CN1952013A - Flame-proof bactericidal plant fiber powder/ high polymer plastic composite hollow straight tube and its preparation method - Google Patents

Flame-proof bactericidal plant fiber powder/ high polymer plastic composite hollow straight tube and its preparation method Download PDF

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Publication number
CN1952013A
CN1952013A CN 200610096282 CN200610096282A CN1952013A CN 1952013 A CN1952013 A CN 1952013A CN 200610096282 CN200610096282 CN 200610096282 CN 200610096282 A CN200610096282 A CN 200610096282A CN 1952013 A CN1952013 A CN 1952013A
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China
Prior art keywords
plant fiber
fiber powder
hollow straight
straight tube
retardant
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CN 200610096282
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Chinese (zh)
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CN100434481C (en
Inventor
华明扬
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Individual
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Individual
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Priority to CNB2006100962825A priority Critical patent/CN100434481C/en
Publication of CN1952013A publication Critical patent/CN1952013A/en
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Publication of CN100434481C publication Critical patent/CN100434481C/en
Expired - Fee Related legal-status Critical Current
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  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a composite hollow straight-tube of flame-proof, sterilization plant fiber powder/macromolecular plastic, which comprises the following parts: 55-75% plant fiber powder, 25-40% waste macromolecular plastic, 2-5% composite fire retardant, 0.5-1% heat stabilizer, 1-2% sterile and 1-2% plasticizer. The preparing method comprises the following steps: allocating plant fiber powder and waste macromolecular plastic, composite fire retardant, plasticizer, heat stabilizer and sterile according to mating rate; setting the breadth at 3-8mm and length at 8-12mm; squeezing plastic once continuously; cutting; rotating side; coating end; moulding through heat to obtain the hollow straight pipe.

