CN201463462U - Plate-fin thermal-coupled rectification device - Google Patents
Plate-fin thermal-coupled rectification device Download PDFInfo
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- CN201463462U CN201463462U CN2009201246605U CN200920124660U CN201463462U CN 201463462 U CN201463462 U CN 201463462U CN 2009201246605 U CN2009201246605 U CN 2009201246605U CN 200920124660 U CN200920124660 U CN 200920124660U CN 201463462 U CN201463462 U CN 201463462U
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Abstract
The utility model provides a plate-fin thermal-coupled rectification device. The device mainly comprises a rectification plate bundle, a liquid distribution device and a gas distribution device, wherein, the rectification plate bundle comprises baffle plates, fins and seals; a fin and a seal are arranged between two adjacent baffle plates so as to form an interlayer; the interlayer forms a fluid passage; in the fluid passage, liquid flows downwards, and gas flows upwards; each two adjacent fluid passages are an upper tower fluid passage and a lower tower fluid passage; and the upper tower fluid passages and the lower tower fluid passages are superposed together layer by layer. The device couples the upper tower fluid passages and the lower tower fluid passages in the field of low-temperature air rectification separation into a whole body, so as to eliminate the traditional main condensation evaporator, reduce the working pressure of the lower tower, and save the energy consumption of an air compressor.
Description
Technical field
The utility model relates to a kind of internal thermal coupled plate-fin rectifier unit that tower connects under the tower that is applied to, belong to the distillation technology in Cryogenic air separation field.
Background technology
In cryogenic air separation process, the distillation process operation affects its energy consumption significantly, and energy consumption accounts for operating cost more than 80%.Along with energy crisis in the global range and the environmental protection demand that grows to even greater heights, how to improve the production efficiency of distillation process, the energy consumption that reduces process has caused that various countries pay close attention to.The research of current rectifying mainly comprises two aspects: the design of rectifying Model Innovation and rectifying device.The rectifying Model Innovation will instruct rectifying device exploitation and design in theory.Up to now, the cryogenic air separation flow process is divided by the rectifying pattern and can be divided into single rectification column flow process and double rectification column flow process.
Figure 1 shows that the single rectification column flow process in the Cryogenic air separation flow process, having shown in the figure: tower body 11, one condenser/evaporators 12, one subcoolers 13, one choke valves 14 of a single rectification column etc.Described flow process is to develop on the steam recompression rectifying pattern basis of generally using in industrial production.Steam recompression rectifying mode feature is by compressor compresses rectifying column top gas products, and the grade that improves gas heat makes it to be enough to be used in the process of boiling again at the bottom of the tower.The single rectification column flow process can only be produced a kind of net product, and recovery rate is low, and economic effect is poor, only is used for some small-sized air separation unit and the device of producing liquid form product.
Figure 2 shows that the double rectification column flow process in the Cryogenic air separation flow process, having shown in the figure: go up tower 21, following tower 22, main condenser evaporimeter 23, subcooler 24 and choke valve 25 etc.Now the Cryogenic air separation industry extensively adopts this distillation process, it overcome the single rectification column flow process only with produce a kind of net product, recovery rate is low and the shortcoming of economic effect difference.
Current reduction Cryogenic air rectifying separating energy consumption more and more is subjected to the attention of industry, and distillation process cuts down the consumption of energy and will reduce effective loss of energy exactly, and the available energy loss is caused by following irreversible procedure: the pressure that (1) fluid flows falls-the pressure reduction motive force; (2) mixing of heat transfer between the different temperatures logistics or different temperatures logistics-temperature difference motive force: the mass transfer between the uneven logistics of (3) phase concentration or the mixing-concentration difference motive force of variable concentrations logistics.Wherein reducing temperature difference motive force is mainly reflected in and reduces the up and down heat exchange mean temperature difference of main condenser evaporimeter (being called for short main cold) between the tower.Therefore many high-performance heat exchangers arise at the historic moment.For example, thermal siphon formula condenser/evaporator, forced cyclic type condenser/evaporator, two boiling condenser/evaporator (patent No. is ZL00226629.6) and film-type condensation evaporimeter etc.Main cold heat exchange mean temperature difference is very big to the influence of energy consumption, and particularly large-scale low-pressure air separation plants is more remarkable, and the main cold temperature difference reduces by 0.1 ℃, the pressure reduction～4.2kPa of following top of tower.In the design of air separation plant, the small-sized empty cold temperature difference of master of dividing is generally 3 ℃, and adopt the cold temperature difference of master of dipping bath formula structure to be generally 1.3 ℃～2 ℃ big-and-middle-sized empty the branch, adopts the cold temperature difference of master of membrane type structure can be reduced to 0.5 ℃～0.8 ℃.The big-and-middle-sized empty cold temperature difference colder than dipping bath formula master of membrane type master of dividing reduces by 0.8 ℃～1.2 ℃, and following top of tower pressure can reduce 33.6kPa～50.4kPa, and air press energy consumption can reduce by 3.3%～5.1% like this.This is for large air separation plant, and energy-conservation is very considerable.But along with leading cold minimum heat transfer temperature difference near the limit, traditional double rectification column energy consumption decline space is little.Many experts carry out the thermodynamics evaluation analysis to distillation process, find that internal thermal coupled distillation technology is an energy-conservation effective and efficient manner in the energy-saving rectifying technology that proposes up to now.
