CN1958746A - Composite oil free from lead prepared by using finished product of gasoline, and carbon five - Google Patents

Composite oil free from lead prepared by using finished product of gasoline, and carbon five Download PDF

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Publication number
CN1958746A
CN1958746A CN 200610150140 CN200610150140A CN1958746A CN 1958746 A CN1958746 A CN 1958746A CN 200610150140 CN200610150140 CN 200610150140 CN 200610150140 A CN200610150140 A CN 200610150140A CN 1958746 A CN1958746 A CN 1958746A
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gasoline
mixture
composite lead
mixed
additive
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CN100412174C (en
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鲁希诺
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Beijing Qingyan Lihua Petroleum Chemical Technology Co., Ltd.
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鲁希诺
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Abstract

This invention relates to a composite lead-free gasoline, which is composed of: 90# gasoline, C5 hydrocarbons, lightweight oil, benzene, aviation kerosene, modified ethanol and additives. The additives are composed of ZnO, antioxidant, metal passivation agent, colorant and soot suppressing/combustion improving agent. The composite lead-free gasoline has such advantages as good evaporation ability, good anti-knock property, high safety, good corrosion resistance, and low cost. Besides, this invention also relates to a method for preparing the above said composite lead-free gasoline.

Description

Utilize the composite lead-free gasoline and the compound method thereof of gasoline product, carbon five preparations
Technical field
The present invention relates to a kind of composite lead-free gasoline and compound method thereof of utilizing gasoline product, carbon five preparations.
Background technology
Existing composite lead-free gasoline generally is made up of methyl alcohol, dimethylbenzene, industrial naptha, and there is following shortcoming in this kind composite lead-free gasoline: when (1) surpassed 45 ℃ at temperature, methanol activity strengthened, and easily forms vapour stream, thereby air-resistance phenomenon takes place; Otherwise when temperature was extremely low, this composite lead-free gasoline convergency increased, and oil circuit then takes place freely do not cause being difficult for starting.(2) adopt industrial naptha to make main raw material, because the various unstable properties of industrial naptha, so the octane value fluctuation is bigger, and phenomenon of detonation takes place sometimes.(3) owing to the general higher stability that influences composite gasoline of industrial naptha gum level.(4) have certain corrodibility, can produce certain influence oil circuit.(5) when mixing use with conventional gasoline, be prone to demixing phenomenon.
At above-mentioned situation, a kind of technology of making the modified version composite lead-free gasoline of raw materials such as methyl alcohol, 90# gasoline, propyl carbinol, Virahol, modification alcohol (also claiming dehydrated alcohol), dimethylbenzene, acetone and core additives is provided among the applicant's the 200410071132X of Chinese patent application formerly, can effectively solve the existing problem of above-mentioned white gasoline, have good vapo(u)rability, anti-knocking property and stability, erosion resistance is good.But because the consumption of the annual gasoline product of China is very huge,, must cause corresponding raw material resources anxiety, make supplydemand relationship unbalance if one or more products of single production substitute existing gasoline product.Therefore develop and a greater variety ofly have same performance, quality, and composite lead-free gasoline cheaply, to satisfy market demand, be the problem that existing market presses for solution.
Summary of the invention
One object of the present invention is at the problems referred to above, and a kind of unleaded, environmental protection is provided, and has good vapo(u)rability, anti-knocking property and stability, erosion resistance is good, cost is low utilizes the composite lead-free gasoline of gasoline product, carbon five preparations.
For achieving the above object, technical scheme of the present invention is: a kind of composite lead-free gasoline that utilizes gasoline product, carbon five preparations, form by raw material with lower volume:
90# gasoline product 350-700 part
Carbon 266-532 part
Lightweight oil 70-140 part
Benzene 0.7-1.4 part
Aviation kerosene 0.07-0.14 part
Modification alcohol 14-28 part
Additive 4.9-9.8 part
