CN1980632A - Cosmetic compositions containing at least one surfactant and at least one ethylene copolymer with polyethylene glycol grafts - Google Patents

Abstract

The invention concerns cosmetic compositions comprising: A) at least one anionic surfactant and at least one nonionic surfactant, and B) at least one ethylene copolymer comprising, in weight percentage based on the total weight of the polymer: a) 10-60 wt. % of one or more monomers of formula (I) as defined below, b) 40-90 wt. % of at least one substantially cationic monomer selected among: (i) one or more cationic monomers of formula (IIa), (ii) one or more amphoteric monomers of formulae (IIc) and (IId), and (iii) a mixture of one or more cationic monomers of formula (IIa) with one or more anionic monomers selected among maleic anhydride and/or those of formula (IIb); and/or with one or more amphoteric monomers selected among those of formulae (IIc) and (IId), and c) optionally 0-50 wt. % of nonionic hydrophilic monomers, excluding methyl acrylate, methyl methacrylate and isopropyl acrylate if they are present in an amount not less than 10 wt. %. Hair treated with said compositions are more easily disentangled during rinsing, and exhibits softness after drying. The inventive compositions also allow particularly interesting hair brushing after drying.

Description

Contain at least a surfactant and at least a novel cosmetic composition with the grafted olefin copolymer of Polyethylene Glycol

Technical field

The present invention relates to contain at least a surfactant and at least a compositions with the grafted olefin copolymer of Polyethylene Glycol.

Background technology

Known way is, in cosmetics, especially uses polymer in the hair products of conservative product, for example is used to obtain hair retentivity and constancy.

For example in the field of shampoo or hair conditioner, also use the water solublity synthetic cationic polymers in " using the afterflush type " compositions, known they provide good beauty treatment for hair; Yet these polymer do not provide the Hair styling effect.The polymer of the cation natural origin for example situation of modified guar is like this equally, and modified guar also provides the beauty treatment performance, but molding is not provided.In the field with afterflush type compositions, polymer does not provide the abundant shaping performance relevant with acceptable beauty treatment.

The purpose of this invention is to provide cosmetic composition, it comprises the typing effect that can provide real, keeps the polymer of acceptable composition beauty treatment property simultaneously, the especially only slight low sticky polymers that changes the viscosity of the compositions that comprises them.

After a large amount of research, the applicant has been found that use comprises that especially the polymer of Polyethylene Glycol (methyl) acrylic ester monomer can prepare usefulness afterflush type or the conservative Hairstyling composition with abundant beauty treatment as defined below.

Description of the Prior Art contain the unitary polymer of Polyethylene Glycol (methyl) acrylate (MPEG).

Therefore, EP 372 546 discloses the copolymer based on MPEG and C1-C8 alkyl (methyl) acrylamide monomers, and this copolymer can comprise cationic monomer.Yet these polymer only comprise a spot of cationic monomer, and this can not make them produce sufficient cosmetic result, especially are enough to provide the deposition on hair of desired properties.

File JP2002-322 219 described contain the MPEG unit with based on the hydrophobic monomer of polypropylene glycol (PPO) or polyoxybutylene and the polymer of cationic monomer.Yet, have been found that these polymer that comprise hydrophobic monomer can not obtain gratifying beauty treatment performance.

Also have, from patent JP2002-284 627, get cicada and contain wherein PEG class monomer and the compositions that comprises the bonded cationic polymer of the unitary monomer of quaternary ammonium.Yet unitary the existing in the application of quaternary ammonium can cause extra deposition gradually, and this can damage the beauty treatment quality of compositions in some cases.And these polymer contain the cationic charge of low content, about 0.5-6%, and this can not provide best hair affinity.

File JP2000-302 649 has described the Haircare composition that comprises a kind of polymer, this polymer comprises cation or ampholytic monomer, monomer with polyether group, especially PEG or PPO class monomer, and optional main hydrophobic monomer (for example methacrylic acid stearyl ester).

The Haircare composition that contains the polymer of other monomer (they are main hydrophobic) that comprises MPEG class monomer and ion, cation or ampholytic monomer and (methyl) acrylic acid C1-C24 alkyl esters can also be learnt from patent JP07-285 831.Yet, hydrophobic comonomer, for example the existence of the comonomer of butyl acrylate or stearyl acrylate esters can not obtain beauty treatment performance fully, especially can not obtain the wet good disentanglement of sending out after the just hair washing.

Patent application WO 03/,075 867 also is known, and it has described linear block copolymers, and wherein poly-(aklylene glycol) block is surrounded by two olefin blocks.The defective of these polymer is to have high-molecular weight poly-(aklylene glycol) class central block, and this makes polymer have high-crystallinity, thereby forms the product of opaque product and/or oils and fats character.

Summary of the invention

The applicant has had been found that the novel polymeric that typing and conditioning effect can be provided for cosmetic hair care.

Do not wish to be subjected to the restriction explained at present, it is believed that this especially can be owing to the existence of PEG (methyl) acrylate (MPEG) unit in polymer chain, these unit go far towards the effect that obtained.Specifically, have been found that the simple mixtures with cationic polymer and PEG base polymer can not obtain this effect.

Surprisingly, polymer according to the present invention has favourable beauty treatment performance, for example in the application of the shampoo composite of the conjugate that comprises specific surfactant; Specifically, have been found that hair is easy to disentanglement in the hair washing process, and be softish; After drying, in case also allow the hair drying just to have good Hair styling according to compositions of the present invention.

Cosmetic composition according to the present invention is characterised in that they comprise:

I) at least a anion surfactant and at least a non-ionic surface active agent and

II) at least a olefin copolymer, by the weight percent based on total polymer weight, it comprises:

A) one or more of 10-60wt% monomer of general formula (I) as defined below;

B) at least a " cation basically " monomer of 40-90wt%, it is selected from:

(i) cationic monomer of one or more general formulas (IIa),

(ii) one or more general formulas (IIc) and ampholytic monomer (IId) and

(iii) the cationic monomer of one or more general formulas (IIa) and one or more are selected from the anionic monomer in those of maleic anhydride and/or general formula (IIb); And/or be selected from the mixture of the ampholytic monomer in general formula (IIc) and (IId) those with one or more,

C) the nonionic hydrophilic monomer of Ren Xuan 0-50wt% if they exist with the amount that is higher than and equal 10wt%, does not comprise acrylic acid methyl ester., methyl methacrylate and isopropyl acrylate.

In the remainder of this description, term " cyclic group " is meant monocycle or multi-ring group, can be one or more saturated and/or undersaturated, the optional ring that replaces (for example, cyclohexyl, the ring decyl, benzyl or fluorenyl), and can be the group (for example to tert-butylcyclohexyl or 4-hydroxybenzyl) that comprises one or more described rings.

Term " saturated and/or unsaturated group " is meant complete saturated group, and unsaturated group comprises aromatic group, and comprise one or more pairs of keys and/or triple bond that remaining key is single bonded group fully.

Anion surfactant, can mention separately or as the salt of the following chemical compound of mixture (alkali metal salt especially, sodium salt especially, ammonium salt, amine salt, amino alkoxide or magnesium salt): alkyl sulfate, alkyl ether sulfate, the alkylamidoalkyl ether sulfate, alkyl aryl polyether sulfate, sulphuric acid monoglyceride salt; Alkylsulfonate, alkylphosphonic, alkylamide sulfonate, alkylaryl sulfonate, alpha-alkene sulfonate, alkane sulfonate; Salts of alkyl sulfosuccinates salt, alkyl ether sulfosuccinate, alkylamide sulfosuccinate; The alkyl sulphosuccinamate, alkyl sulfoacetate; Alkyl ether phosphate; Acyl sarcosinates; Acyl-hydroxyethyl sulfonate and N-acyl taurine salt, the alkyl of all these chemical compounds or acyl group preferably contain 8-24 carbon atom, and aryl is preferably represented phenyl or benzyl.Can also mention soap, for example the salt of oleic acid, castor oil acid, Palmic acid, stearic acid, cocinic acid or hydrogenation coconut oil; Wherein acyl group contains the acyl-lactate of 8-20 carbon atom; Alkyl-D-galactose iduronic acid and their salt, and polyoxy alkylene (C ₆-C ₂₄) alkyl ether carboxylic acid, polyoxy alkylene (C ₆-C ₂₄) the alkyl aryl ether carboxylic acid, polyoxy alkylene (C ₆-C ₂₄) salt of alkylamidoalkyl ether carboxylic acid and they, especially contain the mixture of those and they of 2-50 ethylene oxide group.Fatty acid is not preferred.

In anion surfactant, preferably use alkyl sulfate, the mixture of alkyl ether sulfate and alkyl ether carboxy acid salt and they, especially alkali metal salt (N or K) or alkali salt (for example Mg), or ammonium salt, amine salt or amino alkoxide and their mixture.

Gross weight in cosmetic composition is a benchmark, and the amount of anion surfactant is preferably 3-40wt%, especially 5-25wt%, especially 5-25wt%.

Non-ionic surface active agentCan mention separately or as the polyethoxylated of mixture, poly-propoxylation or bound to polyglycerol fatty acid, induced by alkyl hydroxybenzene, salmefamol, or has for example alcohol of the aliphatic chain of 8-22 carbon atom, the number of ethylene oxide or propylene oxide group especially can be 2-50, and the number of glycerol group especially can be 2-30.Can also mention the copolymer of oxirane and expoxy propane, the condensation substance of oxirane and expoxy propane and aliphatic alcohol; The polyethoxylated fatty acid amide preferably has the oxirane of 2-30ml, on average contains 1-5, especially the bound to polyglycerol fatty acid amide of 1.5-4 glycerol group; The oxyethylation fatty acid ester of anhydro sorbitol with oxirane of 2-30mol; The fatty acid ester of sucrose, the fatty acid ester of Polyethylene Glycol, alkyl poly glucoside, N-alkylated glucamine derivant, amine oxide, for example (C ₁₀-C ₁₄) alkyl amine oxide or N-acyl amino propyl group morpholine oxide.

Preferably, non-ionic surface active agent is selected from:

The glycerol aliphatic alcohol;

Alkyl poly glucoside.

The term aliphatic chain is meant the linearity that contains 6-30 and preferred 8-24 carbon atom or branching, saturated or unsaturated hydrocarbons type chain.

About alkyl poly glucoside, these chemical compounds are well-known, more specifically can represent with following general formula:

R ₁O-(R ₂O) _t(G) _v (11)

R wherein ₁Expression contains linearity or the branched-alkyl and/or the alkenyl of about 8-24 carbon atom, and its neutral line or branched-alkyl contain the alkyl phenyl of 8-24 carbon atom, R ₂Expression contains the alkylidene of about 2-4 carbon atom, and G represents to contain the sugar unit of 5 or 6 carbon atoms, and t represents 0-10 and the value of preferred 0-4 and the value that v represents 1-15.

Preferred alkyl poly glucoside is the chemical compound of general formula (II), wherein R according to the present invention ₁More specifically expression contains the saturated or unsaturated linearity or the branched-alkyl of 8-18 carbon atom, and t represents the value of 0-3, also more specifically equals 0, and G can represent glucose, fructose or galactose, preferred glucose.The degree of polymerization, that is, the v value in the general formula (II) can be 1-15, preferred 1-4.Average degree of polymerization is 1-2 more particularly, also 1.1-1.5 more specifically.Glycosidic bond between sugar unit is 1-6 type or 1-4 type, preferred 1-4 type.

The chemical compound of general formula (II) is representative with the product of being sold under trade name Plantaren  (600CS/U, 1200 and 2000) or Plantacare  (818,1200 and 2000) by Cognis company especially.Can also use the product of selling down at trade name Triton CG110 (or Oramix CG110) and Triton CG312 (or Oramix  NS10) by SEPPIC company, by BASF AG at product of selling under the trade name Lutensol GD70 or the product under trade name AG10 LK, sold by Chem Y company.

For example, can also use the C8/C16 alkyl poly glucoside-1,4 of conduct 53% aqueous solution of under trade name Plantacare  818UP, selling by Cognis.

About monoglycerolifying or bound to polyglycerol surfactant, they preferably include average 1-30 glycerol group, more specifically 1-10, particularly 1.5-5 glycerol group.

Monoglycerolifying or bound to polyglycerol surfactant preferentially are selected from following general formula:

RO[CH ₂CH (CH ₂OH) O] _mH, RO[CH ₂CH (OH) CH ₂O] _mH or RO[CH (CH ₂OH) CH ₂O] _mThe chemical compound of H; Wherein R represents to contain the saturated or unsaturated linearity or the branched hydrocarbon type group of 8-40 carbon atom and preferred 10-30 carbon atom; M is 1-30, preferred 1-10, the more specifically integer of 1.5-6.

R can choose wantonly and comprise hetero atom, for example oxygen and nitrogen.Especially, R can choose wantonly and comprise one or more hydroxyls and/or ether and/or amide group.

R preferably represents optional monohydroxylated or polyhydroxylated C ₁₀-C ₂₀Alkyl and/or alkenyl.

For example, can use the hydroxyl lauryl ether of the bound to polyglycerol of selling by Chimex with the trade name of Chimexane  (3.5mol).

In non-ionic surface active agent, preferably use C ₆-C ₂₄Alkyl poly glucoside and C more specifically ₈-C ₁₆Alkyl poly glucoside.

Gross weight in cosmetic composition is a benchmark, and the total amount of non-ionic surface active agent is preferably 0.5-25wt%, especially 1-20wt%, more specifically 2-10wt%.

Preferably, said composition can also comprise at least a amphoteric surfactant.

Amphoteric surfactantCan mention separately or as the aliphatic secondary amine or the tertiary amines derived thing of mixture, wherein aliphatic group is to contain 8-22 carbon atom and contain at least one water soluble anion group (carboxylate radical for example, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical) linearity or branched chain; Can also mention (C ₈-C ₂₀) alkyl betaine, sulfobetaines, (C ₈-C ₂₀) alkylamidoalkyl (C ₁-C ₆) alkyl betaine, for example cocamidopropyl betaine, or (C ₈-C ₂₀) alkylamidoalkyl (C ₁-C ₆) the alkyl sulfobetaines.

In amphoteric surfactant, C ₈-C ₂₀Alkyl betaine, (C ₈-C ₂₀) alkylamidoalkyl (C ₆-C ₈) alkyl betaine and N-(alkyl amide ethyl)-N-(2-hydroxyethyl amino) sodium diacelate (alkylamphodiacetates) and their mixture be preferred the use.

The total amount of amphoteric surfactant is preferably the 0.5-20wt% of cosmetic composition gross weight, especially 1-10wt%, more specifically 1-5wt%.

In operable surfactant mixtures, the conjugate of anion surfactant, non-ionic surface active agent and amphoteric surfactant is preferred.

The preferential anion surfactant that uses is selected from (C ₁₂-C ₁₄) alkyl sodium sulfate, (C ₁₂-C ₁₄) alkylsurfuric acid triethanolamine or (C ₁₂-C ₁₄) the alkylsurfuric acid ammonium, (the C of the oxirane oxyethylation of usefulness 2.2mol ₁₂-C ₁₄) sodium alkylether sulphate, (the C of the oxirane oxyethylation of usefulness 2.2mol ₁₂-C ₁₄) alkyl ether sulphuric acid triethanolamine the or with (C of the oxirane oxyethylation of 2.2mol ₁₂-C ₁₄) alkyl ether ammonium sulfate, cocamidopropyl sodium isethionate and α-(C ₁₄-C ₁₆) alkene sulfonic acid sodium and they and non-ionic surface active agent and following surfactant mixtures:

-amphoteric surfactant, the amine derivative that for example is called N-(cocamidopropyl ethyl)-N-(2-hydroxyethyl amino)-disodium beclomethasone or N-(cocamidopropyl ethyl)-N-(2-hydroxyethyl amino)-sodium propionate is especially sold by Rhodia Chimie company with the trade name of MiranolC2M CONC or with the trade name of Miranol C32 as the aqueous solution that contains 38% active material;

-or amphoteric ion type amphoteric surfactant, for example alkyl betaine, the especially coco betaine of selling by Cognis company with the trade name of Dehyton AB30 as the aqueous solution that contains 32%AM.

The total amount of surfactant is the 3.5-50wt% of composition total weight especially, preferred 5-30wt%, also more preferably 8-25wt%.

Olefin copolymer

Therefore comprise the monomer of at least a general formula (I) and their salt according to olefin copolymer of the present invention, this monomer can exist separately or as mixture:

Wherein:

-R ₁Be hydrogen atom or C _pH _2p+1The linearity of class or branching hydro carbons group, wherein p is the integer of 1-12, comprises end value;

-Z is selected from-COO-,-CONH-,-CONCH ₃-,-OCO-,-O-,-SO ₂--CO-O-CO-or-CO-CH ₂Divalent group among the-CO-;

-x is 0 or 1;

-R ₂Be that the saturated or unsaturated, optional of 1-30 carbon atom may comprise 1-18 hetero atom that is selected among O, N, S, F, Si and the P for aromatics, linear, branching or ring-type carbon back divalent group,

-m is 0 or 1;

-n is the integer of 3-300, comprises end value;

-R3 is a hydrogen atom, and perhaps 1-30 carbon atom is saturated or unsaturated, optional for aromatics, linear, branching or ring-type carbon back group, can comprise 1-20 hetero atom that is selected among O, N, S, F, Si and the P.

R ₁Especially can represent methyl, ethyl, propyl group or butyl.Preferably, R ₁Expression hydrogen or methyl.

Preferably, Z represents COO or CONH.

Preferably, x equals 1.

In radicals R ₂In, when having hetero atom, hetero atom can be inserted into described radicals R ₂Chain in, perhaps described radicals R ₂Can be by one or more groups that comprise them for example hydroxyl or amino (NH ₂, NHR ' or NR ' R ", wherein R ' and R " can be identical or different, expression linearity or branching C ₁-C ₂₂Alkyl, especially methyl or ethyl) replace.

