after: Hunan Kinghood Resource Utilization of Sludge Co., Ltd.

Address before: 410000, 368 Furong Road, Hunan, Changsha, first BOBO, 20004 world city

Patentee before: Hunan Xiangniu Sludge Advanced Treatment Co., Ltd.

ASS Succession or assignment of patent right

Owner name: HUNAN KINGHOOD ENVIRONMENTAL PROTECTION TECHNOLOGY

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Effective date: 20150723

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Effective date of registration: 20150723

Address after: 410004 Hunan province Changsha Yuelu District City Garden Road No. 16 torch city M building 7 floor

Patentee after: Hunan Kinghood Environmental Protection Technology Co., Ltd.

Address before: 410005, No. 20004, Furong world road, No. 368 Furong Road, Hunan, Changsha Province, No. first, BOBO

Patentee before: Hunan Kinghood Resource Utilization of Sludge Co., Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20101124