CN1994520A - Filter core for removing agricultural chemical or pesticide from drinking water and preparation method thereof - Google Patents

Filter core for removing agricultural chemical or pesticide from drinking water and preparation method thereof Download PDF

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Publication number
CN1994520A
CN1994520A CN 200610170688 CN200610170688A CN1994520A CN 1994520 A CN1994520 A CN 1994520A CN 200610170688 CN200610170688 CN 200610170688 CN 200610170688 A CN200610170688 A CN 200610170688A CN 1994520 A CN1994520 A CN 1994520A
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CN
China
Prior art keywords
filter core
drinking water
powder
agricultural chemicals
pesticide
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Granted
Application number
CN 200610170688
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Chinese (zh)
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CN100444926C (en
Inventor
苟全伦
栾云堂
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Beijing Zhongke Green Hydrogen Technology Co ltd
Original Assignee
BEIJING GENECARE WATER TREATMENT TECHNOLOGY Co Ltd
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Application filed by BEIJING GENECARE WATER TREATMENT TECHNOLOGY Co Ltd filed Critical BEIJING GENECARE WATER TREATMENT TECHNOLOGY Co Ltd
Priority to CNB2006101706883A priority Critical patent/CN100444926C/en
Publication of CN1994520A publication Critical patent/CN1994520A/en
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Abstract

The invention relates to a filter element which can remove the agriculture medicine or disinfector in drinking water and relative production, wherein its production comprises that: preparing materials via formula, mixing and putting into mould; sintering at high temperature, drying to normal temperature, removing mould, to obtain the porous filter element. The invention can effectively remove agriculture medicine or disinfector at 95-99. 5%.

