CN1945869A - Piezoelectric driving device of functional gradient structure and its preparing method - Google Patents
Piezoelectric driving device of functional gradient structure and its preparing method Download PDFInfo
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- CN1945869A CN1945869A CN200610114005.2A CN200610114005A CN1945869A CN 1945869 A CN1945869 A CN 1945869A CN 200610114005 A CN200610114005 A CN 200610114005A CN 1945869 A CN1945869 A CN 1945869A
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- 238000000034 method Methods 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229910052709 silver Inorganic materials 0.000 claims description 23
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- 238000005245 sintering Methods 0.000 claims description 8
- 238000013461 design Methods 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 5
- 239000011812 mixed powder Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- 230000010287 polarization Effects 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims 3
- 230000005494 condensation Effects 0.000 claims 3
- 238000003475 lamination Methods 0.000 claims 3
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 14
- 239000000843 powder Substances 0.000 abstract description 13
- 238000002360 preparation method Methods 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 238000000465 moulding Methods 0.000 abstract 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 27
- 239000002184 metal Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000005452 bending Methods 0.000 description 5
- 241000446313 Lamella Species 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
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- 229910003460 diamond Inorganic materials 0.000 description 1
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- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
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- 239000004570 mortar (masonry) Substances 0.000 description 1
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- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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Abstract
This invention relates to a piezoelectric drive device and its preparation method for a function grads structure, which applies a powder sinter method to composite PZT piezoelectric ceramics and Ag to form a piezoelectric ceramic compound material with varied Ag composition grads by altering Ag content one layer by one layer, coats Ag electrode on the up and down surfaces of the material and cuts it to molding to get a piezoelectric driver of the PZT/Ag functional grads structure, the sinter temperature of the material is 900-1200deg.C and the maximum content of Ag is 15vol%.
Description
Technical field
The invention belongs to cantilever beam structure piezoelectric actuator technical field, piezoelectric driving device of a kind of function gradient structure and preparation method thereof particularly is provided.Be applied to the control of micrometric displacement or micrometeor, and can be for a long time, the ceramic/metal function gradient structure piezoelectric actuator of steady operation.
Background technology
Piezoelectric actuator (being also referred to as actuator, motor, actuator etc.) all is widely used at key areas such as Industry Control, medicine equipment, household electrical appliances, auto industry, aerospace industries as control and accurately setting element automatically.The twin lamella piezoelectric actuator is connected two potsherds by organic binder bond with intermediate metal film, owing to there is bonding interface, this quasi-driver the phenomenon that interfacial stress is concentrated and ftractureed occurs in the process under arms, brings hidden danger with being on active service safely for the efficient operation of driver.In order to solve the interfacial failure problem of twin lamella piezoelectric actuator, Functionally Graded Materials (functionally graded materials is used for reference in many researchs, FGM) notion, by add foreign peoples's pottery in the piezoelectric ceramic matrix, the gradient-structure that adopts composition to change is one by one eliminated the ceramic/metal bonding interface.The Wu of US Naval Research Laboratory etc. are by the diffusion of control boronation zinc, prepared single-chip driver replacement traditional twin lamella driver (C.C.M.Wu, et al., the J.Am.Ceram.Soc. of resistance along the thickness direction graded, Vol.79,809-812 (1996)).The Kahn of Virginia, USA etc. concentrate for the stress that reduces piezoelectric actuator inside, the graded that forms piezoelectric property by blended metal oxide produces stress deformation (the M.Kahn et al. of mutual coordination, " Actuator with graded activity ", U.S. Patent number: US5519278A (1996)).Meng Zhongyan etc. take the lead in studying the functionally gradient piezoelectric actuator at home, priority designs and has synthesized dielectric type and two kinds of functionally gradient piezoelectric ceramic actuators of resistor-type (X.Zhu and Z.Meng, Sensors andActuators A, Vol.48,169-176 (1995)).Yet,, there is no obvious improvement by the mechanical property of adding the heterogeneous ceramic pottery/ceramic composite that forms for above-described functionally gradient piezoelectric actuator.Because the twin lamella piezoelectric actuator must be out of shape under high frequency loads in alternating bending, therefore requires actuator material to have excellent mechanical property, piezoelectric ceramic/metallic composite will be desirable candidate material.
