CN1930967A - 一种含嘧菌酯和稻瘟灵的杀菌组合物及其应用 - Google Patents
一种含嘧菌酯和稻瘟灵的杀菌组合物及其应用 Download PDFInfo
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Abstract
本发明公开了一种含嘧菌酯和稻瘟灵的杀菌组合物及其应用。该杀菌组合物含有嘧菌酯和稻瘟灵，其中嘧菌酯和稻瘟灵的重量比为1～40∶5～50。该组合物可应用于防治禾谷类、瓜果或蔬菜作物病害。该组合物适用范围广、成本低、效果好。
Description
技术领域
本发明涉及一种杀菌组合物及其用途，尤其是一种以嘧菌酯和稻瘟灵为主要活性成分的杀菌组合物及其应用。
背景技术
嘧菌酯(Azoxystrobin)是一种全新的β甲氧基炳烯酸脂类杀菌剂，具保护、治疗和铲除三重功效，通过抑制病菌的呼吸作用来破坏病菌的能量合成而丧失生命力。嘧菌酯具良好的作物安全性和非常突出的环境相容性。为得到最好的防效，在病害发生初期施药，喷雾时应注意加足水量，使作物表面药液充分覆盖。
嘧菌酯是由先正达公司开发产品，制剂产品为25％阿米西达悬浮剂，主要用于防治蔬菜、果蔬病害，由于其用药成本高，使用并不广泛。
稻瘟灵(isoprothiolane)是一种内吸性杀菌剂。对稻瘟病有特效，水稻植株吸收后，能抑制病菌侵入，尤其是抑制了磷酯N-甲基转移酶，从而抑制病菌生长，起到预防和治疗作用。稻瘟灵已经在中国水稻产区及其他农作物上长期、多次使用，这使的病菌对其抗性逐渐增强，使稻瘟灵防治病害的成本增加。
发明内容
本发明的目的是争对上述技术问题提供一种适用范围广、成本低、效果好的含嘧菌酯与稻瘟灵的植物杀菌组合物。
本发明还有一个目的是提供该杀菌组合物的用途。
本发明的目的是通过下列措施来实现的：
一种杀菌组合物，其特征在于含有嘧菌酯和稻瘟灵，其中嘧菌酯和稻瘟灵的重量比为1～40∶5～50。
一种杀菌组合物，其特征在于嘧菌酯和稻瘟灵的重量比为2～40∶8～40。
所述的杀菌组合物，其中嘧菌酯和稻瘟灵与已知的助剂和赋形剂复配成农药上允许的任意一种剂型。这些已知的助剂、赋型剂有分散剂、扩散剂、消泡剂、湿润剂、崩解剂等。
所述的杀菌组合物，其剂型是粉剂、可湿性粉剂、悬乳剂、乳油或颗粒剂。
所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用。
本发明的有益效果：
1、本发明所用的β甲氧基炳烯酸脂类，稻瘟灵是杂环类杀菌剂，两者具有相同的作用机制，两者相互混配不会产生抵触，可协同增效，减少用药量，降低成本。
2、本发明组合物适用范围增加，适用于防治禾谷类、各种瓜果、蔬菜的作物病害，特别是防治水稻、小麦、辣椒、香蕉、芒果、菠萝、黄瓜、番茄、烟草等作物病害，如水稻稻瘟病、瘟枯病、油菜菌核病、辣椒炭疽病、苦瓜黑星病、柑桔青霉病、黄瓜白粉病、番茄早疫病和晚疫病。
具体实施方式
以下结合实施例对本发明作进一步说明。实施例中剂型的制备方法均为常规方法。
实施例1：
将嘧菌酯2g、稻瘟灵25g、十二烷基苯磺酸钙3g、苯乙基酚聚氧乙烯醚2g，壬基酚聚氧乙烯醚1g、二甲苯加之100g，混合至均相液，制得组合物乳油。
实施例2：
将嘧菌酯5g、稻瘟灵20g、净洗剂LS(对甲氧基脂肪酸胺基苯磺酸钠)2g、扩散剂NNO(亚甲基双萘磺酸钠)4g、白炭黑5g，高岭土加至100g，混合物进行气流粉碎，制得可湿性粉剂。
实施例3：
将嘧菌酯3g、稻瘟灵22g、苯乙基酚聚氧乙烯醚膦酸酯3g，壬基酚聚氧乙烯醚2g，丙二醇5g、去离子水加之100g，利用高速均质机搅拌均匀，制得水乳剂。
实施例4：
将嘧菌酯25g、稻瘟灵25g、滑石粉50g混合均匀，制得粉剂。
实施例5：
将嘧菌酯25g、稻瘟灵25g、壬基酚聚氧乙烯醚4g、扩散剂NNO 3g、聚乙烯醇1.2g、碳酸氢钠1g、膨润土30g、高岭土加至100g，混合物经粉碎造粒制成可分散性粒剂。
实施例6：
将嘧菌酯3g、稻瘟灵30g、扩散剂NNO 3g、烷基酚聚氧乙烯醚2g、黄原胶0.15g、丙二醇5g、水适量混合，经湿法研磨，均化，制得水悬浮剂。
应用实施例：
用上述实施例制得的农药制剂防治水稻稻瘟病试验。
1、试验处理：本试验药剂用量根据各个成分的不同分别设三个处理浓度，对照药剂分别是市售农药40％稻瘟灵乳油(EC)和25％嘧菌酯水悬浮剂及空白清水试验。
2、试验方法 每个小区面积为66.7m2，重复3次；施药前调查及防治后的检查药效方法为：在试验处理区内随机取样5点，每点50穗，检查稻瘟病发生程度。
3、试验结果见下表：
| 处理(g/亩) | 药前病情指数(％) | 防效(％) | |||