R ₂Especially can be:

-alkylidene, methylene for example, ethylidene, propylidene, inferior normal-butyl, isobutylidene, the inferior tert-butyl group, inferior n-hexyl, inferior n-octyl, inferior dodecyl, inferior n-octadecane base, inferior n-tetradecane base or inferior n-docosane base;

-phenylene-C ₆H ₄-(ortho position, a position or para-position), optional being chosen wantonly contained 1-25 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P; Perhaps benzal C ₆H ₄-CH ₂-, optional being chosen wantonly contained 1-8 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P;

The pyridine  group of-following formula:

Wherein R ' 1-R ' 4 can be identical or different, is selected from H and the optional individual heteroatomic C1-C12 alkyl that is selected among O, N, S, F, Si and the P of 1-8 that contains; R ' 1-R ' 4 especially can be methyl and/or ethyl;

-chemical formula

-CH ₂-O-CO-O-, CH ₂-CH ₂-O-CO-O-,-CH ₂-CO-O-,-CH ₂-CH ₂-CO-O-,-CH ₂-O-CO-NH-,-CH ₂-CH ₂-O-CO-NH-;-CH ₂-NH-CO-NH-,-CH ₂-CH ₂-NH-CO-NH-;-CH ₂-CHOH-,-CH ₂-CH ₂-CHOH-,-CH ₂-CH ₂-CH (NH ₂)-,-CH ₂-CH (NH ₂)-,-CH ₂-CH ₂-CH (NHR ')-,-CH ₂-CH (NHR ')-,-CH ₂-CH ₂-CH (NR ' R ")-,-CH ₂-CH (NR ' R ")-,-CH ₂-CH ₂-CH ₂-NR '-,-CH ₂-CH ₂-CH ₂-O-;-CH ₂-CH ₂The group of-CHR '-O-, wherein R ' and R " optional individual heteroatomic linearity or the branching C1-C22 alkyl that is selected among O, N, S, F, Si and the P of 1-12 that contain of expression;

-or the mixture of these groups.

Preferably, n is 5-200 (comprising end value), is more preferably 7-100 (comprising end value), or even 9-50 (comprising end value).

Preferably, R ₃It is hydrogen atom; Optional by optional individual benzyl or the phenyl that is selected from the heteroatomic C1-C12 alkyl replacement among O, N, S, F, Si and the P of 1-8 that contain; C1-C30 and especially C1-C22 or even the C2-C16 alkyl, optional contain 1-18 hetero atom that is selected among O, N, S, F, Si and the P.

These benzyls, phenyl or alkyl especially can comprise the functional group that is selected from the following functional group:

Perhaps be selected from-SO ₃H ,-COOH ,-PO ₄,-NR5R6 and-N ⁺Functional group among the R5R6R7; wherein R5, R6 and R7 are independently from each other H and linearity, branching or ring-type C1-C18 alkyl; especially methyl; optional comprise one or more hetero atoms, perhaps carry protecting group for example tertbutyloxycarbonyl (also being called BOC) or 9-fluorenyl methoxy carbonyl (also being called Fmoc).

In radicals R 3, can mention methyl, ethyl, propyl group, benzyl, ethylhexyl, lauryl, stearyl and docosyl ((CH ₂) ₂₁-CH ₃) chain, and fluoroalkyl, for example 17 fluorine octyl group sulfuryl amino ethyl CF ₃-(CF ₂) ₇-SO ₂-N (C ₂H ₅)-CH ₂-CH ₂Perhaps-CH ₂-CH ₂-CN, succimide base, dimaleoyl imino,  base, tosyl, triethoxysilane or phthalimide chain.

The monomeric amine unit of general formula (I) and/or anionic group can be chosen wantonly and be neutralized.

In the middle of salt, can mention for example salt of sulphuric acid, hydrochloric acid, hydrobromic acid, hydroiodic acid, phosphoric acid or boric acid of mineral acid.Can also mention organic acid salt, it can comprise one or more carboxylic acids, sulfonic acid or phosphonyl group.They can be linearity, branching or cyclic aliphatic acid or aromatic acid.These acid can also comprise the hetero atom among one or more O of being selected from and the N, for example with the form of hydroxyl.Especially can mention propanoic acid, acetic acid, p-phthalic acid, citric acid and tartaric acid.

These anionic groups can be with inorganic base for example LiOH, NaOH, KOH, Ca (OH) ₂, NH ₄OH, Mg (OH) ₂Or Zn (OH) ₂Or with organic base for example primary, the second month in a season or alkyl amine, especially triethylamine or butylamine neutralization.This primary, the second month in a season or alkyl amine can comprise one or more nitrogen and/or oxygen atom, therefore can comprise for example one or more alcohol functional group; Especially can mention 2-amino-2-methyl-propanol, triethanolamine and dimethylamino-2-propanol.Can also mention lysine or 3-(dimethylamino) propyl group amine.

In the monomer of especially preferred general formula (I), can mention following chemical compound:

-poly-(ethylene glycol) (methyl) acrylate, wherein R1 is H or methyl; Z is COO, x=1, m=0 and R3=H;

-methyl gathers (ethylene glycol) (methyl) acrylate, also is called poly-(ethylene glycol) (methyl) acrylate of methoxyl group, and wherein R1 is H or methyl, and Z is COO, x=1, m=0 and R3=methyl;

-alkyl gathers (ethylene glycol) (methyl) acrylate, and wherein R1 is H or methyl, and Z is COO, x=1, m=0 and R3=alkyl;

-phenyl gathers (ethylene glycol) (methyl) acrylate, also is called poly-(ethylene glycol) phenyl ether (methyl) acrylate, and wherein R1 is H or methyl, and Z is COO, x=1, m=0 and R3=phenyl;

-following monomer:

N 3-100 (comprising end value) preferably wherein, especially 5-50 (comprising end value), or even 7-30 (comprising end value).

The monomer of the most especially preferred general formula (I) is selected from poly-(ethylene glycol) (methyl) acrylate of poly-(ethylene glycol) (methyl) acrylate and methyl, and preferred molecular weight is 350-15000g/mol and those of 500-8000g/mol especially.

Poly-(ethylene glycol) (methyl) acrylate is the most especially preferred, and especially molecular weight is 350-15000g/mol and those of 500-8000g/mol especially.

Commercial monomeric example is:

-CD350 (methoxyl group gathers (ethylene glycol 350) methacrylate) and CD550 (methoxyl group gathers (ethylene glycol 550) methacrylate) are sold by Sartomer Chemicals;

-M90G (methoxy polyethylene glycol methacrylate-styrene polymer (9 repetitives)) and M230G (methoxy polyethylene glycol methacrylate-styrene polymer (23 repetitives)) are available from Shin-Nakamura Chemicals;

-available from the mean molecule quantity of Sigma-Aldrich poly-(ethylene glycol) methacrylate of methoxyl group of 300,475 or 1100;

-available from the mean molecule quantity of Sigma-Aldrich poly-(ethylene glycol) acrylate of methoxyl group of 426;

-with the trade name of mpeg 3 50, MPEG550, S10W, S20W available from poly-(ethylene glycol) methacrylate of the methoxyl group of Laporte;

-available from the mean molecule quantity of Polysciences poly-(ethylene glycol) monomethyl ether list (succimide base succinate) of 1900 or 5000;

-with the trade name of Sipomer BEM available from poly-(ethylene glycol PEG-25) methacrylate of the docosyl of Rhodia;

-available from the mean molecule quantity of Aldrich poly-(ethylene glycol) phenyl ether acrylate of 236,280 or 324;

-available from methoxy poly (ethylene glycol) 5000 2-(vinylsulfonyl) ethylether of Fluka;

-available from the Polyethylene Glycol ether methacrylate of Aldrich;

-available from Monomer﹠amp; Polyethylene Glycol 8000,4000,2000 methacrylates of Polymer Dajac Laboratories;

-available from the Polyethylene Glycol N-maloyl imines vinyl sulfone of Nektar Molecule Engineering (Shearwater).

Preferably, the monomer of general formula (I) has 350-15000g/mol, especially the molecular weight of 500-8000g/mol.

Weight in final polymer is benchmark, separately or as the monomer of the general formula (I) of mixture with 〉=10wt% to＜60wt%, especially 〉=20wt% is to≤55wt%, preferred 〉=30wt% exists to the ratio of≤50wt%.

Ion unit

Also comprise at least a " cation basically " monomer or its salt according to olefin copolymer of the present invention, be selected from:

-(i) cationic monomer of one or more general formulas (IIa),

-(ii) one or more general formulas (IIc) and ampholytic monomer (IId) and

-(iii) the cationic monomer of one or more general formulas (IIa) and the anionic monomer that one or more are selected from maleic anhydride and/or general formula (IIb) in those; And/or be selected from the mixture of the ampholytic monomer in general formula (IIc) and (IId) those with one or more.

Preferably, " cation basically " monomer is selected from cationic monomer and the general formula (IIc) or the ampholytic monomer (IId) of general formula (IIa), preferentially is selected from the cationic monomer of general formula (IIa).

Term " cationic monomer " is meant and contains the unitary monomer that can carry cationic charge in the pH of 3-12 scope.These unit needn't have permanent charge, no matter pH why.This cation unit need be not protonated in each time of these pH value.

Wherein:

-R ₁Be hydrogen atom or C _pH _2p+1The linearity of class or branching hydro carbons group, wherein p is the integer of 1-12, comprises end value.

R ₁Especially can represent methyl, ethyl, propyl group, isopropyl, normal-butyl, isobutyl group or the tert-butyl group.Preferably, R ₁Expression hydrogen or methyl.

-Z ' is selected from

-COO-,-CONH-,-CONCH ₃-,-OCO-or-O-,-SO ₂-CO-O-CO-or-CO-CH ₂Divalent group among the-CO-.

Preferably, Z ' be selected from-COO-and-CONH-.

-x ' is 0 or 1, preferred 1.

-R ' ₂Be the saturated or unsaturated, optional of 1-30 carbon atom, may comprise 1-18 hetero atom that is selected among O, N, S, F, Si and the P for aromatics, linear, branching or ring-type carbon back divalent group.

In radicals R ' ₂In, when having hetero atom, hetero atom can be inserted into described radicals R ' ₂Chain in, perhaps described radicals R ' ₂Can be by one or more groups that comprise them for example hydroxyl or amino (NH ₂, NHR ' or NR ' R " and replacement, wherein R ' and R " can be identical or different, expression linearity or branching C ₁-C ₂₂Alkyl, especially methyl or ethyl) replace.

R ' ₂Especially can be:

-alkylidene, methylene for example, ethylidene, propylidene, inferior normal-butyl, isobutylidene, the inferior tert-butyl group, inferior n-hexyl, inferior n-octyl, inferior dodecyl, inferior n-octadecane base, inferior n-tetradecane base or inferior n-docosane base;

-phenylene-C ₆H ₄-(ortho position, a position or para-position), optional being chosen wantonly contained 1-25 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and/or the P; Perhaps benzal-C ₆H ₄-CH ₂-, optional being chosen wantonly contained 1-25 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P;

-chemical formula

-CH ₂-O-CO-O-, CH ₂-CH ₂-O-CO-O-,-CH ₂-CO-O-,-CH ₂-CH ₂-CO-O-,-[(CH ₂) ₅-CO-O] _n-,-CH ₂-CH (CH ₃)-O-,-(CH ₂) ₂-O-,-CH ₂-O-CO-NH-,-CH ₂-CH ₂-O-CO-NH-;-CH ₂-NH-CO-NH-or-CH ₂-CH ₂-NH-CO-NH-,-CH ₂-CHOH-,-CH ₂-CH ₂-CHOH-,-CH ₂-CH ₂-CH (NH ₂)-,-CH ₂-CH (NH ₂)-,-CH ₂-CH ₂-CH (NHR ')-,-CH ₂-CH (NHR ')-,-CH ₂-CH ₂-CH (NR ' R ")-,-CH ₂-CH (NR ' R ")-,-CH ₂-CH ₂-CH ₂-NR '-,-CH ₂-CH ₂-CH ₂-O-;-CH ₂-CH ₂The group of-CHR '-O-, wherein R ' and R " optional individual heteroatomic linearity or the branching C1-C22 alkyl that is selected among O, N, S, F, Si and the P of 1-12 that contain of expression;

-m ' is 0 or 1;

-X (among the general formula I Ia) is formula-N (R ₆) (R ₇) or-P (R ₆) (R ₇) or-P ⁺R ₆R ₇R ₈Group, R wherein ₆, R ₇And R ₈Expression (i) hydrogen atom or (ii) contain 1-18 carbon atom independently of one another, may contain 1-10 be selected from heteroatomic linearity, branching or ring-type among O, N, S, F, Si and the P saturated or undersaturated, choose wantonly and be the alkyl of aromatics; Or (iii) R ₆And R ₇Can form with nitrogen-atoms or phosphorus atoms and comprise 5,6,7 or 8 atoms altogether, especially 4,5 or 6 carbon atoms and/or 2-4 are selected from heteroatomic first among O, S and the N and saturatedly or undersaturated, optional are the ring of aromatics; Described first ring can with one or more other comprise 5,6 or 7 atoms altogether separately, especially 4,5,6 or 7 carbon atoms and/or 2-4 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics.

For example, R ₆And R ₇Can be selected from hydrogen and methyl, ethyl, propyl group, isopropyl, normal-butyl, the tert-butyl group, isobutyl group, octyl group, lauryl or stearyl.

Preferably, R ₆And R ₇Be independently from each other H, CH ₃And C ₂H ₅

Perhaps, X can represent group-R ' 6-N-R ' 7-, wherein R ' 6 and R ' 7 form with nitrogen-atoms and comprise 5,6,7 or 8 atoms altogether, and especially 4,5 or 6 carbon atoms and/or 2-4 is selected from heteroatomic saturated or undersaturated, optional among O, S and the N and is the ring of aromatics; Described ring can with one or more other comprise 5,6 or 7 atoms altogether separately, especially 4,5,6,7 or 8 carbon atoms and/or 2-4 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics.

For example, X can constitute aromatics or the non-aromatic ring that comprises tertiary amine group, perhaps can represent to contain the aromatics or the non-aromatic heterocyclic of uncle's nitrogen.

In these preferred radicals X, can mention pyridine radicals, indyl, isoindolinyl, imidazole radicals, imidazolinyl, piperidyl, pyrazolinyl (pyrazolynyl), pyrazolyl, quinolyl, pyrazolinyl, pyridine radicals, piperazinyl, pyrrolidinyl, chinidine base, thiazolinyl, morpholinyl, guanidine radicals, amidino groups or  class group and their mixture.

Guanidine radicals and amidino groups have following chemical formula respectively:

The monomer of general formula (IIa) can be neutralized by the nertralizer of different chemical character.

This nertralizer can be selected from mineral acid or the organic acid on the Bronsted meaning, preferentially is selected from organic acid.Perhaps, it can be selected from the logP value and be less than or equal to 2, and is preferred-6 to 1 for example-8 to 2, especially-6 to 0 nertralizer.

It can also be selected from the logP value greater than 2, and be preferably greater than or equal 2.5, especially greater than 3,3-15 particularly, or even the reagent of 3.5-10.

As mentioned below, the logP value is known, and determines according to the code test of measuring the concentration of nertralizer in the hot alcohol and water of 1-.

Operable mineral acid is sulphuric acid especially, hydrochloric acid, hydrobromic acid, hydroiodic acid, phosphoric acid and boric acid.

The nertralizer of organic acid can be selected from linearity, branching or cyclic aliphatic sour and/or unsaturated or aromatic acid, especially can contain 1-1000 carbon atom, a particularly 2-500 carbon atom.They contain the acid functional group at least one Bronsted meaning, especially one or more carboxylic acids, sulfonic acid and/or phosphonyl group.They can also comprise the hetero atom among one or more O of being selected from, N, Si, F and the P, for example with the form of hydroxyl.

Operable nertralizer especially comprises and contains 6-32 and 8-28 carbon atom especially, and contains at least one COOH or sulfonic acid (SO ₃H) linearity of functional group, branching or cyclic, saturated or unsaturated, optionally be the fatty acid of aromatics.

Can also use and contain 6-32 and 8-28 carbon atom and comprise at least one COOH or sulfonic acid (SO especially ₃H) linearity of functional group, branching or cyclic, saturated or undersaturated, optionally be the hydroxy acid of aromatics, especially 'alpha '-hydroxy acids.

Can also use alkyl benzene sulphonate, wherein this alkyl can contain 4-30 and 6-24 carbon atom especially.

Can also use the both sexes nertralizer, the both sexes nertralizer of alkyl betaine or alkylamidoalkyl CAB class especially, wherein this alkyl can contain 4-30, especially 6-24 carbon atom; Especially can mention cocamidopropyl betaine.

Especially can mention Alpha-hydroxy acetic acid, Alpha-hydroxy is sad, and Alpha-hydroxy is sad, ascorbic acid, acetic acid, benzoic acid, behenic acid, capric acid, citric acid, caproic acid, sad, DBSA, 2 ethyl hexanoic acid, folic acid, fumaric acid, galactosaccharic acid, gluconic acid, glycolic, 2-cetyl arachic acid, hydroxycaproic acid, the 12-hydroxy stearic acid, different lauric acid (or the 2-butyl is sad), different myristic acid (or the 2-hexyl is sad), different arachidic acid (or 2-octyl group dodecylic acid), and isotetracosane acid (l ' acide isolignoc é rique) (or 2-decyl tetradecanoic acid), lactic acid, lauric acid, malic acid, myristic acid, oleic acid, Palmic acid, propanoic acid, capric acid, stearic acid, tartaric acid, p-phthalic acid, trimesic acid, 9-undecylenic acid, CAB, cocamidopropyl betaine, and chemical formula [(CH ₃) ₃N ⁺CH ₂CO ₂HCl ^-] beet alkali hydrochlorate and their mixture.

Preferably use caproic acid, 2 ethyl hexanoic acid, oleic acid, behenic acid, stearic acid, acetic acid, citric acid, tartaric acid, beet alkali hydrochlorate and/or gluconic acid as nertralizer, more preferably beet alkali hydrochlorate and/or behenic acid.

