CN1937924A - Herbicide-safener combination - Google Patents
Herbicide-safener combination Download PDFInfo
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- CN1937924A CN1937924A CN 200580009946 CN200580009946A CN1937924A CN 1937924 A CN1937924 A CN 1937924A CN 200580009946 CN200580009946 CN 200580009946 CN 200580009946 A CN200580009946 A CN 200580009946A CN 1937924 A CN1937924 A CN 1937924A
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Abstract
A herbicide-safener combination contains (A) one or more compounds of formula (I) or their salts, and (B) one or more safeners. In the formula (I), A stands for nitrogen or a CR<11> group, R<11> designating hydrogen, alkyl, halogen and haloalkyl; R<1> stands for hydrogen or an optionally substituted residue from the series composed of alkyl, alkoxy, alkoxyalkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl; R<2> stands for hydrogen, halogen or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having 1-6 carbon atoms; R<3> stands for hydrogen, halogen or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having 1-6 carbon atoms; R<4>-R<7> independently stand for hydrogen, halogen, cyano, thiocyanato or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having 1-3 carbon atoms; and R<8> stands for hydrogen, halogen, cyano, thiocyanato or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having 1-3 carbon atoms. In the above-mentioned residues, each of the alkyl and alkylene groups can have 1-6 C atoms, each of the alkenyl and alkinyl groups can have 2-6 C atoms, each of the cycloalkyl groups can have 3-6 C atoms and each of the aryl groups can have 6-10 C atoms.
Description
The present invention relates to the plant protection composition technical field, especially highly be applicable to the herbicide-safener combination of the noxious plant in the useful crop of control.
US 5,476, and 936 disclose the weeding active compound of control broad-spectrum weeding.Yet part reactive compound wherein is also not exclusively compatible with some important crop such as cereal.Therefore in the part crop, their use can not be guaranteed the broad-spectrum weed-killing activity of required control noxious plant.
Target of the present invention provides and improves the optionally Herbicidal combinations of above-mentioned weed killer herbicide in important crop.Surprisingly, this target reaches by herbicide-safener combination of the present invention.
Therefore, the invention provides a kind of herbicide-safener combination, it comprises
(A) one or more formulas (I) compound or its salt
Wherein
A is nitrogen or CR
11-group,
Wherein
R
11Be hydrogen, alkyl, halogen and alkylhalide group,
R
1Group for group under hydrogen or optional being selected from that is substituted: alkyl, alkoxyl, alkoxyalkyl, thiazolinyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, aralkyl and aryl,
R
2Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that have 1 to 6 carbon atom respectively that replaces through halogen,
R
3Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that have 1 to 6 carbon atom respectively that replaces through halogen,
R
4-R
7Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group, the alkyl amino-carbonyl that have 1 to 3 carbon atom respectively that replaces through halogen independently of one another
R
8Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group, the alkyl amino-carbonyl that have 1 to 3 carbon atom respectively that replaces through halogen,
Wherein in above-mentioned group, alkyl and alkylidene can contain 1 to 6 carbon atom respectively, and thiazolinyl and alkynyl can contain 2 to 6 carbon atoms respectively, and cycloalkyl can contain 3 to 6 carbon atoms respectively, and aryl can contain 6 or 10 carbon atoms respectively; With
(B) one or more safeners.
Herbicide-safener combination of the present invention can also comprise other component, the conventional additives in for example dissimilar plant protection products and/or formulation auxiliary agents and/or the plant protection, or said composition can be used with these other components.
Weed killer herbicide (A) and safener (B) can be used with known method, for example use (for example to be total to preparation or the mixed thing form of bucket) together, or are applied to for example plant, plant part, plant seed or plant growing zone respectively.Can be for example use single reactive compound or herbicide-safener combination (order is used) with many parts, for example behind the preemergence application, subsequently postemergence application, or behind the early stage postemergence application, subsequently mid-term or late period postemergence application.Here preferably simultaneously or almost simultaneously use described reactive compound combination.Single reactive compound or herbicide-safener combination can also be used for seed dressing.
Above-mentioned formula (I) compound comprises all stereoisomers and composition thereof, comprises that especially racemic mixture-Ruo can be an enantiomter-then can be each biologically active enantiomter.
Formula (I) compound and salt thereof are known, and its preparation method is known in for example US5,476,936, and the document is introduced the present invention with for referencial use.
Preferred weed killer herbicide (A) is as shown in the formula (I) compound and salt thereof
Wherein
A is nitrogen or CH-group,
R
1Be hydrogen or the optional respectively group that has group under being selected from of 3 carbon atoms respectively that replaces through halogen: alkyl, alkoxyl, alkoxyalkyl, thiazolinyl and alkynyl,
R
2Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen,
R
3Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen,
R
4-R
7Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group or the alkyl amino-carbonyl that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen independently of one another
R
8Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group or the alkyl amino-carbonyl that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen
Preferred weed killer herbicide (A) can also be by formula (I) salt that compound and alkali obtained by conventional method, described alkali is for example sodium hydroxide, sodium hydride, Sodamide and sodium carbonate, potassium hydroxide, hydrofining, potassamide and potash, or slaked lime, calcium hydride, amino calcium and calcium carbonate, C
1-C
4-sodium alkoxide or C
1-C
4-alkanol potassium, ammonia, C
1-C
4-alkylamine, two-(C
1-C
4-alkyl)-amine or three-(C
1-C
4-alkyl)-amine.
Especially preferred weed killer herbicide (A) is as shown in the formula (I) compound and salt thereof
Wherein
A is nitrogen or CH-group,
R
1Be hydrogen, methyl, ethyl, methoxyl group, methoxy or ethyoxyl,
R
2Be hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxyl group, ethyoxyl, difluoro-methoxy, methyl mercapto, methylamino or dimethylamino,
R
3Be hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxyl group, ethyoxyl, difluoro-methoxy, methyl mercapto, methylamino or dimethylamino,
R
4-R
7Be hydrogen, fluorine, chlorine, cyano group independently of one another, or optional respectively methyl, methyl mercapto, methylsulfinyl, methyl sulphonyl, methoxycarbonyl group and carbethoxyl group through chlorine or fluorine replacement, preferred hydrogen,
R
8Be hydrogen, fluorine, chlorine, bromine, cyano group; or optional methyl, methoxyl group, ethyoxyl, methyl mercapto, ethylmercapto group, methylsulfinyl, ethyl sulfinyl, methyl sulphonyl, ethylsulfonyl, methylamino or dimethylamino through chlorine or fluorine replacement, preferred hydrogen.
Especially preferred weed killer herbicide (A) is as shown in the formula (I) compound and salt thereof, its alkali metal salt especially,
Wherein
A is a nitrogen,
R
1Be hydrogen or methyl,
R
2Be hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxyl group, ethyoxyl, difluoro-methoxy, methyl mercapto, methylamino or dimethylamino,
R
3Be hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxyl group, ethyoxyl, difluoro-methoxy, methyl mercapto, methylamino or dimethylamino,
R
4-R
7Be hydrogen,
R
8Be hydrogen.
Especially preferred in addition weed killer herbicide (A) is as shown in the formula (I) compound and salt thereof, its alkali metal salt especially,
Wherein
A is the CH-group,
R
1Be hydrogen or methyl,
R
2Be hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxyl group, ethyoxyl, difluoro-methoxy, methyl mercapto, methylamino or dimethylamino,
R
3Be hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxyl group, ethyoxyl, difluoro-methoxy, methyl mercapto, methylamino or dimethylamino,
R
4-R
7Be hydrogen,
R
8Be hydrogen.
Above-mentioned routine or preferred group definition can optionally combine each other, promptly comprise the combination between the described preferable range.
Even do not offer some clarification on, the alkyl described in the group definition for example alkyl, alkenyl or alkynyl can be straight or branched, it comprises and heteroatomic combination, for example alkoxyl, alkylthio group, alkylhalide group or alkyl amino.
Optionally, salt can be made by formula (I) compound, slaine for example, for example alkali metal (Na for example, K) salt or alkaline earth metal (for example Ca, Mg) salt or ammonium salt or amine salt.Obtain this class salt by the conventional method that forms salt in simple mode, for example with formula (I) compound dissolution or be dispersed in the suitable thinner, for example carrene, acetone, t-butyl methyl ether or toluene, and add suitable alkali.Subsequently this salt can-if necessary in continue stirring back-by concentrating or bleeding to filter and separated.
Examples of compounds such as following table 1 as weed killer herbicide (A) are mentioned, wherein use following abbreviation:
The Smp.=fusing point
Under the Zers.oder Z.=decomposition
(+)=indicated fusing point (Smp.) expression sodium salt separately, promptly wherein-SO
2The respective compound that the hydrogen of-NH-group is replaced by sodium.
Table 1: formula (I) examples of compounds, wherein
R
4=R
5=R
6=R
7=R
8=H:
Bsp.- Nr. | ?R 1 | ?A | ?R 2 | ?R 3 | ?Smp. ?(℃) |
I-1 | ?H | ?CH | ?OCH 3 | ?OC 2H 5 | ?154 |
I-2 | ?H | ?CH | ?OCH 3 | ?CH 3 | |
I-3 | ?H | ?CH | ?OHC 3 | ?CH 3 | ?180-181 (+) |
I-4 | ?H | ?CH | ?OCH 3 | ?C 2H 5 | |
I-5 | ?H | ?CH | ?OCH 3 | ?CF 3 | |
I-6 | ?H | ?CH | ?OCH 3 | ?OCF 2H | |
I-7 | ?H | ?CH | ?OCH 3 | ?NHCH 3 | |
I-8 | ?H | ?CH | ?OCH 3 | ?N(CH 3) 2 | ?199.5 |
I-9 | ?H | ?CH | ?OCH 3 | ?Cl | ?110-111 |
I-10 | ?H | ?CH | ?OCH 3 | ?Cl | ?175-178 (+) |
I-11 | ?H | ?CH | ?OCH 3 | ?OCH 3 | ?167-168 |
I-12 | ?H | ?CH | ?OCH 3 | ?OCH 3 | ?171-172 (+) |
I-13 | ?H | ?CH | ?OC 2H 5 | ?OC 2H 5 | |
I-14 | ?H | ?CH | ?OC 2H 5 | ?OC 2H 5 | ?152-154 (+) |
I-15 | ?H | ?CH | ?OC 2H 5 | ?CH 3 | |
I-16 | ?H | ?CH | ?OC 2H 5 | ?C 2H 5 | |
I-17 | ?H | ?CH | ?OC 2H 5 | ?CF 3 | |
I-18 | ?H | ?CH | ?OC 2H 5 | ?OCF 2H | |
I-19 | ?H | ?CH | ?OC 2H 5 | ?NHCH 3 | |
I-20 | ?H | ?CH | ?OC 2H 5 | ?N(CH 3) 2 | |
I-21 | ?H | ?CH | ?OC 2H 5 | ?Cl | ?158-159 |
I-22 | ?H | ?CH | ?OC 2H 5 | ?Cl | ?213 (+) |
I-23 | ?H | ?CH | ?CH 3 | ?CH 3 | ?153 |
I-24 | ?H | ?CH | ?CH 3 | ?C 2H 5 | |
I-25 | ?H | ?CH | ?CH 3 | ?CF 3 | |
I-26 | ?H | ?CH | ?CH 3 | ?OCF 2H | |
I-27 | ?H | ?CH | ?CH 3 | ?NHCH 3 | |
I-28 | ?H | ?CH | ?CH 3 | ?N(CH 3) 2 |
?Bsp.- ?Nr. | ?R 1 | ?A | ?R 2 | ?R 3 | ?Smp. ?(℃) |
?I-29 | ?H | ?CH | ?CH 3 | ?Cl | ?108-109 |
?I-30 | ?H | ?CH | ?CH 3 | ?Cl | ?>300 (+) |
?I-31 | ?H | ?CH | ?C 2H 5 | ?C 2H 5 | |
?I-32 | ?H | ?CH | ?C 2H 5 | ?CF 3 | |
?I-33 | ?H | ?CH | ?C 2H 5 | ?OCF 2H | |
?I-34 | ?H | ?CH | ?C 2H 5 | ?NHCH 3 | |
?I-35 | ?H | ?CH | ?C 2H 5 | ?Cl | |
?I-36 | ?H | ?CH | ?CF 3 | ?CF 3 | |
?I-37 | ?H | ?CH | ?CF 3 | ?OCF 2H | |
?I-38 | ?H | ?CH | ?CF 3 | ?NHCH 3 | |
?I-39 | ?H | ?CH | ?CF 3 | ?N(CH 3) 2 | |
?I-40 | ?H | ?CH | ?CF 3 | ?Cl | |
?I-41 | ?H | ?CH | ?OCF 2H | ?OCF 2H | |
?I-42 | ?H | ?CH | ?OCF 2H | ?NHCH 3 | |
?I-43 | ?H | ?CH | ?OCF 2H | ?N(CH 3) 2 | |
?I-44 | ?H | ?CH | ?OCF 2H | ?Cl | |
?I-45 | ?H | ?CH | ?NHCH 3 | ?NHCH 3 | |
?I-46 | ?H | ?CH | ?NHCH3 | ?N(CH 3) 2 | |
?I-47 | ?H | ?CH | ?NHCH 3 | ?Cl | |
?I-48 | ?H | ?CH | ?N(CH 3) 2 | ?N(CH 3) 2 | |
?I-49 | ?H | ?CH | ?N(CH 3) 2 | ?Cl | |
?I-50 | ?H | ?CH | ?Cl | ?Cl | |
?I-51 | ?H | ?N | ?OCH 3 | ?OCH 3 | ?255 |
?I-52 | ?H | ?N | ?OCH 3 | ?OCH 3 | ?159-162 (+) |
?I-53 | ?H | ?N | ?OCH 3 | ?OC 2H 5 | |
?I-54 | ?H | ?N | ?OCH 3 | ?CH 3 | |
?I-55 | ?H | ?N | ?OCH 3 | ?C 2H 5 | |
?I-56 | ?H | ?N | ?OCH 3 | ?CF 3 | |
?I-57 | ?H | ?N | ?OCH 3 | ?OCF 2H |
?Bsp.- ?Nr. | ?R 1 | ?A | ?R 2 | ?R 3 | ?Smp. ?(℃) |
?I-58 | ?H | ?N | ?OCH 3 | ?NHCH 3 | |
?I-59 | ?H | ?N | ?OCH 3 | ?N(CH 3) 2 | |
?I-60 | ?H | ?N | ?OCH 3 | ?N(CH 3) 2 | ?156 (+) |
?I-61 | ?H | ?N | ?OCH 3 | ?Cl | |
?I-62 | ?H | ?N | ?OC 2H 5 | ?OC 2H 5 | |
?I-63 | ?H | ?N | ?OC 2H 5 | ?CH 3 | |
?I-64 | ?H | ?N | ?OC 2H 5 | ?C 2H 5 | |
?I-65 | ?H | ?N | ?OC 2H 5 | ?CF 3 | |
?I-66 | ?H | ?N | ?OC 2H 5 | ?OCF 2H | |
?I-67 | ?H | ?N | ?OC 2H 5 | ?NHCH 3 | |
?I-68 | ?H | ?N | ?OC 2H 5 | ?N(CH 3) 2 | |
?I-69 | ?H | ?N | ?OC 2H 5 | ?Cl | |
?I-70 | ?H | ?N | ?OC 2H 5 | ?Cl | ?213 (+) |
?I-71 | ?H | ?N | ?CH 3 | ?CH 3 | |
?I-72 | ?H | ?N | ?CH 3 | ?C 2H 5 | |
?I-73 | ?H | ?N | ?CH 3 | ?CF 3 | |
?I-74 | ?H | ?N | ?CH 3 | ?OCF 2H | |
?I-75 | ?H | ?N | ?CH 3 | ?NHCH 3 | |
?I-76 | ?H | ?N | ?CH 3 | ?N(CH 3) 2 | |
?I-77 | ?H | ?N | ?CH 3 | ?Cl | |
?I-78 | ?H | ?N | ?C 2H 5 | ?C 2H 5 | |
?I-79 | ?H | ?N | ?C 2H 5 | ?CF 3 | |
?I-80 | ?H | ?N | ?C 2H 5 | ?OCF 2H | |
?I-81 | ?H | ?N | ?C 2H 5 | ?NHCH 3 | |
?I-82 | ?H | ?N | ?C 2H 5 | ?Cl | |
?I-83 | ?H | ?N | ?CF 3 | ?CF 3 | |
?I-84 | ?H | ?N | ?CF 3 | ?OCF 2H | |
?I-85 | ?H | ?N | ?CF 3 | ?NHCH 3 | |
?I-86 | ?H | ?N | ?CF 3 | ?N(CH 3) 2 |
?Bsp.- ?Nr. | ?R 1 | ?A | ?R 2 | ?R 3 | ?Smp. ?(℃) |
?I-87 | ?H | ?N | ?CF 3 | ?Cl | |
?I-88 | ?H | ?N | ?OCF 2H | ?OCF 2H | |
?I-89 | ?H | ?N | ?OCF 2H | ?NHCH 3 | |
?I-90 | ?H | ?N | ?OCF 2H | ?N(CH 3) 2 | |
?I-91 | ?H | ?N | ?OCF 2H | ?Cl | |
?I-92 | ?H | ?N | ?NHCH 3 | ?NHCH 3 | |
?I-93 | ?H | ?N | ?NHCH 3 | ?N(CH 3) 2 | |
?I-94 | ?H | ?N | ?NHCH 3 | ?Cl | |
?I-95 | ?H | ?N | ?N(CH 3) 2 | ?N(CH 3) 2 | |
?I-96 | ?H | ?N | ?N(CH 3) 2 | ?Cl | |
?I-97 | ?H | ?N | ?Cl | ?Cl | |
?I-98 | ?CH 3 | ?N | ?OCH 3 | ?OCH 3 | |
?I-99 | ?CH 3 | ?N | ?OCH 3 | ?OC 2H 5 | |
?I-100 | ?CH 3 | ?N | ?OCH 3 | ?CH 3 | |
?I-101 | ?CH 3 | ?N | ?OCH 3 | ?C 2H 5 | |
?I-102 | ?CH 3 | ?N | ?OCH 3 | ?CF 3 | |
?I-103 | ?CH 3 | ?N | ?OCH 3 | ?OCF 2H | |
?I-104 | ?CH 3 | ?N | ?OCH 3 | ?NHCH 3 | |
?I-105 | ?CH 3 | ?N | ?OCH 3 | ?N(CH 3) 2 | |
?I-106 | ?CH 3 | ?N | ?OCH 3 | ?Cl | |
?I-107 | ?CH 3 | ?N | ?OC 2H 5 | ?OC 2H 5 | |
?I-108 | ?CH 3 | ?N | ?OC 2H 5 | ?CH 3 | |
?I-109 | ?CH 3 | ?N | ?OC 2H 5 | ?C 2H 5 | |
?I-110 | ?CH 3 | ?N | ?OC 2H 5 | ?CF 3 | |
?I-111 | ?CH 3 | ?N | ?OC 2H 5 | ?OCF 2H | |
?I-112 | ?CH 3 | ?N | ?OC 2H 5 | ?NHCH 3 | |
?I-113 | ?CH 3 | ?N | ?OC 2H 5 | ?N(CH 3) 2 | |
?I-114 | ?CH 3 | ?N | ?OC 2H 5 | ?Cl | |
?I-115 | ?CH 3 | ?N | ?CH 3 | ?CH 3 |
?Bsp.- ?Nr. | ?R 1 | ?A | ?R 2 | ?R 3 | ?Smp. ?(℃) |
?I-116 | ?CH 3 | ?N | ?CH 3 | ?C 2H 5 | |
?I-117 | ?CH 3 | ?N | ?CH 3 | ?CF 3 | |
?I-118 | ?CH 3 | ?N | ?CH 3 | ?OCF 2H | |
?I-119 | ?CH 3 | ?N | ?CH 3 | ?NHCH 3 | |
?I-120 | ?CH 3 | ?N | ?CH 3 | ?N(CH 3) 2 | |
?I-121 | ?CH 3 | ?N | ?CH 3 | ?Cl | |
?I-122 | ?CH 3 | ?N | ?C 2H 5 | ?C 2H 5 | |
?I-123 | ?CH 3 | ?N | ?C 2H 5 | ?CF 3 | |
?I-124 | ?CH 3 | ?N | ?C 2H 5 | ?OCF 2H | |
?I-125 | ?CH 3 | ?N | ?C 2H 5 | ?NHCH 3 | |
?I-126 | ?CH 3 | ?N | ?C 2H 5 | ?Cl | |
?I-127 | ?CH 3 | ?N | ?CF 3 | ?CF 3 | |
?I-128 | ?CH 3 | ?N | ?CF 3 | ?OCF 2H | |
?I-129 | ?CH 3 | ?N | ?CF 3 | ?NHCH 3 | |
?I-130 | ?CH 3 | ?N | ?CF 3 | ?N(CH 3) 2 | |
?I-131 | ?CH 3 | ?N | ?CF 3 | ?Cl | |
?I-132 | ?CH 3 | ?N | ?OCF 2H | ?OCF 2H | |
?I-133 | ?CH 3 | ?N | ?OCF 2H | ?NHCH 3 | |
?I-134 | ?CH 3 | ?N | ?OCF 2H | ?N(CH 3) 2 | |
?I-135 | ?CH 3 | ?N | ?OCF 2H | ?Cl | |
?I-136 | ?CH 3 | ?N | ?NHCH 3 | ?NHCH 3 | |
?I-137 | ?CH 3 | ?N | ?NHCH 3 | ?N(CH 3) 2 | |
?I-138 | ?CH 3 | ?N | ?NHCH 3 | ?Cl | |
?I-139 | ?CH 3 | ?N | ?N(CH 3) 2 | ?N(CH 3) 2 | |
?I-140 | ?CH 3 | ?N | ?N(CH 3) 2 | ?Cl | |
?I-141 | ?CH 3 | ?N | ?Cl | ?Cl | |
?I-142 | ?H | ?N | ?N(CH 3) 2 | ?OCH 2CF 3 | ?158 |
?I-143 | ?H | ?CH | ?Cl | ?OCH 2CF 3 | ?204-205 |
?I-144 | ?H | ?CH | ?Cl | ?OCH 2CF 3 |
?Bsp.- ?Nr. | ?R 1 | ?A | ?R 2 | ?R 3 | ?Smp. ?(℃) |
?I-145 | ?H | ?CH | ?Cl | ?OCH 2CF 3 | ?207 (+) |
Weed killer herbicide (A) suppresses acetolactate synthase (ALS), thereby suppresses the protein synthesis in the plant.According to external condition, temperature and humidity for example, and the type of the weed killer herbicide that uses, the amount of application of weed killer herbicide (A) can change in a big way, for example between 0.001g and 500gAS/ha (hereinafter, AS/ha represents the pure reactive compound of " active substance of per hectare "=based on 100%).When the amount of application that utilizes 0.01g to 200g AS/ha is used weed killer herbicide (A), preferred compound I-1 to I-145, by before the seedling with seedling after method control the noxious plant of relative wide spectrum, for example annual and perennial unifacial leaf or broadleaf weed and the crop of not expecting.In composition of the present invention, amount of application is lower usually, and for example its scope is 0.001g to 100g AS/ha, is preferably 0.005g to 50g AS/ha, especially is preferably 0.01g to 9g AS/ha.
Weed killer herbicide (A) is applicable to the noxious plant of control in the following crop: Economic Importance crops for example, unifacial leaf crops such as cereal (wheat for example for example, barley, rye, oat), paddy rice, corn, grain, or dicotyledonous crops such as sugar beet, rape, cotton, sunflower and beans be Glycine (Glycine max. (soybean) for example for example, for example not genetically modified Glycine max. (conventional cultivation kind for example, STS cultivar for example), or transgenosis Glycine max. (for example RR-soybean or LL-soybean), and Hybrid), Phaseolus, Pisum, Vetch and Arachis, or come from different floristic vegetable crops, potato for example, leek, wild cabbage, carrot, tomato, onion, and long-term crop (permanent crops) and kind plant, for example a kind of fruit, such as apple, pear, etc. and drupe, berry, grape, Hevea (Hevea), banana, sugarcane, coffee, tea, oranges and tangerines, nut plantation plant, the lawn, palm plantation plant and forest plantation plant.For using herbicide-safener combination of the present invention (A)+(B), these crops also are preferred; Especially preferred is to be applied in cereal (for example wheat, barley, rye, oat), paddy rice, corn, grain, sugar beet, sugarcane, sunflower, rape and the cotton.Herbicide-safener combination (A)+(B) can also be used for tolerance and non-tolerance sudden change crop and tolerance and non-tolerance genetically modified crops, for example imidazolidinone weedicide, atrazine, careless ammonium phosphine or glyphosate is had in corn, paddy rice, cereal, rape and the soybean of resistance.
Safener as component (B) is interpreted as reducing for example compound of the phytotoxicity effect of weed killer herbicide in crop of plant protection product.
Safener (B) is preferably selected from down group:
A) compound of formula (II) to (IV),
Wherein symbol and index are following defines:
N ' is 0 to 5 natural number, preferred 0 to 3;
T is for being unsubstituted or through one or two (C
1-C
4) alkyl or [(C
1-C
3)-alkoxyl]-(C of carbonyl substituted
1-C
2)-alkane two bases;
W is the divalent heterocyclic group that is unsubstituted or is substituted, it is selected from the fractional saturation with 1 to 3 nitrogen or oxa-annular atoms or the group of aromatics five-ring heterocycles, wherein this ring comprises at least one nitrogen-atoms and oxygen atom at the most, is preferably selected from down the group of group (W1) to (W4)
M ' is 0 or 1;
R
17, R
19Identical or different, and be halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, nitro or (C
1-C
4) alkylhalide group;
R
18, R
20Identical or different, and be OR
24, SR
24Or NR
24R
25, saturated or undersaturated have at least one nitrogen-atoms and up to 3 heteroatomic 3-to 7-unit heterocycle, be preferably selected from the group of forming by oxygen and sulphur, its by nitrogen-atoms be connected in (II) or (III) in carbonyl, and its be unsubstituted or warp (C
1-C
4)-alkyl, (C
1-C
4The phenyl that is substituted that)-alkoxyl replaces and optional, preferred formula OR
24, NHR
25Or N (CH
3)
2Group, especially formula OR
24Group;
R
24For hydrogen or preferably have an aliphatic alkyl that is unsubstituted or is substituted that amounts to 1 to 18 carbon atom;
R
25Be hydrogen, (C
1-C
6)-alkyl, (C
1-C
6)-alkoxyl or the phenyl that is substituted or is unsubstituted;
R
XBe H, (C
1-C
8)-alkyl, (C
1-C
8)-alkylhalide group, (C
1-C
4)-alkoxyl-(C
1-C
8)-alkyl, cyano group or COOR
26, R wherein
26Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
8)-alkylhalide group, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, (C
1-C
6)-hydroxyalkyl, (C
3-C
12)-cycloalkyl or three-(C
1-C
4)-alkyl silicyl;
R
27, R
29, R
29Identical or different, and be hydrogen, (C
1-C
8)-alkyl, (C
1-C
8)-alkylhalide group, (C
3-C
12)-alkylhalide group or the phenyl that is substituted or is unsubstituted;
R
21Be (C
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, (C
2-C
4)-thiazolinyl, (C
2-C
4)-haloalkenyl, (C
3-C
7)-cycloalkyl is preferably dichloromethyl;
R
22, R
23Identical or different, and be hydrogen, (C
1-C
4)-alkyl, (C
2-C
4)-thiazolinyl, (C
2-C
4)-alkynyl, (C
1-C
4)-alkylhalide group, (C
2-C
4)-haloalkenyl, (C
1-C
4)-alkylcarbamoyl group-(C
1-C
4)-alkyl, (C
2-C
4)-thiazolinyl carbamyl-(C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, dioxolanyl-(C
1-C
4)-alkyl, thiazolyl, furyl, furyl alkyl, thienyl, piperidyl, the phenyl that is substituted or is unsubstituted, or R
22And R
23Form the heterocycle that is substituted or is unsubstituted together, preferred azoles, thiazole, piperidines, morpholine, hexahydropyrimidine or benzoxazine ring;
B) one or more are selected from down the compound of group:
1, the 8-naphthalic anhydride,
The diphenyl methoxy menthyl acetate,
1-(2-benzyl chloride base)-3-(1-methyl isophthalic acid-phenethyl) urea (cumyluron),
S-2-ethylenebis dithiocarbamate diethyldithioposphoric acid 0,0-diethylester (disulfoton),
4-chlorphenyl-methyl carbamate (Mephenate),
0-phenyl D2EHDTPA 0,0-diethylester (Dietholate),
4-carboxyl-3,4-dihydro-2H-1-chromene-4-acetate (CL-304415, CAS-Regno:31541-57-8),
Cyano group methoxyimino (phenyl) acetonitrile (cyometrinil),
1,3-dioxolanyl-2-base methoxyimino (phenyl) acetonitrile (oxabetrinil),
4 '-chloro-2,2,2-trifluoroacetophenone 0-1,3-dioxolanyl-2-ylmethyl oxime (fluxofenim),
4,6-two chloro-2-phenyl pyrimidines (fenclorim),
2-chloro-4-Trifluoromethyl-1,3-thiazole-5-carboxylic acid benzyl ester (separating careless amine),
2-dichloromethyl-2-methyl isophthalic acid, 3-dioxolanes (MG-191),
N-(4-aminomethyl phenyl)-N '-(1-methyl isophthalic acid-phenethyl) urea (vanilla is grand),
(2,4 dichloro benzene oxygen base) acetate (2,4-D),
(4-chlorophenoxy) acetate,
(R, S)-2-(4-chloro-neighbour-toloxyl) propionic acid (Vi par),
4-(2,4 dichloro benzene oxygen base) butyric acid (2,4-DB),
(4-chloro-neighbour-toloxyl) acetate (MCPA),
4-(4-chloro-neighbour-toloxyl) butyric acid,
4-(4-chlorophenoxy) butyric acid,
3,6-two chloro-O-Anisic Acids (dicamba),
3,6-two chloro-O-Anisic Acid 1-(carbethoxyl group) ethyl ester (Lactidichlor) and salt and esters, preferred (C
1-C
8) ester;
C) the N-acyl group sulfonamide and the salt thereof of formula (V)
Wherein
R
30Be hydrogen, alkyl, oxyl, sulfenyl or heterocyclic radical (it preferably adheres to via a carbon atom), wherein last 4 described groups are to be unsubstituted or to organize group under one or more identical or different being selected to replace: halogen, cyano group, nitro, amino, hydroxyl, carboxyl, formoxyl, carboxylic acid amides, sulfonamide and formula-Z
a-R
aGroup,
Wherein each hydrocarbyl portion preferably has 1 to 20 carbon atom, and comprises substituent carbon-containing group R
30Preferably has 1 to 30 carbon atom;
R
31Be hydrogen or (C
1-C
4)-alkyl, preferred hydrogen, or
R
30And R
31With the group of formula-CO-N-be the group of the saturated or unsaturated ring of 3-to 8-unit in the lump;
R
32Identical or different, and be halogen, cyano group, nitro, amino, hydroxyl, carboxyl, formoxyl, CONH
2, SO
2NH
2Or formula-Z
b-R
bGroup;
R
33Be hydrogen or (C
1-C
4)-alkyl, preferred hydrogen;
R
34Identical or different, and be halogen, cyano group, nitro, amino, hydroxyl, carboxyl, CHO, CONH
2, SO
2NH
2Or formula-Z
c-R
cGroup;
R
aBe alkyl or heterocyclic radical, wherein latter two described group be unsubstituted or under one or more identical or different being selected from the group group replace: halogen, cyano group, nitro, amino, hydroxyl, list-and two-[(C
1-C
4)-alkyl]-amino, or by alkyl replacement, wherein a plurality of, preferred 2 or 3 non-adjacent CH
2-group is replaced by oxygen atom separately;
R
b, R
cIdentical or different, and be alkyl or heterocyclic radical, wherein latter two described group be unsubstituted or under one or more identical or different being selected from the group group replace: halogen, cyano group, nitro, amino, hydroxyl, phosphoryl, halo-(C
1-C
4)-alkoxyl, list-and two-[(C
1-C
4)-alkyl]-amino, or alkyl, wherein a plurality of, preferred 2 or 3 non-adjacent CH
2-group is replaced by oxygen atom separately;
Z
aDivalent group for following formula :-O-,-S-,-CO-,-CS-,-CO-O-,-CO-S-,-O-CO-,-S-CO-,-SO-,-SO
2-,-NR
*-,-CO-NR
*-,-NR
*-CO-,-SO
2-NR
*-or-NR
*-SO
2-, wherein the key on described divalent group the right is to be bonded in radicals R
a, and the R in 5 described groups in the end
*Be H, (C independently of one another
1-C
4)-alkyl or halo-(C
1-C
4)-alkyl;
Z
b, Z
cBe independently of one another the divalent group of straight key or following formula :-O-,-S-,-CO-,-CS-,-CO-O-,-CO-S-,-O-CO-,-S-CO-,-SO-,-SO
2-,-NR
*-,-SO
2-NR
*-,-NR
*-SO
2-,-CO-NR
*-or-NR
*-CO-, wherein the key on described divalent group the right is to be bonded in radicals R
bOr R
c, and the R in 5 described groups in the end
*Be H, (C independently of one another
1-C
4)-alkyl or halo-(C
1-C
4)-alkyl;
N is 0 to 4 integer, and is preferred 0,1 or 2, especially 0 or 1 and
M is 0 to 5 integer, and is preferred 0,1,2 or 3, especially 0,1 or 2;
D) the acyl group sulfamoyl benzamides of formula (VI), optionally with its salt form,
Wherein
X
3Be CH or N;
R
35Be hydrogen, heterocyclic radical or alkyl, wherein latter two described group is optional through the group group replacement down of one or more identical or different being selected from: halogen, cyano group, nitro, amino, hydroxyl, carboxyl, CHO, CONH
2, SO
2NH
2And Z
a-R
a
R
36Be hydrogen, hydroxyl, (C
1-C
6)-alkyl, (C
2-C
6)-thiazolinyl, (C
2-C
6)-alkynyl, (C
1-C
6)-alkoxyl, (C
2-C
6)-alkene oxygen base, wherein last 5 described groups are the optional group replacements of organizing under one or more identical or different being selected from: halogen, hydroxyl, hydroxyl, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl and (C
1-C
4)-alkylthio group, or
R
35And R
36With the nitrogen-atoms of its load be the saturated or unsaturated ring of 3-to 8-unit in the lump;
R
37Be halogen, cyano group, nitro, amino, hydroxyl, carboxyl, CHO, CONH
2, SO
2NH
2Or Z
b-R
b
R
38Be hydrogen, (C
1-C
4)-alkyl, (C
2-C
4)-thiazolinyl or (C
2-C
4)-alkynyl;
R
39Be halogen, cyano group, nitro, amino, hydroxyl, carboxyl, phosphoryl, CHO, CONH
2, SO
2NH
2Or Z
c-R
c
R
a(the C that is interrupted one or many for carbochain by oxygen atom
2-C
20)-alkyl, or be heterocyclic radical or alkyl, wherein latter two described group is optional through the group group replacement down of one or more identical or different being selected from: halogen, cyano group, nitro, amino, hydroxyl, list-and two-[(C
1-C
4)-alkyl]-amino;
R
b, R
cIdentical or different, and be carbochain is interrupted one or many by oxygen atom (C
2-C
20)-alkyl, or be heterocyclic radical or alkyl, wherein latter two described group is optional through the group group replacement down of one or more identical or different being selected from: halogen, cyano group, nitro, amino, hydroxyl, phosphoryl, (C
1-C
4)-halogen alkoxyl, list-and two-[(C
1-C
4)-alkyl]-amino;
Z
aFor being selected from down the divalent unit of group: O, S, CO, CS, C (O) O, C (O) S, SO, SO
2, NR
d, C (O) NR
dOr SO
2NR
d
Z
b, Z
cIdentical or different, and be straight key or the divalent unit that is selected from down group: O, S, CO, CS, C (O) O, C (O) S, SO, SO
2, NR
d, SO
2NR
dOr C (O) NR
d
R
dBe hydrogen, (C
1-C
4)-alkyl or (C
1-C
4)-alkylhalide group;
N be 0 to 4 integer and
If X is CH, then m is 0 to 5 integer, if X is N, then m is 0 to 4 integer;
E) compound of acyl group sulfamoyl benzamides, following formula (VII) for example, it is known in for example WO99/16744,
For example wherein be compound as giving a definition:
R
21=cyclopropyl and R
22=H (S3-1=4-cyclopropyl amino carbonyl-N-(2-methoxybenzoyl base) benzsulfamide),
R
21=cyclopropyl and R
22=5-C1 (S3-2),
R
21=ethyl and R
22=H (S3-3),
R
21=isopropyl and R
22=5-C1 (S3-4) and
R
21=isopropyl and R
22=H (S3-5);
F) the N-acyl group sulfamoyl phenylurea compounds of formula (VIII), it is known in for example EP-A-365484,
Wherein
A is the group that is selected from down group:
R
αAnd R
βBe hydrogen, C independently of one another
1-C
8-alkyl, C
3-C
8-cycloalkyl, C
3-C
6-thiazolinyl, C
3-C
6-alkynyl,
Or through C
1-C
4-alkoxyl or
The C that replaces
1-C
4-alkoxyl, or
R
αAnd R
βCommon expression C
4-C
6-alkylidene bridge or through oxygen, sulphur, SO, SO
2, NH or-N (C
1-C
4-alkyl) C of Jian Duaning
4-C
6-alkylidene bridge,
R
γBe hydrogen or C
1-C
4-alkyl,
R
aAnd R
bBe hydrogen, halogen, cyano group, nitro, trifluoromethyl, C independently of one another
1-C
4-alkyl, C
1-C
4-alkoxyl, C
1-C
4-alkylthio group, C
1-C
4-alkyl sulphinyl, C
1-C
4-alkyl sulphonyl ,-COOR
j,-CONR
kR
m,-COR
n,-SO
2NR
kR
mOr-OSO
2-C
1-C
4-alkyl, or R
aAnd R
bBe can be together through halogen or C
1-C
4The C that-alkyl replaces
3-C
4-alkylidene bridge, or be can be through halogen or C
1-C
4The C that-alkyl replaces
3-C
4-alkenylene bridge, or be can be through halogen or C
1-C
4The C that-alkyl replaces
4-alkadienylene bridge and
R
gAnd R
hBe hydrogen, halogen, C independently of one another
1-C
4-alkyl, trifluoromethyl, methoxyl group, methyl mercapto or-COOR
j, wherein
R
cBe hydrogen, halogen, C
1-C
4-alkyl or methoxyl group,
R
dBe hydrogen, halogen, nitro, C
1-C
4-alkyl, C
1-C
4-alkoxyl, C
1-C
4-alkylthio group, C
1-C
4-alkyl sulphinyl, C
1-C
4-alkyl sulphonyl ,-COOR
jOr-CONR
kR
m,
R
eBe hydrogen, halogen, C
1-C
4-alkyl ,-COOR
j, trifluoromethyl or methoxyl group, or R
dAnd R
eBe C together
3-C
4-alkylidene bridge,
R
fBe hydrogen, halogen or C
1-C
4-alkyl,
R
XAnd R
YBe hydrogen, halogen, C independently of one another
1-C
4-alkyl, C
1-C
4-alkoxyl, C
1-C
4-alkylthio group ,-COOR
4, trifluoromethyl, nitro or cyano group,
R
j, R
kAnd R
mBe hydrogen or C independently of one another
1-C
4-alkyl,
R
kAnd R
mBe C together
4-C
6-alkylidene bridge or by oxygen, NH or-N (C
1-C
4-alkyl)-C that is interrupted
4-C
6-alkylidene bridge and
R
nBe C
1-C
4-alkyl, phenyl, or by halogen, C
1-C
4The phenyl that-alkyl, methoxyl group, nitro or trifluoromethyl replace,
Preferably
1-[4-(N-2-methoxybenzoyl base sulfamoyl) phenyl]-the 3-methylurea,
1-[4-(N-2-methoxybenzoyl base sulfamoyl) phenyl]-3, the 3-dimethyl urea,
1-[4-(N-4,5-dimethylbenzoyl sulfamoyl) phenyl]-the 3-methylurea,
1-[4-(N-naphthoyl sulfamoyl) phenyl]-3, the 3-dimethyl urea,
Comprise that its stereoisomer and agricultural go up salt commonly used.
