CN200999238Y - Biomass themal pyrolytic gas dust removing-washing-fractional distillation-decoking purification-storing apparatus - Google Patents

Biomass themal pyrolytic gas dust removing-washing-fractional distillation-decoking purification-storing apparatus Download PDF

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Publication number
CN200999238Y
CN200999238Y CNU2007201185180U CN200720118518U CN200999238Y CN 200999238 Y CN200999238 Y CN 200999238Y CN U2007201185180 U CNU2007201185180 U CN U2007201185180U CN 200720118518 U CN200720118518 U CN 200720118518U CN 200999238 Y CN200999238 Y CN 200999238Y
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washing
water
biomass
pyrolysis gas
tube
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周泽宇
谢忠诚
吴先杰
林常泉
刘少烽
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Abstract

The utility model relates to a biological environmental protection technology, in particular to a biomass pyrolysis gas dust removal to washing to fractional distillation to decoking purification to storage device. Through the pyrolysis high temperature biomass pyrolysis gas, the wood vinegar and wood tar are fractionated after the dust removal and condensation of the pyrolysis gas and the depth detar is washed to ensure the normal operation and safe storage of the engine cylinder, so the utility model is a more perfect, scientific and safer technique and device with good effect. The biomass pyrolysis gas dust removal to washing to fractional distillation to decoking purification to storage device is provided with a biomass pyrolysis gas inlet, a dust remover opened with an ash hole vertically, a washing box, a condensing and fractional distillation tank provided with water inlet and outlet of the cooling circulating water and a water seal barrel provided on the vertical bottom, a washing tower provided with a plurality of layers of spray water inlet and spray water outlet provided on the bottom vertical to the washing tower, a vacuum pump and water sealed automatic constant pressure cabinets which are communicated with each other via pipelines.

Description

Pyrolysis gas of biomass dedusting-washing-fractionation-decoking purification-storage facility
Technical field
The utility model relates to a kind of biological environmental production technology, particularly a kind of pyrolysis gas of biomass dedusting-washing-fractionation-decoking purification-storage facility.
Background technology
By retrieval, the most approaching technology of the application's case is the scientific and technological result project " biological waste combustion gas heating power combination preparing device " of Harbin Institute of Technology, and it is made of two portions: i.e. the fluidized-bed combustion boiler of heat supply and dry distillation gas producer.When biological waste enters the dry distillation gas producer, the elevated temperature heat carrier (recycle stock) and the biological waste fluidisation that the self-circulation fluidized-bed combustion boiler are separated with coal gas, the latter is heated by higher temperature carrier, and pyrolytic gasification under anoxia condition decomposites combustion gas, tar and semicoke.Semicoke is sent into the circular fluid bed burning that acts as a fuel, and produces steam heating.This device both can supply combustion gas, can supply steam or hot water again.Performance index are as follows: the gasification efficiency difference of all kinds of biological wastes dry distillation gas production in fluidized-bed.Gasification efficiencies such as wood chip based on xylogen can be greater than 75%, and rice husk is about 50%.The pyrolysis combustion gas calorific value of rice husk, wood chip, sunflower seed shell etc. is all greater than 12MJ/Nm under the best system temperature.Biological waste efficiency of combustion based on xylogen can reach more than 99%, and the rice husk semicoke burns difficulty, and efficiency of combustion is lower slightly.The biological waste amount is big, is renewable energy source, and it is few that burning produces obnoxious flavour, and the characteristics of carbon dioxide zero discharge.
The utility model content
The purpose of this utility model is to overcome above-mentioned weak point of the prior art and provides a kind of dedusting at pyrolysis gas, cooling aftercut to go out wood vinegar and wood tar oil, washs the pyrolysis gas of biomass dedusting-washing-fractionation-decoking purification-storage facility of degree of depth detar to guarantee that normal operation of engine cylinder and safety inspection are stored again.The utility model is not biomass pyrolytic technology and device, but the technique device how the pyrolysis gas that different modes produces is handled and stored.
The purpose of this utility model can reach by following measure:
This pyrolysis gas of biomass dedusting-washing-fractionation-decoking purification-storage facility, its special character is: have pyrolysis gas of biomass import and perpendicular fly-ash separator, the washing tank that offers ash output hole, be provided with condensation fractionating tank that cooling circulating water water-in and cooling circulating water water outlet and perpendicular bottom be provided with the water seal bucket, be provided with washing tower, vacuum pump, the hydrolock automatic constant-pressure cabinet that some grades of spray water imports and perpendicular bottom be provided with the spray water outlet and be communicated with by the road each other.
