CN1924035A - Composite agglomeration technology of iron powdered ore - Google Patents

Composite agglomeration technology of iron powdered ore Download PDF

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Publication number
CN1924035A
CN1924035A CN 200510032095 CN200510032095A CN1924035A CN 1924035 A CN1924035 A CN 1924035A CN 200510032095 CN200510032095 CN 200510032095 CN 200510032095 A CN200510032095 A CN 200510032095A CN 1924035 A CN1924035 A CN 1924035A
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iron
ore
sintering
accounts
bearing materials
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CN 200510032095
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CN100537794C (en
Inventor
姜涛
李光辉
胡友明
张克诚
邬捷鹏
黄柱成
范晓慧
朱德庆
张元波
许斌
郭宇峰
杨永斌
董海刚
刘牡丹
潘健
朱忠平
王海涛
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Central South University
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Central South University
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Abstract

The invention discloses a ferric powder composite block preparing technology, which is characterized by the following: separating fine ferric ore individually; preparing ball; blending rough particle with ferric powder and other raw materials; paving on the traditional sintering machine; inserting high-alkaline sintering ore of acid ball ore.

Description

Composite agglomeration technology of iron powdered ore
Technical field
The invention belongs to the ferrous metallurgy field, relate to a kind of utilization and contain powdered iron ore and prepare the method for blast furnace ironmaking with artificial composite block ore deposit.
Background technology
In recent years, also more and more higher to the requirement of iron-smelting raw material quality and quantity along with China's Iron And Steel Industry fast development, blast furnace ironmaking uses ore agglomerates's's (agglomerate and acidic pellet ore) ratio to surpass 90%.It is to adopt different prepared on different agglomeration equipment with pellet that used agglomerate is produced in ironmaking at present, and delivers to blast furnace hopper respectively, enters blast-furnace smelting after the batching in proportion.Practice shows: traditional sintering process must be produced high basicity sinter could guarantee sinter strength satisfying the requirement of blast-furnace smelting, and sintering process is not suitable for handling on a large scale the fine fraction iron ore concentrate; And the acid pellet ore production technology is to raw material granularity and moisture requirement harshness, to face the problem of resource scarcity, need to set up independently pelletizing plant simultaneously, the high temperature service investment is big, and newly-built pelletizing plant also is subjected to the restriction of conditions such as resource, factory site, thereby makes that fundamentally solving the acidic pellet ore for blast furnace problem of shortage has certain difficulty.
In addition,, cause both in blast furnace, to produce bigger segregation, influence blast furnace production process owing to agglomerate, the kinestate difference of pellet in State of Blast Furnace.
Summary of the invention
For rationally, make full use of fine ore and granule iron concentrate resource, solve the segregation problem that China's blast furnace is under-supply with acid burden material and blast furnace ironmaking uses agglomerate and pellet to exist, reduce sintering energy consumption, save the investment of founding the factory, realize blast furnace good quality and high output less energy-consumption production, special proposition the present invention.
Composite agglomeration technology of iron powdered ore, granule iron concentrate told separately be prepared into pelletizing, again with coarse-grained contain to be taped against after powdered iron ore and other raw materials mix carry out roasting on the conventional sintering machine, make by acidic pellet ore and embed high basicity sinter and the compound iron-smelting furnace charge formed.
It is that 30~60% granule iron concentrate adds binding agent and fuel is prepared burden, mixing that the present invention at first will account for all iron-bearing material per-cents, the binding agent add-on accounts for all iron-bearing materials 0~1.5%, the add-on of fuel accounts for all iron-bearing materials 0~1.5%, and compound is made diameter on balling disc be 8~16mm pelletizing; With accounting for all iron-bearing material per-cents is that 70~40% fine ore and other iron-bearing materials and flux and fuel are prepared burden, the flux add-on accounts for all iron-bearing materials 5.5~4.0%, fuel input accounts for all iron-bearing materials 5.0~3.5%, and by conventional sintering technology carry out once, the secondary combination treatment; With pelletizing and secondary compound mixing, carry out cloth, igniting, sintering on sinter machine then, whole grain gets complex sintered lump ore after cooling off.Whole grain back less than the fine ore of 5mm as returning charge.The sinter bed height is 500~900mm, igniting negative pressure 4~5kPa, ignition time 0.75~1min, sintering exhausting negative pressure 6~9kPa.
Described binding agent is wilkinite or unslaked lime.Described fuel is coke powder or pulverized anthracite.
Described granule iron concentrate be iron ore through ore grinding, sorting products obtained therefrom, general-200 order content are greater than 40%, the consumption in this technology accounts for 30%~60% of all iron-bearing materials.
Described iron ore fine ore refer generally to granularity be 0~8mm without ore grinding, sorting iron ore raw material, the consumption in this technology accounts for 70%~40% of all iron-bearing materials.