Preferably comprise one or more formulas (I) compound or its salt of (A) herbicidally effective amount and (B) herbicide-safener combination of a certain amount of one or more safeners as antipoison.
Herbicidally effective amount among the present invention is meant the amount that is enough to plant growing is had one or more weed killer herbicides of negative interaction.In the present invention, the amount as antipoison refers to be enough to reduce the amount of plant protection product (for example weed killer herbicide) to one or more safeners of the toxic action of crop.
Unless specify in addition, as give a definition and be applicable to the group of formula (I) usually to (VIII) and following structural formula.
Alkyl, alkoxyl, alkylhalide group, halogen alkoxyl, alkyl amino and alkylthio group, and the carbon skeleton of the corresponding unsaturated and/or group that is substituted can be for straight or branched.
Alkyl group comprises its compound containing, for example alkoxyl, alkylhalide group etc. preferably have 1 to 4 carbon atom and for methyl for example, ethyl, just-or different-propyl group, just-, different-, uncle-or 2-butyl.Thiazolinyl and alkynyl refer to the possible unsaturated group of corresponding alkyl; Thiazolinyl is for example pi-allyl, 1-methyl-third-2-alkene-1-base, 2-methyl-third-2-alkene-1-base, but-2-ene-1-base, fourth-3-alkene-1-base, 1-methyl-Ding-3-alkene-1-base and 1-methyl-but-2-ene-1-base; Alkynyl is for example propargyl, fourth-2-alkynes-1-base, fourth-3-alkynes-1-base, 1-methyl-Ding-3-alkynes-1-base." (C
1-C
4)-alkyl " be short symbolic representation with alkyl of 1 to 4 carbon atom; This is applicable to that correspondingly other has the conventional group definition of the possible carbon atom number range as shown in bracket.
Cycloalkyl is preferably has 3 to 8, preferred 3 to 7, the cycloalkyl of especially preferred 3 to 6 carbon atoms, for example cyclopropyl, cyclobutyl, cyclopenta and cyclohexyl.Cycloalkenyl group and cycloalkynyl radical refer to corresponding unsaturated compound.
Halogen is fluorine, chlorine, bromine or iodine.Alkylhalide group, haloalkenyl and alkynyl halide be alkyl, thiazolinyl and alkynyl respectively partially or completely by halogen, preferably by fluorine, chlorine and/or bromine, especially replace, for example CF by fluorine or chlorine
3, CHF
2, CH
2F, CF
2CF
3, CH
2CHFCl, CCl
3, CHCl
2, CH
2CH
2Cl.The halogen alkoxyl is for example OCF
3, OCHF
2, OCH
2F, OCF
2CF
3, OCH
2CF
3And OCH
2CH
2Cl.This correspondingly is applicable to the group that other replaces through halogen.
Alkyl can aromatics or aliphatic alkyl, and aliphatic alkyl is generally the saturated or unsaturated alkyl of straight or branched, and it preferably has 1 to 18, especially preferred 1 to 12 carbon atom, for example alkyl, alkenyl or alkynyl.
Aliphatic alkyl is preferably alkyl, the alkenyl or alkynyl that has up to 12 carbon atoms; This correspondingly is applicable to the aliphatic alkyl in the oxyl.
Aryl is generally has a preferred 6-20 carbon atom, especially 6-14 carbon atom, the list of especially preferred 6-10 carbon atom-, two-or polycyclic aromatic system, for example phenyl, naphthyl, tetralyl, indenyl, indanyl, pentalene base and fluorenyl, especially preferably phenyl.
That heterocycle, heterocyclic radical or heterocyclic radical refer to is single-, two-or multi-loop system, it is saturated, unsaturated and/or aromatics, and contain one or more, preferred 1 to 4 hetero atom that is preferably selected from nitrogen, sulphur and oxygen.
Preferably have 3 to 7 annular atomses and be selected from the heteroatomic saturated heterocyclic of nitrogen, oxygen and sulphur with one or two, wherein chalcogen is non-conterminous.Especially preferred is to have 3 to 7 annular atomses and a heteroatomic monocycle that is selected from nitrogen, oxygen and sulphur, and morpholine, dioxolanes, piperazine, imidazoline and azoles alkane.Extremely preferred saturated heterocyclic is oxirane, pyrrolidones, morpholine and oxolane.
Also preferably have 5 to 7 annular atomses and be selected from the heteroatomic part unsaturated heterocycle of nitrogen, oxygen and sulphur with one or two.Especially preferred is to have 5 to 6 annular atomses and a heteroatomic part unsaturated heterocycle that is selected from nitrogen, oxygen and sulphur.Extremely preferred part unsaturated heterocycle is pyrazoline, imidazoline and different azoles quinoline.
The hetero-aromatic ring that equally preferably has 5 to 6 annular atomses, for example single-or the bicyclic aromatic heterocycle, it comprises 1 to 4 hetero atom that is selected from nitrogen, oxygen and sulphur, and wherein chalcogen is non-conterminous.Especially preferred is the monocyclic aromatic heterocycle with 5 to 6 annular atomses, and it comprises the hetero atom that is selected from nitrogen, oxygen and sulphur, and pyrimidine, pyrazine, pyridazine, azoles, thiazole, thiadiazoles, diazole, pyrazoles, triazole and different azoles.Extremely preferably pyrazoles, thiazole, triazole and furans.
The group that is substituted; the alkyl of the alkyl that for example is substituted as being substituted; thiazolinyl; alkynyl; aryl such as phenyl and aryl alkyl such as benzyl; or the heterocyclic radical that is substituted is to be derived from the group that is substituted that is unsubstituted skeleton; wherein substituting group preferably has one or more; preferred 1; 2 or 3; under Cl and F situation; also can be up to the number of maximum possible; substituting group is selected from down group: halogen; alkoxyl; the halogen alkoxyl; alkylthio group; hydroxyl; amino; nitro; carboxyl; cyano group; azido; alkoxy carbonyl group; alkyl-carbonyl; formoxyl; carbamyl; single-and dialkyl amino carbonyl; amino that is substituted such as acylamino-; single-and dialkyl amido; and alkyl sulphinyl; the alkylhalide group sulfinyl; alkyl sulphonyl; the alkylhalide group sulfonyl; and in cyclic group; and alkyl and alkylhalide group; and the unsaturated aliphatic substituting group is corresponding to the described saturated hydrocarbon substituent that contains, preferred thiazolinyl; alkynyl; alkene oxygen base; alkynyloxy group.In having the group of carbon atom, preferably has 1 to 4 carbon atom, the especially group of 1 or 2 carbon atom.Usually preferred substituted is selected from down group: halogen is fluorine or chlorine for example, (C
1-C
4)-alkyl, preferable methyl or ethyl, (C
1-C
4)-alkylhalide group, preferred trifluoromethyl, (C
1-C
4)-alkoxyl, preferred methoxy or ethoxy, (C
1-C
4)-halogen alkoxyl, nitro and cyano group.The especially preferred substituting group of this paper is methyl, methoxyl group and chlorine.
Through single-or dibasic amino be to be selected to be substituted amino chemically stable group, it is for example by group group N-replacement one or two identical or different being selected under: alkyl, alkoxyl, acyl group and aryl; Preferred alkyl monosubstituted amino, dialkyl amido, acylamino-, arylamino, N-alkyl-N-arylamino, and and N-heterocyclic radical.This paper preferably has the alkyl of 1 to 4 carbon atom.The preferred benzene of aryl.The phenyl that the aryl that is substituted preferably is substituted.Acyl group is following further definition, preferred (C
1-C
4)-alkanoyl.This correspondingly is applicable to hydroxylamino or the diazanyl that is substituted.
That the optional phenyl that is substituted preferably is unsubstituted or identical or different group list-or polysubstituted through being selected from down group, preferred as many as trisubstd phenyl (under halogen such as Cl and F situation, can also up to five replacements): halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-halogen alkoxyl and nitro, for example adjacent, and p-methylphenyl, 3,5-dimethylphenyl, 2-, 3-and 4-chlorphenyl, 2-, 3-and 4-trifluorophenyl and-trichlorophenyl, 2,4-, 3,5-, 2,5-and 2,3-dichlorophenyl, neighbour, and p-methoxyphenyl.
Acyl group is to have preferred organic acid group up to 6 carbon atoms; carboxylic acid and be derived from wherein group for example; for example thiocarboxylic acid optionally through the amino carboxylic acid or the carbon monoesters group of N-replacement, is chosen the carbamic acid, sulfonic acid, sulfinic acid, phosphonic acids, the phosphonous acid that replace through N-wantonly.Acyl group for for example formoxyl, alkyl-carbonyl as (C
1-C
4-alkyl) carbonyl, phenylcarbonyl group, wherein phenyl ring can for example be substituted for phenyl as mentioned above, or alkoxy carbonyl group, carbobenzoxy, benzyloxycarbonyl group, alkyl sulphonyl, alkyl sulphinyl or N-alkyl-1-imino alkyl.
Formula (I) to (VIII) also comprises having all stereoisomers that the same atoms topology connects, and composition thereof.The saturated one or more asymmetric carbon atoms of this compounds or other two keys, this is not concrete expression in general formula.Possible stereoisomer such as enantiomter, diastereoisomer, Z-and E-isomer by this particular space shape definition can obtain from the mixture of stereoisomer by conventional method, or in addition by making with the stereoselective reaction of using the pure parent material of spatial chemistry to combine.
Formula (II) compound is known, for example be known in EP-A-0 333 131 (ZA-89/1960), EP-A-0 269 806 (US-A-4,891,057), EP-A-0 346 620 (AU-A-89/34951), EP-A-0 174 562, EP-A-0 346 620 (WO-A-91/08202), WO-A-91/07 874 or WO-A 95,/07 897 (ZA 94/7120) and the document wherein quoted, maybe can by or be similar to wherein said method and prepared.Formula (III) compound is known in EP-A-0 086 750, EP-A-0 94 349 (US-A-4,902,340), EP-A-0 191736 (US-A-4,881,966) and EP-A-0 492 366 and the document wherein quoted, maybe can by or be similar to wherein said method and prepared.In addition, part of compounds is described among EP-A-0 582 198 and the WO 2002/34048.
Formula (IV) compound is known in many pieces of patent applications, US-A-4 for example, 021,224 and US-A-4,021,229.
In addition, group B (b) compound is known in CN-A-87/102 789, EP-A-365484, and be known in " The Pesticide Manual " (agricultural chemicals handbook), The British CropProtection Council and the Royal Society of Chemistry, the 11st edition, Farnham 1997.
Group B (c) compound is described among the WO-A-97/45016, and group B (d) compound is described among the WO-A-99/16744, and group B (e) compound is described among the EP-A-365484.
The document of being quoted contains the detailed description relevant for preparation method and parent material, and mentions preferred compound.These publications clearly relate to related content; By reference, it forms the part of this specification.
Preferred herbicide-safener combination comprises formula (II) and/or (III) safener, and wherein symbol and index are following defines:
R
24Be hydrogen, (C
1-C
18)-alkyl, (C
3-C
12)-cycloalkyl, (C
2-C
8)-thiazolinyl and (C
2-C
18)-alkynyl, wherein carbon-containing group can be through one or more, preferably up to 3 R
50Group replaces;
R
50Identical or different, and be halogen, hydroxyl (C
1-C
8)-alkoxyl, (C
1-C
8)-alkylthio group, (C
2-C
8)-alkenylthio group, (C
2-C
8)-alkynes sulfenyl, (C
2-C
8)-alkene oxygen base, (C
2-C
8)-alkynyloxy group, (C
3-C
7)-cycloalkyl, (C
3-C
7)-cycloalkyloxy, cyano group, list-and two (C
1-C
4)-alkyl amino, carboxyl, (C
1-C
8)-alkoxy carbonyl group, (C
2-C
8)-allyloxycarbonyl, (C
1-C
8)-alkylthio group carbonyl, (C
2-C
8)-alkynyloxy group carbonyl, (C
1-C
8)-alkyl-carbonyl, (C
2-C
8)-alkenyl carbonyl, (C
2-C
8)-alkynyl carbonyl, 1-(oximido)-(C
1-C
6)-alkyl, 1-[(C
1-C
4)-alkyl imino]-(C
1-C
4)-alkyl, 1-[(C
1-C
4)-Alkoximino]-(C
1-C
6)-alkyl, (C
1-C
8)-alkyl-carbonyl-amino, (C
2-C
8)-alkenyl carbonyl amino, (C
2-C
8)-alkynyl carbonylamino, amino carbonyl, (C
1-C
8)-alkyl amino-carbonyl, two-(C
1-C
6)-alkyl amino-carbonyl, (C
2-C
6)-alkenyl amino carbonyl, (C
2-C
6)-alkynyl amino carbonyl, (C
1-C
8)-alkoxycarbonyl amido, (C
1-C
8)-alkyl amino-carbonyl amino, be unsubstituted or through R
50(the C that replaces
1-C
6)-alkyl-carbonyl oxygen base, (C
2-C
6)-alkenyl carbonyl oxygen base, (C
2-C
6)-alkynyl ketonic oxygen base, (C
1-C
8)-alkyl sulphonyl, phenyl, phenyl-(C
1-C
6)-alkoxyl, phenyl-(C
1-C
6)-alkoxy carbonyl group, phenoxy group, phenoxy group-(C
1-C
6)-alkoxyl, phenoxy group-(C
1-C
6)-alkoxy carbonyl group, phenylcarbonyl group oxygen base, phenylcarbonyl group amino, phenyl-(C
1-C
6)-alkyl-carbonyl-amino, the phenyl ring of wherein last 9 described groups are to be unsubstituted or through R
52The group list-or polysubstituted, preferably up to trisubstituted; SiR '
3,-O-SiR '
3, R '
3Si-(C
1-C
8)-alkoxyl ,-CO-O-NR '
2,-O-N=CR '
2,-N=CR '
2,-O-NR '
2,-NR '
2, CH (OR ')
2,-O-(CH
2)
m-CH (OR ')
2,-CR (OR ')
2,-O-(CH
2)
mCR (OR ")
2Or R " O-CHR CHCOR "-(C
1-C
6)-alkoxyl,
R
51Identical or different, and be halogen, nitro, (C
1-C
4)-alkoxyl and be unsubstituted or through one or more, preferably up to three R
51The phenyl that group replaces;
R
52Identical or different, and be halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-halogen alkoxyl or nitro;
R ' is identical or different, and is halogen, (C
1-C
4)-alkyl, be unsubstituted or through one or more, preferably up to three R
52The phenyl that group replaces, or two R ' groups form (C together
2-C
6)-alkane two basic chains;
R " identical or different, and be (C
1-C
4)-alkyl, or two R " group forms (C together
2-C
6)-alkane two basic chains;
R is hydrogen or (C
1-C
4)-alkyl;
M is 0,1,2,3,4,5 or 6.
Especially preferred herbicide-safener combination of the present invention comprises formula (II) and/or (III) safener, and wherein symbol and index are following defines:
R
24Be hydrogen, (C
1-C
8)-alkyl or (C
3-C
7)-cycloalkyl, wherein above-mentioned carbon-containing group are to be unsubstituted or through halogen list-or polysubstituted, or through R
50The group list-or dibasic, preferred single the replacement,
R
50Identical or different, and be hydroxyl, (C
1-C
4)-alkoxyl, carboxyl, (C
1-C
4)-alkoxy carbonyl group, (C
2-C
6)-allyloxycarbonyl, (C
2-C
6)-alkynyloxy group carbonyl, 1-(oximido)-(C
1-C
4)-alkyl, 1-[(C
1-C
4)-alkyl imino]-(C
1-C
4)-alkyl and 1-[(C
1-C
4)-Alkoximino]-(C
1-C
4)-alkyl;-SiR '
3,-O-N=CR '
2,-N=CR '
2,-NR '
2With-O-NR '
2, wherein R ' is identical or different and be hydrogen, (C
1-C
4)-alkyl, or with (the C of dual form
4-C
5)-alkane two basic chains,
R
27, R
28, R
29Identical or different, and be hydrogen, (C
1-C
8)-alkyl, (C
1-C
6)-alkylhalide group, (C
3-C
7)-cycloalkyl or be unsubstituted or be selected from down the phenyl that the group group replaces through one or more: halogen, cyano group, nitro, amino, list-and two-[(C
1-C
4)-alkyl]-amino, (C
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-alkoxyl, (C
1-C
4)-halogen alkoxyl, (C
1-C
4)-alkylthio group and (C
1-C
4)-alkyl sulphonyl;
R
XBe hydrogen or COOR
24, R wherein
26Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
8)-alkylhalide group, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, (C
1-C
6)-hydroxy alkyl, (C
3-C
7)-cycloalkyl or three-(C
1-C
4)-alkyl silicyl,
R
17, R
19Identical or different, and be halogen, methyl, ethyl, methoxyl group, ethyoxyl, (C
1-C
2)-alkylhalide group, preferred hydrogen, halogen or (C
1-C
2)-alkylhalide group.
Especially preferably symbol in its Chinese style (II) and the following defined safener of index:
R
17Be halogen, nitro or (C
1-C
4)-alkylhalide group;
N ' is 0,1,2 or 3;
R
18Be formula OR
24Group,
R
24Be hydrogen, (C
1-C
8)-alkyl or (C
3-C
7)-cycloalkyl, wherein above-mentioned carbon-containing group are to be unsubstituted or through identical or different halogen radical single group or polysubstituted, are preferably up to trisubstitutedly, or the group of group is high to dibasic, preferably mono-substituted under identical or different being selected from: hydroxyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-alkoxy carbonyl group, (C
2-C
6)-allyloxycarbonyl, (C
2-C
6)-alkynyloxy group carbonyl, 1-(oximido)-(C
1-C
4)-alkyl, 1-[(C
1-C
4)-alkyl imino]-(C
1-C
4)-alkyl, 1-[(C
1-C
4)-Alkoximino]-(C
1-C
4)-alkyl, and formula-SiR '
3,-O-N=R '
2,-N=CR '
2,-NR '
2With-O-NR '
2Group, the R ' in the wherein above-mentioned formula is identical or different, and is hydrogen, (C
1-C
4)-alkyl, or with (the C of dual form
4-C
5)-alkane two basic chains;
R
27, R
28, R
29Identical or different, and be hydrogen, (C
1-C
8)-alkyl, (C
1-C
6)-alkylhalide group, (C
3-C
7)-cycloalkyl or be unsubstituted or be selected from down the phenyl that the group group replaces: halogen, (C through one or more
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, nitro, (C
1-C
4)-alkylhalide group and (C
1-C
4)-halogen alkoxyl and
R
XBe COOR
26, R wherein
26Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
8)-alkylhalide group, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, (C
1-C
6)-hydroxy alkyl, (C
3-C
7)-cycloalkyl or three-(C
1-C
4)-alkyl silicyl,
Especially preferred is wherein symbol and the following defined formula of index (III) safener:
R
19Be halogen or (C
1-C
4)-alkylhalide group;
N ' is 0,1,2 or 3, wherein (R
19)
N 'Be preferably 5-Cl;
R
20Be formula OR
24Group;
T is CH
2Or CH (COO-(C
1-C
3)-alkyl) and
R
24Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
8)-alkylhalide group or (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, preferred hydrogen or (C
1-C
8)-alkyl.
Especially preferred is wherein symbol and the following defined formula of index (II) safener:
W is (W1);
R
17Be halogen or (C
1-C
2)-alkylhalide group;
N ' is 0,1,2 or 3, wherein (R
17)
N 'Be preferably 2,4-Cl
2
R
18Be formula OR
24Group;
R
24Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-hydroxyalkyl, (C
3-C
7)-cycloalkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl or three-(C
1-C
2)-alkyl silicyl, preferred (C
1-C
4)-alkyl;
R
27Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
4)-alkylhalide group or (C
3-C
7)-cycloalkyl, preferred hydrogen or (C
1-C
4)-alkyl and
R
XBe COOR
26, R wherein
26Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-hydroxyalkyl, (C
3-C
7)-cycloalkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl or three-(C
1-C
2)-alkyl silicyl, preferred hydrogen or (C
1-C
4)-alkyl.
The Herbicidal combinations that also especially preferably comprises formula (II) safener, wherein symbol and index are following defines:
W is (W2);
R
17Be halogen or (C
1-C
2)-alkylhalide group;
N ' is 0,1,2 or 3, wherein (R
17)
N 'Be preferably 2,4-Cl
2
R
18Be formula OR
24Group;
R
24Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-hydroxyalkyl, (C
3-C
7)-cycloalkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl or three-(C
1-C
2)-alkyl silicyl, preferred (C
1-C
4)-alkyl and
R
27Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
4)-alkylhalide group, (C
3-C
7)-cycloalkyl or the phenyl that is unsubstituted or is substituted, preferred hydrogen, (C
1-C
4)-alkyl or be unsubstituted or be selected from down the phenyl that the group group replaces: halogen, (C through one or more
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, nitro, cyano group or (C
1-C
4)-alkoxyl.
Especially preferred is wherein symbol and the following defined formula of index (II) safener:
W is (W3);
R
17Be halogen or (C
1-C
2)-alkylhalide group;
N ' is 0,1,2 or 3, wherein (R
17)
N 'Be preferably 2,4-Cl
2
R
18Be formula OR
24Group;
R
24Be hydrogen, (C
1-C
8)-alkyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-hydroxyalkyl, (C
3-C
7)-cycloalkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl or three-(C
1-C
2)-alkyl silicyl, preferred (C
1-C
4)-alkyl and
R
28Be (C
1-C
8)-alkyl or (C
1-C
4)-alkylhalide group, preferred C
1-alkylhalide group.
Also especially preferred is wherein symbol and the following defined formula of index (II) safener:
W is (W4);
R
17Be halogen, nitro, (C
1-C
4)-alkyl, (C
1-C
2)-alkylhalide group, preferred CF
3Or (C
1-C
4)-alkoxyl;
N ' is 0,1,2 or 3;
M ' is 0 or 1;
R
18Be formula OR
24Group;
R
24Be hydrogen, (C
1-C
4)-alkyl, carboxyl-(C
1-C
4)-alkyl, (C
1-C
4)-alkoxy carbonyl group-(C
1-C
4)-alkyl, preferred (C
1-C
4)-alkoxy-C O-CH
2-, (C
1-C
4)-alkoxy-C O-C (CH
3) H-, HO-CO-CH
2-or HO-CO-C (CH
3) H-and
R
29Be hydrogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, (C
3-C
7)-cycloalkyl or be unsubstituted or be selected from down the phenyl that the group group replaces: halogen, (C through one or more
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, nitro, cyano group and (C
1-C
4)-alkoxyl.
The safener that is particularly useful for formula (I) weeding active compound is the compound with following group:
A) dichlorophenyl pyrazoline-3-carboxylic acid compound (i.e. wherein W=(W1) and (R
17)
N '=2,4-Cl
2Formula (II) compound), preferred compound for example is described in the 1-(2 among the WO-A 91/07874, the 4-dichlorophenyl)-5-(ethoxy carbonyl)-5-antazoline-3-carboxylic acid, ethyl ester (II-1, pyrroles's two diethyl phthalates), pyrroles's two dimethyl phthalates and pyrroles's diacid (II-0), and related compound;
B) dichlorophenyl pyrazole carboxylic acid derivative (i.e. wherein W=(W2) and (R
17)
N '=2,4-Cl
2Formula (II) compound), preferred compound is the 1-(2 described in EP-A-0 333 131 and the EP-A-0 269806 for example, the 4-dichlorophenyl)-5-methylpyrazole-3-carboxyl acid ethyl ester (II-2), 1-(2, the 4-dichlorophenyl)-5-isopropyl pyrazoles-3-carboxylic acid, ethyl ester (II-3), 1-(2, the 4-dichlorophenyl)-5-(1, the 1-dimethyl ethyl) pyrazoles-3-carboxylic acid, ethyl ester (II-4), 1-(2,4 dichloro benzene base)-5-Phenylpyrazole-3-carboxylic acid, ethyl ester (II-5), and related compound;
C) triazolylcarboxylic acid's compounds (i.e. wherein W=(W3) and (R
17)
N '=2,4-Cl
2Formula (II) compound), preferred compound is the fenchlorazole ethyl ester for example, i.e. 1-(2,4 dichloro benzene base)-5-trichloromethyl-(1H)-1,2,4-triazole-3-carboxylic acid, ethyl ester (II-6) and related compound (referring to EP-A-0 174 562 and EP-A-0 346 620);
D) 5-benzyl-or the different azoles quinoline of 5-phenyl-2--3-carboxylic acids or 5, the different azoles quinoline of 5-diphenyl-2--3-carboxylic acid compound, for example two benzene azoles acid (II-12) (wherein W=(W4)), preferred compound for example is described in the 5-(2 among the WO-A-91/08202, the 4-dichloro benzyl)-the different azoles quinoline of 2--3-carboxylic acid, ethyl ester (II-7) or the different azoles quinoline of 5-phenyl-2--3-carboxylate (II-8) and related compound, or be described in 5 among the WO-A-95/07897, the different azoles of 5-diphenyl-2-dicarboxylic acid moiety ethyl ester (II-9) (" two benzene carboxylic acid, ethyl ester ") or 5, the different azoles of 5-diphenyl-2-dicarboxylic acid moiety n-propyl (II-10), or the different azoles quinoline of 5-(4-fluorophenyl)-5-phenyl-2--3-carboxylic acid, ethyl ester (II-11).
E) 8-quinoline oxy phenylacetic acid compound, for example (R wherein
19)
N '=5-Cl, R
20=OR
24And T=CH
2Formula (III) compound, preferred compound
(5-chloro-8-quinoline oxy) acetate-(1-methyl hexyl) ester (III-1, cloquitocet_mexyl),
(5-chloro-8-quinoline oxy) acetate-(1,3-dimethyl butyrate-1-yl) ester (III-2),
(5-chloro-8-quinoline oxy) acetate-4-allyloxy butyl ester (III-3),
(5-chloro-8-quinoline oxy) acetate-1-allyloxy third-2-base ester (III-4),
(5-chloro-8-quinoline oxy) ethyl acetate (III-5),
(5-chloro-8-quinoline oxy) methyl acetate (III-6),
(5-chloro-8-quinoline oxy) allyl acetate (III-7),
(5-chloro-8-quinoline oxy) acetate-2-(2-propylene imino oxygen base)-1-ethyl ester (III-8),
(5-chloro-8-quinoline oxy) acetate-2-oxo third-1-base ester (III-9),
(5-chloro-8-quinoline oxy) acetate (III-10) and salt thereof for example is described among the WO-A-2002/34048 as it, and related compound, as is described among EP-A-86 750, EP-A-94 349 and EP-A-191 736 or the EP-A-492 366.
F) (5-chloro-8-quinoline oxygen) malonic acid compounds, i.e. (R wherein
19)
N '=5-Cl, R
20=OR
24, T=-CH (COO-alkyl)-formula (III) compound, preferred compound is described in (5-chloro-8-quinoline oxy) diethyl malonate (III-11), (5-chloro-8-quinoline oxy) malonic acid diallyl, (5-chloro-8-quinoline oxy) malonic acid Methylethyl ester and the related compound among the EP-A-0 582 198.
G) dichloro acetamide class active substance, i.e. formula (IV) compound, preferred:
N, N-diallyl-2, the 2-dichloro acetamide (allyl dichloride amine (IV-1), from US-A4,137,070),
4-dichloro-acetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (IV-2, benoxacor is from EP 0 149 974),
N1, N2-diallyl-N2-dichloro-acetyl glycine amide (DKA-24 (IV-3) is from HU 2143821),
4-dichloro-acetyl-1--4-azaspiro [4,5] decane (AD-67),
2,2-two chloro-N-(1,3-dioxolanes-2-ylmethyl)-N-(2-acrylic) acetamide (PPG-1292),
3-dichloro-acetyl-2,2,5-trimethyl azoles alkane (R-29148, IV-4),
3-dichloro-acetyl-2,2-dimethyl-5-phenyl azoles alkane,
3-dichloro-acetyl-2,2-dimethyl-5-(2-thienyl) azoles alkane,
3-dichloro-acetyl-5-(2-furyl)-2,2-dimethyl azoles alkane (separate careless azoles (IV-5), MON 13900),
1-dichloro-acetyl six hydrogen-3,3,8a-trimethyl pyrroles [1,2-a] pyrimidine-6 (2H)-ketone (Dicyclonon, BAS 145138).
H) compound of group B (b), preferred
1,8-naphthalic anhydride (b-1),
Diphenyl methoxy menthyl acetate (b-2),
Cyano group methoxyimino (phenyl) acetonitrile (cyometrinil) (b-3),
1-(2-benzyl chloride base)-3-(1-methyl isophthalic acid-phenethyl) urea (cumyluron) (b-4),
S-2-ethylenebis dithiocarbamate diethyldithioposphoric acid 0,0-diethylester (disulfoton) (b-5),
4-Chlorophenylmethyl carbamate (Mephenate) (b-6),
0-phenyl D2EHDTPA 0,0-diethylester (Dietholate) (b-7),
4-carboxyl-3,4-dihydro-2H-1-chromene-4-acetate (CL-304415, CAS-Regno:31541-57-8) (b-8),
1,3-dioxolanyl-2-base methoxyimino (phenyl) acetonitrile (oxabetrinil) (b-9),
4 '-chloro-2,2,2-trifluoroacetophenone 0-1,3-dioxolanyl-2-ylmethyl oxime (fluxofenim) (b-10),
4,6-two chloro-2-phenyl pyrimidines (fenclorim) (b-11),
2-chloro-4-Trifluoromethyl-1,3-thiazole-5-carboxylic acid benzyl ester (separating careless amine) (b-12),
2-dichloromethyl-2-methyl isophthalic acid, 3-dioxolanes (MG-191) (b-13),
N-(4-aminomethyl phenyl)-N '-(1-methyl isophthalic acid-phenethyl) urea (vanilla grand) (b-14),
(2,4 dichloro benzene oxygen base) acetate (2,4-D),
(4-chlorophenoxy) acetate,
(R, S)-2-(4-chloro-neighbour-toloxyl) propionic acid (Vi par),
4-(2,4 dichloro benzene oxygen base) butyric acid (2,4-DB),
(4-chloro-neighbour-toloxyl) acetate (MCPA),
4-(4-chloro-neighbour-toloxyl) butyric acid,
4-(4-chlorophenoxy) butyric acid,
3,6-two chloro-O-Anisic Acids (dicamba),
3,6-two chloro-O-Anisic Acid 1-(carbethoxyl group) ethyl esters (Lactidichlor)
And salt and ester, preferred (C
1-C
8) ester.
In addition, preferred safener is the compound or its salt of formula (V), wherein
R
30Be hydrogen, (C
1-C
6)-alkyl, (C
3-C
6)-cycloalkyl, furyl or thienyl, wherein last 4 described groups be unsubstituted or replace through one or more substituting groups that are selected from down group: halogen, (C
1-C
4)-alkoxyl, halo-(C
1-C
6)-alkoxyl and (C
1-C
4)-alkylthio group, and under the situation of cyclic group, also can be (C
1-C
4)-alkyl and (C
1-C
4)-alkylhalide group,
R
31Be hydrogen,
R
32Be hydrogen, halo-(C
1-C
4)-alkyl, halo-(C
1-C
4)-alkoxyl, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl group or (C
1-C
4)-alkyl-carbonyl,
Preferred halogen, (C
1-C
4)-alkylhalide group, for example trifluoromethyl, (C
1-C
4)-alkoxyl, halo-(C
1-C
4)-alkoxyl, (C
1-C
4)-alkoxy carbonyl group or (C
1-C
4)-alkyl sulphonyl,
R
33Be hydrogen,
R
34Be halogen, (C
1-C
4)-alkyl, halo-(C
1-C
4)-alkyl, halo-(C
1-C
4)-alkoxyl, (C
3-C
6)-cycloalkyl, phenyl, (C
1-C
4)-alkoxyl, cyano group, (C
1-C
4)-alkylthio group, (C
1-C
4)-alkyl sulphinyl, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl group or (C
1-C
4)-alkyl-carbonyl,
Preferred halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, for example trifluoromethyl, halo-(C
1-C
4)-alkoxyl, (C
1-C
4)-alkoxyl or (C
1-C
4)-alkylthio group,
N be 0,1 or 2 and
M is 1 or 2.
