CN201433151Y - A device for treating slightly polluted surface water - Google Patents
A device for treating slightly polluted surface water Download PDFInfo
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- CN201433151Y CN201433151Y CN2009201092382U CN200920109238U CN201433151Y CN 201433151 Y CN201433151 Y CN 201433151Y CN 2009201092382 U CN2009201092382 U CN 2009201092382U CN 200920109238 U CN200920109238 U CN 200920109238U CN 201433151 Y CN201433151 Y CN 201433151Y
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Abstract
一种处理微污染地表水的装置,属于饮用水深度净化处理技术领域。该装置包括原水池,原水过滤器,生物滤池,混凝池,沉淀池,中间水池,超滤膜组件以及清水池。在原水池和生物滤池之间设有原水泵;生物滤池和混凝池之间通过管道与阀门连接;混凝池、沉淀池和中间水池分别通过管道及阀门连接;中间水池与超膜组件之间设有超滤进水泵;超滤膜组件通过管道与阀门与清水池连接;在生物滤池的底部设有鼓风曝气系统及生物滤池反冲洗系统;在混凝池外部设有加药系统,超滤膜组件外部设有超滤反洗系统。本实用新型将生物降解及混凝作用和超滤的物理截留作用有机结合,对微污染地表水中的氨氮、有机物等有较好的去除效果,是一种新型的饮用水深度净化设备。
A device for treating slightly polluted surface water belongs to the technical field of deep purification treatment of drinking water. The device includes a raw water tank, a raw water filter, a biological filter, a coagulation tank, a sedimentation tank, an intermediate tank, an ultrafiltration membrane module and a clear water tank. There is a raw water pump between the raw water tank and the biological filter; the biological filter and the coagulation tank are connected by pipes and valves; the coagulation tank, the sedimentation tank and the intermediate tank are respectively connected by pipelines and valves; There is an ultrafiltration inlet pump between them; the ultrafiltration membrane module is connected to the clear water tank through pipes and valves; a blast aeration system and a biofilter backwash system are installed at the bottom of the biofilter; Medicine system, ultrafiltration backwash system is installed outside the ultrafiltration membrane module. The utility model organically combines biodegradation and coagulation with the physical interception of ultrafiltration, and has a good removal effect on ammonia nitrogen and organic matter in slightly polluted surface water, and is a new type of deep purification equipment for drinking water.
Description
技术领域 technical field
本实用新型涉及一种水处理设备,特别涉及一种以生物滤池-混凝沉淀-超滤膜组合处理微污染地表水的装置,属于饮用水深度净化处理技术领域。The utility model relates to a water treatment device, in particular to a device for treating slightly polluted surface water by combining a biological filter tank-coagulation sedimentation-ultrafiltration membrane, and belongs to the technical field of deep purification treatment of drinking water.
背景技术 Background technique
面对水源水质的变化,常规饮用水处理工艺已显得力不从心。国内外的实验研究和实际生产结果表明,受污染水源水经常规的混凝、沉淀及过滤工艺只能去除水中20%~30%的有机物,且由于溶解性有机物存在,不利于破坏胶体的稳定性而使常规工艺对原水浊度去除效果明显下降(仅为50%~60%)。用增加混凝剂投加量的方式来改善处理效果,不仅使水处理成本上升,而且可能使水中金属离子浓度增加,也不利于居民的身体健康。地面水源中普遍存在的氨氮超标问题常规处理也不能有效解决。目前国内大多数水厂采用折点氯化的方法来控制出厂水中的氨氮浓度,以获得必要的活性余氯,但由此产生的大量有机卤化物又导致水质毒理学安全性下降。In the face of changes in water quality, conventional drinking water treatment processes have become inadequate. Experimental research and actual production results at home and abroad show that conventional coagulation, sedimentation and filtration processes can only remove 20% to 30% of the organic matter in the polluted source water, and the presence of dissolved organic matter is not conducive to destroying the stability of the colloid The removal effect of the conventional process on raw water turbidity is significantly reduced (only 50% to 60%). To improve the treatment effect by increasing the dosage of coagulant will not only increase the cost of water treatment, but also may increase the concentration of metal ions in the water, which is not conducive to the health of residents. Conventional treatment of excessive ammonia nitrogen, which is ubiquitous in surface water sources, cannot be effectively resolved. At present, most water plants in China use the method of breakpoint chlorination to control the concentration of ammonia nitrogen in the discharged water to obtain the necessary active residual chlorine, but the resulting large amount of organic halides leads to a decline in the toxicological safety of water quality.
