CN201350707Y - Continuous reinforcing fiber laminate body structure - Google Patents

Continuous reinforcing fiber laminate body structure Download PDF

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Publication number
CN201350707Y
CN201350707Y CNU2009200010027U CN200920001002U CN201350707Y CN 201350707 Y CN201350707 Y CN 201350707Y CN U2009200010027 U CNU2009200010027 U CN U2009200010027U CN 200920001002 U CN200920001002 U CN 200920001002U CN 201350707 Y CN201350707 Y CN 201350707Y
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Prior art keywords
continuity
reinforcing fiber
laminate structure
fiber
thermoplastic resin
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Expired - Fee Related
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CNU2009200010027U
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Chinese (zh)
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马水源
郑玲玲
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RUIHONG COMPOSITE MATERIAL ENTERPRISE Inc
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Priority to CNU2009200010027U priority Critical patent/CN201350707Y/en
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Abstract

The utility model discloses a continuous reinforcing fiber laminate body structure, which comprises a plurality of continuous reinforcing fiber layers and thermoplastic resin layers, wherein the thermoplastic resin layers are impregnated on the continuous reinforcing fiber layers, each of the impregnated continuous reinforcing fiber layers is provided with continuous fiber fabric and first thermoplastic resin, a combined continuous reinforcing fiber plate can be plastic-modeled through hot pressing, and is modeled into a structural body with a stacking layer body in a die, and the first thermoplastic resin provided by the continuous reinforcing fiber structure body can be directly jetted, formed and packed by second thermoplastic resin, which does not need any interface agent, and completes a continuous reinforcing fiber casing with the complex inner structure requirements.