Especially preferred is as shown in the formula (V) compound, wherein
R
30=H
3C-O-CH
2-,R
31=R
33=H,R
34=2-OMe(V-1),
R
30=H
3C-O-CH
2-,R
31=R
33=H,R
34=2-OMe-5-Cl(V-2),
R
30=cyclopropyl, R
31=R
33=H, R
34=2-OMe (V-3),
R
30=cyclopropyl, R
31=R
33=H, R
34=2-OMe-5-Cl (V-4),
R
30=cyclopropyl, R
31=R
33=H, R
34=2-Me (V-5),
R
30=the tert-butyl group, R
31=R
33=H, R
34=2-OMe (V-6).
In addition, be preferably as follows the safener of formula (VI), wherein
X
3Be CH;
R
35Be hydrogen, (C
1-C
6)-alkyl, (C
3-C
6)-cycloalkyl, (C
2-C
6)-thiazolinyl, (C
5-C
6)-cycloalkenyl group, phenyl or have is selected from heteroatomic 3-to the 6-unit heterocyclic radical of nitrogen, oxygen and sulphur up to 3, wherein last 6 described groups are optional through the group group replacement down of one or more identical or different being selected from: halogen, (C
1-C
6)-alkoxyl, (C
1-C
6)-halogen alkoxyl, (C
1-C
2)-alkyl sulphinyl, (C
1-C
2)-alkyl sulphonyl, (C
3-C
6)-cycloalkyl, (C
1-C
4)-alkoxy carbonyl group, (C
1-C
4)-alkyl-carbonyl and phenyl, and under the situation of cyclic group, also can be (C
1-C
4)-alkyl and (C
1-C
4)-alkylhalide group;
R
36Be hydrogen, (C
1-C
6)-alkyl, (C
2-C
6)-thiazolinyl, (C
2-C
6)-alkynyl, wherein last 3 described groups are the optional group replacements of organizing under one or more identical or different being selected from: halogen, hydroxyl, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl and (C
1-C
4)-alkylthio group;
R
37Be halogen, (C
1-C
4)-alkylhalide group, (C
1-C
4)-halogen alkoxyl, nitro, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl group or (C
1-C
4)-alkyl-carbonyl;
R
38Be hydrogen;
R
39Be halogen, nitro, (C
1-C
4)-alkyl, (C
1-C
4)-alkylhalide group, (C
1-C
4)-halogen alkoxyl, (C
3-C
6)-cycloalkyl, phenyl, (C
1-C
4)-alkoxyl, cyano group, (C
1-C
4)-alkylthio group, (C
1-C
4)-alkyl sulphinyl, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl group or (C
1-C
4)-alkyl-carbonyl;
N be 0,1 or 2 and
M is 1 or 2.
Preferred formula (VII) safener be (S3-1), (S3-2), (S3-3), (S3-4) with (S3-5).
Preferred formula (VIII) safener is
1-[4-(N-2-methoxybenzoyl base sulfamoyl) phenyl]-3-methylurea (h-1),
1-[4-(N-2-methoxybenzoyl base sulfamoyl) phenyl]-3,3-dimethyl urea (h-2),
1-[4-(N-4,5-dimethylbenzoyl sulfamoyl) phenyl]-3-methylurea (h-3) and
1-[4-(N-naphthoyl sulfamoyl) phenyl]-3, the 3-dimethyl urea.
Especially preferred safener is vanilla grand (b-14), fenclorim (b-11), cumyluron (b-4), two benzene azoles acetoacetic esters (II-9), pyrroles's two diethyl phthalates (II-1), cloquitocet_mexyl (III-1), S3-1, h-1, h-2, h-3, Dietholate (b-7), disulfoton (b-5), 1, are separated careless amine (b-12), R-29148 (IV-4) at 8-naphthalic anhydride (b-1), fluxofenim (b-10), dichlormide (IV-1), benoxacor (IV-2).Especially be preferred for paddy rice be that vanilla is grand, fenclorim, cumyluron, two benzene azoles acetoacetic ester.What especially be preferred for cereal is pyrroles's two diethyl phthalates, cloquitocet_mexyl, being preferred in the corn is two benzene azoles acetoacetic esters, (S3-1), (h-1), (h-2), (h-3), 1,8-naphthalic anhydride, fluxofenim, dichlormide, benoxacor, separates careless amine and R-29148.Be preferred in the sugarcane is two benzene azoles acetoacetic esters.
The preferred composition example of weeding active compound (A) and safener (B) is:
(I-1)+(II-0),(I-1)+(II-1),(I-1)+(II-2),(I-1)+(II-3),(I-1)+(II-4),(I-1)+(II-5),(I-1)+(II-6),(I-1)+(II-9),(I-1)+(II-12),(I-1)+(III-1),(I-1)+(III-4),(I-1)+(III-10),(I-1)+(III-11),(I-1)+(IV-1),(I-1)+(IV-2),(I-1)+(IV-3),(I-1)+(IV-4),(I-1)+(IV-5),(I-1)+(b-1),(I-1)+(b-2),(I-1)+(b-3),(I-1)+(b-4),(I-1)+(b-5),(I-1)+(b-6),(I-1)+(b-7),(I-1)+(b-8),(I-1)+(b-9),(I-1)+(b-10),(I-1)+(b-11),(I-1)+(b-12),(I-1)+(b-13),(I-1)+(b-14),(I-1)+(S3-1),(I-1)+(S3-2),(I-1)+(S3-3),(I-1)+(S3-4),(I-1)+(S3-5),(I-1)+(h-1),(I-1)+(h-2),(I-1)+(V-1),(I-1)+(V-2),(I-1)+(V-3),(I-1)+(V-4),(I-1)+(V-5),(I-1)+(V-6).
(I-2)+(II-0),(I-2)+(II-1),(I-2)+(II-2),(I-2)+(II-3),(I-2)+(II-4),(I-2)+(II-5),(I-2)+(II-6),(I-2)+(II-9),(I-2)+(II-12),(I-2)+(III-1),(I-2)+(III-4),(I-2)+(III-10),(I-2)+(III-11),(I-2)+(IV-1),(I-2)+(IV-2),(I-2)+(IV-3),(I-2)+(IV-4),(I-2)+(IV-5),(I-2)+(b-1),(I-2)+(b-2),(I-2)+(b-3),(I-2)+(b-4),(I-2)+(b-5),(I-2)+(b-6),(I-2)+(b-7),(I-2)+(b-8),(I-2)+(b-9),(I-2)+(b-10),(I-2)+(b-11),(I-2)+(b-12),(I-2)+(b-13),(I-2)+(b-14),(I-2)+(S3-1),(I-2)+(S3-2),(I-2)+(S3-3),(I-2)+(S3-4),(I-2)+(S3-5),(I-2)+(h-1),(I-2)+(h-2),(I-2)+(V-1),(I-2)+(V-2),(I-2)+(V-3),(I-2)+(V-4),(I-2)+(V-5),(I-2)+(V-6).
(I-3)+(II-0),(I-3)+(II-1),(I-3)+(II-2),(I-3)+(II-3),(I-3)+(II-4),(I-3)+(II-5),(I-3)+(II-6),(I-3)+(II-9),(I-3)+(II-12),(I-3)+(III-1),(I-3)+(III-4),(I-3)+(III-10),(I-3)+(III-11),(I-3)+(IV-1),(I-3)+(IV-2),(I-3)+(IV-3),(I-3)+(IV-4),(I-3)+(IV-5),(I-3)+(b-1),(I-3)+(b-2),(I-3)+(b-3),(I-3)+(b-4),(I-3)+(b-5),(I-3)+(b-6),(I-3)+(b-7),(I-3)+(b-8),(I-3)+(b-9),(I-3)+(b-10),(I-3)+(b-11),(I-3)+(b-12),(I-3)+(b-13),(I-3)+(b-14),(I-3)+(S3-1),(I-3)+(S3-2),(I-3)+(S3-3),(I-3)+(S3-4),(I-3)+(S3-5),(I-3)+(h-1),(I-3)+(h-2),(I-3)+(V-1),(I-3)+(V-2),(I-3)+(V-3),(I-3)+(V-4),(I-3)+(V-5),(I-3)+(V-6).
(I-4)+(II-0),(I-4)+(II-1),(I-4)+(II-2),(I-4)+(II-3),(I-4)+(II-4),(I-4)+(II-5),(I-4)+(II-6),(I-4)+(II-9),(I-4)+(II-12),(I-4)+(III-1),(I-4)+(III-4),(I-4)+(III-10),(I-4)+(III-11),(I-4)+(IV-1),(I-4)+(IV-2),(I-4)+(IV-3),(I-4)+(IV-4),(I-4)+(IV-5),(I-4)+(b-1),(I-4)+(b-2),(I-4)+(b-3),(I-4)+(b-4),(I-4)+(b-5),(I-4)+(b-6),(I-4)+(b-7),(I-4)+(b-8),(I-4)+(b-9),(I-4)+(b-10),(I-4)+(b-11),(I-4)+(b-12),(I-4)+(b-13),(I-4)+(b-14),(I-4)+(S3-1),(I-4)+(S3-2),(I-4)+(S3-3),(I-4)+(S3-4),(I-4)+(S3-5),(I-4)+(h-1),(I-4)+(h-2),(I-4)+(V-1),(I-4)+(V-2),(I-4)+(V-3),(I-4)+(V-4),(I-4)+(V-5),(I-4)+(V-6).
(I-5)+(II-0),(I-5)+(II-1),(I-5)+(II-2),(I-5)+(II-3),(I-5)+(II-4),(I-5)+(II-5),(I-5)+(II-6),(I-5)+(II-9),(I-5)+(II-12),(I-5)+(III-1),(I-5)+(III-4),(I-5)+(III-10),(I-5)+(III-11),(I-5)+(IV-1),(I-5)+(IV-2),(I-5)+(IV-3),(I-5)+(IV-4),(I-5)+(IV-5),(I-5)+(b-1),(I-5)+(b-2),(I-5)+(b-3),(I-5)+(b-4),(I-5)+(b-5),(I-5)+(b-6),(I-5)+(b-7),(I-5)+(b-8),(I-5)+(b-9),(I-5)+(b-10),(I-5)+(b-11),(I-5)+(b-12),(I-5)+(b-13),(I-5)+(b-14),(I-5)+(S3-1),(I-5)+(S3-2),(I-5)+(S3-3),(I-5)+(S3-4),(I-5)+(S3-5),(I-5)+(h-1),(I-5)+(h-2),(I-5)+(V-1),(I-5)+(V-2),(I-5)+(V-3),(I-5)+(V-4),(I-5)+(V-5),(I-5)+(V-6)。
(I-6)+(II-0),(I-6)+(II-1),(I-6)+(II-2),(I-6)+(II-3),(I-6)+(II-4),(I-6)+(II-5),(I-6)+(II-6),(I-6)+(II-9),(I-6)+(II-12),(I-6)+(III-1),(I-6)+(III-4),(I-6)+(III-10),(I-6)+(III-11),(I-6)+(IV-1),(I-6)+(IV-2),(I-6)+(IV-3),(I-6)+(IV-4),(I-6)+(IV-5),(I-6)+(b-1),(I-6)+(b-2),(I-6)+(b-3),(I-6)+(b-4),(I-6)+(b-5),(I-6)+(b-6),(I-6)+(b-7),(I-6)+(b-8),(I-6)+(b-9),(I-6)+(b-10),(I-6)+(b-11),(I-6)+(b-12),(I-6)+(b-13),(I-6)+(b-14),(I-6)+(S3-1),(I-6)+(S3-2),(I-6)+(S3-3),(I-6)+(S3-4),(I-6)+(S3-5),(I-6)+(h-1),(I-6)+(h-2),(I-6)+(V-1),(I-6)+(V-2),(V-6)+(V-3),(I-6)+(V-4),(I-6)+(V-5),(I-6)+(V-6).
(I-7)+(II-0),(I-7)+(II-1),(I-7)+(II-2),(I-7)+(II-3),(I-7)+(II-4),(I-7)+(II-5),(I-7)+(II-6),(I-7)+(II-9),(I-7)+(II-12),(I-7)+(III-1),(I-7)+(III-4),(I-7)+(III-10),(I-7)+(III-11),(I-7)+(IV-1),(I-7)+(IV-2),(I-7)+(IV-3),(I-7)+(IV-4),(I-7)+(IV-5),(I-7)+(b-1),(I-7)+(b-2),(I-7)+(b-3),(I-7)+(b-4),(I-7)+(b-5),(I-7)+(b-6),(I-7)+(b-7),(I-7)+(b-8),(I-7)+(b-9),(I-7)+(b-10),(I-7)+(b-11),(I-7)+(b-12),(I-7)+(b-13),(I-7)+(b-14),(I-7)+(S3-1),(I-7)+(S3-2),(I-7)+(S3-3),(I-7)+(S3-4),(I-7)+(S3-5),(I-7)+(h-1),(I-7)+(h-2),(I-7)+(V-1),(I-7)+(V-2),(I-7)+(V-3),(I-7)+(V-4),(I-7)+(V-5),(I-7)+(V-6).
(I-8)+(II-0),(I-8)+(II-1),(I-8)+(II-2),(I-8)+(II-3),(I-8)+(II-4),(I-8)+(II-5),(I-8)+(II-6),(I-8)+(II-9),(I-8)+(II-12),(I-8)+(III-1),(I-8)+(III-4),(I-8)+(III-10),(I-8)+(III-11),(I-8)+(IV-1),(I-8)+(IV-2),(I-8)+(IV-3),(I-8)+(IV-4),(I-8)+(IV-5),(I-8)+(b-1),(I-8)+(b-2),(I-8)+(b-3),(I-8)+(b-4),(I-8)+(b-5),(I-8)+(b-6),(I-8)+(b-7),(I-8)+(b-8),(I-8)+(b-9),(I-8)+(b-10),(I-8)+(b-11),(I-8)+(b-12),(I-8)+(b-13),(I-8)+(b-14),(I-8)+(S3-1),(I-8)+(S3-2),(I-8)+(S3-3),(I-8)+(S3-4),(I-8)+(S3-5),(I-8)+(h-1),(I-8)+(h-2),(I-8)+(V-1),(I-8)+(V-2),(I-8)+(V-3),(I-8)+(V-4),(I-8)+(V-5),(I-8)+(V-6).
(I-9)+(II-0),(I-9)+(II-1),(I-9)+(II-2),(I-9)+(II-3),(I-9)+(II-4),(I-9)+(II-5),(I-9)+(II-6),(I-9)+(II-9),(I-9)+(II-12),(I-9)+(III-1),(I-9)+(III-4),(I-9)+(III-10),(I-9)+(III-11),(I-9)+(IV-1),(I-9)+(IV-2),(I-9)+(IV-3),(I-9)+(IV-4),(I-9)+(IV-5),(I-9)+(b-1),(I-9)+(b-2),(I-9)+(b-3),(I-9)+(b-4),(I-9)+(b-5),(I-9)+(b-6),(I-9)+(b-7),(I-9)+(b-8),(I-9)+(b-9),(I-9)+(b-10),(I-9)+(b-11),(I-9)+(b-12),(I-9)+(b-13),(I-9)+(b-14),(I-9)+(S3-1),(I-9)+(S3-2),(I-9)+(S3-3),(I-9)+(S3-4),(I-9)+(S3-5),(I-9)+(h-1),(I-9)+(h-2),(I-9)+(V-1),(I-9)+(V-2),(I-9)+(V-3),(I-9)+(V-4),(I-9)+(V-5),(I-9)+(V-6).
(I-10)+(II-0),(I-10)+(II-1),(I-10)+(II-2),(I-10)+(II-3),(I-10)+(II-4),(I-10)+(II-5),(I-10)+(II-6),(I-10)+(II-9),(I-10)+(II-12),(I-10)+(III-1),(I-10)+(III-4),(I-10)+(III-10),(I-10)+(III-11),(I-10)+(IV-1),(I-10)+(IV-2),(I-10)+(IV-3),(I-10)+(IV-4),(I-10)+(IV-5),(I-10)+(b-1),(I-10)+(b-2),(I-10)+(b-3),(I-10)+(b-4),(I-10)+(b-5),(I-10)+(b-6),(I-10)+(b-7),(I-10)+(b-8),(I-10)+(b-9),(I-10)+(b-10),(I-10)+(b-11),(I-10)+(b-12),(I-10)+(b-13),(I-10)+(b-14),(I-10)+(S3-1),(I-10)+(S3-2),(I-10)+(S3-3),(I-10)+(S3-4),(I-10)+(S3-5),(I-10)+(h-1),(I-10)+(h-2),(I-10)+(V-1),(I-10)+(V-2),(I-10)+(V-3),(I-10)+(V-4),(I-10)+(V-5),(I-10)+(V-6).
(I-11)+(II-0),(I-11)+(II-1),(I-11)+(II-2),(I-11)+(II-3),(I-11)+(II-4),(I-11)+(II-5),(I-11)+(II-6),(I-11)+(II-9),(I-11)+(II-12),(I-11)+(III-1),(I-11)+(III-4),(I-11)+(III-10),(I-11)+(III-11),(I-11)+(IV-1),(I-11)+(IV-2),(I-11)+(IV-3),(I-11)+(IV-4),(I-11)+(IV-5),(I-11)+(b-1),(I-11)+(b-2),(I-11)+(b-3),(I-11)+(b-4),(I-11)+(b-5),(I-11)+(b-6),(I-11)+(b-7),(I-11)+(b-8),(I-11)+(b-9),(I-11)+(b-10),(I-11)+(b-11),(I-11)+(b-12),(I-11)+(b-13),(I-11)+(b-14),(I-11)+(S3-1),(I-11)+(S3-2),(I-11)+(S3-3),(I-11)+(S3-4),(I-11)+(S3-5),(I-11)+(h-1),(I-11)+(h-2),(I-11)+(V-1),(I-11)+(V-2),(I-11)+(V-3),(I-11)+(V-4),(I-11)+(V-5),(I-11)+(V-6).
(I-12)+(II-0),(I-12)+(II-1),(I-12)+(II-2),(I-12)+(II-3),(I-12)+(II-4),(I-12)+(II-5),(I-12)+(II-6),(I-12)+(II-9),(I-12)+(II-12),(I-12)+(III-1),(I-12)+(III-4),(I-12)+(III-10),(I-12)+(III-11),(I-12)+(IV-1),(I-12)+(IV-2),(I-12)+(IV-3),(I-12)+(IV-4),(I-12)+(IV-5),(I-12)+(b-1),(I-12)+(b-2),(I-12)+(b-3),(I-12)+(b-4),(I-12)+(b-5),(I-12)+(b-6),(I-12)+(b-7),(I-12)+(b-8),(I-12)+(b-9),(I-12)+(b-10),(I-12)+(b-11),(I-12)+(b-12),(I-12)+(b-13),(I-12)+(b-14),(I-12)+(S3-1),(I-12)+(S3-2),(I-12)+(S3-3),(I-12)+(S3-4),(I-12)+(S3-5),(I-12)+(h-1),(I-12)+(h-2),(I-12)+(V-1),(I-12)+(V-2),(I-12)+(V-3),(I-12)+(V-4),(I-12)+(V-5),(I-12)+(V-6).
(I-13)+(II-0),(I-13)+(II-1),(I-13)+(II-2),(I-13)+(II-3),(I-13)+(II-4),(I-13)+(II-5),(I-13)+(II-6),(I-13)+(II-9),(I-13)+(II-12),(I-13)+(III-1),(I-13)+(III-4),(I-13)+(III-10),(I-13)+(III-11),(I-13)+(IV-1),(I-13)+(IV-2),(I-13)+(IV-3),(I-13)+(IV-4),(I-13)+(IV-5),(I-13)+(b-1),(I-13)+(b-2),(I-13)+(b-3),(I-13)+(b-4),(I-13)+(b-5),(I-13)+(b-6),(I-13)+(b-7),(I-13)+(b-8),(I-13)+(b-9),(I-13)+(b-10),(I-13)+(b-11),(I-13)+(b-12),(I-13)+(b-13),(I-13)+(b-14),(I-13)+(S3-1),(I-13)+(S3-2),(I-13)+(S3-3),(I-13)+(S3-4),(I-13)+(S3-5),(I-13)+(h-1),(I-13)+(h-2),(I-13)+(V-1),(I-13)+(V-2),(I-13)+(V-3),(I-13)+(V-4),(I-13)+(V-5),(I-13)+(V-6).
(I-14)+(II-0),(I-14)+(II-1),(I-14)+(II-2),(I-14)+(II-3),(I-14)+(II-4),(I-14)+(II-5),(I-14)+(II-6),(I-14)+(II-9),(I-14)+(II-12),(I-14)+(III-1),(I-14)+(III-4),(I-14)+(III-10),(I-14)+(III-11),(I-14)+(IV-1),(I-14)+(IV-2),(I-14)+(IV-3),(I-14)+(IV-4),(I-14)+(IV-5),(I-14)+(b-1),(I-14)+(b-2),(I-14)+(b-3),(I-14)+(b-4),(I-14)+(b-5),(I-14)+(b-6),(I-14)+(b-7),(I-14)+(b-8),(I-14)+(b-9),(I-14)+(b-10),(I-14)+(b-11),(I-14)+(b-12),(I-14)+(b-13),(I-14)+(b-14),(I-14)+(S3-1),(I-14)+(S3-2),(I-14)+(S3-3),(I-14)+(S3-4),(I-14)+(S3-5),(I-14)+(h-1),(I-14)+(h-2),(I-14)+(V-1),(I-14)+(V-2),(I-14)+(V-3),(I-14)+(V-4),(I-14)+(V-5),(I-14)+(V-6).
(I-15)+(II-0),(I-15)+(II-1),(I-15)+(II-2),(I-15)+(II-3),(I-15)+(II-4),(I-15)+(II-5),(I-15)+(II-6),(I-15)+(II-9),(I-15)+(II-12),(I-15)+(III-1),(I-15)+(III-4),(I-15)+(III-10),(I-15)+(III-11),(I-15)+(IV-1),(I-15)+(IV-2),(I-15)+(IV-3),(I-15)+(IV-4),(I-15)+(IV-5),(I-15)+(b-1),(I-15)+(b-2),(I-15)+(b-3),(I-15)+(b-4),(I-15)+(b-5),(I-15)+(b-6),(I-15)+(b-7),(I-15)+(b-8),(I-15)+(b-9),(I-15)+(b-10),(I-15)+(b-11),(I-15)+(b-12),(I-15)+(b-13),(I-15)+(b-14),(I-15)+(S3-1),(I-15)+(S3-2),(I-15)+(S3-3),(I-15)+(S3-4),(I-15)+(S3-5),(I-15)+(h-1),(I-15)+(h-2),(I-15)+(V-1),(I-15)+(V-2),(I-15)+(V-3),(I-15)+(V-4),(I-15)+(V-5),(I-15)+(V-6).
(I-16)+(II-0),(I-16)+(II-1),(I-16)+(II-2),(I-16)+(II-3),(I-16)+(II-4),(I-16)+(II-5),(I-16)+(II-6),(I-16)+(II-9),(I-16)+(II-12),(I-16)+(III-1),(I-16)+(III-4),(I-16)+(III-10),(I-16)+(III-11),(I-16)+(IV-1),(I-16)+(IV-2),(I-16)+(IV-3),(I-16)+(IV-4),(I-16)+(IV-5),(I-16)+(b-1),(I-16)+(b-2),(I-16)+(b-3),(I-16)+(b-4),(I-16)+(b-5),(I-16)+(b-6),(I-16)+(b-7),(I-16)+(b-8),(I-16)+(b-9),(I-16)+(b-10),(I-16)+(b-11),(I-16)+(b-12),(I-16)+(b-13),(I-16)+(b-14),(I-16)+(S3-1),(I-16)+(S3-2),(I-16)+(S3-3),(I-16)+(S3-4),(I-16)+(S3-5),(I-16)+(h-1),(I-16)+(h-2),(I-16)+(V-1),(I-16)+(V-2),(I-16)+(V-3),(I-16)+(V-4),(I-16)+(V-5),(I-16)+(V-6).
(I-17)+(II-0),(I-17)+(II-1),(I-17)+(II-2),(I-17)+(II-3),(I-17)+(II-4),(I-17)+(II-5),(I-17)+(II-6),(I-17)+(II-9),(I-17)+(II-12),(I-17)+(III-1),(I-17)+(III-4),(I-17)+(III-10),(I-17)+(III-11),(I-17)+(IV-1),(I-17)+(IV-2),(I-17)+(IV-3),(I-17)+(IV-4),(I-17)+(IV-5),(I-17)+(b-1),(I-17)+(b-2),(I-17)+(b-3),(I-17)+(b-4),(I-17)+(b-5),(I-17)+(b-6),(I-17)+(b-7),(I-17)+(b-8),(I-17)+(b-9),(I-17)+(b-10),(I-17)+(b-11),(I-17)+(b-12),(I-17)+(b-13),(I-17)+(b-14),(I-17)+(S3-1),(I-17)+(S3-2),(I-17)+(S3-3),(I-17)+(S3-4),(I-17)+(S3-5),(I-17)+(h-1),(I-17)+(h-2),(I-17)+(V-1),(I-17)+(V-2),(I-17)+(V-3),(I-17)+(V-4),(I-17)+(V-5),(I-17)+(V-6).
(I-18)+(II-0),(I-18)+(II-1),(I-18)+(II-2),(I-18)+(II-3),(I-18)+(II-4),(I-18)+(II-5),(I-18)+(II-6),(I-18)+(II-9),(I-18)+(II-12),(I-18)+(III-1),(I-18)+(III-4),(I-18)+(III-10),(I-18)+(III-11),(I-18)+(IV-1),(I-18)+(IV-2),(I-18)+(IV-3),(I-18)+(IV-4),(I-18)+(IV-5),(I-18)+(b-1),(I-18)+(b-2),(I-18)+(b-3),(I-18)+(b-4),(I-18)+(b-5),(I-18)+(b-6),(I-18)+(b-7),(I-18)+(b-8),(I-18)+(b-9),(I-18)+(b-10),(I-18)+(b-11),(I-18)+(b-12),(I-18)+(b-13),(I-18)+(b-14),(I-18)+(S3-1),(I-18)+(S3-2),(I-18)+(S3-3),(I-18)+(S3-4),(I-18)+(S3-5),(I-18)+(h-1),(I-18)+(h-2),(I-18)+(V-1),(I-18)+(V-2),(I-18)+(V-3),(I-18)+(V-4),(I-18)+(V-5),(I-18)+(V-6).
(I-19)+(II-0),(I-19)+(II-1),(I-19)+(II-2),(I-19)+(II-3),(I-19)+(II-4),(I-19)+(II-5),(I-19)+(II-6),(I-19)+(II-9),(I-19)+(II-12),(I-19)+(III-1),(I-19)+(III-4),(I-19)+(III-10),(I-19)+(III-11),(I-19)+(IV-1),(I-19)+(IV-2),(I-19)+(IV-3),(I-19)+(IV-4),(I-19)+(IV-5),(I-19)+(b-1),(I-19)+(b-2),(I-19)+(b-3),(I-19)+(b-4),(I-19)+(b-5),(I-19)+(b-6),(I-19)+(b-7),(I-19)+(b-8),(I-19)+(b-9),(I-19)+(b-10),(I-19)+(b-11),(I-19)+(b-12),(I-19)+(b-13),(I-19)+(b-14),(I-19)+(S3-1),(I-19)+(S3-2),(I-19)+(S3-3),(I-19)+(S3-4),(I-19)+(S3-5),(I-19)+(h-1),(I-19)+(h-2),(I-19)+(V-1),(I-19)+(V-2),(I-19)+(V-3),(I-19)+(V-4),(I-19)+(V-5),(I-19)+(V-6).
(I-20)+(II-0),(I-20)+(II-1),(I-20)+(II-2),(I-20)+(II-3),(I-20)+(II-4),(I-20)+(II-5),(I-20)+(II-6),(I-20)+(II-9),(I-20)+(II-12),(I-20)+(III-1),(I-20)+(III-4),(I-20)+(III-10),(I-20)+(III-11),(I-20)+(IV-1),(I-20)+(IV-2),(I-20)+(IV-3),(I-20)+(IV-4),(I-20)+(IV-5),(I-20)+(b-1),(I-20)+(b-2),(I-20)+(b-3),(I-20)+(b-4),(I-20)+(b-5),(I-20)+(b-6),(I-20)+(b-7),(I-20)+(b-8),(I-20)+(b-9),(I-20)+(b-10),(I-20)+(b-11),(I-20)+(b-12),(I-20)+(b-13),(I-20)+(b-14),(I-20)+(S3-1),(I-20)+(S3-2),(I-20)+(S3-3),(I-20)+(S3-4),(I-20)+(S3-5),(I-20)+(h-1),(I-20)+(h-2),(I-20)+(V-1),(I-20)+(V-2),(I-20)+(V-3),(I-20)+(V-4),(I-20)+(V-5),(I-20)+(V-6).
(I-21)+(II-0),(I-21)+(II-1),(I-21)+(II-2),(I-21)+(II-3),(I-21)+(II-4),(I-21)+(II-5),(I-21)+(II-6),(I-21)+(II-9),(I-21)+(II-12),(I-21)+(III-1),(I-21)+(III-4),(I-21)+(III-10),(I-21)+(III-11),(I-21)+(IV-1),(I-21)+(IV-2),(I-21)+(IV-3),(I-21)+(IV-4),(I-21)+(IV-5),(I-21)+(b-1),(I-21)+(b-2),(I-21)+(b-3),(I-21)+(b-4),(I-21)+(b-5),(I-21)+(b-6),(I-21)+(b-7),(I-21)+(b-8),(I-21)+(b-9),(I-21)+(b-10),(I-21)+(b-11),(I-21)+(b-12),(I-21)+(b-13),(I-21)+(b-14),(I-21)+(S3-1),(I-21)+(S3-2),(I-21)+(S3-3),(I-21)+(S3-4),(I-21)+(S3-5),(I-21)+(h-1),(I-21)+(h-2),(I-21)+(V-1),(I-21)+(V-2),(I-21)+(V-3),(I-21)+(V-4),(I-21)+(V-5),(I-21)+(V-6).
(I-22)+(II-0),(I-22)+(II-1),(I-22)+(II-2),(I-22)+(II-3),(I-22)+(II-4),(I-22)+(II-5),(I-22)+(II-6),(I-22)+(II-9),(I-22)+(II-12),(I-22)+(III-1),(I-22)+(III-4),(I-22)+(III-10),(I-22)+(III-11),(I-22)+(IV-1),(I-22)+(IV-2),(I-22)+(IV-3),(I-22)+(IV-4),(I-22)+(IV-5),(I-22)+(b-1),(I-22)+(b-2),(I-22)+(b-3),(I-22)+(b-4),(I-22)+(b-5),(I-22)+(b-6),(I-22)+(b-7),(I-22)+(b-8),(I-22)+(b-9),(I-22)+(b-10),(I-22)+(b-11),(I-22)+(b-12),(I-22)+(b-13),(I-22)+(b-14),(I-22)+(S3-1),(I-22)+(S3-2),(I-22)+(S3-3),(I-22)+(S3-4),(I-22)+(S3-5),(I-22)+(h-1),(I-22)+(h-2),(I-22)+(V-1),(I-22)+(V-2),(I-22)+(V-3),(I-22)+(V-4),(I-22)+(V-5),(I-22)+(V-6).
(I-23)+(II-0),(I-23)+(II-1),(I-23)+(II-2),(I-23)+(II-3),(I-23)+(II-4),(I-23)+(II-5),(I-23)+(II-6),(I-23)+(II-9),(I-23)+(II-12),(I-23)+(III-1),(I-23)+(III-4),(I-23)+(III-10),(I-23)+(III-11),(I-23)+(IV-1),(I-23)+(IV-2),(I-23)+(IV-3),(I-23)+(IV-4),(I-23)+(IV-5),(I-23)+(b-1),(I-23)+(b-2),(I-23)+(b-3),(I-23)+(b-4),(I-23)+(b-5),(I-23)+(b-6),(I-23)+(b-7),(I-23)+(b-8),(I-23)+(b-9),(I-23)+(b-10),(I-23)+(b-11),(I-23)+(b-12),(I-23)+(b-13),(I-23)+(b-14),(I-23)+(S3-1),(I-23)+(S3-2),(I-23)+(S3-3),(I-23)+(S3-4),(I-23)+(S3-5),(I-23)+(h-1),(I-23)+(h-2),(I-23)+(V-1),(I-23)+(V-2),(I-23)+(V-3),(I-23)+(V-4),(I-23)+(V-5),(I-23)+(V-6).
(I-24)+(II-0),(I-24)+(II-1),(I-24)+(II-2),(I-24)+(II-3),(I-24)+(II-4),(I-24)+(II-5),(I-24)+(II-6),(I-24)+(II-9),(I-24)+(II-12),(I-24)+(III-1),(I-24)+(III-4),(I-24)+(III-10),(I-24)+(III-11),(I-24)+(IV-1),(I-24)+(IV-2),(I-24)+(IV-3),(I-24)+(IV-4),(I-24)+(IV-5),(I-24)+(b-1),(I-24)+(b-2),(I-24)+(b-3),(I-24)+(b-4),(I-24)+(b-5),(I-24)+(b-6),(I-24)+(b-7),(I-24)+(b-8),(I-24)+(b-9),(I-24)+(b-10),(I-24)+(b-11),
(I-24)+(b-12),(I-24)+(b-13),(I-24)+(b-14),(I-24)+(S3-1),(I-24)+(S3-2),(I-24)+(S3-3),(I-24)+(S3-4),(I-24)+(S3-5),(I-24)+(h-1),(I-24)+(h-2),(I-24)+(V-1),(I-24)+(V-2),(I-24)+(V-3),(I-24)+(V-4),(I-24)+(V-5),(I-24)+(V-6).
(I-25)+(II-0),(I-25)+(II-1),(I-25)+(II-2),(I-25)+(II-3),(I-25)+(II-4),(I-25)+(II-5),(I-25)+(II-6),(I-25)+(II-9),(I-25)+(II-12),(I-25)+(III-1),(I-25)+(III-4),(I-25)+(III-10),(I-25)+(III-11),(I-25)+(IV-1),(I-25)+(IV-2),(I-25)+(IV-3),(I-25)+(IV-4),(I-25)+(IV-5),(I-25)+(b-1),(I-25)+(b-2),(I-25)+(b-3),(I-25)+(b-4),(I-25)+(b-5),(I-25)+(b-6),(I-25)+(b-7),(I-25)+(b-8),(I-25)+(b-9),(I-25)+(b-10),(I-25)+(b-11),(I-25)+(b-12),(I-25)+(b-13),(I-25)+(b-14),(I-25)+(S3-1),(I-25)+(S3-2),(I-25)+(S3-3),(I-25)+(S3-4),(I-25)+(S3-5),(I-25)+(h-1),(I-25)+(h-2),(I-25)+(V-1),(I-25)+(V-2),(I-25)+(V-3),(I-25)+(V-4),(I-25)+(V-5),(I-25)+(V-6).