Still there are not any research of powdered iron ore composite agglomeration or the report of production at present both at home and abroad.
The present invention has following characteristics:
1) fully, rationally utilizes existing iron-bearing material
Adopt the present invention, with the fine concentrate of original sintering as the acid pellet raw materials for production, and with fine ore as alkaline agglomerate basic raw material, on a sinter machine, prepare the composite artificial lump ore of forming by acidic pellet ore and high basicity sinter simultaneously, make dissimilar iron ore raw materials obtain more rationally utilizing.
2) overcome in the fine concentrate sintering process bed permeability poor, be difficult to the agglomerating shortcoming
Adopt the present invention, allocate granule iron concentrate into an amount of binding agent and make ball separately, after being prepared into green-ball, again with other blended stock thorough mixing that constitutes by fine iron ore, flux etc., cloth, igniting, sintering, the raw materials for sintering of being made up of green-ball and granulation powder can improve the ventilation property of sinter bed greatly, significantly improves vertical sintering speed and utilization coefficient, has overcome the shortcoming that concentrate granulating efficiency difference in the conventional sintering technology causes the permeability of sintering material bed difference.
The shortcoming of existing charging segregation when 3) overcoming blast furnace and use agglomerate and pellet at the same time
Adopt the present invention, make in acidic pellet ore " embedding " the high basicity sinter matrix, form an integral body, fundamentally solved because blast furnace operating has been optimized in the segregation that both kinestates do not occur simultaneously.
4) significantly reduce sintering energy consumption, save the investment of founding the factory
Adopt the present invention, make that (800~900mm) become possibility to employing superelevation bed of material sintering technology.Because the improvement of bed permeability helps making full use of the auto accumulation heat effect of the bed of material, reduce the sintering solid energy consumption.And the significantly raising of productivity of sinter also can corresponding reduction SINTERING PRODUCTION energy consumption.In addition, this technology prepares high basicity sinter and acidic pellet ore simultaneously on sinter machine, to unconditionally building the iron and steel enterprise of chain grate-rotary kiln acid pellet factory or shaft furnace pelletizing plant in addition, can reduce investment outlay greatly.
Description of drawings
Fig. 1: process flow diagram of the present invention.
Embodiment
1. granule iron concentrate partly accounts for 35.5% in the sinter mixture, wherein adds 1.0% unslaked lime, is unworthy of refuel, makes ball in balling disc separately, and basicity keeps 0.6; Fine ore partly accounts for 64.5% in the compound, wherein allocates the unslaked lime of 5.0% coke powder and 4.38% into, and basicity is 3.2, carries out once mixing with secondary.The total alkalinity of control compound is 2.25.With green-ball and the secondary compound mixing for preparing, cloth in sintered cup, igniting, sintering.The sintering negative pressure is 7kPa, bed depth 700mm.The yield rate that can obtain agglomerate is 81.11%, and barrate strength is 63.52%, utilization coefficient 2.212t.m -2.h -1, vertical sintering speed 22.57mm/min.
2. granule iron concentrate partly accounts for 30% in the sinter mixture, wherein adds 1.0% coke powder, and not with addition of unslaked lime, basicity is 0.1, makes ball in balling disc separately; Fine ore partly accounts for 70% in the compound, wherein allocates the unslaked lime of 4.0% coke powder and 5.38% into, and basicity is 3.4, carries out once mixing with secondary.The total alkalinity of control material is 2.25.With green-ball and the secondary compound mixing for preparing, cloth in sintered cup, igniting, sintering.The sintering negative pressure is 8kPa, bed depth 600mm.The yield rate that can obtain agglomerate is 80.16%, and barrate strength is 61.07%, utilization coefficient 2.083t.m -2.h -1, vertical sintering speed 22.20mm/min.
3. granule iron concentrate partly accounts for 40% in the sinter mixture, adds 1.0% wilkinite, and basicity is 0.1, makes ball in balling disc separately; Fine ore partly accounts for 60% in the compound, wherein allocates the unslaked lime of 5.0% coke powder and 5.38% into, keeps basicity 3.4, carries out once mixing with secondary.The total alkalinity of control material is 2.25.With green-ball and the secondary compound mixing for preparing, cloth in sintered cup, igniting, sintering.The sintering negative pressure is 7kPa, bed depth 750mm.The yield rate that can obtain agglomerate is 78.51%, and barrate strength is 62.21%, utilization coefficient 1.985t.m -2.h -1, vertical sintering speed 21.79mm/min.
4. granule iron concentrate partly accounts for 50% in the sinter mixture, wherein adds 0.5% unslaked lime and 0.5% wilkinite, and not with addition of coke powder, basicity is 0.48, makes ball in balling disc separately; Fine ore partly accounts for 50% in the compound, wherein allocates the unslaked lime of 4.7% coke powder and 4.55% into, keeps basicity 2.90, carries out once mixing with secondary.The total alkalinity of control material is 2.0.With green-ball and the secondary compound mixing for preparing, cloth in sintered cup, igniting, sintering.The sintering negative pressure is 8kPa, bed depth 850mm.The yield rate that can obtain agglomerate is 80.38%, and barrate strength is 62.67%, utilization coefficient 1.747t.m -2.h -1, vertical sintering speed 18.35mm/min.