同时20世纪末水中发现了新的致病原生动物-蓝氏贾第虫和隐孢子虫(“两虫”),出现了藻类大量繁殖以及藻毒素、嗅味、水的生物稳定性、有害水生生物-剑水蚤和红虫等重大微生物安全问题,现有常规的混凝沉淀过滤消毒技术已无法有效地解决,在这个背景下有待研发出更安全更有效的城市饮用水净化工艺。At the same time, new pathogenic protozoa-Giardia lamblia and Cryptosporidium (“two insects”) were discovered in water at the end of the 20th century, and algal blooms, algae toxins, smell, water biological stability, and harmful aquatic organisms appeared -Major microbial safety issues such as water fleas and red worms cannot be effectively solved by the existing conventional coagulation sedimentation filtration disinfection technology. Under this background, a safer and more effective urban drinking water purification process needs to be developed.
以膜技术为核心作为微污染水源水处理的一项新技术引起了人们的广泛关注,被誉为21世纪最有前途的水处理技术之一。超滤膜能有效的截留水中颗粒物,使出水浊度降低至0.1NTU以下,并能去除大分子有机物,及绝大部分藻类、水蚤、红虫、两虫、细菌甚至病毒等微生物。As a new technology of micro-polluted water treatment with membrane technology as the core, it has attracted widespread attention and is known as one of the most promising water treatment technologies in the 21st century. The ultrafiltration membrane can effectively intercept particulate matter in the water, reduce the turbidity of the effluent to below 0.1NTU, and remove macromolecular organic matter, as well as most microorganisms such as algae, daphnia, red worms, two worms, bacteria and even viruses.
涉及超滤处理微污染水作为饮用水的专利如《超滤膜混凝/吸附/生物反应器一体化水深度处理方法及其装置》200810063897.7,采用了一体化的装置形势,节省了占地面积,同时存在运行通量较低的问题以;专利《超滤-射流补臭氧-紫外二次激发产生自由基净化微污染水源水的技术和工艺》02128903.4,在紫外消毒的同时二次激发水中的溶解氧和臭氧,生成具有强氧化性的自由基,可以杀死各种病原体去除悬浮物等,但不能去除微污染地表水中的氨氮;《针对饮用水处理的组合式超滤膜法处理装置》200420109820.6实用新型为消毒方式与超滤组合的优化,未涉及生物预处理,也不能去除微污染地表水中的氨氮等。Patents involving ultrafiltration treatment of slightly polluted water as drinking water, such as "Ultrafiltration Membrane Coagulation/Adsorption/Bioreactor Integrated Water Advanced Treatment Method and Device" 200810063897.7, adopt an integrated device situation and save floor space At the same time, there is the problem of low operating flux; the patent "ultrafiltration-jet supplementary ozone-ultraviolet secondary excitation to generate free radicals to purify micro-polluted water source water technology and process" 02128903.4, while ultraviolet disinfection and secondary excitation of water Dissolved oxygen and ozone generate strong oxidizing free radicals, which can kill various pathogens and remove suspended solids, etc., but cannot remove ammonia nitrogen in micro-polluted surface water; "Combined Ultrafiltration Membrane Treatment Device for Drinking Water Treatment" The 200420109820.6 utility model is the optimization of the combination of disinfection method and ultrafiltration, which does not involve biological pretreatment, nor can it remove ammonia nitrogen in slightly polluted surface water.
面对水源逐渐恶化而饮用水标准逐渐提高的趋势,如何将超滤膜技术应用于饮用水处理工程中,保证处理出水的高品质、安全性、稳定性以及工程运行的稳定性,是目前超滤膜饮用水处理工艺上亟待解决的问题。In the face of the gradual deterioration of water sources and the gradual improvement of drinking water standards, how to apply ultrafiltration membrane technology to drinking water treatment projects to ensure the high quality, safety, stability and stability of the treated water is currently a super Problems to be solved urgently in membrane drinking water treatment process.
实用新型内容Utility model content
本实用新型的目的是针对微污染地表水水源,研发一种能够显著提高出水水质的饮用水深度处理设备。The purpose of the utility model is to develop an advanced treatment equipment for drinking water that can significantly improve the quality of effluent water for slightly polluted surface water sources.
