CN1958474A - Suspended biological carrier adapted to microbial bodies, and preparation method - Google Patents

Suspended biological carrier adapted to microbial bodies, and preparation method Download PDF

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Publication number
CN1958474A
CN1958474A CNA2006101237170A CN200610123717A CN1958474A CN 1958474 A CN1958474 A CN 1958474A CN A2006101237170 A CNA2006101237170 A CN A2006101237170A CN 200610123717 A CN200610123717 A CN 200610123717A CN 1958474 A CN1958474 A CN 1958474A
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China
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suspended biological
biological carrier
carrier
adapts
preparation
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CNA2006101237170A
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Chinese (zh)
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陈维平
江帆
李元元
张弢
朱权利
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South China University of Technology SCUT
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South China University of Technology SCUT
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Priority to CNA2006101237170A priority Critical patent/CN1958474A/en
Publication of CN1958474A publication Critical patent/CN1958474A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Biological Treatment Of Waste Water (AREA)

Abstract

This invention relates to a biological carrier for water treatment, more specifically, a suspended microbe carrier and its preparation method. The method adopts a polymer extruder, whose spray nozzle is equipped with a mold with a groove at the section and rough inner surface. The mold can extrude filamentous polymer with convex section and rough surface. The diameters of the filaments are 1-3 mm. winding of several filaments of the filamentous polymer can form suspended microbe carrier with arbitrary structure. The helical diameters of the helically winding filamentous polymer are 6-8 mm, and the pitches are 4-7 mm. The suspended microbe carrier can match the sizes and physical structures of microbes in wastewater, and has such advantages as simple structure, easy preparation, and excellent hydrodynamic properties.