The purpose of this utility model can also reach by following measure:
Described washing tank is provided with the spray circulating outlet parallel with horizontal plane, the parallel respectively inlet pipe that is provided with in bottom half both sides, escape pipe by casing, bottom half and forms.
Spray circulation water-in, the set coupling end in bottom, horn-like spreading area, its lower end that described inlet pipe is offered by big end down horn-like body, its throat's contraction flow region side are formed.
The gas-water separation packing layer that described escape pipe is provided with by the bottom inlet place, the air outlet at top are formed.
Inlet mouth, air outlet, the tank base that described condensation separation column is communicated with respectively by tank body, tank body top is provided with the middle upper cover dividing plate that is used to separate inlet mouth, air outlet that is provided with of water seal bucket, jar inner top that inserts liquid level for pipeline, and the sieve tray that upper cover the lower partition connects is formed with tubulation subassembly, the corresponding respectively cooling circulating water water-in of offering in tank body side, water outlet.
Wood vinegar that be arranged in parallel with horizontal plane that described water seal bucket is offered by staving, staving liquid level top and wood tar oil outlet are formed.
Described sieve tray and tubulation subassembly are put by upper and lower two and are enclosed within some tubulations that are connected between a jar intravital sieve tray, upper and lower two sieve trays and form.
Described washing tower is by middle column, its two ends are respectively equipped with air outlet and the cone-shaped tower tube that sprays circulating outlet, interior and the vertically disposed packing layer of separating by some grids of air outlet direction of tower tube, be provided with the parallel shower of dative grid bearing in the middle of the packing layer, be positioned at spray that the tower tube sidewall of some packing layers is provided with the respectively water-in that circulates with fixed attention, the inlet mouth that tower tube bottom column and taper handing-over position are provided with, the atomizer that is provided with between the packing layer lower end in inlet mouth and the tower tube is formed.
Described hydrolock automatic constant-pressure cabinet is by the pond, wear and direction perpendicular to the ground is extended the inlet pipe of pond liquid level to the pond, back-off is gone into tube, tube crown center in the pond and worn and wear the fire insulation valve assembly that connects the flexible pipe air feed to the tube to the safety valve of unloading pressure pipe, tube top pressure relief water pipe both sides below the liquid level of pond, tensimeter and from the tube top and form with a gap through basin bottom.
Described fire insulation valve assembly by the fire insulation valve that passes through cylindrical shell, this fire insulation valve through Y-tube be communicated to the fire insulation valve and the flexible pipe thereof of roasting kiln, the fire insulation valve that is communicated to generator and flexible pipe thereof respectively and form.
The utility model has following advantage compared to existing technology:
1. the method and the type of furnace of pyrolysis gas of biomass generation are more, but not perfect for the treatment technology of the pyrolysis gas that produces.At first being the condensation fractionation after the dedusting, is thereafter detar more up hill and dale, guarantees engine cylinder not " coking ", " scuffing of cylinder bore ".The storage of combustion gas also needs simple, inexpensive and safe method and apparatus;
2. simple, safety, constant pressure, the water of ejection can make the tube cooling summer.The huge pressure volume pot of the usefulness that compares is good and cheap.
Description of drawings
Fig. 1 is a structural representation of the present utility model.
Fig. 2 is the structure intention of the utility model washing tank.
Fig. 3 is the structural representation of the utility model shell and tube condensation fractionating tank.
Fig. 4 is the structural representation of the utility model shell and tube condensation fractionating tank sieve tray and tubulation subassembly.
Fig. 5 is the structural representation of the utility model three-phase fluidization washing tower.
Fig. 6 is the structural representation of the utility model hydrolock automatic constant-pressure cabinet.
Embodiment
The utility model is described in further detail below in conjunction with accompanying drawing:
See also shown in Figure 1, this pyrolysis gas of biomass dedusting-washing-fractionation-decoking purification-storage facility comprises: have pyrolysis gas of biomass import 11 and perpendicular fly-ash separator 1, the washing tank 2 that offers ash output hole 12, be provided with condensation fractionating tank 3 that cooling circulating water water-in 313 and cooling circulating water water outlet 314 and perpendicular bottom be provided with water seal bucket 32, be provided with washing tower 4 that some grades of spray water imports 413 and perpendicular bottom be provided with spray water outlet 414, vacuum pump 5, hydrolock automatic constant-pressure cabinet 67 be communicated with each other by the road.