Internal thermal coupled Finestill energy-saving principle is introduced the Cryogenic air separation field, and exploitation is fit to the internal thermal coupled distillation process and the internal thermal coupled rectifying device of Cryogenic air separation, will break through existing power-saving technology bottleneck.
Summary of the invention
The purpose of this utility model is to overcome the deficiency that prior art exists, and provide a kind of employing thermal coupling rectification device flow process, the top of tower and the bottom of last tower are thermally coupled in together down, thereby cancellation main condenser evaporimeter, make down the top of tower temperature less than last column bottom temperature, thereby reduce pressure tower down greatly, reduce the plate-fin thermal coupling rectification device of irreversible loss.
The purpose of this utility model is finished by following technical solution, and it mainly is made up of rectifying plate bundle, liquid dispensing apparatus and gas distributing device, and described rectifying plate bundle is made of dividing plate, fin and strip of paper used for sealing; Be provided with fin, strip of paper used for sealing and form an interlayer between two adjacent dividing plates, described interlayer forms the fluid passage of a gas that feeds to the liquid of current downflow and upwards flow; Two fluid passages of adjacent layout are respectively tower fluid passage and Xia Ta fluid passage, and they by one deck alternating floor stack together.
The described tower fluid passage upper fins spacing that goes up is greater than the lower fins spacing; And the upper fins spacing of described Xia Ta fluid passage is less than the lower fins spacing; Described fin height is 8-50mm, and thickness is 0.1-0.2mm, and the fin form is a kind of in flat type, mixed type, porous type or the undaform.
Described liquid dispensing apparatus comprises that one is divided into the distributing fluids passage of fluid passage and gas passage; Offer equally distributed hole on the fin in the described fluid passage that passes through for liquid, below this has the fin in described hole, be provided with the strip of paper used for sealing of inclination, and be provided with the district of passing a bridge and be connected with the fluid passage.
Be horizontally disposed with two or more punching plain fins in the described fluid passage, the perforated area of the punching plain fin on top is bigger than the perforated area of bottom punching plain fin; Described gas passage is connected in described gap bridge district, and is provided with the refluence sheet in gas passage; The side of described gas passage is provided with and is used for the gas vent of drawing after the gas flow guiding centralized collection.
Described gas distributing device includes one and enters from the side and introduce the distribution of gas passage of gas by a flow deflector, is respectively arranged with the gas-liquid guide pad thereafter and the district of passing a bridge, and is connected with described fluid passage.
Described gas-liquid guide pad is that a cross section is trapezoidal rectangular.
The utility model is broken in the Cryogenic air separation double rectification column flow process down the top of tower temperature must be greater than the restriction of last column bottom temperature, thereby reduces tower operating pressure down, reduces the air compressor energy consumption, reduces the irreversible loss that Cryogenic air rectifying separates; It has compactness rational in infrastructure, and is easy to use, reliable, and energy consumption such as reduces greatly at characteristics.
Description of drawings
Fig. 1 is the single rectification column flow process in the Cryogenic air separation flow process.
Fig. 2 is the double rectification column flow process in the Cryogenic air separation flow process.
The thermal coupling Cryogenic air rectifying separation process of Fig. 3 for adopting in the utility model.
Fig. 4 is the structural representation of rectifying plate bundle in the utility model.
Fig. 5 is the intrafascicular profile of going up the tower fluid passage of the utility model rectifying plate.
Fig. 6 is the profile of the intrafascicular Xia Ta of the utility model rectifying plate fluid passage.
