CN1933809A - Oily cleansing material - Google Patents
Oily cleansing material Download PDFInfo
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- CN1933809A CN1933809A CNA2005800087409A CN200580008740A CN1933809A CN 1933809 A CN1933809 A CN 1933809A CN A2005800087409 A CNA2005800087409 A CN A2005800087409A CN 200580008740 A CN200580008740 A CN 200580008740A CN 1933809 A CN1933809 A CN 1933809A
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- cleansing material
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- oily cleansing
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- Life Sciences & Earth Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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- Veterinary Medicine (AREA)
- Birds (AREA)
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- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
A solid or semi-solid cleansing material which has excellent aesthetic appearance and is satisfactory in detergency, suitability for use, and use feeling. It further has a massage effect when applied with rubbing to thereby enhance blood circulation and make the skin condition satisfactory. The oily cleansing material is characterized by comprising (A) a specific polyamide-modified silicone, (B) a surfactant having an amide group and/or a surfactant having no amide group and having an organic value of 2,000 or lower and an inorganic value of 1,500 or lower, and (C) an ester oil, and by being semi-solid or solid.
Description
Technical field
The present invention relates to the oily cleansing material of a kind of semi-solid to solid, shaped, it is good to relate to cleaning strength, usability, usability particularly, has the outward appearance of good transparency, and high-temperature stability is better, and massage effect oily cleansing material preferably.
Background technology
In recent years, popular along with rigid (Ha one De メ イ Network) cosmetics such as oiliness mascara, lipsticks not easy to fade, require cleaning material that higher cleaning strength is arranged, the demand of the oily cleansing material that can remove higher cosmetics of resistance to water or persistency etc. is sharply increased.
But, because general oily cleansing material, main flow be with liquid oil as main component, wait usability so exist to be difficult to take, and wipe afterwards or washed the problem of usability such as be clamminess of skin afterwards with finger.For addressing these problems, research is with bentonite, oil-base gel agent, or solid shape oil makes system present the oily cleansing material (for example patent documentation 1) of viscosity oily set member gelation.
In addition, the oiliness that has taste as appearance transparent is consolidated the shape cosmetics, and the material of the material of known interpolation polyamide (for example, patent documentation 2,3), interpolation 12-hydroxy stearic acid (for example, patent documentation 4,5), add the material (for example, patent documentation 6) etc. of dextrin stearate.
Patent documentation 1: the Japan Patent spy opens the 2001-213726 communique
Patent documentation 2: the special public clear 45-41318 communique of Japan Patent
Patent documentation 3: the special public clear 52-7067 communique of Japan Patent
Patent documentation 4: the Japan Patent spy opens clear 63-119405 communique
Patent documentation 5: Japanese patent laid-open 2-264707 communique
Patent documentation 6: Japanese patent laid-open 9-235210 communique
Summary of the invention
Yet, although with bentonite, oil-base gel agent, or solid shape oil is with oily set member gelation, make system present the cosmetics of viscosity, on usability better, but because gel itself is former thereby be nebulousurine, the taste of outward appearance is relatively poor, and owing to solid shape wet goods reason, existing is clamminess after using etc. can not satisfy the aspect of usability.
Again, expectation improves effect as described below: be coated with the exhibition cleaning material on skin, with the fused behavior of embrocating of beauty treatment material, the same with massage, the skin of promotion blood circulation is arranged, make the soft glossy effect of skin, the cosmetics that use this moment have viscosity, and the opposing sense of appropriateness is arranged on the skin.But with bentonite, oil-base gel agent, or shape oil makes system present the cleaning material of viscosity oily set member gelation admittedly, and the behavior of embrocating during owing to use significantly reduces the viscosity of system, can not obtain sufficient massage effect.
In addition, in the solid shape cosmetics of the oiliness of transparent appearance, add the material of polyamide, by through the time change or variations in temperature takes place by oil ooze out easily, the shortcoming of storage stability difference is arranged.Again, add the material of 12-hydroxy stearic acid, the transparency of outward appearance is better, but temperature stability is poor slightly, adds the material of dextrin fatty acid ester, can not satisfy the requirement of solid-state property two aspects of the transparency and system.And these technology about the transparency are to be the technology of expection with transparent lipstick, in the application as cleaning material, are coated with and open up difficulty, be clamminess etc., can not obtain usability preferably.