See also shown in Figure 2ly, described washing tank 2 is provided with the spray circulating outlet 22 parallel with horizontal plane, the parallel respectively inlet pipe that are provided with of casing 21 two bottom sides (Venturi tube) 23, escape pipe 24 by casing 21, casing 21 bottoms and forms.
The set coupling end 2314 in 23 13 bottoms, the horn-like spreading area in spray circulation water-in 2312, its lower end that described inlet pipe 23 is offered by big end down horn-like body 231, its throat's 2311 contraction flow region sides is formed.
The air outlet 242 at the gas that described escape pipe 24 is provided with by the bottom inlet place, water sepn packing layer 241, top is formed.
See also shown in Figure 3, the inlet mouth 311 that described condensation separation column 3 is communicated with respectively by tank body 31, tank body 31 tops, air outlet 312, tank body 31 bottoms are provided with the middle upper cover dividing plate 33 that is used to separate inlet mouth 311, air outlet 312 that is provided with of water seal bucket 32, jar inner top that inserts liquid level for pipeline, and the sieve tray that upper cover dividing plate 33 bottoms connect is formed with tubulation subassembly 34, the corresponding respectively cooling circulating water water-in of offering 313 in tank body 31 sides, water outlet 314.
Wood vinegar that be arranged in parallel with horizontal plane that described water seal bucket 32 is offered by staving 321, staving 321 liquid level tops and wood tar oil outlet 322 are formed.
See also shown in Figure 4ly, described sieve tray and tubulation subassembly 34 are put the some tubulations 342 that are connected between the sieve tray 341 that is enclosed within the tank body 31, upper and lower two sieve trays 341 by upper and lower two and are formed.Described tubulation 342 is arranged by toroidal.
See also shown in Figure 5ly, described washing tower 4 is by middle column 411, its two ends are respectively equipped with air outlet 413 and the cone-shaped 412 tower tubes 41 that spray circulating outlet 414, tower the tube 41 interior and vertically disposed packing layers of separating by some grids 42 43 of air outlet 413 directions, be provided with the shower 44 parallel between the packing layer 43 with grid 42 directions, be positioned at spray that tower tube 41 sidewalls of some packing layers 43 are provided with the respectively water-in 415 that circulates with fixed attention, the inlet mouth 416 that tower tube 41 bottom columns 411 and cone-shaped 412 handing-over positions are provided with, the atomizer 45 that is provided with between packing layer 43 lower ends in inlet mouth 416 and the tower tube 41 is formed.
See also shown in Figure 6ly, described hydrolock automatic constant-pressure cabinet 6 wears by water seal tank 61, through water seal tank 61 bottoms and direction perpendicular to the ground is extended the inlet pipe 62 of water seal tank liquid level to the pond, back-off is gone into tube 63, tube 63 crown centers in the water seal tank 61 and worn to wear to the safety valve 65 of unloading pressure pipe 64, tube 63 top pressure relief water pipes 64 both sides below 61 liquid levels of pond, tensimeter 66 and from tube 63 tops to the fire insulation valve assembly 67 of tube external hose air feed and form with a gap.
Described fire insulation valve assembly 67 by the fire insulation valve 671 that passes through cylindrical shell 63, this fire insulation valve 671 through Y-tube 672 be communicated to the fire insulation valve 673 and the flexible pipe 675 thereof of roasting kiln, the fire insulation valve 674 that is communicated to generator and flexible pipe 675 thereof respectively and form.
