CN1923929A - Nano composite hot melt type gage mark coating and preparation method thereof - Google Patents
Nano composite hot melt type gage mark coating and preparation method thereof Download PDFInfo
- Publication number
- CN1923929A CN1923929A CN 200510047609 CN200510047609A CN1923929A CN 1923929 A CN1923929 A CN 1923929A CN 200510047609 CN200510047609 CN 200510047609 CN 200510047609 A CN200510047609 A CN 200510047609A CN 1923929 A CN1923929 A CN 1923929A
- Authority
- CN
- China
- Prior art keywords
- hot melt
- melt type
- nano composite
- gage mark
- mark coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses nanometer composite heat-fused reticle paint and preparing method, which comprises the following parts: 10-25% filming material, 3-8% dye, 40-70% filler, 0.5-4% specific reinforced material, 14-25% glass microball and 1-5% other adjuvants, wherein the specific reinforced material contains nanometer fiber, nanometer whisker, micrometer fiber, micrometer whisker. The preparing method comprises the following steps: pouring the filming material in the composite autoclave; adding adjuvant; stirring evenly; adding dye, filler, glass microball and specific reinforced material; stirring evenly; packing.
Description
Technical field
The present invention relates to coating technology technology, be specially nano composite hot melt type gage mark coating and preparation method thereof.
Background technology
Hot melt type gage mark coating with its fast drying, be coated with characteristics such as thickness, long service life, reflective persistence are good, being used widely on China Higher level highway at present.Though there are two hang-ups in hot melt type gage mark coating in application: 1) speed of application is slow, and execution conditions are poor; 2) old line upgrades difficulty.Graticule in use weares and teares, aging coming off, and remove incomplete old line, needs to consume great amount of manpower and material resources, construction cost height.But do not replace owing to still have reliable product innovation at present, expressway particularly, must adopt reflector marking, and reflector marking needs glass microballon, this just requires the graticule coating to reach certain thickness, could guarantee the glass microballon difficult drop-off, thereby guarantees reflective persistence, this is that general normal temperature solvent based coating is beyond one's reach, so the dominant position of hot-melt traffic paint on China Higher level highway will continue for some time.
From existing literature report and patent formulation, this coating mainly adopts solid resins such as petroleum resin, rosin remodeling resin, xylene resin as filmogen, with titanium dioxide, zinc oxide, medium chrome yellow medium yellow, lead-chrome yellow etc. as pigment, light reflecting material multiselect glass microballon, multiselect dibenzoic acid lipid, mineral oil, plant wet goods are as softening agent.But these coating generally all have the following disadvantages, because the fragility of petroleum resin, modified rosin resin is generally all bigger, films and chap easily, wear no resistance, and are particularly outstanding in geographical environment or season that temperature is lower.To this, common adopt remedial measures be to improve the content of softening agent, but this is subjected to the restriction of aspects such as cost, workability again.At the problems referred to above, the present invention filters out the optimum proportion of resin, pigment, filler, auxiliary agent etc. by experiment, is equipped with an amount of extraordinary strongthener again, obtains a kind of hot melt gage mark coating with excellent abrasive resistance and freedom from cracking performance.
Summary of the invention
The purpose of this invention is to provide a kind of hot melt gage mark coating and preparation method thereof with excellent abrasive resistance and freedom from cracking performance.
Technical program of the present invention lies in:
Nano composite hot melt type gage mark coating and preparation method thereof, this coating be by 10～25% synthetic resins, 3～8% pigment, 40～70% fillers, and 0.5～4% extraordinary strongthener, 14～25% glass microballons, 1～5% auxiliary agent is formed.
Filmogen of the present invention (synthetic resins) is one or more of petroleum resin, vibrin, xylene resin, terpine resin, modified rosin resin.
Auxiliary agent used in the present invention comprises softening agent, toughner, anti-stick dirty agent, and by weight percentage, softening agent is 0.5～4%, and toughner is 0.5～3%, and anti-stick dirty agent is 0.4～3%.Described softening agent is a dioctyl sebacate, Octyl adipate, Dinonylphthalate, dioctyl terephthalate, dioctyl phthalate (DOP), trioctyl trimellitate, one or more of epoxy soybean oil; Described toughner adopts ethene-vinyl acetate elastomerics (EVA); Polyethylene wax is adopted in described anti-stick dirty agent.