Description

Continuity reinforcing fiber laminate structure
Technical field
The utility model relates to a kind of continuity reinforcing fiber laminate structure, especially has the continuity reinforcing fiber of preimpregnated thermoplastic resin.
Background technology
Developing under the rapid demand with the action message sci-tech product on the global topic of " carbon reduction ", industry begins invariably to pursue and has more impact resistance, anti electromagnetic wave and can be recovered the material that processing utilized and reduced the petrochemical industry resin demand again, in the hope of the environmental requirement that meets the whole world and the demand of related industry.
At present, the employed material of continuity reinforcing fiber lamination industry has carbon fiber, glass reinforced fiber, polyester fiber and aromatic polyamide fibrid etc., and the continuity reinforcing fiber generally has the continuity reinforcing fiber, pre-preg through thermosetting resin (as epoxy resin), make thermosetting resin covered fiber surface, by manually with the impregnation thermosetting resin not the continuity reinforcing fiber lamination of slaking elaborate in mould, again by suitable mechanical device heating, vacuumize and cure into solid shape or fiber pad hot pressing plastotype in mould, heating makes the thermosetting resin slaking, the thermosetting plastics of slaking can tightly combine with fiber surface, can utilize thermosetting plastics and interfibrous interface to absorb external impulsive force energy, and then form the structure of high impact resistance.
The characteristic of thermosetting plastics is, in case with the thermosetting resin heating of tool flowable and after cureing into solid-state thermosetting plastics, this thermosetting plastics just can not be subjected to follow-up heating and be out of shape, that is still keep original solid shape.Thermosetting plastics also is a kind of resin that can't repeat to reclaim use.
In the prior art, fiber accumulations layer plastotype in mould heats when pressurizeing, pre-soaked resin can cause crystal hardened because of pressure, temperature or time difference, between fiber, cause part resin quantity not sufficient to cover all fiber surfaces or to fill up interfibrous space, make the plastotype finished surface cave in, not only cause the outward appearance disappearance, also bring the worry of structural strength influence.For improving above-mentioned disappearance, the depression position of plastotype finished product needs through mending native application, play polishing and just can reach appearance requirement, but takes a lot of work when spacious, beat to polish the dust that causes and also pollute easily, but a large amount of costs of labor of needs be difficult to a large amount of productions.
In addition, prior art mostly adopts the epoxy resin of thermosetting resin as pre-soaked resin, need expense extremely long man-hour to finish crystallization, to be cooled to the maturing process of sclerosis plastotype, and in case by after the plastotype curing, combining with any material all needs to be coated with interface solvent resin to improve adhesion, increases extra manufacturing cost and environmental protection doubt when therefore causing subsequent applications.
Therefore, the reinforcing fiber laminate structure that needs a kind of tool thermoplasticity pre-soaked resin, make at need during in conjunction with the assembly of unlike material, can reach with mode of heating, and need not be coated with interface solvent resin to improve adhesion, the thermoplasticity pre-soaked resin has viscosity in forming process simultaneously, and can not produce partly solidified when heating, pressurization, and then can avoid product appearance to cave in, to solve all shortcomings of above-mentioned prior art.
The utility model content
Main purpose of the present utility model is in that a kind of continuity reinforcing fiber laminate structure is provided, to solve deficiency of the prior art.
A kind of continuity reinforcing fiber laminate structure that the utility model provides, comprise a plurality of continuity reinforcing fiber layers, each continuity reinforcing fiber layer of described continuity reinforcing fiber layer comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this continuity fiber cloth have a plurality of can be around the continuity fiber of song, this first thermoplastic resin thoroughly envelopes all continuity fibers, and described continuity reinforcing fiber layer is storehouse and be combined into this continuity reinforcing fiber laminate structure successively.
This first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
This filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
This continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
A kind of continuity reinforcing fiber laminate structure that the utility model further provides, comprise a plurality of continuity reinforcing fiber layers and a plurality of thermoplastic resin, each continuity reinforcing fiber layer of described continuity reinforcing fiber layer comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this continuity fiber cloth have a plurality of can be around the continuity fiber of song, this first thermoplastic resin thoroughly envelopes all continuity fibers, described continuity reinforcing fiber layer is storehouse and be combined into the pre-laminate structure of a continuity reinforcing fiber successively, each thermoplastic resin of described thermoplastic resin comprises that one coats object and one second thermoplastic resin, this second thermoplastic resin envelopes this coating object, through hot pressing with in conjunction with pre-laminate structure of this continuity reinforcing fiber and described thermoplastic resin.
This continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
This first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
This filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
This coating object comprise a hardware, a pottery magnetic member, a solar heat-collection plate and a heat resistant plastice member at least one of them.