Claims (4)

1. composite agglomeration technology of iron powdered ore is characterized in that: will account for all iron-bearing material per-cents and be that 30~60% granule iron concentrate adds binding agent and fuel is prepared burden, mixing, compound is made diameter on balling disc be 8~16mm pelletizing; With accounting for all iron-bearing material per-cents is that 70~40% fine ore and other iron-bearing materials and flux and fuel are prepared burden, the flux add-on accounts for all iron-bearing materials 5.5~4.0%, fuel input accounts for all iron-bearing materials 5.0~3.5%, and by conventional sintering technology carry out once, the secondary combination treatment; With pelletizing and secondary compound mixing, on sinter machine, carry out cloth, igniting, sintering then, whole grain after cooling off, get complex sintered lump ore, the sinter bed height is 500~900mm, igniting negative pressure 4~5kPa, ignition time 0.75~1min, sintering exhausting negative pressure 6~9kPa.
2. method according to claim 1 is characterized in that: described binding agent is wilkinite or unslaked lime, and its add-on accounts for all iron-bearing materials 0~1.5%.
3. method according to claim 1 is characterized in that: described fuel is coke powder or pulverized anthracite, and its add-on accounts for all iron-bearing materials 0~1.5%.
4. method according to claim 1 is characterized in that: and described granule iron concentrate refers generally to-and 0.074mm content is greater than 40% iron ore raw material; It is 0~8mm iron ore raw material that described iron ore fine ore refers generally to granularity.
CNB2005100320956A 2005-09-01 2005-09-01 Composite agglomeration technology of iron powdered ore Active CN100537794C (en)