The Li Jing of Tsing-Hua University cutting edge of a knife or a sword etc. utilizes metal Pt complex sintered with piezoelectric ceramic PZT as second, has prepared the piezoelectric ceramic actuator (J.-F.Li, et al., Appl.Phys.Lett., Vol.79,2441-2443 (2001)) of PZT/Pt function gradient structure.PZT/Pt functionally gradient piezoelectric actuator has not only improved unborn interfacial stress to be concentrated, and the dispersion-strengtherning of metal second phase has also significantly improved the matrix strength and the fracture toughness of PZT/Pt composite material.Although PZT/Pt functionally gradient piezoelectric actuator combination property is superior, yet the price of Pt costliness has increased production cost and has limited extensive use in practice.
Summary of the invention
The object of the present invention is to provide piezoelectric driving device of a kind of function gradient structure and preparation method thereof, with metal A g as second with the design and the preparation method of the complex sintered function gradient structure piezoelectric actuator of piezoelectric ceramic lead zirconate titanate (PZT).
On the piezoelectric driving device of function gradient structure of the present invention under be followed successively by silver electrode, PZT/Ag composite material, silver electrode, Ag content is 0-15vol% in the composite material, the thickness of each composite bed is the 0.2-0.5 millimeter, and the gross thickness of piezoelectric driving device is the 1-2 millimeter.The described piezoelectric driving device number of plies is the 2-7 layer.
The present invention provides a kind of preparation method of ceramic/metal function gradient structure piezoelectric actuator simultaneously.Preparation PZT/Ag mixed-powder in the Ag of 0-15vol% composition range, Ag content and thickness according to theory of hierarchies and each composite bed of ANSYS finite element analysis software optimal design, in the cylinder type mould, successively pile up and obtain Ag content continually varying PZT/Ag multilayer materials, in 900-1200 ℃ of temperature range, gained disk upper and lower surface is applied the silver electrode and the processing that polarizes after normal pressure-sintered, according to the corresponding size excision forming and draw lead, an end is fixed and is constituted cantilever beam structure along its length, prepares the piezoelectric actuator of PZT/Ag function gradient structure.
The Ag content of prepared each composite bed of PZT/Ag functionally gradient piezoelectric actuator is between 0-15vol%, and every layer thickness is between the 0.2-0.5 millimeter, and the length of cantilever beam driver and thickness are respectively between 8-15 millimeter and 1-2 millimeter.Optimizing structure of described functionally gradient piezoelectric actuator is that PZT/5%Ag/15%Ag, each layer thickness are the 0.33/0.33/0.33 millimeter, and the number of plies of piezo-electricity composite material is 3 layers.
Preparation PZT/Ag function gradient structure piezoelectric actuator carries out as follows:
(a) in the Ag of 0-15vol% composition range, according to different proportionings PZT and Ag powder are ground half an hour at least to guarantee the even mixing of two kinds of powder in mortar, polyvinyl alcohol (PVA) aqueous solution that in mixed-powder, adds several 5wt% content as binding agent to help follow-up moulded section.
(b) calculate the thickness of the different Ag content of optimal design composite bed with theory of hierarchies and finite element analysis software.According to the weigh with scale PZT/Ag composite powder of different Ag content of optimal design parameter, according to the order of setting lay successively, the composition of each composite bed changes as shown in Figure 1 in the cylinder type stainless steel mould.In the lay process of powder, must keep every layer smooth obtaining having the composite bed at straight interface, and the pressure that must note control mould pressure head is to avoid occurring delamination.
(c) under 100MP pressure, the powder in the stainless steel mould is carried out moulded section with tablet press machine.
(d) sample behind the pressing mold is put into the latex jacket and is immersed oil body, with cold isostatic press sample is carried out isostatic cool pressing and handle under 200MP pressure.
(e) sample after isostatic cool pressing is handled is put into the alumina crucible sintering of sealing, and at sample placed around PbZrO
3Powder is to prevent the excessive volatilization of Pb in the sample.Insulation makes the PVA in the sample volatilize fully half an hour near 200 ℃ of temperature earlier, and sintering was carried out in insulation in 1-2 hour in 900-1200 ℃ of temperature range at last.Whole sintering process is carried out in air.
(f) the disc sample upper and lower surface behind the sintering polishes flat and applies silver slurry preparation silver electrode, under the electric field of 1-2kV/cm, and keeps the processing that polarizes in 10 minutes in 120 ℃ silicone oil.
(g) sample after polarization is handled cuts into the square column shape on the diamond scribing machine, and draws silver-colored lead in the upper and lower surface of square column.
