CN1958275A - Method for preparing composite material of polymethyl methacrylate enhanced by 3D weaving carbon fiber - Google Patents
Method for preparing composite material of polymethyl methacrylate enhanced by 3D weaving carbon fiber Download PDFInfo
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- CN1958275A CN1958275A CN 200610016187 CN200610016187A CN1958275A CN 1958275 A CN1958275 A CN 1958275A CN 200610016187 CN200610016187 CN 200610016187 CN 200610016187 A CN200610016187 A CN 200610016187A CN 1958275 A CN1958275 A CN 1958275A
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Abstract
A 3D braided carbon fibers reinforced methyl polymethylacrylate with high biocompatibility and excellent mechanical performance is prepared through mixing methyl methylacrylate with benzoyl oxide, heating at 90-100 deg.C, cooling, vacuum defoaming to obtain the prepolymer of methyl methylacrylate, oxidizing the surface of 3D braided carbon fibers in the air at 450 deg.C, putting them in a sealed mould, injecting said prepolymer in the mould, low-temp solidifying at 45 deg.C, heating to 100 deg.C, cooling and demoulding.
Description
Technical field
The present invention relates to a kind of polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite material and preparation method thereof, belong to the technology of carbon fibre composite.
Background technology
Carbon fiber has advantages such as low-density, high strength, high-modulus, high temperature resistant, resist chemical, low resistance, high thermal conductance, low bulk, chemically-resistant radiation.In addition, carbon fiber has the favorable tissue compatibility, is a kind of good biomaterial.With the carbon fiber reinforced composite because the intensity height, modulus is adjustable etc., and advantage is widely used in preparation bone anchoring device and implant.So far employed carbon fibre composite mainly comprises short carbon fiber, long carbon fiber and control of two-dimensional braided carbon fibre composite.Compare with above-mentioned composite, the 3 D weaving carbon fiber composite has incomparable advantage.For example, traditional laminate composite has the inherent shortcoming that is difficult to overcome: poor as rigidity and strength character along thickness direction, inplane shear and interlaminar shear strength are lower, easily layering, impact flexibility and damage tolerance level are low etc., therefore, can not satisfy instructions for use under many occasions.Composite combines the shortcoming that the 3 D weaving carbon fiber composite that produces has overcome tradition stratum plywood composite with textile technology, and becomes Aeronautics and Astronautics and the indispensable novel high-performance material of weaponry with its excellent performance.Simultaneously, (intensity as the 3 D weaving carbon fiber composite can surpass medical metal material commonly used because the 3 D weaving carbon fiber composite has very high bending strength, as stainless steel, titanium or titanium alloy etc.), high fatigue strength and damage-resistant energy, high impact flexibility.In addition, the 3 D weaving body can change shape easily, and complex need not secondary operations, so the 3 D weaving carbon fiber composite utmost point is suitable for preparing orthopaedics implant, is a kind of novel biomaterial that development potentiality is arranged very much.The composite that 3-d braided fiber and medical polymer are formed is expected to complete alternative metals bone implant material.This seminar is used for the research of orthopaedics implant with the external D braided composites of almost having carried out simultaneously, but because the preparation difficulty of D braided composites is big, only can prepares 3-d braided fiber at present and strengthen some thermoset polymer matrix composite.
