CN200981896Y - Chlorine dioxide cooperating sterilizing agent generator by electrolytic method - Google Patents

Chlorine dioxide cooperating sterilizing agent generator by electrolytic method Download PDF

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Publication number
CN200981896Y
CN200981896Y CNU2006201184554U CN200620118455U CN200981896Y CN 200981896 Y CN200981896 Y CN 200981896Y CN U2006201184554 U CNU2006201184554 U CN U2006201184554U CN 200620118455 U CN200620118455 U CN 200620118455U CN 200981896 Y CN200981896 Y CN 200981896Y
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China
Prior art keywords
inner room
mistress
dissolved salt
salt case
electrolytic
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Expired - Fee Related
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CNU2006201184554U
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Chinese (zh)
Inventor
张喜成
李德纯
张万益
段王喜
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Beijing Xinxin Xuqing Tech & Trade Co Ltd
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Priority to CNU2006201184554U priority Critical patent/CN200981896Y/en
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Abstract

A generator for chlorine dioxide and disinfectant with a novel electrolytic method belongs to a novel generating apparatus for chlorine dioxide and disinfectant, which produces a plurality of mixture gas for disinfecting, such as C1O2, C12, O3, H2O2 or the like by electrolyzing saturated salting solution, comprising a auto-controlling apparatus, a direct supply, a electrolytic tank and a detachable dissolved salt case. The auto-controlling apparatus and the direct supply are connected with the magnetic valve arranged on inner and outer room of the electrolytic tank and the heat-sensitive element in inner room by directing lines in order to realize the automatic control of the electrolytic temperature and the elimination of the alkali liquor. The inner and outer room of the electrolytic groove and the dissolved salt case has detachable conformation, wherein the inner room is connected with the dissolved salt case by the upper and the lower circulating pipes, and the inner room is supplied with saturated salting solution from the dissolved salt case continually in the endless form of temperature difference and concentration difference. The optimized choice of the polar distance in the electrolytic tank and the current density and the high performance of osmotic membrane are the key point to reduce the pressure of electrolytic tank and improve the current efficiency, thereby making the whole active chlorine satisfy nominal rating and reducing bulk of the generator.