Description

A kind of filter core of removing agricultural chemicals in the drinking water or pesticide and preparation method thereof
Technical field
The present invention relates to a kind of filter core, particularly relate to a kind of filter core of removing agricultural chemicals in the drinking water or pesticide and preparation method thereof.
Background technology
Developing rapidly of whole world worker, agricultural driven the economic stability sustainable growth, and living standards of the people progressively improve.But the problem of environmental pollution of Yin Faing is more and more serious also thus.In numerous organic pollutions, (persistent organic pollutants POPs) has caused national governments, academia, industrial quarters and the public's extensive attention to persistence organic pollutant for the significant damage of global environment and human health.POPs has four obvious characteristics: 1. persistence exists in the environment that institute discharges and transmits.2. can be accumulated in the food chain and the biology of last nutrition registration is impacted.3. can arrive remote arctic regions by long-distance migration.4. meeting causes harmful to the biology that contacts this material or toxic effect is arranged under respective environment concentration.
For improving crop yield, promote crops to grow up, a large amount of employing agricultural chemicals and pesticide in the agricultural production, and wherein most of pollutant all belongs to POPs.These pollutants are propagated in every way as in air, are entered the face of land or underground water etc. with irrigation water or rainwater, finally human body are produced harm, and severe patient can cause death.
May 23 calendar year 2001, in the Sweden capital, the environment minister of 127 countries or high-ranking official represent separately, and government has signed " about the Convention of Stockholm of persistence organic pollutant ", i.e. " POPs pact ", this pact and on May 17th, 2004 are formally effective, thereby have started human process of declaring a war to POPs.
At present, traditional water purifier all can not effectively be removed this class harmful substance of agricultural chemicals or pesticide, and this type of organic pollution situation is still waiting further to study and improve.
Summary of the invention
The present invention provides a kind of drink water purifying that is used in order to address the above problem, and improves water quality, and the especially a kind of filter core that can effectively remove agricultural chemicals or pesticide can reduce the harm of this type of material to human body, guarantees that safety of drinking water is reliable.
An object of the present invention is to provide a kind of filter core of removing agricultural chemicals in the drinking water or pesticide.
Another object of the present invention provides the preparation method of the filter core of agricultural chemicals in the described removal drinking water or pesticide.
The objective of the invention is to be achieved through the following technical solutions:
A kind of filter core of removing agricultural chemicals in the drinking water or pesticide, it is respectively formed by the raw material system that comprises following parts by weight;
The polyethylene powder 100-300 zeolite powder 5-50 of 1,500,000-7,000,000 molecular weight
Activated carbon powder 50-200 attapulgite powder 10-80
Gas generation agent 5-100
Preferably, a kind of filter core of removing agricultural chemicals in the drinking water or pesticide, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 150-200 zeolite powder 20-40 of 1,500,000-7,000,000 molecular weight
Activated carbon powder 100-150 attapulgite powder 20-60
Gas generation agent 20-70
More preferably, a kind of filter core of removing agricultural chemicals in the drinking water or pesticide, it is formed by the feedstock production that comprises following parts by weight;
Polyethylene powder 150 zeolite powders 30 of 1,500,000-7,000,000 molecular weight
Activated carbon powder 100 attapulgite powder 40
Gas generation agent 30
Activated carbon powder described in the present invention is the medicinal active powdered carbon, has the effect of efficient absorption chemical fertilizer, residues of pesticides, heterochromatic peculiar smell, chlorine and heavy metal, and its order number is the 100-200 order.
Polyethylene powder described in the present invention has the effect of powerful static dynamic absorption, can capture trickle, superfine particle that microfiltration can not filtration resistance, and its order number is the 20-160 order, and molecular weight is 1,500,000-7,000,000, and preferred, molecular weight is 2,500,000-4,000,000.
Zeolite powder described in the present invention and attapulgite powder have good adsorption effect to agricultural chemicals, pesticide residues, and its order number average is the 100-250 order.
Gas generation agent described in the present invention is food-grade carbonic hydroammonium, Celogen Az, oxalic acid, can play pore-creating and make the effect in chamber, and is preferred, food-grade carbonic hydroammonium.