Resin transfer moulding (RTM) technology is the optimum technology of preparing of D braided composites, RTM requires (as viscosity, hardening time etc.) to make the matrix of D braided composites only limit to some low viscous thermosetting polymers to the harshness of matrix, and mainly be BMI of part epoxy and minute quantity etc., this has seriously restricted the fast development of D braided composites.As everyone knows, thermoplastic polymer is a large amount of materials that use in the engineering; In addition, in the bio-medical material of clinical use, the thermosetting polymer that with epoxy resin is representative only accounts for about 5% of polymer biomaterial, and biocompatibility is not fully up to expectations, most polymer biomaterials such as polymethyl methacrylate, nylon, polytetrafluoroethylene (PTFE), polysulfones, polyethylene etc., and be considered to the absorbable polymer of following biomaterial development main flow such as PLA, polyglycolic acid, polycaprolactone etc. and be thermoplastic polymer.Polymethyl methacrylate is a kind of thermoplastic resin, is the product of methyl methacrylate polymerisation in bulk.Polymethyl methacrylate has good against weather and chemical stability, good processability, good insulation performance and compare the characteristics such as lightweight high-ductility that had with unorganic glass.Polymethacrylate is to use one of medical macromolecular materials the earliest.Up till now, they remain consumption maximum, the kind that purposes is the widest.Polymethyl methacrylate has excellent biological compatibility, and higher mechanical strength and thermoforming performance have been used for artificial bone, bone cement, joint prosthesis, particularly occupies critical role at aspects such as dental material, skeletal agglutinant and skull reparations.Therefore, the compound of 3 D weaving carbon fiber and polymethyl methacrylate not only can obtain high mechanical property, and can keep good biocompatibility.From application of engineering project, 3-d braided fiber strengthens polymethyl methacrylate can obtain high-grade high performance engineering plastics, increases substantially the added value of product of polymethyl methacrylate.These high performance enhancing resins are expected to be used for high speed ship, bullet train, aircraft, sports equipment and high-performing car etc., alternative corresponding metal parts, and its market prospects are fine.From the biomaterial angle, be expected to obtain the novel orthopaedics material that intensity and biocompatibility all are better than stainless steel, titanium or titanium alloy with polymethyl methacrylate enhanced by 3 D weaving carbon fiber etc., thereby alternative this metalloid material, and can develop wide novel artificial bone of market prospects and joint prosthesis material on this basis.Yet, because the preparation difficulty until today, does not all have success to prepare the report that the high performance three-dimensional weaving carbon fiber strengthens composite material of polymethyl methacrylate at home and abroad.Given this, seek effective technology of preparing of polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite,, enlarge its range of application and have important significance for theories and practice significance promoting the development of D braided composites.
Summary of the invention
The object of the present invention is to provide a kind of polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite material and preparation method thereof, the Biocomposite material that makes with this method has than other carbon fiber reinforced composite material of polymethyl methacrylate improved comprehensive mechanical performance and biology performance.
The present invention is realized that by following technical proposals a kind of polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite material and preparation method thereof is characterized in that comprising following process:
1. benzoyl peroxide (BPO) initator that adds quality and be 0.08%-0.15% in methyl methacrylate (MMA) mixes, the water-bath heating is incubated 5-60 minute down in 90-100 ℃, is cooled to room temperature, carry out vacuum defoamation, make the methyl methacrylate performed polymer;
2. be that the 25-65% 3 D weaving carbon fiber is that medium carried out surface oxidation treatment after 1 hour at the air of 450 ℃ of temperature with fiber name volume ratio, inserting cavity volume is in 1.2 times the closed mould of carbon fiber preform apparent volume;
3. the pressure with 2-6MPa injects the methyl methacrylate performed polymer that step 1 makes in mould, methyl methacrylate performed polymer injection rate is 2-3 a times of carbon fiber preform apparent volume, the mould that will fill behind the type places in the baking oven, in 45 ℃ of low-temperature settings 16 hours, heating up 100 ℃ kept 1 hour down again, was cooled to the room temperature depanning then and promptly got the polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite product.
Advantage of the present invention is: the viscosity of liquid performed polymer is controlled, and is good to the dipping of carbon fiber; Closed moulding, pollution-free, be a kind of green manufacture technology; Technical process is easy to control; The fiber volume fraction of composite can be regulated and control (25-65%); Prepared polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite has kept the biocompatibility of carbon fiber and polymethyl methacrylate and the excellent mechanical property of D braided composites.
Description of drawings
Fig. 1 presses the electron scanning micrograph of the length direction shear fracture of vertical carbon fiber for carbon fiber name content is the polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite product of 45vol.%.