Below provided the information of the logP value of some common acids:

Sulphuric acid	-1.031+/-0.613
		Acetic acid	-0.285+/-0.184
Propanoic acid	0.246+/-0.184
		Citric acid	-1.721+/-0.396
Gluconic acid	-3.175+/-0.852
		Boric acid	-0.292+/-0.753
Phosphoric acid	-2.148+/-0.587
		Benzoic acid	1.895+/-0.206
Stearic acid	8.216+/-0.186
		Behenic acid	10.342+/0.186
Oleic acid	7.698+/-0.199

Term " neutralization " is meant all or part of the effect of the organic acid that comprises the acid functional group at least one Bronsted meaning according to the present invention to the above-mentioned monomer that comprises the basic functionality at least one Bronsted meaning and/or polymer.

Separately or can be based on the 0.01-3 of polymer or monomeric whole amine functional groups and 0.05-2.5 molar equivalent especially, or even the amount interpolation of 0.1-2 molar equivalent as the nertralizer of mixture.

Therefore this polymer that can partly neutralize, that is, can the neutralize 1-99% of described polymer or monomeric whole amine functional groups of this nertralizer, especially 5-90% or even the required amount of 10-80% exist; This means it with 0.01-0.99,0.05-0.9 molar equivalent especially, or even the amount of 0.1-0.8 molar equivalent exist.

Excessive this polymer of neutralization, that is, can the neutralize 101-300% of described polymer or monomeric whole amine functional groups of this nertralizer, especially 120-250% or even the required amount of 150-200% exist; When needs guaranteed that this polymer has pH scope that the formulation with regard to imagination is fit to and/or ionic strength, situation came to this.It therefore can described polymer or the 1.01-3 of monomeric whole amine functional groups, 1.2-2.5 molar equivalent especially, or even the amount of 1.5-2 molar equivalent exist.

Preferably, exist with stoichiometric amount separately or as the nertralizer of mixture with respect to described polymer or monomeric whole amine functional groups; It therefore can in and the amount (that is 1 molar equivalent) of 100% described polymer or monomeric amine unit exist.

Preferably, the property quality and quantity of nertralizer can be determined by those skilled in the art, so that finally obtain water solublity or aqueous dispersion polymers.

The monomer of the preferred general formula (IIa) that can mention is:

In the monomer of especially preferred general formula (IIa), can mention dimethylaminopropyl (methyl) acrylamide, dimethyl aminoethyl (methyl) acrylamide, (methyl) acrylic acid diethylamino ethyl ester, (methyl) acrylic acid dimethyl aminoethyl ester, vinyl imidazole, vinylpyridine and (methyl) acrylic acid morpholino ethyl ester, more specifically dimethylaminopropyl (methyl) acrylamide.

In general formula (IIb), the implication of radicals R 1, Z ', x ', R ' 2 and m ' with above for given identical of general formula (IIa).

In general formula (IIb), Y is selected from-COOH-SO ₃H ,-OSO ₃H ,-PO ₃H ₂With-OPO ₃H ₂In group.

Described anionic group can be with inorganic base for example LiOH, NaOH, KOH, Ca (OH) ₂, NH ₄OH, Mg (OH) ₂Or Zn (OH) ₂Or with organic base for example primary, the second month in a season or alkyl amine, especially triethylamine or butylamine neutralization.This primary, the second month in a season or alkyl amine can comprise one or more nitrogen and/or oxygen atom, therefore for example can comprise one or more alcohol functional group; Especially can mention 2-amino-2-methyl propanol, triethanolamine and dimethylamino-2-propanol.Can also mention lysine or 3-(dimethylamino) propylamine.

Be appreciated that according to prior art SO ₄H ₂And PO ₄H ₂Group is connected in R ' 2 via oxygen atom, and SO ₃H and PO ₃The H group is connected in R ' 2 via S and P atom respectively.

In the preferred anionic surfactants monomer, can mention the monomer of maleic anhydride and following preferred general formula (IIb): acrylic acid, methacrylic acid .beta.-methylacrylic acid, itaconic acid, fumaric acid, maleic acid, acrylic acid 2-carboxy ethyl ester (CH ₂=CH-C (O)-O-(CH ₂) ₂-COOH); Styrene sulfonic acid, 2-acrylamido-2-methyl propane sulfonic acid, vinyl benzoic acid, vinyl phosphoric acid, (methyl) acrylic acid sulfopropyl ester and their salt.

In general formula (IIc), the implication of radicals R 1, Z ', x ', R ' 2 and m ' with above for given identical of general formula (IIa).

Other group has following implication:

-X ' ⁺Be-N ⁺(R ₆) (R ₇)-divalent group, R wherein ₆And R ₇Expression (i) hydrogen atom or (ii) contain 1-25 carbon atom independently of one another, may contain 1-20 be selected from heteroatomic linearity among O, N, S and the P, branching or cyclic, choose wantonly and be the alkyl of aromatics; Or (iii) R ₆And R ₇Can form with nitrogen-atoms and comprise 5,6,7 or 8 atoms altogether, especially 4,5,6 or 7 carbon atoms and/or 2-3 are selected from heteroatomic first among O, S and the N and saturatedly or undersaturated, optional are the ring of aromatics; Described first ring can with one or more other comprise 5,6,7 or 8 atoms altogether separately, especially 4,5,6 or 7 carbon atoms and/or 2-3 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics.

For example, R ₆And R ₇Can be selected from hydrogen and methyl, ethyl, propyl group, isopropyl, normal-butyl, the tert-butyl group or isobutyl group.

The preferred radicals X that can mention ' ⁺Be pyridine radicals, indyl, isoindolinyl, imidazole radicals, imidazolinyl, piperidyl, pyrazolinyl, pyrazolyl, quinolyl, pyrazolinyl, pyridine radicals, piperazinyl, pyrrolidinyl, chinidine base, thiazolinyl, morpholinyl, guanidine radicals or amidino groups class group and their mixture.

-Y ' ^-Be to be selected from-COO ^-,-SO ₃ ^-,-OSO ₃ ^-,-PO ₃ ^2-With-OPO ₃ ^2-In group.

-R ' the 3rd, and 1-30 carbon atom saturated or unsaturated, optional for aromatics, linear, branching or ring-type carbon back divalent group may comprise 1-18 hetero atom that is selected among O, N, S, F, Si and the P.

In radicals R in ' 3, when having hetero atom, in the chain of this hetero atom can be inserted into described radicals R ' 3, perhaps described radicals R ' 3 can be by one or more groups that comprise them for example hydroxyl or amino (NH ₂, NHR ' or NR ' R " and replacement, wherein R ' and R " can be identical or different, expression linearity or branching C ₁-C ₁₈Alkyl, especially methyl or ethyl) replace.

R ' 3 especially can be:

-alkylidene, methylene for example, ethylidene, propylidene, inferior normal-butyl, isobutylidene, the inferior tert-butyl group, inferior n-hexyl, inferior n-octyl, inferior dodecyl, inferior n-octadecane base, inferior n-tetradecane base or inferior n-docosane base;

-phenylene-C ₆H ₄-(ortho position, a position or para-position), optional being chosen wantonly contained 1-5 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P; Perhaps benzal-C ₆H ₄-CH ₂-, optional being chosen wantonly contained 1-5 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P;

-chemical formula

-CH ₂-O-CO-O-, CH ₂-CH ₂-O-CO-O-,-CH ₂-CO-O-,-CH ₂-CH ₂-CO-O-,-[(CH ₂) ₅-CO-O] _n-,-CH ₂-CH (CH ₃)-O-,-(CH ₂) ₂-O-,-CH ₂-O-CO-NH-,-CH ₂-CH ₂-O-CO-NH-;-CH ₂-NH-CO-NH-or-CH ₂-CH ₂-NH-CO-NH-,-CH ₂-CHOH-,-CH ₂-CH ₂-CHOH-,-CH ₂-CH ₂-CH (NH ₂)-,-CH ₂-CH (NH ₂)-,-CH ₂-CH ₂-CH (NHR ')-,-CH ₂-CH (NHR ')-,-CH ₂-CH ₂-CH (NR ' R ")-,-CH ₂-CH (NR ' R ")-,-CH ₂-CH ₂-CH ₂-NR '-,-CH ₂-CH ₂-CH ₂-O-;-[CH ₂-CH ₂-O] _n-and-[CH ₂-CH (CH ₃)-O] _n-,-CH ₂-CH ₂The group of-CHR '-O-, wherein R ' and R " optional individual heteroatomic linearity or the branching C1-C22 alkyl that is selected among O, N, S, F, Si and the P of 1-12 that contain of expression;

-or the mixture of these groups;

-n ' is 1-100, preferred 1-5 (comprising end value).

In general formula (IId), the implication of radicals R 1, Z ', x ', R ' 2 and m ' with above for given identical of general formula (IIa), and the implication of radicals R ' 3 and n ' with for given identical of general formula (IIc).

In general formula (IId), X " ⁺Be-N ⁺R ₆R ₇R ₈Divalent group, R wherein ₆, R ₇And R ₈Expression (i) hydrogen atom or (ii) contain 1-18 carbon atom independently of one another, may contain 1-5 be selected from heteroatomic linearity among O, N, S and the P, branching or cyclic, choose wantonly and be the alkyl of aromatics; Or (iii) R ₆And R ₇Can form with nitrogen-atoms and comprise 5,6 or 7 atoms altogether, especially 4,5 or 6 carbon atoms and/or 2-3 are selected from heteroatomic first among O, S and the N and saturatedly or undersaturated, optional are the ring of aromatics; Described first ring can with one or more other comprise 5,6 or 7 atoms separately, especially 4,5,6 or 7 carbon atoms and/or 2-3 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics.

For example, R ₆, R ₇And R ₈Can be selected from hydrogen and methyl, ethyl, propyl group, isopropyl, normal-butyl, the tert-butyl group, isobutyl group, octyl group, lauryl or stearyl.

The preferred radicals X that can mention " ⁺It is trimethyl ammonium; Triethyl ammonium; N, N-dimethyl-N-octyl group ammonium; N, N-dimethyl-N-lauryl ammonium group.

Preferred general formula (IIc) or the monomer (IId) that can mention are N, N-dimethyl-N-(2-methacryloxyethyl)-N-(3-sulfo group propyl group) ammonium betanin (especially coming from the SPE of Raschig company); N, N-dimethyl-N-(3-methacryl amido propyl group)-N-(3-sulfo group propyl group) ammonium betanin (coming from the SPV of Raschig) and 1-(3-sulfopropyl)-2-vinylpyridine  betanin (coming from the SPV of Raschig) and 2-methacryloxyethyl phosphocholine.

When " cation basically " monomer is selected from the mixture of cation and/or ampholytic monomer and anionic monomer, weight in " cationic monomer and/or ampholytic monomer+anionic monomer " mixture is benchmark, described anion is preferably with 5-40wt%, especially 10-30wt%, more preferably the ratio of 15-25wt% exists.

Be somebody's turn to do the 40-90wt% of " cation basically " monomer with final polymer weight, especially the ratio of 45-80wt% and preferred 50-70wt% exists.

Preferably, polymer according to the present invention comprises that weight ratio is 60/40 to 40/60, the monomer of preferred 50/50 general formula (I) and ion monomer (cationic monomer+optional both sexes and anionic monomer).

Can choose wantonly according to olefin copolymer of the present invention and to comprise except above-mentioned monomer those.Therefore these additional monomers are non-ionic.

When it comprised this additional monomer, they must be selected from meaning of the present invention was the monomer of " hydrophilic ".

Term " hydrophilic monomer " is meant that the logarithm value (also being called logP) of 1-octanol/water apparent partition coefficient is less than or equal to 2, for example-8 to 2, preferably is less than or equal to 1.5, especially is less than or equal to 1, particularly-7 to 1, or even-6 to 0 monomer.

Log P value is known, determines according to the code test of measuring the concentration of monomer in the hot alcohol and water of 1-.

This value especially can use ACD software (Advanced Chemistry Development) Solaris V4.67 to calculate; They can also pass through Exploring QSAR: hydrophobic constant, electronics constant and stearic acid constant (ACS specialty handbook, 1995) obtain.

Also exist a network address that estimated value is provided (address:

http://esc.svrres.com/interkow/kowdemo.htm)。

Below provided some common monomeric log P value of using ACD software to measure:

	Methacrylate ( *Or Methacrylamide)	Acrylate ( *Or acrylamide)
			(methyl) acrylic acid methyl ester.	1.346+/-0.250	0.793+/-0.223
(methyl) ethyl acrylate	1.877+/-0.250	1.325+/-0.223
			(methyl) propyl acrylate	2.408+/-0.250	1.856+/-0.223
(methyl) isopropyl acrylate	2.224+/-0.254	1.672+/-0.228
			(methyl) butyl acrylate	2.940+/-0.250	2.387+/-0.223
(methyl) Isobutyl 2-propenoate	2.756+/-0.254	2.208+/-0.228
			(methyl) tert-butyl acrylate	2.574+/-0.261	2.022+/-0.238
(methyl) cyclohexyl acrylate	3.405+/-0.252	2.853+/-0.226
			(methyl) 1-Octyl acrylate	5.065+/-0.521	4.513+/-0.224
(methyl) lauryl acrylate	7.190+/-0.251	6.638+/-0.224
			(methyl) tridecyl acrylate	7.712+/-0.251	7.170+/-0.224
(methyl) acrylic acid cetyl	9.316+/-0.251	8.764+/-0.224
			(methyl) acrylic acid Petiolus Trachycarpi ester	＞9	＞9
(methyl) stearyl acrylate ester	10.379+/-0.251	9.826+/-0.224
			(methyl) acrylic acid docosyl ester	11.952+/-0.225	12.504±0.251
(methyl) acrylic acid oil base ester	＞9	9.308±0.232
			(methyl) acrylic acid tetrahydro furfuryl ester	1.352±0.283	0.800±0.263
(methyl) 2-ethylhexyl acrylate	4.881±0.254	4.329±0.229
			(methyl) acrylic acid 2-hydroxyl ethyl ester	0.718±0.277	0.166±0.258
(methyl) acrylic acid ethoxyethyl group ester	1.887±0.293	1.335±0.268
			(methyl) Hydroxypropyl acrylate		0.383±0.241
N-isopropyl (methyl) acrylamide *	0.748±0.276	0.195±0.256
			N-octyl group (methyl) acrylamide *	3.558±0.273	3.036±0.253
N, N-dimethyl (methyl) acrylamide *	0.906±0.553	-0.168±0.556
			N, N-dibutyl (methyl) acrylamide *	3.573±0.570	3.021±0.557

Vinyl acetate	0.730±0.286
		Methyl vinyl ether	0.509±0.286
Ethyl vinyl ether	1.040±0.286
		Caprolactam	1.499±0.207
Vinyl pyrrolidone	0.370±0.206
		The N-vinyl acetamide	0±0.231

This additional hydrophilic monomer especially can be selected from separately or as those of the general formula (III) of mixture:

Wherein:

-R ' ₁Be hydrogen or-CH ₃

-Z " be to be selected from

-COO-,-CONH-,-CONCH ₃-,-OCO-,-SO ₂,-CO-O-CO-,-CO-CH ₂-CO-or-divalent group among the O-; Preferred COO and CONH;

-x " be 0 or 1;

-R " be that the saturated or undersaturated, optional of 1-30 carbon atom is the linearity of aromatics, branching or ring-type carbon back group, may contain 1-18 hetero atom that is selected among O, N, S, F, Si and the P.

In radicals R " in, when having hetero atom, hetero atom can be inserted in the chain of described group, and perhaps described group can be by one or more for example hydroxyl, ester, amide, urethane or urea replacements of group that comprise them.

R " especially can be methyl, ethyl, propyl group, isopropyl, normal-butyl, isobutyl group, the tert-butyl group, phenyl or benzyl, perhaps chemical formula CH ₂-CH ₂-CH ₂OH ,-CH ₂-CH ₂-OH ,-CH ₂-CH ₂-CH ₂The group of OH or furfuryl group.

Other hydrophilic non-ionic monomer especially is selected from following monomer: methyl methacrylate, acrylic acid methyl ester., ethyl methacrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, the methacrylic acid tetrahydro furfuryl ester, acrylic acid tetrahydro furfuryl ester, methacrylic acid 2-hydroxyl ethyl ester, acrylic acid 2-hydroxyl ethyl ester, methacrylic acid ethoxy ethyl ester, acrylic acid ethoxyethyl group ester, the N-N-isopropylacrylamide, N-isopropyl methyl acrylamide, N, the N-DMAA, N, N-dimethylmethacryl amide, vinyl acetate, methyl vinyl ether, ethyl vinyl ether, vinyl pyrrolidone, caprolactam, N-vinyl acetamide, Hydroxypropyl acrylate, the N-vinyl lactam, acrylamide, N methacrylamide, N, the N-DMAA, N-methyl-N-vinyl acetamide, N-vinyl formamide, N-methyl-N-vinyl formamide, vinyl alcohol (with the form copolymerization of vinyl acetate, hydrolysis then).

Can not be present in according to (0%) in the polymer of the present invention separately or as the additional monomer of mixture, perhaps can exist based on the amount of the 50wt% at the most of the weight of final polymer; It especially can be based on the 0.1-35wt% of the gross weight of polymer, preferred 1-25wt%, 3-15wt% for example, or even the amount of 5-9.5wt% exist.

Yet, have been found that when this additional monomer is selected from acrylic acid methyl ester., methyl methacrylate and isopropyl acrylate these monomers can not exist with the amount that is greater than or equal to 10wt%.Therefore these monomers can 0-9.5wt%, and especially the ratio of 0.1-8wt% and preferred 1-5wt% is present in the final polymer.

Preferably, do not comprise any monomer except general formula (I), (IIa), (IIb), (IIc) and (IId) those according to copolymer of the present invention.Preferably, only comprise general formula (I) and monomer (IIa) according to copolymer of the present invention.

Preferably, polymer used according to the invention comprises that weight ratio is 60/40 to 40/60, the monomer of preferred 50/50 general formula (I) and " cation basically " monomer.