Fig. 7 is the structural representation of the liquid dispensing apparatus in the utility model.
Fig. 8 is the structural representation of the gas distributing device in the utility model.
The specific embodiment
Below in conjunction with accompanying drawing the utility model is described in detail:
The rectifying of thermal coupling rectification device flow process is calculated in the utility model: described rectifying computational mathematics model adopts equilibrium stage rectifying model; This rectifying model adopts theoretical stage (plate) to suppose and the full level hypothesis of mixing that the fundamental equation group of using has the molar fraction of the equation that balances each other, mass balance equation, heat balance equation and component to add and equation in calculating.Use the rectifying column of this model hypothesis to be called theoretical rectifying column, the balance progression of calculating is exactly the theoretical cam curve of rectifying column.
The calculating of thermal coupling rectification device flow process is different with the conventional rectification flow process just to have inputed or outputed additional heat in the equilibrium stage of thermal coupling.This function can be implemented in existing commercialization flowsheeting software, as ASPEN, VMGSim, PRO/II and HYSYS etc.Carry out simple declaration based on HYSYS flowsheeting software below.The state equation that air low temperature rectifying separates adopts P-R (Peng-Robinson) equation, then the mutual coefficient of binary of nitrogen-oxygen-argon ternary system is revised, then set up the rectifying model according to regular situation, different is quantity of heat given up on the equilibrium stage of Xia Ta top the same tower bottom thermal coupling, corresponding input heat on the equilibrium stage of last tower bottom with the thermal coupling of Xia Ta top, by the temperature difference relation of tower thermal coupling part about the electrical form function association of HYSYS, just can calculate then.
Plate-fin thermal coupling rectification device described in the utility model is development on the plate-fin heat exchanger basis, but has increased the rectifying function on the plate-fin heat exchanger basis; The elementary cell of plate-fin thermal coupling rectification device is compositions such as dividing plate, fin and strip of paper used for sealing; Place fin between adjacent two dividing plates, strip of paper used for sealing etc. are formed an interlayer, are called the fluid passage.Liquid that flows downward and the gas that upwards flows are arranged in the fluid passage, and liquids and gases carry out heat and mass at the flow process of fluid passage, and single fluid passage just is equivalent to a conventional rectifying passage.Last tower fluid passage and Xia Ta fluid passage one deck alternating floor are stacked, become an integral body to form the rectifying plate bundle by soldering, and the rectifying plate bundle is equipped with necessary gas-liquid distributor, adapter, end socket, supporting etc. and has just formed the plate-fin thermal coupling rectification device.
The effect of the utility model median septum, fin and strip of paper used for sealing: spacer function is that last tower logistics and following tower logistics are separated, and heat exchange area is provided one time.The fin effect is constantly to change intensity and the bearing capacity that uprising gas and dropping liq flow direction improve mass-transfer efficiency in the fluid passage, secondary heat exchange area and raising rectifier unit are provided.The strip of paper used for sealing effect is to cut apart and closed channel.
Fin arrangement described in the utility model: the spacing of fin changes when adopting fin form of the same race in the same fluid passage, or adopt the fin of several forms in the same fluid passage simultaneously, even stacked two-layer or multilayer fin in fluid passage.The profile of plate-fin thermal coupling rectification device described in the utility model: rectangular.
Shown in Figure 3, the utility model mainly is on the basis of structure shown in Figure 2, last tower hypomere in traditional Cryogenic air rectifying separation process and following tower epimere is thermally coupled in together, thereby has cancelled the main condenser evaporimeter; Having shown in the figure: go up tower 31, following tower 32, plate-fin thermal coupling rectification device 33, subcooler 34, choke valve 35, etc.Described plate-fin thermal coupling rectification device 33 mainly is made up of rectifying plate bundle, liquid dispensing apparatus and gas distributing device, and described rectifying plate bundle is made of dividing plate, fin and strip of paper used for sealing; Be provided with fin, strip of paper used for sealing and form an interlayer between two adjacent dividing plates, described interlayer forms the fluid passage of a gas that feeds to the liquid of current downflow and upwards flow; Two fluid passages of adjacent layout are respectively tower fluid passage and Xia Ta fluid passage, and they by one deck alternating floor stack together.
The described tower fluid passage upper fins spacing that goes up is greater than the lower fins spacing; And the upper fins spacing of described Xia Ta fluid passage is less than the lower fins spacing; Described fin height is 8-50mm, and thickness is 0.1-0.2mm, and the fin form is a kind of in flat type, mixed type, porous type or the undaform.