That is, do not find to have in the market to be clear to translucent outward appearance, usability is better, can the behavior of embrocating owing to using reduce viscosity and massage effect oily cleansing material preferably.
In this case, the present inventor, repeatedly concentrates on studies about the composition of oily cleansing material for solving the problems of the technologies described above.Its result, discovery is added specific polyamide modified siloxanes, the surfactant with special properties and ester oil by combination, can obtain having good cleaning strength, outward appearance is to be clear to the semi-solid translucent, that taste is good to solid, shaped, has the good easily usability of taking that can from hands, not drip when using simultaneously, and can expect blood circulation promoting and the soft massage effect that removes exfoliation etc., high-temperature stability is oily cleansing material preferably also, and finishes the present invention.
Again, the behavior of embrocating by this oily cleansing material not only has massage effects such as blood circulation promoting, finds simultaneously to have to improve cleaning material and soak into to skin texture inside, and composition is cleaned in stripping, is cleaned the cleaning effect of composition emersion on the skin.
That is, the invention provides a kind of oily cleansing material, it is characterized in that containing following composition (A)～(C):
(A) have polyamide modified siloxanes with the repetitive of following general expression (1) expression:
[Chemical formula 2]
(in the formula, X represents to have the bivalent hydrocarbon radical of 1～30 carbon atom, and Y represents to have the bivalent hydrocarbon radical of 1～40 carbon atom, and m represents the integer of 1≤m≤700, and n represents the integer of 1≤n≤500);
(B) organic value is below 2000 and inorganic value is a surfactant below 1500;
(C) ester oil,
For semi-solid to solid, shaped.
The present invention further provides a kind of outward appearance for being clear to translucent above-mentioned oily cleansing material.
The effect of invention
Oily cleansing material of the present invention is that cleaning strength is good, for semi-solid to solid, shaped, have cosmetics do not drip when using good usability and massage effect simultaneously from hands, and the taste of outward appearance is better, the also novel preferably cleaning material of high-temperature stability.
Therefore, by cleaning material of the present invention, can obtain to remove the clean effect and the massage effect of higher cosmetics of resistance to water or persistency etc. simultaneously.
The optimal morphology that carries out an invention
Cleaning material of the present invention, mentioned component (A) to (C) is necessary composition, wherein composition (A) is the gelating agent of oiliness composition, be to be that semi-solid is to solid, shaped by the oiliness composition of keeping oily cleansing material, give the good usability that can from hands, not drip when using etc. and can expect blood circulation promoting and the soft composition that removes the massage effect of exfoliation etc.The polyamide modified siloxanes of this composition (A) is represented with following general expression (1).
[chemical formula 3]
(in the formula, X represents to have the bivalent hydrocarbon radical of 1～30 carbon atom, and Y represents to have the bivalent hydrocarbon radical of 1～40 carbon atom, and m represents the integer of 1≤m≤700, and n represents the integer of 1≤n≤500).
In the above-mentioned formula (1), X is the straight or branched bivalent hydrocarbon radical that 1～30 carbon atom is arranged, and preferably has the straight or branched bivalent hydrocarbon radical of 3～10 carbon atoms.Again, Y is the straight or branched bivalent hydrocarbon radical that 1～40 carbon atom is arranged, and preferably has the straight or branched bivalent hydrocarbon radical of 2～6 carbon atoms.
Moreover in the above-mentioned formula (1), m is 1～700 integer, preferred 15～500 integer, preferred especially 15～45 integer.N is 1～500 integer, preferred 1～100 integer, preferred especially 4～25 integer.
As the polyamide modified siloxanes of composition (A) of formula (1) expression, concrete example is put down in writing in the special table of Japan Patent 2001-512164 communique, as its commercially available product, can list Dow Corning 2-8178 Gellant (Dow Corning Corporation's manufacturing) etc.
The content of mentioned component (A) has no particular limits, 0.5-50 quality % during preferred total composition divides (below, only with " % " expression).If in this scope, can obtain having the gel strength of appropriateness, massage effect is arranged, the oily cleansing material of no high-temperature stability, cleaning power problem.Moreover, from hands take conveniently and easily with fused etc. the usability aspect consideration of skin (use position), most preferably 0.5～15%.
Again, the composition that uses among the present invention (B) surfactant is an organic value below 2000, and the surfactant of inorganic value below 1500, be to be mixed with cleaning composition when using, and emersion is the composition that purpose is added by the effect of clean composition to bring into play with composition (A).
