CN100360019C - 一种含水杨菌胺和丙环唑的杀菌组合物及其应用 - Google Patents
一种含水杨菌胺和丙环唑的杀菌组合物及其应用 Download PDFInfo
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Abstract
本发明公开了一种含水杨菌胺和丙环唑的杀菌组合物及其应用。该杀菌组合物含有水杨菌胺和丙环唑，其中水杨菌胺和丙环唑重量比为1～30∶1～40。该组合物可应用于防治禾谷类、瓜果或蔬菜作物病害。该组合物适用范围广、成本低、效果好。
Description
技术领域
本发明涉及一种杀菌组合物及其用途，尤其是一种以水杨菌胺和丙环唑为主要活性成分的杀菌组合物及其应用。
技术背景
水杨菌胺(Trichlamide)属酰胺类杀菌剂，可防治白菜、甘蓝、芫箐等的根肿病、青碗豆根腐病、马铃薯疮痂病和粉痂病等多种病害。防治由立枯病引起的黄瓜苗猝倒病有较好的效果。但是水杨菌胺的原药国内生产较少，其价格极高，难以在农田防治病害方面使用。
丙环唑(propiconazol)是具有保护和治疗作用的内吸性杀菌剂，可被根、茎、叶部吸收，并能很快地在植物株体内向上传导，防治子囊菌，担子菌和半知菌引起的病害，属麦角甾醇生物合成的抑制剂。麦角甾醇在真菌细胞膜的构成中起重要作用，丙环唑通过干扰C14-去甲基化而妨碍真菌体内麦角甾醇的生物合成，从而破坏真菌的生长繁殖，起到保护和治疗作用。丙环唑除对藻菌病害无效外，对子囊菌属、担子菌数、半知菌属真菌在粮食作物、蔬菜、水果以及观赏植物上引起的多种病害有效。
丙环唑对于作物病害的病原菌有一定的治疗作用，但是单一使用丙环唑不能达到防治作物病害的作用。
发明内容
本发明的目的是针对上述技术问题提供一种适用范围广、成本低、效果好的含水杨菌胺与丙环唑的植物杀菌组合物。
本发明还有一个目的是提供该杀菌组合物的用途。
本发明的目的是通过下列措施来实现的：
一种杀菌组合物，它含有水杨菌胺与丙环唑，其中水杨菌胺与丙环唑的重量比为1～30∶1～40。
所述的杀菌组合物，其中水杨菌胺与丙环唑的重量比为3～15∶10～40。
所述的杀菌组合物，其中水杨菌胺和丙环唑与已知的助剂和赋形剂复配成农药上允许的任意一种剂型。这些已知的助剂、赋型剂有分散剂、扩散剂、消泡剂、湿润剂、崩解剂等。
所述的杀菌组合物，其剂型是粉剂、可湿性粉剂、悬乳剂、乳油或颗粒剂。
所述的杀菌组合物在防治禾谷类、瓜果或蔬菜作物病害方面的应用。
本发明的有益效果：
1、本发明所用的水杨菌胺是酰胺类杀菌剂，丙环唑是唑类杀菌剂，两者相互混配不会产生抵触，可协同增效，减少用药量，降低成本。
2、本发明组合物适用范围增加，适用于防治禾谷类、各种瓜果、蔬菜的作物病害，特别是防治水稻、小麦、辣椒、香蕉、芒果、菠萝、黄瓜、番茄、烟草等作物病害，如马铃薯疮痂病和粉痂病、小麦白粉病、水稻稻瘟病、瘟枯病、油菜菌核病、辣椒炭疽病、苦瓜黑星病、柑桔青霉病、黄瓜白粉病、番茄早疫病和晚疫病。
具体实施方式
以下结合实施例对本发明作进一步说明。实施例中剂型的制备方法均为常规方法。
实施例1：
将水杨菌胺5g、丙环唑10g、十二烷基苯磺酸钙3g、苯乙基酚聚氧乙烯醚2g，二甲苯加至100g，混合至均相液，制得组合物乳油。
实施例2：
将水杨菌胺2g、丙环唑15g、净洗剂LS(对甲氧基脂肪酸胺基苯磺酸钠)3g、扩散剂NNO(亚甲基双萘磺酸钠)2g、白炭黑5g，高岭土加至100g，混合物进行气流粉碎，制得可湿性粉剂。
实施例3：
将水杨菌胺10g、丙环唑5g、苯乙基酚聚氧乙烯醚膦酸酯3g，壬基酚聚氧乙烯醚2g，丙二醇5g、去离子水加至100g，利用高速均质机搅拌均匀，制得水乳剂。
实施例4：
将水杨菌胺12g、丙环唑6g、扩散剂NNO3g，滑石粉92g混合均匀，制得粉剂。
实施例6：
将水杨菌胺15g、丙环唑4g、净洗剂LS5g、羧甲基纤维素5g、轻质碳酸钙29.5g混合均匀，制得可湿性粉剂。
应用实施例：
用上述实施例制得的制剂防治水稻稻瘟病试验。
1、试验处理：本试验药剂用量根据各个成分的不同分别设三个处理浓度，对照药剂分别是市售农药15％水杨菌胺可湿性粉剂和25％丙环唑乳油(EC)及空白清水试验。
2、试验方法每个小区面积为66.7m2，重复3次；施药前调查及防治后的检查药效方法为：在试验处理区内随机取样5点，每点50穗，检查稻瘟病发生程度。
3、试验结果见下表：
| 处理(g/亩) | 药前病情指数(％) | 防效(％) | |||
| 药后5天 | 药后10天 | 药后14天 | |||
| 实施例1 | 80 | 72.0 | 72.3ab | 79.2ab | 73.4ab |