Description

Novel electrolysis chlorine dioxide concurrent disinfection agent generator
Technical applications electrolysis chlorine dioxide concurrent disinfection agent generator produces ClO by the electrolysis saturated salt solution 2, Cl 2, O 3, H 2O 2Etc. the various mixed gases sterilizing agent, can be widely used in water fields such as tap water, swimming-pool water, hospital sewage, sanitary sewage, industrial circulating water disinfection, remove algae, deodorizing, bleaching and oxide treatment etc.
Background technology is present, the electrolysis chlorine dioxide disinfectant generator of selling on the market, its structure is similar substantially, but electrolyzer inner room and mistress's structure design of most of producers are unreasonable, the spacing between anode, perviousness barrier film, the negative electrode three and the coupling of area thereof are also unreasonable, cause the bulky of electrolyzer, electrolysis poor performance, current efficiency are low,, total available chlorine do not reach rated value.And the waste lye of electrolytic temperature and discharge also is difficult to control.Especially the operation of equipment is entirely by manual operation guard, very trouble.
The summary of the invention the purpose of this utility model is defective and the deficiency that exists at above-mentioned prior art, and a kind of modern design, rational in infrastructure, technological performance, novel electrolysis chlorine dioxide concurrent disinfection agent generator that level of automation is high are provided.
The purpose of this utility model realizes by following technical proposals.This novel electrolysis chlorine dioxide concurrent disinfection agent generator comprises two-position controller, direct supply and the electrolyzer that is made of inner room, mistress and dissolved salt case four major parts of split.Window on the inner room two side is installed the perviousness barrier film and the mistress communicates, the anode that inner room loam cake central authorities install, and its useful area and required current density are complementary, and link to each other with the positive pole of direct supply by cable.On perviousness barrier film outer wall, negative electrode is housed, links to each other with the negative pole of direct supply with cable.Distance size between anode and the negative electrode, the span of control of pressing with the groove of electrolyzer is complementary.Inner room with outside indoorly snakelike titanium alloy cooling tube be housed be connected with the tap water water source, magnetic valve is housed on water-cooled tube, be connected with two-position controller with lead, the thermal sensing element that is connected with two-position controller is housed in the inner room, at any time measure the temperature variation of inner room, information is input to two-position controller, after software processes, assign instruction, open or close the water coolant magnetic valve, control the lifting of electrolysis temperature.The water inlet pipe that magnetic valve is housed in mistress's bottom is connected with the tap water water source, and magnetic valve links to each other with two-position controller with lead, and the software of two-position controller is provided with direct supply ampere-hour accumulative total program.When equipment moved, the ampere-hour number added up immediately, and when accumulative total reached set(ting)value, two-position controller sent instruction, opened the magnetic valve of mistress's water inlet, and water is injected the mistress, and with water dilution method row alkali, alkali lye is discharged from the overflow port on mistress top.After the discharge alkali lye amount that reaches setting, two-position controller sends the instruction of cutting out entering water electromagnetic valve, stops to arrange alkali.Upper and lower two circulation tubes of electrolyzer are connected inner room with the dissolved salt case, constantly the saturated salt solution in the dissolved salt case is added to inner room during electrolysis, to guarantee the stable of electrolyte concentration.
This accompanying drawing of description of drawings is a structural representation of the present utility model.Among the figure: 1 is two-position controller; 2 is direct supply; 3 are row's alkali magnetic valve; 4 are cooling temperature control magnetic valve; 5 is the dissolved salt case; 6 is the saturated salt water drum; 7 is blowdown apparatus; 8 for circulating for brine tube; 9 is anode; 10 is inner room; 11 is the mistress; 12 is the alkali lye overflow port; 13 is the perviousness barrier film; 14 is negative electrode; 15 is wash water valve; 16 is water intaking valve; 17 is external AC power supply.
Electrolyzer and (5) four complete machines that split is formed of dissolved salt case that embodiment the utility model device mainly is made up of two-position controller (1), direct supply (2), inner room (10) and mistress (11).Anode in device (9) uses cable to be connected with the positive and negative electrode of direct supply (2) respectively with negative electrode (14).After the start-up command of controller (1) is assigned, direct supply (2) promptly starts start, electrolyzer begins to carry out the electrolysis operation, the electrolysis temperature of inner room (10) progressively raises, after the saturated brine with dissolved salt case (5) has formed the temperature difference and concentration difference, form the liquid automated cycle by upper and lower circulation tube (8), can constantly replenish saturated brine to inner room (10) by dissolved salt case (5).Because anode (9), perviousness barrier film (13) and the unique texture of negative electrode (14) and the reasonableness of spacing distance, it is little to make it the electrolyzer volume, and the groove of electrolysis operation forces down current efficiency height, sterilizing agent stable yield.Because the electrolysis active is proceeded, when inner room (10) and mistress's (11) temperature is elevated to the limiting temperature value, inner room (10) and thermal sensing element are delivered to two-position controller (1) with temperature information by lead, controller (1) promptly sends instruction, open water coolant magnetic valve (4), water coolant flows into the serpentine tube of inner room (10), and the serpentine tube through mistress (11) flows out again, can reduce inner room (10) and mistress's (11) temperature.When temperature dropped to design temperature, two-position controller (1) sent the instruction of cutting out water coolant magnetic valve (4) again, promptly stopped cooling.In electrolytic process, during the excessive concentration of mistress (11) alkali lye, can influence electrolysis effectiveness, just must be mistress's (11) the alkali lye part of suitably draining.This device is that the ampere-hour accumulative total by direct supply carries out, when number is accumulated to the numerical value of setting by two-position controller (1) when the ampere of direct supply (2), the instruction of row's alkali promptly takes place, row's alkali magnetic valve (3) is opened, tap water flows into mistress (11) through the pipeline of magnetic valve, make the alkali lye among the mistress (11) obtain dilution, and discharge from overflow port (12).After the alkali lye discharge reached the numerical value of setting, two-position controller (1) promptly sent and stops to arrange the alkali instruction, and row's alkali magnetic valve (3) cuts out.And when above function action, two-position controller (1) is also with corresponding voice suggestion.Because the realization of the utility model electrolytic process device technique scheme, the history of every day with manual operation guard equipment just is through with.