Herein, organic value, inorganic value are the values of obtaining according to organic conceptional diagram (Tentianmu, the prediction of organic compound and organic conceptional diagram, the field VOL.11 of chemistry, No.10 (1957) 719-715).Concrete is, in this organic conceptional diagram, for the physicochemical properties of chemical compound, definition is " organic property " by the degree of the rerum natura of Van der Waals (Van Der Waals) power decision mainly, mainly the degree by the rerum natura of static affinity decision be " inorganic nature ", and then the value that shows.
If it is good that the organic value of composition (B) and inorganic value in this scope, then can obtain with the intermiscibility of composition (A) and composition (C), system does not have nebulousurine, the gelation power of appropriateness is arranged, the good cleaning material of problems such as no waste liquid.
Below 2000 and the surfactant component (B) of inorganic value below 1500, concrete lists as this organic value: cocoanut fatty acid diethanolamide, lauric acid diethyl amide, myristic acid diglycollic amide, myristic acid list isopropanol amide, coconut oil fatty acid monoethanolamide, lauric acid list isopropanol amide, polyoxypropylene coco-nut oil fatty acid list isopropanol amide etc. contain amino activating agent; Esters surface active agents such as polyethyleneglycol isostearate, polyoxyethylene iso stearic acid of glycerine ester; The ethers surfactant of polyoxyethylene chains such as polyoxyethylene stearyl base ether, polyoxyethylene iso stearyl ether, polyoxyethylene cetyl base ether, the different cetyl ether of polyoxyethylene, polyoxyethylene oleyl ether, polyoxyethylene lauryl ether and fatty acid.
As the commercially available product of this composition (B), for example can list: Amizole CDE (cocoanut fatty acid diethanolamide (river is ground fine chemistry company and made); Organic value 327, inorganic value 400), Amizole LDE (lauric acid diethyl amide (river is ground fine chemistry company and made); Organic value 320, inorganic value 400), Amizole CME (coconut oil fatty acid monoethanolamide (river is ground fine chemistry company and made); Organic value 300, inorganic value 300), PEIS-8EX (polyethyleneglycol isostearate (Japanese エ マ Le ジ ョ Application company make); Organic value 670, inorganic value 685), PEIS-10EX (polyethyleneglycol isostearate (Japanese エ マ Le ジ ョ Application company make); Organic value 750, inorganic value 835), GWIS-108 (polyoxyethylene iso stearic acid of glycerine ester (Japanese エ マ Le ジ ョ Application company make); Organic value 730, inorganic value 695), GWIS-110 (polyoxyethylene iso stearic acid of glycerine ester (Japanese エ マ Le ジ ョ Application company make); Organic value 810, inorganic value 845), GWIS-115 (polyoxyethylene iso stearic acid of glycerine ester (Japanese エ マ Le ジ ョ Application company make); Organic value 1010, inorganic value 1220) etc.
Add this composition (B),, and can keep the compositions appearance transparent, obtain good taste, so more satisfactory because can satisfy the performance of oily cleansing material.Particularly as composition (B) if use cocoanut fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, polyoxyethylene (E.O.8-10) glycol list isostearate, polyoxyethylene (E.O.8-10) iso stearic acid of glycerine ester etc., then the intermiscibility with composition (A) is good, can obtain the gel strength of appropriateness, so more satisfactory.
The content of composition (B) has no particular limits, preferred total 0.5-50% in the branch that forms, preferred especially 3-20%.If in this scope, it is good then can to obtain cleaning strength, and the salubrious sense during rinsing and use the good oily cleansing material of usabilities such as state of back skin.Can use this composition (B) more than a kind or 2 kinds again.
Moreover, as the composition that uses among the present invention (C) ester oil, can use any of the material that uses in the common cosmetics.As the example of this composition (C), can list: Palmic acid 2-Octyl Nitrite, 2 ethyl hexanoic acid cetyl, isopropyl palmitate, isopropyl myristate, different tridecane イ ソ ノ Na ェ one ト, different nonyl イ ソ ノ Na ネ one ト, two sad DOPCP, three 2 ethyl hexanoic acid glyceride, didecyl acid propylene glycol ester, two sad propylene glycol esters, three (sad capric acid) glyceride etc.Moreover in the above-mentioned ester oil, the person that most preferably has the branched alkyl chain in the structure such as three 2 ethyl hexanoic acid glyceride makes oily cleansing material stability and appearance transparent good because of itself and composition (A) intermiscibility are good.