Beneficial effect of the present invention is, increase Ag content successively along the piezoelectric actuator thickness direction and make the PZT/Ag piezo-electricity composite material have the piezoelectric property that successively decreases successively and the electricity that thereupon successively decreases causes driveability, the compatible deformation between each composite bed has avoided the bigger stress that produces at the interface between layer and layer to concentrate.Ag second splits job stability and the service life that toughening effect has significantly improved piezoelectric actuator with respect to the dispersion-strengtherning of PZT matrix and resistance, thus be particularly useful in specific environment when long, the Primary Component and the equipment of continuous operation.Result of study shows, compares with the PZT matrix, and the Ag that adds 15vol% makes the fracture strength of PZT/Ag composite material increase more than 1 times, and fracture toughness then increases more than 3 times.Figure 2 shows that microstructure pattern by each component layer of functionally gradient piezoelectric actuator of method for preparing.As can be seen from Figure 2, the thickness of three component layers is all in 0.3 millimeter, and the driver gross thickness is about 1.0 millimeters.Upper and lower surface to functionally gradient piezoelectric actuator shown in Figure 2 applies direct voltage, detects its bending curvature k (can further be scaled cantilever beam tip displacement ε) under different electric field actions.Testing result shown in Figure 3 shows, under the voltage effect below the 400V, applies between voltage and the bending curvature roughly linearly, begins to occur nonlinear variation at the above bending curvature of 400V.The result of calculation of testing result and traditional double wafer piezoelectric actuator is more or less the same, but the mechanical property of functionally gradient piezoelectric actuator and military service characteristic are significantly improved among the present invention.
Description of drawings
Fig. 1 is the structural representation of ceramic/metal function gradient structure piezoelectric actuator.
Fig. 2 is the microstructure photograph of the PZT/Ag 3-layer composite material for preparing.
Fig. 3 is that the prepared bending curvature of piezoelectric actuator under different electric field actions changes.
Embodiment
PZT used in the present invention and Ag raw material are commercially available.
Embodiment 1:
With commercially available PZT powder (Japanese Sakai chemical industrial company, the Zr/Ti mol ratio is 0.516/0.484, average grain diameter is 0.97 micron) and Ag powder (Japanese high-purity chemical company, purity is 99.9wt%, average grain diameter is 2.0 microns) be raw material, prepared three layers of compound functionally gradient piezoelectric actuator of PZT/5%Ag/15%Ag at 1200 ℃ of sintering temperatures, each layer thickness is 0.33 millimeter, and cantilever beam is of a size of 12 * 2 * 1 millimeter.
Embodiment 2:
With commercially available PZT powder (Japanese Sakai chemical industrial company, the Zr/Ti mol ratio is 0.516/0.484, average grain diameter is 0.97 micron) and Ag powder (Japanese high-purity chemical company, purity is 99.9wt%, average grain diameter is 2.0 microns) be raw material, prepared five layers of compound functionally gradient piezoelectric actuator of PZT/1%Ag/5%Ag/10%Ag/15%Ag at 1160 ℃ of sintering temperatures, each layer thickness is 0.4 millimeter, and cantilever beam is of a size of 15 * 3 * 2 millimeters.
Embodiment 3:
With commercially available PZT powder (Japanese Sakai chemical industrial company, the Zr/Ti mol ratio is 0.516/0.484, average grain diameter is 0.97 micron) and Ag powder (Japanese high-purity chemical company, purity is 99.9wt%, average grain diameter is 2.0 microns) be raw material, prepared seven layers of compound functionally gradient piezoelectric actuator of 1%Ag/3%Ag/5%Ag/10%Ag/5%Ag/3%Ag/1%Ag at 900 ℃ of sintering temperatures, each layer thickness is 0.2 millimeter, and cantilever beam is of a size of 8 * 2 * 1.5 millimeters.
Claims (5)
1. the piezoelectric driving device of a function gradient structure, it is characterized in that: on this device under be followed successively by silver electrode, PZT/Ag composite material, silver electrode, Ag content is 0-15vol% in the composite material, the thickness of each composite bed is the 0.2-0.5 millimeter, and the gross thickness of piezoelectric driving device is the 1-2 millimeter.
2. according to the described device of claim 1, it is characterized in that: the described piezoelectric driving device number of plies is the 2-7 layer.