Filler of the present invention is one or more of wollastonite powder, ground barium sulfate, lime carbonate, talcum powder, ground dolomite, quartz sand.Its size range is respectively 200～800 orders.
Glass microballon particle diameter of the present invention is 5 orders～120 orders.
Pigment of the present invention comprises white pigment or yellow ultramarine.Described white pigment adopts titanium dioxide, and it is blue or green blue to add micro-phthalein, addition be gross weight five thousandths～ten thousand/; Described yellow ultramarine adopts the sun-proof medium chrome yellow medium yellow.
A principal character one by one of the present invention is to contain in the described nano composite hot melt type gage mark coating extraordinary strongthener.Described extraordinary strongthener is one or more of nano-scale fiber, nano level whisker, micron order fiber, micron order whisker.For example: described fiber can adopt nano-grade glass fibre, micron order glass fibre, nano level polypropylene fibre, micron order polypropylene fibre, nano-scale carbon fiber, micron order carbon fiber; Described whisker can adopt Nano-class zinc oxide whisker, micron silicon whisker.Wherein, nano-grade glass fibre, nano level polypropylene fibre, nano-scale carbon fiber, nano silicone whisker, Nano-class zinc oxide diameter of whiskers are 20～100nm, and length-to-diameter ratio is 10～60000: 1.Wherein, micron order glass fibre, micron order polypropylene fibre, micron order carbon fiber, micron silicon whisker, micron order ZnOw diameter are 1～20 μ m, and length-to-diameter ratio is 1～300: 1.
The present invention also provides the preparation method of above-mentioned nano composite hot melt type gage mark coating, its preparation process is as follows: at first pour filmogen into mixing kettle, then add auxiliary agent, after stirring, under agitation condition, add pigment, filler, glass microballon, extraordinary strongthener successively, after stirring, go out the still pack and get final product.
The invention has the beneficial effects as follows:
Contain extraordinary strongthener among the present invention, the hot melt roadmarking that utilizes the present invention to prepare has excellent abrasion resisting, the ability of freedom from cracking, and it is fast, rapidly dry to have heat fused simultaneously, anti-discolouring, anti-efflorescence, water-fast, alkali proof advantage.
Embodiment
Except that specializing, the ratio that relates to is weight ratio among the present invention.
Embodiment 1
Take by weighing 13 kilograms of petroleum resin, 4 kilograms of titanium dioxides, 21.5 kilograms of wollastonite powder, 10 kilograms of water-ground limestones, 30 kilograms of quartz sands, 19.5 kilograms of glass microballons (particle diameter is 60 orders), 0.2 kilogram of nano-grade glass fibre, 0.3 kilogram of nano level polypropylene fibre, 1.2 kilograms of epoxy soybean oils, 0.8 kilogram on ethene-vinyl acetate elastomerics, 1.2 kilograms of polyethylene waxs, blue or green blue 15 grams of phthalein.During making, earlier petroleum resin are added in the container, spray epoxy soybean oil, under agitation condition, add titanium dioxide, wollastonite powder, water-ground limestone, quartz sand, glass fibre etc., dispersing and mixing is even, goes out the still packing, promptly gets the nano composite hot melt type gage mark coating of the present invention of about double centner.
Embodiment 2
Take by weighing 16 kilograms of petroleum resin, 4.5 kilograms of titanium dioxides, 31.5 kilograms of water-ground limestones, 30 kilograms of quartz sands, 16 kilograms of glass microballons (particle diameter is 40 orders), 0.1 kilogram of nano silicone whisker, 0.4 kilogram of Nano-class zinc oxide whisker, 1.5 kilograms of o-phthalic acid dibutyl esters, 0.5 kilogram on ethene-vinyl acetate elastomerics, 1.0 kilograms of polyethylene waxs, blue or green blue 19 grams of phthalein.During making, earlier petroleum resin are added in the container, spray o-phthalic acid dibutyl ester, under agitation condition, add titanium dioxide, water-ground limestone, quartz sand, glass fibre etc., dispersing and mixing is even, goes out the still packing, promptly gets the nano composite hot melt type gage mark coating of the present invention of about double centner.
