CN1921202A - Fuel cell with water-cooled power converter - Google Patents

Fuel cell with water-cooled power converter Download PDF

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Publication number
CN1921202A
CN1921202A CNA2006101213848A CN200610121384A CN1921202A CN 1921202 A CN1921202 A CN 1921202A CN A2006101213848 A CNA2006101213848 A CN A2006101213848A CN 200610121384 A CN200610121384 A CN 200610121384A CN 1921202 A CN1921202 A CN 1921202A
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CN
China
Prior art keywords
unit
fuel
water
water tank
hydrogen
Prior art date
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Pending
Application number
CNA2006101213848A
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Chinese (zh)
Inventor
金泰元
崔弘
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LG Electronics Inc
LG Corp
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LG Electronics Inc
LG Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Electronics Inc, LG Chemical Co Ltd filed Critical LG Electronics Inc
Publication of CN1921202A publication Critical patent/CN1921202A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02MAPPARATUS FOR CONVERSION BETWEEN AC AND AC, BETWEEN AC AND DC, OR BETWEEN DC AND DC, AND FOR USE WITH MAINS OR SIMILAR POWER SUPPLY SYSTEMS; CONVERSION OF DC OR AC INPUT POWER INTO SURGE OUTPUT POWER; CONTROL OR REGULATION THEREOF
    • H02M7/00Conversion of ac power input into dc power output; Conversion of dc power input into ac power output
    • H02M7/003Constructional details, e.g. physical layout, assembly, wiring or busbar connections
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029Heat exchange using liquids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/40Combination of fuel cells with other energy production systems
    • H01M2250/405Cogeneration of heat or hot water
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04052Storage of heat in the fuel cell system
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B90/00Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02B90/10Applications of fuel cells in buildings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Fuel Cell (AREA)

Abstract

A fuel cell having a water type radiating device comprising a fuel supply unit for supplying a certain rate of fuel, a reformer for generating a hydrogen containing gas containing a hydrogen gas by receiving the fuel from the fuel supply unit, a stack unit for generating an electricity and heat according to an electrochemical reaction between the hydrogen containing gas generated from the reformer and oxygen separately supplied a water tank connected to one side of the stack unit for heating water contained therein by use of the heat generated from the stack unit, a power converter connected to one side of the stack unit for converting the electricity generated from the stack unit into an alternating current and having a plurality of radiating plates, and a forcible radiating unit for forcibly cooling the radiating plates and for heating the water contained in the water tank.