Use:
See also shown in Figure 1ly, pyrolysis gas of biomass is earlier through tornado dust collector 1, and centrifugal action is solid down, gas two is separated, and thick dust is thrown to around the tower body, because of than great 12 li in the fly-ash separator 1 tower body below ash bucket that falls into.Also have tiny dust to be taken away through cyclone dust removal, therefore adopt wet dedusting by air-flow.See also shown in Figure 2, pyrolysis gas of biomass is inhaled into from inlet pipe (Venturi tube) 23 tops earlier, attenuate because of diameter shrinks at larynx neck 2311, the very big formation negative pressure of gas velocity, the spray recirculated water that pump is made is drawn into, mix with pyrolysis gas of biomass, horn-like spreading area 2313 forms eddy current and turbulence state mixing in the lower end again then, arrived in the casing 21, volume enlarges, the separation of meeting of gas, water two washes away the dust in the pyrolysis gas of biomass mostly, and washing water are collected by high and low flowing automatically in the circulating water pool from casing 21 below pipes 22.Pyrolysis gas of biomass after the purification is sucked into upper right side gas, the water sepn packing layer 241 of casing 21, the moisture of taking away by filler hold back drop onto case at the bottom of, the pyrolysis gas of biomass after the purification enters shell and tube condensation fractionating tank 3.See also shown in Figure 3ly, pyrolysis gas of biomass does not only have dust through the front two-step purification, and temperature has reduced many.Enter in the jar 31, it at first is the leftward space that enters upper cover, it is separated by upper cover dividing plate 33, and pyrolysis gas of biomass can only flow to tank body 31 bottom head spaces along the half of tubulation in a left side, flows to the rightward space of tank body 31 top upper cover dividing plates 33 again along right half of tubulation.Tank body 31 has the clear water of coming from refrigeration cycle pond pump that the biogas in whole tubulations is cooled off, 2-3 this device of can connecting as required.Cooled pyrolysis gas of biomass just can be separated wood vinegar and wood tar oil.In order not allow outside air see in, underlying water seal bucket 32, its side is taken over and is allowed the collection that flows away of fractionated product.The tubulation here and sieve tray subassembly 34 are some tubulations 342 with upper and lower two sieve trays, 341 combinations after again sealing weld on tank body 31, becomes as a whole, assurance gas, water are respectively walked the road of each.Enter three-phase fluidization washing tower 4 again, see also shown in Figure 5,2 series connection as the case may be of this washing tower 4.After pyrolysis gas of biomass fractionates out wood vinegar and wood tar oil, still need degree of depth ground to remove wood tar oil and wood vinegar, " coking ", " scuffing of cylinder bore " and corrosion can take place otherwise enter engine cylinder.Pyrolysis gas of biomass is that the below from washing tower 4 is sucked into, at first be subjected to the atomized water spray washing of atomizer 45 ejections, then from bottom to top through 2 layers of light filler layer 43, mix in packing layer 43 with upper and lower 2 row's showers 44 spray waters, mass transfer, wood tar oil in the pyrolysis gas of biomass and wood vinegar are dissolved in the spray water, make its purification.Gas, liquid and filler (Gu) the three-phase relative movement, form the three-phase fluidization state.Pyrolysis gas of biomass after the purification fails to be convened for lack of a quorum and takes away small amount of moisture, in the 3rd layer of packing layer most of water is retained down, and drips to 4 ends of washing tower.Spray water is to recycle and accomplish that environmental purification handles, and with pump water is driven in the tower as shown in Figure 5 three positions, upper, middle and lower, and backwater is to flow automatically to circulating water pool from 4 ends of washing tower under by height.Vacuum pump 5 is arranged on after the three-phase fluidization washing tower 4, make total system all suction type work under negative pressure of all facilities before this pump 5, otherwise all centrifugal blower to be installed before each processing unit equipment, this is irrational, and the front just go out pyrolyzer pyrolysis gas of biomass temperature up to 650 ℃, general centrifugal blower can't bear high temperature like this.Because work in 24 hours, this pump must be provided with 2, and the using and the reserved are used alternatingly.Being connected on after 2 vacuum pumps 5 is hydrolock automatic constant-pressure gas holder 6, see also shown in Figure 6, by tube 63, water seal tank 61, inlet pipe 62, unload pressure pipe 64, three standard fire insulation valves 67, tensimeter 66 and safety valve 65 are formed.Purify artifact matter pyrolysis gas and must store adjusting air demand and pressure, guarantee that the engine air feed is constant with gas holder.Pyrolysis gas of biomass after the purification pumps into hydrolock automatic constant-pressure cabinet 6 by vacuum pump 5, is air storage under the positive pressure.Pass water seal tank 61 through inlet pipe 62 and enter tube 63, tube 63 upwards pressure and is and acts on a pressure opposite sign but equal magnitude of interior water seal tank 61 waters surface, at this moment release water absorption tube 64 just has water in tube 63 top ejections, and it is constant to remain tube 63 air pressure inside.When just beginning not have pyrolysis gas of biomass, tube 63 weight make its height that falls into the pond a certain design in bottom, and air is compressed to a certain degree maintenance balance in the tube 63.When the pyrolysis gas of biomass input, tube 63 is subjected to the gas upward pressure upwards to float, gas is many more highly more floating, when levitation height makes release water absorption tube 64 exceed the water surface, pyrolysis gas of biomass will all be gone to the ambient atmosphere from release water absorption tube 64 and go, automatically unloading is to original original state, and tube 63 falls into the home position, bottom of water seal tank 61 at once.As long as pyrolysis gas of biomass has been arranged, can be through 3 fire insulation valve 67 pipelines output air feed be housed, wherein one is for the personal gas of roasting kiln; Another strand is for engine power generation.All receive and use the gas place, use valve regulated with rubber hose.For safer, tensimeter 66 is set shows, also can connect warning.Safety valve 65 is set simultaneously.Water seal tank 61 is used skeleton construction, is arranged on underground certain projected depth, reduces the rising height of tube 63, otherwise too high.
