Rotary-type organic exhaust gas absorption and desorption apparatus
[technical field]
The utility model relates to a kind of emission-control equipment, particularly a kind of organic exhaust gas absorption and desorption treating apparatus.
[background technology]
Organic exhaust gas improvement technology mainly contains condensation method, absorption process, firing method, Production by Catalytic Combustion Process, absorption method and absorption-Production by Catalytic Combustion Process etc. at present, and the new method of abroad studying, and also has biological method purification VOC technology, ionization technology etc.
(1), condensation method
This law is that waste gas is directly imported condenser condenses, and condensate liquid is through separating recyclable valuable organic matter.Adopt condensation method to require organic concentration height in the waste gas, general organic concentration will reach several ten thousand even hundreds of thousands ppm.Inapplicable for this method of low-concentration organic exhaust gas.
(2), absorption process
Absorption process can be divided into chemical absorbing and Physical Absorption, and most of organic exhaust gas should not adopt chemical absorbing.Physical Absorption be in the waste gas one or more components dissolved in selected liquid-absorbant, this law is suitable for the waste gas of middle and high concentration, but select a kind of low volatility absorption liquid of Cheap highly effective also relatively more difficult, the problem of secondary pollution simultaneously can't solve, and clean-up effect is undesirable.
(3), firing method
Firing method is to utilize auxiliary fuel burning liberated heats such as combustion gas or fuel oil that mist is heated to uniform temperature (700~800 ℃), the resident regular hour (0.3~0.5 second), makes flammable harmful substance carry out pyrolytic and becomes innocuous substance.This law is suitable for high-concentration waste gas and administers; Shortcoming is that energy consumption is big, and operating cost is higher more than 10 times than Production by Catalytic Combustion Process, and running technology requires high, wayward and grasp.
(4), Production by Catalytic Combustion Process
This law is that waste gas is heated to carbon dioxide and the water that 200~300 ℃ of process catalytic bed catalytic combustions change into harmless odorless, reaches the purification purpose.The characteristics of this law: initiation temperature is low, energy savings; The purifying rate height, non-secondary pollution; Technology is simple, and is easy to operate, and security is good; Device volume is little, and floor space is few; The maintenance and the depreciation cost of equipment are lower.This method is applicable to the organic exhaust gas improvement of high temperature, middle and high concentration, and existing both at home and abroad widely used experience is respond well.This method is one of effective ways of administering organic exhaust gas.
(5), absorption method
A. direct active carbon adsorption
Organic exhaust gas can reach 95% purifying rate by the absorption of active carbon, and equipment is simple, investment is little.Shortcoming is that system can not regenerate to adsorbing saturated active carbon, and often the active carbon requirement of changing is very big, and spillage of material is big, and operating cost is quite high.
B. adsorb--absorption method
This method is utilized adsorbents adsorb " triphen " waste gas such as fiber-reactive charcoal, near saturated back carrying out desorption and regeneration with superheated vapour blowback active carbon, " triphen " gas that water vapour and desorption come out through condensation, separate recyclable " triphen " liquid.This method purification efficiency is higher, but requires to provide the quantity of steam of necessity." triphen " solvent is not really thorough with separating of water in addition, and " benzene mixed " liquid quality that obtains is not high, and steam condensation effect and equipment operation safety problem also need to be resolved hurrily.This method still awaits improving on technology.
(6), absorption--Production by Catalytic Combustion Process
Use the organic exhaust gas of novel absorbent charcoal (mostly being honeycomb briquet or fiber charcoal) absorption concentrating low-concentration, absorption is introduced the hot air active carbon near saturated back, make " triphen " waste gas desorption come out to enter the catalytic combustion bed and carry out the flameless combustion purified treatment, hot gas recycles or sets up secondary heat exchanger and carries out energy recovery in system.This method is passed through catalytic combustion bed with its thorough purification by active carbon with its organic exhaust gas that is condensed into high concentration with the organic exhaust gas of low concentration again.This method has been drawn the advantage of absorption method and Production by Catalytic Combustion Process, has overcome the shortcoming of using separately separately, has solved a difficult problem of administering low concentration, big air quantity organic exhaust gas existence, is the maturation of present domestic improvement organic exhaust gas, practical method.
(7), ionization method
Shine waste gas with electron beam, VOC chemical bond is wherein ruptured.The equipment that produces electron beam at present is also relatively more expensive.
(8), bioanalysis
The biological method purification organic exhaust gas is the air pollution control technology that development in recent years is got up, and this technology has obtained the application of certain scale in countries such as Germany, Holland.It is with pollutant microorganism to be tamed, and making microorganism can VOC be the carbon source and the energy, with its degraded, is converted into harmless, simple material (as CO2, H20 etc.), thereby reaches the purpose of gas purification.Be in the experimental stage more than at present domestic, do not have the case report of practical engineering application.