This second thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material resin at least one of them.
This filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
The utility model provides a kind of continuity reinforcing fiber laminate structure again, and it comprises:
A plurality of continuity reinforcing fiber layers, each continuity reinforcing fiber layer of described continuity reinforcing fiber layer comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this continuity fiber cloth have a plurality of can be around the continuity fiber of song, this first thermoplastic resin thoroughly envelopes all fibers, and described continuity reinforcing fiber layer is storehouse and be combined into the pre-laminate structure of a continuity reinforcing fiber successively;
One plane materiel object, tool one is laminar; And
One thermoplastic cement resin is coated with between the plane materiel object of first thermoplastic resin between the pre-laminate structure of this continuity reinforcing fiber and this impregnation, presses on the pre-laminate structure of this continuity reinforcing fiber with the heating pressurization.
This continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
This first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
This filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
This plane materiel object comprise ripple in a printing film sheet material, the mould seal transfer film, a cloth, a bamboo thin slice, a wooden thin slice and a leather at least one of them.
The utility model provides a kind of continuity reinforcing fiber laminate structure again, and it comprises:
A plurality of continuity reinforcing fiber layers, each continuity reinforcing fiber layer that the continuity reinforcing fiber layer of first thermoplastic resin is crossed in described impregnation comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this fiber cloth have a plurality of can be around the continuity fiber of song, the thorough impregnation of this first thermoplastic resin envelopes all continuity fibers, and described continuity reinforcing fiber layer is storehouse and be combined into the pre-laminate structure of a continuity reinforcing fiber successively; And
One plane materiel object, tool one is laminar, directly attaches to this continuity reinforcing fiber preimpregnation laminate structure through hot pressing.
This continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
This first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
This filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
This plane materiel object comprise ripple in a printing film sheet material, the mould seal transfer film, a cloth, a bamboo thin slice, a wooden thin slice and a leather at least one of them.
The beneficial effects of the utility model are: the continuity reinforcing fiber laminate structure that is provided has a plurality of continuity reinforcing fiber layers and plane materiel object, plane materiel object preimpregnation first thermoplastic resin mat again adds hot pressing and attaches on the continuity reinforcing fiber layer, and need not use extra gummed solvent resin, save cost and improve the quality of product, avoid the doubt of structural strength.
Description of drawings
Fig. 1 is the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model first embodiment.
Fig. 2 is the schematic perspective view of Fig. 1.
Fig. 3 is the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model second embodiment.
Fig. 4 is the schematic perspective view of Fig. 3.
Fig. 5 is the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model the 3rd embodiment.
Fig. 6 is the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model the 4th embodiment.
The specific embodiment
Below cooperation is graphic does more detailed description to embodiment of the present utility model, and those of ordinary skill in the art can be implemented after studying this specification carefully according to this.
With reference to figure 1, the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model first embodiment.As shown in Figure 1, continuity reinforcing fiber laminate structure 10 comprises a plurality of continuity reinforcing fiber layers 20, each continuity reinforcing fiber layer 20 comprises can be around the continuity fiber cloth of song and first thermoplastic resin 40 of impregnation, wherein the continuity fiber cloth have a plurality of can be around the continuity reinforcing fiber 30 of song, the continuity fiber cloth is immersed in first thermoplastic resin 40 in advance, makes the thermoplastic resin 40 of winning envelope all continuity reinforcing fibers 30.Several continuity reinforcing fiber layers 20 can be stacked into continuity reinforcing fiber laminate structure, and utilize and heat pressuring method, make first thermoplastic resin 40 of each continuity reinforcing fiber layer 20 produce gel and form combination, and then continuity reinforcing fiber laminate structure is combined into one.In addition, can further utilize shaping dies, add in heating and depress, this laminate structure plastotype is become required shape, as the three-dimensional plastotype of the bending 3D among Fig. 1.
Be noted that only to demonstrate two continuity reinforcing fiber layers in graphic, and scope of the present utility model comprises a plurality of continuity reinforcing fiber layers with convenient explanation.
For further showing the characteristics of the utility model first embodiment, please refer to Fig. 2, the schematic perspective view of Fig. 1, wherein continuity reinforcing fiber laminate structure 10 has complicated shape after shaping dies is with the heating compression molding.
