CN201304323Y - Circumfluence cycling fluidized bed flue gas desulfurization reactor in homogeneous flow field - Google Patents
Circumfluence cycling fluidized bed flue gas desulfurization reactor in homogeneous flow field Download PDFInfo
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- CN201304323Y CN201304323Y CNU2008201233691U CN200820123369U CN201304323Y CN 201304323 Y CN201304323 Y CN 201304323Y CN U2008201233691 U CNU2008201233691 U CN U2008201233691U CN 200820123369 U CN200820123369 U CN 200820123369U CN 201304323 Y CN201304323 Y CN 201304323Y
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- flue gas
- reactor
- flue
- gas desulfurization
- desulfurization reactor
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Abstract
The utility model relates to the circumfluence cycling flue gas desulfurization technology in homogeneous flow field. The core device of the technology - reactor adopts the structure: a direct-flow streamline bottom part gas inlet, a flow guiding plate, a center built-in-type absorbent distributor, a flue gas accelerator, a humidifying active spraying nozzle, a whirl-blast plate gas-solid separator and a center outlet flue which is arranged on the upper part of a reactor cylinder. Two arc flue gas uniformly-distributed flow guiding plates are arranged inside the reactor inlet flue; the center built-in-type absorbent separator, the Laval-nozzle-like flue gas accelerator, the two-level double-fluid humidifying active spraying nozzle and the whirl-blast plate gas-solid separator are arranged inside the reactor. The circumfluence cycling fluidized bed flue gas desulfurization reactor in homogeneous flow field has reasonable structure; the flue gas of the reactor can achieve stable homogeneous flow field and temperature field; the absorbent can obtain high cycling rate and high utilization rate; at the same time, the dust content of the outlet flue can be reduced, thereby reducing the load of a rear part bag-type dust remover, and resolving the technical difficulties of the semi-dry cycling fluidized bed flue gas desulfurization technology.
Description
Technical field
The present invention relates to flue gas desulfurization technique and equipment, be specifically related to a kind of semidry-method recirculating fluidized bed flue gas desulfurization technique that is applicable to medium and small unit coal-burning power plant and waste incineration power plant.
Background technology
Semidry-method recirculating fluidized bed flue gas desulfurization technique, reduced investment (only for 50% below of wet method), occupation of land less, non-wastewater discharge, can not cause that secondary pollution, desulfuration efficiency height, operating cost are low, burn into can be with general carbon steel manufacturing substantially in system, tally with the national condition, thereby favored.But still there are three big technical barriers in its nucleus equipment---reactor: (1). the flow field is inhomogeneous, even serious bias current or local eddy currents; (2). the sticking wall of desulfurization ash, the bed that lumps, collapses, stifled tower have generation more; (3). the too high (800～1000g/Nm of outlet exhaust gas dust concentration
3), making the sack cleaner overload at rear portion, resistance drop is big.These Three Difficult Issues have become to restrict the bottleneck of this technology.
Summary of the invention
Purpose of the present invention is to overcome above-mentioned deficiency of the prior art, provides a kind of rational in infrastructure, the interior very uniformly reflux cycle fluid bed flue gas desulfurization reactor of flue gas flow field, temperature field, pressure field.
The objective of the invention is to be achieved through the following technical solutions.
The present invention's " return current circulating fluidized bed in flow equalizing field flue gas desulfurization reactor ", structure from the bottom to top is followed successively by: the streamlined bottom air inlet of direct current, as the central outlet flue at the built-in absorbent distributor in deflector, the center of admission gear's part, flue gas accelerator, humidification activation nozzle, eddy flow plate gas-solid separator and reactor shell top, calcium hydroxide and the circulating ash import that is connected with the built-in absorbent distributor in center in addition.
The streamlined bottom inflow flue of described direct current is square variable section structure.
Described deflector as an air inlet flue structure part is the uniform deflector of biplate circular arc type.
The built-in absorbent distributor in described center is 6 outlets, aims at 6 arrival ends of flue gas accelerator respectively.
Described flue gas accelerator is imitative " Laval nozzle " formula flue gas accelerator.