A kind of preparation method who removes the filter core of agricultural chemicals in the drinking water or pesticide of the present invention, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the mould, at high temperature through sinter molding, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness, height of porous.In use, this naked filter core liner two-layer nonwoven, the outsourcing two-layer nonwoven wraps polypropylene porous net at skin again, and bonding the going up in filter core two ends connects end cap, is positioned over stainless steel or plastic casing, gets final product.
Sintering temperature is at 200-300 ℃ among the preparation method of a kind of filter core of removing agricultural chemicals in the drinking water or pesticide of the present invention, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
A kind of filter core of removing agricultural chemicals in the drinking water or pesticide of the present invention can obviously reduce the harm to human body of agricultural chemicals, pesticide in purifying drinking water, make water after filtering become safety, relieved drinking water.After testing, this filter core to the clearance of benzo pollutants, agricultural chemicals and pesticide in the drinking water at 95%-99.5%.
The specific embodiment
Following examples are in order further to describe the present invention for example, rather than limit the present invention by any way.
Embodiment 1
The polyethylene powder of 4,000,000 molecular weight (100 order) 150g
Medicinal active powdered carbon (160 order) 100g
Zeolite powder (250 order) 30g
Attapulgite powder (200 order) 40g
Food-grade carbonic hydroammonium 30g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 250 ℃ of following sintering after 150 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 2
The polyethylene powder of 2,000,000 molecular weight (40 order) 200g
Medicinal active powdered carbon (100 order) 50g
Zeolite powder (100 order) 50g
Attapulgite powder (120 order) 20g
Celogen Az 50g
It is as follows that it makes each method:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 260 ℃ of following sintering after 130 minutes, the demoulding after 45 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 3
The polyethylene powder of 3,000,000 molecular weight (80 order) 250g
Medicinal active powdered carbon (150 order) 70g
Zeolite powder (150 order) 10g
Attapulgite powder (150 order) 30g
Oxalic acid 10g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 230 ℃ of following sintering after 160 minutes, the demoulding after 50 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Embodiment 4
The polyethylene powder of 5,000,000 molecular weight (140 order) 100g
Medicinal active powdered carbon (180 order) 150g
Zeolite powder (200 order) 20g
Attapulgite powder (220 order) 70g
Food-grade carbonic hydroammonium 20g
Its preparation method is as follows:
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the tubular die, at 220 ℃ of following sintering after 120 minutes, the demoulding after 60 ℃ of drying in the air.Promptly become the tubular structure filter core of porous.
Below remove the effect of the filter core of agricultural chemicals in the drinking-water or pesticide by the survey report explanation embodiment of the invention 1 a kind of;
Institute for Environment Hygiene and Health Related Product Safety, China CDC
Survey report
Sample is accepted numbering: the 2005KF0890 date: on December 9th, 2005
The sample title The filter core of the embodiment of the invention 1Kind of inspection Entrust
Interventions Requested The filter element filtering performance testDate of manufacture In September, 2005
Be subjected to the sample date On November 28th, 2005Inspected the date On December 9th, 2005
Assay:
According to " U.S.'s 2001 drinking water standards ", " European Union's 1998 drinking water standards ", U.S. EPA 524.2 methods " stripping capture-gas phase look/mass spectrometric determination volatile organic matter method ", the filter core with molecular sieve structure of inspecting by ready samples is carried out filtration test.At specified aquifer yield 0m 3The time, through this filter core, filter core sees Table 1 to the clearance of test compound to running water with flow 0.19L/min.
The filter core with molecular sieve structure water examination result of table 1 embodiment of the invention 1
Sequence number The mensuration project Mark-on influent density (μ g/L) Filter back water concentration (μ g/L) Clearance (%)
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Mercury selenium beryllium barium chromium cadmium antimony chloroform bromofom chlorodibromomethane 1,1,1-trichloroethanes 1,1,2-trichloroethanes 1,2-dichloropropane 1,1,1,2-tetrachloroethanes 1,2-Bromofume vinyl chloride cis-1,2-dichloroethylene anti-form-1,2-dichloroethylene vinylidene chloride trichloro-ethylene tetrachloro-ethylene benzene toluene ethylbenzene 8.7 9.3 9.2 14 19 9.0 9.6 9.63 10.3 11.2 8.17 11.3 9.28 9.09 11.0 9.61 8.17 8.70 8.20 9.04 9.90 8.85 9.27 10.0 <0.2 <1 0.5 7 8 0.4 <0.5 <0.05 <0.18 <0.06 <0.08 <0.14 0.103 <0.11 <0.10 <0.19 <0.08 <0.08 <0.35 <0.09 <0.07 <0.03 <0.03 <0.04 98.9 94.6 94.6 50.0 57.9 95.6 97.4 99.7 99.1 99.7 99.5 99.4 99.4 99.4 99.5 99.0 99.5 99.5 97.9 99.5 99.6 99.8 99.8 99.8
25 26 27 28 29 30 31 32 33 34 35 36 Chlorobenzene butachlor butylate Niran heptachlor Bravo 4,4 '-drip to drip her 4,4 '-DDT a-BHC 2,2 ', 3 ', 4, Tianjin is gone in the show of 6 '-pentachlorodiphenyl endrin 12.1 5.10 2.28 1.36 1.68 3.00 0.75 0.66 8.93 1.09 1.24 4.10 <0.05 <0.02 <0.008 <0.01 <0.01 <0.02 <0.003 <0.006 <0.02 <0.003 <0.03 <0.008 99.8 99.8 99.9 99.6 99.7 99.7 99.8 99.5 99.9 99.9 98.8 99.9