Wherein additive by zinc oxide, oxidation inhibitor, metal passivator, tinting material and smoke abatement combustion adjuvant by weight 1: 1: 3: ratio was formulated in 5: 8.
The effect of additive is divided into effect and the effect of composite lead-free gasoline in the automobile use in building-up process; its function is simply the adding up of simple function of several constitutive materials anything but; in the building-up process of composite lead-free gasoline; additive rises and shortens the chemosynthesis time; coordinate various industrial chemicals molecule contacts; change intermolecular reactive force, make the synthetic particulate increased activity that is polymerized, reach the abundant and maximized purpose of chemical energy of atomizing when in engine, using.When composite lead-free gasoline burns use in motor car engine, additive has converging action to distributing of heat energy under specific High Temperature High Pressure, thereby guaranteeing does not have unnecessary heat energy dissipation, and the utilization ratio that makes heat energy be converted into mechanical energy improves, and reaches the purpose of Conversion of energy optimum.
Above-mentioned composite lead-free gasoline, the preferred volume ratio of its each component is:
90# gasoline product 450-600 part
Carbon five 350-450 parts
Lightweight oil 90-110 part
Benzene 0.9-1.1 part
Aviation kerosene 0.09-0.11 part
Modification alcohol 17-24 part
Additive 6-7 part.
At oxidation inhibitor described in the above-mentioned additive is 2,6 ditertiary butyl p cresol, and described metal passivator is N, and N '-two salicylidenes-propylene diamine, described tinting material are Vat Yellow GCN, and described smoke abatement combustion adjuvant is joined by ferrocene and isooctyl ester nitrate at 1: 1.
In the component of composite lead-free gasoline of the present invention, the technical grade carbon five that carbon five adopts content 〉=80% all can, the iso-pentane that contains in technical grade carbon five can improve the anti-knocking property of composite lead-free gasoline; Lightweight oil adopt proportion the oil product of 0.68 * 103kg/m3 to 0.70 * 103kg/m3 scope such as petroleum naphtha, solvent oil all can, it is mainly used in the density of regulating composite lead-free gasoline; And the boat coal that aviation kerosene adopts various models all can, it is mainly used in the component of regulating composite lead-free gasoline, increases the dynamic performance of composite lead-free gasoline.
Another object of the present invention is to provide a kind of method of preparing above-mentioned composite lead-free gasoline, and it is prepared according to the following steps:
1) at first get zinc oxide, oxidation inhibitor, metal passivator, tinting material and smoke abatement combustion adjuvant by weight 1: 1: 3: ratio was mixed with additive in 5: 8, got the allotment of aviation kerosene and above-mentioned additive then in proportion and formed CHF;
2) get the maternal gasoline of CHF allotment formation that 90# gasoline product and step 1) are mixed with in proportion;
3) get the allotment of carbon five and lightweight oil in proportion and form mixture A;
4) get the mixture A that benzene and step 3) be mixed with in proportion and be deployed into mixture B;
5) get the mixture B allotment formation mixture C that modification alcohol and step 4) are mixed with in proportion;
6) with mixture C and step 2) the maternal gasoline compounding that is mixed with forms; White gasoline.
Composite lead-free gasoline of the present invention has the following advantages: 1) unleaded, environmental protection; 2) vapo(u)rability, anti-knocking property are good; 3) stability, erosion resistance are good; 4) cost is low.
Be the detected result that composite lead-free gasoline product of the present invention detects by the GB17930-1999 national standard below:
Detect parameters The national Specification technical indicator Detected result
Research octane number (RON) Be not less than 93 >97
Lead content g/l Be not more than 0.005 0.0011
Boiling range: 10% vaporization temperature, ℃ 50% vaporization temperature, ℃ 90% vaporization temperature, ℃ final boiling point, ℃ residual quantity, % (v/v) Not being higher than 70 is not higher than 120 and is not higher than 190 and is not higher than 205 and is not more than 2 44 70 156 186 1.2
Vapour pressure, KPa Be not more than 74 49
Existent gum, mg/100ml Be not more than 5 1.8
Copper corrosion (50 ℃, 3h) level Be not more than 1 1
Inductive phase, min Be not more than 480 1172
Detected result shows that every technical indicator of product of the present invention all is better than national standard.
Embodiment
Embodiment 1:
1) at first gets zinc oxide, 2, the 6-ditertbutylparacresol, N, N '-two salicylidenes-propylene diamine, Vat Yellow GCN, smoke abatement combustion adjuvant was by weight 1: 1: 3: ratio was mixed with additive in 5: 8, and wherein smoke abatement combustion adjuvant by joining at 1: 1, is got 0.07 liter of aviation kerosene and 4.9 liters of additives are allocated formation CHF by ferrocene and isooctyl ester nitrate then;
2) get the maternal gasoline of CHF allotment formation that 350 liters of 90# gasoline products and step 1) are mixed with;
3) get 532 liters of carbon five and 70 liters of light naphtha allotment formation mixture A;
4) get the mixture A that 1.4 liters of benzene and step 3) be mixed with and be deployed into mixture B;
5) get the mixture B allotment formation mixture C that 28 liters of modification alcohol and step 4) are mixed with;
6) with mixture C and step 2) the maternal gasoline compounding that is mixed with forms composite lead-free gasoline.
Embodiment 2:
1) at first gets zinc oxide, 2, the 6-ditertbutylparacresol, N, N '-two salicylidenes-propylene diamine, Vat Yellow GCN, smoke abatement combustion adjuvant was by weight 1: 1: 3: ratio was mixed with additive in 5: 8, and wherein smoke abatement combustion adjuvant by joining at 1: 1, is got 0.14 liter of aviation kerosene and 9.8 liters of additives are allocated formation CHF by ferrocene and isooctyl ester nitrate then;
2) get the maternal gasoline of CHF allotment formation that 700 liters of 90# gasoline products and step 1) are mixed with;
3) get 266 liters of carbon five and 140 liters of light naphtha allotment formation mixture A;
4) get the mixture A that 0.7 liter of benzene and step 3) be mixed with and be deployed into mixture B;
5) get the mixture B allotment formation mixture C that 14 liters of modification alcohol and step 4) are mixed with;
6) with mixture C and step 2) the maternal gasoline compounding that is mixed with forms composite lead-free gasoline.
Embodiment 3:
1) at first gets zinc oxide, 2, the 6-ditertbutylparacresol, N, N '-two salicylidenes-propylene diamine, Vat Yellow GCN, smoke abatement combustion adjuvant was by weight 1: 1: 3: ratio was mixed with additive in 5: 8, and wherein smoke abatement combustion adjuvant by joining at 1: 1, is got 0.09 liter of aviation kerosene and 6 liters of additives are allocated formation CHF by ferrocene and isooctyl ester nitrate then;
2) get the maternal gasoline of CHF allotment formation that 450 liters of 90# gasoline products and step 1) are mixed with;
3) get 450 liters of carbon five and 90 liters of solvent oil allotment formation mixture A;
4) get the mixture A that 1.1 liters of benzene and step 3) be mixed with and be deployed into mixture B;
5) get the mixture B allotment formation mixture C that 24 liters of modification alcohol and step 4) are mixed with;
6) with mixture C and step 2) the maternal gasoline compounding that is mixed with forms composite lead-free gasoline.
Embodiment 4:
1) at first gets zinc oxide, 2, the 6-ditertbutylparacresol, N, N '-two salicylidenes-propylene diamine, Vat Yellow GCN, smoke abatement combustion adjuvant was by weight 1: 1: 3: ratio was mixed with additive in 5: 8, and wherein smoke abatement combustion adjuvant by joining at 1: 1, is got 0.11 liter of aviation kerosene and 7 liters of additives are allocated formation CHF by ferrocene and isooctyl ester nitrate then;
2) get the maternal gasoline of CHF allotment formation that 600 liters of 90# gasoline products and step 1) are mixed with;
3) get 350 liters of carbon five and 110 liters of solvent oil allotment formation mixture A;
4) get the mixture A that 0.9 liter of benzene and step 3) be mixed with and be deployed into mixture B;
5) get the mixture B allotment formation mixture C that 17 liters of modification alcohol and step 4) are mixed with;
6) with mixture C and step 2) the maternal gasoline compounding that is mixed with forms composite lead-free gasoline.
Embodiment 5:
1) at first gets zinc oxide, 2,6 ditertiary butyl p cresol, N, N '-two salicylidenes-propylene diamine, Vat Yellow GCN, smoke abatement combustion adjuvant were by weight 1: 1: 3: ratio was mixed with 7 liters of additives in 5: 8, wherein smoke abatement combustion adjuvant by ferrocene and isooctyl ester nitrate by joining at 1: 1;
2) get 500 liters of 90# gasoline products, 5 400 liters in carbon, 100 liters of lightweight oils, 1 liter of benzene, 0.1 liter of 1# aviation kerosene, 20 liters of modification alcohol and 7 liters of mixed together of additive and stir, form composite lead-free gasoline.
Describe the present invention with way of example above, but the invention is not restricted to above-mentioned specific embodiment, all protection domains that any improvement that the present invention did or modification are all belonged to claim of the present invention.