Described humidification activation nozzle adopts the two-stage two-fluid spray nozzle, is positioned at the centre of reactor.
Described eddy flow plate gas-solid separator is located at reactor shell top.
The present invention adopts the data of actual engineering, through rigorous technology Calculation, and uses Fluent software to carry out flow field analysis and is verified that effect is very good.
The present invention disposes rationally, and the flue gas of reactor is fully mixed with absorbent; And acquisition stabilized uniform flow field and temperature field; Absorbent obtains high circulating ratio and high usage; Two-stage humidification can effectively improve the reactivity of absorbent, also can effectively avoid wet wall, fouling, bed collapses; Guarantee desulfuration efficiency; Obviously reduce simultaneously the dustiness of exhaust pass, alleviated rear portion sack cleaner load greatly, solved the technical barrier in the semidry-method recirculating fluidized bed flue gas desulfurization technique.
Description of drawings
Fig. 1 is the nucleus equipment of the present invention's " flue gas desulfurization technique of return current circulating fluidized bed in flow equalizing field "---the structural representation of reactor.
Among the figure: 1. air inlet, 2. deflector, 3. absorbent distributor, 4. flue gas accelerator, 5. humidification activation nozzle, 6. gas-solid separator, 7. reactor shell, 8. central outlet flue, 9. calcium hydroxide and circulating ash access road.
The specific embodiment
Referring to Fig. 1, the nucleus equipment of " flue gas desulfurization technique of return current circulating fluidized bed in flow equalizing field "---reactor, its structure from the bottom to top is followed successively by: the central outlet flue 8 on the streamlined bottom air inlet 1 of direct current, deflector 2, the built-in absorbent distributor 3 in center, flue gas accelerator 4, humidification activation nozzle 5, eddy flow plate gas-solid separator 6, reactor shell 7 tops and calcium hydroxide and the circulating ash access road 9 that is connected with the built-in absorbent distributor 3 in center.Humidification activation nozzle 5 adopts the two-stage two-fluid spray nozzle, is positioned at the centre of reactor.Deflector 2 as admission gear's part is the uniform deflector of biplate circular arc type.Flue gas accelerator 4 is imitative " Laval nozzle " formula flue gas accelerator.
The streamlined bottom inflow flue of direct current, the built-in absorbent distributor of uniform deflector of biplate garden arc formula and center are original creation structure of the present invention.
The outlet flue gas of coal-burning power plant or garbage incinerating power plant boiler enters reactor from the streamlined air inlet flue 1 of this reactor bottom direct current, is divided into trisection through biplate circular arc type airflow uniform distribution deflector 2, continues to move upward; Fresh calcium hydroxide and circulating ash enter the built-in absorbent distributor 3 in center by access road 9, and are divided into six five equilibriums, in the injecting reactor, mix with the flue gas that rises, and enter imitative " Laval nozzle " formula flue gas accelerator 4; Flue gas and absorbent are by flue gas accelerator 4, and gas, solid two-phase fully contact, mix, moment flow velocity can improve more than three times, and form cylindric flue gas high velocity; Humidification water is by two-fluid spray nozzle 5, and (40～60 μ m) sprays in the reactor with superfine water smoke, and moisture evaporates rapidly, makes the absorbent humidification, makes flue gas cool-down, improves reactivity, realizes desulphurization reaction.
The flue gas that has a large amount of absorbents and product, through being located at eddy flow plate gas, the solid separator 6 on reactor top, because the centrifugation of eddy flow plate, solid phase (absorbent and product) is thrown toward wall, lean on gravity along the downward landing of wall again, reflux in forming.Be separated the flue gas of a part of absorbent and product,, enter the sack cleaner at this flue gas desulfurization technique rear portion, carry out gas, the solid separation through being located at the exhanst gas outlet 8 in reactor head centre.Through the flue gas that deduster has purified, send chimney to by air-introduced machine, enter atmosphere.The solid phase that is separated (being circulating ash), most of circulation is gone back, and advances reactor and continues to participate in desulphurization reaction.Small part is delivered to grey storehouse, otherwise processed.Bigger particle or agglomerate in the reactor flue gas, air-flow can't drive, and will fall, and enters down ash bucket, regularly discharges.