3. method for preparing the described device of claim 1, it is characterized in that: be added to PZT with Ag as second and regulate and control its dielectric and piezoelectric property, reply the function gradient structure piezoelectric actuator that condensation material constitutes by cable by the 2-7 lamination by successively changing the formation of Ag content; At first carry out the optimal design of Ag content and the mixed-powder of proportioning PZT and Ag, the mixed-powder that successively piles up different Ag content in mould forms the graded of Ag composition, adopt the ordinary sinter method to prepare the PZT/Ag piezo-electricity composite material through pressing mold and isostatic cool pressing processing back, upper and lower surface at composite material applies silver electrode, polarization, excision forming, traction lead, an end is fixed and is constituted cantilever beam structure along its length, prepares the piezoelectric actuator of PZT/Ag function gradient structure.
4. method according to claim 3 is characterized in that: the sintering temperature that described 2-7 lamination is replied condensation material by cable is 900-1200 ℃.
5. method according to claim 3 is characterized in that: the Ag content that described 2-7 lamination is replied condensation material by cable is 0-15vol%.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101537494B (en) * | 2009-04-29 | 2010-07-28 | 北京科技大学 | Method for preparing nickel particle dispersion barium calcium zirconate titanate piezoelectric composite material |
| CN101981801A (en) * | 2008-04-01 | 2011-02-23 | 株式会社村田制作所 | Piezoelectric power-generating unit |
| CN102060529A (en) * | 2011-01-22 | 2011-05-18 | 浙江大学 | Nano Ag particle-Pb(Zr0.52Ti0.48)O3 filtration type composite ceramic film and preparation method thereof |
| CN102589966A (en) * | 2012-01-17 | 2012-07-18 | 上海海事大学 | Method for measuring elasticity modulus and shear modulus of functionally graded material beam |
| CN104092402A (en) * | 2014-07-31 | 2014-10-08 | 王少夫 | Piezoelectric ceramic transformer |
| CN106003849A (en) * | 2016-05-12 | 2016-10-12 | 吉林大学 | Functionally graded piezoelectric material preparation method for improving anti-fracture performance |
| CN109239189A (en) * | 2018-09-20 | 2019-01-18 | 河南理工大学 | High-temperature pipe supersonic guide-wave based on functionally graded material monitors system and method |
| CN114644510A (en) * | 2022-01-18 | 2022-06-21 | 燕山大学 | Ceramic cutter material with piezoelectric effect, preparation method thereof and cutting tool |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH0610100B2 (en) * | 1990-01-26 | 1994-02-09 | 日本電気株式会社 | Porcelain composition |
| US5935485A (en) * | 1996-10-31 | 1999-08-10 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Piezoelectric material and piezoelectric element |
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- 2006-10-24 CN CNB2006101140052A patent/CN100449813C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101981801A (en) * | 2008-04-01 | 2011-02-23 | 株式会社村田制作所 | Piezoelectric power-generating unit |
| CN101981801B (en) * | 2008-04-01 | 2013-08-28 | 株式会社村田制作所 | Piezoelectric power-generating unit |
| CN101537494B (en) * | 2009-04-29 | 2010-07-28 | 北京科技大学 | Method for preparing nickel particle dispersion barium calcium zirconate titanate piezoelectric composite material |
| CN102060529A (en) * | 2011-01-22 | 2011-05-18 | 浙江大学 | Nano Ag particle-Pb(Zr0.52Ti0.48)O3 filtration type composite ceramic film and preparation method thereof |
| CN102589966A (en) * | 2012-01-17 | 2012-07-18 | 上海海事大学 | Method for measuring elasticity modulus and shear modulus of functionally graded material beam |
| CN104092402A (en) * | 2014-07-31 | 2014-10-08 | 王少夫 | Piezoelectric ceramic transformer |
| CN106003849A (en) * | 2016-05-12 | 2016-10-12 | 吉林大学 | Functionally graded piezoelectric material preparation method for improving anti-fracture performance |
| CN106003849B (en) * | 2016-05-12 | 2017-11-14 | 吉林大学 | A kind of functionally graded piezoelectric strip preparation method that can improve break resistance |
| CN109239189A (en) * | 2018-09-20 | 2019-01-18 | 河南理工大学 | High-temperature pipe supersonic guide-wave based on functionally graded material monitors system and method |
| CN114644510A (en) * | 2022-01-18 | 2022-06-21 | 燕山大学 | Ceramic cutter material with piezoelectric effect, preparation method thereof and cutting tool |
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