本实用新型提供的一种处理微污染地表水的装置,其特征在于:所述装置包括原水池1,原水过滤器2,生物滤池3,混凝池4,沉淀池5,中间水池15,超滤膜组件6以及清水池16;在所述的原水池和生物滤池之间设有原水泵7;在生物滤池和混凝池之间通过管道与阀门连接;混凝池、沉淀池和中间水池分别通过管道及阀门连接;中间水池与超膜组件之间设有超滤进水泵11;超滤膜组件通过管道与阀门与清水池16连接;在生物滤池的底部设有鼓风曝气系统及生物滤池反冲洗系统;在所述的混凝池外部设有加药系统8,在混凝池内设有搅拌装置14;所述的超滤膜组件外部设有超滤反洗系统。A device for treating slightly polluted surface water provided by the utility model is characterized in that: the device includes a
上述装置中所述沉淀池采用斜管沉淀池或斜板沉淀池;所述的超滤膜组件采用外置式,膜材料为聚偏氟乙烯或聚氯乙烯,膜孔孔径在0.01~0.1微米;所述生物滤池的添料采用沸石或陶粒。The sedimentation tank in the above device adopts an inclined tube sedimentation tank or an inclined plate sedimentation tank; the ultrafiltration membrane module is an external type, and the membrane material is polyvinylidene fluoride or polyvinyl chloride, and the membrane pore diameter is 0.01 to 0.1 microns; The feed material of the biological filter adopts zeolite or ceramsite.
本实用新型具有以下优点:针对饮用水水源普遍受到有机物及氨氮的污染,把生物处理与常规的混凝沉淀和超滤有机的结合起来,通过生物处理去除氨氮及部分小分子有机物,混凝沉淀去除部分中、大分子有机物,最后通过超滤膜高效截留作用,去除颗粒物和微生物,使其出水达到优质饮用水标准。本实用新型采用外置式超滤膜组件,有效的提高了膜通量,减少了超滤膜的使用面积,组件便于更换,降低了工程造价和运行费用。同时采用外置式膜组件进一步降低了微生物及颗粒物的泄漏。本实用新型超滤膜组件内浓缩液回流到混凝沉淀池,在混凝沉淀池中进行固液分离,进一步提高了水的利用率。The utility model has the following advantages: Aiming at the pollution of drinking water sources by organic matter and ammonia nitrogen, biological treatment is combined with conventional coagulation sedimentation and ultrafiltration organically, ammonia nitrogen and some small molecular organic matter are removed through biological treatment, coagulation sedimentation Part of the medium and macromolecular organic matter is removed, and finally through the high-efficiency interception effect of the ultrafiltration membrane, the particulate matter and microorganisms are removed, so that the effluent can meet the standard of high-quality drinking water. The utility model adopts an external ultrafiltration membrane assembly, which effectively improves the membrane flux, reduces the use area of the ultrafiltration membrane, facilitates the replacement of the assembly, and reduces the engineering cost and operation cost. At the same time, the external membrane module is used to further reduce the leakage of microorganisms and particles. The concentrated liquid in the ultrafiltration membrane module of the utility model is returned to the coagulation sedimentation tank, and the solid-liquid separation is carried out in the coagulation sedimentation tank, thereby further improving the utilization rate of water.
附图说明 Description of drawings
图1为本实用提供的一种处理微污染地表水装置的结构及工艺流程图。Figure 1 is a structure and process flow chart of a device for treating slightly polluted surface water provided by the utility.
图中:1-原水池;2-原水过滤器;3-生物滤池;4-混凝池;5-沉淀池;6-超滤膜组件;7-原水泵;8-加药系统;9-风机;10-生物滤池反洗泵;11-超滤进水泵;12-反洗空气压缩机;13-超滤反洗泵;14-搅拌装置;15-中间水池;16-清水池。In the figure: 1-raw water pool; 2-raw water filter; 3-biological filter; 4-coagulation tank; 5-sedimentation tank; 6-ultrafiltration membrane module; 7-raw water pump; 8-dosing system; 9 -fan; 10-biological filter backwash pump; 11-ultrafiltration inlet pump; 12-backwash air compressor; 13-ultrafiltration backwash pump; 14-stirring device; 15-intermediate pool; 16-clear water pool.
具体实施方式 Detailed ways
下面结合附图对本实用新型作进一步说明。Below in conjunction with accompanying drawing, the utility model is further described.