The invention has the advantages that:
1) the streamlined bottom inflow structure of direct current (comprising ash bucket and diffuser) meets the natural streamline of flow of flue gas, can realize the steady flow of flue gas, and help regulating again; Fluid resistance is little.This structure is better than the bilateral air intake structure of Wulff, is better than single flow (two the 135 ° of elbows) air intake structure of Lurgi, more is better than domestic traditional one-sided quadrature air intake structure.
2) biplate circular arc type airflow uniform distribution deflector can realize effectively that flue gas flow field is uniform, and resistance drop is very little; Deflector bottom (straight plate section) can change according to exhaust gas volumn adjusts angle, and can make the dust landing that accumulates on the deflector, falls in the ash bucket and discharges.
3) the built-in absorbent distributor in center is positioned at the input of fresh calcium hydroxide and circulating ash (general designation absorbent) in this distributor of reactor center, and reactor is gone in uniform distribution again again.
Six ash holes of distributor, 6 flue gas accelerator arrival ends of directed aligning can be realized absorbent equivalent, fixed direction allocation; Discharging opening is located at the flue gas high velocity, can be mixed into the flue gas accelerator with the rising flue gas accurately and effectively; Fresh calcium hydroxide, circulating ash shift to an earlier date and SO
2Contact is heated by flue gas, makes its rapid draing; Calcium hydroxide and Cl
-In reaction more than 100 ℃, generate the alkali formula calcium chloride (CaCl that moisture absorption is relatively poor, particle is thin, be difficult for condensing
2Ca (OH)
2H
2O), can significantly reduce the phenomenon of sticking wall, fouling; The dust hardness of the pellet hardness of fresh calcium hydroxide and circulating ash in the boiler smoke will weaken the impact wear to flue gas accelerator inlet greatly after the mixing; Rationally utilize the space.
4) six " Laval nozzle " formula flue gas accelerators: can effectively improve flue gas flow rate, can reduce the height of reactor, can effectively improve gas, the solid uniformity of mixing.Very short because of the straight section of aditus laryngis, air inlet section and diffuser angle are less, and its pressure falls more much lower than the Venturi tube of foreign technologies such as Lurgi, Wulff, AE, but and efficient hardening smoke inlet section gas-solid contact, mass transfer, heat transfer, improve desulphurization reaction efficient.Flue gas accelerator entrance can adopt abrasion-resistant stee or wear-resistant paint.
5) two-fluid spray nozzle two-stage humidification activation: water smoke particle diameter very thin (40～60 μ m), water smoke is in the zone of flue gas tubulence energy maximum, grain density maximum, and moisture can evaporate fully; Compare with the traditional single stage spraying, obviously reduced average reaction temperature and outlet cigarette temperature in the reactor; Make the reactor temperature field distribution more even; Can effectively avoid because of the excessive wet wall effect that causes of part water spray; Atomized water can effectively reduce flue-gas temperature (will be controlled at above 10～20 ℃ of flue gas dew point temperature), and humidification is effective, makes SO
2With Ca (OH)
2But be converted into the reaction of ionic type that moment finishes, effectively improve desulfuration efficiency.Second level nozzle is mainly used in the temperature of regulating the outlet flue gas.
Adopt this nozzle can effectively improve the utilization rate of Ca, reduce operating cost; System's operation is more reliable and more stable; Output investment ratio high pressure reflow formula nozzle is low more than 30%; The water of first order nozzle, compressed air hose are arranged in flue gas accelerator upper face bottom, can avoid taking place to stretch into because of the side direction cantilever, and the water of nozzle, gas entrance pipe are by the worn out situation of exhaust gas dust particle.
6) eddy flow plate gas, solid separator are located at reactor shell top.