First thermoplastic resin of the present utility model comprises acrylonitrile-butadiene-styrene copolymer (Acrylonitrile-Butadiene-Styrene, ABS), polystyrene (Polystyrene, PS), Merlon (Polycarbonate, PC), polyethylene (Polyethylene, PE), acrylonitritrile-styrene resin (Acrylonitrile-Styrene, AS), polymethyl methacrylate (Polymethylmethacrylate, PMMA), PETG (Polyethylene Terephthalate, PET), polyamide (Polyamide, PA), poly terephthalic acid second butanediol ester (Polybothlene Terephthalate, PBT), polyphenyl ether ether ketone (Polyether Ether Ketone, PEEK) and the polyamide acyl (Polyetherimide, PEI) at least one of them.Continuity fiber of the present utility model comprises one of them of continuity carbon fiber, glass fibre, asbestos fibre, engineering plastics fiber and natural fiber.
With reference to figure 3, the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model second embodiment.As shown in Figure 3, have thermoplastic resin 22 on the continuity reinforcing fiber layer 20 of the superiors, this thermoplastic resin 22 comprises the coating object 50 and second thermoplastic resin 60, and wherein second thermoplastic resin 60 envelopes this coating object 50.In addition, the continuity reinforcing fiber laminate structure of the utility model second embodiment can have a plurality of thermoplastic resins 22, therefore Fig. 3 demonstrates the just convenient the utility model characteristics that explain orally of thermoplastic resin 22 of individual layer, is not in order to restriction the utility model scope.But mat heating pressuring method, second thermoplastic resin 60 enveloped this coating object 50 and form the continuity reinforcing fiber laminate of flat coating thermoplastic resin, the mat shaping dies is with the heating pressuring method again, the continuity reinforcing fiber laminate of flat coating thermoplastic resin is attached to continuity reinforcing fiber layer 20 be combined into one, form the continuity reinforcing fiber laminate structure 12 of second embodiment.Also can be directly penetrate processing or post bake when moulding, second thermoplastic resin 60 is attached to continuity reinforcing fiber layer 20 with coating object 50, form the continuity reinforcing fiber laminate structure 12 of second embodiment at the secondary plastics.
For further showing the characteristics of the utility model second embodiment, with reference to figure 4, the schematic perspective view of Fig. 3, wherein continuity reinforcing fiber laminate structure 12 comprises thermoplastic resin 22 and the pre-laminate structure of a continuity reinforcing fiber that impregnation coats, and the continuity reinforcing fiber laminate structure 10 of pre-laminate structure first embodiment of this continuity reinforcing fiber.As shown in Figure 4, thermoplastic resin 22 is penetrated the internal edge of the continuity reinforcing fiber laminate structure 10 that is attached at first embodiment in the mould.Be noted that, present embodiment is an exemplary explanation example of the present utility model, be not in order to limiting the utility model scope, promptly penetrated the structure that thermoplastic resin 22 is positioned at continuity reinforcing fiber laminate structure 10 outsides of first embodiment in the mould and still drop on the utility model scope.
Second thermoplastic resin of the present utility model comprises that ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and this arbitrary aforementioned resin add one and fill the synthetic resin that material forms, this filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.Coating object 50 of the present utility model comprises hardware, pottery magnetic member, solar heat-collection plate and heat resistant plastice member.
Be noted that only to demonstrate single thermoplastic resin in graphic, and scope of the present utility model contains the continuity reinforcing fiber laminate structure that comprises a plurality of thermoplastic resins of interlayer with convenient explanation.
With reference to figure 5, the schematic diagram of the continuity reinforcing fiber structure of the utility model the 3rd embodiment.As shown in Figure 5, utilize thermoplastic cement resin 80 that plane materiel object 70 is attached on the pre-laminate structure of a continuity reinforcing fiber, and the continuity reinforcing fiber laminate structure 10 of pre-laminate structure first embodiment of this continuity reinforcing fiber, to form the continuity reinforcing fiber laminate structure 16 of tool plane materiel object.Plane materiel object 70 comprises the different materials of sheet such as transfer film, cloth, bamboo thin slice, wooden thin slice and leather that ripple and print in the exquisite thin-film sheet that print, the mould, with reach protection, beautify, the function of advertisement, propaganda or caution.Therefore, for the produce market demand of portion of the mechanism product of the outward appearance of multiple material of needs or tinctorial pattern or shell, do not need back processing procedures such as any spraying, printing, directly mat structure of the present utility model and finishing.
The 3rd thermoplastic resin of the present utility model comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK and PEI at least one of them.
With reference to figure 6, the schematic diagram of the continuity reinforcing fiber laminate structure of the utility model the 4th embodiment.As shown in Figure 6, the continuity reinforcing fiber laminate structure 18 of the 4th embodiment comprises on plane materiel object 70 and the pre-laminate structure of a continuity reinforcing fiber, and the continuity reinforcing fiber laminate structure 10 of pre-laminate structure first embodiment of this continuity reinforcing fiber, wherein but the thermoplastic resin 40 in the plane materiel object 70 mat pressurized, heated continuity reinforcing fiber layers 20 can directly combine with containing the plane materiel object 70 that is soaked with first thermoplastic resin, does not need extra thermoplastic cement resin.
The above only is in order to explain preferred embodiment of the present utility model; be not that attempt is done any pro forma restriction to the utility model according to this; therefore; all have in that identical utility model spirit is following do relevant any modification of the present utility model or change, all must be included in the category of the utility model intention protection.