Embodiment 3
Take by weighing modified rosin resin (sky, Linan, Zhejiang pine highway novel material company limited, trade mark LB2000B) 16 kilogram, 5 kilograms of medium chrome yellow medium yellows, 31 kilograms of water-ground limestones, 31 kilograms of quartz sands, 16 kilograms of glass microballons (particle diameter is 40 orders), 1.0 kilograms in micron order glass fibre, 1.0 kilograms of nano-grade glass fibres, 1.6 kilograms of epoxy soybean oils, 0.5 kilogram on ethene-vinyl acetate elastomerics, 1.2 kilograms of polyethylene waxs, blue or green blue 17 grams of phthalein.During making, earlier petroleum resin are added in the container, spray epoxy soybean oil, under agitation condition, add titanium dioxide, water-ground limestone, quartz sand, glass fibre etc., dispersing and mixing is even, goes out the still packing, promptly gets the nano composite hot melt type gage mark coating of the present invention of about double centner.
Embodiment 4
Take by weighing 10 kilograms of modified rosin resins (sky, Linan, Zhejiang pine highway novel material company limited, trade mark LB2000B), 8 kilograms of petroleum resin, 5 kilograms of titanium dioxides, 30 kilograms of water-ground limestones, 30 kilograms of quartz sands, 16 kilograms of glass microballons (particle diameter is 40 orders), 0.5 kilogram of nano-scale carbon fiber, 0.5 kilogram of Nano-class zinc oxide whisker, 1.0 kilograms of micron silicon whiskers, 1.6 kilograms of epoxy soybean oils, 0.5 kilogram on ethene-vinyl acetate elastomerics, 1.2 kilograms of polyethylene waxs, blue or green blue 17 grams of phthalein.During making, earlier petroleum resin are added in the container, spray epoxy soybean oil, under agitation condition, add titanium dioxide, water-ground limestone, quartz sand, glass fibre etc., dispersing and mixing is even, goes out the still packing, promptly gets the nano composite hot melt type gage mark coating of the present invention of about double centner.
Embodiment 5
Take by weighing modified rosin resin (sky, Linan, Zhejiang pine highway novel material company limited, trade mark LB2000B) 18 kilograms, 3 kilograms of xylene resins, 6 kilograms of titanium dioxides, 28 kilograms of water-ground limestones, 29 kilograms of quartz sands, 15 kilograms of glass microballons (particle diameter is 40 orders), 0.5 kilogram of nano-grade glass fibre, 0.5 kilogram of micron silicon whisker, 1.7 kilograms of o-phthalic acid dibutyl esters, 0.4 kilogram on ethene-vinyl acetate elastomerics, 1.1 kilograms of polyethylene waxs, blue or green blue 21 grams of phthalein.During making, earlier petroleum resin are added in the container, spray o-phthalic acid dibutyl ester, under agitation condition, add titanium dioxide, water-ground limestone, quartz sand, glass fibre etc., dispersing and mixing is even, goes out the still packing, promptly gets the nano composite hot melt type gage mark coating of the present invention of about double centner.
Comparative example 1
Take by weighing modified rosin resin (sky, Linan, Zhejiang pine highway novel material company limited, trade mark LB2000B) 16 kilogram, 5 kilograms of titanium dioxides, 31 kilograms of water-ground limestones, 31 kilograms of quartz sands, 16 kilograms of glass microballons (particle diameter is 40 orders), 1.6 kilograms of epoxy soybean oils, 0.5 kilogram on ethene-vinyl acetate elastomerics, 1.2 kilograms of polyethylene waxs, blue or green blue 17 grams of phthalein.During making, earlier petroleum resin are added in the container, spray epoxy soybean oil, under agitation condition, add titanium dioxide, water-ground limestone, quartz sand, glass fibre etc., dispersing and mixing is even, goes out the still packing, promptly gets the common hot melt gage mark coating that does not contain strongthener of about double centner.