(I-26)+(II-0),(I-26)+(II-1),(I-26)+(II-2),(I-26)+(II-3),(I-26)+(II-4),(I-26)+(II-5),(I-26)+(II-6),(I-26)+(II-9),(I-26)+(II-12),(I-26)+(III-1),(I-26)+(III-4),(I-26)+(III-10),(I-26)+(III-11),(I-26)+(IV-1),(I-26)+(IV-2),(I-26)+(IV-3),(I-26)+(IV-4),(I-26)+(IV-5),(I-26)+(b-1),(I-26)+(b-2),(I-26)+(b-3),(I-26)+(b-4),(I-26)+(b-5),(I-26)+(b-6),(I-26)+(b-7),(I-26)+(b-8),(I-26)+(b-9),(I-26)+(b-10),(I-26)+(b-11),(I-26)+(b-12),(I-26)+(b-13),(I-26)+(b-14),(I-26)+(S3-1),(I-26)+(S3-2),(I-26)+(S3-3),(I-26)+(S3-4),(I-26)+(S3-5),(I-26)+(h-1),(I-26)+(h-2),(I-26)+(V-1),(I-26)+(V-2),(I-26)+(V-3),(I-26)+(V-4),(I-26)+(V-5),(I-26)+(V-6).
(I-27)+(II-0),(I-27)+(II-1),(I-27)+(II-2),(I-27)+(II-3),(I-27)+(II-4),(I-27)+(II-5),(I-27)+(II-6),(I-27)+(II-9),(I-27)+(II-12),(I-27)+(III-1),(I-27)+(III-4),(I-27)+(III-10),(I-27)+(III-11),(I-27)+(IV-1),(I-27)+(IV-2),(I-27)+(IV-3),(I-27)+(IV-4),(I-27)+(IV-5),(I-27)+(b-1),(I-27)+(b-2),(I-27)+(b-3),(I-27)+(b-4),(I-27)+(b-5),(I-27)+(b-6),(I-27)+(b-7),(I-27)+(b-8),(I-27)+(b-9),(I-27)+(b-10),(I-27)+(b-11),
(I-27)+(b-12),(I-27)+(b-13),(I-27)+(b-14),(I-27)+(S3-1),(I-27)+(S3-2),(I-27)+(S3-3),(I-27)+(S3-4),(I-27)+(S3-5),(I-27)+(h-1),(I-27)+(h-2),(I-27)+(V-1),(I-27)+(V-2),(I-27)+(V-3),(I-27)+(V-4),(I-27)+(V-5),(I-27)+(V-6).
(I-28)+(II-0),(I-28)+(II-1),(I-28)+(II-2),(I-28)+(II-3),(I-28)+(II-4),(I-28)+(II-5),(I-28)+(II-6),(I-28)+(II-9),(I-28)+(II-12),(I-28)+(III-1),(I-28)+(III-4),(I-28)+(III-10),(I-28)+(III-11),(I-28)+(IV-1),(I-28)+(IV-2),(I-28)+(IV-3),(I-28)+(IV-4),(I-28)+(IV-5),(I-28)+(b-1),(I-28)+(b-2),(I-28)+(b-3),(I-28)+(b-4),(I-28)+(b-5),(I-28)+(b-6),(I-28)+(b-7),(I-28)+(b-8),(I-28)+(b-9),(I-28)+(b-10),(I-28)+(b-11),(I-28)+(b-12),(I-28)+(b-13),(I-28)+(b-14),(I-28)+(S3-1),(I-28)+(S3-2),(I-28)+(S3-3),(I-28)+(S3-4),(I-28)+(S3-5),(I-28)+(h-1),(I-28)+(h-2),(I-28)+(V-1),(I-28)+(V-2),(I-28)+(V-3),(I-28)+(V-4),(I-28)+(V-5),(I-28)+(V-6)-
(I-29)+(II-0),(I-29)+(II-1),(I-29)+(II-2),(I-29)+(II-3),(I-29)+(II-4),(I-29)+(II-5),(I-29)+(II-6),(I-29)+(II-9),(I-29)+(II-12),(I-29)+(III-1),(I-29)+(III-4),(I-29)+(III-10),(I-29)+(III-11),(I-29)+(IV-1),(I-29)+(IV-2),(I-29)+(IV-3),(I-29)+(IV-4),(I-29)+(IV-5),(I-29)+(b-1),(I-29)+(b-2),(I-29)+(b-3),(I-29)+(b-4),(I-29)+(b-5),(I-29)+(b-6),(I-29)+(b-7),(I-29)+(b-8),(I-29)+(b-9),(I-29)+(b-10),(I-29)+(b-11),(I-29)+(b-12),(I-29)+(b-13),(I-29)+(b-14),(I-29)+(S3-1),(I-29)+(S3-2),(I-29)+(S3-3),(I-29)+(S3-4),(I-29)+(S3-5),(I-29)+(h-1),(I-29)+(h-2),(I-29)+(V-1),(I-29)+(V-2),(I-29)+(V-3),(I-29)+(V-4),(I-29)+(V-5),(I-29)+(V-6).
(I-30)+(II-0),(I-30)+(II-1),(I-30)+(II-2),(I-30)+(II-3),(I-30)+(II-4),(I-30)+(II-5),(I-30)+(II-6),(I-30)+(II-9),(I-30)+(II-12),(I-30)+(III-1),(I-30)+(III-4),(I-30)+(III-10),(I-30)+(III-11),(I-30)+(IV-1),(I-30)+(IV-2),(I-30)+(IV-3),(I-30)+(IV-4),(I-30)+(IV-5),(I-30)+(b-1),(I-30)+(b-2),(I-30)+(b-3),(I-30)+(b-4),(I-30)+(b-5),(I-30)+(b-6),(I-30)+(b-7),(I-30)+(b-8),(I-30)+(b-9),(I-30)+(b-10),(I-30)+(b-11),(I-30)+(b-12),(I-30)+(b-13),(I-30)+(b-14),(I-30)+(S3-1),(I-30)+(S3-2),(I-30)+(S3-3),(I-30)+(S3-4),(I-30)+(S3-5),(I-30)+(h-1),(I-30)+(h-2),(I-30)+(V-1),(I-30)+(V-2),(I-30)+(V-3),(I-30)+(V-4),(I-30)+(V-5),(I-30)+(V-6).
(I-31)+(II-0),(I-31)+(II-1),(I-31)+(II-2),(I-31)+(II-3),(I-31)+(II-4),(I-31)+(II-5),(I-31)+(II-6),(I-31)+(II-9),(I-31)+(II-12),(I-31)+(III-1),(I-31)+(III-4),(I-31)+(III-10),(I-31)+(III-11),(I-31)+(IV-1),(I-31)+(IV-2),(I-31)+(IV-3),(I-31)+(IV-4),(I-31)+(IV-5),(I-31)+(b-1),(I-31)+(b-2),(I-31)+(b-3),(I-31)+(b-4),(I-31)+(b-5),(I-31)+(b-6),(I-31)+(b-7),(I-31)+(b-8),(I-31)+(b-9),(I-31)+(b-10),(I-31)+(b-11),(I-31)+(b-12),(I-31)+(b-13),(I-31)+(b-14),(I-31)+(S3-1),(I-31)+(S3-2),(I-31)+(S3-3),(I-31)+(S3-4),(I-31)+(S3-5),(I-31)+(h-1),(I-31)+(h-2),(I-31)+(V-1),(I-31)+(V-2),(I-31)+(V-3),(I-31)+(V-4),(I-31)+(V-5),(I-31)+(V-6).
(I-32)+(II-0),(I-32)+(II-1),(I-32)+(II-2),(I-32)+(II-3),(I-32)+(II-4),(I-32)+(II-5),(I-32)+(II-6),(I-32)+(II-9),(I-32)+(II-12),(I-32)+(III-1),(I-32)+(III-4),(I-32)+(III-10),(I-32)+(III-11),(I-32)+(IV-1),(I-32)+(IV-2),(I-32)+(IV-3),(I-32)+(IV-4),(I-32)+(IV-5),(I-32)+(b-1),(I-32)+(b-2),(I-32)+(b-3),(I-32)+(b-4),(I-32)+(b-5),(I-32)+(b-6),(I-32)+(b-7),(I-32)+(b-8),(I-32)+(b-9),(I-32)+(b-10),(I-32)+(b-11),(I-32)+(b-12),(I-32)+(b-13),(I-32)+(b-14),(I-32)+(S3-1),(I-32)+(S3-2),(I-32)+(S3-3),(I-32)+(S3-4),(I-32)+(S3-5),(I-32)+(h-1),(I-32)+(h-2),(I-32)+(V-1),(I-32)+(V-2),(I-32)+(V-3),(I-32)+(V-4),(I-32)+(V-5),(I-32)+(V-6).
(I-33)+(II-0),(I-33)+(II-1),(I-33)+(II-2),(I-33)+(II-3),(I-33)+(II-4),(I-33)+(II-5),(I-33)+(II-6),(I-33)+(II-9),(I-33)+(II-12),(I-33)+(III-1),(I-33)+(III-4),(I-33)+(III-10),(I-33)+(III-11),(I-33)+(IV-1),(I-33)+(IV-2),(I-33)+(IV-3),(I-33)+(IV-4),(I-33)+(IV-5),(I-33)+(b-1),(I-33)+(b-2),(I-33)+(b-3),(I-33)+(b-4),(I-33)+(b-5),(I-33)+(b-6),(I-33)+(b-7),(I-33)+(b-8),(I-33)+(b-9),(I-33)+(b-10),(I-33)+(b-11),(I-33)+(b-12),(I-33)+(b-13),(I-33)+(b-14),(I-33)+(S3-1),(I-33)+(S3-2),(I-33)+(S3-3),(I-33)+(S3-4),(I-33)+(S3-5),(I-33)+(h-1),(I-33)+(h-2),(I-33)+(V-1),(I-33)+(V-2),(I-33)+(V-3),(I-33)+(V-4),(I-33)+(V-5),(I-33)+(V-6).
(I-34)+(II-0),(I-34)+(II-1),(I-34)+(II-2),(I-34)+(II-3),(I-34)+(II-4),(I-34)+(II-5),(I-34)+(II-6),(I-34)+(II-9),(I-34)+(II-12),(I-34)+(III-1),(I-34)+(III-4),(I-34)+(III-10),(I-34)+(III-11),(I-34)+(IV-1),(I-34)+(IV-2),(I-34)+(IV-3),(I-34)+(IV-4),(I-34)+(IV-5),(I-34)+(b-1),(I-34)+(b-2),(I-34)+(b-3),(I-34)+(b-4),(I-34)+(b-5),(I-34)+(b-6),(I-34)+(b-7),(I-34)+(b-8),(I-34)+(b-9),(I-34)+(b-10),(I-34)+(b-11),(I-34)+(b-12),(I-34)+(b-13),(I-34)+(b-14),(I-34)+(S3-1),(I-34)+(S3-2),(I-34)+(S3-3),(I-34)+(S3-4),(I-34)+(S3-5),(I-34)+(h-1),(I-34)+(h-2),(I-34)+(V-1),(I-34)+(V-2),(I-34)+(V-3),(I-34)+(V-4),(I-34)+(V-5),(I-34)+(V-6).
(I-35)+(II-0),(I-35)+(II-1),(I-35)+(II-2),(I-35)+(II-3),(I-35)+(II-4),(I-35)+(II-5),(I-35)+(II-6),(I-35)+(II-9),(I-35)+(II-12),(I-35)+(III-1),(I-35)+(III-4),(I-35)+(III-10),(I-35)+(III-11),(I-35)+(IV-1),(I-35)+(IV-2),(I-35)+(IV-3),(I-35)+(IV-4),(I-35)+(IV-5),(I-35)+(b-1),(I-35)+(b-2),(I-35)+(b-3),(I-35)+(b-4),(I-35)+(b-5),(I-35)+(b-6),(I-35)+(b-7),(I-35)+(b-8),(I-35)+(b-9),(I-35)+(b-10),(I-35)+(b-11),(I-35)+(b-12),(I-35)+(b-13),(I-35)+(b-14),(I-35)+(S3-1),(I-35)+(S3-2),(I-35)+(S3-3),(I-35)+(S3-4),(I-35)+(S3-5),(I-35)+(h-1),(I-35)+(h-2),(I-35)+(V-1),(I-35)+(V-2),(I-35)+(V-3),(I-35)+(V-4),(I-35)+(V-5),(I-35)+(V-6).
(I-36)+(II-0),(I-36)+(II-1),(I-36)+(II-2),(I-36)+(II-3),(I-36)+(II-4),(I-36)+(II-5),(I-36)+(II-6),(I-36)+(II-9),(I-36)+(II-12),(I-36)+(III-1),(I-36)+(III-4),(I-36)+(III-10),(I-36)+(III-11),(I-36)+(IV-1),(I-36)+(IV-2),(I-36)+(IV-3),(I-36)+(IV-4),(I-36)+(IV-5),(I-36)+(b-1),(I-36)+(b-2),(I-36)+(b-3),(I-36)+(b-4),(I-36)+(b-5),(I-36)+(b-6),(I-36)+(b-7),(I-36)+(b-8),(I-36)+(b-9),(I-36)+(b-10),(I-36)+(b-11),(I-36)+(b-12),(I-36)+(b-13),(I-36)+(b-14),(I-36)+(S3-1),(I-36)+(S3-2),(I-36)+(S3-3),(I-36)+(S3-4),(I-36)+(S3-5),(I-36)+(h-1),(I-36)+(h-2),(I-36)+(V-1),(I-36)+(V-2),(I-36)+(V-3),(I-36)+(V-4),(I-36)+(V-5),(I-36)+(V-6).
(I-37)+(II-0),(I-37)+(II-1),(I-37)+(II-2),(I-37)+(II-3),(I-37)+(II-4),(I-37)+(II-5),(I-37)+(II-6),(I-37)+(II-9),(I-37)+(II-1?2),(I-37)+(III-1),(I-37)+(III-4),(I-37)+(III-10),(I-37)+(III-11),(I-37)+(IV-1),(I-37)+(IV-2),(I-37)+(IV-3),(I-37)+(IV-4),(I-37)+(IV-5),(I-37)+(b-1),(I-37)+(b-2),(I-37)+(b-3),(I-37)+(b-4),(I-37)+(b-5),(I-37)+(b-6),(I-37)+(b-7),(I-37)+(b-8),(I-37)+(b-9),(I-37)+(b-10),(I-37)+(b-11),(I-37)+(b-12),(I-37)+(b-13),(I-37)+(b-14),(I-37)+(S3-1),(I-37)+(S3-2),(I-37)+(S3-3),(I-37)+(S3-4),(I-37)+(S3-5),(I-37)+(h-1),(I-37)+(h-2),(I-37)+(V-1),(I-37)+(V-2),(I-37)+(V-3),(I-37)+(V-4),(I-37)+(V-5),(I-37)+(V-6).
(I-38)+(II-0),(I-38)+(II-1),(I-38)+(II-2),(I-38)+(II-3),(I-38)+(II-4),(I-38)+(II-5),(I-38)+(II-6),(I-38)+(II-9),(I-38)+(II-12),(I-38)+(III-1),(I-38)+(III-4),(I-38)+(III-10),(I-38)+(III-11),(I-38)+(IV-1),(I-38)+(IV-2),(I-38)+(IV-3),(I-38)+(IV-4),(I-38)+(IV-5),(I-38)+(b-1),(I-38)+(b-2),(I-38)+(b-3),(I-38)+(b-4),(I-38)+(b-5),(I-38)+(b-6),(I-38)+(b-7),(I-38)+(b-8),(I-38)+(b-9),(I-38)+(b-10),(I-38)+(b-11),(I-38)+(b-12),(I-38)+(b-13),(I-38)+(b-14),(I-38)+(S3-1),(I-38)+(S3-2),(I-38)+(S3-3),(I-38)+(S3-4),(I-38)+(S3-5),(I-38)+(h-1),(I-38)+(h-2),(I-38)+(V-1),(I-38)+(V-2),(I-38)+(V-3),(I-38)+(V-4),(I-38)+(V-5),(I-38)+(V-6).
(I-39)+(II-0),(I-39)+(II-1),(I-39)+(II-2),(I-39)+(II-3),(I-39)+(II-4),(I-39)+(II-5),(I-39)+(II-6),(I-39)+(II-9),(I-39)+(II-12),(I-39)+(III-1),(I-39)+(III-4),(I-39)+(III-10),(I-39)+(III-11),(I-39)+(IV-1),(I-39)+(IV-2),(I-39)+(IV-3),(I-39)+(IV-4),(I-39)+(IV-5),(I-39)+(b-1),(I-39)+(b-2),(I-39)+(b-3),(I-39)+(b-4),(I-39)+(b-5),(I-39)+(b-6),(I-39)+(b-7),(I-39)+(b-8),(I-39)+(b-9),(I-39)+(b-10),(I-39)+(b-11),(I-39)+(b-12),(I-39)+(b-13),(I-39)+(b-14),(I-39)+(S3-1),(I-39)+(S3-2),(I-39)+(S3-3),(I-39)+(S3-4),(I-39)+(S3-5),(I-39)+(h-1),(I-39)+(h-2),(I-39)+(V-1),(I-39)+(V-2),(I-39)+(V-3),(I-39)+(V-4),(I-39)+(V-5),(I-39)+(V-6).
(I-40)+(II-0),(I-40)+(II-1),(I-40)+(II-2),(I-40)+(II-3),(I-40)+(II-4),(I-40)+(II-5),(I-40)+(II-6),(I-40)+(II-9),(I-40)+(II-12),(I-40)+(III-1),(I-40)+(III-4),(I-40)+(III-10),(I-40)+(III-11),(I-40)+(IV-1),(I-40)+(IV-2),(I-40)+(IV-3),(I-40)+(IV-4),(I-40)+(IV-5),(I-40)+(b-1),(I-40)+(b-2),(I-40)+(b-3),(I-40)+(b-4),(I-40)+(b-5),(I-40)+(b-6),(I-40)+(b-7),(I-40)+(b-8),(I-40)+(b-9),(I-40)+(b-10),(I-40)+(b-11),(I-40)+(b-12),(I-40)+(b-13),(I-40)+(b-14),(I-40)+(S3-1),(I-40)+(S3-2),(I-40)+(S3-3),(I-40)+(S3-4),(I-40)+(S3-5),(I-40)+(h-1),(I-40)+(h-2),(I-40)+(V-1),(I-40)+(V-2),(I-40)+(V-3),(I-40)+(V-4),(I-40)+(V-5),(I-40)+(V-6).
(I-41)+(II-0),(I-41)+(II-1),(I-41)+(II-2),(I-41)+(II-3),(I-41)+(II-4),(I-41)+(II-5),(I-41)+(II-6),(I-41)+(II-9),(I-41)+(II-12),(I-41)+(III-1),(I-1)+(III-4),(I-41)+(III-10),(I-41)+(III-11),(I-41)+(IV-1),(I-41)+(IV-2),(I-41)+(IV-3),(I-41)+(IV-4),(I-41)+(IV-5),(I-41)+(b-1),(I-41)+(b-2),(I-41)+(b-3),(I-41)+(b-4),(I-41)+(b-5),(I-41)+(b-6),(I-41)+(b-7),(I-41)+(b-8),(I-41)+(b-9),(I-41)+(b-10),(I-41)+(b-11),(I-41)+(b-12),(I-41)+(b-13),(I-41)+(b-14),(I-41)+(S3-1),(I-41)+(S3-2),(I-41)+(S3-3),(I-41)+(S3-4),(I-41)+(S3-5),(I-41)+(h-1),(I-41)+(h-2),(I-41)+(V-1),(I-41)+(V-2),(I-41)+(V-3),(I-41)+(V-4),(I-41)+(V--5),(I-41)+(V-6).
(I-42)+(II-0),(I-42)+(II-1),(I-42)+(II-2),(I-42)+(II-3),(I-42)+(II-4),(I-42)+(II-5),(I-42)+(II-6),(I-42)+(II-9),(I-42)+(II-12),(I-42)+(III-1),(I-42)+(III-4),(I-42)+(III-10),(I-42)+(III-11),(I-42)+(IV-1),(I-42)+(IV-2),(I-42)+(IV-3),(I-42)+(IV-4),(I-42)+(IV-5),(I-42)+(b-1),(I-42)+(b-2),(I-42)+(b-3),(I-42)+(b-4),(I-42)+(b-5),(I-42)+(b-6),(I-42)+(b-7),(I-42)+(b-8),(I-42)+(b-9),(I-42)+(b-10),(I-42)+(b-11),(I-42)+(b-12),(I-42)+(b-13),(I-42)+(b-14),(I-42)+(S3-1),(I-42)+(S3-2),(I-42)+(S3-3),(I-42)+(S3-4),(I-42)+(S3-5),(I-42)+(h-1),(I-42)+(h-2),(I-42)+(V-1),(I-42)+(V-2),(I-42)+(V-3),(I-42)+(V-4),(I-42)+(V-5),(I-42)+(V-6).
(I-43)+(II-0),(I-43)+(II-1),(I-43)+(II-2),(I-43)+(II-3),(I-43)+(II-4),(I-43)+(II-5),(I-43)+(II-6),(I-43)+(II-9),(I-43)+(II-12),(I-43)+(III-1),(I-43)+(III-4),(I-43)+(III-10),(I-43)+(III-11),(I-43)+(IV-1),(I-43)+(IV-2),(I-43)+(IV-3),(I-43)+(IV-4),(I-43)+(IV-5),(I-43)+(b-1),(I-43)+(b-2),(I-43)+(b-3),(I-43)+(b-4),(I-43)+(b-5),(I-43)+(b-6),(I-43)+(b-7),(I-43)+(b-8),(I-43)+(b-9),(I-43)+(b-10),(I-43)+(b-11),(I-43)+(b-12),(I-43)+(b-13),(I-43)+(b-14),(I-43)+(S3-1),(I-43)+(S3-2),(I-43)+(S3-3),(I-43)+(S3-4),(I-43)+(S3-5),(I-43)+(h-1),(I-43)+(h-2),(I-43)+(V-1),(I-43)+(V-2),(I-43)+(V-3),(I-43)+(V-4),(I-43)+(V-5),(I-43)+(V-6).
(I-44)+(II-0),(I-44)+(II-1),(I-44)+(II-2),(I-44)+(II-3),(I-44)+(II-4),(I-44)+(II-5),(I-44)+(II-6),(I-44)+(II-9),(I-44)+(II-12),(I-44)+(III-1),(I-44)+(III-4),(I-44)+(III-10),(I-44)+(III-11),(I-44)+(IV-1),(I-44)+(IV-2),(I-44)+(IV-3),(I-44)+(IV-4),(I-44)+(IV-5),(I-44)+(b-1),(I-44)+(b-2),(I-44)+(b-3),(I-44)+(b-4),(I-44)+(b-5),(I-44)+(b-6),(I-44)+(b-7),(I-44)+(b-8),(I-44)+(b-9),(I-44)+(b-10),(I-44)+(b-11),(I-44)+(b-12),(I-44)+(b-13),(I-44)+(b-14),(I-44)+(S3-1),(I-44)+(S3-2),(I-44)+(S3-3),(I-44)+(S3-4),(I-44)+(S3-5),(I-44)+(h-1),(I-44)+(h-2),(I-44)+(V-1),(I-44)+(V-2),(I-44)+(V-3),(I-44)+(V-4),(I-44)+(V-5),(I-44)+(V-6).
(I-45)+(II-0),(I-45)+(II-1),(I-45)+(II-2),(I-45)+(II-3),(I-45)+(II-4),(I-45)+(II-5),(I-45)+(II-6),(I-45)+(II-9),(I-45)+(II-12),(I-45)+(III-1),(I-45)+(III-4),(I-45)+(III-10),(I-45)+(III-11),(I-45)+(IV-1),(I-45)+(IV-2),(I-45)+(IV-3),(I-45)+(IV-4),(I-45)+(IV-5),(I-45)+(b-1),(I-45)+(b-2),(I-45)+(b-3),(I-45)+(b-4),(I-45)+(b-5),(I-45)+(b-6),(I-45)+(b-7),(I-45)+(b-8),(I-45)+(b-9),(I-45)+(b-10),(I-45)+(b-11),(I-45)+(b-12),(I-45)+(b-13),(I-45)+(b-14),(I-45)+(S3-1),(I-45)+(S3-2),(I-45)+(S3-3),(I-45)+(S3-4),(I-45)+(S3-5),(I-45)+(h-1),(I-45)+(h-2),(I-45)+(V-1),(I-45)+(V-2),(I-45)+(V-3),(I-45)+(V-4),(I-45)+(V-5),(I-45)+(V-6).
(I-46)+(II-0),(I-46)+(II-1),(I-46)+(II-2),(I-46)+(II-3),(I-46)+(II-4),(I-46)+(II-5),(I-46)+(II-6),(I-46)+(II-9),(I-46)+(II-1?2),(I-46)+(III-1),(I-46)+(III-4),(I-46)+(III-10),(I-46)+(III-11),(I-46)+(IV-1),(I-46)+(IV-2),(I-46)+(IV-3),(I-46)+(IV-4),(I-46)+(IV-5),(I-46)+(b-1),(I-46)+(b-2),(I-46)+(b-3),(I-46)+(b-4),(I-46)+(b-5),(I-46)+(b-6),(I-46)+(b-7),(I-46)+(b-8),(I-46)+(b-9),(I-46)+(b-10),(I-46)+(b-11),(I-46)+(b-12),(I-46)+(b-13),(I-46)+(b-14),(I-46)+(S3-1),(I-46)+(S3-2),(I-46)+(S3-3),(I-46)+(S3-4),(I-46)+(S3-5),(I-46)+(h-1),(I-46)+(h-2),(I-46)+(V-1),(I-46)+(V-2),(I-46)+(V-3),(I-46)+(V-4),(I-46)+(V-5),(I-46)+(V-6).
(I-47)+(II-0),(I-47)+(II-1),(I-47)+(II-2),(I-47)+(II-3),(I-47)+(II-4),(I-47)+(II-5),(I-47)+(II-6),(I-47)+(II-9),(I-47)+(II-12),(I-47)+(III-1),(I-47)+(III-4),(I-47)+(III-10),(I-47)+(III-11),(I-47)+(IV-1),(I-47)+(IV-2),(I-47)+(IV-3),(I-47)+(IV-4),(I-47)+(IV-5),(I-47)+(b-1),(I-47)+(b-2),(I-47)+(b-3),(I-47)+(b-4),(I-47)+(b-5),(I-47)+(b-6),(I-47)+(b-7),(I-47)+(b-8),(I-47)+(b-9),(I-47)+(b-10),(I-47)+(b-11),(I-47)+(b-12),(I-47)+(b-1?3),(I-47)+(b-14),(I-47)+(S3-1),(I-47)+(S3-2),(I-47)+(S3-3),(I-47)+(S3-4),(I-47)+(S3-5),(I-47)+(h-1),(I-47)+(h-2),(I-47)+(V-1),(I-47)+(V-2),(I-47)+(V-3),(I-47)+(V-4),(I-47)+(V-5),(I-47)+(V-6).
(I-48)+(II-0),(I-48)+(II-1),(I-48)+(II-2),(I-48)+(II-3),(I-48)+(II-4),(I-48)+(II-5),(I-48)+(II-6),(I-48)+(II-9),(I-48)+(II-12),(I-48)+(III-1),(I-48)+(III-4),(I-48)+(III-10),(I-48)+(III-11),(I-48)+(IV-1),(I-48)+(IV-2),(I-48)+(IV-3),(I-48)+(IV-4),(I-48)+(IV-5),(I-48)+(b-1),(I-48)+(b-2),(I-48)+(b-3),(I-48)+(b-4),(I-48)+(b-5),(I-48)+(b-6),(I-48)+(b-7),(I-48)+(b-8),(I-48)+(b-9),(I-48)+(b-10),(I-48)+(b-11),(I-48)+(b-12),(I-48)+(b-13),(I-48)+(b-14),(I-48)+(S3-1),(I-48)+(S3-2),(I-48)+(S3-3),(I-48)+(S3-4),(I-48)+(S3-5),(I-48)+(h-1),(I-48)+(h-2),(I-48)+(V-1),(I-48)+(V-2),(I-48)+(V-3),(I-48)+(V-4),(I-48)+(V-5),(I-48)+(V-6).
(I-49)+(II-0),(I-49)+(II-1),(I-49)+(II-2),(I-49)+(II-3),(I-49)+(II-4),(I-49)+(II-5),(I-49)+(II-6),(I-49)+(II-9),(I-49)+(II-12),(I-49)+(III-1),(I-49)+(III-4),(I-49)+(III-10),(I-49)+(III-11),(I-49)+(IV-1),(I-49)+(IV-2),(I-49)+(IV-3),(I-49)+(IV-4),(I-49)+(IV-5),(I-49)+(b-1),(I-49)+(b-2),(I-49)+(b-3),(I-49)+(b-4),(I-49)+(b-5),(I-49)+(b-6),(I-49)+(b-7),(I-49)+(b-8),(I-49)+(b-9),(I-49)+(b-10),(I-49)+(b-11),(I-49)+(b-12),(I-49)+(b-13),(I-49)+(b-14),(I-49)+(S3-1),(I-49)+(S3-2),(I-49)+(S3-3),(I-49)+(S3-4),(I-49)+(S3-5),(I-49)+(h-1),(I-49)+(h-2),(I-49)+(V-1),(I-49)+(V-2),(I-49)+(V-3),(I-49)+(V-4),(I-49)+(V-5),(I-49)+(V-6).
(I-50)+(II-0),(I-50)+(II-1),(I-50)+(II-2),(I-50)+(II-3),(I-50)+(II-4),(I-50)+(II-5),(I-50)+(II-6),(I-50)+(II-9),(I-50)+(II-12),(I-50)+(III-1),(I-50)+(III-4),(I-50)+(III-10),(I-50)+(III-11),(I-50)+(IV-1),(I-50)+(IV-2),(I-50)+(IV-3),(I-50)+(IV-4),(I-50)+(IV-5),(I-50)+(b-1),(I-50)+(b-2),(I-50)+(b-3),(I-50)+(b-4),(I-50)+(b-5),(I-50)+(b-6),(I-50)+(b-7),(I-50)+(b-8),(I-50)+(b-9),(I-50)+(b-10),(I-50)+(b-11),(I-50)+(b-12),(I-50)+(b-13),(I-50)+(b-14),(I-50)+(S3-1),(I-50)+(S3-2),(I-50)+(S3-3),(I-50)+(S3-4),(I-50)+(S3-5),(I-50)+(h-1),(I-50)+(h-2),(I-50)+(V-1),(I-50)+(V-2),(I-50)+(V-3),(I-50)+(V-4),(I-50)+(V-5),(I-50)+(V-6).
(I-51)+(II-0),(I-51)+(II-1),(I-51)+(II-2),(I-51)+(II-3),(I-51)+(II-4),(I-51)+(II-5),(I-51)+(II-6),(I-51)+(II-9),(I-51)+(II-12),(I-51)+(III-1),(I-51)+(III-4),(I-51)+(III-10),(I-51)+(III-11),(I-51)+(IV-1),(I-51)+(IV-2),(I-51)+(IV-3),(I-51)+(IV-4),(I-51)+(IV-5),(I-51)+(b-1),(I-51)+(b-2),(I-51)+(b-3),(I-51)+(b-4),(I-51)+(b-5),(I-51)+(b-6),(I-51)+(b-7),(I-51)+(b-8),(I-51)+(b-9),(I-51)+(b-10),(I-51)+(b-11),(I-51)+(b-12),(I-51)+(b-13),(I-51)+(b-14),(I-51)+(S3-1),(I-51)+(S3-2),(I-51)+(S3-3),(I-51)+(S3-4),(I-51)+(S3-5),(I-51)+(h-1),(I-51)+(h-2),(I-51)+(V-1),(I-51)+(V-2),(I-51)+(V-3),(I-51)+(V-4),(I-51)+(V-5),(I-51)+(V-6).
(I-52)+(II-0),(I-52)+(II-1),(I-52)+(II-2),(I-52)+(II-3),(I-52)+(II-4),(I-52)+(II-5),(I-52)+(II-6),(I-52)+(II-9),(I-52)+(II-12),(I-52)+(III-1),(I-52)+(III-4),(I-52)+(III-10),(I-52)+(III-11),(I-52)+(IV-1),(I-52)+(IV-2),(I-52)+(IV-3),(I-52)+(IV-4),(I-52)+(IV-5),(I-52)+(b-1),(I-52)+(b-2),(I-52)+(b-3),(I-52)+(b-4),(I-52)+(b-5),(I-52)+(b-6),(I-52)+(b-7),(I-52)+(b-8),(I-52)+(b-9),(I-52)+(b-10),(I-52)+(b-11),(I-52)+(b-12),(I-52)+(b-13),(I-52)+(b-14),(I-52)+(S3-1),(I-52)+(S3-2),(I-52)+(S3-3),(I-52)+(S3-4),(I-52)+(S3-5),(I-52)+(h-1),(I-52)+(h-2),(I-52)+(V-1),(I-52)+(V-2),(I-52)+(V-3),(I-52)+(V-4),(I-52)+(V-5),(I-52)+(V-6).
(I-53)+(II-0),(I-53)+(II-1),(I-53)+(II-2),(I-53)+(II-3),(I-53)+(II-4),(I-53)+(II-5),(I-53)+(II-6),(I-53)+(II-9),(I-53)+(II-12),(I-53)+(III-1),(I-53)+(III-4),(I-53)+(III-10),(I-53)+(III-11),(I-53)+(IV-1),(I-53)+(IV-2),(I-53)+(IV-3),(I-53)+(IV-4),(I-53)+(IV-5),(I-53)+(b-1),(I-53)+(b-2),(I-53)+(b-3),(I-53)+(b-4),(I-53)+(b-5),(I-53)+(b-6),(I-53)+(b-7),(I-53)+(b-8),(I-53)+(b-9),(I-53)+(b-10),(I-53)+(b-11),(I-53)+(b-12),(I-53)+(b-13),(I-53)+(b-14),(I-53)+(S3-1),(I-53)+(S3-2),(I-53)+(S3-3),(I-53)+(S3-4),(I-53)+(S3-5),(I-53)+(h-1),(I-53)+(h-2),(I-53)+(V-1),(I-53)+(V-2),(I-53)+(V-3),(I-53)+(V-4),(I-53)+(V-5),(I-53)+(V-6).
(I-54)+(II-0),(I-54)+(II-1),(I-54)+(II-2),(I-54)+(II-3),(I-54)+(II-4),(I-54)+(II-5),(I-54)+(II-6),(I-54)+(II-9),(I-54)+(II-12),(I-54)+(III-1),(I-54)+(III-4),(I-54)+(III-10),(I-54)+(III-11),(I-54)+(IV-1),(I-54)+(IV-2),(I-54)+(IV-3),(I-54)+(IV-4),(I-54)+(IV-5),(I-54)+(b-1),(I-54)+(b-2),(I-54)+(b-3),(I-54)+(b-4),(I-54)+(b-5),(I-54)+(b-6),(I-54)+(b-7),(I-54)+(b-8),(I-54)+(b-9),(I-54)+(b-10),(I-54)+(b-11),(I-54)+(b-12),(I-54)+(b-13),(I-54)+(b-14),(I-54)+(S3-1),(I-54)+(S3-2),(I-54)+(S3-3),(I-54)+(S3-4),(I-54)+(S3-5),(I-54)+(h-1),(I-54)+(h-2),(I-54)+(V-1),(I-54)+(V-2),(I-54)+(V-3),(I-54)+(V-4),(I-54)+(V-5),(I-54)+(V-6).
(I-55)+(II-0),(I-55)+(II-1),(I-55)+(II-2),(I-55)+(II-3),(I-55)+(II-4),(I-55)+(II-5),(I-55)+(II-6),(I-55)+(II-9),(I-55)+(II-12),(I-55)+(III-1),(I-55)+(III-4),(I-55)+(III-10),(I-55)+(III-11),(I-55)+(IV-1),(I-55)+(IV-2),(I-55)+(IV-3),(I-55)+(IV-4),(I-55)+(IV-5),(I-55)+(b-1),(I-55)+(b-2),(I-55)+(b-3),(I-55)+(b-4),(I-55)+(b-5),(I-55)+(b-6),(I-55)+(b-7),(I-55)+(b-8),(I-55)+(b-9),(I-55)+(b-10),(I-55)+(b-11),(I-55)+(b-12),(I-55)+(b-13),(I-55)+(b-14),(I-55)+(S3-1),(I-55)+(S3-2),(I-55)+(S3-3),(I-55)+(S3-4),(I-55)+(S3-5),(I-55)+(h-1),(I-55)+(h-2),(I-55)+(V-1),(I-55)+(V-2),(I-55)+(V-3),(I-55)+(V-4),(I-55)+(V-5),(I-55)+(V-6).