The specific embodiment
Example 1
Methyl methacrylate (MMA) 500 grams (BPO=0.08%) are mixed with initator benzoyl peroxide (BPO), and the water-bath heating is incubated 30 minutes down in 90 ℃, is cooled to room temperature and carries out vacuum defoamation.Meanwhile, will be undertaken being laid in the mould after the air oxidation (1 hour 450 ℃/time of temperature) by cylinder (long 60mm, the diameter 20mm) sample (fiber name volume ratio is 45%) that the T300 carbon fiber knit becomes, then mold closing.Pressure with 2MPa injects above-mentioned mixed solution in mould, the volume of mixed liquor is about 2 times of carbon fiber preform apparent volume, when treating that performed polymer is full of mould and does not have bubble, stops injection molding.The mould that will fill behind the type places in the baking oven, and 45 ℃ of low-temperature settings 16 hours kept 1 hour at 100 ℃, with the stove cooling, were cooled to the room temperature depanning, promptly obtained polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite sample.
Example 2
Methyl methacrylate (MMA) 200 grams (BPO=0.15%) are mixed with initator benzoyl peroxide (BPO), and the water-bath heating is incubated 25 minutes down in 100 ℃, is cooled to room temperature, vacuum defoamation.Meanwhile, will by the T300 carbon fiber knit become rectangular (80 * 12 * 2mm) samples (fiber name volume ratio is 65%) carry out being laid in the mould after the air oxidation (1 hour 450 ℃/time of temperature), then mold closing.Pressure with 6MPa injects above-mentioned mixed solution in mould, the volume of mixed liquor is about 3 times of carbon fiber preform apparent volume, when treating that performed polymer is full of mould and does not have bubble, stops injection molding.The mould that will fill behind the type places in the baking oven, and 45 ℃ of low-temperature settings 16 hours kept 1 hour at 100 ℃, with the stove cooling, were cooled to the room temperature depanning, promptly got polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite sample.
Example 3
Methyl methacrylate (MMA) 250 grams (BPO=0.10%) are mixed with initator benzoyl peroxide (BPO), and the water-bath heating is incubated 25 minutes down in 90 ℃, is cooled to room temperature, carries out vacuum defoamation.Meanwhile, will be undertaken being laid in the mould after the air oxidation (1 hour 450 ℃/time of temperature) by disk (diameter 80mm, the thickness 2mm) sample (fiber name volume ratio is 45%) that the T300 carbon fiber knit becomes, then mold closing.Pressure with 3MPa injects above-mentioned mixed solution in mould, the volume of mixed liquor is about 2.5 times of carbon fiber preform apparent volume, when treating that performed polymer is full of mould and does not have bubble, stops injection molding.The mould that will fill behind the type places in the vacuum drying oven, and 45 ℃ of low-temperature settings 16 hours kept 1 hour at 100 ℃, with the stove cooling, were cooled to the room temperature depanning, obtained polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite sample.
Claims (1)
1. polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite material and preparation method thereof is characterized in that comprising following process:
1) adding quality in methyl methacrylate is that the benzoyl peroxide initator of 0.08%-0.15% mixes, and the water-bath heating in 90-100 ℃ of insulation 5-60 minute down, is cooled to room temperature, carries out vacuum defoamation, makes the methyl methacrylate performed polymer;
2) 3 D weaving carbon fiber that is 25-65% with the nominal volume ratio of fiber is that medium carried out surface oxidation treatment after 1 hour at the air of 450 ℃ of temperature, and inserting cavity volume is in 1.2 times the closed mould of carbon fiber preform apparent volume;
3) pressure with 2-6MPa injects the methyl methacrylate performed polymer that step 1) makes in mould, methyl methacrylate performed polymer injection rate is 2-3 a times of carbon fiber preform apparent volume, the mould that will fill behind the type places in the baking oven, in 45 ℃ of low-temperature settings 16 hours, heating up 100 ℃ kept 1 hour down again, was cooled to the room temperature depanning then and promptly got the polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite product.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB200610016187XA CN100569494C (en) | 2006-10-23 | 2006-10-23 | The polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite material and preparation method thereof |