Table 1
| Sticking tire time of drying/minute | Water tolerance | Alkali resistance | Levelling property | Wear resistance/mg (200 commentaries on classics/1000kg) | The surface crack of resistance to cleavage/generation after motorway was constructed 15 days | |
| Embodiment 1 | ≤3 | By | By | Difference | 43.2 | Many |
| Embodiment 2 | ≤3 | By | By | Very | 39.5 | Few |
| Embodiment 3 | ≤3 | By | By | Very | 31.0 | Seldom |
| Embodiment 4 | ≤3 | By | By | Excellent | 34.3 | Few |
| Embodiment 5 | ≤3 | By | By | Excellent | 37.2 | Few |
| Comparative example 1 | ≤3 | By | By | Very | 45.9 | A lot |
Claims (9)
1, a kind of nano composite hot melt type gage mark coating is characterized in that by weight percentage, it basic composition is: filmogen 10～25%, pigment 3～8%, filler 40～70%, extraordinary strongthener 0.5～4%, glass microballon 14～25%, other auxiliary agent 1～5%.
2, nano composite hot melt type gage mark coating according to claim 1 is characterized in that: employed extraordinary strongthener is one or more of nano-scale fiber, nano level whisker, micron order fiber, micron order whisker.
3, nano composite hot melt type gage mark coating according to claim 1 is characterized in that: employed filmogen is one or more of petroleum resin, vibrin, xylene resin, terpine resin, modified rosin resin.
4, nano composite hot melt type gage mark coating according to claim 1, it is characterized in that: employed auxiliary agent comprises softening agent, toughner, anti-stick dirty agent, and by weight percentage, softening agent is 0.5～4%, toughner is 0.5～3%, and anti-stick dirty agent is 0.4～3%.
5, nano composite hot melt type gage mark coating according to claim 3, it is characterized in that: described softening agent is a dioctyl sebacate, Octyl adipate, Dinonylphthalate, dioctyl terephthalate, dioctyl phthalate (DOP), trioctyl trimellitate, one or more of epoxy soybean oil; Described toughner adopts the ethene-vinyl acetate elastomerics; Polyethylene wax is adopted in described anti-stick dirty agent.
6, nano composite hot melt type gage mark coating according to claim 1 is characterized in that: described pigment comprises white pigment or yellow ultramarine.
7, nano composite hot melt type gage mark coating according to claim 5 is characterized in that: described white pigment adopts titanium dioxide, and it is blue or green blue to add micro-phthalein, addition be gross weight five thousandths～ten thousand/; Described yellow ultramarine is selected the sun-proof medium chrome yellow medium yellow for use.
8, nano composite hot melt type gage mark coating according to claim 1 is characterized in that: described filler is one or more of wollastonite powder, ground barium sulfate, lime carbonate, talcum powder, ground dolomite, quartz sand.
9, the preparation method of the described nano composite hot melt type gage mark coating of one of a kind of claim 1～8, it is characterized in that preparation process is as follows: at first pour filmogen into mixing kettle, then add auxiliary agent, after stirring, under agitation condition, add pigment, filler, glass microballon, extraordinary strongthener successively, after stirring, go out the still pack and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100476095A CN100406528C (en) | 2005-11-02 | 2005-11-02 | Nano composite hot melt type gage mark coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100476095A CN100406528C (en) | 2005-11-02 | 2005-11-02 | Nano composite hot melt type gage mark coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1923929A true CN1923929A (en) | 2007-03-07 |
| CN100406528C CN100406528C (en) | 2008-07-30 |
Family