(I-56)+(II-0),(I-56)+(II-1),(I-56)+(II-2),(I-56)+(II-3),(I-56)+(II-4),(I-56)+(II-5),(I-56)+(II-6),(I-56)+(II-9),(I-56)+(II-12),(I-56)+(III-1),(I-56)+(III-4),(I-56)+(III-10),(I-56)+(III-11),(I-56)+(IV-1),(I-56)+(IV-2),(I-56)+(IV-3),(I-56)+(IV-4),(I-56)+(IV-5),(I-56)+(b-1),(I-56)+(b-2),(I-56)+(b-3),(I-56)+(b-4),(I-56)+(b-5),(I-56)+(b-6),(I-56)+(b-7),(I-56)+(b-8),(I-56)+(b-9),(I-56)+(b-10),(I-56)+(b-11),(I-56)+(b-12),(I-56)+(b-13),(I-56)+(b-14),(I-56)+(S3-1),(I-56)+(S3-2),(I-56)+(S3-3),(I-56)+(S3-4),(I-56)+(S3-5),(I-56)+(h-1),(I-56)+(h-2),(I-56)+(V-1),(I-56)+(V-2),(I-56)+(V-3),(I-56)+(V-4),(I-56)+(V-5),(I-56)+(V-6).
(I-57)+(II-0),(I-57)+(II-1),(I-57)+(II-2),(I-57)+(II-3),(I-57)+(II-4),(I-57)+(II-5),(I-57)+(II-6),(I-57)+(II-9),(I-57)+(II-12),(I-57)+(III-1),(I-57)+(III-4),(I-57)+(III-10),(I-57)+(III-11),(I-57)+(IV-1),(I-57)+(IV-2),(I-57)+(IV-3),(I-57)+(IV-4),(I-57)+(IV-5),(I-57)+(b-1),(I-57)+(b-2),(I-57)+(b-3),(I-57)+(b-4),(I-57)+(b-5),(I-57)+(b-6),(I-57)+(b-7),(I-57)+(b-8),(I-57)+(b-9),(I-57)+(b-10),(I-57)+(b-11),(I-57)+(b-12),(I-57)+(b-13),(I-57)+(b-14),(I-57)+(S3-1),(I-57)+(S3-2),(I-57)+(S3-3),(I-57)+(S3-4),(I-57)+(S3-5),(I-57)+(h-1),(I-57)+(h-2),(I-57)+(V-1),(I-57)+(V-2),(I-57)+(V-3),(I-57)+(V-4),(I-57)+(V-5),(I-57)+(V-6).
(I-58)+(II-0),(I-58)+(II-1),(I-58)+(II-2),(I-58)+(II-3),(I-58)+(II-4),(I-58)+(II-5),(I-58)+(II-6),(I-58)+(II-9),(I-58)+(II-12),(I-58)+(III-1),(I-58)+(III-4),(I-58)+(III-10),(I-58)+(III-11),(I-58)+(IV-1),(I-58)+(IV-2),(I-58)+(IV-3),(I-58)+(IV-4),(I-58)+(IV-5),(I-58)+(b-1),(I-58)+(b-2),(I-58)+(b-3),(I-58)+(b-4),(I-58)+(b-5),(I-58)+(b-6),(I-58)+(b-7),(I-58)+(b-8),(I-58)+(b-9),(I-58)+(b-10),(I-58)+(b-11),(I-58)+(b-12),(I-58)+(b-13),(I-58)+(b-14),(I-58)+(S3-1),(I-58)+(S3-2),(I-58)+(S3-3),(I-58)+(S3-4),(I-58)+(S3-5),(I-58)+(h-1),(I-58)+(h-2),(I-58)+(V-1),(I-58)+(V-2),(I-58)+(V-3),(I-58)+(V-4),(I-58)+(V-5),(I-58)+(V-6).
(I-59)+(II-0),(I-59)+(II-1),(I-59)+(II-2),(I-59)+(II-3),(I-59)+(II-4),(I-59)+(II-5),(I-59)+(II-6),(I-59)+(II-9),(I-59)+(II-12),(I-59)+(III-1),(I-59)+(III-4),(I-59)+(III-10),(I-59)+(III-11),(I-59)+(IV-1),(I-59)+(IV-2),(I-59)+(IV-3),(I-59)+(IV-4),(I-59)+(IV-5),(I-59)+(b-1),(I-59)+(b-2),(I-59)+(b-3),(I-59)+(b-4),(I-59)+(b-5),(I-59)+(b-6),(I-59)+(b-7),(I-59)+(b-8),(I-59)+(b-9),(I-59)+(b-10),(I-59)+(b-11),(I-59)+(b-12),(I-59)+(b-13),(I-59)+(b-14),(I-59)+(S3-1),(I-59)+(S3-2),(I-59)+(S3-3),(I-59)+(S3-4),(I-59)+(S3-5),(I-59)+(h-1),(I-59)+(h-2),(I-59)+(V-1),(I-59)+(V-2),(I-59)+(V-3),(I-59)+(V-4),(I-59)+(V-5),(I-59)+(V-6).
(I-60)+(II-6),(I-60)+(II-1),(I-60)+(II-2),(I-60)+(II-3),(I-60)+(II-4),(I-60)+(II-5),(I-60)+(II-6),(I-60)+(II-9),(I-60)+(II-12),(I-60)+(III-1),(I-60)+(III-4),(I-60)+(III-10),(I-60)+(III-11),(I-60)+(IV-1),(I-60)+(IV-2),(I-60)+(IV-3),(I-60)+(IV-4),(I-60)+(IV-5),(I-60)+(b-1),(I-60)+(b-2),(I-60)+(b-3),(I-60)+(b-4),(I-60)+(b-5),(I-60)+(b-6),(I-60)+(b-7),(I-60)+(b-8),(I-60)+(b-9),(I-60)+(b-10),(I-60)+(b-11),(I-60)+(b-12),(I-60)+(b-13),(I-60)+(b-14),(I-60)+(S3-1),(I-60)+(S3-2),(I-60)+(S3-3),(I-60)+(S3-4),(I-60)+(S3-5),(I-60)+(h-1),(I-60)+(h-2),(I-60)+(V-1),(I-60)+(V-2),(I-60)+(V-3),(I-60)+(V-4),(I-60)+(V-5),(I-60)+(V-6).
(I-61)+(II-0),(I-61)+(II-1),(I-61)+(II-2),(I-61)+(II-3),(I-61)+(II-4),(I-61)+(II-5),(I-61)+(II-6),(I-61)+(II-9),(I-61)+(II-12),(I-61)+(III-1),(I-61)+(III-4),(I-61)+(III-10),(I-61)+(III-11),(I-61)+(IV-1),(I-61)+(IV-2),(I-61)+(IV-3),(I-61)+(IV-4),(I-61)+(IV-5),(I-61)+(b-1),(I-61)+(b-2),(I-61)+(b-3),(I-61)+(b-4),(I-61)+(b-5),(I-61)+(b-6),(I-61)+(b-7),(I-61)+(b-8),(I-61)+(b-9),(I-61)+(b-10),(I-61)+(b-11),(I-61)+(b-12),(I-61)+(b-13),(I-61)+(b-14),(I-61)+(S3-1),(I-61)+(S3-2),(I-61)+(S3-3),(I-61)+(S3-4),(I-61)+(S3-5),(I-61)+(h-1),(I-61)+(h-2),(I-61)+(V-1),(I-61)+(V-2),(I-61)+(V-3),(I-61)+(V-4),(I-61)+(V-5),(I-61)+(V-6).
(I-62)+(II-0),(I-62)+(II-1),(I-62)+(II-2),(I-62)+(II-3),(I-62)+(II-4),(I-62)+(II-5),(I-62)+(II-6),(I-62)+(II-9),(I-62)+(II-12),(I-62)+(III-1),(I-62)+(III-4),(I-62)+(III-10),(I-62)+(III-11),(I-62)+(IV-1),(I-62)+(IV-2),(I-62)+(IV-3),(I-62)+(IV-4),(I-62)+(IV-5),(I-62)+(b-1),(I-62)+(b-2),(I-62)+(b-3),(I-62)+(b-4),(I-62)+(b-5),(I-62)+(b-6),(I-62)+(b-7),(I-62)+(b-8),(I-62)+(b-9),(I-62)+(b-10),(I-62)+(b-11),(I-62)+(b-12),(I-62)+(b-13),(I-62)+(b-14),(I-62)+(S3-1),(I-62)+(S3-2),(I-62)+(S3-3),(I-62)+(S3-4),(I-62)+(S3-5),(I-62)+(h-1),(I-62)+(h-2),(I-62)+(V-1),(I-62)+(V-2),(I-62)+(V-3),(I-62)+(V-4),(I-62)+(V-5),(I-62)+(V-6).
(I-63)+(II-0),(I-63)+(II-1),(I-63)+(II-2),(I-63)+(II-3),(I-63)+(II-4),(I-63)+(II-5),(I-63)+(II-6),(I-63)+(II-9),(I-63)+(II-12),(I-63)+(III-1),(I-63)+(III-4),(I-63)+(III-10),(I-63)+(III-11),(I-63)+(IV-1),(I-63)+(IV-2),(I-63)+(IV-3),(I-63)+(IV-4),(I-63)+(IV-5),(I-63)+(b-1),(I-63)+(b-2),(I-63)+(b-3),(I-63)+(b-4),(I-63)+(b-5),(I-63)+(b-6),(I-63)+(b-7),(I-63)+(b-8),(I-63)+(b-9),(I-63)+(b-10),(I-63)+(b-11),(I-63)+(b-12),(I-63)+(b-13),(I-63)+(b-14),(I-63)+(S3-1),(I-63)+(S3-2),(I-63)+(S3-3),(I-63)+(S3-4),(I-63)+(S3-5),(I-63)+(h-1),(I-63)+(h-2),(I-63)+(V-1),(I-63)+(V-2),(I-63)+(V-3),(I-63)+(V-4),(I-63)+(V-5),(I-63)+(V-6).
(I-64)+(II-0),(I-64)+(II-1),(I-64)+(II-2),(I-64)+(II-3),(I-64)+(II-4),(I-64)+(II-5),(I-64)+(II-6),(I-64)+(II-9),(I-64)+(II-12),(I-64)+(III-1),(I-64)+(III-4),(I-64)+(III-10),(I-64)+(III-11),(I-64)+(IV-1),(I-46)+(IV-2),(I-64)+(IV-3),(I-64)+(IV-4),(I-64)+(IV-5),(I-64)+(b-1),(I-64)+(b-2),(I-64)+(b-3),(I-64)+(b-4),(I-64)+(b-5),(I-64)+(b-6),(I-64)+(b-7),(I-64)+(b-8),(I-64)+(b-9),(I-64)+(b-10),(I-64)+(b-11),(I-64)+(b-12),(I-64)+(b-13),(I-64)+(b-14),(I-64)+(S3-1),(I-64)+(S3-2),(I-64)+(S3-3),(I-64)+(S3-4),(I-64)+(S3-5),(I-64)+(h-1),(I-64)+(h-2),(I-64)+(V-1),(I-64)+(V-2),(I-64)+(V-3),(I-64)+(V-4),(I-64)+(V-5),(I-64)+(V-6).
(I-65)+(II-0),(I-65)+(II-1),(I-65)+(II-2),(I-65)+(II-3),(I-65)+(II-4),(I-65)+(II-5),(I-65)+(II-6),(I-65)+(II-9),(I-65)+(II-12),(I-65)+(III-1),(I-65)+(III-4),(I-65)+(III-10),(I-65)+(III-11),(1-65)+(IV-1),(I-65)+(IV-2),(I-65)+(IV-3),(I-65)+(IV-4),(I-65)+(IV-5),(I-65)+(b-1),(I-65)+(b-2),(I-65)+(b-3),(I-65)+(b-4),(I-65)+(b-5),(I-65)+(b-6),(I-65)+(b-7),(I-65)+(b-8),(I-65)+(b-9),(I-65)+(b-10),(I-65)+(b-11),(I-65)+(b-12),(I-65)+(b-13),(I-65)+(b-14),(I-65)+(S3-1),(I-65)+(S3-2),(I-65)+(S3-3),(I-65)+(S3-4),(I-65)+(S3-5),(I-65)+(h-1),(I-65)+(h-2),(I-65)+(V-1),(I-65)+(V-2),(I-65)+(V-3),(I-65)+(V-4),(I-65)+(V-5),(I-65)+(V-6).
(I-66)+(II-0),(I-66)+(II-1),(I-66)+(II-2),(I-66)+(II-3),(I-66)+(II-4),(I-66)+(II-5),(I-66)+(II-6),(I-66)+(II-9),(I-66)+(II-12),(I-66)+(III-1),(I-66)+(III-4),(I-66)+(III-10),(I-66)+(III-11),(I-66)+(IV-1),(I-66)+(IV-2),(I-66)+(IV-3),(I-66)+(IV-4),(I-66)+(IV-5),(I-66)+(b-1),(I-66)+(b-2),(I-66)+(b-3),(I-66)+(b-4),(I-66)+(b-5),(I-66)+(b-6),(I-66)+(b-7),(I-66)+(b-8),(I-66)+(b-9),(I-66)+(b-10),(I-66)+(b-11),(I-66)+(b-12),(I-66)+(b-13),(I-66)+(b-14),(I-66)+(S3-1),(I-66)+(S3-2),(I-66)+(S3-3),(I-66)+(S3-4),(I-66)+(S3-5),(I-66)+(h-1),(I-66)+(h-2),(I-66)+(V-1),(I-66)+(V-2),(I-66)+(V-3),(I-66)+(V-4),(I-66)+(V-5),(I-66)+(V-6).
(I-67)+(II-0),(I-67)+(II-1),(I-67)+(II-2),(I-67)+(II-3),(I-67)+(II-4),(I-67)+(II-5),(I-67)+(II-6),(I-67)+(II-9),(I-67)+(II-12),(I-67)+(III-1),(I-67)+(III-4),(I-67)+(III-10),(I-67)+(III-11),(I-67)+(IV-1),(I-67)+(IV-2),(I-67)+(IV-3),(I-67)+(IV-4),(I-67)+(IV-5),(I-67)+(b-1),(I-67)+(b-2),(I-67)+(b-3),(I-67)+(b-4),(I-67)+(b-5),(I-67)+(b-6),(I-67)+(b-7),(I-67)+(b-8),(I-67)+(b-9),(I-67)+(b-10),(I-67)+(b-11),(I-67)+(b-12),(I-67)+(b-13),(I-67)+(b-14),(I-67)+(S3-1),(I-67)+(S3-2),(I-67)+(S3-3),(I-67)+(S3-4),(I-67)+(S3-5),(I-67)+(h-1),(I-67)+(h-2),(I-67)+(V-1),(I-67)+(V-2),(I-67)+(V-3),(I-67)+(V-4),(I-67)+(V-5),(I-67)+(V-6).
(I-68)+(II-0),(I-68)+(II-1),(I-68)+(II-2),(I-68)+(II-3),(I-68)+(II-4),(I-68)+(II-5),(I-68)+(II-6),(I-68)+(II-9),(I-68)+(II-12),(I-68)+(III-1),(I-68)+(III-4),(I-68)+(III-10),(I-68)+(III-11),(I-68)+(IV-1),(I-68)+(IV-2),(I-68)+(IV-3),(I-68)+(IV-4),(I-68)+(IV-5),(I-68)+(b-1),(I-68)+(b-2),(I-68)+(b-3),(I-68)+(b-4),(I-68)+(b-5),(I-68)+(b-6),(I-68)+(b-7),(I-68)+(b-8),(I-68)+(b-9),(I-68)+(b-10),(I-68)+(b-11),(I-68)+(b-12),(I-68)+(b-13),(I-68)+(b-14),(I-68)+(S3-1),(I-68)+(S3-2),(I-68)+(S3-3),(I-68)+(S3-4),(I-68)+(S3-5),(I-68)+(h-1),(I-68)+(h-2),(I-68)+(V-1),(I-68)+(V-2),(I-68)+(V-3),(I-68)+(V-4),(I-68)+(V-5),(I-68)+(V-6).
(I-69)+(II-0),(I-69)+(II-1),(I-69)+(II-2),(I-69)+(II-3),(I-69)+(II-4),(I-69)+(II-5),(I-69)+(II-6),(I-69)+(II-9),(I-69)+(II-12),(I-69)+(III-1),(I-69)+(III-4),(I-69)+(III-10),(I-69)+(III-11),(I-69)+(IV-1),(I-69)+(IV-2),(I-69)+(IV-3),(I-69)+(IV-4),(I-69)+(IV-5),(I-69)+(b-1),(I-69)+(b-2),(I-69)+(b-3),(I-69)+(b-4),(I-69)+(b-5),(I-69)+(b-6),(I-69)+(b-7),(I-69)+(b-8),(I-69)+(b-9),(I-69)+(b-10),(I-69)+(b-11),(I-69)+(b-12),(I-69)+(b-13),(I-69)+(b-14),(I-69)+(S3-1),(I-69)+(S3-2),(I-69)+(S3-3),(I-69)+(S3-4),(I-69)+(S3-5),(I-69)+(h-1),(I-69)+(h-2),(I-69)+(V-1),(I-69)+(V-2),(I-69)+(V-3),(I-69)+(V-4),(I-69)+(V-5),(I-69)+(V-6).
(I-70)+(II-0),(I-70)+(II-1),(I-70)+(II-2),(I-70)+(II-3),(I-70)+(II-4),(I-70)+(II-5),(I-70)+(II-6),(I-70)+(II-9),(I-70)+(II-12),(I-70)+(III-1),(I-70)+(III-4),(I-70)+(III-10),(I-70)+(III-11),(I-70)+(IV-1),(I-70)+(IV-2),(I-70)+(IV-3),(I-70)+(IV-4),(I-70)+(IV-5),(I-70)+(b-1),(I-70)+(b-2),(I-70)+(b-3),(I-70)+(b-4),(I-70)+(b-5),(I-70)+(b-6),(I-70)+(b-7),(I-70)+(b-8),(I-70)+(b-9),(I-70)+(b-10),(I-70)+(b-11),(I-70)+(b-12),(I-70)+(b-13),(I-70)+(b-14),(I-70)+(S3-1),(I-70)+(S3-2),(I-70)+(S3-3),(I-70)+(S3-4),(I-70)+(S3-5),(I-70)+(h-1),(I-70)+(h-2),(I-70)+(V-1),(I-70)+(V-2),(I-70)+(V-3),(I-70)+(V-4),(I-70)+(V-5),(I-70)+(V-6).
(I-71)+(II-0),(I-71)+(II-1),(I-71)+(II-2),(I-71)+(II-3),(I-71)+(II-4),(I-71)+(II-5),(I-71)+(II-6),(I-71)+(II-9),(I-71)+(II-12),(I-71)+(III-1),(I-71)+(III-4),(I-71)+(III-10),(I-71)+(III-11),(I-71)+(IV-1),(I-71)+(IV-2),(I-71)+(IV-3),(I-71)+(IV-4),(I-71)+(IV-5),(I-71)+(b-1),(I-71)+(b-2),(I-71)+(b-3),(I-71)+(b-4),(I-71)+(b-5),(I-71)+(b-6),(I-71)+(b-7),(I-71)+(b-8),(I-71)+(b-9),(I-71)+(b-10),(I-71)+(b-11),(I-71)+(b-12),(I-71)+(b-13),(I-71)+(b-14),(I-71)+(S3-1),(I-71)+(S3-2),(I-71)+(S3-3),(I-71)+(S3-4),(I-71)+(S3-5),(I-71)+(h-1),(I-71)+(h-2),(I-71)+(V-1),(I-71)+(V-2),(I-71)+(V-3),(I-71)+(V-4),(I-71)+(V-5),(I-71)+(V-6).
(I-72)+(II-0),(I-72)+(II-1),(I-72)+(II-2),(I-72)+(II-3),(I-72)+(II-4),(I-72)+(II-5),(I-72)+(II-6),(I-72)+(II-9),(I-72)+(II-12),(I-72)+(III-1),(I-72)+(III-4),(I-72)+(III-10),(I-72)+(III-11),(I-72)+(IV-1),(I-72)+(IV-2),(I-72)+(IV-3),(I-72)+(IV-4),(I-72)+(IV-5),(I-72)+(b-1),(I-72)+(b-2),(I-72)+(b-3),(I-72)+(b-4),(I-72)+(b-5),(I-72)+(b-6),(I-72)+(b-7),(I-72)+(b-8),(I-72)+(b-9),(I-72)+(b-10),(I-72)+(b-11),(I-72)+(b-12),(I-72)+(b-13),(I-72)+(b-14),(I-72)+(S3-1),(I-72)+(S3-2),(I-72)+(S3-3),(I-72)+(S3-4),(I-72)+(S3-5),(I-72)+(h-1),(I-72)+(h-2),(I-72)+(V-1),(I-72)+(V-2),(I-72)+(V-3),(I-72)+(V-4),(I-72)+(V-5),(I-72)+(V-6).
(I-73)+(II-0),(I-73)+(II-1),(I-73)+(II-2),(I-73)+(II-3),(I-73)+(II-4),(I-73)+(II-5),(I-73)+(II-6),(I-73)+(II-9),(I-73)+(II-12),(I-73)+(III-1),(I-73)+(III-4),(I-73)+(III-10),(I-73)+(III-11),(I-73)+(IV-1),(I-73)+(IV-2),(I-73)+(IV-3),(I-73)+(IV-4),(I-73)+(IV-5),(I-73)+(b-1),(I-73)+(b-2),(I-73)+(b-3),(I-73)+(b-4),(I-73)+(b-5),(I-73)+(b-6),(I-73)+(b-7),(I-73)+(b-8),(I-73)+(b-9),(I-73)+(b-10),(I-73)+(b-11),(I-73)+(b-12),(I-73)+(b-13),(I-73)+(b-14),(I-73)+(S3-1),(I-73)+(S3-2),(I-73)+(S3-3),(I-73)+(S3-4),(I-73)+(S3-5),(I-73)+(h-1),(I-73)+(h-2),(I-73)+(V-1),(I-73)+(V-2),(I-73)+(V-3),(I-73)+(V-4),(I-73)+(V-5),(I-73)+(V-6).
(I-74)+(II-0),(I-74)+(II-1),(I-74)+(II-2),(I-74)+(II-3),(I-74)+(II-4),(I-74)+(II-5),(I-74)+(II-6),(I-74)+(II-9),(I-74)+(II-12),(I-74)+(III-1),(I-74)+(III-4),(I-74)+(III-10),(I-74)+(III-11),(I-74)+(IV-1),(I-74)+(IV-2),(I-74)+(IV-3),(I-74)+(IV-4),(I-74)+(IV-5),(I-74)+(b-1),(I-74)+(b-2),(I-74)+(b-3),(I-74)+(b-4),(I-74)+(b-5),(I-74)+(b-6),(I-74)+(b-7),(I-74)+(b-8),(I-74)+(b-9),(I-74)+(b-10),(I-74)+(b-11),(I-74)+(b-12),(I-74)+(b-13),(I-74)+(b-14),(I-74)+(S3-1),(I-74)+(S3-2),(I-74)+(S3-3),(I-74)+(S3-4),(I-74)+(S3-5),(I-74)+(h-1),(I-74)+(h-2),(I-74)+(V-1),(I-74)+(V-2),(I-74)+(V-3),(I-74)+(V-4),(I-74)+(V-5),(I-74)+(V-6).
(I-75)+(II-0),(I-75)+(II-1),(I-75)+(II-2),(I-75)+(II-3),(I-75)+(II-4),(I-75)+(II-5),(I-75)+(II-6),(I-75)+(II-9),(I-75)+(II-12),(I-75)+(III-1),(I-75)+(III-4),(I-75)+(III-10),(I-75)+(III-11),(I-75)+(IV-1),(I-75)+(IV-2),(I-75)+(IV-3),(I-75)+(IV-4),(I-75)+(IV-5),(I-75)+(b-1),(I-75)+(b-2),(I-75)+(b-3),(I-75)+(b-4),(I-75)+(b-5),(I-75)+(b-6),(I-75)+(b-7),(I-75)+(b-8),(I-75)+(b-9),(I-75)+(b-10),(I-75)+(b-11),(I-75)+(b-12),(I-75)+(b-13),(I-75)+(b-14),(I-75)+(S3-1),(I-75)+(S3-2),(I-75)+(S3-3),(I-75)+(S3-4),(I-75)+(S3-5),(I-75)+(h-1),(I-75)+(h-2),(I-75)+(V-1),(I-75)+(V-2),(I-75)+(V-3),(I-75)+(V-4),(I-75)+(V-5),(I-75)+(V-6).
(I-76)+(II-0),(I-76)+(II-1),(I-76)+(II-2),(I-76)+(II-3),(I-76)+(II-4),(I-76)+(II-5),(I-76)+(II-6),(I-76)+(II-9),(I-76)+(II-12),(I-76)+(III-1),(I-76)+(III-4),(I-76)+(III-10),(I-76)+(III-11),(I-76)+(IV-1),(I-76)+(IV-2),(I-76)+(IV-3),(I-76)+(IV-4),(I-76)+(IV-5),(I-76)+(b-1),(I-76)+(b-2),(I-76)+(b-3),(I-76)+(b-4),(I-76)+(b-5),(I-76)+(b-6),(I-76)+(b-7),(I-76)+(b-8),(I-76)+(b-9),(I-76)+(b-10),(I-76)+(b-11),(I-76)+(b-12),(I-76)+(b-1?3),(I-76)+(b-14),(I-76)+(S3-1),(I-76)+(S3-2),(I-76)+(S3-3),(I-76)+(S3-4),(I-76)+(S3-5),(I-76)+(h-1),(I-76)+(h-2),(I-76)+(V-1),(I-76)+(V-2),(I-76)+(V-3),(I-76)+(V-4),(I-76)+(V-5),(I-76)+(V-6).
(I-77)+(II-0),(I-77)+(II-1),(I-77)+(II-2),(I-77)+(II-3),(I-77)+(II-4),(I-77)+(II-5),(I-77)+(II-6),(I-77)+(II-9),(I-77)+(II-12),(I-77)+(III-1),(I-77)+(III-4),(I-77)+(III-10),(I-77)+(III-11),(I-77)+(IV-1),(I-77)+(IV-2),(I-77)+(IV-3),(I-77)+(IV-4),(I-77)+(IV-5),(I-77)+(b-1),(I-77)+(b-2),(I-77)+(b-3),(I-77)+(b-4),(I-77)+(b-5),(I-77)+(b-6),(I-77)+(b-7),(I-77)+(b-8),(I-77)+(b-9),(I-77)+(b-10),(I-77)+(b-11),(I-77)+(b-12),(I-77)+(b-13),(I-77)+(b-14),(I-77)+(S3-1),(I-77)+(S3-2),(I-77)+(S3-3),(I-77)+(S3-4),(I-77)+(S3-5),(I-77)+(h-1),(I-77)+(h-2),(I-77)+(V-1),(I-77)+(V-2),(I-77)+(V-3),(I-77)+(V-4),(I-77)+(V-5),(I-77)+(V-6).
(I-78)+(II-0),(I-78)+(II-1),(I-78)+(II-2),(I-78)+(II-3),(I-78)+(II-4),(I-78)+(II-5),(I-78)+(II-6),(I-78)+(II-9),(I-78)+(II-12),(I-78)+(III-1),(I-78)+(III-4),(I-78)+(III-10),(I-78)+(III-11),(I-78)+(IV-1),(I-78)+(IV-2),(I-78)+(IV-3),(I-78)+(IV-4),(I-78)+(IV-5),(I-78)+(b-1),(I-78)+(b-2),(I-78)+(b-3),(I-78)+(b-4),(I-78)+(b-5),(I-78)+(b-6),(I-78)+(b-7),(I-78)+(b-8),(I-78)+(b-9),(I-78)+(b-10),(I-78)+(b-11),(I-78)+(b-12),(I-78)+(b-13),(I-78)+(b-14),(I-78)+(S3-1),(I-78)+(S3-2),(I-78)+(S3-3),(I-78)+(S3-4),(I-78)+(S3-5),(I-78)+(h-1),(I-78)+(h-2),(I-78)+(V-1),(I-78)+(V-2),(I-78)+(V-3),(I-78)+(V-4),(I-78)+(V-5),(I-78)+(V-6).
(I-79)+(II-0),(I-79)+(II-1),(I-79)+(II-2),(I-79)+(II-3),(I-79)+(II-4),(I-79)+(II-5),(I-79)+(II-6),(I-79)+(II-9),(I-79)+(II-12),(I-79)+(III-1),(I-79)+(III-4),(I-79)+(III-10),(I-79)+(III-11),(I-79)+(IV-1),(I-79)+(IV-2),(I-79)+(IV-3),(I-79)+(IV-4),(I-79)+(IV-5),(I-79)+(b-1),(I-79)+(b-2),(I-79)+(b-3),(I-79)+(b-4),(I-79)+(b-5),(I-79)+(b-6),(I-79)+(b-7),(I-79)+(b-8),(I-79)+(b-9),(I-79)+(b-10),(I-79)+(b-11),(I-79)+(b-12),(I-79)+(b-13),(I-79)+(b-14),(I-79)+(S3-1),(I-79)+(S3-2),(I-79)+(S3-3),(I-79)+(S3-4),(I-79)+(S3-5),(I-79)+(h-1),(I-79)+(h-2),(I-79)+(V-1),(I-79)+(V-2),(I-79)+(V-3),(I-79)+(V-4),(I-79)+(V-5),(I-79)+(V-6).
(I-80)+(II-0),(I-80)+(II-1),(I-80)+(II-2),(I-80)+(II-3),(I-80)+(II-4),(I-80)+(II-5),(I-80)+(II-6),(I-80)+(II-9),(I-80)+(II-12),(I-80)+(III-1),(I-80)+(III-4),(I-80)+(III-10),(I-80)+(III-11),(I-80)+(IV-1),(I-80)+(IV-2),(I-80)+(IV-3),(I-80)+(IV-4),(I-80)+(IV-5),(I-80)+(b-1),(I-80)+(b-2),(I-80)+(b-3),(I-80)+(b-4),(I-80)+(b-5),(I-80)+(b-6),(I-80)+(b-7),(I-80)+(b-8),(I-80)+(b-9),(I-80)+(b-10),(I-80)+(b-11),(I-80)+(b-12),(I-80)+(b-13),(I-80)+(b-14),(I-80)+(S3-1),(I-80)+(S3-2),(I-80)+(S3-3),(I-80)+(S3-4),(I-80)+(S3-5),(I-80)+(h-1),(I-80)+(h-2),(I-80)+(V-1),(I-80)+(V-2),(I-80)+(V-3),(I-80)+(V-4),(I-80)+(V-5),(I-80)+(V-6).
(I-81)+(II-0),(I-81)+(II-1),(I-81)+(II-2),(I-81)+(II-3),(I-81)+(II-4),(I-81)+(II-5),(I-81)+(II-6),(I-81)+(II-9),(I-81)+(II-12),(I-81)+(III-1),(I-81)+(III-4),(I-81)+(III-10),(I-81)+(III-11),(I-81)+(IV-1),(I-81)+(IV-2),(I-81)+(IV-3),(I-81)+(IV-4),(I-81)+(IV-5),(I-81)+(b-1),(I-81)+(b-2),(I-81)+(b-3),(I-81)+(b-4),(I-81)+(b-5),(I-81)+(b-6),(I-81)+(b-7),(I-81)+(b-8),(I-81)+(b-9),(I-81)+(b-10),(I-81)+(b-11),(I-81)+(b-12),(I-81)+(b-13),(I-81)+(b-14),(I-81)+(S3-1),(I-81)+(S3-2),(I-81)+(S3-3),(I-81)+(S3-4),(I-81)+(S3-5),(I-81)+(h-1),(I-81)+(h-2),(I-81)+(V-1),(I-81)+(V-2),(I-81)+(V-3),(I-81)+(V-4),(I-81)+(V-5),(I-81)+(V-6).
(I-82)+(II-0),(I-82)+(II-1),(I-82)+(II-2),(I-82)+(II-3),(I-82)+(II-4),(I-82)+(II-5),(I-82)+(II-6),(I-82)+(II-9),(I-82)+(II-12),(I-82)+(III-1),(I-82)+(III-4),(I-82)+(III-10),(I-82)+(III-11),(I-82)+(IV-1),(I-82)+(IV-2),(I-82)+(IV-3),(I-82)+(IV-4),(I-82)+(IV-5),(I-82)+(b-1),(I-82)+(b-2),(I-82)+(b-3),(I-82)+(b-4),(I-82)+(b-5),(I-82)+(b-6),(I-82)+(b-7),(I-82)+(b-8),(I-82)+(b-9),(I-82)+(b-10),(I-82)+(b-11),(I-82)+(b-12),(I-82)+(b-13),(I-82)+(b-14),(I-82)+(S3-1),(I-82)+(S3-2),(I-82)+(S3-3),(I-82)+(S3-4),(I-82)+(S3-5),(I-82)+(h-1),(I-82)+(h-2),(I-82)+(V-1),(I-82)+(V-2),(I-82)+(V-3),(I-82)+(V-4),(I-82)+(V-5),(I-82)+(V-6).
(I-83)+(II-0),(I-83)+(II-1),(I-83)+(II-2),(I-83)+(II-3),(I-83)+(II-4),(I-83)+(II-5),(I-83)+(II-6),(I-83)+(II-9),(I-83)+(II-12),(I-83)+(III-1),(I-83)+(III-4),(I-83)+(III-10),(I-83)+(III-11),(I-83)+(IV-1),(I-83)+(IV-2),(I-83)+(IV-3),(I-83)+(IV-4),(I-83)+(IV-5),(I-83)+(b-1),(I-83)+(b-2),(I-83)+(b-3),(I-83)+(b-4),(I-83)+(b-5),(I-83)+(b-6),(I-83)+(b-7),(I-83)+(b-8),(I-83)+(b-9),(I-83)+(b-10),(I-83)+(b-11),(I-83)+(b-12),(I-83)+(b-13),(I-83)+(b-14),(I-83)+(S3-1),(I-83)+(S3-2),(I-83)+(S3-3),(I-83)+(S3-4),(I-83)+(S3-5),(I-83)+(h-1),(I-83)+(h-2),(I-83)+(V-1),(I-83)+(V-2),(I-83)+(V-3),(I-83)+(V-4),(I-83)+(V-5),(I-83)+(V-6).
(I-84)+(II-0),(I-84)+(II-1),(I-84)+(II-2),(I-84)+(II-3),(I-84)+(II-4),(I-84)+(II-5),(I-84)+(II-6),(I-84)+(II-9),(I-84)+(II-12),(I-84)+(III-1),(I-84)+(III-4),(I-84)+(III-10),(I-84)+(III-11),(I-84)+(IV-1),(I-84)+(IV-2),(I-84)+(IV-3),(I-84)+(IV-4),(I-84)+(IV-5),(I-84)+(b-1),(I-84)+(b-2),(I-84)+(b-3),(I-84)+(b-4),(I-84)+(b-5),(I-84)+(b-6),(I-84)+(b-7),(I-84)+(b-8),(I-84)+(b-9),(I-84)+(b-10),(I-84)+(b-11),(I-84)+(b-12),(I-84)+(b-13),(I-84)+(b-14),(I-84)+(S3-1),(I-84)+(S3-2),(I-84)+(S3-3),(I-84)+(S3-4),(I-84)+(S3-5),(I-84)+(h-1),(I-84)+(h-2),(I-84)+(V-1),(I-84)+(V-2),(I-84)+(V-3),(I-84)+(V-4),(I-84)+(V-5),(I-84)+(V-6).