Description

Fire-retardant, bactericidal plant fiber powder/high polymer plastic composite hollow straight tube and preparation method thereof
Technical field
The present invention relates to be used in a kind of weaving around cloth, winding yarns, around paper, around plastic film, around the hollow straight tube of aluminium foil film, be particularly related to a kind of fire-retardant, bactericidal plant fiber powder/high polymer plastic composite hollow straight tube and preparation method thereof, replace original papery and in layer glue together the hollow straight tube of making.
Background technology
The papery hollow tubing that every profession and trade is used.The waste water that papery tubing produces when making paper pulp brings very big pollution, very not environmental protection to environment.The papery pipe in layer glues together to be made, and labour intensity is big, and degree of compactness is poor, poor dimensional stability.Therefore finding the material of more environmental protection to replace paper tube is scientific and technological progress of industry.
Summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, a kind of fire-retardant, bactericidal plant fiber powder/high polymer plastic composite hollow straight tube and preparation method thereof is provided.Replace original papery hollow straight tube.
The object of the present invention is achieved like this: a kind of fire-retardant, bactericidal plant fiber powder/high polymer plastic composite hollow straight tube is characterized in that it mainly is made up of the raw material of following weight part:
Plant fiber powder 55-75 part
Spent high molecular plastics 25-40 part
Composite flame-retardant agent 2-5 part
Thermo-stabilizer 0.5-1 part
Sterilant 1-2 part
Softening agent 1-2 part;
Described plant fiber powder is the stalk fibre powder of stalk fibre powder or germicidal treatment, comprises stalk fibre powder such as soybean stalk, straw, straw, sorghum stalk, weeds, tobacco leaf stalk, husk class, and granularity is the 20-50 order;
Waste and old polyethylene, polypropylene or the polyvinyl chloride of described spent high molecular plastics for reclaiming;
Described composite flame-retardant agent is that both weight ratios are: polygorskite by the compound of polygorskite and tripolyphosphate ammonium: tripolyphosphate ammonium=6~8: 1;
Described thermo-stabilizer is calcium stearate or tribasic Tai-Ace S 150;
Described sterilant is isothiazolinone, Ka Song or triumphant pine;
Described softening agent is a phthalate, can be phthalic acid-2-ethylhexyl, o-phthalic acid dibutyl ester or diethyl phthalate.
Preparation method of the present invention is: by proportioning plant fiber powder and spent high molecular plastics, composite flame-retardant agent and softening agent, thermo-stabilizer, sterilant mixing granulation in screw extrusion press are made composite particles earlier, be of a size of wide 3-8mm, long 8-12mm; Once continuously shaped on the plastic shaping forcing machine, extruded product.Tint, be thermoformed into hollow straight tube through cutting, commentaries on classics limit, end.
The present invention adopts plant fiber powder and waste and old high molecule plastic blend granulation, and moulding revests its fire-retardant performance.This products characteristics is to utilize materials such as waste and old plastics and vegetable fibre, and the product structure of preparation is tight, dimensional stabilizing, and waterproof, fire-retardant.Production cost is low, can the serialization industrial production, and product can cyclic regeneration, save energy, cleaner production is environmentally friendly product.
Embodiment
Embodiment 1:
Broomcorn straw fiber powder 60Kg, calcium stearate 1Kg, isothiazolinone 1.5Kg, 3Kg composite flame-retardant agent, 1Kg phthalic acid-2-ethylhexyl mixing granulation in screw extrusion press of waste and old polyethylene 30Kg and germicidal treatment are made 5 *The composite particles of 10mm; Once continuously shaped on the plastic shaping forcing machine, extruded product.Tint, be thermoformed into the hollow straight tube of national standard size through cutting, commentaries on classics limit, end.Wherein composite flame-retardant agent is that both weight ratios are: polygorskite by the compound of polygorskite and tripolyphosphate ammonium: tripolyphosphate ammonium=6: 1.
Embodiment 2
With waste and old polyvinyl chloride 30Kg and tobacco leaf stalk fibre powder 60Kg, tribasic Tai-Ace S 150 0.5Kg, block loose 1Kg, 2Kg composite flame-retardant agent, 2Kg phthalic acid-2-ethylhexyl mixing granulation in screw extrusion press and make 5 *The composite particles of 10mm; Once continuously shaped on the plastic shaping forcing machine, extruded product.Tint, be thermoformed into the hollow straight tube of national standard size through cutting, commentaries on classics limit, end.Wherein composite flame-retardant agent is that both weight ratios are: polygorskite by the compound of polygorskite and tripolyphosphate ammonium: tripolyphosphate ammonium=8: 1.
Embodiment 3
Waste and old polyethylene 35Kg and rice straw fiber powder 80Kg, calcium stearate 1Kg, triumphant loose 1Kg, 3Kg composite flame-retardant agent, 1.5Kg o-phthalic acid dibutyl ester mixing granulation in screw extrusion press are made 6 *The composite particles of 10mm; Once continuously shaped on the plastic shaping forcing machine, extruded product.Tint, be thermoformed into the hollow straight tube of national standard size through cutting, commentaries on classics limit, end.Wherein composite flame-retardant agent is that both weight ratios are: polygorskite by the compound of polygorskite and tripolyphosphate ammonium: tripolyphosphate ammonium=7: 1.
Embodiment 4
Waste and old polypropylene 30Kg and wheat straw fibre powder 60Kg, calcium stearate 1Kg, triumphant loose 1.5Kg, 5Kg composite flame-retardant agent, 1Kg diethyl phthalate mixing granulation in screw extrusion press are made 5 *The composite particles of 10mm; Once continuously shaped on the plastic shaping forcing machine, extruded product.Tint, be thermoformed into the hollow straight tube of national standard size through cutting, commentaries on classics limit, end.Wherein composite flame-retardant agent is that both weight ratios are: polygorskite by the compound of polygorskite and tripolyphosphate ammonium: tripolyphosphate ammonium=7: 1.