ID=37816760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100476095A Expired - Fee Related CN100406528C (en) | 2005-11-02 | 2005-11-02 | Nano composite hot melt type gage mark coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100406528C (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067057B (en) * | 2007-05-29 | 2010-06-23 | 东莞市拓扑光电科技有限公司 | Nanometer hot melt road line paint additive |
| CN101338152B (en) * | 2007-07-20 | 2010-11-17 | 潘东海 | Road reflective marker line coating |
| CN103409064A (en) * | 2013-07-18 | 2013-11-27 | 丹阳市永生涂料有限公司 | Formula of propylene white primer paint |
| CN103951931A (en) * | 2014-05-16 | 2014-07-30 | 保定维特瑞交通设施工程有限责任公司 | Heat-fused highly-wear-resisting anti-pollution white traffic marking material and preparation method thereof |
| CN103980747A (en) * | 2014-05-16 | 2014-08-13 | 保定维特瑞交通设施工程有限责任公司 | Heat melting high-wear-resistant anti-pollution yellow traffic marking material and preparation method thereof |
| CN104059466A (en) * | 2014-06-23 | 2014-09-24 | 蓝星（成都）新材料有限公司 | Hot melt coating for road sign and preparation method thereof |
| CN104312251A (en) * | 2014-10-30 | 2015-01-28 | 东北大学 | Method for preparing energy-saving and environment-friendly heat fusing mark coating |
| CN104387891A (en) * | 2014-11-06 | 2015-03-04 | 浙江兄弟路标涂料有限公司 | Environment-friendly heating liner paint |
| CN104388015A (en) * | 2014-11-06 | 2015-03-04 | 浙江兄弟路标涂料有限公司 | Pavement marking |
| CN104592852A (en) * | 2015-01-21 | 2015-05-06 | 西北民族大学 | Hot-melting road-marking coating and preparation method thereof |
| CN105348975A (en) * | 2015-10-15 | 2016-02-24 | 武汉纵横交通工程有限公司 | Vibrating hot-melt marking paint composition |
| CN105348976A (en) * | 2015-10-15 | 2016-02-24 | 武汉纵横交通工程有限公司 | Reflective hot-melt marking paint composition |
| CN105925115A (en) * | 2016-06-08 | 2016-09-07 | 杭州阑氏道路工程技术有限公司 | Coating for hot melting luminous mark line and preparation method thereof |
| CN106046899A (en) * | 2016-07-01 | 2016-10-26 | 深圳市烯世传奇科技有限公司 | Light reflecting coating based on graphene powder and used for roads and preparation method of light reflecting coating |
| CN107325495A (en) * | 2017-07-07 | 2017-11-07 | 砀山润龙公共交通有限公司 | A kind of antifreeze low temperature resistant traffic marking material and preparation method thereof |
| CN108659686A (en) * | 2018-05-25 | 2018-10-16 | 北京路桥方舟交通科技发展有限公司 | Heat reflective type road mark paint |
| CN109971296A (en) * | 2019-04-12 | 2019-07-05 | 河南天华交通科技有限公司 | A kind of hot melt type gage mark coating and preparation method thereof |
| CN110997818A (en) * | 2017-08-16 | 2020-04-10 | 科腾聚合物有限责任公司 | Granular pavement marking binders and related methods |
| CN111500145A (en) * | 2020-05-28 | 2020-08-07 | 河南三艾斯交通科技有限公司 | Wear-resistant hot-melt marking paint and preparation method thereof |
| CN112480775A (en) * | 2020-11-18 | 2021-03-12 | 东南大学 | Microwave easy-to-clean modified hot-melt marked line for cement pavement and preparation method thereof |
| CN112521825A (en) * | 2020-12-08 | 2021-03-19 | 辽宁省高速公路运营管理有限责任公司 | Composite enhanced hot-melt marking paint and preparation method thereof |
| CN112552774A (en) * | 2020-12-10 | 2021-03-26 | 湖南长达交通设施有限公司 | High-wear-resistance hot-melt coating and preparation method thereof |
| CN112662267A (en) * | 2020-12-31 | 2021-04-16 | 山西中涂交通科技股份有限公司 | Continuous reflective high-standard hot-melt coating |
| CN113025152A (en) * | 2021-04-25 | 2021-06-25 | 北京市政路桥管理养护集团有限公司 | Anti-cracking hot-melt reflective marking paint |
| CN114438915A (en) * | 2020-11-05 | 2022-05-06 | 洛阳尖端技术研究院 | All-weather active luminous marking device and preparation method thereof |
| CN114539868A (en) * | 2022-02-21 | 2022-05-27 | 南宁程润金交通设备有限公司 | High-performance hot-melt road sign coating and preparation method thereof |
| CN114736582A (en) * | 2022-04-28 | 2022-07-12 | 四川兄弟路标科技有限公司 | Preparation method of durable and environment-friendly road hot-melt marking paint |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079487A (en) * | 1992-06-03 | 1993-12-15 | 黄志启 | Powdery hot-melt road pattern sign coating and making method |