(I-85)+(II-0),(I-85)+(II-1),(I-85)+(II-2),(I-85)+(II-3),(I-85)+(II-4),(I-85)+(II-5),(I-85)+(II-6),(I-85)+(II-9),(I-85)+(II-12),(I-85)+(III-1),(I-85)+(III-4),(I-85)+(III-10),(I-85)+(III-11),(I-85)+(IV-1),(I-85)+(IV-2),(I-85)+(IV-3),(I-85)+(IV-4),(I-85)+(IV-5),(I-85)+(b-1),(I-85)+(b-2),(I-85)+(b-3),(I-85)+(b-4),(I-85)+(b-5),(I-85)+(b-6),(I-85)+(b-7),(I-85)+(b-8),(I-85)+(b-9),(I-85)+(b-10),(I-85)+(b-11),(I-85)+(b-12),(I-85)+(b-13),(I-85)+(b-14),(I-85)+(S3-1),(I-85)+(S3-2),(I-85)+(S3-3),(I-85)+(S3-4),(I-85)+(S3-5),(I-85)+(h-1),(I-85)+(h-2),(I-85)+(V-1),(I-85)+(V-2),(I-85)+(V-3),(I-85)+(V-4),(I-85)+(V-5),(I-85)+(V-6).
(I-86)+(II-0),(I-86)+(II-1),(I-86)+(II-2),(I-86)+(II-3),(I-86)+(II-4),(I-86)+(II-5),(I-86)+(II-6),(I-86)+(II-9),(I-86)+(II-12),(I-86)+(III-1),(I-86)+(III-4),(I-86)+(III-10),(I-86)+(III-11),(I-86)+(IV-1),(I-86)+(IV-2),(I-86)+(IV-3),(I-86)+(IV-4),(I-86)+(IV-5),(I-86)+(b-1),(I-86)+(b-2),(I-86)+(b-3),(I-86)+(b-4),(I-86)+(b-5),(I-86)+(b-6),(I-86)+(b-7),(I-86)+(b-8),(I-86)+(b-9),(I-86)+(b-10),(I-86)+(b-11),(I-86)+(b-12),(I-86)+(b-13),(I-86)+(b-14),(I-86)+(S3-1),(I-86)+(S3-2),(I-86)+(S3-3),(I-86)+(S3-4),(I-86)+(S3-5),(I-86)+(h-1),(I-86)+(h-2),(I-86)+(V-1),(I-86)+(V-2),(I-86)+(V-3),(I-86)+(V-4),(I-86)+(V-5),(I-86)+(V-6).
(I-87)+(II-0),(I-87)+(II-1),(I-87)+(II-2),(I-87)+(II-3),(I-87)+(II-4),(I-87)+(II-5),(I-87)+(II-6),(I-87)+(II-9),(I-87)+(II-12),(I-87)+(III-1),(I-87)+(III-4),(I-87)+(III-10),(I-87)+(III-11),(I-87)+(IV-1),(I-87)+(IV-2),(I-87)+(IV-3),(I-87)+(IV-4),(I-87)+(IV-5),(I-87)+(b-1),(I-87)+(b-2),(I-87)+(b-3),(I-87)+(b-4),(I-87)+(b-5),(I-87)+(b-6),(I-87)+(b-7),(I-87)+(b-8),(I-87)+(b-9),(I-87)+(b-10),(I-87)+(b-11),(I-87)+(b-12),(I-87)+(b-13),(I-87)+(b-14),(I-87)+(S3-1),(I-87)+(S3-2),(I-87)+(S3-3),(I-87)+(S3-4),(I-87)+(S3-5),(I-87)+(h-1),(I-87)+(h-2),(I-87)+(V-1),(I-87)+(V-2),(I-87)+(V-3),(I-87)+(V-4),(I-87)+(V-5),(I-87)+(V-6).
(I-88)+(II-0),(I-88)+(II-1),(I-88)+(II-2),(I-88)+(II-3),(I-88)+(II-4),(I-88)+(II-5),(I-88)+(II-6),(I-88)+(II-9),(I-88)+(II-12),(I-88)+(III-1),(I-88)+(III-4),(I-88)+(III-10),(I-88)+(III-11),(I-88)+(IV-1),(I-88)+(IV-2),(I-88)+(IV-3),(I-88)+(IV-4),(I-88)+(IV-5),(I-88)+(b-1),(I-88)+(b-2),(I-88)+(b-3),(I-88)+(b-4),(I-88)+(b-5),(I-88)+(b-6),(I-88)+(b-7),(I-88)+(b-8),(I-88)+(b-9),(I-88)+(b-10),(I-88)+(b-11),(I-88)+(b-12),(I-88)+(b-13),(I-88)+(b-14),(I-88)+(S3-1),(I-88)+(S3-2),(I-88)+(S3-3),(I-88)+(S3-4),(I-88)+(S3-5),(I-88)+(h-1),(I-88)+(h-2),(I-88)+(V-1),(I-88)+(V-2),(I-88)+(V-3),(I-88)+(V-4),(I-88)+(V-5),(I-88)+(V-6).
(I-89)+(II-0),(I-89)+(II-1),(I-89)+(II-2),(I-89)+(II-3),(I-89)+(II-4),(I-89)+(II-5),(I-89)+(II-6),(I-89)+(II-9),(I-89)+(II-12),(I-89)+(III-1),(I-89)+(III-4),(I-89)+(III-10),(I-89)+(III-11),(I-89)+(IV-1),(I-89)+(IV-2),(I-89)+(IV-3),(I-89)+(IV-4),(I-89)+(IV-5),(I-89)+(b-1),(I-89)+(b-2),(I-89)+(b-3),(I-89)+(b-4),(I-89)+(b-5),(I-89)+(b-6),(I-89)+(b-7),(I-89)+(b-8),(I-89)+(b-9),(I-89)+(b-10),(I-89)+(b-11),(I-89)+(b-12),(I-89)+(b-13),(I-89)+(b-14),(I-89)+(S3-1),(I-89)+(S3-2),(I-89)+(S3-3),(I-89)+(S3-4),(I-89)+(S3-5),(I-89)+(h-1),(I-89)+(h-2),(I-89)+(V-1),(I-89)+(V-2),(I-89)+(V-3),(I-89)+(V-4),(I-89)+(V-5),(I-89)+(V-6).
(I-90)+(II-0),(I-90)+(II-1),(I-90)+(II-2),(I-90)+(II-3),(I-90)+(II-4),(I-90)+(II-5),(I-90)+(II-6),(I-90)+(II-9),(I-90)+(II-12),(I-90)+(III-1),(I-90)+(III-4),(I-90)+(III-10),(I-90)+(III-11),(I-90)+(IV-1),(I-90)+(IV-2),(I-90)+(IV-3),(I-90)+(IV-4),(I-90)+(IV-5),(I-90)+(b-1),(I-90)+(b-2),(I-90)+(b-3),(I-90)+(b-4),(I-90)+(b-5),(I-90)+(b-6),(I-90)+(b-7),(I-90)+(b-8),(I-90)+(b-9),(I-90)+(b-10),(I-90)+(b-11),(I-90)+(b-12),(I-90)+(b-13),(I-90)+(b-14),(I-90)+(S3-1),(I-90)+(S3-2),(I-90)+(S3-3),(I-90)+(S3-4),(I-90)+(S3-5),(I-90)+(h-1),(I-90)+(h-2),(I-90)+(V-1),(I-90)+(V-2),(I-90)+(V-3),(I-90)+(V-4),(I-90)+(V-5),(I-90)+(V-6).
(I-91)+(II-0),(I-91)+(II-1),(I-91)+(II-2),(I-91)+(II-3),(I-91)+(II-4),(I-91)+(II-5),(I-91)+(II-6),(I-91)+(II-9),(I-91)+(II-12),(I-91)+(III-1),(I-91)+(III-4),(I-91)+(III-10),(I-91)+(III-11),(I-91)+(IV-1),(I-91)+(IV-2),(I-91)+(IV-3),(I-91)+(IV-4),(I-91)+(IV-5),(I-91)+(b-1),(I-91)+(b-2),(I-91)+(b-3),(I-91)+(b-4),(I-91)+(b-5),(I-91)+(b-6),(I-91)+(b-7),(I-91)+(b-8),(I-91)+(b-9),(I-91)+(b-10),(I-91)+(b-11),(I-91)+(b-12),(I-91)+(b-13),(I-91)+(b-14),(I-91)+(S3-1),(I-91)+(S3-2),(I-91)+(S3-3),(I-91)+(S3-4),(I-91)+(S3-5),(I-91)+(h-1),(I-91)+(h-2),(I-91)+(V-1),(I-91)+(V-2),(I-91)+(V-3),(I-91)+(V-4),(I-91)+(V-5),(I-91)+(V-6).
(I-92)+(II-0),(I-92)+(II-1),(I-92)+(II-2),(I-92)+(II-3),(I-92)+(II-4),(I-92)+(II-5),(I-92)+(II-6),(I-92)+(II-9),(I-92)+(II-12),(I-92)+(III-1),(I-92)+(III-4),(I-92)+(III-10),(I-92)+(III-11),(I-92)+(IV-1),(I-92)+(IV-2),(I-92)+(IV-3),(I-92)+(IV-4),(I-92)+(IV-5),(I-92)+(b-1),(I-92)+(b-2),(I-92)+(b-3),(I-92)+(b-4),(I-92)+(b-5),(I-92)+(b-6),(I-92)+(b-7),(I-92)+(b-8),(I-92)+(b-9),(I-92)+(b-10),(I-92)+(b-11),(I-92)+(b-12),(I-92)+(b-13),(I-92)+(b-14),(I-92)+(S3-1),(I-92)+(S3-2),(I-92)+(S3-3),(I-92)+(S3-4),(I-92)+(S3-5),(I-92)+(h-1),(I-92)+(h-2),(I-92)+(V-1),(I-92)+(V-2),(I-92)+(V-3),(I-92)+(V-4),(I-92)+(V-5),(I-92)+(V-6).
(I-93)+(II-0),(I-93)+(II-1),(I-93)+(II-2),(I-93)+(II-3),(I-93)+(II-4),(I-93)+(II-5),(I-93)+(II-6),(I-93)+(II-9),(I-93)+(II-12),(I-93)+(III-1),(I-93)+(III-4),(I-93)+(III-10),(I-93)+(III-11),(I-93)+(IV-1),(I-93)+(IV-2),(I-93)+(IV-3),(I-93)+(IV-4),(I-93)+(IV-5),(I-93)+(b-1),(I-93)+(b-2),(I-93)+(b-3),(I-93)+(b-4),(I-93)+(b-5),(I-93)+(b-6),(I-93)+(b-7),(I-93)+(b-8),(I-93)+(b-9),(I-93)+(b-10),(I-93)+(b-11),(I-93)+(b-12),(I-93)+(b-13),(I-93)+(b-14),(I-93)+(S3-1),(I-93)+(S3-2),(I-93)+(S3-3),(I-93)+(S3-4),(I-93)+(S3-5),(I-93)+(h-1),(I-93)+(h-2),(I-93)+(V-1),(I-93)+(V-2),(I-93)+(V-3),(I-93)+(V-4),(I-93)+(V-5),(I-93)+(V-6).
(I-94)+(II-0),(I-94)+(II-1),(I-94)+(II-2),(I-94)+(II-3),(I-94)+(II-4),(I-94)+(II-5),(I-94)+(II-6),(I-94)+(II-9),(I-94)+(II-12),(I-94)+(III-1),(I-94)+(III-4),(I-94)+(III-10),(I-94)+(III-11),(I-94)+(IV-1),(I-94)+(IV-2),(I-94)+(IV-3),(I-94)+(IV-4),(I-94)+(IV-5),(I-94)+(b-1),(I-94)+(b-2),(I-94)+(b-3),(I-94)+(b-4),(I-94)+(b-5),(I-94)+(b-6),(I-94)+(b-7),(I-94)+(b-8),(I-94)+(b-9),(I-94)+(b-10),(I-94)+(b-11),(I-94)+(b-12),(I-94)+(b-13),(I-94)+(b-14),(I-94)+(S3-1),(I-94)+(S3-2),(I-94)+(S3-3),(I-94)+(S3-4),(I-94)+(S3-5),(I-94)+(h-1),(I-94)+(h-2),(I-94)+(V-1),(I-94)+(V-2),(I-94)+(V-3),(I-94)+(V-4),(I-94)+(V-5),(I-94)+(V-6).
(I-95)+(II-0),(I-95)+(II-1),(I-95)+(II-2),(I-95)+(II-3),(I-95)+(II-4),(I-95)+(II-5),(I-95)+(II-6),(I-95)+(II-9),(I-95)+(II-12),(I-95)+(III-1),(I-95)+(III-4),(I-95)+(III-10),(I-95)+(III-11),(I-95)+(IV-1),(I-95)+(IV-2),(I-95)+(IV-3),(I-95)+(IV-4),(I-95)+(IV-5),(I-95)+(b-1),(I-95)+(b-2),(I-95)+(b-3),(I-95)+(b-4),(I-95)+(b-5),(I-95)+(b-6),(I-95)+(b-7),(I-95)+(b-8),(I-95)+(b-9),(I-95)+(b-10),(I-95)+(b-11),(I-95)+(b-12),(I-95)+(b-13),(I-95)+(b-14),(I-95)+(S3-1),(I-95)+(S3-2),(I-95)+(S3-3),(I-95)+(S3-4),(I-95)+(S3-5),(I-95)+(h-1),(I-95)+(h-2),(I-95)+(V-1),(I-95)+(V-2),(I-95)+(V-3),(I-95)+(V-4),(I-95)+(V-5),(I-95)+(V-6).
(I-96)+(II-0),(I-96)+(II-1),(I-96)+(II-2),(I-96)+(II-3),(I-96)+(II-4),(I-96)+(II-5),(I-96)+(II-6),(I-96)+(II-9),(I-96)+(II-12),(I-96)+(III-1),(I-96)+(III-4),(I-96)+(III-10),(I-96)+(III-11),(I-96)+(IV-1),(I-96)+(IV-2),(I-96)+(IV-3),(I-96)+(IV-4),(I-96)+(IV-5),(I-96)+(b-1),(I-96)+(b-2),(I-96)+(b-3),(I-96)+(b-4),(I-96)+(b-5),(I-96)+(b-6),(I-96)+(b-7),(I-96)+(b-8),(I-96)+(b-9),(I-96)+(b-10),(I-96)+(b-11),(I-96)+(b-12),(I-96)+(b-13),(I-96)+(b-14),(I-96)+(S3-1),(I-96)+(S3-2),(I-96)+(S3-3),(I-96)+(S3-4),(I-96)+(S3-5),(I-96)+(h-1),(I-96)+(h-2),(I-96)+(V-1),(I-96)+(V-2),(I-96)+(V-3),(I-96)+(V-4),(I-96)+(V-5),(I-96)+(V-6).
(I-97)+(II-0),(I-97)+(II-1),(I-97)+(II-2),(I-97)+(II-3),(I-97)+(II-4),(I-97)+(II-5),(I-97)+(II-6),(I-97)+(II-9),(I-97)+(II-12),(I-97)+(III-1),(I-97)+(III-4),(I-97)+(III-10),(I-97)+(III-11),(I-97)+(IV-1),(I-97)+(IV-2),(I-97)+(IV-3),(I-97)+(IV-4),(I-97)+(IV-5),(I-97)+(b-1),(I-97)+(b-2),(I-97)+(b-3),(I-97)+(b-4),(I-97)+(b-5),(I-97)+(b-6),(I-97)+(b-7),(I-97)+(b-8),(I-97)+(b-9),(I-97)+(b-10),(I-97)+(b-11),(I-97)+(b-12),(I-97)+(b-13),(I-97)+(b-14),(I-97)+(S3-1),(I-97)+(S3-2),(I-97)+(S3-3),(I-97)+(S3-4),(I-97)+(S3-5),(I-97)+(h-1),(I-97)+(h-2),(I-97)+(V-1),(I-97)+(V-2),(I-97)+(V-3),(I-97)+(V-4),(I-97)+(V-5),(I-97)+(V-6).
(I-98)+(II-0),(I-98)+(II-1),(I-98)+(II-2),(I-98)+(II-3),(I-98)+(II-4),(I-98)+(II-5),(I-98)+(II-6),(I-98)+(II-9),(I-98)+(II-12),(I-98)+(III-1),(I-98)+(III-4),(I-98)+(III-10),(I-98)+(III-11),(I-98)+(IV-1),(I-98)+(IV-2),(I-98)+(IV-3),(I-98)+(IV-4),(I-98)+(IV-5),(I-98)+(b-1),(I-98)+(b-2),(I-98)+(b-3),(I-98)+(b-4),(I-98)+(b-5),(I-98)+(b-6),(I-98)+(b-7),(I-98)+(b-8),(I-98)+(b-9),(I-98)+(b-10),(I-98)+(b-11),(I-98)+(b-12),(I-98)+(b-13),(I-98)+(b-14),(I-98)+(S3-1),(I-98)+(S3-2),(I-98)+(S3-3),(I-98)+(S3-4),(I-98)+(S3-5),(I-98)+(h-1),(I-98)+(h-2),(I-98)+(V-1),(I-98)+(V-2),(I-98)+(V-3),(I-98)+(V-4),(I-98)+(V-5),(I-98)+(V-6).
(I-99)+(II-0),(I-99)+(II-1),(I-99)+(II-2),(I-99)+(II-3),(I-99)+(II-4),(I-99)+(II-5),(I-99)+(II-6),(I-99)+(II-9),(I-99)+(II-12),(I-99)+(III-1),(I-99)+(III-4),(I-99)+(III-10),(I-99)+(III-11),(I-99)+(IV-1),(I-99)+(IV-2),(I-99)+(IV-3),(I-99)+(IV-4),(I-99)+(IV-5),(I-99)+(b-1),(I-99)+(b-2),(I-99)+(b-3),(I-99)+(b-4),(I-99)+(b-5),(I-99)+(b-6),(I-99)+(b-7),(I-99)+(b-8),(I-99)+(b-9),(I-99)+(b-10),(I-99)+(b-11),(I-99)+(b-12),(I-99)+(b-13),(I-99)+(b-14),(I-99)+(S3-1),(I-99)+(S3-2),(I-99)+(S3-3),(I-99)+(S3-4),(I-99)+(S3-5),(I-99)+(h-1),(I-99)+(h-2),(I-99)+(V-1),(I-99)+(V-2),(I-99)+(V-3),(I-99)+(V-4),(I-99)+(V-5),(I-99)+(V-6).
(I-100)+(II-0),(I-100)+(II-1),(I-100)+(II-2),(I-100)+(II-3),(I-100)+(II-4),(I-100)+(II-5),(I-100)+(II-6),(I-100)+(II-9),(I-100)+(II-12),(I-100)+(III-1),(I-100)+(III-4),(I-100)+(III-10),(I-100)+(III-11),(I-100)+(IV-1),(I-1?00)+(IV-2),(I-100)+(IV-3),(I-100)+(IV-4),(I-100)+(IV5),(I-100)+(b-1),(I-100)+(b-2),(I-100)+(b-3),(I-100)+(b-4),(I-100)+(b-5),(I-100)+(b-6),(I-100)+(b-7),(I-100)+(b-8),(I-100)+(b-9),(I-100)+(b-10),(I-100)+(b-11),(I-100)+(b-12),(I-100)+(b-13),(I-100)+(b-14),(I-100)+(S3-1),(I-100)+(S3-2),(I-100)+(S3-3),(I-100)+(S3-4),(I-100)+(S3-5),(I-100)+(h-1),(I-100)+(h-2),(I-100)+(V-1),(I-100)+(V-2),(I-100)+(V-3),(I-100)+(V-4),(I-100)+(V-5),(I-100)+(V-6).
(I-101)+(II-0),(I-101)+(II-1),(I-101)+(II-2),(I-101)+(II-3),(I-101)+(II-4),(I-101)+(II-5),(I-101)+(II-6),(I-101)+(II-9),(I-101)+(II-12),(I-101)+(III-1),(I-101)+(III-4),(I-101)+(III-10),(I-101)+(III-11),(I-101)+(IV-1),(I-101)+(IV-2),(I-101)+(IV-3),(I-101)+(IV-4),(I-101)+(IV-5),(I-101)+(b-1),(I-101)+(b-2),(I-101)+(b-3),(I-101)+(b-4),(I-101)+(b-5),(I-101)+(b-6),(I-101)+(b-7),(I-101)+(b-8),(I-101)+(b-9),(I-101)+(b-10),(I-101)+(b-11),(I-101)+(b-12),(I-101)+(b-13),(I-101)+(b-14),(I-101)+(S3-1),(I-101)+(S3-2),(I-101)+(S3-3),(I-101)+(S3-4),(I-101)+(S3-5),(I-101)+(h-1),(I-101)+(h-2),(I-101)+(V-1),(I-101)+(V-2),(I-101)+(V-3),(I-101)+(V-4),(I-101)+(V-5),(I-101)+(V-6).
(I-102)+(II-0),(I-102)+(II-1),(I-102)+(II-2),(I-102)+(II-3),(I-102)+(II-4),(I-102)+(II-5),(I-102)+(II-6),(I-102)+(II-9),(I-102)+(II-12),(I-102)+(III-1),(I-102)+(III-4),(I-102)+(III-10),(I-102)+(III-11),(I-102)+(IV-1),(I-102)+(IV-2),(I-102)+(IV-3),(I-102)+(IV-4),(I-102)+(IV-5),(I-102)+(b-1),(I-102)+(b-2),(I-102)+(b-3),(I-102)+(b-4),(I-102)+(b-5),(I-102)+(b-6),(I-102)+(b-7),(I-102)+(b-8),(I-102)+(b-9),(I-102)+(b-10),(I-102)+(b-11),(I-102)+(b-12),(I-102)+(b-13),(I-102)+(b-14),(I-102)+(S3-1),(I-102)+(S3-2),(I-102)+(S3-3),(I-102)+(S3-4),(I-102)+(S3-5),(I-102)+(h-1),(I-102)+(h-2),(I-102)+(V-1),(I-102)+(V-2),(I-102)+(V-3),(I-102)+(V-4),(I-102)+(V-5),(I-102)+(V-6).
(I-103)+(II-0),(I-103)+(II-1),(I-103)+(II-2),(I-103)+(II-3),(I-103)+(II-4),(I-103)+(II-5),(I-103)+(II-6),(I-103)+(II-9),(I-103)+(II-12),(I-103)+(III-1),(I-103)+(III-4),(I-103)+(III-10),(I-103)+(III-11),(I-103)+(IV-1),(I-103)+(IV-2),(I-103)+(IV-3),(I-103)+(IV-4),(I-103)+(IV-5),(I-103)+(b-1),(I-103)+(b-2),(I-103)+(b-3),(I-103)+(b-4),(I-103)+(b-5),(I-103)+(b-6),(I-103)+(b-7),(I-103)+(b-8),(I-103)+(b-9),(I-103)+(b-10),(I-103)+(b-11),(I-103)+(b-12),(I-103)+(b-13),(I-103)+(b-14),(I-103)+(S3-1),(I-103)+(S3-2),(I-103)+(S3-3),(I-103)+(S3-4),(I-103)+(S3-5),(I-103)+(h-1),(I-103)+(h-2),(I-103)+(V-1),(I-103)+(V-2),(I-103)+(V-3),(I-103)+(V-4),(I-103)+(V-5),(I-103)+(V-6).
(I-104)+(II-0),(I-104)+(II-1),(I-104)+(II-2),(I-104)+(II-3),(I-104)+(II-4),(I-104)+(II-5),(I-104)+(II-6),(I-104)+(II-9),(I-104)+(II-12),(I-104)+(III-1),(I-104)+(III-4),(I-104)+(III-10),(I-104)+(III-11),(I-104)+(IV-1),(I-104)+(IV-2),(I-104)+(IV-3),(I-104)+(IV-4),(I-104)+(IV-5),(I-104)+(b-1),(I-104)+(b-2),(I-104)+(b-3),(I-104)+(b-4),(I-104)+(b-5),(I-104)+(b-6),(I-104)+(b-7),(I-104)+(b-8),(I-104)+(b-9),(I-104)+(b-10),(I-104)+(b-11),(I-104)+(b-12),(I-104)+(b-13),(I-104)+(b-14),(I-104)+(S3-1),(I-104)+(S3-2),(I-104)+(S3-3),(I-104)+(S3-4),(I-104)+(S3-5),(I-104)+(h-1),(I-104)+(h-2),(I-104)+(V-1),(I-104)+(V-2),(I-104)+(V-3),(I-104)+(V-4),(I-104)+(V-5),(I-104)+(V-6).
(I-105)+(II-0),(I-105)+(II-1),(I-105)+(II-2),(I-105)+(II-3),(I-105)+(II-4),(I-105)+(II-5),(I-105)+(II-6),(I-105)+(II-9),(I-105)+(II-12),(I-105)+(III-1),(I-105)+(III-4),(I-105)+(III-10),(I-105)+(III-11),(I-105)+(IV-1),(I-105)+(IV-2),(I-105)+(IV-3),(I-105)+(IV-4),(I-105)+(IV-5),(I-105)+(b-1),(I-105)+(b-2),(I-105)+(b-3),(I-105)+(b-4),(I-105)+(b-5),(I-105)+(b-6),(I-105)+(b-7),(I-105)+(b-8),(I-105)+(b-9),(I-105)+(b-10),(I-105)+(b-11),(I-105)+(b-12),(I-105)+(b-13),(I-105)+(b-14),(I-105)+(S3-1),(I-105)+(S3-2),(I-105)+(S3-3),(I-105)+(S3-4),(I-105)+(S3-5),(I-105)+(h-1),(I-105)+(h-2),(I-105)+(V-1),(I-105)+(V-2),(I-105)+(V-3),(I-105)+(V-4),(I-105)+(V-5),(I-105)+(V-6).
(I-106)+(II-0),(I-106)+(II-1),(I-106)+(II-2),(I-106)+(II-3),(I-106)+(II-4),(I-106)+(II-5),(I-106)+(II-6),(I-106)+(II-9),(I-106)+(II-12),(I-106)+(III-1),(I-106)+(III-4),(I-106)+(III-10),(I-106)+(III-11),(I-106)+(IV-1),(I-106)+(IV-2),(I-106)+(IV-3),(I-106)+(IV-4),(I-106)+(IV-5),(I-106)+(b-1),(I-106)+(b-2),(I-106)+(b-3),(I-106)+(b-4),(I-106)+(b-5),(I-106)+(b-6),(I-106)+(b-7),(I-106)+(b-8),(I-106)+(b-9),(I-106)+(b-10),(I-106)+(b-11),(I-106)+(b-12),(I-106)+(b-13),(I-106)+(b-14),(I-106)+(S3-1),(I-106)+(S3-2),(I-106)+(S3-3),(I-106)+(S3-4),(I-106)+(S3-5),(I-106)+(h-1),(I-106)+(h-2),(I-106)+(V-1),(I-106)+(V-2),(I-106)+(V-3),(I-106)+(V-4),(I-106)+(V-5),(I-106)+(V-6).
(I-107)+(II-0),(I-107)+(II-1),(I-107)+(II-2),(I-107)+(II-3),(I-107)+(II-4),(I-107)+(II-5),(I-107)+(II-6),(I-107)+(II-9),(I-107)+(II-12),(I-107)+(III-1),(I-107)+(III-4),(I-107)+(III-10),(I-107)+(III-11),(I-107)+(IV-1),(I-107)+(IV-2),(I-107)+(IV-3),(I-107)+(IV-4),(I-107)+(IV-5),(I-107)+(b-1),(I-107)+(b-2),(I-107)+(b-3),(I-107)+(b-4),(I-107)+(b-5),(I-107)+(b-6),(I-107)+(b-7),(I-107)+(b-8),(I-107)+(b-9),(I-107)+(b-10),(I-107)+(b-11),(I-107)+(b-12),(I-107)+(b-13),(I-107)+(b-14),(I-107)+(S3-1),(I-107)+(S3-2),(I-107)+(S3-3),(I-107)+(S3-4),(I-107)+(S3-5),(I-107)+(h-1),(I-107)+(h-2),(I-107)+(V-1),(I-107)+(V-2),(I-107)+(V-3),(I-107)+(V-4),(I-107)+(V-5),(I-107)+(V-6).
(I-108)+(II-0),(I-108)+(II-1),(I-108)+(II-2),(I-108)+(II-3),(I-108)+(II-4),(I-108)+(II-5),(I-108)+(II-6),(I-108)+(II-9),(I-108)+(II-12),(I-108)+(III-1),(I-108)+(III-4),(I-108)+(III-10),(I-108)+(III-11),(I-108)+(IV-1),(I-108)+(IV-2),(I-108)+(IV-3),(I-108)+(IV-4),(I-108)+(IV-5),(I-108)+(b-1),(I-108)+(b-2),(I-108)+(b-3),(I-108)+(b-4),(I-108)+(b-5),(I-108)+(b-6),(I-108)+(b-7),(I-108)+(b-8),(I-108)+(b-9),(I-108)+(b-10),(I-108)+(b-11),(I-108)+(b-12),(I-108)+(b-13),(I-108)+(b-14),(I-108)+(S3-1),(I-108)+(S3-2),(I-108)+(S3-3),(I-108)+(S3-4),(I-108)+(S3-5),(I-108)+(h-1),(I-108)+(h-2),(I-108)+(V-1),(I-108)+(V-2),(I-108)+(V-3),(I-108)+(V-4),(I-108)+(V-5),(I-108)+(V-6).
(I-109)+(II-0),(I-109)+(II-1),(I-109)+(II-2),(I-109)+(II-3),(I-109)+(II-4),(I-109)+(II-5),(I-109)+(II-6),(I-109)+(II-9),(I-109)+(II-12),(I-109)+(III-1),(I-109)+(III-4),(I-109)+(III-10),(I-109)+(III-11),(I-109)+(IV-1),(I-109)+(IV-2),(I-109)+(IV-3),(I-109)+(IV-4),(I-109)+(IV-5),(I-109)+(b-1),(I-109)+(b-2),(I-109)+(b-3),(I-109)+(b-4),(I-109)+(b-5),(I-109)+(b-6),(I-109)+(b-7),(I-109)+(b-8),(I-109)+(b-9),(I-109)+(b-10),(I-109)+(b-11),(I-109)+(b-12),(I-109)+(b-13),(I-109)+(b-14),(I-109)+(S3-1),(I-109)+(S3-2),(I-109)+(S3-3),(I-109)+(S3-4),(I-109)+(S3-5),(I-109)+(h-1),(I-109)+(h-2),(I-109)+(V-1),(I-109)+(V-2),(I-109)+(V-3),(I-109)+(V-4),(I-109)+(V-5),(I-109)+(V-6).
(I-110)+(II-0),(I-110)+(II-1),(I-110)+(II-2),(I-110)+(II-3),(I-110)+(II-4),(I-110)+(II-5),(I-110)+(II-6),(I-110)+(II-9),(I-110)+(II-12),(I-110)+(III-1),(I-110)+(III-4),(I-110)+(III-10),(I-110)+(III-11),(I-110)+(IV-1),(I-110)+(IV-2),(I-110)+(IV-3),(I-110)+(IV-4),(I-110)+(IV-5),(I-110)+(b-1),(I-110)+(b-2),(I-110)+(b-3),(I-110)+(b-4),(I-110)+(b-5),(I-110)+(b-6),(I-110)+(b-7),(I-110)+(b-8),(I-110)+(b-9),(I-110)+(b-10),(I-110)+(b-11),(I-110)+(b-12),(I-110)+(b-13),(I-110)+(b-14),(I-110)+(S3-1),(I-110)+(S3-2),(I-110)+(S3-3),(I-110)+(S3-4),(I-110)+(S3-5),(I-110)+(h-1),(I-110)+(h-2),(I-110)+(V-1),(I-110)+(V-2),(I-110)+(V-3),(I-110)+(V-4),(I-110)+(V-5),(I-110)+(V-6).
(I-111)+(II-0),(I-111)+(II-1),(I-111)+(II-2),(I-111)+(II-3),(I-111)+(II-4),(I-111)+(II-5),(I-111)+(II-6),(I-111)+(II-9),(I-111)+(II-12),(I-111)+(III-1),(I-111)+(III-4),(I-111)+(III-10),(I-111)+(III-11),(I-111)+(IV-1),(I-111)+(IV-2),(I-111)+(IV-3),(I-111)+(IV-4),(I-111)+(IV-5),(I-111)+(b-1),(I-111)+(b-2),(I-111)+(b-3),(I-111)+(b-4),(I-111)+(b-5),(I-111)+(b-6),(I-111)+(b-7),(I-111)+(b-8),(I-111)+(b-9),(I-111)+(b-10),(I-111)+(b-11),(I-111)+(b-12),(I-111)+(b-13),(I-111)+(b-14),(I-111)+(S3-1),(I-111)+(S3-2),(I-111)+(S3-3),(I-111)+(S3-4),(I-111)+(S3-5),(I-111)+(h-1),(I-111)+(h-2),(I-111)+(V-1),(I-111)+(V-2),(I-111)+(V-3),(I-111)+(V-4),(I-111)+(V-5),(I-111)+(V-6).
(I-112)+(II-0),(I-112)+(II-1),(I-112)+(II-2),(I-112)+(II-3),(I-112)+(II-4),(I-112)+(II-5),(I-112)+(II-6),(I-112)+(II-9),(I-112)+(II-12),(I-112)+(III-1),(I-112)+(III-4),(I-112)+(III-10),(I-112)+(III-11),(I-112)+(IV-1),(I-112)+(IV-2),(I-112)+(IV-3),(I-112)+(IV-4),(I-112)+(IV-5),(I-112)+(b-1),(I-112)+(b-2),(I-112)+(b-3),(I-112)+(b-4),(I-112)+(b-5),(I-112)+(b-6),(I-112)+(b-7),(I-112)+(b-8),(I-112)+(b-9),(I-112)+(b-10),(I-112)+(b-11),(I-112)+(b-12),(I-112)+(b-13),(I-112)+(b-14),(I-112)+(S3-1),(I-112)+(S3-2),(I-112)+(S3-3),(I-112)+(S3-4),(I-112)+(S3-5),(I-112)+(h-1),(I-112)+(h-2),(I-112)+(V-1),(I-112)+(V-2),(I-112)+(V-3),(I-112)+(V-4),(I-112)+(V-5),(I-112)+(V-6).
(I-113)+(II-0),(I-113)+(II-1),(I-113)+(II-2),(I-113)+(II-3),(I-113)+(II-4),(I-113)+(II-5),(I-113)+(II-6),(I-113)+(II-9),(I-113)+(II-12),(I-113)+(III-1),(I-113)+(III-4),(I-113)+(III-10),(I-113)+(III-11),(I-113)+(IV-1),(I-113)+(IV-2),(I-113)+(IV-3),(I-113)+(IV-4),(I-113)+(IV-5),(I-113)+(b-1),(I-113)+(b-2),(I-113)+(b-3),(I-113)+(b-4),(I-113)+(b-5),(I-113)+(b-6),(I-113)+(b-7),(I-113)+(b-8),(I-113)+(b-9),(I-113)+(b-10),(I-113)+(b-11),(I-113)+(b-12),(I-113)+(b-13),(I-113)+(b-14),(I-113)+(S3-1),(I-113)+(S3-2),(I-113)+(S3-3),(I-113)+(S3-4),(I-113)+(S3-5),(I-113)+(h-1),(I-113)+(h-2),(I-113)+(V-1),(I-113)+(V-2),(I-113)+(V-3),(I-113)+(V-4),(I-113)+(V-5),(I-113)+(V-6).