图1为本实用新型提供的一种处理微污染地表水装置的结构积工艺流程图,该装置包括原水池1,原水过滤器2,生物滤池3,混凝池4,沉淀池5,中间水池15,超滤膜组件6以及清水池16;在所述的原水池和生物滤池之间设有原水泵7;在生物滤池和混凝池之间通过管道与阀门连接;混凝池、沉淀池和中间水池分别通过管道及阀门连接;中间水池与超膜组件之间设有超滤进水泵11;超滤膜组件通过管道与阀门与清水池16连接;在生物滤池的底部设有鼓风曝气系统及生物滤池反冲洗系统;在所述的混凝池外部设有加药系统8,在混凝池内设有搅拌装置14;所述的超滤膜组件外部设有超超滤反洗系统。生物滤池采用沸石或陶粒为添料。所述沉淀池采用斜管沉淀池或斜板沉淀池。Fig. 1 is a kind of structural flow chart of the device for processing slightly polluted surface water provided by the utility model, and the device comprises a
其具体工艺体流程是:待处理原水,包括浊度较低的湖泊、水库水及经初步澄清处理后的江河水等在原水池1中,由原水泵7经过滤器2到达生物滤池3;生物滤池的水力停留时间为10~60min范围内,氨氮及有机物在生物滤池3降解。生物滤池为曝气生物滤池,生物滤池的添料采用沸石或陶粒;由风机9为生物滤池3供气,气水比在0.5∶1~2∶1范围,以满足微生物需氧量。并定期对生物滤池进行反冲洗,通过生物滤池反洗泵10从清水池16中抽水从底部打入生物滤池3中,反洗空气压缩机12提供的压缩空气从生物滤池底部进入,对生物滤池进行反冲洗;反洗出水通过电磁阀控制排出系统,电磁阀与反洗泵10同步;同时在生物滤池底部设有排泥装置,定期对生物滤池排泥。生物滤池3的出水到达混凝池4,由加药系统8向混凝池中添加混凝剂,混凝剂可以为聚合氯化铝、氯化铁、硫酸铝、聚合硫酸铝铁或其他可以用于饮用水生产的混凝剂中的一种或几种。在混凝池4中,由搅拌装置14对混合液搅拌均匀后自流到斜板(或斜管)沉淀池5中,经混凝沉淀后可以去除中等分子及大分子的有机物,在沉淀池中进行固液分离,沉淀池中污泥经管道由阀门控制定期排出系统,上清液自流到中间水池15中;经超滤进水泵11从中间水池15中抽吸加压后到超滤膜组件6中,超滤膜材质可以是聚偏氟乙烯或聚氯乙烯或其他超滤膜,孔径应在0.01微米~0.1微米范围内,超滤膜组件的形式可以是中空纤维式或卷帘式,通过超滤膜组件11控制超滤膜压力在0.01MPa~0.15MPa范围内,膜通量在20L/m2.h~100L/m2.h范围,超滤浓缩液回流至混凝池从而使超滤膜组件内形成错流,经沉淀池进行固液分离或通过超滤膜反洗时出水经混凝沉淀后进行固液分离,为保证膜通量定期对超滤膜组件进行反冲洗,定期由超滤反洗泵13从清水池中抽水打入超滤膜组件6中,同时由反洗空气压缩机12为超滤膜组件提供反洗用气,在超滤膜组件6中形成气水反冲洗。反洗时关闭超滤进水及超滤出水及回流阀门,打开反洗进水、反洗出水及反洗进气阀门。反洗周期根据超滤膜压力与膜通量确定。超滤膜出水到清水池16,经消毒后即可输送到用户。The specific process flow is as follows: raw water to be treated, including lakes and reservoirs with low turbidity, and river water after preliminary clarification treatment, etc. in the
下面举个具体的实施例Give a specific example below
实施例1:待处理原水为湖水。由原水泵从原水池中抽水经碟片过滤器进入生物滤池,生物滤池采2~3毫米的沸石,在生物滤池中的水力停留时间为30min,气水比为2∶1,其出水进入混凝沉淀池,由加药系统向混凝沉淀池中按6mg/L添加聚合氯化铝,混凝5分钟后进入斜板沉淀池,在斜板沉淀池中沉降30min,上清液进入中间水池,由超滤泵抽吸加压打入超滤膜组件中,超滤膜孔径为0.03微米,材质为聚偏氟乙烯外置式的超滤膜组件。通量为20L/m2.h,压力在0.05~0.07Mpa之间变化。过滤30min,反洗1min30s,超滤膜组件出水进入清水池中,在清水池中进行消毒后即可输送到用户。进出水水质如表1所示。Example 1: The raw water to be treated is lake water. The raw water pump draws water from the raw water pool and enters the biofilter through the disc filter. The biofilter adopts 2-3mm zeolite. The hydraulic retention time in the biofilter is 30min, and the gas-water ratio is 2:1. The effluent enters the coagulation sedimentation tank, and the dosing system adds polyaluminum chloride to the coagulation sedimentation tank at a rate of 6 mg/L. After coagulating for 5 minutes, it enters the inclined plate sedimentation tank, settles in the inclined plate sedimentation tank for 30 minutes, and the supernatant After entering the middle pool, it is sucked and pressurized by the ultrafiltration pump into the ultrafiltration membrane module. The ultrafiltration membrane has a pore size of 0.03 microns and is made of polyvinylidene fluoride external ultrafiltration membrane module. The flux is 20L/m 2 .h, and the pressure varies from 0.05 to 0.07Mpa. After filtering for 30 minutes and backwashing for 1 minute and 30 seconds, the effluent from the ultrafiltration membrane module enters the clean water pool, where it can be sterilized and delivered to users. The quality of influent and effluent water is shown in Table 1.