Described liquid dispensing apparatus comprises that one is divided into the distributing fluids passage of fluid passage and gas passage; Offer equally distributed hole on the fin in the described fluid passage that passes through for liquid, below this has the fin in described hole, be provided with the strip of paper used for sealing of inclination, and be provided with the district of passing a bridge and be connected with the fluid passage.
Be horizontally disposed with two or more punching plain fins in the described fluid passage, the perforated area of the punching plain fin on top is bigger than the perforated area of bottom punching plain fin; Described gas passage is connected in described gap bridge district, and is provided with the refluence sheet in gas passage; The side of described gas passage is provided with and is used for the gas vent of drawing after the gas flow guiding centralized collection.
Described gas distributing device includes one and enters from the side and introduce the distribution of gas passage of gas by a flow deflector, is respectively arranged with the gas-liquid guide pad thereafter and the district of passing a bridge, and is connected with described fluid passage.
Described gas-liquid guide pad is that a cross section is trapezoidal rectangular.
Fig. 4 is a rectifying plate bundle in the utility model, and the rectifying plate bundle is the core of plate-fin thermal coupling rectification device.It includes strip of paper used for sealing 41, fin 42, dividing plate 43, goes up the rising steam 44 in the tower fluid passage, the dropping liq 45 in the last tower fluid passage, the rising steam 46 in the Xia Ta fluid passage, the dropping liq 47 in the Xia Ta fluid passage.The Xia Ta fluid passage is passed to the tower fluid passage to heat, and is carrying out the rectifying mass-and heat-transfer between the vapour-liquid in each fluid passage.
Fig. 5 is a fin profile of rectifying plate Shu Shangta fluid passage in the utility model, this fluid passage upper fins gap ratio lower fins spacing is big, the hydraulic radius that just goes up the tower fluid passage increases with highly rising, and can guarantee to have in the fluid passage a good rectifying mass transfer effect like this.Last tower fluid passage absorbs heat from the Xia Ta fluid passage, the rising quantity of steam increases with rising on the fluid passage, and the dropping liq amount descends with the fluid passage and reduces.For control operation gas speed a reasonable percentage of fluid passage spotting out gas speed (conventional generally get spotting out gas speed 70%), increased hydraulic radius with the fluid rising passway.In addition, because spacing continually varying fin is difficult to realize on producing, and different equidistantly fin ladder is arranged on the performance and also can finely substitutes, and the hydraulic radius of fluid passage is not to change continuously but staged changes.
Fig. 6 is a fin profile of rectifying plate bundle Xia Ta fluid passage in the utility model, and it is just in time opposite with situation shown in Figure 5.
Fig. 7 is the liquid dispensing apparatus in the utility model.Fluid passage 71 is divided into two, and is divided into fluid passage 72 and gas passage 73.The design of fluid passage 71 is: liquid is introduced the spacing of fin from the top, have equally distributed circular hole on the fin, liquid flows on the inclination sealing strip 74 from aperture, become wire by liquid behind the inclination sealing strip by spot distribution and distribute, liquid is distinguished 75 backs with the membranaceous fluid passage 71 that enters by passing a bridge then.In fact fluid passage is exactly the punching fin of horizontal positioned, but the general fin of placing two kinds of punching sizes of this passage, the hole on the upper fins is smaller, the Kong Yaoda on the lower fins some.The upper fins perforate is smaller to be for following consideration, liquid is introduced from fluid passage top one end, thereby there is bottom horizontal flow sheet in liquid in channel roof, there is pressure reduction in the liquid of same like this horizontal direction, liquid distributes just inhomogeneous, if allow liquid from top to bottom continuously by the bigger aperture of several roads resistance, the fluid pressure of same horizontal direction will compare evenly.So the upper fins effect may be summarized to be balanced fluid pressure.The lower fins perforate is more greatly in order to reduce small hole stream speed, prevents from that liquid from flowing to produce on the inclination sealing strip 74 to splash, and liquid distributes can also reduce simultaneously uniformly and distinguishes uprising gas carrying secretly liquid 75 from passing a bridge like this.The design of gas passage 76 is: gas enters the district 75 of passing a bridge by the fluid passage, enters gas passage 73 then.Flow deflector is set in the gas passage 73 draws the gas flow guiding centralized collection from the side; The gas vent channels designs is basic identical in the design of gas passage and the conventional plate-fin heat exchanger.