(I-114)+(II-0),(I-114)+(II-1),(I-114)+(II-2),(I-114)+(II-3),(I-114)+(II-4),(I-114)+(II-5),(I-114)+(II-6),(I-114)+(II-9),(I-114)+(II-12),(I-114)+(III-1),(I-114)+(III-4),(I-114)+(III-10),(I-114)+(III-11),(I-114)+(IV-1),(I-114)+(IV-2),(I-114)+(IV-3),(I-114)+(IV-4),(I-114)+(IV-5),(I-114)+(b-1),(I-114)+(b-2),(I-114)+(b-3),(I-114)+(b-4),(I-114)+(b-5),(I-114)+(b-6),(I-114)+(b-7),(I-114)+(b-8),(I-114)+(b-9),(I-114)+(b-10),(I-114)+(b-11),(I-114)+(b-12),(I-114)+(b-13),(I-114)+(b-14),(I-114)+(S3-1),(I-114)+(S3-2),(I-114)+(S3-3),(I-114)+(S3-4),(I-114)+(S3-5),(I-114)+(h-1),(I-114)+(h-2),(I-114)+(V-1),(I-114)+(V-2),(I-114)+(V-3),(I-114)+(V-4),(I-114)+(V-5),(I-114)+(V-6).
(I-115)+(II-0),(I-115)+(II-1),(I-115)+(II-2),(I-115)+(II-3),(I-115)+(II-4),(I-115)+(II-5),(I-115)+(II-6),(I-115)+(II-9),(I-115)+(II-12),(I-115)+(III-1),(I-115)+(III-4),(I-115)+(III-10),(I-115)+(III-11),(I-115)+(IV-1),(I-115)+(IV-2),(I-115)+(IV-3),(I-115)+(IV-4),(I-115)+(IV-5),(I-115)+(b-1),(I-115)+(b-2),(I-115)+(b-3),(I-115)+(b-4),(I-115)+(b-5),(I-115)+(b-6),(I-115)+(b-7),(I-115)+(b-8),(I-115)+(b-9),(I-115)+(b-10),(I-115)+(b-11),(I-115)+(b-12),(I-115)+(b-13),(I-115)+(b-14),(I-115)+(S3-1),(I-115)+(S3-2),(I-115)+(S3-3),(I-115)+(S3-4),(I-115)+(S3-5),(I-115)+(h-1),(I-115)+(h-2),(I-115)+(V-1),(I-115)+(V-2),(I-115)+(V-3),(I-115)+(V-4),(I-115)+(V-5),(I-115)+(V-6).
(I-116)+(II-0),(I-116)+(II-1),(I-116)+(II-2),(I-116)+(II-3),(I-116)+(II-4),(I-116)+(II-5),(I-116)+(II-6),(I-116)+(II-9),(I-116)+(II-12),(I-116)+(III-1),(I-116)+(III-4),(I-116)+(III-10),(I-116)+(III-11),(I-116)+(IV-1),(I-116)+(IV-2),(I-116)+(IV-3),(I-116)+(IV-4),(I-116)+(IV-5),(I-116)+(b-1),(I-116)+(b-2),(I-116)+(b-3),(I-116)+(b-4),(I-116)+(b-5),(I-116)+(b-6),(I-116)+(b-7),(I-116)+(b-8),(I-116)+(b-9),(I-116)+(b-10),(I-116)+(b-11),(I-116)+(b-12),(I-116)+(b-13),(I-116)+(b-14),(I-116)+(S3-1),(I-116)+(S3-2),(I-116)+(S3-3),(I-116)+(S3-4),(I-116)+(S3-5),(I-116)+(h-1),(I-116)+(h-2),(I-116)+(V-1),(I-116)+(V-2),(I-116)+(V-3),(I-116)+(V-4),(I-116)+(V-5),(I-116)+(V-6).
(I-117)+(II-0),(I-117)+(II-1),(I-117)+(II-2),(I-117)+(II-3),(I-117)+(II-4),(I-117)+(II-5),(I-117)+(II-6),(I-117)+(II-9),(I-117)+(II-12),(I-117)+(III-1),(I-117)+(III-4),(I-117)+(III-10),(I-117)+(III-11),(I-117)+(IV-1),(I-117)+(IV-2),(I-117)+(IV-3),(I-117)+(IV-4),(I-117)+(IV-5),(I-117)+(b-1),(I-117)+(b-2),(I-117)+(b-3),(I-117)+(b-4),(I-117)+(b-5),(I-117)+(b-6),(I-117)+(b-7),(I-117)+(b-8),(I-117)+(b-9),(I-117)+(b-10),(I-117)+(b-11),(I-117)+(b-12),(I-117)+(b-13),(I-117)+(b-14),(I-117)+(S3-1),(I-117)+(S3-2),(I-117)+(S3-3),(I-117)+(S3-4),(I-117)+(S3-5),(I-117)+(h-1),(I-117)+(h-2),(I-117)+(V-1),(I-117)+(V-2),(I-117)+(V-3),(I-117)+(V-4),(I-117)+(V-5),(I-117)+(V-6).
(I-118)+(II-0),(I-118)+(II-1),(I-118)+(II-2),(I-118)+(II-3),(I-118)+(II-4),(I-118)+(II-5),(I-118)+(II-6),(I-118)+(II-9),(I-118)+(II-12),(I-118)+(III-1),(I-118)+(III-4),(I-118)+(III-10),(I-118)+(III-11),(I-118)+(IV-1),(I-118)+(IV-2),(I-118)+(IV-3),(I-118)+(IV-4),(I-118)+(IV-5),(I-118)+(b-1),(I-118)+(b-2),(I-118)+(b-3),(I-118)+(b-4),(I-118)+(b-5),(I-118)+(b-6),(I-118)+(b-7),(I-118)+(b-8),(I-118)+(b-9),(I-118)+(b-10),(I-118)+(b-11),(I-118)+(b-12),(I-118)+(b-13),(I-118)+(b-14),(I-118)+(S3-1),(I-118)+(S3-2),(I-118)+(S3-3),(I-118)+(S3-4),(I-118)+(S3-5),(I-118)+(h-1),(I-118)+(h-2),(I-118)+(V-1),(I-118)+(V-2),(I-118)+(V-3),(I-118)+(V-4),(I-118)+(V-5),(I-118)+(V-6).
(I-119)+(II-0),(I-119)+(II-1),(I-119)+(II-2),(I-119)+(II-3),(I-119)+(II-4),(I-119)+(II-5),(I-119)+(II-6),(I-119)+(II-9),(I-119)+(II-12),(I-119)+(III-1),(I-119)+(III-4),(I-119)+(III-10),(I-119)+(III-11),(I-119)+(IV-1),(I-119)+(IV-2),(I-119)+(IV-3),(I-119)+(IV-4),(I-119)+(IV-5),(I-119)+(b-1),(I-119)+(b-2),(I-119)+(b-3),(I-119)+(b-4),(I-119)+(b-5),(I-119)+(b-6),(I-119)+(b-7),(I-119)+(b-8),(I-119)+(b-9),(I-119)+(b-10),(I-119)+(b-11),(I-119)+(b-12),(I-119)+(b-13),(I-119)+(b-14),(I-119)+(S3-1),(I-119)+(S3-2),(I-119)+(S3-3),(I-119)+(S3-4),(I-119)+(S3-5),(I-119)+(h-1),(I-119)+(h-2),(I-119)+(V-1),(I-119)+(V-2),(I-119)+(V-3),(I-119)+(V-4),(I-119)+(V-5),(I-119)+(V-6).
(I-120)+(II-0),(I-120)+(II-1),(I-120)+(II-2),(I-120)+(II-3),(I-120)+(II-4),(I-120)+(II-5),(I-120)+(II-6),(I-120)+(II-9),(I-120)+(II-12),(I-120)+(III-1),(I-120)+(III-4),(I-120)+(III-10),(I-120)+(III-11),(I-120)+(IV-1),(I-120)+(IV-2),(I-120)+(IV-3),(I-120)+(IV-4),(I-120)+(IV-5),(I-120)+(b-1),(I-120)+(b-2),(I-120)+(b-3),(I-120)+(b-4),(I-120)+(b-5),(I-120)+(b-6),(I-120)+(b-7),(I-120)+(b-8),(I-120)+(b-9),(I-120)+(b-10),(I-120)+(b-11),(I-120)+(b-12),(I-120)+(b-13),(I-120)+(b-14),(I-120)+(S3-1),(I-120)+(S3-2),(I-120)+(S3-3),(I-120)+(S3-4),(I-120)+(S3-5),(I-120)+(h-1),(I-120)+(h-2),(I-120)+(V-1),(I-120)+(V-2),(I-120)+(V-3),(I-120)+(V-4),(I-120)+(V-5),(I-120)+(V-6).
(I-121)+(II-0),(I-121)+(II-1),(I-121)+(II-2),(I-121)+(II-3),(I-121)+(II-4),(I-121)+(II-5),(I-121)+(II-6),(I-121)+(II-9),(I-121)+(II-12),(I-121)+(III-1),(I-121)+(III-4),(I-121)+(III-10),(I-121)+(III-11),(I-121)+(IV-1),(I-121)+(IV-2),(I-121)+(IV-3),(I-121)+(IV-4),(I-121)+(IV-5),(I-121)+(b-1),(I-121)+(b-2),(I-121)+(b-3),(I-121)+(b-4),(I-121)+(b-5),(I-121)+(b-6),(I-121)+(b-7),(I-121)+(b-8),(I-121)+(b-9),(I-121)+(b-10),(I-121)+(b-11),(I-121)+(b-12),(I-121)+(b-13),(I-121)+(b-14),(I-121)+(S3-1),(I-121)+(S3-2),(I-121)+(S3-3),(I-121)+(S3-4),(I-121)+(S3-5),(I-121)+(h-1),(I-121)+(h-2),(I-121)+(V-1),(I-121)+(V-2),(I-121)+(V-3),(I-121)+(V-4),(I-121)+(V-5),(I-121)+(V-6).
(I-122)+(II-0),(I-122)+(II-1),(I-122)+(II-2),(I-122)+(II-3),(I-122)+(II-4),(I-122)+(II-5),(I-122)+(II-6),(I-122)+(II-9),(I-122)+(II-12),(I-122)+(III-1),(I-122)+(III-4),(I-122)+(III-10),(I-122)+(III-11),(I-122)+(IV-1),(I-122)+(IV-2),(I-122)+(IV-3),(I-122)+(IV-4),(I-122)+(IV-5),(I-122)+(b-1),(I-122)+(b-2),(I-122)+(b-3),(I-122)+(b-4),(I-122)+(b-5),(I-122)+(b-6),(I-122)+(b-7),(I-122)+(b-8),(I-122)+(b-9),(I-122)+(b-10),(I-122)+(b-11),(I-122)+(b-12),(I-122)+(b-13),(I-122)+(b-14),(I-122)+(S3-1),(I-122)+(S3-2),(I-22)+(S3-3),(I-122)+(S3-4),(I-122)+(S3-5),(I-122)+(h-1),(I-122)+(h-2),(I-122)+(V-1),(I-122)+(V-2),(I-122)+(V-3),(I-122)+(V-4),(I-122)+(V-5),(I-122)+(V-6).
(I-123)+(II-0),(I-123)+(II-1),(I-123)+(II-2),(I-123)+(II-3),(I-123)+(II-4),(I-123)+(II-5),(I-123)+(II-6),(I-123)+(II-9),(I-123)+(II-12),(I-123)+(III-1),(I-123)+(III-4),(I-123)+(III-10),(I-123)+(III-11),(I-123)+(IV-1),(I-123)+(IV-2),(I-123)+(IV-3),(I-123)+(IV-4),(I-123)+(IV-5),(I-123)+(b-1),(I-123)+(b-2),(I-123)+(b-3),(I-123)+(b-4),(I-123)+(b-5),(I-123)+(b-6),(I-123)+(b-7),(I-123)+(b-8),(I-123)+(b-9),(I-123)+(b-10),(I-123)+(b-11),(I-123)+(b-12),(I-123)+(b-13),(I-123)+(b-14),(I-123)+(S3-1),(I-123)+(S3-2),(I-123)+(S3-3),(I-123)+(S3-4),(I-123)+(S3-5),(I-123)+(h-1),(I-123)+(h-2),(I-123)+(V-1),(I-123)+(V-2),(I-123)+(V-3),(I-123)+(V-4),(I-123)+(V-5),(I-123)+(V-6).
(I-124)+(II-0),(I-124)+(II-1),(I-124)+(II-2),(I-124)+(II-3),(I-124)+(II-4),(I-124)+(II-5),(I-124)+(II-6),(I-124)+(II-9),(I-124)+(II-12),(I-124)+(III-1),(I-124)+(III-4),(I-124)+(III-10),(I-124)+(III-11),(I-124)+(IV-1),(I-124)+(IV-2),(I-124)+(IV-3),(I-124)+(IV-4),(I-124)+(IV-5),(I-124)+(b-1),(I-124)+(b-2),(I-124)+(b-3),(I-124)+(b-4),(I-124)+(b-5),(I-124)+(b-6),(I-124)+(b-7),(I-124)+(b-8),(I-124)+(b-9),(I-124)+(b-10),(I-124)+(b-11),(I-124)+(b-12),(I-124)+(b-13),(I-124)+(b-14),(I-124)+(S3-1),(I-124)+(S3-2),(I-124)+(S3-3),(I-124)+(S3-4),(I-124)+(S3-5),(I-124)+(h-1),(I-124)+(h-2),(I-124)+(V-1),(I-124)+(V-2),(I-124)+(V-3),(I-124)+(V-4),(I-124)+(V-5),(I-124)+(V-6).
(I-125)+(II-0),(I-125)+(II-1),(I-125)+(II-2),(I-125)+(II-3),(I-125)+(II-4),(I-125)+(II-5),(I-125)+(II-6),(I-125)+(II-9),(I-125)+(II-12),(I-125)+(III-1),(I-125)+(III-4),(I-125)+(III-10),(I-125)+(III-11),(I-125)+(IV-1),(I-125)+(IV-2),(I-125)+(IV-3),(I-125)+(IV-4),(I-125)+(IV-5),(I-125)+(b-1),(I-125)+(b-2),(I-125)+(b-3),(I-125)+(b-4),(I-125)+(b-5),(I-125)+(b-6),(I-125)+(b-7),(I-125)+(b-8),(I-125)+(b-9),(I-125)+(b-10),(I-125)+(b-11),(I-125)+(b-12),(I-125)+(b-13),(I-125)+(b-14),(I-125)+(S3-1),(I-125)+(S3-2),(I-125)+(S3-3),(I-125)+(S3-4),(I-125)+(S3-5),(I-125)+(h-1),(I-125)+(h-2),(I-125)+(V-1),(I-125)+(V-2),(I-125)+(V-3),(I-125)+(V-4),(I-125)+(V-5),(I-125)+(V-6).
(I-126)+(II-0),(I-126)+(II-1),(I-126)+(II-2),(I-126)+(II-3),(I-126)+(II-4),(I-126)+(II-5),(I-126)+(II-6),(I-126)+(II-9),(I-126)+(II-12),(I-126)+(III-1),(I-126)+(III-4),(I-126)+(III-10),(I-126)+(III-11),(I-126)+(IV-1),(I-126)+(IV-2),(I-126)+(IV-3),(I-126)+(IV-4),(I-126)+(IV-5),(I-126)+(b-1),(I-126)+(b-2),(I-126)+(b-3),(I-126)+(b-4),(I-126)+(b-5),(I-126)+(b-6),(I-126)+(b-7),(I-126)+(b-8),(I-126)+(b-9),(I-126)+(b-10),(I-126)+(b-11),(I-126)+(b-12),(I-126)+(b-13),(I-126)+(b-14),(I-126)+(S3-1),(I-126)+(S3-2),(I-126)+(S3-3),(I-126)+(S3-4),(I-126)+(S3-5),(I-126)+(h-1),(I-126)+(h-2),(I-126)+(V-1),(I-126)+(V-2),(I-126)+(V-3),(I-126)+(V-4),(I-126)+(V-5),(I-126)+(V-6).
(I-127)+(II-0),(I-127)+(II-1),(I-127)+(II-2),(I-127)+(II-3),(I-127)+(II-4),(I-127)+(II-5),(I-127)+(II-6),(I-127)+(II-9),(I-127)+(II-12),(I-127)+(III-1),(I-127)+(III-4),(I-127)+(III-10),(I-127)+(III-11),(I-127)+(IV-1),(I-127)+(IV-2),(I-127)+(IV-3),(I-127)+(IV-4),(I-127)+(IV-5),(I-127)+(b-1),(I-127)+(b-2),(I-127)+(b-3),(I-127)+(b-4),(I-127)+(b-5),(I-127)+(b-6),(I-127)+(b-7),(I-127)+(b-8),(I-127)+(b-9),(I-127)+(b-10),(I-127)+(b-11),(I-127)+(b-12),(I-127)+(b-13),(I-127)+(b-14),(I-127)+(S3-1),(I-127)+(S3-2),(I-127)+(S3-3),(I-127)+(S3-4),(I-127)+(S3-5),(I-127)+(h-1),(I-127)+(h-2),(I-127)+(V-1),(I-127)+(V-2),(I-127)+(V-3),(I-127)+(V-4),(I-127)+(V-5),(I-127)+(V-6).
(I-128)+(11-0),(I-128)+(11-1),(I-128)+(II-2),(I-128)+(II-3),(I-128)+(II-4),(I-128)+(II-5),(I-128)+(II-6),(I-128)+(II-9),(I-128)+(II-12),(I-128)+(III-1),(I-128)+(III-4),(I-128)+(III-10),(I-128)+(III-11),(I-128)+(IV-1),(I-128)+(IV-2),(I-128)+(IV-3),(I-128)+(IV-4),(I-128)+(IV-5),(I-128)+(b-1),(I-128)+(b-2),(I-128)+(b-3),(I-128)+(b-4),(I-128)+(b-5),(I-128)+(b-6),(I-128)+(b-7),(I-128)+(b-8),(I-128)+(b-9),(I-128)+(b-10),(I-128)+(b-11),(I-128)+(b-12),(I-128)+(b-13),(I-128)+(b-14),(I-128)+(S3-1),(I-128)+(S3-2),(I-128)+(S3-3),(I-128)+(S3-4),(I-128)+(S3-5),(I-128)+(h-1),(I-128)+(h-2),(I-128)+(V-1),(I-128)+(V-2),(I-128)+(V-3),(I-128)+(V-4),(I-128)+(V-5),(I-128)+(V-6).
(I-129)+(II-0),(I-129)+(II-1),(I-129)+(II-2),(I-129)+(II-3),(I-129)+(II-4),(I-129)+(II-5),(I-129)+(II-6),(I-129)+(II-9),(I-129)+(II-12),(I-129)+(III-1),(I-129)+(III-4),(I-129)+(III-10),(I-129)+(III-11),(I-129)+(IV-1),(I-129)+(IV-2),(I-129)+(IV-3),(I-129)+(IV-4),(I-129)+(IV-5),(I-129)+(b-1),(I-129)+(b-2),(I-129)+(b-3),(I-129)+(b-4),(I-129)+(b-5),(I-129)+(b-6),(I-129)+(b-7),(I-129)+(b-8),(I-129)+(b-9),(I-129)+(b-10),(I-129)+(b-11),(I-129)+(b-12),(I-129)+(b-13),(I-129)+(b-14),(I-129)+(S3-1),(I-129)+(S3-2),(I-129)+(S3-3),(I-129)+(S3-4),(I-129)+(S3-5),(I-129)+(h-1),(I-129)+(h-2),(I-129)+(V-1),(I-129)+(V-2),(I-129)+(V-3),(I-129)+(V-4),(I-129)+(V-5),(I-129)+(V-6).
(I-130)+(II-0),(I-130)+(II-1),(I-130)+(II-2),(I-130)+(II-3),(I-130)+(II-4),(I-130)+(II-5),(I-130)+(II-6),(I-130)+(II-9),(I-130)+(II-12),(I-130)+(III-1),(I-130)+(III-4),(I-130)+(III-10),(I-130)+(III-11),(I-130)+(IV-1),(I-130)+(IV-2),(I-130)+(IV-3),(I-130)+(IV-4),(I-130)+(IV-5),(I-130)+(b-1),(I-130)+(b-2),(I-130)+(b-3),(I-130)+(b-4),(I-130)+(b-5),(I-130)+(b-6),(I-130)+(b-7),(I-130)+(b-8),(I-130)+(b-9),(I-130)+(b-10),(I-130)+(b-11),(I-130)+(b-12),(I-130)+(b-13),(I-130)+(b-14),(I-130)+(S3-1),(I-130)+(S3-2),(I-130)+(S3-3),(I-130)+(S3-4),(I-130)+(S3-5),(I-130)+(h-1),(I-130)+(h-2),(I-130)+(V-1),(I-130)+(V-2),(I-130)+(V-3),(I-130)+(V-4),(I-130)+(V-5),(I-130)+(V-6).
(I-131)+(II-0),(I-131)+(II-1),(I-131)+(II-2),(I-131)+(II-3),(I-131)+(II-4),(I-131)+(II-5),(I-131)+(II-6),(I-131)+(II-9),(I-131)+(II-12),(I-131)+(III-1),(I-131)+(III-4),(I-131)+(III-10),(I-131)+(III-11),(I-131)+(IV-1),(I-131)+(IV-2),(I-131)+(IV-3),(I-131)+(IV-4),(I-131)+(IV-5),(I-131)+(b-1),(I-131)+(b-2),(I-131)+(b-3),(I-131)+(b-4),(I-131)+(b-5),(I-131)+(b-6),(I-131)+(b-7),(I-131)+(b-8),(I-131)+(b-9),(I-131)+(b-10),(I-131)+(b-11),(I-131)+(b-12),(I-131)+(b-13),(I-131)+(b-14),(I-131)+(S3-1),(I-131)+(S3-2),(I-131)+(S3-3),(I-131)+(S3-4),(I-131)+(S3-5),(I-131)+(h-1),(I-131)+(h-2),(I-131)+(V-1),(I-131)+(V-2),(I-131)+(V-3),(I-131)+(V-4),(I-131)+(V-5),(I-131)+(V-6).
(I-132)+(II-0),(I-132)+(II-1),(I-132)+(II-2),(I-132)+(II-3),(I-132)+(II-4),(I-132)+(II-5),(I-132)+(II-6),(I-132)+(II-9),(I-132)+(II-12),(I-132)+(III-1),(I-132)+(III-4),(I-132)+(III-10),(I-132)+(III-11),(I-132)+(IV-1),(I-132)+(IV-2),(I-132)+(IV-3),(I-132)+(IV-4),(I-132)+(IV-5),(I-132)+(b-1),(I-132)+(b-2),(I-132)+(b-3),(I-132)+(b-4),(I-132)+(b-5),(I-132)+(b-6),(I-132)+(b-7),(I-132)+(b-8),(I-132)+(b-9),(I-132)+(b-10),(I-132)+(b-11),(I-132)+(b-12),(I-132)+(b-13),(I-132)+(b-14),(I-132)+(S3-1),(I-132)+(S3-2),(I-132)+(S3-3),(I-132)+(S3-4),(I-132)+(S3-5),(I-132)+(h-1),(I-132)+(h-2),(I-132)+(V-1),(I-132)+(V-2),(I-132)+(V-3),(I-132)+(V-4),(I-132)+(V-5),(I-132)+(V-6).
(I-133)+(II-0),(I-133)+(II-1),(I-133)+(II-2),(I-133)+(II-3),(I-133)+(II-4),(I-133)+(II-5),(I-133)+(II-6),(I-133)+(II-9),(I-133)+(II-12),(I-133)+(III-1),(I-133)+(III-4),(I-133)+(III-10),(I-133)+(III-11),(I-133)+(IV-1),(I-133)+(IV-2),(I-133)+(IV-3),(I-133)+(IV-4),(I-133)+(IV-5),(I-133)+(b-1),(I-133)+(b-2),(I-133)+(b-3),(I-133)+(b-4,(I-133)+(b-5),(I-133)+(b-6),(I-133)+(b-7),(I-133)+(b-8),(I-133)+(b-9),(I-133)+(b-10),(I-133)+(b-11),(I-133)+(b-12),(I-133)+(b-13),(I-133)+(b-14),(I-133)+(S3-1),(I-133)+(S3-2),(I-133)+(S3-3),(I-133)+(S3-4),(I-133)+(S3-5),(I-133)+(h-1),(I-133)+(h-2),(I-133)+(V-1),(I-133)+(V-2),(I-133)+(V-3),(I-133)+(V-4),(I-133)+(V-5),(I-133)+(V-6).
(I-134)+(II-0),(I-134)+(II-1),(I-134)+(II-2),(I-134)+(II-3),(I-134)+(II-4),(I-134)+(II-5),(I-134)+(II-6),(I-134)+(II-9),(I-134)+(II-12),(I-134)+(III-1),(I-134)+(III-4),(I-134)+(III-10),(I-134)+(III-11),(I-134)+(IV-1),(I-134)+(IV-2),(I-134)+(IV-3),(I-134)+(IV-4),(I-134)+(IV-5),(I-134)+(b-1),(I-134)+(b-2),(I-134)+(b-3),(I-134)+(b-4),(I-134)+(b-5),(I-134)+(b-6),(I-134)+(b-7),(I-134)+(b-8),(I-134)+(b-9),(I-134)+(b-10),(I-134)+(b-11),(I-134)+(b-12),(I-134)+(b-13),(I-134)+(b-14),(I-134)+(S3-1),(I-134)+(S3-2),(I-134)+(S3-3),(I-134)+(S3-4),(I-134)+(S3-5),(I-134)+(h-1),(I-134)+(h-2),(I-134)+(V-1),(I-134)+(V-2),(I-134)+(V-3),(I-134)+(V-4),(I-134)+(V-5),(I-134)+(V-6).
(I-135)+(II-0),(I-135)+(II-1),(I-135)+(II-2),(I-135)+(II-3),(I-135)+(II-4),(I-135)+(II-5),(I-135)+(II-6),(I-135)+(II-9),(I-135)+(II-12),(I-135)+(III-1),(I-135)+(III-4),(I-135)+(III-10),(I-135)+(III-11),(I-135)+(IV-1),(I-135)+(IV-2),(I-135)+(IV-3),(I-135)+(IV-4),(I-135)+(IV-5),(I-135)+(b-1),(I-135)+(b-2),(I-135)+(b-3),(I-135)+(b-4),(I-135)+(b-5),(I-135)+(b-6),(I-135)+(b-7),(I-135)+(b-8),(I-135)+(b-9),(I-135)+(b-10),(I-135)+(b-11),(I-135)+(b-12),(I-135)+(b-13),(I-135)+(b-14),(I-135)+(S3-1),(I-135)+(S3-2),(I-135)+(S3-3),(I-135)+(S3-4),(I-135)+(S3-5),(I-135)+(h-1),(I-135)+(h-2),(I-135)+(V-1),(I-135)+(V-2),(I-135)+(V-3),(I-135)+(V-4),(I-135)+(V-5),(I-135)+(V-6).
(I-136)+(II-0),(I-136)+(II-1),(I-136)+(II-2),(I-136)+(II-3),(I-136)+(II-4),(I-136)+(II-5),(I-136)+(II-6),(I-136)+(II-9),(I-136)+(II-12),(I-136)+(III-1),(I-136)+(III-4),(I-136)+(III-10),(I-136)+(III-11),(I-136)+(IV-1),(I-136)+(IV-2),(I-136)+(IV-3),(I-136)+(IV-4),(I-136)+(IV-5),(I-136)+(b-1),(I-136)+(b-2),(I-136)+(b-3),(I-136)+(b-4),(I-136)+(b-5),(I-136)+(b-6),(I-136)+(b-7),(I-136)+(b-8),(I-136)+(b-9),(I-136)+(b-10),(I-136)+(b-11),(I-136)+(b-12),(I-136)+(b-13),(I-136)+(b-14),(I-136)+(S3-1),(I-136)+(S3-2),(I-136)+(S3-3),(I-136)+(S3-4),(I-136)+(S3-5),(I-136)+(h-1),(I-136)+(h-2),(I-136)+(V-1),(I-136)+(V-2),(I-136)+(V-3),(I-136)+(V-4),(I-136)+(V-5),(I-136)+(V-6).
(I-137)+(II-0),(I-137)+(II-1),(I-137)+(II-2),(I-137)+(II-3),(I-137)+(II-4),(I-137)+(II-5),(I-137)+(II-6),(I-137)+(II-9),(I-137)+(II-12),(I-137)+(III-1),(I-137)+(III-4),(I-137)+(III-10),(I-137)+(III-11),(I-137)+(IV-1),(I-137)+(IV-2),(I-137)+(IV-3),(I-137)+(IV-4),(I-137)+(IV-5),(I-137)+(b-1),(I-137)+(b-2),(I-137)+(b-3),(I-137)+(b-4),(I-137)+(b-5),(I-137)+(b-6),(I-137)+(b-7),(I-137)+(b-8),(I-137)+(b-9),(I-137)+(b-10),(I-137)+(b-11),(I-137)+(b-12),(I-137)+(b-13),(I-137)+(b-14),(I-137)+(S3-1),(I-137)+(S3-2),(I-137)+(S3-3),(I-137)+(S3-4),(I-137)+(S3-5),(I-137)+(h-1),(I-137)+(h-2),(I-137)+(V-1),(I-137)+(V-2),(I-137)+(V-3),(I-137)+(V-4),(I-137)+(V-5),(I-137)+(V-6).
(I-138)+(II-0),(I-138)+(II-1),(I-138)+(II-2),(I-138)+(II-3),(I-138)+(II-4),(I-138)+(II-5),(I-138)+(II-6),(I-138)+(II-9),(I-138)+(II-12),(I-138)+(III-1),(I-138)+(III-4),(I-138)+(III-10),(I-138)+(III-11),(I-138)+(IV-1),(I-138)+(IV-2),(I-138)+(IV-3),(I-138)+(IV-4),(I-138)+(IV-5),(I-138)+(b-1),(I-138)+(b-2),(I-138)+(b-3),(I-138)+(b-4),(I-138)+(b-5),(I-138)+(b-6),(I-138)+(b-7),(I-138)+(b-8),(I-138)+(b-9),(I-138)+(b-10),(I-138)+(b-11),(I-138)+(b-12),(I-138)+(b-13),(I-138)+(b-14),(I-138)+(S3-1),(I-138)+(S3-2),(I-138)+(S3-3),(I-138)+(S3-4),(I-138)+(S3-5),(I-138)+(h-1),(I-138)+(h-2),(I-138)+(V-1),(I-138)+(V-2),(I-138)+(V-3),(I-138)+(V-4),(I-138)+(V-5),(I-138)+(V-6).
(I-139)+(II-0),(I-139)+(II-1),(I-139)+(II-2),(I-139)+(II-3),(I-139)+(II-4),(I-139)+(II-5),(I-139)+(II-6),(I-139)+(II-9),(I-139)+(II-12),(I-139)+(III-1),(I-139)+(III-4),(I-139)+(III-10),(I-139)+(III-11),(I-139)+(IV-1),(I-139)+(IV-2),(I-139)+(IV-3),(I-139)+(IV-4),(I-139)+(IV-5),(I-139)+(b-1),(I-139)+(b-2),(I-139)+(b-3),(I-139)+(b-4),(I-139)+(b-5),(I-139)+(b-6),(I-139)+(b-7),(I-139)+(b-8),(I-139)+(b-9),(I-139)+(b-10),(I-139)+(b-11),(I-139)+(b-12),(I-139)+(b-13),(I-139)+(b-4),(I-139)+(S3-1),(I-139)+(S-2),(I-139)+(S3-3),(I-139)+(S3-4),(I-139)+(S3-5),(I-139)+(h-1),(I-139)+(h-2),(I-139)+(V-1),(I-139)+(V-2),(I-139)+(V-3),(I-139)+(V-4),(I-139)+(V-5),(I-139)+(V-6).
(I-140)+(II-0),(I-140)+(II-1),(I-140)+(II-2),(I-140)+(II-3),(I-140)+(II-4),(I-140)+(II-5),(I-140)+(II-6),(I-140)+(II-9),(I-140)+(II-12),(I-140)+(III-1),(I-140)+(III-4),(I-140)+(III-10),(I-140)+(III-11),(I-140)+(IV-1),(I-140)+(IV-2),(I-140)+(IV-3),(I-140)+(IV-4),(I-140)+(IV-5),(I-140)+(b-1),(I-140)+(b-2),(I-140)+(b-3),(I-140)+(b-4),(I-140)+(b-5),(I-140)+(b-6),(I-140)+(b-7),(I-140)+(b-8),(I-140)+(b-9),(I-140)+(b-10),(I-140)+(b-11),(I-140)+(b-12),(I-140)+(b-13),(I-140)+(b-14),(I-140)+(S3-1),(I-140)+(S3-2),(I-140)+(S3-3),(I-140)+(S3-4),(I-140)+(S3-5),(I-140)+(h-1),(I-140)+(h-2),(I-140)+(V-1),(I-140)+(V-2),(I-140)+(V-3),(I-140)+(V-4),(I-140)+(V-5),(I-140)+(V-6).
(I-141)+(II-0),(I-141)+(II-1),(I-141)+(II-2),(I-141)+(II-3),(I-141)+(II-4),(I-141)+(II-5),(I-141)+(II-6),(I-141)+(II-9),(I-141)+(II-12),(I-141)+(III-1),(I-141)+(III-4),(I-141)+(III-10),(I-141)+(III-11),(I-141)+(IV-1),(I-141)+(IV-2),(I-141)+(IV-3),(I-141)+(IV-4),(I-141)+(IV-5),(I-141)+(b-1),(I-141)+(b-2),(I-141)+(b-3),(I-141)+(b-4),(I-141)+(b-5),(I-141)+(b-6),(I-141)+(b-7),(I-141)+(b-8),(I-141)+(b-9),(I-141)+(b-10),(I-141)+(b-11),(I-141)+(b-12),(I-141)+(b-13),(I-141)+(b-14),(I-141)+(S3-1),(I-141)+(S3-2),(I-141)+(S3-3),(I-141)+(S3-4),(I-141)+(S3-5),(I-141)+(h-1),(I-141)+(h-2),(I-141)+(V-1),(I-141)+(V-2),(I-141)+(V-3),(I-141)+(V-4),(I-141)+(V-5),(I-141)+(V-6).
(I-142)+(II-0),(I-142)+(II-1),(I-142)+(II-2),(I-142)+(II-3),(I-142)+(II-4),(I-142)+(II-5),(I-142)+(II-6),(I-142)+(II-9),(I-142)+(II-12),(I-142)+(III-1),(I-142)+(III-4),(I-142)+(III-10),(I-142)+(III-11),(I-142)+(IV-1),(I-142)+(IV-2),(I-142)+(IV-3),(I-142)+(IV-4),(I-142)+(IV-5),(I-142)+(b-1),(I-142)+(b-2),(I-142)+(b-3),(I-142)+(b-4),(I-142)+(b-5),(I-142)+(b-6),(I-142)+(b-7),(I-142)+(b-8),(I-142)+(b-9),(I-142)+(b-10),(I-142)+(b-11),(I-142)+(b-12),(I-142)+(b-13),(I-142)+(b-14),(I-142)+(S3-1),(I-142)+(S3-2),(I-142)+(S3-3),(I-142)+(S3-4),(I-142)+(S3-5),(I-142)+(h-1),(I-142)+(h-2),(I-142)+(V-1),(I-142)+(V-2),(I-142)+(V-3),(I-142)+(V-4),(I-142)+(V-5),(I-142)+(V-6).
(I-143)+(II-0),(I-143)+(II-1),(I-143)+(II-2),(I-143)+(II-3),(I-143)+(II-4),(I-143)+(II-5),(I-143)+(II-6),(I-143)+(II-9),(I-143)+(II-12),(I-143)+(III-1),(I-143)+(III-4),(I-143)+(III-10),(I-143)+(III-11),(I-143)+(IV-1),(I-143)+(IV-2),(I-143)+(IV-3),(I-143)+(IV-4),(I-143)+(IV-5),(I-143)+(b-1),(I-143)+(b-2),(I-143)+(b-3),(I-143)+(b-4),(I-143)+(b-5),(I-143)+(b-6),(I-143)+(b-7),(I-143)+(b-8),(I-143)+(b-9),(I-143)+(b-10),(I-143)+(b-11),(I-143)+(b-12),(I-143)+(b-13),(I-143)+(b-14),(I-143)+(S3-1),(I-143)+(S3-2),(I-143)+(S3-3),(I-143)+(S3-4),(I-143)+(S3-5),(I-143)+(h-1),(I-143)+(h-2),(I-143)+(V-1),(I-143)+(V-2),(I-143)+(V-3)(I-143)+(V-4),(I-143)+(V-5),(I-143)+(V-6).