| 100 | 78.6 | 86.4a | 90.5a | 81.3a | |
| 120 | 69.4 | 88.3a | 92.4a | 83.2a | |
| 实施例2 | 60 | 72.9 | 69.7ab | 77.4b | 70.5b |
| 80 | 50.8 | 79.6a | 83.2a | 80.4a | |
| 90 | 59.3 | 83.1a | 93.4a | 89.9a | |
| 实施例3 | 60 | 61.0 | 63.2ab | 71.9b | 69.3b |
| 80 | 57.3 | 79.5a | 85.2a | 84.2ab | |
| 100 | 56.6 | 83.3a | 89.4a | 86.9a | |
| 15％水杨菌胺可湿性粉剂 | 120 | 62.3 | 62.2c | 65.2c | 49.1c |
| 25％丙环唑乳油 | 170 | 60.3 | 63.7c | 65.8c | 59.9c |
| 空白清水对照 | 63.2 | - | - | - | |
注：a表示在α＝0.05水平上显著，b表示在α＝0.05水平上有差异，c表示在α＝0.05水平上不显著。
田间药效结果表明，水杨菌胺与丙环唑组合物对稻瘟病具有优良的防治效果，防治效果均好于单剂品种。
Claims (5)
1、一种杀菌组合物，其特征在于含有水杨菌胺和丙环唑，其中水杨菌胺和丙环唑的重量比为1～30∶1～40。
2、根据权利要求1所述的杀菌组合物，其特征在于水杨菌胺和丙环唑的重量比为3～15∶10～40。
3、根据权利要求1或2所述的杀菌组合物，其特征在于水杨菌胺和丙环唑与已知的助剂和赋形剂复配成农药上允许的任意一种剂型。
4、根据权利要求3所述的杀菌组合物，其特征在于剂型是粉剂、可湿性粉剂、悬乳剂、乳油或颗粒剂。
5、权利要求1所述的杀菌组合物在防治水稻稻瘟病方面的应用。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943853A CN100360019C (zh) | 2005-09-15 | 2005-09-15 | 一种含水杨菌胺和丙环唑的杀菌组合物及其应用 |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943853A CN100360019C (zh) | 2005-09-15 | 2005-09-15 | 一种含水杨菌胺和丙环唑的杀菌组合物及其应用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1930971A CN1930971A (zh) | 2007-03-21 |
| CN100360019C true CN100360019C (zh) | 2008-01-09 |
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| CN108617676A (zh) * | 2018-08-20 | 2018-10-09 | 贵州道元生物技术有限公司 | 一种防治草坪镰刀枯萎病的复配杀菌组合物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1268292A (zh) * | 1999-03-31 | 2000-10-04 | 江苏诺华农化有限公司 | 丙环唑与三唑酮的复配制剂 |
| CN1628523A (zh) * | 2003-12-16 | 2005-06-22 | 武汉绿世纪生物工程有限责任公司 | 一种增效杀菌组合物及其泡腾剂 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1268292A (zh) * | 1999-03-31 | 2000-10-04 | 江苏诺华农化有限公司 | 丙环唑与三唑酮的复配制剂 |
| CN1628523A (zh) * | 2003-12-16 | 2005-06-22 | 武汉绿世纪生物工程有限责任公司 | 一种增效杀菌组合物及其泡腾剂 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108617676A (zh) * | 2018-08-20 | 2018-10-09 | 贵州道元生物技术有限公司 | 一种防治草坪镰刀枯萎病的复配杀菌组合物 |
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