Fig. 8 is the gas distributing device in the utility model.Gas enters gas passage 81 from the gas distributor side by flow deflector, and the guiding by gas-liquid guide pad 82 enters the district 83 of passing a bridge then, then enters fluid passage 12.Liquid 84 flows downward from the fluid passage, and a part directly enters the district 83 of passing a bridge, and another part enters the district 83 of passing a bridge after by gas-liquid guide pad 85 again.Two strands of liquid converge the back and enter fluid passage from the district 83 of passing a bridge, and are preferably in and discharge this device after the bottom is converged.Described gas-liquid guide pad 82 is that a cross section is trapezoidal rectangular, and effect is to prevent that liquid from falling into gas passage and changing gas and the flow direction of liquid.
Claims (6)
1. plate-fin thermal coupling rectification device, it mainly is made up of rectifying plate bundle, liquid dispensing apparatus and gas distributing device, it is characterized in that described rectifying plate bundle is made of dividing plate, fin and strip of paper used for sealing; Be provided with fin, strip of paper used for sealing and form an interlayer between two adjacent dividing plates, described interlayer forms the fluid passage of a gas that feeds to the liquid of current downflow and upwards flow; Two fluid passages of adjacent layout are respectively tower fluid passage and Xia Ta fluid passage, and they by one deck alternating floor stack together.
2. plate-fin thermal coupling rectification device according to claim 1 is characterized in that the described tower fluid passage upper fins spacing that goes up is greater than the lower fins spacing; And the upper fins spacing of described Xia Ta fluid passage is less than the lower fins spacing; Described fin height is 8-50mm, and thickness is 0.1-0.2mm, and the fin form is a kind of in flat type, mixed type, porous type or the undaform.
3. plate-fin thermal coupling rectification device according to claim 1 is characterized in that described liquid dispensing apparatus comprises that one is divided into the distributing fluids passage of fluid passage and gas passage; Offer equally distributed hole on the fin in the described fluid passage that passes through for liquid, below this has the fin in described hole, be provided with the strip of paper used for sealing of inclination, and be provided with the district of passing a bridge and be connected with the fluid passage.
4. plate-fin thermal coupling rectification device according to claim 3, it is characterized in that being horizontally disposed with in the described fluid passage two or more punching plain fins, the perforated area of the punching plain fin on top is bigger than the perforated area of bottom punching plain fin; Described gas passage is connected in described gap bridge district, and is provided with the refluence sheet in gas passage; The side of described gas passage is provided with and is used for the gas vent of drawing after the gas flow guiding centralized collection.
5. plate-fin thermal coupling rectification device according to claim 1, it is characterized in that described gas distributing device includes a distribution of gas passage that enters and introduce by a flow deflector gas from the side, be respectively arranged with the gas-liquid guide pad and the district of passing a bridge, and be connected with described fluid passage thereafter.
6. plate-fin thermal coupling rectification device according to claim 5 is characterized in that described gas-liquid guide pad is that a cross section is trapezoidal rectangular.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2009201246605U CN201463462U (en) | 2009-07-16 | 2009-07-16 | Plate-fin thermal-coupled rectification device |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2009201246605U CN201463462U (en) | 2009-07-16 | 2009-07-16 | Plate-fin thermal-coupled rectification device |
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| CN201463462U true CN201463462U (en) | 2010-05-12 |
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| CN2009201246605U Expired - Fee Related CN201463462U (en) | 2009-07-16 | 2009-07-16 | Plate-fin thermal-coupled rectification device |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102179059A (en) * | 2011-02-24 | 2011-09-14 | 中国石油大学(华东) | Hydrolysis separation device of methyl acetate and process method thereof |
| CN101614465B (en) * | 2009-07-16 | 2011-11-09 | 杭州杭氧股份有限公司 | Plate-fin thermal coupling rectification device |
-
2009
- 2009-07-16 CN CN2009201246605U patent/CN201463462U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101614465B (en) * | 2009-07-16 | 2011-11-09 | 杭州杭氧股份有限公司 | Plate-fin thermal coupling rectification device |
| CN102179059A (en) * | 2011-02-24 | 2011-09-14 | 中国石油大学(华东) | Hydrolysis separation device of methyl acetate and process method thereof |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100512 Termination date: 20140716 |
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| EXPY | Termination of patent right or utility model |