Description

Fuel cell with water-cooled power converter
Technical field
The present invention relates to a kind of fuel cell with water-cooled (water type) heat abstractor, more specifically, relate to and a kind ofly can come the water stored in the heating fuel inside battery water tank (or water receptacle), and can utilize water-cooled radiating structure to improve the fuel cell with water-cooled power converter of radiating effect by collecting (fetching) heat through heating panel is dispersed into fuel cell outside.
Background technology
Recently, heating power that produces from the power plant or waterpower are in order to produce the electric power that uses the building.The electric energy that produces from the power plant is supplied to the building (for example every institute house) that is positioned at various places through power transmission line, and the electric energy of being supplied is in order to operation television set, refrigerator, air-conditioning etc., thereby makes life convenient.
But in order to obtain used electric energy, combustion oil or coal are electric energy with thermal power transfer to produce heat energy then in the power plant, therefore, compare with the fuel energy of using, and generating efficiency is quite low.In addition, very big energy loss takes place in the electric energy that the power plant is produced when power transmission line is supplied to the building of various places, therefore, compare with the fuel energy of consumption, has reduced the efficient of the electric energy that uses in each building.That is to say that the electric energy that uses in each building is to obtain by consuming very a large amount of fuel energy.In addition, the burning of a large amount of fuel such as oil or coal can produce pollutant, thereby causes environmental pollution.
Therefore, recently just in development of fuel cells, so that very high energy efficiency can be provided, and produce eco-friendly electric energy.This fuel cell is meant fuel that utilization is without interruption from the outside and the electrochemical reaction between the air, chemical energy contained in the fuel directly is converted to the device of electric energy.
Fig. 1 is the schematic diagram that the fuel cell structure with heat abstractor of prior art is shown, and Fig. 2 is the stereogram that cooling plate structure among Fig. 1 is shown.
As shown in the figure, the fuel cell of prior art comprises: fuel supply unit 10 is used to supply a certain amount of fuel; Reformer 20 is used for producing hydrogen-containing gas and the heat that comprises hydrogen by receiving fuel from fuel supply unit 10; Heap unit 30, the electrochemical reaction that is used between hydrogen that produces by reformer 20 and the oxygen of supplying separately produces electric power and heat; Power supply changeover device (power converter) 40, the power conversions that is used for heap unit 30 is produced is alternating current (AC); And water tank (or water receptacle) 50, the heat that is used to utilize heap unit 30 to produce comes hot-water supply.
Reformer (reformer) 20 comprises: desulfurization reactor (DS) 21 is used to introduce water, air and from fuel supply unit 10 supplied fuel, thereby removes contained sulphur in the fuel; Steam reformer (SR) 22 is used to make fuel and steam generation reaction; High-temperature steam reactor (HTSR) 23 is used to make carbon monoxide and steam generation reaction; Low Temperature Steam reactor (LTSR) 24 is used for carbon monoxide is converted to carbon dioxide; Partial oxidation reactor (PRO) 25 is used for unoxidized carbon monoxide is converted to carbon dioxide; Reacting furnace 26 is used for producing hydrogen by reforming process and Hydrogen upgrading process from fuel; And burner 27, by being connected, be used for to reacting furnace 26 supply institute calorific requirements with reacting furnace 26 contacts.
Heap unit 30 is realized by piling up a plurality of element cells, and is comprised anode 31, electrolytic film 32 and negative electrode 33.
Power supply changeover device 40 is meant a kind of device that is used for the direct current (DC) that heap unit 30 produces is converted to the alternating current that can be used for family.Be provided with a plurality of device (not shown) that are used to move transducer 41 and inverter 42 in the power supply changeover device 40.Each device all is coupled to heating panel, is dispersed into the outside with the heat that will be produced.
The a plurality of fin 43a that upwards have certain-length along the thickness direction of heating panel 43 are arranged on the upper end face of heating panel 43, thereby carry out the heat radiation of heating panel 43 fast by the contact area that increases between heating panel 43 and the air.Heat emission fan 44 is arranged on a side of heating panel 43, in order to cooling heat dissipation plate 43.
The bottom that connecting line 60 will be piled unit 30 is connected with the bottom of water tank 50, and the water in the water tank 50 flows into and outflow through this connecting line 60, thereby the heat that can utilize heap unit 30 to produce comes water contained in the heating water tank 50.By connecting line 60 being connected to the bottom of water tank 50, by the convection current of water, colder water level is in the downside of water tank 50, and the water level of heat side thereon heats the used time thereby reduced to water.
But,, be to utilize the fin 43a of heating panel 43 and heat emission fan 44 that the heat that power supply changeover device 40 produces is discharged power supply changeover device 40 for the fuel cell of prior art.Here, the air cooling method that uses in the heating panel 43 does not provide quick cooling effect.In addition, the heat that power supply changeover device 40 produces is not collected but is discharged away, and this causes the utilization ratio of energy low.
Summary of the invention
Therefore, the object of the present invention is to provide a kind of fuel cell with water-cooled power converter, it can come the middle water of storing of heating fuel inside battery water tank (or water receptacle) by collecting (fetching) heat outside heating panel is dispersed into fuel cell, and can utilize water-cooled radiating structure to improve radiating effect.
For obtaining these and other advantage, and according to the intent of the present invention, as this concrete implements and broadly described, the invention provides a kind of fuel cell with water-cooled power converter, comprising: fuel supply unit is used to supply the fuel of certain ratio; Reformer is used for producing the hydrogen-containing gas that comprises hydrogen by receiving fuel from this fuel supply unit; The heap unit, the electrochemical reaction that is used between hydrogen-containing gas that produces by this reformer and the oxygen of supplying separately produces electric power and heat; Water tank, the side that it is connected to this heap unit, the heat that is used for utilizing this heap unit to produce heats the contained water of this water tank; Power supply changeover device, the side that it is connected to this heap unit, the power conversions that is used for this heap unit is produced is an alternating current, and this power supply changeover device has a plurality of heating panels; And the forced heat radiation unit, be used for forcing to cool off described heating panel and being used to heat the contained water of this water tank.