Claims (4)

1, novel electrolysis chlorine dioxide concurrent disinfection agent generator, form by two-position controller (1), direct supply (2) with by electrolyzer and split type dissolved salt case (5) four parts that inner room (10), mistress (11) constitute, it is characterized in that dissolved salt case (5) and inner room (10), mistress (11) are the circulating structures of split, inner room (10) and dissolved salt case (5) are coupled together by upper and lower circulation tube (8).
2, disinfectant generator as claimed in claim 1 is characterized in that anode (9) useful area in the inner room (10) is to be complementary with current density; The anode (9) in the inner room (10) and the spacing distance of the negative electrode (14) among the mistress (11) are to press with the groove of electrolyzer to be complementary; Inner room (10) and mistress (11) are connected by perviousness barrier film (13) optionally.
3, as right 1 described disinfectant generator, it is characterized in that being equipped with in the inner room (10) the snakelike titanium alloy water composite cooling pipe of thermal sensing element and charged magnet valve, thermal sensing element is connected with two-position controller (1) by lead respectively with magnetic valve.
4, disinfectant generator as claimed in claim 1 is characterized in that bottom among the mistress (11) is equipped with the water inlet pipe of the charged magnet valve of discharging alkali lye, is connected with two-position controller (1) by lead.
CNU2006201184554U 2006-06-08 2006-06-08 Chlorine dioxide cooperating sterilizing agent generator by electrolytic method Expired - Fee Related CN200981896Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNU2006201184554U CN200981896Y (en) 2006-06-08 2006-06-08 Chlorine dioxide cooperating sterilizing agent generator by electrolytic method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNU2006201184554U CN200981896Y (en) 2006-06-08 2006-06-08 Chlorine dioxide cooperating sterilizing agent generator by electrolytic method

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CN200981896Y true CN200981896Y (en) 2007-11-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109055966A (en) * 2018-09-13 2018-12-21 北京化工大学 A kind of chemical combined method for preparing chlorine dioxide of electrochemistry-
CN109536987A (en) * 2018-12-26 2019-03-29 九阳股份有限公司 A kind of new structural electrolysis unit
CN113930805A (en) * 2021-11-30 2022-01-14 清华大学 Temperature prediction control method and device for electric hydrogen production system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109055966A (en) * 2018-09-13 2018-12-21 北京化工大学 A kind of chemical combined method for preparing chlorine dioxide of electrochemistry-
CN109536987A (en) * 2018-12-26 2019-03-29 九阳股份有限公司 A kind of new structural electrolysis unit
CN113930805A (en) * 2021-11-30 2022-01-14 清华大学 Temperature prediction control method and device for electric hydrogen production system
CN113930805B (en) * 2021-11-30 2022-09-09 清华大学 Temperature prediction control method and device for electric hydrogen production system

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C14 Grant of patent or utility model
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ASS Succession or assignment of patent right

Owner name: ZHANG XICHENG

Free format text: FORMER OWNER: BEIJING XINXIN XUQING TECH + TRADE CO., LTD.

Effective date: 20110620

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 100854 NO. 91, WUKESONG ROAD, HAIDIAN DISTRICT, BEIJING TO: 100039 NO. 1-8,BUILDING 219, NO. 57, YONGDING ROAD, HAIDIAN DISTRICT, BEIJING

TR01 Transfer of patent right

Effective date of registration: 20110620

Address after: 100039 No. 219, No. 57, Yongding Road, Beijing, Haidian District, No. 1-8

Patentee after: Zhang Xicheng

Address before: 100854 Beijing city Haidian District Wukesong Road No. 91

Patentee before: Beijing Xinxin Xuqing Tech & Trade Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20071128

Termination date: 20150608

EXPY Termination of patent right or utility model