In a particular of the present invention, this polymer is gone up substantially by separately or as the monomer of the general formula (I) of mixture with form separately or as the monomer of the general formula (IIa) of mixture.

The most particularly preferred polymer is those that meet the following conditions:

-separately or as the monomer of the general formula (I) of mixture with 10-60wt% based on final polymer weight, especially the ratio of 20-60wt% and preferred 30-50wt% exists, and be selected from separately or as poly-(ethylene glycol) (methyl) acrylate of mixture, preferred molecular weight is 350-13000g/mol and those of 500-8000g/mol especially; With

-" cation basically " monomer is with the 40-90wt% of the weight of final polymer, especially the ratio of 40-80wt% and preferred 50-70wt% exists, and be selected from separately or as dimethylaminopropyl (methyl) acrylamide of mixture, dimethyl aminoethyl (methyl) acrylamide, (methyl) acrylic acid diethylamino ethyl ester, (methyl) acrylic acid dimethyl aminoethyl ester, vinyl imidazole, vinylpyridine and (methyl) acrylic acid morpholino ethyl ester;

With

Preferably with the organic acid nertralizer that especially is selected from 2 ethyl hexanoic acid, oleic acid, behenic acid, stearic acid, acetic acid, citric acid, tartaric acid, beet alkali hydrochlorate and/or the gluconic acid, more preferably behenic acid and/or beet alkali hydrochlorate neutralize-this polymer.

Also more specifically preferred polymer is those that meet the following conditions:

-separately or as the monomer of the general formula (I) of mixture with 10-60wt% based on final polymer weight, especially the ratio of 20-60wt% and preferred 30-50wt% exists, and be selected from separately or as poly-(ethylene glycol) (methyl) acrylate of mixture, preferred molecular weight is 350-13000g/mol and those of 500-8000g/mol especially; With

-" cation basically " monomer is with the 40-90wt% of the weight of final polymer, and especially the ratio of 40-80wt% and preferred 50-70wt% exists, and is selected from separately or as dimethylaminopropyl (methyl) acrylamide of mixture; With

-this polymer neutralizes with the nertralizer that is selected from behenic acid and/or the beet alkali hydrochlorate.

Can be according to those skilled in the art known and for example prepare according to polymer of the present invention at the working standard free radical polymerisation process described in people's such as Gnanou the works " Chimie et Physicochimie des polymeres " (publishing) by Dunod.

These polymer especially can prepare by the following method:

-direct polymerisation in solution in water, optional preneutralization cation unit and/or anionic units;

-emulsion polymerisation in water, optional preneutralization cation unit and/or anionic units are used surfactant;

-in for example polymerization in ethanol or the methyl ethyl ketone of organic solvent, optional preneutralization cation unit and/or anionic units are dissolved subsequently or are dispersed in the water solvent evaporated.

Peroxide-2 ethyl hexanoic acid the tert-butyl ester) or azo class (AIBN V50:2 these polymerizations can be at (the Trigonox215: of peroxide especially, carry out under the existence of radical initiator two (2-amidine propane) dihydrochlorides of 2 '-azo), they can exist with the ratio of the 0.3-5wt% of total monomer weight.

Polymer according to the present invention is a non-crosslinked.They contain the olefinic type monomers (PEG group side is hung on skeleton) of PEG group with one or more and the form of one or more olefinic type monomers that contains Cationic functional groups (nonquaternary neutralizing amine) and/or betanin functional group and the statistics of one or more other unit price nonionic hydrophilic olefinic comonomer of choosing wantonly, preferred film forming olefin copolymer exists.

Term " alkene " polymer is meant the polymer that polymerization obtained by ethylenically unsaturated monomer.

Term " film forming " polymer is meant itself or can forms in the presence of secondary film formers and be attached to carrier, especially the polymer of the continuous film of keratin material.

They have preferred 500-5000000,1000-3000000 especially, more preferably 2000-2000000, or even 4000-500000,7000-250000 and the preferably weight average molecular weight (Mw) of 8000-100000 better.

Weight average molecular weight (Mw) is measured by gel permeation chromatography or light scattering method, depends on the ease of use (dissolubility of described polymer) of this method.

Polymer that can be used according to the invention preferably can transport in aqueous medium, that is, they are preferably water miscible or water dispersible.

Term " water solublity " is meant that its ratio with 5wt% at least under 25 ℃ is soluble in water, and forms clear solution.

Term " water dispersible " is meant that it has formed meticulous, common spheric particulate stabilising dispersions under the concentration at 5wt% under 25 ℃ in water.The particulate particle mean size that constitutes described dispersion is more typically 5-400nm less than 1 μ m, preferred 10-250nm.These granularities are measured by light scattering.

Dissolving in water or dispersion can be by directly dissolving this polymer (if it is a solubility) or carrying out so that make this polymer dissolve in maybe can be scattered in the water by neutralize this amine and/or acid unit.Dissolving in water or dispersion can also be added water subsequently by dissolved intermediate steps in organic solvent, and the revaporization organic solvent is finished.

And, have been found that can be used according to the invention polymer advantageously have for expection is used water medium viscosity fully, for example can be 1-1000mPa.s, preferred 1.5-750mPa.s also is more preferably 2-500mPa.s.

This viscosity uses brookfield's viscometer that the water or the methyl ethyl ketone solution (dissolubility and/or polymerization according to polymer come selective solvent) that contain the 15wt% polymer are used the pin class mandrel that is selected from Brookfield 00-07 model down at 25 ℃, and preferred No. 1 mandrel is measured; Measuring Time 5 minutes, speed 0.1-6 minute.This viscosity is mensuration after all water-soluble or methyl ethyl ketone at polymer.

In addition, polymer that can be used according to the invention can preferably have-150 to 20 ℃, especially-120 to 10 ℃, also is more preferably-100 to 0 ℃ glass transition temperature; Tg measures according to the method that provided before embodiment.

Polymer that can be used according to the invention can preferably have-100 to 80 ℃, especially-80 and 50 ℃, also is more preferably-70 to 45 ℃, or even-10 to 25 ℃ fusing point (m.p.).

In addition, polymer that can be used according to the invention preferably has 3-150wt% under 75% relative humidity (75%HR), preferred 4-100wt%, the especially water absorption rate of 5-50wt%; This water absorption rate is measured according to the method that provided before embodiment.

They can also have 3-20wt% under 85% relative humidity (85%HR), preferably 2.5-150wt% and the especially water absorption rate of 3-100wt%.

Described polymer can be present in the compositions by dissolved form (for example water-soluble or organic solvent), and perhaps the form with water or organic dispersion is present in the compositions.

They can be by the 0.01-30wt% of composition total weight, especially 0.1-20wt% or even 0.1-10wt% and the solid ratio that also is more preferably 0.5-3wt% in cosmetic composition according to the present invention, use.

Therefore said composition can comprise the hydrophilic media of the mixture that contains water or water and hydrophilic organic solvent, and described organic solvent for example is alcohol, especially linearity or branching C ₁-C ₆Low-grade monobasic alcohol, ethanol for example, the tert-butyl alcohol, n-butyl alcohol, isopropyl alcohol or normal propyl alcohol, and polyhydric alcohol, glycerol for example, diglycerol, propylene glycol, sorbitol, pentanediol and Polyethylene Glycol, perhaps glycol ethers, especially C ₂Glycol ethers and hydrophilic C ₂-C ₄Ketone.

The mixture of water or water and hydrophilic organic solvent can compositions the 30-99wt% of gross weight, the amount of preferred 40-80wt% is present in according in the compositions of the present invention.

Said composition can also comprise basically by in room temperature (common 25 ℃) down for the fatty material of liquid and/or at room temperature be solid fatty material for example wax, paste fatty material, sizing material and their mixture form mutually fatty.These fatty materials can be animal, plant, mineral or synthetic source.This fat can also contain the lipotropy organic solvent mutually.

At room temperature be the liquid fatty material of (often being called oil) as what can use in the present invention, can mention: the alkyl oil of animal origin, for example perhydro Squalene; The alkyl vegetable oil for example contains the liquid triglycerides of the fatty acid of 4-10 carbon atom, for example enanthic acid or Trivent OCG, Semen pruni armeniacae oil, olive oil, wheat germ oil, Oleum Arachidis hypogaeae semen, Oleum Brassicae campestris, safflower oil, Oleum Cocois, hazelnut oil, Petiolus Trachycarpi oil, almond oil, calophyllum oil, Oleum helianthi, Semen Maydis oil, soybean oil, Oleum Vitis viniferae, Oleum sesami, macadimia nut oil, Oleum Ricini, American Avocado Tree oil, caprylic/capric triglyceride, jojoba oil and Adeps Bovis seu Bubali resin; The linearity in inorganic or synthetic source or branching hydro carbons be liquid paraffin and their derivant for example, petroleum jelly, and poly decene and Parleam be parleam for example; Synthetic ester and synthetic ether, the especially synthetic ester of fatty acid and synthetic ether, for example sad spermaceti/stearyl ester (purcellin oil), isopropyl myristate, Palmic acid 2-ethyl hexyl ester, stearic acid 2-octyl group dodecyl ester, erucic acid 2-octyl group dodecyl ester and isostearic acid iso stearyl ester; The hydroxylating ester, lactic acid stearyl ester for example, octyl hydroxystearate, hydroxy stearic acid octyl group dodecyl ester, malic acid two different stearyl esters, citric acid three different cetyl esters, and the fatty alkyl ester of enanthic acid, sad and capric acid; Polyol ester, propylene glycol dicaprylate for example, two enanthic acid DOPCP or diethylene glycol two different pelargonates; And pentaerythritol ester; The aliphatic alcohol that contains 12-26 carbon atom, octyldodecanol for example, 2-butyl capryl alcohol, 2-hexyldecanol, 2-undecyl pentadecanol and oleyl alcohol; Part alkyl or siloxy group fluorocarbon oil; The siloxanes base oil; Their mixture.

These oil can compositions the 0.01-90wt% of gross weight and the content that also is more preferably 0.1-85wt% exist.

For the present invention, term wax is meant at room temperature (25 ℃) for solid lipophilic compound, has reversible solid-liquid attitude and changes, and have the fusing point that is greater than or equal to 25 ℃ (can up to 120 ℃)).By making wax reach liquid (fusion), can make it with may exist oily miscible, the uniform mixture of formation microcosmic, but when the temperature that makes mixture turns back to room temperature, in the oil of mixture, obtained the recrystallize of wax.The fusing point of wax can use differential scanning calorimetry (DSC) (DSC), is for example measured by the calorimeter that Mettler company sells with the trade name of DSC30.

These waxes can be alkyl wax, and fluorine wax and/or siloxane wax can be plant, mineral, animal and/or synthetic source.Especially, these waxes have the fusing point that is higher than 30 ℃ and preferably is higher than 45 ℃.As the wax that can in compositions of the present invention, use, can mention Cera Flava, Brazil wax or candelilla wax, paraffin, microwax, ceresine or ozocerite; Synthetic wax, for example Tissuemat E or fischer-tropsch wax, or siloxane wax for example contain the alkyl polydimethylsiloxane or the alkoxyl polydimethylsiloxane of 16-45 carbon atom.

Described sizing material generally is high-molecular weight polydimethylsiloxane (PDMSs) or cellulose gum or polysaccharide, and these pasty masses generally are alkyl compounds, for example derivant of lanoline and they, or PDMSs.

The character of described solid matter and amount depend on required mechanical performance and quality.As guidance, said composition can contain the 0.1-50wt% based on composition total weight, also is more preferably the wax of 1-30wt%.

Said composition can also comprise additional polymer, for example film forming polymer.According to the present invention, film forming polymer is meant itself or can forms in the presence of secondary film formers and is attached to the especially polymer of the continuous film on the keratin material of carrier.At the film forming polymer that can be used for compositions of the present invention, can mention the synthetic polymer of free radical type or condensation polymer type, the polymer of natural origin and their mixture, especially acrylic acid series polymeric compounds, polyurethane, polyester, polyamide, polyureas and cellulose-based polymer, for example NC Nitroncellulose.

Said composition can also comprise the conditioning polymer except having the grafted copolymer of PEG, is made up of cationic polymer usually.

Cationic polymer that can be used according to the invention can be selected from those of itself known beauty treatment performance of improving hair, promptly, especially at patent application EP-A-0 337 354 and french patent application FR-A-2 270 846,238 3660, described in 2 598 611,2 470 596 and 2 519 863 and that have suitable cationic charge density those.

Also more generally, for the present invention, the statement cationic polymer represent any contain cation group and/or can ionization be cation group the polymer of group.

The preferred cation polymer be selected from contain carry primary, unitary those polymer of secondary, uncle and/or quaternary amines, described unit can form the part of main polymer chain, it is entrained perhaps to hang substituent group by the side that is directly connected in described chain.

Normally used cationic polymer generally has about 500-5 * 10 ⁶Preferably approximately 10 ³-3 * 10 ⁶Number-average molecular weight or weight average molecular weight.

More specifically the cationic polymer that can mention is the polymer of polyamine, polyaminoamide and polyquaternary amine class.They are known products.

Can be used according to the invention, and the polyamine that especially can mention, polyaminoamide and polyquaternary amine base polymer are at described in French Patent (FRP) 2 303 348 or 2 542 997 those.In these polymer, can mention:

(1) by acrylic or methacrylic acid esters or amide and comprise the homopolymer or the copolymer of at least one unit of following formula:

Wherein:

R ₃Can be identical or different, expression hydrogen atom or CH ₃Group;

A can be identical or different, represents 1-6 carbon atom, the linearity of preferred 2 or 3 carbon atoms or branched-alkyl, or the hydroxyalkyl of 1-4 carbon atom;

R ₄, R ₅And R ₆Can be identical or different, expression contains the alkyl or the benzyl of 1-18 carbon atom, preferably contains the alkyl of 1-6 carbon atom;

R ₁And R ₂Can be identical or different, expression hydrogen or contain the alkyl of 1-6 carbon atom, preferable methyl or ethyl;

X represents by the inorganic or deutero-anion of organic acid, for example methylsulfate anion or halogen chlorine or bromine for example.

The copolymer of family (1) can also contain one or more unit by comonomer-derived, this comonomer can be selected from acrylamide, Methacrylamide, N-[2-(2-methyl-4-oxopentyl), on nitrogen-atoms by rudimentary (C ₁-C ₄) AAM and Methacrylamide, acrylic or methacrylic acid or their ester, the vinyl lactam family of vinyl pyrrolidone or caprolactam and vinyl esters for example.

Therefore, in those polymer of family (1), can mention:

-with the copolymer of dimethyl sulfate or quaternised acrylamide of dimethyl halogenide and dimethylaminoethyl acrylate methyl base amino-ethyl ester, the product of selling by Hercules company with the trade name of Hercofloc for example,

-for example at described in the patent application EP-A-080 976 and the acrylamide that sell by Ciba Geigy company with the trade name of Bina Quat P100 and the copolymer of methacryloxyethyl trimethyl ammonium chloride;

-the acrylamide sold by Hercules company with the trade name of Reten and the copolymer of methylsulfuric acid methacryloxyethyl trimethyl ammonium,

-quaternized or on-quaternised vinyl pyrrolidone/acrylic or methacrylic acid dialkyl aminoalkyl ester copolymer.These polymer have a detailed description in French Patent (FRP) 2 077 143 and 2 393 573,

-dimethylaminoethyl acrylate methyl base amino-ethyl ester/caprolactam/vinyl pyrrolidone terpolymer,

-vinyl pyrrolidone/methacryl amido propyl-dimethyl amine copolymer and

-quaternized vinyl pyrrolidone/dimethylaminopropyl methacrylamide copolymer.

(2) cationic polysaccharide, especially cationic cellulose and cationic galactomannan glue.More specifically the cationic polysaccharide that can mention is the cellulose ether derivative that comprises quaternary ammonium group, cationic cellulose copolymer or with grafted cellulose derivative of water solublity quaternary ammonium monomer and cationic galactomannan glue.

The cellulose ether derivative that comprises quaternary ammonium group is stated in French Patent (FRP) 1 492 597.These polymer also are defined as the epoxide reactive hydroxyethyl-cellulose quaternary ammonium that replaces with the trimethyl ammonium in the CTFA dictionary.

Cationic cellulose copolymer or especially be described among the patent US 4 131 576 with the grafted cellulose derivative of water solublity quaternary ammonium monomer; such as especially using the methacryl ethyl trimethyl ammonium; methacryl amido oxypropyl trimethyl ammonium or the grafted hydroxy alkyl cellulose of dimethyldiallylammonium salt, for example methylol-, ethoxy-or hydroxypropyl cellulose.

Cationic galactomannan glue, the guar gum that especially contains the trialkyl ammonium cation group more specifically is described in patent US 3 589 578 and 4 031 307.For example use with 2 the guar gum of the salt of 3-glycidyl trimethyl ammonium (for example chloride) modification.

(3) by piperazinyl units with contain the divalent alkyl of the optional straight or branched that has inserted oxygen, sulfur or nitrogen-atoms or aromatic ring or hetero-aromatic ring or the polymer that hydroxy alkylidene is formed, and the oxidation of these polymer and/or quaternized products.This base polymer is especially stated in French Patent (FRP) 2 162025 and 2 280 361.

(4) the water-soluble poly amino amides of the preparation of the polycondensation by acid compound and polyamine especially; These polychlorostyrene base amide can be used epihalohydrins, diepoxide, dicarboxylic anhydride, unsaturated dicarboxylic anhydride, two-unsaturated derivant, two-halohydrin, two-azetidine , two-halo acyl group diamidogen, two-alkyl halide is crosslinked, perhaps uses by the oligomer that can obtain with the reaction of difunctional's compound of two-halohydrin, two-azetidine , two-halo acyl group diamidogen, two-alkyl halide, epihalohydrins, diepoxide or two-unsaturated derivatives reaction crosslinked; This cross-linking agent uses with the ratio of the amido of 0.025-0.35mol/ polyaminoamide; These polyaminoamides can alkylation, if perhaps they contain one or more tertiary amine functional group, they can be quaternized.This base polymer especially is described in French Patent (FRP) 2 252 840 and 2 368 508.