| 药后5天 | 药后10天 | 药后14天 | |||
| 实施例1 | 60 | 72.0 | 72.3ab | 79.2ab | 73.4ab |
| 80 | 78.6 | 86.4a | 90.5a | 81.3a | |
| 100 | 69.4 | 88.3a | 92.4a | 83.2a | |
| 实施例2 | 60 | 72.9 | 69.7ab | 77.4b | 70.5b |
| 80 | 50.8 | 79.6a | 83.2a | 80.4a | |
| 90 | 59.3 | 83.1a | 93.4a | 89.9a | |
| 实施例3 | 60 | 61.0 | 63.2ab | 71.9b | 69.3b |
| 80 | 57.3 | 79.5a | 85.2a | 84.2ab | |
| 100 | 56.6 | 83.3a | 89.4a | 86.9a | |
| 40％稻瘟灵乳油 | 150 | 62.3 | 62.2c | 65.2c | 49.1c |
| 25％嘧菌酯水悬浮剂 | 120 | 60.3 | 63.7c | 65.8c | 59.9c |
| 空白清水对照 | 63.2 | - | - | - | |
注：a表示在α＝0.05水平上显著，b表示在α＝0.05水平上有差异，c表示在α＝0.05水平上不显著。
田间药效结果表明，嘧菌酯与稻瘟灵组合物对水稻稻瘟病具有优良的防治效果，防治效果均好于单剂品种。
Claims (5)
1、一种杀菌组合物，其特征在于含有嘧菌酯和稻瘟灵，其中嘧菌酯和稻瘟灵的重量比为1～40∶5～50。
2、根据权利要求1所述的杀菌组合物，其特征在于嘧菌酯和稻瘟灵的重量比为2～40∶8～40。
3、根据权利要求1或2所述的杀菌组合物，其特征在于嘧菌酯和稻瘟灵与已知的助剂和赋形剂复配成农药上允许的任意一种剂型。
4、根据权利要求3所述的杀菌组合物，其特征在于剂型是粉剂、可湿性粉剂、悬乳剂、乳油剂或颗粒剂。
5、权利要求1所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用。
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| CN103004768A (zh) * | 2011-10-11 | 2013-04-03 | 陕西上格之路生物科学有限公司 | 一种杀菌组合物 |
| AU2015202122B2 (en) * | 2010-03-03 | 2015-12-03 | Sumitomo Chemical Company, Limited | Plant disease controlling composition and method for controlling plant disease |
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| JP2011201857A (ja) * | 2010-03-03 | 2011-10-13 | Sumitomo Chemical Co Ltd | 植物病害防除組成物及び植物病害防除方法 |
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| CN1385070A (zh) * | 2001-05-10 | 2002-12-18 | 沈阳化工研究院 | 含氟吗啉的杀菌剂组合物 |
| DE10347090A1 (de) * | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| AU2015202122B2 (en) * | 2010-03-03 | 2015-12-03 | Sumitomo Chemical Company, Limited | Plant disease controlling composition and method for controlling plant disease |
| CN103004768A (zh) * | 2011-10-11 | 2013-04-03 | 陕西上格之路生物科学有限公司 | 一种杀菌组合物 |
| CN103004768B (zh) * | 2011-10-11 | 2014-06-11 | 陕西上格之路生物科学有限公司 | 一种杀菌组合物 |
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