The content of mentioned component (C) has no particular limits, preferred total 10-99%, more preferably 10-80% in the branch that form.Can use this composition (C) more than a kind or 2 kinds again.
Oily cleansing material of the present invention, mentioned component (A) to (C) is as containing by composition, and it is shaped as semi-solid to solid, shaped in addition.In this description, semi-solid to solid, shaped is meant, (motionless Industrial Co., Ltd makes by flow graph, flow graph NRM-2002D.D) gel hardness of Ce Dinging (25 ℃ of sample storage temperatures, the pin footpath 10mm φ of pressure-sensitive axle (adapter), the platform translational speed is in the penetration test of 60mm/min, the load that applies on the pressure-sensitive axle when pressure-sensitive axle is inserted into the 5mm degree of depth) for more than the 15gf, more than the preferred 50gf.
Again, oily cleansing material of the present invention more preferably is clear to translucent.In this description, be clear to translucent being meant, when filling the present invention product were to the 15mm degree of depth in glass beaker, the sort of state (translucent) of the literal (about font 11) on the paper of placing at the bottom of can recognizing glass was to more transparent.
For make oily cleansing material of the present invention such as above-mentioned present be clear to translucent, as the preferred surfactant that uses of composition of the present invention (B) with acylamino-.This surfactant is because of better with composition (A) compatibility, so when improving oily cleansing material stability, also be clear to translucent making contributions for the outward appearance of oily cleansing material presents.
In the oily cleansing material of the present invention, except that above-mentioned each composition, can further add volatile siloxanes such as decamethylcyclopentaandoxane.By adding these volatile siloxanes, cosmetics such as lipstick or mascara and the fused of cleaning material become especially good, and its result can obtain cleaning power and improve, and spot is removed splendid cleaning material.Content when containing these volatile siloxanes is for total composition, about preferred 3-25%.
In the oily cleansing material of the present invention, except that above-mentioned each composition, according to purpose in the scope of not damaging effect of the present invention, can add composition general in the cosmetics, for example: preserve moisture composition, beauty treatment composition, antioxidant, antiseptic, chelating agen, pH of oil preparation, surfactant, water soluble polymer, clay mineral, powder body, water solublity adjusted compositions such as agent, coloring agent, active ingredient, spice.
But in the oily cleansing material of the present invention, the heavy addition water composition is undesirable, in fact preferably property of water-bearing composition not.
Embodiment
Enumerate embodiment below and specifically describe the present invention, but the present invention is not limited to these fully
Embodiment.
Embodiment 1
Oily cleansing material:
Forming shown in table 1 and the table 2 and following manufacture method, the modulation the present invention product 1～19 and the cleaning material of product 1～9 relatively, for following assessment item, later commentary valency method and criterion are carried out performance evaluation.These results represent in table 3.