(5) by polyalkylene polyamine and polycarboxylic acid condensation, the polyaminoamide derivant that is obtained with difunctional's agent alkylation subsequently.For example, can mention adipic acid/dialkyl amido hydroxyalkyl two alkylene triamine polymer, wherein this alkyl contains 1-4 carbon atom and preferred expression methyl, ethyl or propyl group.This base polymer is especially stated in French Patent (FRP) 1 583 363.

In these derivants, more specifically can mention adipic acid/dimethylamino hydroxypropyl/diethylenetriamines polymer of selling by Sandoz company with the title of " Cartaretine F, F4 or F8 ".

(6) polyalkylene polyamine by containing two primary amine groups and at least one secondary amine group be selected from Acetic acid,oxo-,monohydrate and have the polymer of the reaction acquisition of the dicarboxylic acids in the radical of saturated aliphatic dicarboxylic acids of 3-8 carbon atom.The mol ratio of polyalkylene polyamine and dicarboxylic acids is 0.8: 1 to 1.4: 1; Thus obtained polyaminoamide and chloropropylene oxide are with the molar ratio reaction of the secondary amine group of 0.5: 1 to 1.8: 1 chloropropylene oxide and polyaminoamide.This base polymer especially is described in US patent 3 227 615 and 2 961 347.

This base polymer is especially sold (under the situation of adipic acid/glycidyl/diethylenetriamines copolymer) with the trade name of " Hercosett57 " by Hercules Inc. company.

(7) cyclocopolymer of cyclopolymers of alkyldiallylamine or dialkyl diallyl ammonium, such as containing corresponding to the unit of formula (I) or (I ') copolymer as the main component of chain:

In following formula, k and t equal 0 or 1, and the summation of k+t equals 1; R ₁₂Expression hydrogen atom or methyl; R ₁₀And R ₁₁Expression has the alkyl of 1-6 carbon atom independently of one another, and wherein alkyl preferably has the hydroxyalkyl of 1-5 carbon atom, rudimentary C ₁-C ₄Amido alkyl, perhaps R ₁₀And R ₁₁Can represent that heterocyclic group is such as piperidyl or morpholinyl with the nitrogen-atoms that they connected; Y ^-Be anion ratio such as bromine root, chlorine root, acetate, borate, citrate, tartrate anion, bisulfate ion, bisulfite, sulfate radical or phosphate radical.These polymer especially are described in French Patent (FRP) 2 080 759 and the certificate of addition 2 190 406 thereof.

R ₁₀And R ₁₁Preferred independently of one another expression contains the alkyl of 1-4 carbon atom.

In the polymer of above definition, more specifically can mention the dimethyl diallyl ammonium chloride homopolymer (and analog of lower molecular wt) sold by Nalco company with the title of " Merquat100 " and the copolymer of diallyldimethylammonium chloride and acrylamide chlorination thing.

(8) contain two quaternary ammonium polymers corresponding to the repetitive of following formula:

In formula (II):

R ₁₃, R ₁₄, R ₁₅And R ₁₆Can be identical or different, expression contains the aliphatic series of 1-20 carbon atom, alicyclic or araliphatic group, or rudimentary hydroxyalkyl aliphatic group, perhaps R ₁₃, R ₁₄, R ₁₅And R ₁₆The nitrogen-atoms that is connected with them constitutes and chooses the heterocycle that contains second non-nitrogen heteroatom, perhaps R wantonly together or separately ₁₃, R ₁₄, R ₁₅And R ₁₆Expression is by nitrile, ester, acyl group or amide group or group-CO-O-R ₁₇-D or-CO-NH-R ₁₇Linearity or branching C that-D replaces ₁-C ₆Alkyl, wherein R ₁₇Be that alkylidene and D are quaternary ammonium groups;

A ₁And B ₁Expression contains the polymethylene of 2-20 carbon atom, this group can be linear and branching, saturated or undersaturated, and can contain a pair of or a plurality of aromatic rings or one or more oxygen or sulphur atom or the sulfoxide that is connected in main chain or inserts in main chain, sulfone, disulphide, amino, alkyl amino, hydroxyl, quaternary ammonium, urea groups, amide or ester group and

X ^-Expression is by the inorganic or deutero-anion of organic acid;

A ₁, R ₁₃And R ₁₅Can form piperazine ring with two nitrogen-atoms that they connected; In addition, if A ₁Expression linearity or branching, saturated or unsaturated alkylene or hydroxy alkylidene, B ₁Can also represent group (CH ₂) _n-CO-D-OC-(CH ₂) _n-,

Wherein D represents:

A) diol residue of formula-O-Z-O-, wherein Z represents linearity or branching hydro carbons group or corresponding to the group of one of following formula:

-(CH2-CH2-O)x-CH2-CH2-

-[CH2-CH(CH3)-O]y-CH2-CH(CH3)-

Wherein x and y are the integers of the 1-4 of the clear and definite and unique degree of polymerization of expression, or any numerical value of the 1-4 of expression average degree of polymerization;

B) two-secondary diamine residue is such as bridged piperazine derivatives;

C) two-primary diamines the residue :-NH-Y-NH-of following formula, wherein Y represents linearity or branching hydro carbons group, perhaps divalent group-CH ₂-CH ₂-S-S-CH ₂-CH ₂-;

D) urylene of formula-NH-CO-NH-.

Preferably, X ^-Be anion ratio such as chlorine or bromine.

These polymer generally have the number-average molecular weight of 1000-100000.

This base polymer especially is described in French Patent (FRP)

2.320.330,2.270.846,2.316.271,2.336.434 and 2.413.907 and U.S. Pat 2.273.780,2.375.853,2.388.614,2.454.547,3.206.462,2.261.002,2.271.378,3.874.870,4.001.432,3.929.990,3.966.904,4.005.193,4.025.617,4.025.627 4.025.653 is among 4.026.945 and the 4.027.020.

More specifically can use the polymer of forming by corresponding to the repetitive of following formula:

R wherein ₁, R ₂, R ₃And R ₄Can be identical or different, expression contains the alkyl or the hydroxyalkyl of about 1-4 carbon atom, and n and p are the integers of about 2-20, and X ^-Be by mineral acid or the deutero-anion of organic acid.

A kind of chemical compound of especially preferred formula (a) is R wherein ₁, R ₂, R ₃And R ₄Expression methyl and n=3, the chemical compound of p=6 and X=Cl, according to INCI (CTFA) nomenclature, it is called as the own dimethylamine of chlorination.

(9) comprise the unitary polyquaternary amine polymer of formula (III):

In the formula:

R ₁₈, R ₁₉, R ₂₀And R ₂₁Can be identical or different, expression hydrogen atom or methyl, ethyl, propyl group, beta-hydroxyethyl, β-hydroxypropyl or-CH ₂CH ₂(OCH ₂CH ₂) _pThe OH group,

Wherein p equals 0 or the integer of 1-6, and prerequisite is R ₁₈, R ₁₉, R ₂₀And R ₂₁Do not represent hydrogen atom simultaneously,

R and s can be identical or different, are the integers of 1-6,

Q equals 0 or the integer of 1-34,

X ^-Expression anion ratio such as halogen,

A represents dihalide group or preferred expression-CH ₂-CH ₂-O-CH ₂-CH ₂-.

This compounds especially is described among the patent application EP-A-122324.

In these products, for example, can mention the product Mirapol  A15 that sells by Miranol company, Mirapol  AD1, Mirapol  AZ1 and Mirapol  175.

(10) quaternary ammonium polymer of vinyl pyrrolidone and vinyl imidazole, for example with Luviquat  FC905, the product that the title of FC550 and FC370 is sold by BASF AG.

(11) crosslinked methacryloxy (C ₁-C ₄) alkyl three (C ₁-C ₄) the alkylammonium salt polymer, such as the polymer that obtains by homopolymerization with the quaternised dimethylaminoethyl acrylate methyl base of methyl chloride amino-ethyl ester, or by the polymer of acrylamide with the copolymerization acquisition of using the quaternised dimethylaminoethyl acrylate methyl base of methyl chloride amino-ethyl ester, be that especially methylene-bisacrylamide is crosslinked with the chemical compound that contains ethylenic unsaturated bond after this homopolymerization or the copolymerization.

Other cationic polymer that can use in the present invention is cationic protein or cationic protein hydrolyzate, polyalkyleneimine, especially polyethyleneimine: amine, contain vinylpyridine or the unitary polymer of vinylpyridine , the condensation substance of polyamine and chloropropylene oxide, quaternized polyureas and chitin derivatives, especially chitosan or their salt.

Especially operable salt is the acetic acid chitosan, lactic acid chitosan, glutamic acid chitin, gluconic acid chitin or 2-pyrrolidone-5-carboxylic acid's chitin.

In these chemical compounds, can mention the chitin of deacetylation, perhaps 2-pyrrolidone-5-carboxylic acid's chitin of selling by Amerchol with the title of Kytamer  PC with 90wt%.

In can be used for all cationic polymers of the present invention, the preferred cation cyclic polymer that uses, especially with Merquat100, dimethyl diallyl ammonium chloride homopolymer or copolymer that the title of Merquat550 and Merquat S is sold by Nalco company, the quaternary ammonium polymer of vinyl pyrrolidone and vinyl imidazole, methacryloxy (C ₁-C ₄) alkyl three (C ₁-C ₄) cross-linked homopolymer of alkylammonium salt or copolymer and 2-pyrrolidone-5-carboxylic acid's chitosan of selling by Amerchol with the title of Kytamer  PC, and their mixture.

According to the present invention, cation or amphiphilic polymers can account for the 0.001-20wt% of the gross weight of final composition, preferably 0.01-10wt% and more specifically 0.02-5wt%.

According to a preferred embodiment of the invention, these compositionss can also comprise at least a siloxanes.

As the siloxanes that can in compositions of the present invention, use, especially can mention siloxanes volatility as described below or nonvolatile, ring-type or acyclic, branching or non-branching, organic group modification or non-organic group modification.

Siloxanes that can be used according to the invention can be solvable or insoluble in said composition, especially can be the poly-organopolysiloxane that is insoluble to compositions of the present invention; They can be the form of oil, wax, resin or sizing material.

According to the present invention, these siloxanes all can non-modified forms or are used with the form of solution, dispersion, emulsion, nanoemulsions or microemulsion.

Organopolysiloxane is at Walter Noll, specific definition among Chemistry and Technology ofSilicones (1968) the Academic Press.They can be volatile or nonvolatile.

When they when being volatile, it is those of 60-260 ℃ that these siloxanes more specifically are selected from boiling point, also more specifically is selected from:

(i) contain the annular siloxane of 3-7 and preferred 4-5 silicon atom.They for example are the octamethylcy-clotetrasiloxanes of especially being sold by Union Carbide with the title of Volatile Silicone7207 or sold by Rhodia with the title of Silbione70045V2, decamethylcyclopentaandoxane that sell by Union Carbide with the title of VolatileSilicone7158 and that sell by Rhodia with the title of Silbione70045V5, and their mixture.

Can also mention the cyclocopolymer of dimethyl siloxane/methyl alkyl siloxane class, for example have the Volatile Silicone FZ3109 by the sale of Union Caride company of following chemical constitution:

Can also mention the mixture of annular siloxane and organo-silicon compound, the for example mixture of octamethylcy-clotetrasiloxane and four-trimethyl silyl tetramethylolmethane (50/50) and octamethylcy-clotetrasiloxane and oxygen-1,1 '-two (2,2,2 ', 2 ', 3,3 '-six trimethylsiloxy) mixture of neopentane.

(ii) contain 2-9 silicon atom and have under 25 ℃ and be less than or equal to 5 * 10 ^-6m ²The linear volatile siloxane of the viscosity of/s.An example is the decamethyl tetrasiloxane of especially being sold by Toray Silicone with the title of SH200.The siloxanes that belongs to this class is also at Cosmetics and Toiletries, and the 19th rolls up Jan.76,27-32 page or leaf, Todd﹠amp; State in the disclosed article among the Byers " Volatile Silicone Fluids for Cosmetics ".

Non-volatile siloxane, more specifically poly-alkylsiloxane, poly-aryl siloxanes, poly-alkaryl siloxanes, silicone rubber compounds and resin are preferred uses with the poly-organopolysiloxane and their mixture of organo-functional group modification.

These siloxanes more specifically are selected from poly-alkylsiloxane, and wherein mainly can mention 25 ℃ of following viscosity is 5 * 10 ^-6To 2.5m ²/ s and preferred 1 * 10 ^-5To 1m ²The polydimethylsiloxane that contains trimethylsilyl end groups of/s.The viscosity of these siloxanes is for example measured according to ASTM standard 445 appendix C under 25 ℃.

In these poly-alkylsiloxanes, can not be with and restrictedly mention following commodity:

The Silbion oil or the Mirasil oil of-47 and 70047 series of selling by Rhodia, for example oily 70047V500000;

The oil of-Mirasil the series of selling by Rhodia company;

The oil of-200 series of being sold by Dow Corning company, more specifically, for example viscosity is 60000mm ²The DC200 of/s;

-come from the Viscasil oil of General Electric and come from the SF series of General Electric oil (SF96, SF18).

Can also mention the polydimethylsiloxane that contains dimethyl silane alcohol end group, name is called dimethiconol (CTFA title), for example originates from the oil of 48 series of Rhodia company.

In this birdss of the same feather flock together alkylsiloxane, can also mention the product of selling by Goldschmidt company with the title of Abil Wax9800 and 9801, they are poly-(C ₁-C ₂₀) alkylsiloxane.

Poly-alkaryl siloxanes especially is selected to have at 25 ℃ following 1 * 10 ^-5To 5 * 10 ^-2m ²The linearity of the viscosity of/s and/or branching poly dimethyl methyl phenyl siloxane and poly dimethyl diphenyl siloxane.

In these poly-alkaryl siloxanes, for example can mention the product of selling with following trade name:

Originate from the Silbione oil of 70641 series of Rhodia;

Originate from the Rhodorsil70633 of Rhodia and the oil of 763 series;

Originate from the silicone oil Dow Corning556 cosmetics-stage oil of Dow Corning;

Originate from the siloxanes of the PL series of Bayer, for example product P K20;

Originate from the PN of Bayer and the siloxanes of PH series, for example product P N1000 and PH1000;

Originate from some oil of the SF series of General Electric, for example SF1023, SF1154, SF1250 and SF1265.

Silicone rubber compounds that can be used according to the invention especially separately or the poly-diorganosiloxane of the high number-average molecular weight of using in solvent as mixture with 200000-1000000.This solvent can be selected from volatile siloxane, polydimethylsiloxane (PDMS) oil, polyphenyl methyl siloxane (PPMS) oil, isoparaffin, polyisobutylene, dichloromethane, pentane, dodecane and tridecane, or their mixture.

More specifically can mention following product:

-polydimethylsiloxane,

-polydimethylsiloxane/methyl ethylene siloxane glue material,

-polydimethylsiloxane/diphenyl siloxane,

-polydimethylsiloxane/phenyl methyl siloxanes,

-polydimethylsiloxane/diphenyl siloxane/ethylene methacrylic radical siloxane,

Can product used according to the invention be mixture more specifically, for example:

By the polydimethylsiloxane of end of the chain hydroxylation or (CTFA) and also be called the mixture that the annular dimethyl polysiloxane of cyclomethicone (CTFA) forms, for example by the product Q2 1401 of Dow Corning company sale;

By the mixture that polydimethylsiloxane sizing material and annular siloxane form, for example originate from the product SF1214 silicone oil of General Electric company; This product is the SF30 sizing material corresponding to polydimethylsiloxane, has 500000 number-average molecular weight, is dissolved in the oily SF1202 silicone oil corresponding to decamethylcyclopentaandoxane;

The mixture of two kinds of PDMSs of different viscosities, the mixture of PDMS sizing material and PDMS oil more specifically for example originates from the product SF1236 of General Electric company.Product SF1236 is the 20m that has of above definition ²The SE30 sizing material of the viscosity of/s and have 5 * 10 ^-6m ²The mixture of the SF96 oil of the viscosity of/s.This product preferably contains 15%SE30 sizing material and 85%SF96 oil.

Can organopolysiloxane used according to the invention be the crosslinking silicone system that contains the following units:

R ₂SiO _2/2, R3SiO _1/2, RSiO _3/2And SiO _4/2, wherein R represents to contain the hydro carbons group or the phenyl of 1-16 carbon atom.In these products, especially preferred those are that wherein R represents C ₁-C ₄Low alkyl group, the product of more specifically methyl, or phenyl.

In these resins, can mention product of selling with the title of Dow Corning593 or those products of being sold by General Electric company with the title of Silicone Fluid SS4230 and SS4267, they are siloxanes of dimethyl/trimethicone structure.

Can also mention especially with X22-4914 the trimethylsiloxy silicate class resin that the trade name of X21-5034 and X21-5037 is sold by Shin-Etsu company.

Organic group modified siloxane that can be used according to the invention is the siloxanes that comprises the one or more organo-functional groups that connect via the hydro carbons group in their structure as above definition.