Claims (2)

1, a kind of fire-retardant, bactericidal plant fiber powder/high polymer plastic composite hollow straight tube is characterized in that it mainly is made up of the raw material of following weight part:
Plant fiber powder 55-75 part
Spent high molecular plastics 25-40 part
Composite flame-retardant agent 2-5 part
Thermo-stabilizer 0.5-1 part
Sterilant 1-2 part
Softening agent 1-2 part;
Described plant fiber powder is the stalk fibre powder of stalk fibre powder or germicidal treatment, comprises stalk fibre powder such as soybean stalk, straw, straw, sorghum stalk, weeds, tobacco leaf stalk, husk class, and granularity is the 20-50 order;
Waste and old polyethylene, polypropylene or the polyvinyl chloride of described spent high molecular plastics for reclaiming;
Described composite flame-retardant agent is that both weight ratios are: polygorskite by the compound of polygorskite and tripolyphosphate ammonium: tripolyphosphate ammonium=6~8: 1;
Described thermo-stabilizer is calcium stearate or tribasic Tai-Ace S 150;
Described sterilant is isothiazolinone, Ka Song or triumphant pine;
Described softening agent is a phthalate, is phthalic acid-2-ethylhexyl, o-phthalic acid dibutyl ester or diethyl phthalate.
2, a kind of preparation method of fire-retardant, bactericidal plant fiber powder/high polymer plastic composite hollow straight tube as claimed in claim 1, it is characterized in that this method comprises following processing step: by proportioning plant fiber powder and spent high molecular plastics, composite flame-retardant agent and softening agent, thermo-stabilizer, sterilant mixing granulation in screw extrusion press are made composite particles earlier, be of a size of wide 3-8mm, long 8-12mm; Once continuously shaped on the plastic shaping forcing machine, extruded product.Tint, be thermoformed into hollow straight tube through cutting, commentaries on classics limit, end.
CNB2006100962825A 2006-10-09 2006-10-09 Flame-proof bactericidal plant fiber powder/ high polymer plastic composite hollow straight tube and its preparation method Expired - Fee Related CN100434481C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100962825A CN100434481C (en) 2006-10-09 2006-10-09 Flame-proof bactericidal plant fiber powder/ high polymer plastic composite hollow straight tube and its preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100962825A CN100434481C (en) 2006-10-09 2006-10-09 Flame-proof bactericidal plant fiber powder/ high polymer plastic composite hollow straight tube and its preparation method

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CN1952013A true CN1952013A (en) 2007-04-25
CN100434481C CN100434481C (en) 2008-11-19

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101173079B (en) * 2007-10-19 2010-04-14 东北林业大学 Xylem filber-polyvinyl chloride composite material and method for producing the same
CN101787167A (en) * 2010-02-26 2010-07-28 华南师范大学 High-performance antibiosis wood plastic composite material and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1101838C (en) * 1999-07-23 2003-02-19 四川大学 Production method of straw and plastic composite material
JP2002003693A (en) * 2000-06-21 2002-01-09 Mitsui Chemicals Inc Thermoplastic resin composition and its molded article
CN1467246A (en) * 2002-07-10 2004-01-14 邢加林 Plastic wood flour composite material building section bar and making method thereof
CN1536028A (en) * 2003-04-09 2004-10-13 上海铭新环卫工程科技有限公司 Wheat straw plastics composite material
CN1320064C (en) * 2004-07-02 2007-06-06 袁学发 Novel materials made of waste plastic and plant fibre and method for making same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101173079B (en) * 2007-10-19 2010-04-14 东北林业大学 Xylem filber-polyvinyl chloride composite material and method for producing the same
CN101787167A (en) * 2010-02-26 2010-07-28 华南师范大学 High-performance antibiosis wood plastic composite material and preparation method thereof
CN101787167B (en) * 2010-02-26 2011-08-03 华南师范大学 High-performance antibiosis wood plastic composite material and preparation method thereof

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CN100434481C (en) 2008-11-19

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C06 Publication
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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Jiangyin Ruco Technology Co., Ltd.

Assignor: Hua Mingyang

Contract fulfillment period: 2009.4.10 to 2014.4.10 contract change

Contract record no.: 2009320000800

Denomination of invention: Flame-proof bactericidal plant fiber powder/ high polymer plastic composite hollow straight tube and its preparation method

Granted publication date: 20081119

License type: Exclusive license

Record date: 2009.5.6

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.4.10 TO 2014.4.10; CHANGE OF CONTRACT

Name of requester: JIANGYIN CITY NUOKE SCIENCE CO., LTD.

Effective date: 20090506

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20081119

Termination date: 20151009

EXPY Termination of patent right or utility model