| JP4674546B2 (en) * | 2003-06-30 | 2011-04-20 | 日本ゼオン株式会社 | Acid-modified petroleum resin and heat-sealing type road surface marking material |
-
2005
- 2005-11-02 CN CNB2005100476095A patent/CN100406528C/en not_active Expired - Fee Related
Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067057B (en) * | 2007-05-29 | 2010-06-23 | 东莞市拓扑光电科技有限公司 | Nanometer hot melt road line paint additive |
| CN101338152B (en) * | 2007-07-20 | 2010-11-17 | 潘东海 | Road reflective marker line coating |
| CN103409064A (en) * | 2013-07-18 | 2013-11-27 | 丹阳市永生涂料有限公司 | Formula of propylene white primer paint |
| CN103951931B (en) * | 2014-05-16 | 2016-03-02 | 保定维特瑞交通设施工程有限责任公司 | A kind of heat fusing high abrasion antipollution White traffic graticule material and preparation method thereof |
| CN103980747A (en) * | 2014-05-16 | 2014-08-13 | 保定维特瑞交通设施工程有限责任公司 | Heat melting high-wear-resistant anti-pollution yellow traffic marking material and preparation method thereof |
| CN103951931A (en) * | 2014-05-16 | 2014-07-30 | 保定维特瑞交通设施工程有限责任公司 | Heat-fused highly-wear-resisting anti-pollution white traffic marking material and preparation method thereof |
| CN103980747B (en) * | 2014-05-16 | 2016-04-20 | 保定维特瑞交通设施工程有限责任公司 | A kind of heat fusing high abrasion antipollution yellow traffic graticule material and preparation method thereof |
| CN104059466A (en) * | 2014-06-23 | 2014-09-24 | 蓝星（成都）新材料有限公司 | Hot melt coating for road sign and preparation method thereof |
| CN104312251A (en) * | 2014-10-30 | 2015-01-28 | 东北大学 | Method for preparing energy-saving and environment-friendly heat fusing mark coating |
| CN104312251B (en) * | 2014-10-30 | 2016-07-27 | 东北大学 | A kind of preparation method of energy saving and environment friendly hot melt gage mark coating |
| CN104387891A (en) * | 2014-11-06 | 2015-03-04 | 浙江兄弟路标涂料有限公司 | Environment-friendly heating liner paint |
| CN104388015A (en) * | 2014-11-06 | 2015-03-04 | 浙江兄弟路标涂料有限公司 | Pavement marking |
| CN104592852A (en) * | 2015-01-21 | 2015-05-06 | 西北民族大学 | Hot-melting road-marking coating and preparation method thereof |
| CN105348975A (en) * | 2015-10-15 | 2016-02-24 | 武汉纵横交通工程有限公司 | Vibrating hot-melt marking paint composition |
| CN105348976A (en) * | 2015-10-15 | 2016-02-24 | 武汉纵横交通工程有限公司 | Reflective hot-melt marking paint composition |
| CN105925115A (en) * | 2016-06-08 | 2016-09-07 | 杭州阑氏道路工程技术有限公司 | Coating for hot melting luminous mark line and preparation method thereof |
| CN106046899A (en) * | 2016-07-01 | 2016-10-26 | 深圳市烯世传奇科技有限公司 | Light reflecting coating based on graphene powder and used for roads and preparation method of light reflecting coating |
| CN106046899B (en) * | 2016-07-01 | 2021-04-20 | 深圳市烯世传奇科技有限公司 | Graphene powder-based road reflective coating and preparation method thereof |
| CN107325495A (en) * | 2017-07-07 | 2017-11-07 | 砀山润龙公共交通有限公司 | A kind of antifreeze low temperature resistant traffic marking material and preparation method thereof |
| CN110997818A (en) * | 2017-08-16 | 2020-04-10 | 科腾聚合物有限责任公司 | Granular pavement marking binders and related methods |
| CN108659686A (en) * | 2018-05-25 | 2018-10-16 | 北京路桥方舟交通科技发展有限公司 | Heat reflective type road mark paint |
| CN108659686B (en) * | 2018-05-25 | 2020-01-14 | 北京路桥方舟交通科技发展有限公司 | Hot-melt reflective road marking paint |
| CN109971296A (en) * | 2019-04-12 | 2019-07-05 | 河南天华交通科技有限公司 | A kind of hot melt type gage mark coating and preparation method thereof |
| CN111500145A (en) * | 2020-05-28 | 2020-08-07 | 河南三艾斯交通科技有限公司 | Wear-resistant hot-melt marking paint and preparation method thereof |
| CN114438915A (en) * | 2020-11-05 | 2022-05-06 | 洛阳尖端技术研究院 | All-weather active luminous marking device and preparation method thereof |