Claims (5)

1. composite lead-free gasoline that utilizes five preparations of gasoline product, carbon is characterized in that being made up of the raw material with lower volume:
90# gasoline product 350-700 part
Carbon five 266-532 parts
Lightweight oil 70-140 part
Benzene 0.7-1.4 part
Aviation kerosene 0.07-0.14 part
Modification alcohol 14-28 part
Additive 4.9-9.8 part
Wherein additive by zinc oxide, oxidation inhibitor, metal passivator, tinting material and smoke abatement combustion adjuvant by weight 1: 1: 3: ratio was formulated in 5: 8.
2. composite lead-free gasoline according to claim 1 is characterized in that the volume ratio of its each component is:
90# gasoline product 450-600 part
Carbon five 350-450 parts
Lightweight oil 90-110 part
Benzene 0.9-1.1 part
Aviation kerosene 0.09-0.11 part
Modification alcohol 17-24 part
Additive 6-7 part.
3. composite lead-free gasoline according to claim 1 and 2, it is characterized in that: at oxidation inhibitor described in the additive is 2, the 6-ditertbutylparacresol, described metal passivator is N, N '-two salicylidenes-propylene diamine, described tinting material is a Vat Yellow GCN, and described smoke abatement combustion adjuvant is joined by ferrocene and isooctyl ester nitrate at 1: 1.
4. composite lead-free gasoline according to claim 1 and 2 is characterized in that: described lightweight oil is petroleum naphtha or solvent oil.
5. prepare the method that aforesaid right requires described composite lead-free gasoline for one kind, it is characterized in that preparing according to the following steps:
1) at first get zinc oxide, oxidation inhibitor, metal passivator, tinting material and smoke abatement combustion adjuvant by weight 1: 1: 3: ratio was mixed with additive in 5: 8, got the allotment of aviation kerosene and above-mentioned additive then in proportion and formed CHF;
2) get the maternal gasoline of CHF allotment formation that 90# gasoline product and step 1) are mixed with in proportion;
3) get the allotment of carbon five and lightweight oil in proportion and form mixture A;
4) get the mixture A that benzene and step 3) be mixed with in proportion and be deployed into mixture B;
5) get the mixture B allotment formation mixture C that modification alcohol and step 4) are mixed with in proportion;
6) with mixture C and step 2) the maternal gasoline compounding that is mixed with forms composite lead-free gasoline.
CNB2006101501402A 2005-10-31 2006-10-27 Composite oil free from lead prepared by using finished product of gasoline, and carbon five Expired - Fee Related CN100412174C (en)

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Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200510116883.3 2005-10-31
CN 200510116883 CN1766062A (en) 2005-10-31 2005-10-31 Composite lead-free gasoline prepared by petroleum products and C5 and its preparation method
CNB2006101501402A CN100412174C (en) 2005-10-31 2006-10-27 Composite oil free from lead prepared by using finished product of gasoline, and carbon five

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CN100412174C CN100412174C (en) 2008-08-20

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102212400A (en) * 2011-05-12 2011-10-12 谢晓懂 Synthetic gasoline
CN101381635B (en) * 2008-10-27 2011-12-07 河南省科学院 Application of modified C5 in gasoline additives
CN101381642B (en) * 2008-10-27 2011-12-07 河南省科学院 Automobile fuel oil additive
CN101463278B (en) * 2009-01-14 2012-08-29 北京恩多利新能源科技有限公司 Synthetic gasoline

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1772849A (en) * 2005-10-31 2006-05-17 鲁希诺 Compound lead-less gasoline compounded with gasoline product and its compounding process
CN1766061A (en) * 2005-10-31 2006-05-03 鲁希诺 Composite lead-free gasoline and its preparation method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381635B (en) * 2008-10-27 2011-12-07 河南省科学院 Application of modified C5 in gasoline additives
CN101381642B (en) * 2008-10-27 2011-12-07 河南省科学院 Automobile fuel oil additive
CN101463278B (en) * 2009-01-14 2012-08-29 北京恩多利新能源科技有限公司 Synthetic gasoline
CN102212400A (en) * 2011-05-12 2011-10-12 谢晓懂 Synthetic gasoline

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Assignee: Beijing Qingyan Lihua Petroleum Chemical Technology Co., Ltd.

Assignor: Lu Xinuo

Contract fulfillment period: 2007.2.16 to 2017.2.16 contract change

Contract record no.: 2009990000386

Denomination of invention: Composite oil free from lead prepared by using finished product of gasoline, and carbon five

Granted publication date: 20080820

License type: Exclusive license

Record date: 2009.4.29

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.2.16 TO 2017.2.16; CHANGE OF CONTRACT

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Address after: 100081 Beijing City, Haidian District Zhongguancun South Street No. 5, building 683, ligongkeji building 14 room 1409

Patentee after: Beijing Qingyan Lihua Petroleum Chemical Technology Co., Ltd.

Address before: 100081 Beijing City, Haidian District Zhongguancun South Street, ligongkeji building 14 layer in the company

Patentee before: Lu Xinuo

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Denomination of invention: Composite oil free from lead prepared by using finished product of gasoline, and carbon five

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