(composition)
Table 1
| No. | Composition (%) | The present invention's product | ||||||||||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | ||
| 1 | Polyamide modified siloxanes *1 | 1 | 30 | 50 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
| 8 | Three 2 ethyl hexanoic acid glyceride | 74 | 5 | 15 | 10 | 45 | 85 | 85 | 85 | 85 | 945 | 90 | 45 | 90 | 90 | 90 | 90 | 90 | 90 | 87 |
| 9 | The 2 ethyl hexanoic acid cetyl | - | 40 | 20 | 80 | 45 | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| 10 | Decanoin | - | 10 | 5 | - | - | 5 | - | - | - | - | - | - | - | - | - | - | - | - | - |
| 11 | Squalane | - | - | - | - | - | - | 5 | - | - | - | - | - | - | - | - | - | - | - | - |
| 12 | Liquid paraffin | - | 10 | 5 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
| 13 | Decamethylcyclopentaandoxane | 20 | - | - | - | - | - | - | 5 | - | - | - | - | - | - | - | - | - | - | - |
| 14 | Dimethyl polysiloxane | - | - | - | - | - | - | - | - | 5 | - | - | - | - | - | - | - | - | - | - |
| 15 | Polyoxyethylene (E.O.20) glycerol three isostearates *2 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | 1 | - | - | - |
| 16 | Polyoxyethylene sorbitol tetraoleate | - | - | - | - | - | - | - | - | - | - | - | - | - | - | 1 | - | - | - | - |
| 17 | Cocoanut fatty acid diethanolamide | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 05 | 5 | 50 | - | - | 4 | 4 | - | - | 3 |
| 18 | Coconut oil fatty acid monoethanolamide | - | - | - | - | - | - | - | - | - | - | - | - | 5 | - | - | - | - | - | - |
| 19 | Month silicic acid diglycollic amide | - | - | - | - | - | - | - | - | - | - | - | - | - | 5 | - | - | - | - | - |
| 20 | The polyethyleneglycol isostearate *3 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | 5 | - | - |
| 21 | Polyoxyethylene (EO.10) iso stearic acid of glycerine ester *4 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | 5 | 5 |
*1 DOW CORNING silicone company makes Dow Corning 2-8178 gellant
*The 2 Japanese エ マ Le ジ ョ Application manufacturing GWIS-320 (organic value 1940 inorganic values 1515) of company
*The 3 Japanese エ マ Le ジ ョ Application manufacturing PEIS-8EX (organic value 670 inorganic values 685) of company
*The 4 Japanese エ マ Le ジ ョ Application manufacturing GWIS-110 (organic value 810 inorganic values 845) of company
*The 5 Japanese エ マ Le ジ ョ Application manufacturing GWIS-330 (organic value 2310 inorganic values 2265) of company
[table 2]
| No . | Composition (%) | Product relatively | ||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | ||
| 1 | Polyamide modified siloxanes *1 | - | - | - | 5 | - | - | - | 5 | 5 |
| 2 | Hydrogenated coconut oil (m.p.37 ℃) | - | - | - | - | - | - | 40 | - | - |
| 3 | The dextrin cetylate | 5 | 5 | - | - | - | - | - | - | - |
| 4 | The 12-hydroxy stearic acid | - | - | 5 | - | - | - | - | - | - |
| 5 | Pentaerythritol abietate | - | - | 5 | - | - | - | - | - | - |
| 6 | Paraffin (m.p.57 ℃) | - | - | - | - | 5 | - | 4 | - | - |
| 7 | Tissuemat E (m.p.88 ℃) | - | - | - | - | - | 5 | 1 | - | - |
| 8 | Three 2 ethyl hexanoic acid glyceride | 90 | 40 | 85 | 90 | 15 | 15 | 24. 5 | 90 | 50 |
| 11 | Squalane | - | 50 | - | - | - | - | - | - | - |
| 12 | Liquid paraffin | - | - | - | - | 75 | 75 | 30 | - | - |
| 13 | Decamethylcyclopentaandoxane | - | - | - | - | - | - | - | - | - |
| 14 | Dimethyl polysiloxane | - | - | - | - | - | - | - | - | 40 |
| 15 | Polyoxyethylene (E.O.20) glycerol three isostearates *2 | - | - | - | - | - | - | - | 5 | - |
| 16 | Polyoxyethylene sorbitol tetraoleate | - | - | - | 5 | - | - | 0.5 | - | - |
| 17 | Cocoanut fatty acid diethanolamide | 5 | 5 | 5 | - | 5 | 5 | - | - | - |
| 22 | Polyoxyethylene (E.O.30) glycerol three isostearates *5 | - | - | - | - | - | - | - | - | 5 |
*1 DOW CORNING silicone company makes Dow Corning 2-8178 gellant
*The 2 Japanese エ マ Le ジ ョ Application manufacturing GWIS-320 (organic value 1940 inorganic values 1515) of company
*The 3 Japanese エ マ Le ジ ョ Application manufacturing PEIS-8EX (organic value 670 inorganic values 685) of company
*The 4 Japanese エ マ Le ジ ョ Application manufacturing GWIS-110 (organic value 810 inorganic values 845) of company
*The 5 Japanese エ マ Le ジ ョ Application manufacturing GWIS-330 (organic value 2310 inorganic values 2265) of company
(manufacture method)