Claims (9)

1. filter core of removing agricultural chemicals in the drinking water or pesticide, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 100-300 zeolite powder 5-50 of 1,500,000-7,000,000 molecular weight
Activated carbon powder 50-200 attapulgite powder 10-80
Gas generation agent 5-100
2. a kind of filter core of removing agricultural chemicals in the drinking water or pesticide according to claim 1, it is formed by the feedstock production that comprises following parts by weight;
The polyethylene powder 150-200 zeolite powder 20-40 of 1,500,000-7,000,000 molecular weight
Activated carbon powder 100-150 attapulgite powder 20-60
Gas generation agent 20-70
3. a kind of filter core of removing agricultural chemicals in the drinking water or pesticide according to claim 2, it is formed by the feedstock production that comprises following parts by weight;
Polyethylene powder 150 zeolite powders 30 of 1,500,000-7,000,000 molecular weight
Activated carbon powder 100 attapulgite powder 40
Gas generation agent 30
4. a kind of filter core of removing agricultural chemicals in the drinking water or pesticide according to claim 1, wherein said activated carbon powder is the medicinal active powdered carbon, its order number is the 100-200 order.
5. a kind of filter core of removing agricultural chemicals in the drinking water or pesticide according to claim 4, the polyethylene powder of wherein said 1,500,000-7,000,000 molecular weight, molecular weight are 2,500,000-4,000,000, its order number is the 20-160 order.
6. a kind of filter core of removing agricultural chemicals in the drinking water or pesticide according to claim 5, wherein said gas generation agent is food-grade carbonic hydroammonium or Celogen Az or oxalic acid.
7. a kind of filter core of removing agricultural chemicals in the drinking water or pesticide according to claim 6, wherein said zeolite powder and attapulgite powder order number are the 100-250 order.
8. a kind of preparation method who removes the filter core of agricultural chemicals in the drinking water or pesticide according to claim 1, it may further comprise the steps;
Take by weighing each raw material by formula ratio, after the mixing and stirring, insert in the mould, at high temperature through sinter molding, the demoulding to the normal temperature of drying in the air promptly becomes the tubular structure filter core with regulation wall thickness and height of porous.
9. a kind of preparation method who removes the filter core of agricultural chemicals in the drinking water or pesticide according to claim 8, wherein said sintering temperature is at 200-300 ℃, and sintering time is 120-160 minute, dries in the air behind the sintering to the 40-60 ℃ of demoulding.
CNB2006101706883A 2006-12-28 2006-12-28 Filter core for removing agricultural chemical or pesticide from drinking water and preparation method thereof Active CN100444926C (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
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CN101310854B (en) * 2008-02-22 2010-06-02 周奇迪 Filter media and preparation method, filter element, purifier and drinking machine using the filter media
CN101822923A (en) * 2010-04-29 2010-09-08 奇迪电器集团有限公司 Filter medium for removing chloroacetamide in drinking water and preparation method thereof
CN101569856B (en) * 2008-04-30 2011-06-01 周奇迪 Filtering medium for removing metallic lead in water and preparation method thereof
CN101628222B (en) * 2009-08-20 2011-12-07 蒋永锋 Filtering medium for removing micro radioactive substances in water and preparation method thereof
CN102527155A (en) * 2011-10-20 2012-07-04 常州亚环环保科技有限公司 Structural filter element for removing acraldehyde from drinking water and preparation method of structural filter element
CN102553352A (en) * 2011-10-20 2012-07-11 常州亚环环保科技有限公司 Structure filter for removing formaldehyde from drinking water and its preparation method
CN101992078B (en) * 2009-08-18 2012-07-18 奇迪电器集团有限公司 Filter medium for removing estrogen medicine from water and preparation method thereof
CN103463868A (en) * 2013-06-20 2013-12-25 天长市天乐电器厂 Active carbon air filter element and preparation method thereof
CN103768841A (en) * 2012-10-17 2014-05-07 单建民 Manufacturing method of activated carbon filter
CN104587959A (en) * 2015-01-29 2015-05-06 慈溪市天泉电器科技有限公司 Filter medium for removing endosulfan from water as well as filter element and preparation method of filter medium
CN104587984A (en) * 2015-01-29 2015-05-06 江苏中翔网络科技有限公司 Filtering medium for removing nitrate in drinking water, filter element and preparation method of filtering medium
CN107308920A (en) * 2017-05-22 2017-11-03 福建省福灿环保科技有限公司 One kind removes hexachloro-benzene filter medium, filter core and preparation method in drinking water
CN107349921A (en) * 2017-09-07 2017-11-17 广州尊卓环保科技有限公司 Filter medium, filter core and the preparation method of methacrylaldehyde in a kind of removal frying oil