Administer technology at above-mentioned various organic exhaust gas, adsorption technology is primary key.Have only earlier organic exhaust gas to be retained down from air, just can carry out subsequent treatment.Traditional adsorption technology mainly is the mode that adopts fixed adsorption bed.Traditional fixed adsorption bed comprises an absorption air inlet, an absorption gas outlet and a desorption air inlet, a desorption gas outlet, and adsorbent layer is fixed on some position of adsorbent bed inside.During use, passing to organic exhaust gas from the absorption air inlet earlier is adsorbed gas, and when air communication was crossed adsorbent layer, adsorbent kept transfixion, and organic exhaust gas is purified, and purified gas is discharged from the absorption gas outlet again.When adsorbent layer has certain adsorbance, pass to desorption gas from the desorption air inlet again, when air communication is crossed adsorbent layer, can carry out desorption to adsorbent, gas behind the desorption is discharged from the desorption gas outlet, meet the requirement that reuses up to adsorbent, so circulation is adsorbed and desorption.Because of traditional fixed adsorption bed needs carry out work under the exhaust environment of low concentration, big air quantity, and adsorbent keeps transfixion during work, and its adsorbance is less, and adsorbent layer is easy to the state of reaching capacity and breakdown; Moreover because of absorption and desorption are to carry out step by step, its operating efficiency is lower.
[utility model content]
The technical problems to be solved in the utility model, be to provide a kind of rotary-type organic exhaust gas absorption and desorption apparatus, adsorbent layer hockets in the process of rotation and adsorbs and two steps of desorption, its operating efficiency is greatly improved, adsorbent layer is in continuous update mode, and its adsorbance has also improved several times.
The utility model is to realize like this, a kind of rotary-type organic exhaust gas absorption and desorption apparatus, comprise that the space is provided with adsorbent layer in housing, the housing, housing is provided with an absorption air inlet, absorption gas outlet and a desorption air inlet and a desorption gas outlet, the space is provided with an adsorbed gas passage and a desorption gas passage in the described housing, described adsorbed gas passage two ends connect absorption air inlet and absorption gas outlet respectively, and the two ends of desorption gas passage then connect desorption air inlet and desorption gas outlet respectively; Described adsorbent layer is located on adsorbed gas passage and the desorption gas passage, and this adsorbent layer comprises a rotating shaft, and around this rotating shaft rotation, and adsorbent layer is divided at least two separate subregions along described rotating shaft direction; Fixedly install a desorption air chamber shrouding between the two ends of described adsorbent layer and the desorption gas passage respectively, this desorption air chamber shrouding mid portion hollows out, and forms a blow vent, and arbitrary subregion of the adsorbent layer in this blow vent and the rotation all intermittently docks.
Wherein, also comprise a runner, its profile is a cylinder, and described rotating shaft is located at the circle centre position of cylindrical structure, described runner is divided into big and separate fanned partition such as 12 grades along described rotating shaft direction, and the sorbing material of described adsorbent layer decomposes and is filled in each fanned partition.
Wherein, the sorbing material of the adsorbent layer of filling in each fanned partition of described runner is with the efficient high-temperature resistant adhesive bond together.
Wherein, described desorption air chamber shrouding be shaped as 1/4 the circle, described blow vent be 30 the degree sector structures.
Wherein, also be provided with a main air blower and a desorption blower fan on the described housing, described main air blower is located on the adsorbed gas passage, and is between described adsorbent layer and the absorption gas outlet; Described desorption blower fan is located on the desorption gas passage, and is between described adsorbent layer and the desorption gas outlet.
Wherein, also be provided with an electric control room on the described housing, this electric control room is electrically connected to described main air blower, desorption blower fan and a drive motors respectively.
Wherein, the sorbing material of described adsorbent layer is a cellular activated carbon, and described desorption air chamber shrouding is made for the high-performance composite high-molecular material.
The utility model adopts the absorption and the desorption apparatus of rotary-type organic exhaust gas, have following beneficial effect: adsorbent layer hockets in the process of rotation and adsorbs and adsorb two steps, can carry out continuous absorption, desorption, adsorbent layer is in the continuous update state, and its operating efficiency is greatly improved.Adsorbent layer is in continuous update mode, compares with the adsorbent layer of equal volume, and the organic exhausted air quantity of the absorption of rotary-type absorption and desorption apparatus is the several times of fixed adsorption bed, has remarkable advantages.And by the sealing of desorption air chamber shrouding, reduced the amount of collaborating between adsorption zone and the desorption air chamber effectively between absorption subregion and the desorption subregion.
[description of drawings]
In conjunction with the embodiments the utility model is further described with reference to the accompanying drawings.
Fig. 1 a is the perspective view of rotary-type organic exhaust gas absorption of the utility model and desorption apparatus.
Fig. 1 b is the positive TV structure cross-sectional schematic of Fig. 1 a.
Fig. 2 is an adsorbent layer cross-sectional structure schematic diagram of the present utility model.