In the organic group modified siloxane, can mention the poly-organopolysiloxane that contains following group:

-optional the C that contains ₆-C ₂₄The polyethylene glycol oxide of alkyl and/or polypropylene oxide group, for example product of selling by Dow Coring company with the DC1248 title that is called dimethicone copolyol or the oily Silwet  L722 that sells by Union Carbide company, L7500, L77 and L711, and the poly-(C that sells by Dow Corning company with the trade name of Q2 5200 ₁₂) the alkyl methyl silicone copolyol;

-replace or unsubstituted amido the product of selling by Genesee company with the trade name of GP 4 Siliocone Fluid and GP7100 for example, or the product of selling by Dow Corning company with the trade name of Q2 8220 and Dow Corning929 or 939.The amido that replaces is C especially ₁-C ₄Aminoalkyl;

-thiol group, for example product of selling by Genesee with the trade name of GP72A and GP71;

-alkoxylate group, the product of for example selling by SWSSilicones and sell by Goldschmidt company with the trade name of Abil Wax  2428,2434 and 2440 with the title of silicone copolymers F-755;

-hydroxylating group is for example at the poly-organopolysiloxane that contains hydroxyalkyl functional group described in the french patent application FR-A-85/16334;

-acyloxy alkyl is for example at the poly-organopolysiloxane described in the patent US-A-4 957 732;

The anionic group of-carboxylic acid type, for example at the product that originates from Chisso Corporation company described in the patent EP 186 507, the perhaps anionic group of alkyl carboxylic acid class for example is present among the product X-22-3701E that comes from Shin-Etsu company those; 2-hydroxyalkylated sulfonic acid root, 2-hydroxyalkyl thiosulfate anion, for example product of selling by Goldschmidt company with the trade name of Abil  S201 and Abil  S255;

-hydroxy amide base is for example at the poly-organopolysiloxane described in the patent application EP 342 834.For example can mention the product Q2-8413 that originates from Dow Corning company.

Above-mentioned siloxanes can use with the 0.01-20wt% of composition total weight and the amount of preferred 0.1-5wt% separately or as mixture.

Can also comprise the composition that is generally used for cosmetics according to compositions of the present invention, vitamin for example, aromatic, Concha Margaritifera, thickening agent, the polymer except polymer with PEG group, gellant, trace element, softening agent, sequestering agent, aromatic, acidulant or basifier, antiseptic, sunscreen, antioxidant, anti-alopecia agent, dandruff removing agent, free radical scavenger and ceramide or their mixture.Much less, those skilled in the art can careful select one or more other optional chemical compounds, and/or their amount, make expection interpolation not adverse effect or basically not adverse effect according to the advantageous property of compositions of the present invention.

Advantageously, the pH that selects compositions of the present invention is 2-11, preferred 3-10, for example 5-8.

Can comprise propellant according to compositions of the present invention.This propellant is liquefaction or one of Compressed Gas and their mixture that is generally used for preparing aerosol composition.Air, carbon dioxide, compressed nitrogen or the soluble gas for example mixture of dimethyl ether, halogenation (especially fluoridizing) hydro carbons or non-halogenated hydro carbons and they are preferred uses.

Said composition especially can advantageously be applied to the hair care field, especially keeps hair style or makes Hair styling.The preferably shampoo of described Haircare composition, hair conditioner, hair styling gel or washing liquid dry up washing liquid or Hairstyling composition and for example spray paint or spray.Described compositions can be packed by various forms, especially disperses bottle or aerosol container inner packing at bottle, aerosol apparatus, pump, so that can use with vaporization form or mousse form for compositions.

In a preferred embodiment, can be used for washing keratin material for example hair, skin, eyelashes, eyebrow, fingernail, lip or scalp, more specifically hair according to compositions of the present invention.

According to compositions of the present invention can be for example shampoo of composition of detergent, shower gels and foam bath.In this embodiment of the present invention, described compositions comprises based at least a anion of the 4wt% at least of composition total weight and/or nonionic surfactant for washing.

Therefore a theme of the present invention also is for example method of skin or hair of processing angle protein material, be characterised in that it comprise with as the cosmetic composition of above definition be applied to keratin material, optional then water flushing.

Therefore, the method according to this invention can keep hair style, nursing and washed skin, hair or any other keratin material, or from skin, hair or any other keratin material, remove ornaments and formal dress.

In a further preferred embodiment, compositions of the present invention can be for using afterflush type or conservative hair conditioner form, perhaps be form with afterflush type compositions, in any hair treatment, especially dye, before or after bleaching, long-acting curly hair or the loose hair, perhaps between two steps of long-acting curly hair or the loose operation of hair, use.

When said composition was the form of the optional hair conditioner that rinses out, it advantageously contained at least a cationic surfactant, and for example concentration is generally the 0.1-10wt% of the gross weight of compositions, preferred 0.5-5wt%.

Compositions of the present invention can also be the form of skin with cleaning compositions, especially bathe with or shower with solution or gel, or the form of makeup removing product.

Can also be the water lotion that is used for skin nursing and/or hair nursing or the form of water-pure washing liquid according to compositions of the present invention.

According to compositions of the present invention, after being applied to human hair and scalp, rinsing out after can in officely where managing or keep.It can be any form that is generally used for described field, for example is the form of thicker or not too condensed washing liquid, gel, frost, spray or mousse.Said composition can be single-phase or heterogeneous compositions.

According to a preferred embodiment of the invention, said composition can be used as shampoo.

When compositions according to the present invention is used as the standard hair conditioner, their simple application are sent out in wetting, then, after optional action time, remove the foam that is produced by with hands massage or friction by the water flushing, this operation can repeat one or many.

Below describe compositions of the present invention in an embodiment in detail.

The measurement of Tg

The aqueous solution that use contains the polymer of 6wt% prepares thin film, under 50% relative humidity and 25 ℃ under controlled atmospher dry 48 hours.The thin film of Huo Deing has the thickness of 10-20 μ m like this.

This measuring device is DSC (TA Instruments).

To place in the airtight crucible by the sample that this thin film obtains, according to following programmed heating:

-balance under initial temperature Ti;

-heating 1: with the speed of+10 ℃/min with temperature be elevated to final temperature Tf (℃);

-constant temperature 1 minute;

-with the speed of-10 ℃/min with temperature be reduced to Ti (℃);

-heating 2: with the speed of+10 ℃/min with temperature be elevated to Tf (℃);

-constant temperature 1 minute,

Ti wherein: initial temperature-120 ℃

Tf: final temperature+120 ℃.

The Tg value is at heating steps 1 and 2 period detectings.

The mensuration of water absorption rate

The dry polymer of about 1g is put into the aluminum crucible (0.01m of diameter 4.5cm ²) in.With its baking oven inner drying 48 hours under 60 ℃ and decompression.Take crucible away, (taking away from baking oven within back 1 minute) immediately weighs.Obtain W1.

Crucible is put in the glove box with set relative humidity (75%HR or 85%HR) then, kept therein 6 hours.Them weigh immediately once more after from glove box, taking out then.Obtain W2.

Calculate water absorption rate in the following manner:

[(W2-W1)×100]/W1

Preparation embodiment 1

The methyl ethyl ketone (MEK) of 75ml is put in the reactor (four neck flasks) that two charging hoppers, condenser and mechanical agitators have been installed, and be heated to 80 ℃.

Simultaneously, preparation comprises the polyethylene glycol methacrylate-styrene polymer (MPEG550) of monomer: 50g, the solution 1 of the dimethylaminopropyl Methacrylamide (DMAPMA) of 50g and (Trigonox21S) of initiator: 0.5g.Also prepare solution 2, comprise the methyl ethyl ketone of 75ml and the initiator of 0.5g (Trigonox21S).

Through 1 hour solution 1 is splashed in the four neck flask reactors, splashed into solution 2 through 2 hours.The gained mixture kept 5 hours down at 80 ℃ then.With the orange-yellow solution cooling that is obtained.Obtain the polymer of 95g.

This polymer has the brookfield viscosity of 7.5mPa.s, this viscosity under 25 ℃, with No. 1 pin core barrel, under the speed of 0.1rpm to the 15%MEK measured in solution of this polymer.

This polymer can neutralize then in the following manner: under agitation the 1N HCl of 290ml is joined in the distilled water of the polymer of 95g and 200ml.Solvent evaporated (MEK) then.

Should neutral polymer (reaching 50wt% at least) soluble in water.Its Tg is-60 ℃.

Neutral polymer has 51% water absorption rate under 85% HR.

Preparation embodiment 2

The water of 100ml is put in the reactor (four neck flasks) that two charging hoppers, condenser and mechanical agitators have been installed, and be heated to 80 ℃.

Simultaneously, preparation comprises 50g monomer M PEG550, the solution 1 of the initiator of 1g (potassium peroxydisulfate KPS) and 50ml water.

Also preparation comprises the garden beet alkali salt hydrochlorate 100% neutral monomer DMAPMA of 50g and the solution 2 of 50g water.

Through 1 hour solution 1 and 2 is splashed in the four neck flasks.At 80 ℃ after following 1 hour, with splashing into the mixture of 1g KPS in 50ml water in 15 minutes.

The gained mixture kept 3 hours down at 80 ℃ then.Obtain the neutral polymer of garden beet alkali salt hydrochlorate of 90g.

This polymer has the brookfield viscosity of 164mPa.s, this viscosity under 25 ℃, with No. 1 pin core barrel, under the speed of 6rpm to 15% determination of aqueous solution of this polymer.

(reach 50wt% at least) in this polymer water soluble.

Its Tg is-60 ℃.

Neutral polymer has 90% water absorption rate under 85% HR.

Preparation embodiment 3-17

According to the method (solvent method) of embodiment 1 or the method (water method) of embodiment 2

The following polymer of preparation according to polymer of the present invention or Comparative Examples.

Embodiment	Monomer	Method and neutralization	Dissolubility
				Embodiment 3	10％MPEG550 90％DMAPMA	Method 1 HCl	Water
Embodiment 4	25％MPEG1100 75％DMAPMA	Method 1 HCl	Water
				Embodiment 5	50％MPEG1100 50％DMAPMA	Method 1 HCl	Water
Embodiment 6	50％MPEG550 50％DMAPMA	Method 1 HCl	Water
				Embodiment 7	50％MPEG550 50％SPE	Method 2 does not neutralize	Water
Embodiment 8	50％MPEG550 50％DMAEMA	Method 1 HCl	Water
				Embodiment 9	5,0%M,PEG,550 50% methacrylic acid morpholino ethyl ester	Method 1 HCl	Water
Embodiment 10	50％MPEG2000 50％DMAPMA	Method 2 does not neutralize	Water
				Embodiment 11	50％MPEG550 50％DMAPMA	Method 1 beet alkali hydrochlorate	Water
Embodiment 12	40％MPEG550 50％DMAPMA 10％EEMA	Method 1 HCl	Water
				Embodiment 13	40%MPEG550 50%DMAPMA 10% 2-(Acryloyloxy)ethanol	Method 2 HCl	Water

Embodiment 14	40%MPEG550 50%DMAPMA 10% vinyl pyrrolidone	Method 1 HCl	Water
				Embodiment 15	40%MPEG550 35%DMAPMA 15% acrylic acid	Method 1 HCl	Water
Embodiment 16	4,0%M,PEG,550 10% methacrylic acid tetrahydro furfuryl ester 50%DMAPMA	Method 1 HCl	Water
				Embodiment 17	4,0%M,PEG,550 10% caprolactam 50%DMAPMA	Method 1 HCl	Water
Embodiment 18	50％MPEG550 50％DMAPMA	Method 1 behenic acid	Can be scattered in the water
				Embodiment 19	50％MPEG550 50％DMAPMA	Method 1 oleic acid	Can be scattered in the water
Embodiment 20	50％MPEG8000 50％DMAPMA	Method 1 post neutralization beet alkali hydrochlorate	Water
				Embodiment 21	25％MPEG5000 75％DMAPMA	Method 1 preneutralization beet alkali hydrochlorate	Water
Embodiment 22	50％MPEG4000 50％DMAPMA	Method 1 beet alkali hydrochlorate	Water
				Embodiment 23	20％MPEG8000 80％DMAPMA	Method 1 beet alkali hydrochlorate	Water

MPEG: polyethylene glycol methacrylate-styrene polymer (MW=550,1100 or 2000)

DMAPMA: dimethylaminopropyl Methacrylamide

SPE:N, N-dimethyl-N-(2-methacryloxyethyl)-N-(3-sulfopropyl) ammonium betanin

DMAEMA: dimethylaminoethyl acrylate methyl base amino-ethyl ester

EEMA: methacrylic acid ethoxyethyl group ester.

The embodiment of comparative polymer

1 preparation is not a following polymer of the present invention according to embodiment:

Comparative Examples 1 (hydrophobic additional monomer)	35%MPEG550 50%DMAPMA 15% acrylic acid ethyl hexyl ester	Method 1 HCl
			Comparative Examples 2 (cross linked polymer)	50%MPEG550 50%DMAPMA 1% butanediol dimethylacrylate	Method 1 HCl
Comparative Examples 3 (quaternary ammonium polymer)	50％MPEG550 50％TMEACL *

^*TMEACL: acrylic acid 2-(dimethylamino) ethyl ester, quaternized with methyl chloride.

The embodiment of compositions

Embodiment according to shampoo of the present invention

Below illustrate the present invention with non exhaustive property compositions.Following compositions is nonrestrictive.Percentage rate is represented by the weight percent of active material.

	Embodiment 20	Embodiment 21	Embodiment 22	Embodiment 23
					Sodium laureth sulfate [1]	8％AM	8％AM	8％AM	8％AM
Coco-Glucoside [2]	5％AM	5％AM	5％AM	5％AM
					Coco betaine [3]	2％AM	2％AM	2％AM	2％AM
Polyquaternary ammonium salt 10[6]	0.5％AM	-	-	0.5％AM
					DMAPMA/MPEG550 (50/50)[7]	0.5％AM	0.5％AM	0.5％AM	0.5％AM
Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	-	0.1％AM	-	-
					Polydimethylsiloxane [9]	-	2％AM	-	-
Polydimethylsiloxane [10]	-	-	2％AM	1.0％AM
					Coconut oleoyl amine MIPA[13]	-	-	1.5％AM	1.5％AM
Antiseptic	In right amount	In right amount	In right amount	In right amount
					Aromatic	In right amount	In right amount	In right amount	In right amount
Sodium hydroxide/citric acid	An amount of pH6	An amount of pH7	An amount of pH7	An amount of pH7
					Water	An amount of 100%	An amount of 100%	An amount of 100%	An amount of 100%

	Embodiment 24	Embodiment 25	Embodiment 26
				Sodium laureth sulfate [1]	8％AM	8％AM	8％AM
Coco-Glucoside [2]	5％AM	5％AM	5％AM
				Coco betaine [3]	2％AM	2％AM	2％AM
Polyquaternary ammonium salt 10[6]	-	-	-
				DMAPMA/MPEG 550 (50/50)[7]	0.5％AM	0.5％AM	0.5％AM
Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	0.2％AM	0.2％AM
				Polydimethylsiloxane [11]	2％AM	-	-
Amino-terminated polydimethylsiloxane [12]	-	2％AM	3％AM
				Coconut oleoyl amine MIPA[13]	1.5％AM	1.5％AM	1.5％AM
Antiseptic	In right amount	In right amount	In right amount
				Aromatic	In right amount	In right amount	In right amount
Sodium hydroxide/citric acid	An amount of pH7	An amount of pH7	An amount of pH7
				Water	An amount of 100%	An amount of 100%	An amount of 100%

[1]Texapon N 702(Cognis)

[2]Plantacare 818 UP(Cognis)

[3]Dehyton AB 30(Cognis)

[6]Ucar polymer JR400 LT(Amerchol)

[7] polymer of embodiment 11

[8]Jaguar C13S(Rhodla)

[9]Belsll DM300000(Wacker)

[10]Mirasll DM 500000(Rhodia)

[11]Dow Corning 200 fiuid 60000(DoW corning)

[12]Dow Corning 939 emulsion(Dow corning)

[13]Empllan CIS(Huntsman)

Composition	Embodiment 27	Embodiment 28	Embodiment 29	Embodiment 30
					Sodium laureth sulfate [1]	10％AM	10％AM	10％AM	10％AM
Lauryl polyoxyethylene (12) ether [16]	4％AM	4％AM	4％AM	4％AM
					Polyquaternary ammonium salt 10[6]	0.5％AM	-	-	0.5％AM
DMAPMA/MPEG550 (50/50)[7]	0.5％AM	0.5％AM	0.5％AM	0.5％AM
					Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	-	0.1％AM	-	-
Polydimethylsiloxane [9]	-	2％AM	-	-
					Polydimethylsiloxane [10]	-	-	2％AM	1％AM
Coconut oleoyl amine MIPA[13]	-	-	1.5％AM	1.5％AM
					Antiseptic	In right amount	In right amount	In right amount	In right amount
Aromatic	In right amount	In right amount	In right amount	In right amount
					Sodium hydroxide/citric acid	An amount of pH6	An amount of pH7	An amount of pH7	An amount of pH7
Water	An amount of 100%	An amount of 100%	An amount of 100%	An amount of 100%

Composition	Embodiment 31	Embodiment 32	Embodiment 33
				Sodium laureth sulfate [1]	10％AM	10％AM	10％AM
Lauryl polyoxyethylene (12) ether [16]	4％AM	4％AM	4％AM
				Polyquaternary ammonium salt 10[6]	0.5％AM	0.5％AM	0.5％AM
DMAPMA/MPEG550(50/50) [7]	0.5％AM	0.5％AM	0.5％AM
				Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	0.2％AM	0.2％AM	-
Polydimethylsiloxane [11]	2％AM	-	-
				Amino-terminated polydimethylsiloxane [12]	-	2％AM	3％AM
Coconut oleoyl amine MIPA[13]	1.5％AM	1.5％AM	1.5％AM
				Antiseptic	In right amount	In right amount	In right amount
Aromatic	In right amount	In right amount	In right amount
				Sodium hydroxide/citric acid	An amount of pH7	An amount of pH7	An amount of pH7
Water	An amount of 100%	An amount of 100%	An amount of 100%

Composition	Embodiment 34	Embodiment 35	Embodiment 36	Embodiment 37
					Lauryl polyoxyethylene (5) ether carboxylic acid [14]	6％AM	6％AM	6％AM	6％AM
Coco-Glucoside [2]	11％AM	11％AM	11％AM	11％AM
					Polyquaternary ammonium salt 10[6]	0.5％AM	-	-	0.5％AM
DMAPMA/MPEG550 (50/50)[7]	0.5％AM	0.5％AM	0.5％AM	0.5％AM
					Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	-	0.1％AM	-	-
Polydimethylsiloxane [9]	-	2％AM	-	-
					Polydimethylsiloxane [10]	-	-	2％AM	1.0％AM
Coconut oleoyl amine MIPA[13]	-	-	1.5％AM	1.5％AM
					Antiseptic	In right amount	In right amount	In right amount	In right amount
Aromatic	In right amount	In right amount	In right amount	In right amount
					Sodium hydroxide/citric acid	An amount of pH6	An amount of pH7	An amount of pH7	An amount of pH7
Water	An amount of 100%	An amount of 100%	An amount of 100%	An amount of 100%