(I-144)+(II-0),(I-144)+(II-1),(I-144)+(II-2),(I-144)+(II-3),(I-144)+(II-4),(I-144)+(II-5),(I-144)+(II-6),(I-144)+(II-9),(I-144)+(II-12),(I-144)+(III-1),(I-144)+(III-4),(I-144)+(III-10),(I-144)+(III-11),(I-144)+(IV-1),(I-144)+(IV-2),(I-144)+(IV-3),(I-144)+(IV-4),(I-144)+(IV-5),(I-144)+(b-1),(I-144)+(b-2),(I-144)+(b-3),(I-144)+(b-4),(I-144)+(b-5),(I-144)+(b-6),(I-144)+(b-7),(I-144)+(b-8),(I-144)+(b-9),(I-144)+(b-10),(I-144)+(b-11),(I-144)+(b-12),(I-144)+(b-13),(I-144)+(b-14),(I-144)+(S3-1),(I-144)+(S3-2),(I-144)+(S3-3),(I-144)+(S3-4),(I-144)+(S3-5),(I-144)+(h-1),(I-144)+(h-2),(I-144)+(V-1),(I-144)+(IV-2),(I-144)+(V-3),(I-144)+(V-4),(I-144)+(V-5),(I-144)+(V-6).
(I-145)+(II-0),(I-145)+(II-1),(I-145)+(II-2),(I-145)+(II-3),(I-145)+(II-4),(I-145)+(II-5),(I-145)+(II-6),(I-145)+(II-9),(I-145)+(II-12),(I-145)+(III-1),(I-145)+(II-4),(I-145)+(III-10),(I-145)+(III-11),(I-145)+(IV-1),(I-145)+(IV-2),(I-145)+(IV-3),(I-145)+(IV-4),(I-145)+(IV-5),(I-145)+(b-1),(I-145)+(b-2),(I-145)+(b-3),(I-145)+(b-4),(I-145)+(b-5),(I-145)+(b-6),(I-145)+(b-7),(I-145)+(b-8),(I-145)+(b-9),(I-145)+(b-10),(I-145)+(b-11),(I-145)+(b-12),(I-145)+(b-13),(I-145)+(b-14),(I-145)+(S3-1),(I-145)+(S3-2),(I-145)+(S3-3),(I-145)+(S3-4),(I-145)+(S3-5),(I-145)+(h-1),(I-145)+(h-2),(I-145)+(V-1),(I-145)+(V-2),(I-145)+(V-3),(I-145)+(V-4),(I-145)+(V-5),(I-145)+(V-6).
The safener (antipoison) of formula (II)-(VIII) and group (B) compound (b), for example preferably organize a) to h) safener be applicable to reduction when the phytotoxicity effect that weed killer herbicide (A) can be produced when being used for useful crop, but its activity of weeding active compound to the control noxious plant does not have considerable influence.According to its character, it can expand significantly to the field of using of conventional plant protection composition, for example is applied to and can not uses weed killer herbicide or the limited extent crop of using only up to now.
According to indication and employed weeding active compound, the amount of application of required safener can change in relative broad range, and normal ranges is 0.001 to 5kg, is preferably reactive compound/hectare of 0.005 to 2.5kg.
Weeding active compound (A) and safener (B) can pass through for example atomizing, injection or spraying, or use (for example with finished product preparation or bucket mixing method) by broadcasting sowing particle together or successively use with any desired sequence.Weed killer herbicide (A): the weight ratio of safener (B) can change in relative broad range, and preferable range is 1: 10000 to 10000: 1, is preferably 1: 1000 to 1000: 1.Under concrete situation, the type that the optimised quantity of weed killer herbicide and safener depends on the weed killer herbicide that uses with safe in utilization dose type, and the character of pending vegetable material and developmental stage, it can be measured respectively by simple conventional preliminary experiment.
According to its character, the safener (B) that is included in the herbicide-safener combination of the present invention can be used for preliminary treatment crop seed (utilization is used for seed dressing) or introduce the seed ditch dug with a plow prior to seeding, or uses with weed killer herbicide before seedling or behind the seedling.The seedling pre-treatment not only is included in sowing pre-treatment planting area (optionally include the planting area that water exists, for example paddy rice is used), and comprises the soil of having sowed of handling no seedlings.It is preferred using with weed killer herbicide.To this, can use mixed thing of bucket or finished product preparation.
In preferred embodiment, with safener (B), optionally with combined preliminary treatment seed of other agricultural chemical activity compound (such as grain, seed or plant propagation organ for example have the stem tuber or the branch part of bud) or seedling.For the preliminary treatment seed, reactive compound can for example be applied to seed by seed dressing, or reactive compound and seed can introduce in the water or other solvent, and forms or with the impregnation method expanding by complex compound, or by swelling or germination treatment, reactive compound can be absorbed.For the preliminary treatment seedling, for example by spraying, flood or watering, young plant and safener optionally can be contacted with other agricultural chemical activity compound compositions, and transplant and optionally use weed killer herbicide (A) to carry out the seedling post processing subsequently.
Can utilize independent safener (B) or with other agricultural chemical activity compound, for example weed killer herbicide especially weed killer herbicide (A), fungicide, insecticide or fortification of plants as fertilising or promote to expand and the reagent of germination treatment comes together to handle seed or seedling.In this article, after preliminary treatment is used, can use safener before, afterwards or together once more at weed killer herbicide (A).By preliminary treatment seed or seedling, can obtain safener long term preferably.
Therefore, the present invention also provides a kind of method that crop is not expected plant that is used for controlling, this method comprise with herbicide-safener combination of the present invention component (A) and (B) for example be applied to plant (noxious plant for example in the lump or respectively, for example unifacial leaf or broadleaf weed or the crop do not expected), seed (such as grain, seed or plant propagation material, the stem tuber or the branch part that for example have bud), or be applied to plant growing zone (for example cultural area).In this article, can be before, afterwards or simultaneously at weed killer herbicide (A), with one or more safeners (B), preferably one or more, especially a kind of formula (II), (III), (IV), (V), (VI), (VII), (VIII) and/or from the group B (b) compound administration to plant, its seed or plant growing zone (for example cultural area).In preferred embodiment, safener (B) is used to handle seed.
The plant of not expecting is interpreted as referring to be grown in all plants of not expecting the place.It can be for example noxious plant (for example unifacial leaf or broadleaf weed or the crop do not expected), for example comprises that for example glyphosate, atrazine, careless ammonium phosphine or imidazolidinone weedicide have the plant of resistance to some weeding active compound.
Monocotyledon weed is for for example: Echinochloa (Echinochloa), setaria (Setaria), Panicum (Panicum), knotgrass (Digitaria), ladder forage spp (Phleum), annual bluegrass belongs to (Poa), Festuca (Festuca), eleusine indica belongs to (Eleusine), Brachiaria (Brachiaria), Lolium (Lollum), Brome (Bromus), Avena (Avena), Cyperus (Cyperus), jowar belongs to (Sorghum), Agropyron (Agropyron), Cynodon (Cynodon), Monochoria (Monochoria), genus fimbristylis (Fimbristylls), arrowhead belongs to (Sagittaria), Eleocharis (Eleocharis), the Fischer grass belongs to (Scirpus), Paspalum (Paspalum), ischaemum (Ischaemum), cusp Pittosporum (Sphenoclea), talon eria (Dactyloctenium), Agrostis (Agrostis), amur foxtail belongs to (Alopecurus), Ah draping over one's shoulders draws grass to belong to (Apera).
Broadleaf weed is for for example: sinapsis alba belongs to (Sinapis), Lepidium, Bedstraw (Galium), Stellaria (Stellaria), Matricaria (Matricaria), Anthemis (Anthemis), ox Teng Chrysanthemum (Galinsoga), Chenopodium (Chenopodium), Urtica (Urtica), Senecio (Senecio), Amaranthus (Amaranthus), Portulaca (Portulaca), Xanthium (Xanthium), japanese bearbind belongs to (ConvolVulus), Ipomoea (Ipomoea), Polygonum (Polygonum), the field mountain valley with clumps of trees and bamboo belongs to (Sesbania), Ambrosia (Ambrosia), Cirsium (Cirsium), bristlethistle (Carduus), sonchus (Sonchus), Solanum (Solanum) Han Lepidium (Rorippa), joint joint Lepidium (Rotala), Vandellia (Lindernia), lamium (Lamium), Veronica (Veronica), abutilon (Abutilon), thorn Rumex (Emex), Datura (Datura), Vinca (Viola), the weasel hemp nettle belongs to (Galeopsis), papaver (Papaver), bachelor's-button (Centaurea), Clover (Trifolium), Ranunculus (Ranunculus), Dandelion (Taraxacum), Euphorbia (Euphorbia).
In the method for the invention, preferably with the component (A) of effective dose with (B) be used for controlling the noxious plant of crop, the crops of Economic Importance for example, unifacial leaf crops for example, cereal (wheat for example for example, barley, rye, oat), paddy rice, corn, grain, or dicotyledonous crops such as sugar beet, rape, cotton, sunflower and beans be Glycine (Glycine max. for example for example, for example not genetically modified Glycine max. (conventional cultivation kind for example, STS cultivar for example), or transgenosis Glycine max. (for example RR-soybean or LL-soybean), and Hybrid), Phaseolus, Pisum, Vetch and Arachis, or come from different floristic vegetable crops, potato for example, leek, wild cabbage, carrot, tomato, onion, and long-term crop and kind plant, for example a kind of fruit, such as apple, pear, etc. and drupe, berry, grape, Hevea (Hevea), banana, sugarcane, coffee, tea, oranges and tangerines, nut plantation plant, the lawn, palm plantation plant and forest plantation plant.
The present invention also provides the purposes of not expecting plant that herbicide-safener combination of the present invention is used for controlling preferred crop.
Herbicide-safener combination of the present invention can make by known method, for example with single component, optionally with the mix preparation of other reactive compound, additive and/or conventional formulation auxiliary agent, to use in a usual manner behind its dilute with water subsequently, maybe will mix thing with bucket by each component that water dilutes in the lump and be prepared, it can be prepared respectively or part preparation respectively.In addition, can use each component (by stages) of preparing or partly prepare respectively respectively at different times.Can also use single component or herbicide-safener combination (order is used) with many parts, for example carry out postemergence application behind the preemergence application, or carry out behind the early stage postemergence application mid-term or late period postemergence application.The present invention preferably uses described active compound combinations in the lump or almost simultaneously.
Herbicide-safener combination of the present invention can also be used for controlling the noxious plant of gene engineering improvement plant known or still under development.Usually genetically modified plants are celebrated with particularly advantageous characteristic, for example for the protectant tolerance of specified plant, for plant disease or plant disease pathogen such as specific insect or microorganism such as fungi, bacterium or viral resistance.Other special characteristic relates to for example amount, quality, shelf time, composition and the certain content thing of harvest thing.Therefore, genetically modified plants are with the content of starch through improving or through the starch quality of improvement, or those have the harvest product that different fatty acid components or amino acid forms and are celebrated.
Preferably composition of the present invention is used for economic important useful plant and the genetically modified crops of ornamental plants, for example cereal (as wheat, barley, rye, oat), grain, paddy rice, cassava and corn, or other crop such as beet, cotton, soybean, rape, potato, tomato, pea and other plant.
When composition of the present invention is used for genetically modified crops, except the effect of common observable anti-noxious plant on other crop, also observe the certain effects that is applied on the described genetically modified crops, the controllable weeds spectrum of for example change or special expansion, the amount of application of the change that can be used for using, preferably with the good combination that the weed killer herbicide of resistance is arranged for genetically modified crops, and to the growth of genetically modified crops and the influence of output.
Therefore, the invention still further relates to and activity of weeding composition of the present invention is used for controlling genetically modified crops or owing to the purposes of the crop weeds of selecting breeding to tolerate.
Weed killer herbicide (A) and safener (B) can be together or are changed into the conventional formulation that for example is used for atomizing, waters, sprays and dresses seed and use respectively, for example solution, emulsion, suspension, pulvis, foam, paste, granule, aerosol, the native compound or the synthetic material that soak into reactive compound are with the microcapsule formulations of polymerizable compound form.Said preparation can comprise conventional auxiliary agent and additive.
Prepare these preparations with known method, for example with reactive compound and bulking agent, i.e. liquid flux, pressurized liquefied gas and/or solid carrier, optionally using surfactant is emulsifier and/or dispersant, and/or foaming agent mixes mutually.
If the bulking agent that uses is a water, then also can be with an organic solvent as cosolvent.Basically the appropriate liquid solvent is: aromatic hydrocarbons is dimethylbenzene, toluene or Fluhyzon for example, chlorinated aromatics or chlorinated aliphatic hydrocarbon such as chlorobenzene, vinyl chloride or carrene, aliphatic hydrocarbon such as cyclohexane, or paraffin such as mineral oil fractions, mineral oil and vegetable oil, alcohols such as butanols or ethylene glycol and ether thereof and ester, ketone such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone, intensive polar solvent such as dimethyl formamide and methyl-sulfoxide, or other water.
Suitable solid carrier is: for example ammonium salt and the natural mineral matter through grinding, for example kaolin, clay, talcum, chalk, quartz, Attagel, imvite or diatomite, the synthetic material through grinding, for example finely divided silica, aluminium oxide and silicate; The solid carrier that is applicable to particle is: that for example pulverize and natural rock classification such as calcite, marble, float stone, sepiolite and dolomite, or the synthetic particle of other inorganic or organic powdery, organic material particle such as sawdust, cocoa husk, corncob, shuck or tobacco rods; Examples of suitable emulsifiers and/or foaming agent are: for example nonionic and anion emulsifier such as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, for example alkylaryl polyglycol ether, alkyl sulfonic ester, alkyl sulfate, aromatic yl sulphonate or other protein hydrolysate; Suitable dispersant is: for example lignin-sulfite waste liquor and methylcellulose.
Tackifier such as carboxymethyl cellulose; and with the natural and synthetic polymer of powder, particle or latex form; for example gum Arabic, polyvinyl alcohol or polyvinyl acetate, or other natural phospholipid such as cephalin or lecithin, and synthetic phospholipid can be used in the preparation.Other additive can be mineral oil and vegetable oil.
Can use colouring agent such as inorganic pigment, for example iron oxide, titanium oxide and Prussian blue, and organic dyestuff such as alizarin dyes, azo dyes or metal phthalein cyanine dye, and micronutrient such as molysite, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.
Said preparation comprises the reactive compound between 0.1 and 95 weight % usually, preferably between 0.5 and 90 weight %.
Weed killer herbicide (A) and safener (B) with itself or dosage form, comprise with the mixture of other agricultural chemical activity compound such as known weed killer herbicide and can optionally be used to control the plant of not expecting, for example be used to control the crop that weeds or control are not expected with a finished product preparation or the mixed thing form of bucket.
Can also be the mixture with other known activity compound, for example fungicide, insecticide, miticide, nematocide, safener, bird repellent.Nutrient for plants and the material that improves soil structure, and conventional auxiliary agent and additive in the plant protection.
Weed killer herbicide (A) and safener (B) can for example be used with available at once solution, suspension, emulsion, pulvis, paste and granule with its dosage form or the type of service that makes thus by further dilution.Use with conventional method, for example water, spraying, atomizing, broadcast sowing.
Reactive compound can be applied to plant, plant part, seed or cultural area (field soil), preferably is applied to soil or green plants and plant part, and optionally also is applied to field soil.Possible use is to use in the lump with the reactive compound that bucket mixes the thing form, and wherein the concentrate formulation with each reactive compound of optimal formulation form mixes in the lump with water in bucket, and uses the spraying liquid of gained.
Because the amount of each component exists with appropriate each other ratio, thus reactive compound of the present invention (A) and (B) the common preparation of composition have the advantage that is easy to use.In addition, the auxiliary agent in the preparation to each other the best match.
Be applicable to that the combination partner of herbicide-safener combination of the present invention with mix preparation or the mixed thing form of bucket is, for example known agricultural chemical activity compound, for example weed killer herbicide, fungicide or insecticide, it is described in for example Weed Research (weeds research) 26,441-445 (1986), or " The Pesticide Manual " (agricultural chemicals handbook), the 13rd edition, The BritishCrop Protection Council, 2003, and the document of wherein being quoted.
Can with mixture of the present invention combined by weed killer herbicide known in the document can mention following reactive compound (annotate: compound according to International Organization for Standardization with " common name " or adopt chemical name to represent, optionally with its coding expression commonly used, and include all possible type of service, for example acid, salt, ester and isomer such as stereoisomer and optical isomer.Can mention multiple administration form a kind of and in some cases):
2,4-D, (Acetochlor); (Acifiuorfen), (Acifluorfen-Sodium), (Aclonifen); (Alachlor), (Alloxydim), (Alloxydim-sodium); (Ametryn), (Amicarbazone), (Amidosulfuron);Aminopyralid, (Amitrole), (Anilofos); (Asulam), (Atrazine), (Azafenidin); (Azimsulfuron), (Beflubutamid), (Benazolin);, (Benfuresate), (Bensulfuron-methyl); (Bentazone), (Benzfendizone),Benzobicyclon; (Benzofenap), (Bifenox),Bilanafos; (Bispyribac-Sodium), (Bromacil), (Bromobutide); (Bromofenoxim), (Bromoxynil), (Butachlor);Butafenacil, (Butenachlor), (Butralin); (Butroxydim), (Butylate), (Cafenstrole); (Carbetamide), (Carfentrazone-Ethyl),Chlometoxyfen; (Chloridazon), (Chlorimuron-Ethyl), (Chlornitrofen); (Chlorotoluron), (Chlorsulfuron),Cinidon-Ethyl; (Cinmethylin), (Cinosulfuron),Clefoxydim; (Clethodim), (Clodinafop-Propargyl), (Clomazone); (Clomeprop), (Clopyralid), (Cloransulam-methyl); (Cumyluron), (Cyanazine), (Cyclosulfamuron); (Cycloxydim), (Cyhalofop-Butyl), (Desmedipham); (Dicamba), (Dichlobenil)),2;4- (Dichlorprop),2,4- (Dichlor prop-P); (Diclofop-Methyl), (Diclosulam), (Difenzoquat); (Diflufenican), (Diflufenzopyr), (Dikegulac-sodium); (Dimefuron), (Dimepiperate), (Dimethachlor); (Dimethametryn), (Dimethenamid), (Triaziflam); (Diquat-Dibromide), (Dithiopyr), (Diuron); (Dymron),EPTC, (Esprocarb); (Ethalfluralin), (Ethametsulfuron-Methyl), (Ethofumesate); (Ethoxyfen), (Ethoxysulfuron), (Ethobenzanid)); (Fenoxaprop-ethyl), (Fenoxaprop-P-Ethyl), (Fentrazamide); (Flamprop-M-Isoproyl), (Flamprop-M-Methyl), (Flazasulfuron); (Florasulam), (Fluazifop), (Fluazifop-Butyl); (Fluazifop-butyl),Fluazolate, (Flucarbazone-Sodium);Flucetosulfuron, (Fluchloralin), (Flufenacet);Flufenpyr, (Flumetsulam), (Flumiclorac-Pentyl); (Flumioxazin), (Fluometuron), (Fluorochloridone);Fluoroglycofen-Ethyl, (Flupoxam), (Flupyrsulfuron-Methyl-Sodium); (Fluridone), (Fluroxypyr), (Fluroxypyr-Butoxypropyl);Fluroxypyr-Meptyl, (Flurprimidol), (Flurtamone); (Fluthiacet-methyl), (Fomesafen), (Foramsulfuron); (Glufosinate), (Glufosinate-Ammonium), (Glyphosate); (Halosulfuron-Methyl), (Haloxyfop), (Haloxyfop-Ethoxyethyl); (Haloxyfop-Methyl), (Haloxyfop-P-Methyl), (Hexazinone); (Imazamethabenz-Methyl), (Imazamox),Imazapic; (Imazapyr), (Imazaquin),Imazethpyr; (Imazosulfuron), (Indanofan), (Iodosulfuron-Methyl-Sodium); (Ioxynil), (Isoproturon), (Isouron); (Isoxaben), (Isoxachlortole), (Isoxaflutole);Ketospiradox, (Lactofen), (Lenacll); (Linuron),MCPA,24 (Mecoprop);24 (Mecoprop-P), (Mefenacet), (Mesosulfuron-Methyl); (Mesotrione),Metamifop, (Metamitron); (Metazachlor), (Methabenzthiazuron), (Methyldymron); (Metobromuron), (Metolachlor), (Metosulam); (Metoxuron), (Metribuzin), (Metsulfuron-methyl); (Molinate), (Monolinuron), (Naproanilide); (Napropamide); (Neburon), (Nicosulfuron), (Norflurazon); (Orbencarb); (Oryzalin), (Oxadiargyl), (Oxadiazon); (Oxasulfuron); (Oxaziclomefone), (Oxyfluorfen), (Paraquat); (Pelargonicacid); (Pendimethalin),Pendralin,Penoxsulam; (Pentoxazone);Penthoxamid, (Phenmedipham), (Picloram);Picolinafen;Pinoxaden, (Piperophos), (Pretilachlor); (Primisulfuron-Methyl); (Profluazol),Profoxydim, (Prometryn); (Propachlor); (Propanil), (Propaquizafop), (Propisochlor);Propoxycarbazone-Sodium; (Propyzamide), (Prosulfocarb), (Prosulfuron); (Pyraclonil); (Pyraflufen-Ethyl), (Pyrazolate), (Pyrazosulfuron-Ethyl); (Pyrazoxyfen); (Pyribenzoxim), (Pyributicarb),Pyridafol); (Pyridate); (Pyriftalid), (Pyriminobac-Methyl), (Pyrithiobac-sodium);Quinclorac; (Quinmerac), (Quinoclamine), (Quizalofop-Ethyl);;, (Rimsulfuron), (Selhoxydim); (Simazine); (Simetryn),S- (S-Metolachlor), (Sulcotrione); (Sulfentrazone); (Sulfometuron-Methyl), (Sulfosate), (Sulfosulfuron); (Tebuthiuron);Tepraloxydim, (Terbuthylazine), (Terbutryn); (Thenylchlor); (Thiazopyr), (Thifensulfuron-methyl), (Thiobencarb);Tiocarbazil; (Tralkoxydim), (Triallate), (Triasulfuron); (Tribenuron-Methyl); (Triclopyr), (Tridiphane), (Trifloxysulfuron); (Trifluralin), (Triflusulfuron-methyl) (Tritosulfuron)。
For using, the preparation that exists with commercial form can optionally for example utilize water to dilute with conventional method.The granule of pulvis, soil particle agent, spreading and the preparation of sprayable solution form usually before use need not any other inert substance dilutions.
Biological Examples
1. the seedling previous crops of control weeds is used
The sandy loam that seed or the rhizome of unifacial leaf and broadleaf weed plant placed carton box also is covered with soil.Under the amount of application of 600~800 liters of water/hectares (through convert) subsequently will be applied to soil surface with the water slurry or the emulsion form of the different water yields with the reactive compound (A) of wetting powder or the preparation of missible oil form and (B).
After the processing, place greenhouse and maintenance to be suitable for the excellent growing conditions of weeds carton box.After test carried out for 3 to 4 weeks, after test plant emerges, compare with untreated control, visual assessment is to the infringement of the plant or the plant that emerges.Shown in the result, this test herbicide-safener combination has the preceding activity of weeding of good seedling of control wide spectrum standing grain this class weeds and broad leaved weed.For example, when with the amount of application of 100g or lower weed killer herbicide (A)/hectare by seedling before method when using, compound number I-1, I-3, I-8, I-9, I-10, I-11, I-12, I-14, I-21, I-22, I-23, I-29, I-30, I-51, I-52, I-60, I-70, I-142, I-143, other compound in I-145 and the table 1 and safener vanilla are swelled (b-14), fenclorim (b-11), cumyluron (b-4), two benzene azoles acetoacetic esters (II-9), pyrroles's two diethyl phthalates (II-1), cloquitocet_mexyl (III-1), S3-1, h-1, h-2, h-3, Dietholate (b-7), disulfoton (b-5), 1,8-naphthalic anhydride (b-1), fluxofenim (b-10), dichlormide (IV-1), benoxacor (IV-2), the herbicide-safener combination of separating careless amine (b-12) and R-29148 (IV-4) has shown the very good activity of weeding of controlling following noxious plant: sinapsis alba, the south crowndaisy chrysanthemum, oat, chickweed, barnyard grass, Annual Ryegrass, green foxtail, piemarker, Amaranthus retroflexus and millet.
2. act on behind the seedling of control weeds
The sandy loam that the seed or the rhizome of unifacial leaf and broadleaf weed placed carton box also is covered with soil, and grow in the greenhouse under the excellent growing conditions.After sowing for 3 weeks, three leaves Processing Test plant during the stage.Under the amount of application of 600~800 liters of water/hectares (through converting) subsequently will be applied to the green plants part surface with the different water yields with the The compounds of this invention of wetting powder or the preparation of missible oil form.Place greenhouse under the desirable growth conditions after 3 to 4 weeks test plant, compare the effect of range estimation record preparation subsequently with untreated control.Herbicide-safener combination of the present invention also has the good postemergence herbicide activity of control wide spectrum Economic Importance standing grain this class weeds and broad leaved weed.For example when with the amount of application of 100g or lower weed killer herbicide (A)/hectare by seedling after method when using, compound number I-1, I-3, I-8, I-9, I-10, I-11, I-12, I-14, I-21, I-22, I-23, I-29, I-30, I-51, I-52, I-60, I-70, I-142, I-143, other compound in I-145 and the table 1 and safener vanilla are swelled (b-14), fenclorim (b-11), cumyluron (b-4), two benzene azoles acetoacetic esters (II-9), pyrroles's two diethyl phthalates (II-1), cloquitocet_mexyl (III-1), S3-1, h-1, h-2, h-3, Dietholate (b-7), disulfoton (b-5), 1,8-naphthalic anhydride (b-1), fluxofenim (b-10), dichlormide (IV-1), benoxacor (IV-2), the herbicide-safener combination of separating careless amine (b-12) and R-29148 (IV-4) has shown the very good activity of weeding of controlling following noxious plant: sinapsis alba, barnyard grass, Annual Ryegrass, the south crowndaisy chrysanthemum, green foxtail, piemarker, Amaranthus retroflexus, millet and oat.
3. with the compatibility of crop
In further greenhouse test, the seeds of a large amount of relatively crops and weeds is placed sandy loam and is covered with soil.A part of basin is handled as described in part 1 immediately, other basin place the greenhouse until plant growing to 2 to 3 true leaves, and, spray with the various dose of herbicide-safener combination of the present invention subsequently as described in the part 2.After the to be administered and time of repose in the greenhouse was 4 to 5 weeks, when method was used behind method or the seedling before by seedling, the herbicide-safener combination tested was determined in range estimation, compound number I-1 for example, I-3, I-8, I-9, I-10, I-11, I-12, I-14, I-21, I-22, I-23, I-29, I-30, I-51, I-52, I-60, I-70, I-142, I-143, other compound in I-145 and the table 1 and safener vanilla are swelled (b-14), fenclorim (b-11), cumyluron (b-4), two benzene azoles acetoacetic esters (II-9), pyrroles's two diethyl phthalates (II-1), cloquitocet_mexyl (III-1), S3-1, h-1, h-2, h-3, Dietholate (b-7), disulfoton (b-5), 1,8-naphthalic anhydride (b-1), fluxofenim (b-10), dichlormide (IV-1), benoxacor (IV-2), the composition of separating careless amine (b-12) and R-29148 (IV-4) does not cause any infringement to following crop: cotton for example, rape, beet and gramineous crop be barley for example, wheat, rye, grain, corn or paddy rice.The composition of using the two benzene azoles acetoacetic esters (II-9) of 30g/ha compound (I-9) and 100g does not cause any infringement to corn crop.
Claims (8)
1. herbicide-safener combination, it comprises
(A) one or more formulas (I) compound or its salt
Wherein
A is nitrogen or CR
11-group,
Wherein
R
11Be hydrogen, alkyl, halogen and alkylhalide group,
R
1Group for group under hydrogen or optional being selected from that is substituted: alkyl, alkoxyl, alkoxyalkyl, thiazolinyl, alkynyl, cycloalkyl, cycloalkyl-alkyl, aralkyl and aryl,
R
2Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that have 1 to 6 carbon atom respectively that replaces through halogen,
R
3Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that have 1 to 6 carbon atom respectively that replaces through halogen,
R
4-R
7Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group, the alkyl amino-carbonyl that have 1 to 3 carbon atom respectively that replaces through halogen independently of one another
R
8Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group, the alkyl amino-carbonyl that have 1 to 3 carbon atom respectively that replaces through halogen,
Wherein in above-mentioned group, alkyl and alkylidene can contain 1 to 6 carbon atom respectively, and thiazolinyl and alkynyl can contain 2 to 6 carbon atoms respectively, and cycloalkyl can contain 3 to 6 carbon atoms respectively, and aryl can contain 6 or 10 carbon atoms respectively; With
(B) one or more safeners.
2. according to the herbicide-safener combination of claim 1, wherein in formula (I) compound
A is nitrogen or CH-group,
R
1Be hydrogen or the optional respectively group that has group under being selected from of 3 carbon atoms respectively that replaces through halogen: alkyl, alkoxyl, alkoxyalkyl, thiazolinyl and alkynyl,
R
2Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen,
R
3Be hydrogen, halogen or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl amino or the dialkyl amido that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen,
R
4-R
7Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group or the alkyl amino-carbonyl that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen independently of one another
R
8Be hydrogen, halogen, cyano group, thiocyano or the optional respectively alkyl, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl amino, alkyl-carbonyl, alkoxy carbonyl group or the alkyl amino-carbonyl that in alkyl, have 1 to 3 carbon atom respectively that replaces through halogen.
3. according to the herbicide-safener combination of claim 1 or 2, wherein safener (B) is selected from down group:
Vanilla is swelled (b-14); fenclorim (b-11); cumyluron (b-4); two benzene azoles acetoacetic esters (II-9); pyrroles's two diethyl phthalates (II-1); cloquitocet_mexyl (III-1); 4-cyclopropyl amino carbonyl-N-(2-methoxybenzoyl base) benzsulfamide) (S3-1); 1-[4-(N-2-methoxybenzoyl base sulfamoyl) phenyl]-3-methylurea (h-1); 1-[4-(N-2-methoxybenzoyl base sulfamoyl) phenyl]-3; 3-dimethyl urea (h-2); 1-[4-(N-4; 5-dimethylbenzoyl sulfamoyl) phenyl]-3-methylurea (h-3); Dietholate (b-7); disulfoton (b-5); 1,8-naphthalic anhydride (b-1); fluxofenim (b-10); dichlormide (IV-1); benoxacor (IV-2); separate careless amine (b-12); R-29148 (IV-4).
4. according to one of claim 1 to 3 or multinomial described herbicide-safener combination, it also contains conventional additive and formulation auxiliary agents in one or more other agricultural chemical activity compound and/or the plant protection.
One kind preferred in crop control do not expect the method for plant, wherein with the component (A) of one of claim 1 to 4 or multinomial described herbicide-safener combination and (B) preferably be applied to plant, seed or plant growing zone together or dividually.
6. according to the method for claim 5, wherein crop is selected from crops, vegetable crop or long-term crop and kind plant.
7. according to the method for claim 5 or 6, wherein crop is genetically modified or owing to the crop of selecting breeding to tolerate.
8. one of claim 1 to 4 or multinomial described herbicide-safener combination are used for preferred purposes at crop control noxious plant.
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DE102004015140.7 | 2004-03-27 | ||
DE102004015140 | 2004-03-27 | ||
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CN 200580009788 Pending CN1937923A (en) | 2004-03-27 | 2005-03-12 | Herbicide combination |
CN 200580003930 Pending CN1913779A (en) | 2004-03-27 | 2005-03-12 | Use of sulfonylurears |
CNB2005800099463A Expired - Fee Related CN100475039C (en) | 2004-03-27 | 2005-03-12 | Herbicide-safener combination |
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CN 200580003930 Pending CN1913779A (en) | 2004-03-27 | 2005-03-12 | Use of sulfonylurears |
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UA (1) | UA86619C2 (en) |
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Cited By (2)
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CN102665416A (en) * | 2009-11-27 | 2012-09-12 | 辛根塔有限公司 | Herbicidal compositions |
WO2017107579A1 (en) * | 2015-12-23 | 2017-06-29 | Rotam Agrochem International Company Limited | Herbicidal composition and method for controlling plant growth |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101971841B (en) * | 2010-05-24 | 2013-07-31 | 北京颖泰嘉和生物科技有限公司 | Herbicide composition and application thereof |
CN101953354B (en) * | 2010-06-01 | 2013-09-11 | 北京颖泰嘉和生物科技有限公司 | Compound herbicide composition and use thereof |
CN101971859A (en) * | 2010-10-22 | 2011-02-16 | 吉林金秋农药有限公司 | Weedicide composition, preparation method and application thereof |
CN101971822B (en) * | 2010-10-28 | 2013-05-29 | 江苏龙灯化学有限公司 | Synergistic weeding composition and application method thereof |
CN104094953A (en) * | 2014-07-24 | 2014-10-15 | 江苏神禾农业科技发展有限公司 | Rice weed killer for weeds in rice fields adopting direct seeding in districts of Jiangsu and Zhejiang as well as application thereof |
CN105325444A (en) * | 2015-10-29 | 2016-02-17 | 北京燕化永乐生物科技股份有限公司 | Pesticide composition |
CN106561695A (en) * | 2016-11-15 | 2017-04-19 | 江苏龙灯化学有限公司 | Weeding composition |
CN107279144A (en) * | 2017-06-23 | 2017-10-24 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing fluorochloridone |
CN107494548A (en) * | 2017-10-13 | 2017-12-22 | 北京科发伟业农药技术中心 | Herbicidal combinations containing pyrithiobac-sodium and amicarbazone |
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DE4336875A1 (en) * | 1993-09-27 | 1995-03-30 | Bayer Ag | N-Azinyl-N '- (het) arylsulfonylureas |
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2005
- 2005-03-12 CN CN 200580009788 patent/CN1937923A/en active Pending
- 2005-03-12 UA UAA200611302A patent/UA86619C2/en unknown
- 2005-03-12 CN CN 200580003930 patent/CN1913779A/en active Pending
- 2005-03-12 CN CNB2005800099463A patent/CN100475039C/en not_active Expired - Fee Related
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- 2006-06-26 ZA ZA200605244A patent/ZA200605244B/en unknown
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102665416A (en) * | 2009-11-27 | 2012-09-12 | 辛根塔有限公司 | Herbicidal compositions |
WO2017107579A1 (en) * | 2015-12-23 | 2017-06-29 | Rotam Agrochem International Company Limited | Herbicidal composition and method for controlling plant growth |
CN108290862A (en) * | 2015-12-23 | 2018-07-17 | 江苏龙灯化学有限公司 | Herbicidal combinations for controlling plant growth and method |
CN108290862B (en) * | 2015-12-23 | 2021-03-23 | 江苏龙灯化学有限公司 | Herbicidal compositions and methods for controlling plant growth |
Also Published As
Publication number | Publication date |
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CN1913779A (en) | 2007-02-14 |
UA86619C2 (en) | 2009-05-12 |
CN100475039C (en) | 2009-04-08 |
ZA200606546B (en) | 2008-05-28 |
ZA200606721B (en) | 2008-01-30 |
CN1937923A (en) | 2007-03-28 |
ZA200605244B (en) | 2008-04-30 |
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