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| CNB200610016187XA CN100569494C (en) | 2006-10-23 | 2006-10-23 | The polymethyl methacrylate enhanced by 3 D weaving carbon fiber composite material and preparation method thereof |
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| CN1958275A true CN1958275A (en) | 2007-05-09 |
| CN100569494C CN100569494C (en) | 2009-12-16 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101905503A (en) * | 2010-08-04 | 2010-12-08 | 浙江恒林椅业股份有限公司 | Method for producing acryl chair back |
| CN102107534A (en) * | 2009-12-29 | 2011-06-29 | 合肥杰事杰新材料有限公司 | Method for manufacturing bicycle frame by using continuous fiber reinforced thermoplastic composite materials |
| CN102477199A (en) * | 2010-11-25 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Organic fiber cloth filled polymethyl methacrylate composite board and preparation method thereof |
| CN103172512A (en) * | 2011-12-23 | 2013-06-26 | 中国医学科学院医药生物技术研究所 | Cajanin compound with similar structures, as well as preparation method and application thereof |
| CN105315475A (en) * | 2014-07-16 | 2016-02-10 | 合复新材料科技(无锡)有限公司 | Fiber reinforced resin composite material, preparation method and applications thereof |
| CN110835807A (en) * | 2019-11-29 | 2020-02-25 | 吉林大学 | Carbon fiber reinforced polyether-ether-ketone fiber composite material and preparation method and application thereof |
| CN111875729A (en) * | 2020-07-08 | 2020-11-03 | 中国航发北京航空材料研究院 | Methyl methacrylate resin in-situ polymerization system for forming carbon fiber composite material |
| CN111976171A (en) * | 2020-07-08 | 2020-11-24 | 中国航发北京航空材料研究院 | In-situ polymerization carbon fiber reinforced polymethyl methacrylate composite material forming method |
-
2006
- 2006-10-23 CN CNB200610016187XA patent/CN100569494C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102107534A (en) * | 2009-12-29 | 2011-06-29 | 合肥杰事杰新材料有限公司 | Method for manufacturing bicycle frame by using continuous fiber reinforced thermoplastic composite materials |
| CN102107534B (en) * | 2009-12-29 | 2013-06-26 | 合肥杰事杰新材料股份有限公司 | Method for manufacturing bicycle frame by using continuous fiber reinforced thermoplastic composite materials |
| CN101905503A (en) * | 2010-08-04 | 2010-12-08 | 浙江恒林椅业股份有限公司 | Method for producing acryl chair back |
| CN101905503B (en) * | 2010-08-04 | 2012-07-04 | 浙江恒林椅业股份有限公司 | Method for producing acryl chair back |
| CN102477199A (en) * | 2010-11-25 | 2012-05-30 | 合肥杰事杰新材料股份有限公司 | Organic fiber cloth filled polymethyl methacrylate composite board and preparation method thereof |
| CN102477199B (en) * | 2010-11-25 | 2015-06-24 | 合肥杰事杰新材料股份有限公司 | Organic fiber cloth filled polymethylmethacrylate composite plate material and its preparation method |
| CN103172512A (en) * | 2011-12-23 | 2013-06-26 | 中国医学科学院医药生物技术研究所 | Cajanin compound with similar structures, as well as preparation method and application thereof |
| CN105315475A (en) * | 2014-07-16 | 2016-02-10 | 合复新材料科技(无锡)有限公司 | Fiber reinforced resin composite material, preparation method and applications thereof |
| CN105315475B (en) * | 2014-07-16 | 2018-05-04 | 合复新材料科技(无锡)有限公司 | Fiber-resin composite and its preparation method and application |
| CN110835807A (en) * | 2019-11-29 | 2020-02-25 | 吉林大学 | Carbon fiber reinforced polyether-ether-ketone fiber composite material and preparation method and application thereof |
| CN111875729A (en) * | 2020-07-08 | 2020-11-03 | 中国航发北京航空材料研究院 | Methyl methacrylate resin in-situ polymerization system for forming carbon fiber composite material |
| CN111976171A (en) * | 2020-07-08 | 2020-11-24 | 中国航发北京航空材料研究院 | In-situ polymerization carbon fiber reinforced polymethyl methacrylate composite material forming method |
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Granted publication date: 20091216 Termination date: 20101023 |