Composition	Embodiment 38	Embodiment 39	Embodiment 40
				Lauryl polyoxyethylene (5) ether carboxylic acid [14]	6％AM	6％AM	6％AM
Coco-Glucoside [2]	11％AM	11％AM	11％AM
				Coco betaine [3]	2％AM	2％AM	2％AM
DMAPMA/MPEG550 (50/50)[7]	0.5％AM	0.5％AM	0.5％AM
				Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	0.2％AM	0.2％AM
Polydimethylsiloxane [11]	2％AM	-	-
				Amino-terminated polydimethylsiloxane [12]	-	2％AM	3％AM
Coconut oleoyl amine MIPA[13]	1.5％AM	1.5％AM	1.5％AM
				Antiseptic	In right amount	In right amount	In right amount
Aromatic	In right amount	In right amount	In right amount
				Sodium hydroxide/citric acid	An amount of pH7	An amount of pH7	An amount of pH7
Water	An amount of 100%	An amount of 100%	An amount of 100%

Composition	Embodiment 41	Embodiment 42	Embodiment 43
				Ammonium lauryl sulfate [15]	15％AM	15％AM	15％AM
Coco-Glucoside [2]	5％AM	5％AM	5％AM
				Polyquaternary ammonium salt 10[6]	-	-	-
DMAPMA/MPEG550 (5050)[7]	0.5％AM	0.5％AM	0.5％AM
				Guar gum hydroxypropyl-trimethyl ammonium chloride [8]	0.2％AM	0.2％AM
Polydimethylsiloxane [11]	2％AM	-	-
				Amino-terminated polydimethylsiloxane [12]	-	2％AM	3％AM
Coconut oleoyl amine MIPA[13]	1.5％AM	1.5％AM	1.5％AM
				Antiseptic	In right amount	In right amount	In right amount
Aromatic	In right amount	In right amount	In right amount
				Sodium hydroxide/citric acid	An amount of pH7	An amount of pH7	An amount of pH7
Water	An amount of 100%	An amount of 100%	An amount of 100%

[1]Texapon N 702(Cognis)

[2]Plantacare 818 UP(Cognis)

[3]Dehyton AB 30(Cognis)

[4]Tego bétalne F50(Goldshmldt)

[5]Miranol C 2M-conc.NP(Rhodia)

[6]Ucar polymer JR400 LT(Amerchol)

[7] polymer of preparation embodiment 11

[8]Jaguar C13S(Rhodia)

[9]Belsil DM 300000(Wacker)

[10]Mirasll DM 500000(Rhodia)

[11]Dow Corning 200 fluid 60000(Dow corning)

[12]Dow Corning 939 emulsion(Dow corning)

[13]Empilan CIS(Huntsman)

[14]AKYPO RLM 45 CA(Kao)

[15]EMPICOL AL 30/FL(Huntsman)

[16]REWOP AL 12(Goldshmidt)

DMAPMA/MPEG550 (50/50) polymer [7] can be replaced with the polymer of preparation embodiment 1-23.

Embodiment 44

Preparation comprises the compositions (wt%) of following ingredients:

-7.5% sodium laureth sulfate

-2.5% coco betaine amphoteric surfactant (coming from the DehytonAB30 of Cognis)

-5% cocoyl polyglucoside surfactant (coming from the Plantacare 818UP of Cognis)

The polymer of-1.5% embodiment 11

-qsp100% water.

The shampoo composite that is obtained provides good typing effect, is good especially to doing the beauty treatment performance of sending out.

Embodiment 45

Preparation comprises the compositions (wt%) of following ingredients:

-7.5% sodium laureth sulfate

-2.5% coco betaine amphoteric surfactant

-5% cocoyl polyglucoside surfactant

Among-1.5% the embodiment 18 and polymer

-qsp100% water.

The result compares (test is carried out with the compositions of the embodiment 44 of the polymer that comprises embodiment 11 with the compositions of the embodiment 45 of the polymer that comprises embodiment 18) in following table.

	The wet disentanglement of sending out	The wet flatness of sending out	Do and send out disentanglement	Gloss	Elastic force
						The compositions of embodiment 44	+++	+++	+++	+++	++
The compositions of embodiment 45	++++	++++		++++
						Tester (shampoo of DOP Chamomile)	++	++	++	++	0

Claims (49)

1. cosmetic composition is characterised in that it comprises in the acceptable water-bearing media of cosmetics:

I) at least a anion surfactant and at least a non-ionic surface active agent and

II) at least a olefin copolymer, by the weight percent based on total polymer weight, it comprises:

-a) monomer of one or more general formulas (I) of 10-60wt% and their salt:

Wherein:

-R ₁Be hydrogen atom or C _pH _2p+1The linearity of class or branching hydro carbons group, wherein p is the integer of 1-12, comprises end value;

-Z is selected from

-COO-,-CONH-,-CONCH ₃-,-OCO-,-O-,-SO ₂--CO-O-CO-or-CO-CH ₂-CO-; In divalent group;

-x is 0 or 1;

-R ₂Be that the saturated or unsaturated, optional of 1-30 carbon atom can comprise 1-18 hetero atom that is selected among O, N, S, F, Si and the P for aromatics, linear, branching or cyclic carbon back divalent group,

-m is 0 or 1;

-n is the integer of 3-300, comprises end value;

-R3 is a hydrogen atom, and perhaps the saturated or unsaturated, optional of 1-30 carbon atom can comprise 1-20 hetero atom that is selected among O, N, S, F, Si and the P for aromatics, linear, branching or cyclic carbon back group,

-b) at least a " cation basically " monomer or its salt of 40-90wt% is selected from:

(i) cationic monomer of one or more general formulas (IIa),

(ii) one or more general formulas (IIc) and ampholytic monomer (IId) and

(iii) the cationic monomer of one or more general formulas (IIa) and one or more are selected from the anionic monomer in those of maleic anhydride and/or general formula (IIb); And/or be selected from the mixture of the ampholytic monomer in general formula (IIc) and (IId) those with one or more:

Wherein:

-R ₁Be hydrogen atom or C _pH _2p+1The linearity of class or branching hydro carbons group, wherein p is the integer of 1-12, comprises end value; Preferred expression hydrogen or methyl, ethyl, propyl group or butyl;

-Z ' is selected from

-COO-,-CONH-,-CONCH ₃-,-OCO-or-O-,-SO ₂--CO-O-CO-or-CO-CH ₂Divalent group among the-CO-;

-x ' is 0 or 1, preferred 1;

-R ' ₂Be the saturated or unsaturated, optional of 1-30 carbon atom, can comprise 1-18 hetero atom that is selected among O, N, S, F, Si and the P for aromatics, linear, branching or cyclic carbon back divalent group;

-m ' is 0 or 1;

-X (among the general formula I Ia) is (a) formula-N (R ₆) (R ₇) or-P (R ₆) (R ₇) or-P ⁺R ₆R ₇R ₈Group, R wherein ₆, R ₇And R ₈Expression (i) hydrogen atom or (ii) contain 1-18 carbon atom independently of one another, can contain 1-10 be selected from heteroatomic linearity, branching or ring-type among O, N, S, F, Si and the P, saturated or undersaturated, choose wantonly and be the alkyl of aromatics; Or (iii) R ₆And R ₇Can form with nitrogen-atoms or phosphorus atoms and comprise 5,6,7 or 8 atoms altogether, especially 4,5 or 6 carbon atoms and/or 2-4 are selected from heteroatomic first among O, S and the N and saturatedly or undersaturated, optional are the ring of aromatics; Described first ring can with one or more other comprise 5,6 or 7 atoms separately, especially 4,5,6 or 7 carbon atoms and/or 2-4 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics;

Perhaps (b) X represents group-R ' 6-N-R ' 7-, wherein R ' 6 and R ' 7 form with nitrogen-atoms and comprise 5,6,7 or 8 atoms altogether, and especially 4,5 or 6 carbon atoms and/or 2-4 is selected from heteroatomic saturated or undersaturated, optional among O, S and the N and is the ring of aromatics; Described ring can with one or more other comprise 5,6 or 7 atoms separately, especially 4,5,6,7 or 8 carbon atoms and/or 2-4 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics;

-Y is selected from-COOH-SO ₃H ,-OSO ₃H ,-PO ₃H ₂With-OPO ₃H ₂In group;

-X ' ⁺Be-N ⁺(R ₆) (R ₇)-divalent group, R wherein ₆And R ₇Expression (i) hydrogen atom or (ii) contain 1-25 carbon atom independently of one another, can contain 1-20 be selected from heteroatomic linearity among O, N, S and the P, branching or cyclic, choose wantonly and be the alkyl of aromatics; Or (iii) R ₆And R ₇Can form with nitrogen-atoms and comprise 5,6,7 or 8 atoms altogether, especially 4,5,6 or 7 carbon atoms and/or 2-3 are selected from heteroatomic first among O, S and the N and saturatedly or undersaturated, optional are the ring of aromatics; Described first ring can with one or more other comprise 5,6,7 or 8 atoms separately, especially 4,5,6 or 7 carbon atoms and/or 2-3 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics;

-Y ' ^-Be to be selected from-COO ^-,-SO ₃ ^-,-OSO ₃ ^-,-PO ₃ ^2-With-OPO ₃ ^2-In group;

-R ' the 3rd, and 1-30 carbon atom saturated or unsaturated, optional for aromatics, linear, branching or cyclic carbon back divalent group can comprise 1-18 hetero atom that is selected among O, N, S, F, Si and the P;

-n ' is 1-100, and preferred 1-5 comprises end value;

-X " ⁺Be-N ⁺R ₆R ₇R ₈Divalent group, R wherein ₆, R ₇And R ₈Expression (i) hydrogen atom or (ii) contain 1-18 carbon atom independently of one another, can contain 1-5 be selected from heteroatomic linearity among O, N, S and the P, branching or cyclic, choose wantonly and be the alkyl of aromatics; Or (iii) R ₆And R ₇Can form with nitrogen-atoms and comprise 5,6 or 7 atoms altogether, especially 4,5 or 6 carbon atoms and/or 2-3 are selected from heteroatomic first among O, S and the N and saturatedly or undersaturated, optional are the ring of aromatics; Described first ring can with one or more other comprise 5,6 or 7 atoms separately, especially 4,5,6 or 7 carbon atoms and/or 2-3 are selected from heteroatomic saturated or undersaturated, optional among O, S and the N and condense for the ring of aromatics;

-c) the nonionic hydrophilic monomer of optional 0-50wt% if they exist with the amount that is greater than or equal to 10wt%, does not comprise acrylic acid methyl ester., methyl methacrylate and isopropyl acrylate.

2. compositions as claimed in claim 1 is characterized in that, in general formula (I), R1 represents hydrogen or methyl, ethyl, propyl group or butyl.

3. each described compositions of claim as described above is characterized in that in general formula (I), Z represents COO or CONH.

4. each described compositions of claim as described above is characterized in that, in general formula (I), and radicals R ₂Be selected from:

-alkylidene, methylene for example, ethylidene, propylidene, inferior normal-butyl, isobutylidene, the inferior tert-butyl group, inferior n-hexyl, inferior n-octyl, inferior dodecyl, inferior n-octadecane base, inferior n-tetradecane base or inferior n-docosane base;

-phenylene-C ₆H ₄-(ortho position, a position or para-position), optional being chosen wantonly contained 1-25 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P; Perhaps benzal-C ₆H ₄-CH ₂-, optional being chosen wantonly contained 1-8 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P;

The pyridine  group of-following formula:

Wherein R ' 1-R ' 4 can be identical or different, is selected from H and the optional individual heteroatomic C1-C12 alkyl that is selected among O, N, S, F, Si and the P of 1-8 that contains; R ' 1-R ' 4 especially can be methyl and/or ethyl;

-chemical formula

-CH ₂-CHOH-,-CH ₂-CH ₂-CHOH-,-CH ₂-CH ₂-CH (NH ₂)-,-CH ₂-CH (NH ₂)-,-CH ₂-CH ₂-CH (NHR ')-,-CH ₂-CH (NHR ')-,-CH ₂-CH ₂-CH (NR ' R ")-,-CH ₂-CH (NR ' R ")-,-CH ₂-CH ₂-CH ₂-NR '-,-CH ₂-O-CO-O-, CH ₂-CH ₂-O-CO-O-,-CH ₂-CO-O-,-CH ₂-CH ₂-CO-O-,-CH ₂-O-CO-NH-,-CH ₂-CH ₂-O-CO-NH-;-CH ₂-NH-CO-NH-or-CH ₂-CH ₂-NH-CO-NH-;-CH ₂-CH ₂-CH ₂-O-;-CH ₂-CH ₂The group of-CHR '-O-, wherein R ' and R " optional individual heteroatomic linearity or the branching C1-C22 alkyl that is selected among O, N, S, F, Si and the P of 1-12 that contain of expression;

-or the mixture of these groups.

5. each described compositions of claim as described above is characterized in that in general formula (I), n is 5-200, is more preferably 7-100, or even 9-50, include end value in all cases.

6. each described compositions of claim as described above is characterized in that, in general formula (I), and R ₃It is hydrogen atom; The succimide base, dimaleoyl imino, the  base, tosyl, triethoxysilane, phthalimide or-CH ₂-CH ₂The CN group; Or it is optional by optional individual benzyl or the phenyl that is selected from the heteroatomic C1-C12 alkyl replacement among O, N, S, F, Si and the P of 1-8 that contain; C1-C30 and especially C1-C22 or even the C2-C16 alkyl, optional contain 1-18 hetero atom that is selected among O, N, S, F, Si and the P;

Described benzyl, phenyl or alkyl can also comprise the functional group that is selected from the following functional group: the succimide base; Glutarate-succimide base; Glutarate; Dimaleoyl imino; The  base, benzoate; Tosyl; Triethoxysilane; Phthalimide; The sulfur ester; The benzotriazole carbonic ester; Butyraldehyde; Acetaldehyde diethyl acetal; Biotin; Phospholipid; Succinate; N-maloyl imines;

-SO ₃H ,-COOH ,-PO ₄,-NR5R6 and-N ⁺Functional group among the R5R6R7, wherein R5, R6 and R7 are independently from each other H and linearity, branching or ring-type C1-C18 alkyl, methyl especially, optional one or more hetero atoms or protecting group for example tertbutyloxycarbonyl or the 9-fluorenyl methoxy carbonyl of comprising.

7. each described compositions of claim as described above is characterized in that, the monomer of general formula (I) is selected from separately or as the following chemical compound of mixture:

-poly-(ethylene glycol) (methyl) acrylate;

-methyl gathers (ethylene glycol) (methyl) acrylate;

-alkyl gathers (ethylene glycol) (methyl) acrylate;

-phenyl gathers (ethylene glycol) (methyl) acrylate;

-following monomer:

Be characterised in that preferably 3-100 of n, 5-50 especially, or even 7-30, include end value in all cases.

8. each described compositions of claim as described above is characterized in that separately or the ratio of making preferred 30-50wt% exists.

9. each described compositions of claim as described above is characterized in that, at general formula (IIa), (IIb), (IIc) and/or (IId), and radicals R ' ₂Be selected from:

-alkylidene, methylene for example, ethylidene, propylidene, inferior normal-butyl, isobutylidene, the inferior tert-butyl group, inferior n-hexyl, inferior n-octyl, inferior dodecyl, inferior n-octadecane base, inferior n-tetradecane base or inferior n-docosane base;

-phenylene-C ₆H ₄-(ortho position, a position or para-position), optional being chosen wantonly contained 1-5 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and/or the P; Perhaps benzal-C ₆H ₄-CH ₂-, optional being chosen wantonly contained 1-5 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P;

-chemical formula

-CH ₂-O-CO-O-, CH ₂-CH ₂-O-CO-O-,-CH ₂-CO-O-,-CH ₂-CH ₂-CO-O-,-[(CH ₂) ₅-CO-O] _n-,-CH ₂-CH (CH ₃)-O-,-(CH ₂) ₂-O-,-CH ₂-O-CO-NH-,-CH ₂-CH ₂-O-CO-NH-;-CH ₂-NH-CO-NH-or-CH ₂-CH ₂-NH-CO-NH-,-CH ₂-CHOH-,-CH ₂-CH ₂-CHOH-,-CH ₂-CH ₂-CH (NH ₂)-,-CH ₂-CH (NH ₂)-,-CH ₂-CH ₂-CH (NHR ')-,-CH ₂-CH (NHR ')-,-CH ₂-CH ₂-CH (NR ' R ")-,-CH ₂-CH (NR ' R ")-,-CH ₂-CH ₂-CH ₂-NR '-,-CH ₂-CH ₂-CH ₂-O-;-CH ₂-CH ₂The group of-CHR '-O-, wherein R ' and R " optional individual heteroatomic linearity or the branching C1-C22 alkyl that is selected among O, N, S, F, Si and the P of 1-12 that contain of expression;

-or the mixture of these groups.

10. each described compositions of claim as described above is characterized in that, in general formula (IIa), is present in the R among the X ₆And R ₇Be selected from hydrogen and methyl, ethyl, propyl group, isopropyl, normal-butyl, the tert-butyl group, isobutyl group, octyl group, lauryl or stearyl.

11. the described compositions of each of claim is characterized in that as described above, in general formula (IIa), X is selected from pyridine radicals, indyl, isoindolinyl, imidazole radicals, imidazolinyl, piperidyl, pyrazolinyl, pyrazolyl, quinolyl, pyrazolinyl, pyridine radicals, piperazinyl, pyrrolidinyl, chinidine base, thiazolinyl, morpholinyl, guanidine radicals, the group in amidino groups or  class group and their mixture.