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CN101898060B (en) * 2010-08-04 2013-04-03 奇迪电器集团有限公司 Filter medium for removing halogenated nitromethane in drinking water and preparation method thereof

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CN1075975C (en) * 1999-05-21 2001-12-12 徐祝平 Technology for producing filter element cup
US20060000763A1 (en) * 2004-06-30 2006-01-05 Rinker Edward B Gravity flow carbon block filter

Cited By (16)

* Cited by examiner, † Cited by third party
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CN101310854B (en) * 2008-02-22 2010-06-02 周奇迪 Filter media and preparation method, filter element, purifier and drinking machine using the filter media
CN101569856B (en) * 2008-04-30 2011-06-01 周奇迪 Filtering medium for removing metallic lead in water and preparation method thereof
CN101992078B (en) * 2009-08-18 2012-07-18 奇迪电器集团有限公司 Filter medium for removing estrogen medicine from water and preparation method thereof
CN101628222B (en) * 2009-08-20 2011-12-07 蒋永锋 Filtering medium for removing micro radioactive substances in water and preparation method thereof
CN101822923A (en) * 2010-04-29 2010-09-08 奇迪电器集团有限公司 Filter medium for removing chloroacetamide in drinking water and preparation method thereof
CN101822923B (en) * 2010-04-29 2011-12-07 奇迪电器集团有限公司 Filter medium for removing chloroacetamide in drinking water and preparation method thereof
CN102527155A (en) * 2011-10-20 2012-07-04 常州亚环环保科技有限公司 Structural filter element for removing acraldehyde from drinking water and preparation method of structural filter element
CN102553352A (en) * 2011-10-20 2012-07-11 常州亚环环保科技有限公司 Structure filter for removing formaldehyde from drinking water and its preparation method
CN103768841B (en) * 2012-10-17 2015-11-25 南通美亚新型活性炭制品有限公司 Manufacturing method of activated carbon filter
CN103768841A (en) * 2012-10-17 2014-05-07 单建民 Manufacturing method of activated carbon filter
CN103463868A (en) * 2013-06-20 2013-12-25 天长市天乐电器厂 Active carbon air filter element and preparation method thereof
CN103463868B (en) * 2013-06-20 2015-08-19 天长市天乐电器厂 A kind of active carbon air filter element and preparation method thereof
CN104587984A (en) * 2015-01-29 2015-05-06 江苏中翔网络科技有限公司 Filtering medium for removing nitrate in drinking water, filter element and preparation method of filtering medium
CN104587959A (en) * 2015-01-29 2015-05-06 慈溪市天泉电器科技有限公司 Filter medium for removing endosulfan from water as well as filter element and preparation method of filter medium
CN107308920A (en) * 2017-05-22 2017-11-03 福建省福灿环保科技有限公司 One kind removes hexachloro-benzene filter medium, filter core and preparation method in drinking water
CN107349921A (en) * 2017-09-07 2017-11-17 广州尊卓环保科技有限公司 Filter medium, filter core and the preparation method of methacrylaldehyde in a kind of removal frying oil

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Address after: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

Patentee after: Beijing Zhongke Green Hydrogen Technology Co.,Ltd.

Country or region after: China

Address before: 100031, room 8, building 813, Capital Times Square, 88 West Chang'an Avenue, Beijing, Xicheng District

Patentee before: Beijing Genecare Water Treatment Technology Co.,Ltd.

Country or region before: China