The desulfurization ash is swerved with flow of flue gas by this device, makes particle obtain centrifugal inertial force, is thrown toward wall, leans on the gravity effect along the downward landing of wall again, refluxes in forming; The desulfurization ash is collision mutually in this motion, with the wall friction, quickens the Surface Renewal of absorbent; Effectively improve the circulating ratio (can reach 100～150) of absorbent, the time of staying of extension of absorbent in reactor, the utilization rate of raising absorbent; Can make reactor outlet exhaust gas dust content significantly reduce (can reduce more than 50%), alleviate the load of sack cleaner greatly.Can improve the air cloth ratio of sack cleaner, reduce filter area, reduce investment outlay; This cyclone separator arrangement is simple, separative efficiency height, the pressure loss very little (being lower than 150pa).
Reactor shell comprises cylindrical shell bottom diffuser.Exhanst gas outlet 8 is for being located at the rectangular flue in reactor head centre, and it is even to help the whole reactor Flow Field Distribution, helps refluxing in the absorbent.
Claims (7)
1. return current circulating fluidized bed in flow equalizing field flue gas desulfurization reactor, comprise air inlet (1), reactor shell (7), gas-solid separator (6), central outlet flue (8) and calcium hydroxide and circulating ash access road etc., it is characterized in that: reactor structure from the bottom to top is followed successively by, the streamlined bottom air inlet of direct current (1), deflector (2) as an air intake structure part, the built-in absorbent distributor in center (3), flue gas accelerator (4), humidification activation nozzle (5), the central outlet flue (8) of eddy flow plate gas-solid separator (6) and reactor shell (7), calcium hydroxide that is connected with the built-in absorbent distributor in center (3) and circulating ash access road (9).
2. reflux cycle fluid bed flue gas desulfurization reactor in according to claim 1, be characterised in that: the streamlined bottom inflow flue of described direct current is square variable section structure.
3. reflux cycle fluid bed flue gas desulfurization reactor in according to claim 1, it is characterized in that: described deflector as an air inlet flue structure part is the uniform deflector of biplate circular arc type.
4. reflux cycle fluid bed flue gas desulfurization reactor in according to claim 1 is characterized in that: described flue gas accelerator is imitative " Laval nozzle " formula flue gas accelerator.
5. reflux cycle fluid bed flue gas desulfurization reactor in according to claim 1, it is characterized in that: the built-in absorbent distributor in described center is 6 outlets, aims at 6 arrival ends of flue gas accelerator respectively.
6. reflux cycle fluid bed flue gas desulfurization reactor in according to claim 1 is characterized in that: described humidification activation nozzle adopts two-fluid spray nozzle, is positioned at the centre of reactor.
7. reflux cycle fluid bed flue gas desulfurization reactor in according to claim 1, it is characterized in that: described eddy flow plate gas-solid separator is located at reactor shell top.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2008201233691U CN201304323Y (en) | 2008-11-06 | 2008-11-06 | Circumfluence cycling fluidized bed flue gas desulfurization reactor in homogeneous flow field |
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|---|---|---|---|
| CNU2008201233691U CN201304323Y (en) | 2008-11-06 | 2008-11-06 | Circumfluence cycling fluidized bed flue gas desulfurization reactor in homogeneous flow field |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402019B (en) * | 2008-11-06 | 2012-12-26 | 北京博朗环境工程技术股份有限公司 | Flue gas desulfurization reactor of return current circulating fluidized bed in flow equalizing field |
-
2008
- 2008-11-06 CN CNU2008201233691U patent/CN201304323Y/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402019B (en) * | 2008-11-06 | 2012-12-26 | 北京博朗环境工程技术股份有限公司 | Flue gas desulfurization reactor of return current circulating fluidized bed in flow equalizing field |
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| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of utility model: Circumfluence cycling fluidized bed flue gas desulfurization reactor in homogeneous flow field Effective date of registration: 20120929 Granted publication date: 20090909 Pledgee: Beijing Zhongguancun development group Limited by Share Ltd Pledgor: Beijing Bolang Environmental Engineering & Technology Co., Ltd. Registration number: 2012990000586 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20090909 Effective date of abandoning: 20081106 |
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| RGAV | Abandon patent right to avoid regrant | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20150116 Granted publication date: 20090909 Pledgee: Beijing Zhongguancun development group Limited by Share Ltd Pledgor: Beijing Bolang Environmental Engineering & Technology Co., Ltd. Registration number: 2012990000586 |
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| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model |