表1Table 1
实施例2:Example 2:
待处理原水为河水。由原水泵从原水池中抽水经碟片过滤器进入生物滤池,生物滤池采2~3毫米的沸石,在生物滤池中的水力停留时间为10min,气水比为0.5∶1,其出水进入混凝沉淀池,由加药系统向混凝沉淀池中按4mg/L添加聚合氯化铝,混凝5分钟后进入斜板沉淀池,在斜板沉淀池中沉降30min,上清液进入中间水池,由超滤泵抽吸加压打入超滤膜组件中,超滤膜孔径为0.1微米,材质为聚偏氟乙烯外置式的超滤膜组件。通量为100L/m2.h,压力在0.12~0.15Mpa之间变化。过滤30min,反洗1min30s,超滤膜组件出水进入清水池中,在清水池中进行消毒后即可输送到用户。进出水水质如表2所示。The raw water to be treated is river water. The raw water pump draws water from the raw water pool and enters the biofilter through the disc filter. The biofilter uses 2-3mm zeolite. The hydraulic retention time in the biofilter is 10 minutes, and the gas-water ratio is 0.5:1. The effluent enters the coagulation sedimentation tank, and the dosing system adds polyaluminum chloride to the coagulation sedimentation tank at a rate of 4 mg/L. After coagulating for 5 minutes, it enters the inclined plate sedimentation tank, settles in the inclined plate sedimentation tank for 30 minutes, and the supernatant After entering the middle pool, it is sucked and pressurized by the ultrafiltration pump into the ultrafiltration membrane module. The ultrafiltration membrane has a pore size of 0.1 micron and is made of polyvinylidene fluoride external ultrafiltration membrane module. The flux is 100L/m 2 .h, and the pressure varies between 0.12 and 0.15Mpa. After filtering for 30 minutes and backwashing for 1 minute and 30 seconds, the effluent from the ultrafiltration membrane module enters the clean water pool, where it can be sterilized and delivered to users. The quality of influent and effluent water is shown in Table 2.
表2Table 2
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624340A (en) * | 2017-03-16 | 2018-10-09 | 邢台旭阳科技有限公司 | Wet method coke pressure quenching system and coke quenching method |
| CN108911417A (en) * | 2018-08-10 | 2018-11-30 | 苏州立升膜分离科技有限公司 | Drinking water purification system |
| CN111875182A (en) * | 2020-08-07 | 2020-11-03 | 南京天河水环境科技有限公司 | Micro-polluted water treatment system |
| CN115536215A (en) * | 2022-10-19 | 2022-12-30 | 江西心连心化学工业有限公司 | High-efficient recovery system of chemical plant area rainwater |
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2009
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624340A (en) * | 2017-03-16 | 2018-10-09 | 邢台旭阳科技有限公司 | Wet method coke pressure quenching system and coke quenching method |
| CN108911417A (en) * | 2018-08-10 | 2018-11-30 | 苏州立升膜分离科技有限公司 | Drinking water purification system |
| CN111875182A (en) * | 2020-08-07 | 2020-11-03 | 南京天河水环境科技有限公司 | Micro-polluted water treatment system |
| CN111875182B (en) * | 2020-08-07 | 2023-07-04 | 南京天河水环境科技有限公司 | Operation method of micro-polluted water body treatment system |
| CN115536215A (en) * | 2022-10-19 | 2022-12-30 | 江西心连心化学工业有限公司 | High-efficient recovery system of chemical plant area rainwater |
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