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Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100582256C (en) * 2007-11-30 2010-01-20 攀钢集团攀枝花钢铁研究院 Method for preparing low-silicon superhigh-alkalinity sintered ore
CN102296176A (en) * 2011-08-18 2011-12-28 内蒙古包钢钢联股份有限公司 Burden distribution method of composite agglomeration technology utilized for ultra-fine concentrate
CN102399979A (en) * 2011-11-10 2012-04-04 山西太钢不锈钢股份有限公司 Manufacturing method of low-alkalinity agglomerate
CN102872961A (en) * 2012-10-19 2013-01-16 中冶北方(大连)工程技术有限公司 Solid fuel crushing system and crushing process in sinter production
CN103160687A (en) * 2011-12-14 2013-06-19 鞍钢股份有限公司 Method for manufacturing crushing pellet sinter
CN103305688A (en) * 2013-06-14 2013-09-18 内蒙古包钢钢联股份有限公司 Industrial preparation method of high-fine-powder-rate ore agglomerates
CN103409616A (en) * 2013-09-05 2013-11-27 中南大学 Method for inhibiting low-temperature reduction degradation of sintering ore of iron ore
CN103614548A (en) * 2013-11-12 2014-03-05 山西太钢不锈钢股份有限公司 Method for producing sinter from hematite concentrate powder
CN104630449A (en) * 2015-02-09 2015-05-20 东北大学 Method for preparing sintered ore by using high-chromium-type vanadium-titanium mixture
CN104673948A (en) * 2015-01-30 2015-06-03 中南大学 Iron making furnace burden and mineralizing method of iron making furnace burden
CN104894367A (en) * 2014-03-05 2015-09-09 吕庆 Sintering technology for acidic pellet ore and alkaline material mixed ultra-thick material layer
CN105087907A (en) * 2015-09-25 2015-11-25 中冶东方工程技术有限公司 Ferrochromium fine ore sintering technology
CN105132672A (en) * 2015-09-10 2015-12-09 中南大学 Method for reducing emission of PM2.5 in iron ore sintering flue gas
CN105886753A (en) * 2016-06-22 2016-08-24 中冶华天工程技术有限公司 System and sintering process taking pellet return fines as embedded materials
CN106282546A (en) * 2015-06-05 2017-01-04 中冶长天国际工程有限责任公司 A kind of smoke gas circulating type prereduction sintering process and device
CN106337117A (en) * 2016-09-12 2017-01-18 鞍钢股份有限公司 Super-thick material layer sintering method for dual-alkalinity complex sintered ore
CN106544498A (en) * 2015-09-17 2017-03-29 宝山钢铁股份有限公司 A kind of iron dust containing high-efficiency sintered method
CN107012318A (en) * 2016-01-27 2017-08-04 鞍钢股份有限公司 A kind of sintered material fuel and its Adding Way
CN107304460A (en) * 2016-04-19 2017-10-31 中冶长天国际工程有限责任公司 A kind of iron ore prereduction sintering method and its device
CN108823404A (en) * 2018-06-15 2018-11-16 甘肃酒钢集团宏兴钢铁股份有限公司 A kind of iron ore pellets bentonite adhesive formula and preparation method thereof
CN109402382A (en) * 2018-10-25 2019-03-01 山西太钢不锈钢股份有限公司 It is sintered the sintering feed and sinter of preparation method for material and its preparation
CN109652643A (en) * 2019-01-30 2019-04-19 中南大学 High quality sinter and preparation method thereof for COREX ironmaking technique of fusion and reduction
CN111647739A (en) * 2020-06-17 2020-09-11 攀钢集团攀枝花钢铁研究院有限公司 Utilization method of iron-containing resource
CN111809044A (en) * 2020-07-27 2020-10-23 北京科技大学 Multi-source complex low-grade iron ore resource utilization method and high-quality composite iron-making furnace burden
CN111996367A (en) * 2020-08-27 2020-11-27 西安建筑科技大学 Method for utilizing superfine coal powder in sintering and sintering mixture
CN112760479A (en) * 2020-12-27 2021-05-07 中南大学 Sintering method for improving quality of vanadium-titanium sintered mineral product
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CN114574694A (en) * 2022-01-19 2022-06-03 中南大学 New method for sintering fine iron powder pellets
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Cited By (43)