12. the described compositions of each of claim is characterized in that as described above, the monomer of general formula (IIa) is less than or equal to 2 with being selected from the 1ogP value, and is preferred-6 to 1 for example-8 to 2, especially-6 to 0 nertralizer; And/or with the logP value greater than 2, be preferably greater than or equal 2.5, especially greater than 3,3-15 particularly, or even the reagent neutralization of 3.5-10.

13. the described compositions of each of claim is characterized in that as described above, the monomer of general formula (IIa) is selected from separately or as the following chemical compound of mixture:

Dimethylaminopropyl (methyl) acrylamide, dimethyl aminoethyl (methyl) acrylamide, (methyl) acrylic acid diethylamino ethyl ester, (methyl) acrylic acid dimethyl aminoethyl ester, vinyl imidazole, vinylpyridine and (methyl) acrylic acid morpholino ethyl ester and following monomer:

14. the described compositions of each of claim is characterized in that as described above, described anionic monomer is selected from maleic anhydride, acrylic acid, methacrylic acid .beta.-methylacrylic acid, itaconic acid, fumaric acid, maleic acid, acrylic acid 2-carboxy ethyl ester (CH ₂=CH-C (O)-O-(CH ₂) ₂-COOH); Styrene sulfonic acid, 2-acrylamido-2-methyl propane sulfonic acid, vinyl benzoic acid, vinyl phosphoric acid, (methyl) acrylic acid sulfopropyl ester and their salt.

15. the described compositions of each of claim is characterized in that as described above, in general formula (IIc), and radicals X ' ⁺Be selected from pyridine radicals, indyl, isoindolinyl, imidazole radicals, imidazolinyl, piperidyl, pyrazolinyl, pyrazolyl, quinolyl, pyrazolinyl, pyridine radicals, piperazinyl, pyrrolidinyl, chinidine base, thiazolinyl, morpholinyl, guanidine radicals or amidino groups class group and their mixture.

16. the described compositions of each of claim is characterized in that as described above, at general formula (IIc) and/or (IId), R ' 3 is selected from:

-alkylidene, methylene for example, ethylidene, propylidene, inferior normal-butyl, isobutylidene, the inferior tert-butyl group, inferior n-hexyl, inferior n-octyl, inferior dodecyl, inferior n-octadecane base, inferior n-tetradecane base or inferior n-docosane base;

-phenylene-C ₆H ₄-(ortho position, a position or para-position), optional being chosen wantonly contained 1-5 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P; Perhaps benzal-C ₆H ₄-CH ₂-, optional being chosen wantonly contained 1-5 heteroatomic C1-C12 alkyl replacement that is selected among O, N, S, F, Si and the P;

-chemical formula

-CH ₂-O-CO-O-, CH ₂-CH ₂-O-CO-O-,-CH ₂-CO-O-,-CH ₂-CH ₂-CO-O-,-[(CH ₂) ₅-CO-O] _n-,-CH ₂-CH (CH ₃)-O-,-(CH ₂) ₂-O-,-CH ₂-O-CO-NH-,-CH ₂-CH ₂-O-CO-NH-;-CH ₂-NH-CO-NH-or-CH ₂-CH ₂-NH-CO-NH-,-CH ₂-CHOH-,-CH ₂-CH ₂-CHOH-,-CH ₂-CH ₂-CH (NH ₂)-,-CH ₂-CH (NH ₂)-,-CH ₂-CH ₂-CH (NHR ')-,-CH ₂-CH (NHR ')-,-CH ₂-CH ₂-CH (NR ' R ")-,-CH ₂-CH (NR ' R ")-,-CH ₂-CH ₂-CH ₂-NR '-,-CH ₂-CH ₂-CH ₂-O-;-[CH ₂-CH ₂-O] _n-and-[CH ₂-CH (CH ₃)-O] _n-,-CH ₂-CH ₂The group of-CHR '-O-, wherein R ' and R " optional individual heteroatomic linearity or the branching C1-C22 alkyl that is selected among O, N, S, F, Si and the P of 1-12 that contain of expression;

-or the mixture of these groups.

17. the described compositions of each of claim is characterized in that as described above, in general formula (IId), and X " ⁺Be selected from trimethyl ammonium; Triethyl ammonium; N, N-dimethyl-N-octyl group ammonium; N, N-dimethyl-N-lauryl ammonium group.

18. the described compositions of each of claim is characterized in that as described above, general formula (IIc) or monomer (IId) are selected from N, N-dimethyl-N-(2-methacryloxyethyl)-N-(3-sulfo group propyl group) ammonium betanin; N, N-dimethyl-N-(3-methacryl amido propyl group)-N-(3-sulfo group propyl group) ammonium betanin, 1-(3-sulfopropyl)-2-vinylpyridine  betanin and 2-methacryloxyethyl phosphocholine.

19. the described compositions of each of claim as described above, it is characterized in that, be selected from " cation basically " monomer under the situation of mixture of cation and/or ampholytic monomer and anionic monomer, weight in " cationic monomer and/or ampholytic monomer+anionic monomer " mixture is benchmark, described anionic monomer is preferably with 5-40wt%, especially 10-30wt%, more preferably the ratio of 15-25wt% exists.

20. the described compositions of each of claim is characterized in that as described above, should exist with the 45-80wt% of final polymer weight and the ratio of preferred 50-70wt% by " cation basically " monomer.

21. the described compositions of each of claim is characterized in that as described above, this additional nonionic hydrophilic monomer has-8 to 2, preferably is less than or equal to 1.5, especially is less than or equal to 1, particularly-7 to 1, or even-6 to 0 logP.

22. the described compositions of each of claim is characterized in that as described above, this additional nonionic hydrophilic monomer is selected from separately or as those of the general formula (III) of mixture:

Wherein:

-R ' ₁Be hydrogen or-CH ₃

-Z " be to be selected from

-COO-,-CONH-,-CONCH ₃-,-OCO-,-SO ₂,-CO-O-CO-,-CO-CH ₂-CO-or-divalent group among the O-; Preferred COO and CONH;

-x " be 0 or 1;

-R " be that 1-30 carbon atom saturated or undersaturated, optional be the linearity of aromatics, branching or cyclic carbon back group; can contain the individual hetero atom that is selected among O, N, S, F, Si and the P of 1-18, methyl especially, ethyl; propyl group; isopropyl, normal-butyl, isobutyl group; the tert-butyl group; phenyl, benzyl, perhaps chemical formula-CH ₂-CH ₂-CH ₂OH ,-CH ₂-CH ₂-OH ,-CH ₂-CH ₂-CH ₂The group of OH or furfuryl group.

23. the described compositions of each of claim as described above, it is characterized in that, this additional nonionic hydrophilic monomer is selected from: methyl methacrylate, acrylic acid methyl ester., ethyl methacrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, the methacrylic acid tetrahydro furfuryl ester, acrylic acid tetrahydro furfuryl ester, methacrylic acid 2-hydroxyl ethyl ester, acrylic acid 2-hydroxyl ethyl ester, the methacrylic acid ethoxy ethyl ester, acrylic acid ethoxyethyl group ester, N-N-isopropylacrylamide, N-isopropyl methyl acrylamide, N,N-DMAA, N, the N-dimethylmethacryl amide, vinyl acetate, methyl vinyl ether, ethyl vinyl ether, vinyl pyrrolidone, caprolactam, N-vinyl acetamide, Hydroxypropyl acrylate, the N-vinyl lactam, acrylamide, N methacrylamide, N, the N-DMAA, N-methyl-N-vinyl acetamide, N-vinyl formamide, N-methyl-N-vinyl formamide, vinyl alcohol (with the form copolymerization of vinyl acetate, hydrolysis then).

24. the described compositions of each of claim as described above, it is characterized in that, separately or as mixture should additional nonionic hydrophilic monomer with the 0.1-35wt% based on the gross weight of polymer, preferred 1-25wt%, 3-15wt% for example, or even the amount of 5-9.5wt% exist.

25. the described compositions of each of claim is characterized in that as described above, described copolymer is neutralized.

26. the described compositions of each of claim as described above, it is characterized in that, described copolymer neutralizes with the nertralizer that is selected from linearity, branching or cyclic aliphatic sour and/or unsaturated or the aromatic acid, and this nertralizer especially can contain 1-1000 carbon atom, a particularly 2-500 carbon atom; Contain the acid functional group at least one Bronsted meaning, especially one or more carboxylic acids, sulfonic acid and/or phosphonyl group; Can also comprise the hetero atom among one or more O of being selected from, N, Si, F and the P, for example with the form of hydroxyl.

27. the described compositions of each of claim is characterized in that as described above, this copolymer neutralizes with being selected from separately or as the nertralizer in the following chemical compound of mixture:

-contain 6-32 and 8-28 carbon atom especially, and contain at least one COOH or sulfonic acid (SO ₃H) linearity of functional group, branching or cyclic, saturated or unsaturated, optionally be the fatty acid of aromatics;

-contain 6-32 and 8-28 carbon atom and comprise at least one COOH or sulfonic acid (SO especially ₃H) linearity of functional group, branching or cyclic, saturated or undersaturated, optionally be the hydroxy acid of aromatics, especially 'alpha '-hydroxy acids;

-alkyl benzene sulphonate, wherein this alkyl can contain 4-30 and 6-24 carbon atom especially;

-both sexes nertralizer, the both sexes nertralizer of alkyl betaine or alkylamidoalkyl CAB class especially, wherein this alkyl can contain 4-30, especially 6-24 carbon atom; Especially cocamidopropyl betaine.

28. the described compositions of each of claim is characterized in that as described above, described copolymer is with the nertralizer neutralization that is selected among following: Alpha-hydroxy acetic acid, and Alpha-hydroxy is sad, Alpha-hydroxy is sad, ascorbic acid, acetic acid, benzoic acid, behenic acid, capric acid, citric acid, caproic acid is sad, DBSA, 2 ethyl hexanoic acid, folic acid, fumaric acid, galactosaccharic acid, gluconic acid, glycolic, 2-cetyl arachic acid, hydroxycaproic acid, the 12-hydroxy stearic acid, different lauric acid (or the 2-butyl is sad), different myristic acid (or the 2-hexyl is sad), different arachidic acid (or 2-octyl group dodecylic acid), isotetracosane acid (or 2-decyl tetradecanoic acid), lactic acid, lauric acid, malic acid, myristic acid, oleic acid, Palmic acid, propanoic acid, capric acid, stearic acid, tartaric acid, p-phthalic acid, trimesic acid, 9-undecylenic acid, CAB, cocamidopropyl betaine, and chemical formula [(CH ₃) ₃N ⁺CH ₂CO ₂HCl ^-] beet alkali hydrochlorate and their mixture.

29. the described compositions of each of claim as described above, it is characterized in that, described copolymer is with being selected from caproic acid, 2 ethyl hexanoic acid, oleic acid, behenic acid, stearic acid, acetic acid, citric acid, tartaric acid, beet alkali hydrochlorate and/or gluconic acid, the nertralizer neutralization in preferred beet alkali hydrochlorate and/or the behenic acid.

30. each the described compositions as claim 25-29 is characterized in that, this nertralizer is with the 1-300% based on described polymer or monomeric whole amine functional groups, especially 5-250% or even the amount of 10-200% add.

31. compositions as claimed in claim 30, wherein separately or as the nertralizer of mixture with 1-99% based on described polymer or monomeric whole amine functional groups, especially 5-90% or even the amount of 10-80% add.

32. compositions as claimed in claim 30, wherein separately or as the nertralizer of mixture with 0.01-3 molar equivalent based on polymer or monomeric whole amine functional groups, 0.05-2.5 molar equivalent especially, or even the amount of 0.1-2 molar equivalent add.

33. the described compositions of each of claim as described above, it is characterized in that, described copolymer has 500-5 000 000, especially 1000-3 000 000, more preferably 2000-2 000000, or even 4000-500 000, the weight average molecular weight (Mw) of 7000-250 000 and best 8000-100 000 better.

34. the described compositions of each of claim is characterized in that as described above, described copolymer comprises:

-separately or as the monomer of the general formula (I) of mixture, with 20-80wt% based on final polymer weight, especially the ratio of 20-60wt% and preferred 30-50wt% exists, and be selected from separately or as poly-(ethylene glycol) (methyl) acrylate of mixture, preferred molecular weight is 350-13 000g/mol and those of 500-8000g/mol especially; With

-" cation basically " monomer, 40-90wt% with the weight of final polymer, especially the ratio of 40-80wt% and preferred 50-70wt% exists, and be selected from separately or as dimethylaminopropyl (methyl) acrylamide of mixture, dimethyl aminoethyl (methyl) acrylamide, (methyl) acrylic acid diethylamino ethyl ester, (methyl) acrylic acid dimethyl aminoethyl ester, vinyl imidazole, vinylpyridine and (methyl) acrylic acid morpholino ethyl ester; With

-this copolymer neutralizes with the nertralizer that especially is selected from 2 ethyl hexanoic acid, oleic acid, behenic acid, stearic acid, acetic acid, citric acid, tartaric acid, beet alkali hydrochlorate and/or the gluconic acid, preferred behenic acid and/or beet alkali hydrochlorate.

35. the described compositions of each of claim is characterized in that as described above, described copolymer comprises:

-separately or as the monomer of the general formula (I) of mixture, with 20-80wt% based on final polymer weight, especially the ratio of 20-60wt% and preferred 30-50wt% exists, and be selected from separately or as poly-(ethylene glycol) (methyl) acrylate of mixture, preferred molecular weight is 350-13 000g/mol and those of 500-8000g/mol especially; With

-" cation basically " monomer, with the 40-90wt% of the weight of final polymer, especially the ratio of 40-80wt% and preferred 50-70wt% exists, and is selected from separately or as dimethylaminopropyl (methyl) acrylamide of mixture; With

-this polymer neutralizes with the nertralizer that is selected from behenic acid and/or the beet alkali hydrochlorate.

36. the described compositions of each of claim as described above, wherein this copolymer is with the 0.01-30wt% of said composition gross weight, especially 0.1-20wt% or even 0.1-10wt% and the ratio that also is more preferably the dry of 0.5-3wt% exist.

37. the described compositions of each of claim is characterized in that as described above, this anion surfactant is selected from alkyl sulfate, alkyl ether sulfate, alkyl ether carboxy acid salt and their mixture.

38. the described compositions of each of claim is characterized in that as described above, described anion surfactant is with the 3-40wt% based on the gross weight of said composition, and the concentration of preferred 5-25wt% exists.

39. the described compositions of each of claim as described above, it is characterized in that, described non-ionic surface active agent is selected from alcohol, salmefamol, induced by alkyl hydroxybenzene, the fatty acid of polyethoxylated, poly-propoxylation or bound to polyglycerol, it has for example aliphatic chain of 8-22 carbon atom, the number of ethylene oxide or propylene oxide group especially can be 2-50, and the number of glycerol group especially can be 2-30; Can also mention the copolymer of oxirane and expoxy propane, the condensation substance of oxirane and expoxy propane and aliphatic alcohol; The polyethoxylated fatty acid amide preferably has the oxirane of 2-30ml, on average contains 1-5, especially the bound to polyglycerol fatty acid amide of 1.5-4 glycerol group; The oxyethylation fatty acid ester of anhydro sorbitol with oxirane of 2-30mol; The fatty acid ester of sucrose, the fatty acid ester of Polyethylene Glycol, alkyl poly glucoside, N-alkylated glucamine derivant, amine oxide, for example (C ₁₀-C ₁₄) alkyl amine oxide or N-acyl amino propyl group morpholine oxide.

40. the described compositions of each of claim is characterized in that as described above, is benchmark in the gross weight of cosmetic composition, described non-ionic surface active agent is with 0.5-25wt%, 1-20wt% especially, and more specifically the concentration of 2-10wt% exists.

41. the described compositions of each of claim is characterized in that as described above, it also comprises amphoteric surfactant.

42. the described compositions of each of claim is characterized in that as described above, the total amount of surfactant is the 3.5-50wt% based on the gross weight of said composition, preferred 5-30wt% and more preferably 8-25wt% also.

43. the described compositions of each of claim as described above, wherein this cosmetics acceptable medium comprises at least a water that is selected from; Hydrophilic organic solvent, for example alcohol, especially linearity or branching C ₁-C ₆Monohydric alcohol, the composition in polyhydric alcohol and the glycol ethers.

44. the described compositions of each of claim is characterized in that as described above, described compositions also comprises at least a cation or amphiphilic polymers.

45. the described compositions of each of claim is characterized in that as described above, described cation or amphiphilic polymers account for the 0.001-20wt% of the gross weight of final composition, preferred 0.01-10wt%.

46. the described compositions of each of claim is characterized in that as described above, said composition also comprises at least a siloxanes.

47. the described compositions of each of claim is characterized in that as described above, this cation or amphiphilic polymers account for the 0.001-20wt% of the gross weight of final composition, preferred 0.1-5wt%.

48. the described compositions of each of claim is characterized in that as described above, said composition also comprises at least a additive that is selected among following: wax, the paste fatty material, sizing material and their mixture, the oil in animal, plant, mineral or synthetic source, synthetic ester and synthetic ether; The aliphatic alcohol that contains 12-26 carbon atom; Volatility or non-volatile, linear or cyclic at room temperature be the type siloxane oil of liquid or paste; Polymer except polymer with PEG group; Vitamin, aromatic, Concha Margaritifera, thickening agent, gellant, trace element, softening agent, sequestering agent, aromatic, acidulant or basifier, antiseptic, sunscreen, antioxidant, anti-alopecia agent, dandruff removing agent, propellant, ceramide and their mixture.

49. the described compositions of each of claim is the form of hair care composition as described above, is particularly useful for keeping hair style or makes Hair styling, for example is the form of shampoo.

50. be used for for example beauty method of body or skin of face, fingernail, body hair, hair and/or eyelashes of processing angle protein material, it is characterized in that, this method comprises each the defined cosmetic composition as claim 1-34 is applied on the keratin material, chooses wantonly and is using afterflush after action time arbitrarily.