Fig. 3 is the structural representation of desorption air chamber shrouding of the present utility model.
Fig. 4 is adsorbent layer of the present utility model and desorption air chamber shrouding mated condition schematic diagram.
[specific embodiment]
See also Fig. 1 a, Fig. 1 b and shown in Figure 2, machine waste gas absorption of the present utility model and desorption apparatus, comprise that housing 1, housing 1 are provided with an electric control room 2, an absorption air inlet 3, an absorption gas outlet 4, a desorption air inlet 5, a desorption gas outlet 6, a main air blower 7 and a desorption blower fan 8, the space is provided with an adsorbent layer 9 and a runner 90, an adsorbed gas path 10, a desorption gas passage 11, two desorption air chamber shroudings 12 and a drive motors 14 in the described housing.
Wherein, described adsorbed gas path 10 two ends connect absorption air inlet 3 and absorption gas outlet 4 respectively, and the two ends of desorption gas passage 11 then connect desorption air inlet 5 and desorption gas outlet 6 respectively; Described adsorbent layer 9 and runner 90 are located on adsorbed gas path 10 and the desorption gas passage 11; Described main air blower 7 is located on the adsorbed gas path 10, and is between described adsorbent layer 9 and the absorption gas outlet 4; Described desorption blower fan 8 is located on the desorption gas passage 11, and is between described adsorbent layer 9 and the desorption gas outlet 6.
Described runner 90 is the hollow cylinder that comprises a rotating shaft 92, described rotating shaft 92 is located at the circle centre position of cylindrical structure, described runner 90 is divided into big and separate fanned partition 94 such as 12 grades along described rotating shaft 92 directions, and the sorbing material of described adsorbent layer 9 resolves into 12 five equilibriums and is filled in each fanned partition 94.Described runner 90 also can rotate around this rotating shaft 92 under the driving of described drive motors 14 with adsorbent layer 9.The sorbing material of described adsorbent layer 9 is a cellular activated carbon, and the sorbing material of the adsorbent layer 9 in each subregion 94 is with the efficient high-temperature resistant adhesive bond together.The zone, top of the corresponding attached dose of layer 9 of described adsorbed gas path 10, desorption gas passage 11 are then corresponding to the zone, lower part (seeing Fig. 1 a and Fig. 1 b) of attached dose of layer 9.
Described two desorption air chamber shroudings 12 are separately positioned between the two ends and desorption gas passage 11 of adsorbent layer 9, please refer to shown in Figure 3, these desorption air chamber shrouding 12 mid portions hollow out, and form a blow vent 122, and arbitrary subregion 94 of the runner 90 in this blow vent 122 and the rotation all intermittently docks.For easy to process, can be with 1/4 circle that is shaped as of described desorption air chamber shrouding 12, blow vent 122 is the sector structure of 30 degree, like this can be corresponding to the fanned partition 94 that absorbs wheel 90.Described desorption air chamber shrouding 12 is made for the high-performance composite high-molecular material.
Described electric control room 2 is electrically connected to described main air blower 7, desorption blower fan 8 and drive motors 14 respectively, and this electric control room 2 is provided with several buttons, is used to control the running of described main air blower 7, desorption blower fan 8 and drive motors 14.
Please also refer to Fig. 1 to shown in Figure 4, during work, open drive motors 14, adsorbent layer 9 is rotated around rotating shaft 92 in the drive of drive motors 14, and pass to adsorbed gas from absorption air inlet 3, it is organic exhaust gas, with main air blower 7 energising runnings, so adsorbent layer 9 fully contacts with organic exhaust gas in the process of rotation with runner 90, and organic exhaust gas is carried out adsorption cleaning simultaneously, purified gas is discharged from absorption gas outlet 4 by the adsorbed gas path 10 under the effect of main air blower 7.Pass to desorption gas from desorption air inlet 5 again, it is clean air, simultaneously with the 8 energising runnings of desorption blower fan, desorption gas arrives desorption air chamber shrouding 12 from desorption gas passage 11, blow vent 122 from desorption air chamber shrouding 12 enters runner 90 some or two subregions 94 again, and the sorbing material of adsorbent layer 9 in this subregion 94 is carried out desorption handle.Because of the zone of desorption air chamber shrouding 12 except that blow vent 122 is closed state, desorption gas can't pass through the sorbing material of adsorbent layer 9 in other subregion 94, thereby has avoided collaborating.Like this, runner 90 is in the process of rotation, sorbing material in most of subregion 94 (having 10-11 usually) is in adsorbed state, be absorption subregion 942, and fraction subregion 94 (having 1-2 usually) is in detachment status, be desorption subregion 944, promptly realized rotation along with adsorbent layer 9, make each subregion hocket absorption, desorption, thereby form a continuous absorption, desorption system, adsorbent layer 9 is in the continuous update state, and the organic exhausted air quantity of the absorption of equal volume has obvious raising, and operating efficiency is greatly improved.