Description

Suspended biological carrier that a kind of and microbial bodies adapts and preparation method thereof
Technical field
The present invention relates to water treatment biological carrier, be meant suspended biological carrier that a kind of and microbial bodies adapts and preparation method thereof more specifically.
Background technology
Suspended biological carrier is one of existing biological sewage treatment important materials, and the suspended biological carrier of practical application at present is more, is bringing into play important effect in sewage disposal.In the research of suspended biological carrier, carrier structure is one of research focus, a kind of suspended biological carrier of regulating proportion is disclosed as Chinese patent 02218096.6, connect to form by circular arc retaining plate, circular arc wing plate, fixed ring, proportion adjustable pipe, set collar, specific surface area is bigger, can regulate proportion, freely suspends in sewage, be fluidization under the effect of aeration in biological contact oxidation pond, processing efficiency is greatly improved.But still come with some shortcomings: (1) makes smooth surface because this retaining plate is a slab construction, and the serrated slot on wing plate surface is a single direction in addition, so be not easy to biological attachment; (2) because of the wing plate plane does not have hole, hydrodynamic performance is not good, causes on the carrier nutrition and oxygen to supply with insufficient; (3) owing to will regulate proportion by structure, make complex structure, manufacturing cost is higher.
Chinese patent 99253300.7 discloses a kind of spindle-type suspended biological carrier, is made up of rack, guipure, filler, axial cord, and it is little to have a volume, advantage such as specific surface area is big.But also come with some shortcomings: the hole pattern structure of (1) rack and guipure is blocked by microorganism easily, makes the filler of inner face and internal space thereof be difficult to make full use of; (2) attaching surface mainly relies on the filling surface of inner face, and the structural frames of rack and guipure is more tiny, does not obtain utilizing.
Summary of the invention
The objective of the invention is to the shortcoming that exists at existing suspended biological carrier, provide that microbial bodies adapts in a kind of and the sewage, simple in structure, it is convenient to prepare, and cost is low, hydrodynamic characteristic good suspension bio-carrier during use.
The objective of the invention is to be achieved through the following technical solutions:
The preparation method of the suspended biological carrier that a kind of and microbial bodies adapts is as follows,
(1) adopt polymer-extruded machine, nozzle is equipped with the cross section and has groove, and the mould of rough inner surface;
(2) extrude the cross section by this mould projection, shaggy thread polymeric acceptor are arranged;
(3) there are projection, shaggy thread polymeric acceptor to twine the suspended biological carrier of any face shaping that forms irregular space through spiral by some cross sections.It is 1~3mm that suspended biological carrier adopts the silk footpath of thread polymeric acceptor; The screw diameter of selecting for use when thread polymeric acceptor spiral twines is 6~8mm, and pitch is 4~7mm.
The suspended biological carrier of the present invention's preparation, there are projection and surface irregularity in the cross section of its filament, is twined by thread polymeric acceptor and forms any face shaping of random layer.
The structure of the suspended biological carrier that this and microbial bodies adapts can be individual layer or bilayer or multilayered structure; Face shaping is generally cube, also can be cylindrical or spherical.
The present invention compares with existing suspended biological carrier has following advantage:
(1) space structure of carrier of the present invention and microbial bodies are complementary, and are fit to the apposition growth of the microorganism of each population, make that the accumulative microbe species is many on the carrier, and all contaminations is all had Degradation, and be more thorough to sewage disposal.
(2) effective surface area of carrier of the present invention is big, can adsorb a large amount of microorganisms and form stable, ecological abundant microbial film, has improved the degradation capability of microbial film to pollutent in the sewage.
(3) carrier winding arrangement, hydrodynamic characteristic is good, each surface of carrier is direct and gas-to-liquid contact in BAF, embodied good hydrodynamic characteristic, make biomembranous nutrition and oxygen supply with fully, improve the biological activity of microorganism greatly, improve microbial film thereupon sewage treatment effect.
(4) the old microbial film on the carrier can leave carrier more up hill and dale under the ballistic effect of Liquid Flow, does not block bio-carrier.
(5) carrier is entwined by the filament spiral, and is simple in structure, and preparation is easy, and cost is low, easily applies.
Description of drawings
Fig. 1 is the structural representation of the suspended biological carrier that adapts with cube individual layer microbial bodies;
Fig. 2 is the thread polymeric acceptor schematic cross-section of circular six projectioies;
Fig. 3 is the structural representation of the suspended biological carrier that adapts with 7 layers of microbial bodies of cube;
Fig. 4 is the structural representation of the suspended biological carrier that adapts with cylindrical 3 layers of microbial bodies;
Fig. 5 is the thread polymeric acceptor schematic cross-section of circular eight projectioies;
Fig. 6 is the structural representation of the suspended biological carrier that adapts with spherical 7 layers of microbial bodies;
Fig. 7 is the thread polymeric acceptor schematic cross-section of square four projectioies.
Embodiment
The present invention is described in further detail by following embodiment and accompanying drawing.But embodiments of the present invention are not limited thereto.
Embodiment 1
The suspended biological carrier that adapts with microbial bodies as shown in Figure 1, its preparation method is: adopt the cross section fluted, and the mould of rough inner surface, by polymer-extruded machine the fused polymeric colloid is extruded, form the cross section projection is arranged, shaggy thread polymeric acceptor, the cross-sectional shape of thread polymeric acceptor is determined by the mold sections shape, the cross-sectional shape of thread polymeric acceptor as shown in Figure 2 is circular, the cross section has the projection of 6 0.5mm, surface ratio is more coarse, the silk footpath is 2mm, the screw diameter of selecting for use when thread polymeric acceptor spiral twines is 8mm, pitch is 6mm, and 7 filaments twine the cuboidal suspended biological carrier that forms the irregular space of individual layer through spiral.
When the suspended biological carrier that adapts with microbial bodies of needs bilayer or multilayered structure, form by the overlapping winding of two or more individual layers, the suspended biological carrier that adapts with 7 layers of microbial bodies of cube is as shown in Figure 3.
The working process of the suspended biological carrier that adapts with microbial bodies is as follows: the suspended biological carrier that adapts with microbial bodies of BAF volumetrical about 50% is placed BAF, and this carrier can the effect of aeration stream be issued to fluidized state in the pond.The structural shape of this carrier can be fit to the not microorganism of isomorph, adapts as strip microbial bodies such as spiral helicine mycelia, nematode, campanularian in the winding vesicular structure of this carrier and the sewage, and the environment that is easy to adhere to is provided for this quasi-microorganism; The side face of the filament of this carrier and small embossment form the bigger little surface of flow disturbance that is subjected to, and are fit to shaft-like, spherical mushroom and miniature primary and metazoan adheres to; Thereby this carrier can assemble the not microorganic adhesion of isomorph, for they provide the environment of suitable growth and breeding, reaches the purpose of rapid biofilm, and can make full use of the integrated degraded advantage of each quasi-microorganism; Simultaneously, all surface of this carrier is effective surface, can adsorb a large amount of microorganisms and form stable, ecological abundant microbial film, has improved the degradation capability of microbial film to pollutent in the sewage.The pitch and the screw diameter of the spiral filament of this carrier are enough big, be difficult for being blocked by microbial film, aeration stream and current can arrive any place of this carrier, biomembranous oxygen and nutrition supply are abundant on the carrier, make that microbial film metabolism is vigorous, active good, strengthen degradation effect to sewage, old film more thoroughly leaves carrier simultaneously, and the carrier space is difficult for blocking.
With above-mentioned suspended biological carrier, making apparent size is 30 * 25mm cubes, and after measured, its density is 211.927kg/m 3, porosity is 86.76%, and piling up voidage is 93.24%, and specific surface area is 0.00546m 2/ g.Getting volume is the winding-type suspending carrier of 900mL, puts into the reactor that useful volume is 1.8L, in sewage water inlet average COD CrBe 148.96mg/L, average N H 3-N is 22.0mg/L, under the operating mode of residence time 1h, and COD CrClearance be 79.5%, NH 3The clearance of-N is 80.3%, and biofilm effect and wastewater treatment efficiency all are better than other carrier under the operating mode of the same race (as multiaspect hollow ball, cascade ring etc.).
Embodiment 2
The suspended biological carrier that adapts with microbial bodies as shown in Figure 4, its preparation method is: adopt the cross section fluted, and the mould of rough inner surface, by polymer-extruded machine the fused polymeric colloid is extruded, form the cross section projection is arranged, shaggy thread polymeric acceptor, the cross-sectional shape of thread polymeric acceptor is determined by the mold sections shape, the cross-sectional shape of thread polymeric acceptor as shown in Figure 5 is circular, the cross section has the projection of 8 1mm, surface ratio is more coarse, the silk footpath is 1.2mm, the screw diameter of selecting for use when thread polymeric acceptor spiral twines is 7mm, pitch is 7mm, 24 rhizoid shaped polymer bodies twine to form 3 layers of cube of every layer of 8 filament through spiral, are cut into the suspended biological carrier that adapts with cylindrical microbial bodies as shown in Figure 4 again.Its working process is with implementing 1.
Embodiment 3
The suspended biological carrier that adapts with microbial bodies as shown in Figure 6, its preparation method is: adopt the cross section fluted, and the mould of rough inner surface, by polymer-extruded machine the fused polymeric colloid is extruded, form the cross section projection is arranged, shaggy thread polymeric acceptor, the cross-sectional shape of thread polymeric acceptor is determined by the mold sections shape, the cross-sectional shape of thread polymeric acceptor as shown in Figure 7 is square, sectional dimension is 1 * 1mm, the projection that has 4 0.7mm, surface ratio is more coarse, the silk footpath is 2.5mm, the screw diameter of selecting for use when thread polymeric acceptor spiral twines is 8mm, pitch is 5mm, and 49 filaments twine 7 layers of cubes that form every layer of 7 filament through spiral, is cut into the suspended biological carrier that adapts with the ball shape microbial bodies as shown in Figure 6 again.Its working process is with implementing 1.