The above only is preferred embodiment of the present utility model, and all equalizations of being done according to the utility model claim scope change and modify, and all should belong to the covering scope of the utility model claim.

Claims (10)

1. pyrolysis gas of biomass dedusting-washing-fractionation-decoking purification-storage facility is characterized in that: have pyrolysis gas of biomass import and perpendicular fly-ash separator, the washing tank that offers ash output hole, be provided with condensation fractionating tank that cooling circulating water water-in and cooling circulating water water outlet and perpendicular bottom be provided with the water seal bucket, be provided with washing tower, vacuum pump, the hydrolock automatic constant-pressure cabinet that some grades of spray water imports and perpendicular bottom be provided with the spray water outlet and be communicated with by the road each other.
2. pyrolysis gas of biomass dedusting according to claim 1-washing-fractionation-decoking purification-storage facility is characterized in that: described washing tank is provided with the spray circulating outlet parallel with horizontal plane, the parallel respectively inlet pipe that is provided with in bottom half both sides, escape pipe by casing, bottom half and forms.
3. pyrolysis gas of biomass dedusting according to claim 2-washing-fractionation-decoking purification-storage facility is characterized in that: spray circulation water-in, the set coupling end in bottom, horn-like spreading area, its lower end that described inlet pipe is offered by big end down horn-like body, its throat's contraction flow region side are formed.
4. pyrolysis gas of biomass dedusting according to claim 2-washing-fractionation-decoking purification-storage facility is characterized in that: the gas-water separation packing layer that described escape pipe is provided with by the bottom inlet place, the air outlet at top are formed.
5. pyrolysis gas of biomass dedusting according to claim 1-washing-fractionation-decoking purification-storage facility, it is characterized in that: inlet mouth, air outlet, the tank base that described condensation separation column is communicated with respectively by tank body, tank body top is provided with the middle upper cover dividing plate that is used to separate inlet mouth, air outlet that is provided with of water seal bucket, jar inner top that inserts liquid level for pipeline, and the sieve tray that upper cover the lower partition connects is formed with tubulation subassembly, the corresponding respectively cooling circulating water water-in of offering in tank body side, water outlet.
6. pyrolysis gas of biomass dedusting according to claim 5-washing-fractionation-decoking purification-storage facility is characterized in that: wood vinegar that be arranged in parallel with horizontal plane that described water seal bucket is offered by staving, staving liquid level top and wood tar oil outlet are formed.
7. pyrolysis gas of biomass dedusting according to claim 5-washing-fractionation-decoking purification-storage facility is characterized in that: described sieve tray and tubulation subassembly are put by upper and lower two and are enclosed within some tubulations that are connected between a jar intravital sieve tray, upper and lower two sieve trays and form.
8. pyrolysis gas of biomass dedusting according to claim 1-washing-fractionation-decoking purification-storage facility, it is characterized in that: described washing tower is by middle column, its two ends are respectively equipped with air outlet and the cone-shaped tower tube that sprays circulating outlet, interior and the vertically disposed packing layer of separating by some grids of air outlet direction of tower tube, be provided with the parallel shower of dative grid bearing in the middle of the packing layer, be positioned at spray that the tower tube sidewall of some packing layers is provided with the respectively water-in that circulates with fixed attention, the inlet mouth that tower tube bottom column and taper handing-over position are provided with, the atomizer that is provided with between the packing layer lower end in inlet mouth and the tower tube is formed.