A. with composition (1)～(22) at 120 ℃ of following heating for dissolving, mix homogeneously.
B. in container, fill A, leave standstill cooling and obtain the cleaning material of semi-solid to solid, shaped.
(performance test)
＜assessment item 〉
(1) takes convenience (whether from hands, dripping)
(2) massage effect
(3) clean effect (the clean effect of the commercially available lipstick that lip is smeared)
(4) there is not the sense of being clamminess (state of cleaning back skin)
(5) skin does not have dry sensation (state of cleaning back skin)
(6) transparency of outward appearance
(7) high-temperature stability (50 ℃, 1 month)
(8) gel hardness
＜evaluation methodology 1: subjective appreciation test 〉
Assessment item (1)～(5) are carried out the subjective appreciation test for each test portion to 10 panels.Subjective appreciation test is estimated with 7 ranks based on following (a) absolute evaluation index, each sample, and the meansigma methods of the scoring that provides according to 10 people's panels is judged based on following (b) criterion.
(a) absolute evaluation standard
(scoring): (evaluation)
6: very good
5: good
4: good slightly
3: general
2: poor slightly
1: poor
0: non-constant
(b) criterion
(judgement): (meansigma methods of scoring)
◎: more than 5.0 (very good)
More than zero: 3.5, less than 5.0 (good)
△: more than 1.0, less than 3.5 (poor slightly)
*: less than 1.0 (poor)
＜evaluation methodology 2: the transparency of outward appearance 〉
In glass beaker filling the present invention product or relatively product judge the literal (about font 11) on the paper of placing at the bottom of can recognizing glass based on following (c) criterion to 5mm～20mm degree of depth.
(c) criterion
(judgement): (evaluation)
◎: the above degree of depth of filling 20mm also can be recognized literal (transparency is very good)
Zero: the 15mm degree of depth can be recognized literal (transparency is good)
△: the 10mm degree of depth can be recognized literal (transparency is poor slightly)
*: the 5mm degree of depth also can not be recognized literal (transparency is poor)
＜evaluation methodology 3: high-temperature stability 〉
Filling the present invention product or product are relatively preserved in 50 ℃ of temperature chambers in container, and the state after detecting by an unaided eye 1 month is judged based on following (d) criterion.
(d) criterion
(judgement): (evaluation)
◎: do not have oil to ooze out (high-temperature stability is very good) fully
Zero: have a small amount of oil to ooze out, transfer postpone disappearance (high-temperature stability is good) in room temperature
△: have a small amount of oil to ooze out, transfer postpone do not disappear (high-temperature stability is poor slightly) in room temperature
*: there is big gauging to ooze out, usability poor (poor high temperature stability)
＜evaluation methodology 4: gel hardness 〉
The flow graph (NRM-2002D.D) that uses motionless Industrial Co., Ltd to make, 25 ℃ of sample preservation temperature, the pin footpath 10mm φ of pressure-sensitive axle (adapter), the platform translational speed is in the penetration test under the 60mm/min condition, and the load that applies on the pressure-sensitive axle when inserting the pressure-sensitive axle to the 5mm degree of depth is estimated.
(composition)
[table 3]
| No. | Estimate | The present invention's product | Product relatively | ||||||||||||||||||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | ||
| (1) | Take convenience | ○ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | ○ | △ | △ | ○ | ○ | ◎ | ◎ | ◎ |
| (2) | Massage effect | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | ○ | △ | △ | ○ | ○ | ◎ | ◎ | ◎ |
| (3) | Clean effect | ◎ | ○ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ○ | ○ | ○ | ○ | ○ | ○ | ◎ | ◎ | ◎ |
| (4) | There is not the sense of being clamminess | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | △ | △ | △ | ◎ | △ | △ | ○ | ◎ | ◎ |
| (5) | Skin does not have dry sensation | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ○ | × |
| (6) | The appearance transparent sense | ◎ | ○ | ○ | ◎ | ◎ | ◎ | ○ | ◎ | ○ | ◎ | ◎ | ○ | ◎ | ◎ | ○ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | △ | × | × | × | × | ○ |
| (7) | High-temperature stability | ○ | ○ | ○ | ○ | ◎ | ○ | ○ | ○ | ○ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | ◎ | × | × | × | × | × | △ | △ | △ | △ |
| (8) | Gel hardness (gf) | 15 | 385 | 452 | 120 | 132 | 147 | 146 | 186 | 193 | 153 | 181 | 305 | 182 | 191 | 188 | 194 | 175 | 165 | 171 | 114 | 90 | 78 | 141 | 159 | 283 | 60 | 118 | 75 |
Result by table 3 shows, the cleaning material of the present invention's product 1～19 be take convenience, massage effect, clean effect, do not have the sense of being clamminess, skin does not have all good oily cleansing material in dry sensation, appearance transparent sense, the high-temperature stability all items.