Claims (5)

1, the preparation method of the suspended biological carrier that adapts of a kind of and microbial bodies is characterized in that:
(1) adopt polymer-extruded machine, nozzle is equipped with the cross section and has groove, and the mould of rough inner surface;
(2) extrude the cross section by this mould projection, shaggy thread polymeric acceptor are arranged;
(3) there are projection, shaggy thread polymeric acceptor to twine the suspended biological carrier of any face shaping that forms irregular space through spiral by some cross sections.
2, the preparation method of the suspended biological carrier that adapts according to a kind of and microbial bodies described in the claim 1 is characterized in that: the screw diameter of selecting for use when thread polymeric acceptor spiral twines is 6~8mm, and pitch is 4~7mm.
3, the suspended biological carrier of preparation methods' preparation of the suspended biological carrier that adapts of claim 1 or 2 described a kind of and microbial bodies, it is characterized in that: there are projection and surface irregularity in the cross section of its filament, is twined by thread polymeric acceptor and forms any face shaping of random layer.
4, the suspended biological carrier that adapts according to a kind of and microbial bodies described in the claim 3 is characterized in that: the silk footpath of thread polymeric acceptor is 1~3mm.
5, a kind of suspended biological carrier that adapts with microbial bodies according to claim 3, it is characterized in that: twining the suspended biological carrier that forms is individual layer or bilayer or multilayer, and its face shaping is that cube is cylindrical or spherical.
CNA2006101237170A 2006-11-23 2006-11-23 Suspended biological carrier adapted to microbial bodies, and preparation method Pending CN1958474A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN1958474A true CN1958474A (en) 2007-05-09

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109016429A (en) * 2018-07-03 2018-12-18 海南海上美海洋生态工程有限公司 A kind of preparation method of microorganism attachment ball
CN111875036A (en) * 2020-07-20 2020-11-03 大力(武汉)环保科技有限公司 Sewage treatment filler loaded with biological membrane and application thereof
CN112630245A (en) * 2020-11-30 2021-04-09 广东省微生物研究所(广东省微生物分析检测中心) Method for capturing long-line-shaped microorganisms in sediment by using carbon felt and imaging
CN113373139A (en) * 2021-06-15 2021-09-10 佛山市南海区苏科大环境研究院 Immobilized microbial material for treating wastewater containing heavy metal ions and preparation method thereof
CN114434794A (en) * 2020-10-30 2022-05-06 海帕斯科技股份有限公司 Composite structure of bio-carrier, method for manufacturing bio-carrier and manufactured article

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109016429A (en) * 2018-07-03 2018-12-18 海南海上美海洋生态工程有限公司 A kind of preparation method of microorganism attachment ball
CN111875036A (en) * 2020-07-20 2020-11-03 大力(武汉)环保科技有限公司 Sewage treatment filler loaded with biological membrane and application thereof
CN114434794A (en) * 2020-10-30 2022-05-06 海帕斯科技股份有限公司 Composite structure of bio-carrier, method for manufacturing bio-carrier and manufactured article
CN112630245A (en) * 2020-11-30 2021-04-09 广东省微生物研究所(广东省微生物分析检测中心) Method for capturing long-line-shaped microorganisms in sediment by using carbon felt and imaging
CN113373139A (en) * 2021-06-15 2021-09-10 佛山市南海区苏科大环境研究院 Immobilized microbial material for treating wastewater containing heavy metal ions and preparation method thereof

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