| CN112480775B (en) * | 2020-11-18 | 2021-09-28 | 东南大学 | Microwave easy-to-clean modified hot-melt marked line for cement pavement and preparation method thereof |
| CN112480775A (en) * | 2020-11-18 | 2021-03-12 | 东南大学 | Microwave easy-to-clean modified hot-melt marked line for cement pavement and preparation method thereof |
| CN112521825A (en) * | 2020-12-08 | 2021-03-19 | 辽宁省高速公路运营管理有限责任公司 | Composite enhanced hot-melt marking paint and preparation method thereof |
| CN112552774A (en) * | 2020-12-10 | 2021-03-26 | 湖南长达交通设施有限公司 | High-wear-resistance hot-melt coating and preparation method thereof |
| CN112662267A (en) * | 2020-12-31 | 2021-04-16 | 山西中涂交通科技股份有限公司 | Continuous reflective high-standard hot-melt coating |
| CN113025152A (en) * | 2021-04-25 | 2021-06-25 | 北京市政路桥管理养护集团有限公司 | Anti-cracking hot-melt reflective marking paint |
| CN114539868A (en) * | 2022-02-21 | 2022-05-27 | 南宁程润金交通设备有限公司 | High-performance hot-melt road sign coating and preparation method thereof |
| CN114736582A (en) * | 2022-04-28 | 2022-07-12 | 四川兄弟路标科技有限公司 | Preparation method of durable and environment-friendly road hot-melt marking paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100406528C (en) | 2008-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100406528C (en) | Nano composite hot melt type gage mark coating and preparation method thereof | |
| KR930006570B1 (en) | Transparent non-vitreous ceramic particles | |
| CN107573777B (en) | A kind of hot melt type gage mark coating and preparation method thereof | |
| CN100475922C (en) | Nano composite normal temperature type gage mark coating and preparation method thereof | |
| CN111518455B (en) | High-standard hot-melt marking paint and preparation method and application thereof | |
| CN102070981A (en) | Ultraviolet curing paint and preparation method and application thereof | |
| CN104109453B (en) | Composite functional type agricultural machinery clear top powder coatings and production technology thereof | |
| CN101614835B (en) | Retro-reflective structure body and preparation method thereof | |
| CN102409403A (en) | Preparation method of self-supporting monocrystal photonic crystal | |
| CN106085006A (en) | Glass surface inkjet printing bismuth silicon boron system low melting point ink and preparation method thereof | |
| US11860388B2 (en) | Polymer compatible heat fused retroreflective bead | |
| KR102070122B1 (en) | Inorganic paint composition for coating image film and construction method of scenery type finish layer using the same | |
| KR101045007B1 (en) | Method for road line marking | |
| CN111138807A (en) | Epoxy resin mud for hand-carved model and preparation method thereof | |
| KR101176043B1 (en) | Liquid paint composition containing the mixed beads for traffic lane | |
| CN102993864A (en) | Aqueous traffic paint and preparation method thereof | |
| KR20040021885A (en) | Resin mortar composition for construction and floor operating method using the same | |
| CN103666181A (en) | Preparation method of anti-pollution road marking paint | |
| CN103666180A (en) | Anti-pollution road marking paint | |
| CN1566238A (en) | Thermoplastic fast-dry traffic paint | |
| KR102482273B1 (en) | Road marking hot melt tape with high non-slip properties | |
| CN109971413B (en) | Preparation method of high-refractive-index LED packaging adhesive material | |
| CN103387759A (en) | Organic/inorganic hybrid hardening agent, and preparation method and application thereof | |
| CN111635688A (en) | Environment-friendly hot-melt marking paint and preparation method thereof | |
| CN101585677A (en) | Method for producing attapulgite pavement marking paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080730 Termination date: 20171102 |