On the other hand, as shown in table 3, replace composition (A) to make the solidified relatively product 1～3 of system with dextrin cetylate, 12-hydroxy stearic acid, in high-temperature stability and aspect existing problems such as be clamminess.Again, add the relatively product 4 that Polyoxyethylene sorbitol tetraoleate replaces composition (B), appearance transparent is not good enough, existing problems aspect high-temperature stability and usability.
Again, make the solidified relatively product 5～7 of system with paraffin, Tissuemat E, high-temperature stability and appearance transparent are not good enough, and the sense of being clamminess is arranged.Moreover, not adding (B) composition and only add organic value or inorganic value in the relatively product 8,9 of extraneous surfactant, product 8 (inorganic value 1515) relatively can not obtain the transparency of outward appearance, and high-temperature stability is also relatively poor.Relatively product 9 (organic value 2310, inorganic value 2265) by improving the addition of volatile siloxane, can obtain the transparency of outward appearance, but use back skin feel drying, and storage stability is also not good enough, is unfavorable.
Embodiment 2
Solid-state cleaning material:
(composition) (%)
(1) polyamide modified siloxanes
* 15.0
(2) three 2 ethyl hexanoic acid glyceride 73.6
(3) decamethylcyclopentaandoxane 15.0
(4) squalane 3.0
(5) cocoanut fatty acid diethanolamide 3.0
(6) spice 0.3
(7) oil of rosemary 0.1
*1Dow Corning 2-8178 gellant (manufacturing of DOW CORNING silicone company)
(preparation method)
Above-mentioned (1) to (7) after 100 ℃ of following even heating mix, are filled in the container, obtain solid shape cleaning material.
The solid shape cleaning material that the solid shape cleaning material of embodiment 2 is that high-temperature stability and appearance transparent are good, hands is taken conveniently, usability is also good, massage effect is good, clean the effect height, do not have the sense of being clamminess, usability is good.
Embodiment 3
Solid-state cleaning material:
(composition) (%)
(1) polyamide modified siloxanes
* 15.0
(2) three 2 ethyl hexanoic acid glyceride 69.9
(3) decamethylcyclopentaandoxane 15.0
(4) squalane 3.0
(5) cocoanut fatty acid diethanolamide 7.0
(6) oil of rosemary 0.1
*1Dow Corning 2-8178 gellant (manufacturing of DOW CORNING silicone company)
(preparation method)
Above-mentioned (1) to (6) after 100 ℃ of following even heating mix, are filled in the container, obtain rinsing solid shape cleaning material.
The solid shape cleaning material that the solid shape cleaning material of embodiment 3 is that high-temperature stability and appearance transparent are good, hands is taken conveniently, usability is also good, massage effect is good, clean the effect height, do not have the sense of being clamminess, usability is good.
Embodiment 4
Solid-state cleaning material:
(composition) (%)
(1) polyamide modified siloxanes
* 15.0
(2) three 2 ethyl hexanoic acid glyceride 69.9
(3) decamethylcyclopentaandoxane 15.0
(4) squalane 3.0
(5) cocoanut fatty acid diethanolamide 5.0
(6) polyethyleneglycol isostearate
* 32.0
(7) orange oil 0.1
*1Dow Corning 2-8178 gellant (manufacturing of DOW CORNING silicone company)
*(Japanese エ マ Le ジ ョ Application company makes 3PEIS-8EX; Organic value 670 inorganic values 685)
(preparation method)
Above-mentioned (1) to (7) after 100 ℃ of following even heating mix, are filled in the container, obtain the solid-state cleaning material of rinsing.
The solid shape cleaning material that the solid shape cleaning material of embodiment 4 is that high-temperature stability and appearance transparent are good, hands is taken conveniently, usability is also good, massage effect is good, clean the effect height, do not have the sense of being clamminess, usability is good.
Utilizability on the industry
Oily cleansing material of the present invention, Polyoxyethylene Lauryl Ether, for semi-solid to the solid shape, has simultaneously the good usability that cosmetics can not drip when using from hand, and massage effect, and be that the taste of outward appearance is good, high-temperature stability is Novel clean material preferably also.