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Publication number Priority date Publication date Assignee Title
CN100582256C (en) * 2007-11-30 2010-01-20 攀钢集团攀枝花钢铁研究院 Method for preparing low-silicon superhigh-alkalinity sintered ore
CN102296176A (en) * 2011-08-18 2011-12-28 内蒙古包钢钢联股份有限公司 Burden distribution method of composite agglomeration technology utilized for ultra-fine concentrate
CN102399979A (en) * 2011-11-10 2012-04-04 山西太钢不锈钢股份有限公司 Manufacturing method of low-alkalinity agglomerate
CN103160687B (en) * 2011-12-14 2014-12-31 鞍钢股份有限公司 Method for manufacturing crushing pellet sinter
CN103160687A (en) * 2011-12-14 2013-06-19 鞍钢股份有限公司 Method for manufacturing crushing pellet sinter
CN102872961A (en) * 2012-10-19 2013-01-16 中冶北方(大连)工程技术有限公司 Solid fuel crushing system and crushing process in sinter production
CN102872961B (en) * 2012-10-19 2014-12-03 中冶北方(大连)工程技术有限公司 Solid fuel crushing system and crushing process in sinter production
CN103305688A (en) * 2013-06-14 2013-09-18 内蒙古包钢钢联股份有限公司 Industrial preparation method of high-fine-powder-rate ore agglomerates
CN103409616A (en) * 2013-09-05 2013-11-27 中南大学 Method for inhibiting low-temperature reduction degradation of sintering ore of iron ore
CN103614548B (en) * 2013-11-12 2015-03-25 山西太钢不锈钢股份有限公司 Method for producing sinter from hematite concentrate powder
CN103614548A (en) * 2013-11-12 2014-03-05 山西太钢不锈钢股份有限公司 Method for producing sinter from hematite concentrate powder
CN104894367A (en) * 2014-03-05 2015-09-09 吕庆 Sintering technology for acidic pellet ore and alkaline material mixed ultra-thick material layer
CN104673948A (en) * 2015-01-30 2015-06-03 中南大学 Iron making furnace burden and mineralizing method of iron making furnace burden
CN104630449A (en) * 2015-02-09 2015-05-20 东北大学 Method for preparing sintered ore by using high-chromium-type vanadium-titanium mixture
CN106282546B (en) * 2015-06-05 2018-11-06 中冶长天国际工程有限责任公司 A kind of smoke gas circulating type prereduction sintering process
CN106282546A (en) * 2015-06-05 2017-01-04 中冶长天国际工程有限责任公司 A kind of smoke gas circulating type prereduction sintering process and device
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CN106544498B (en) * 2015-09-17 2018-07-06 宝山钢铁股份有限公司 A kind of iron dust containing high-efficiency sintered method
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CN105087907B (en) * 2015-09-25 2018-02-13 中冶东方工程技术有限公司 A kind of ferrochrome powder mine sintering technique
CN105087907A (en) * 2015-09-25 2015-11-25 中冶东方工程技术有限公司 Ferrochromium fine ore sintering technology
CN107012318A (en) * 2016-01-27 2017-08-04 鞍钢股份有限公司 A kind of sintered material fuel and its Adding Way
CN107304460A (en) * 2016-04-19 2017-10-31 中冶长天国际工程有限责任公司 A kind of iron ore prereduction sintering method and its device
CN107304460B (en) * 2016-04-19 2019-10-01 中冶长天国际工程有限责任公司 A kind of iron ore prereduction sintering method and its device
CN105886753A (en) * 2016-06-22 2016-08-24 中冶华天工程技术有限公司 System and sintering process taking pellet return fines as embedded materials
CN106337117B (en) * 2016-09-12 2018-05-29 鞍钢股份有限公司 A kind of super thick bed of material sintering method of double basicity composite sinters
CN106337117A (en) * 2016-09-12 2017-01-18 鞍钢股份有限公司 Super-thick material layer sintering method for dual-alkalinity complex sintered ore
CN108823404A (en) * 2018-06-15 2018-11-16 甘肃酒钢集团宏兴钢铁股份有限公司 A kind of iron ore pellets bentonite adhesive formula and preparation method thereof
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CN109402382B (en) * 2018-10-25 2020-07-03 山西太钢不锈钢股份有限公司 Sintered material preparation method, sintered material prepared by sintered material preparation method and sintered ore
CN109652643A (en) * 2019-01-30 2019-04-19 中南大学 High quality sinter and preparation method thereof for COREX ironmaking technique of fusion and reduction
CN111647739B (en) * 2020-06-17 2022-05-03 攀钢集团攀枝花钢铁研究院有限公司 Utilization method of iron-containing resource
CN111647739A (en) * 2020-06-17 2020-09-11 攀钢集团攀枝花钢铁研究院有限公司 Utilization method of iron-containing resource
CN111809044A (en) * 2020-07-27 2020-10-23 北京科技大学 Multi-source complex low-grade iron ore resource utilization method and high-quality composite iron-making furnace burden
CN111996367A (en) * 2020-08-27 2020-11-27 西安建筑科技大学 Method for utilizing superfine coal powder in sintering and sintering mixture
CN112760479A (en) * 2020-12-27 2021-05-07 中南大学 Sintering method for improving quality of vanadium-titanium sintered mineral product
CN112760479B (en) * 2020-12-27 2022-03-25 中南大学 Sintering method for improving quality of vanadium-titanium sintered mineral product
CN114763583A (en) * 2021-01-15 2022-07-19 宝山钢铁股份有限公司 Preparation method of iron ore powder cold briquetting and application of iron ore powder cold briquetting
CN114763583B (en) * 2021-01-15 2023-09-12 宝山钢铁股份有限公司 Preparation method of iron ore powder cold-pressed pellet and application of iron ore powder cold-pressed pellet
CN114574694A (en) * 2022-01-19 2022-06-03 中南大学 New method for sintering fine iron powder pellets
CN114574694B (en) * 2022-01-19 2023-08-22 中南大学 Novel method for sintering iron concentrate powder balls
CN114410962A (en) * 2022-01-26 2022-04-29 宝钢德盛有限公司 Method for preparing sulfur-containing composite sinter from stainless steel pickling sludge
CN114410962B (en) * 2022-01-26 2023-10-03 宝钢德盛有限公司 Method for preparing sulfur-containing composite sinter from stainless steel pickling sludge

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