Claims (21)

1. continuity reinforcing fiber laminate structure, comprise a plurality of continuity reinforcing fiber layers, it is characterized in that, each continuity reinforcing fiber layer of described continuity reinforcing fiber layer comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this continuity fiber cloth have a plurality of can be around the continuity fiber of song, this first thermoplastic resin thoroughly envelopes all continuity fibers, and described continuity reinforcing fiber layer is storehouse and be combined into this continuity reinforcing fiber laminate structure successively.
2. continuity reinforcing fiber laminate structure as claimed in claim 1, it is characterized in that, this first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
3. continuity reinforcing fiber laminate structure as claimed in claim 2 is characterized in that, this filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
4. continuity reinforcing fiber laminate structure as claimed in claim 1 is characterized in that, this continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
5. continuity reinforcing fiber laminate structure, comprise a plurality of continuity reinforcing fiber layers and a plurality of thermoplastic resin, it is characterized in that, each continuity reinforcing fiber layer of described continuity reinforcing fiber layer comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this continuity fiber cloth have a plurality of can be around the continuity fiber of song, this first thermoplastic resin thoroughly envelopes all continuity fibers, described continuity reinforcing fiber layer is storehouse and be combined into the pre-laminate structure of a continuity reinforcing fiber successively, each thermoplastic resin of described thermoplastic resin comprises that one coats object and one second thermoplastic resin, this second thermoplastic resin envelopes this coating object, through hot pressing with in conjunction with pre-laminate structure of this continuity reinforcing fiber and described thermoplastic resin.
6. continuity reinforcing fiber laminate structure as claimed in claim 5 is characterized in that, this continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
7. continuity reinforcing fiber laminate structure as claimed in claim 5, it is characterized in that, this first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
8. continuity reinforcing fiber laminate structure as claimed in claim 7 is characterized in that, this filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
9. continuity reinforcing fiber laminate structure as claimed in claim 5 is characterized in that, this coating object comprise a hardware, a pottery magnetic member, a solar heat-collection plate and a heat resistant plastice member at least one of them.
10. continuity reinforcing fiber laminate structure as claimed in claim 5, it is characterized in that, this second thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material resin at least one of them.
11. continuity reinforcing fiber laminate structure as claimed in claim 10 is characterized in that, this filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
12. a continuity reinforcing fiber laminate structure is characterized in that this structure comprises:
A plurality of continuity reinforcing fiber layers, each continuity reinforcing fiber layer of described continuity reinforcing fiber layer comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this continuity fiber cloth have a plurality of can be around the continuity fiber of song, this first thermoplastic resin thoroughly envelopes all fibers, and described continuity reinforcing fiber layer is storehouse and be combined into the pre-laminate structure of a continuity reinforcing fiber successively;
One plane materiel object, tool one is laminar; And
One thermoplastic cement resin is coated with between the plane materiel object of first thermoplastic resin between the pre-laminate structure of this continuity reinforcing fiber and this impregnation, presses on the pre-laminate structure of this continuity reinforcing fiber with the heating pressurization.
13. continuity reinforcing fiber laminate structure as claimed in claim 12 is characterized in that, this continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
14. continuity reinforcing fiber laminate structure as claimed in claim 12, it is characterized in that, this first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
15. continuity reinforcing fiber laminate structure as claimed in claim 14 is characterized in that, this filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
16. continuity reinforcing fiber laminate structure as claimed in claim 12 is characterized in that, this plane materiel object comprise ripple in a printing film sheet material, the mould seal transfer film, a cloth, a bamboo thin slice, a wooden thin slice and a leather at least one of them.
17. a continuity reinforcing fiber laminate structure is characterized in that this structure comprises:
A plurality of continuity reinforcing fiber layers, each continuity reinforcing fiber layer that the continuity reinforcing fiber layer of first thermoplastic resin is crossed in described impregnation comprises that one can be around the continuity fiber cloth of song and first thermoplastic resin of an impregnation, this fiber cloth have a plurality of can be around the continuity fiber of song, the thorough impregnation of this first thermoplastic resin envelopes all continuity fibers, and described continuity reinforcing fiber layer is storehouse and be combined into the pre-laminate structure of a continuity reinforcing fiber successively; And
One plane materiel object, tool one is laminar, directly attaches to this continuity reinforcing fiber preimpregnation laminate structure through hot pressing.
18. continuity reinforcing fiber laminate structure as claimed in claim 17 is characterized in that, this continuity fiber comprise continuity carbon fiber, glass fibre, asbestos fibre and engineering plastics fiber at least one of them.
19. continuity reinforcing fiber laminate structure as claimed in claim 17, it is characterized in that, this first thermoplastic resin comprise ABS, PS, PC, PE, AS, PMMA, PET, PA, PBT, PEEK, PEI and add one fill material aforementioned resin at least one of them.
20. continuity reinforcing fiber laminate structure as claimed in claim 19 is characterized in that, this filling material comprise talcum powder, carbon fiber and glass fibre at least one of them.
21. continuity reinforcing fiber laminate structure as claimed in claim 17 is characterized in that, this plane materiel object comprise ripple in a printing film sheet material, the mould seal transfer film, a cloth, a bamboo thin slice, a wooden thin slice and a leather at least one of them.
CNU2009200010027U 2009-01-14 2009-01-14 Continuous reinforcing fiber laminate body structure Expired - Fee Related CN201350707Y (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102233694A (en) * 2010-04-24 2011-11-09 陈正盛 Improved structure of thermoset fiber product, and preparation method of improved structure
CN102922833A (en) * 2011-08-12 2013-02-13 明安国际企业股份有限公司 Fiber reinforced shell manufacturing method
CN102922832A (en) * 2011-08-12 2013-02-13 明安国际企业股份有限公司 Fiber reinforced shell manufacturing method
CN104708978A (en) * 2013-12-17 2015-06-17 科森复合材料股份有限公司 Sheet decoration structure and production method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102233694A (en) * 2010-04-24 2011-11-09 陈正盛 Improved structure of thermoset fiber product, and preparation method of improved structure
CN102922833A (en) * 2011-08-12 2013-02-13 明安国际企业股份有限公司 Fiber reinforced shell manufacturing method
CN102922832A (en) * 2011-08-12 2013-02-13 明安国际企业股份有限公司 Fiber reinforced shell manufacturing method
CN102922833B (en) * 2011-08-12 2015-06-17 明安国际企业股份有限公司 Fiber reinforced shell manufacturing method
CN104708978A (en) * 2013-12-17 2015-06-17 科森复合材料股份有限公司 Sheet decoration structure and production method thereof

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Owner name: MA SHUIYUAN

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Effective date: 20110818

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Effective date of registration: 20110818

Address after: Taichung District, Taichung City, Taiwan, China, Dongguan Road, No. 22-1

Patentee after: Ma Shuiyuan

Address before: Taipei City, Taiwan, China

Patentee before: Ruihong Composite Material Enterprise Inc.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20091125

Termination date: 20160114