9. pyrolysis gas of biomass dedusting according to claim 1-washing-fractionation-decoking purification-storage facility is characterized in that: described hydrolock automatic constant-pressure cabinet wears by the pond, through water seal tank bottom and direction perpendicular to the ground is extended the inlet pipe of water seal tank liquid level to the water seal tank, back-off is gone into tube, tube crown center in the water seal tank and worn and wear the fire insulation valve assembly that connects the flexible pipe air feed to the tube to the safety valve of unloading pressure pipe, tube top pressure relief water pipe both sides below the water seal tank liquid level, tensimeter and from the tube top and form with a gap.
10. pyrolysis gas of biomass dedusting according to claim 9-washing-fractionation-decoking purification-storage facility is characterized in that: described fire insulation valve assembly by the fire insulation valve that passes through cylindrical shell, this fire insulation valve through Y-tube be communicated to the fire insulation valve and the flexible pipe thereof of roasting kiln, the fire insulation valve that is communicated to generator and flexible pipe thereof respectively and form.
CNU2007201185180U 2007-02-01 2007-02-01 Biomass themal pyrolytic gas dust removing-washing-fractional distillation-decoking purification-storing apparatus Expired - Fee Related CN200999238Y (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101564630B (en) * 2009-06-08 2010-12-29 南京林业大学 Gas-liquid separation and purification system for pyrolysis gas of agriculture and forestry biomass materials
CN102199455A (en) * 2011-04-28 2011-09-28 武汉天颖环境工程有限公司 Purification system of biomass pyrolysis gas
CN102380276A (en) * 2011-09-05 2012-03-21 南京林业大学 Gas-solid-liquid separation and purification system for agricultural and forestry biomass material gasified gas
US20130011321A1 (en) * 2011-07-07 2013-01-10 Hsueh Yuan Lee Exhaust gas treatment apparatus and method
CN102100997B (en) * 2009-12-22 2013-06-19 贵阳铝镁设计研究院有限公司 Filler washing tower
CN104017609A (en) * 2014-05-21 2014-09-03 梁鹏 Dry process purifying, cracking and fraction recovering device and process of coal pyrolysis gas
CN105112108A (en) * 2015-09-11 2015-12-02 蒙娜丽莎集团股份有限公司 Water gas cooling washing tower
CN108219861A (en) * 2018-02-08 2018-06-29 武汉金中石化工程有限公司 A kind of thick straw fuel gas purification technique and its purifier
CN115371445A (en) * 2022-06-14 2022-11-22 成都易态科技有限公司 Yellow phosphorus flue gas purification system and industrial kiln flue gas purification device

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101564630B (en) * 2009-06-08 2010-12-29 南京林业大学 Gas-liquid separation and purification system for pyrolysis gas of agriculture and forestry biomass materials
CN102100997B (en) * 2009-12-22 2013-06-19 贵阳铝镁设计研究院有限公司 Filler washing tower
CN102199455A (en) * 2011-04-28 2011-09-28 武汉天颖环境工程有限公司 Purification system of biomass pyrolysis gas
US20130011321A1 (en) * 2011-07-07 2013-01-10 Hsueh Yuan Lee Exhaust gas treatment apparatus and method
US8728210B2 (en) * 2011-07-07 2014-05-20 Hsueh Yuan Lee Exhaust gas treatment apparatus and method
CN102380276A (en) * 2011-09-05 2012-03-21 南京林业大学 Gas-solid-liquid separation and purification system for agricultural and forestry biomass material gasified gas
CN104017609A (en) * 2014-05-21 2014-09-03 梁鹏 Dry process purifying, cracking and fraction recovering device and process of coal pyrolysis gas
CN104017609B (en) * 2014-05-21 2015-11-25 山东科技大学 A kind of coal pyrolysis gas body dry cleaning, cracking and cut retrieving arrangement and technique
CN105112108A (en) * 2015-09-11 2015-12-02 蒙娜丽莎集团股份有限公司 Water gas cooling washing tower
CN108219861A (en) * 2018-02-08 2018-06-29 武汉金中石化工程有限公司 A kind of thick straw fuel gas purification technique and its purifier
CN115371445A (en) * 2022-06-14 2022-11-22 成都易态科技有限公司 Yellow phosphorus flue gas purification system and industrial kiln flue gas purification device

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