Therefore, useful as the novel oiliness cleaning agent of the clean effect that can obtain simultaneously removing higher cosmetics of resistance to water and persistence etc. and massage effect.
Claims (8)
1. oily cleansing material is characterized in that: contain following composition (A)～(C):
(A) has polyamide modified siloxanes with the repetitive of following general expression (1) expression
In the formula, X represents to have the bivalent hydrocarbon radical of 1～30 carbon atom, and Y represents to have the bivalent hydrocarbon radical of 1～40 carbon atom, and m represents the integer of 1≤m≤700, and n represents the integer of 1≤n≤500;
(B) organic value is below 2000 and inorganic value is a surfactant below 1500; With
(C) ester oil,
For semi-solid to solid, shaped.
2. the oily cleansing material of claim 1, wherein the addition of mentioned component (A) is 0.5～50 quality %.
3. claim 1 or 2 oily cleansing material, wherein the addition of mentioned component (B) is 0.5～50 quality %.
4. the oily cleansing material of any one in the claim 1 to 3, wherein the addition of mentioned component (C) is 10～99 quality %.
5. the oily cleansing material of any one in the claim 1 to 4, its outward appearance is translucent for being clear to.
6. the oily cleansing material of any one in the claim 1 to 5, wherein mentioned component (C) is for having the ester oil of branched alkyl chain in the structure.
7. the oily cleansing material of any one in the claim 1 to 6 wherein further contains volatile siloxane.
8. the oily cleansing material of any one in the claim 1 to 7, wherein mentioned component (B) is for having the surfactant of acylamino-.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP076986/2004 | 2004-03-17 | ||
| JP2004076986 | 2004-03-17 | ||
| JP2004280862 | 2004-09-28 | ||
| JP280862/2004 | 2004-09-28 | ||
| PCT/JP2005/004632 WO2005087183A1 (en) | 2004-03-17 | 2005-03-16 | Oily cleansing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1933809A true CN1933809A (en) | 2007-03-21 |
| CN1933809B CN1933809B (en) | 2010-12-01 |
Family
ID=34975299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800087409A Expired - Fee Related CN1933809B (en) | 2004-03-17 | 2005-03-16 | Oily cleansing material |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP4990616B2 (en) |
| KR (1) | KR101160799B1 (en) |
| CN (1) | CN1933809B (en) |
| TW (1) | TW200533380A (en) |
| WO (1) | WO2005087183A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102055021B1 (en) * | 2013-10-28 | 2019-12-11 | 가부시키가이샤 미르본 | Oily composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61204227A (en) * | 1985-03-08 | 1986-09-10 | Toshiba Silicone Co Ltd | Polysiloxane-polyamide multi-block copolymer and production thereof |
| JPH0699275B2 (en) * | 1985-11-05 | 1994-12-07 | 株式会社コーセー | Non-water cleansing fee |
| JP3545574B2 (en) * | 1997-07-17 | 2004-07-21 | 株式会社資生堂 | Liquid oily skin cleanser |
| US6051216A (en) * | 1997-08-01 | 2000-04-18 | Colgate-Palmolive Company | Cosmetic composition containing siloxane based polyamides as thickening agents |
| JP3655564B2 (en) * | 2001-06-15 | 2005-06-02 | 株式会社資生堂 | Solid cleansing cosmetic |
| JP2003095919A (en) * | 2001-09-27 | 2003-04-03 | Kose Corp | Oil-base cleansing material |
-
2005
- 2005-03-16 KR KR1020067021367A patent/KR101160799B1/en not_active IP Right Cessation
- 2005-03-16 TW TW094108082A patent/TW200533380A/en unknown
- 2005-03-16 WO PCT/JP2005/004632 patent/WO2005087183A1/en active Application Filing
- 2005-03-16 CN CN2005800087409A patent/CN1933809B/en not_active Expired - Fee Related
- 2005-03-16 JP JP2006511050A patent/JP4990616B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TW200533380A (en) | 2005-10-16 |
| JP4990616B2 (en) | 2012-08-01 |
| JPWO2005087183A1 (en) | 2008-01-24 |
| CN1933809B (en) | 2010-12-01 |
| WO2005087183A1 (en) | 2005-09-22 |
| KR101160799B1 (en) | 2012-06-28 |
| KR20060130254A (en) | 2006-12-18 |
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