By below in conjunction with accompanying drawing for specific descriptions of the present invention, aforementioned and other purpose, feature, scheme and advantage of the present invention will be more obvious.
Description of drawings
Accompanying drawing is included in the specification and constitutes the part of specification, and in order to provide for further understanding of the present invention, accompanying drawing illustrates embodiments of the invention, and is used from the explanation inventive principle with specification one.
In the accompanying drawings:
Fig. 1 is the schematic diagram that the fuel cell structure with heat abstractor of prior art is shown;
Fig. 2 is the stereogram that cooling plate structure among Fig. 1 is shown;
Fig. 3 is the schematic diagram that the fuel cell structure that has heat abstractor according to an embodiment of the invention is shown; And
Fig. 4 is the stereogram that heating panel among Fig. 3 is shown.
Embodiment
Describe the present invention in detail below with reference to accompanying drawing.
The invention provides a kind of fuel cell with water-cooled power converter, comprising: fuel supply unit is used to supply the fuel of certain ratio; Reformer is used for producing the hydrogen-containing gas that comprises hydrogen by receiving fuel from fuel supply unit; The heap unit, the electrochemical reaction that is used between hydrogen-containing gas that produces by reformer and the oxygen of supplying separately produces electric power and heat; Water tank, the side that it is connected to the heap unit, the heat that is used for utilizing the heap unit to produce comes the contained water of heating water tank; Power supply changeover device, the side that it is connected to the heap unit, the power conversions that is used for the heap unit is produced is an alternating current, and this power supply changeover device has a plurality of heating panels; And the forced heat radiation unit, be used for forcing the cooling heat dissipation plate and be used for the contained water of heating water tank.
The present invention is described in detail below with reference to accompanying drawing.
Fig. 3 is the schematic diagram that the fuel cell structure that has heat abstractor according to an embodiment of the invention is shown, and Fig. 4 is the stereogram that heating panel among Fig. 3 is shown.
As shown in the figure, comprise according to the fuel cell with water-cooled power converter of the embodiment of the invention: fuel supply unit 100 is used to supply the fuel of certain ratio; Reformer 200 is used for producing the hydrogen-containing gas that comprises hydrogen by receiving fuel from fuel supply unit 100; Heap unit 300, the electrochemical reaction that is used between hydrogen-containing gas that produces by reformer 200 and the oxygen of supplying separately produces electric power and heat; Water tank 500, the side that it is connected to heap unit 300, the heat that is used for utilizing heap unit 300 to produce heats the contained water of this water tank; Power supply changeover device 400, the side that it is connected to heap unit 300, the power conversions that is used for heap unit 300 is produced is an alternating current, and this power supply changeover device 400 has a plurality of heating panels 430; And the forced heat radiation unit, be used for forcing cooling heat dissipation plate 430 and be used for the contained water of heating water tank 500.
Reformer 200 comprises: desulfurization reactor (DS) 210 is used to introduce water, air and from fuel supply unit 100 supplied fuel, thereby removes contained sulphur in the fuel; Steam reformer (SR) 220 is used to make fuel and steam generation reaction; High-temperature steam reactor (HTSR) 230 is used to make carbon monoxide and steam generation reaction; Low Temperature Steam reactor (LTSR) 240 is used for carbon monoxide is converted to carbon dioxide; Partial oxidation reactor (PRO) 250 is used for unoxidized carbon monoxide is converted to carbon dioxide; Reacting furnace 260 is used for producing hydrogen by reforming process and Hydrogen upgrading process from fuel; And burner 270, by being connected, be used for to reacting furnace 260 supply institute calorific requirements with reacting furnace 260 contacts.
Heap unit 300 is realized by piling up a plurality of element cells, and is comprised anode 310, electrolytic film 320 and negative electrode 330.
Power supply changeover device 400 is meant a kind of device that is used for the direct current (DC) that heap unit 300 produces is converted to the alternating current (AC) that can be used for family.Be provided with a plurality of device (not shown) that are used to move transducer 410 and inverter 420 in the power supply changeover device 400.Each device all is coupled to heating panel 430, is dispersed into the outside with the heat that will be produced.
The a plurality of fin 431 that upwards have certain-length along the thickness direction of heating panel 430 are arranged on the upper end face of heating panel 430, thereby carry out the heat radiation of heating panel 430 fast by the contact area that increases between heating panel 430 and the air.A plurality of patchholes 432 form a side of passing heating panel 430, thereby are connected to branched pipe (divergence pipe) 700, this branched pipe 700 explanation after a while in the mode of inserting.
Connecting line 600 is installed in the bottom of heap unit 300 and the bottom of water tank 500, and the water in the water tank 500 flows into and outflow through this connecting line 600, thereby the heat that can utilize heap unit 300 to produce comes water contained in the heating water tank 500.By connecting line 600 being connected to the bottom of water tank 500, by the convection current of water, colder water level is in the downside of water tank 500, and the water level of heat side thereon heats the used time thereby reduced to water.
The forced heat radiation unit is meant branched pipe 700, and it comes out from connecting line 600 branches that connect heap unit 300 and water tank 500, merges mutually with connecting line 600 through heating panel 430 then, thereby contacts with heating panel 430.Branched pipe 700 is inserted in the patchhole 432 of heating panel 430 to contact with heating panel 430, is connected to a side of connecting line 600 then, so that the water in the water tank can therefrom flow through.In addition, the forced heat radiation unit can pass through heating panel 430 in the mode of zigzag.
In the fuel cell according to the embodiment of the invention of this kind structure with forced heat radiation unit, when fuel supply unit 100 with water and fuel (for example, methyl alcohol, liquefied natural gas (being LNG), gasoline etc.) when being supplied to reformer 200, in reformer 200, mix and carry out steam reformation and partial oxidation, thereby produce hydrogen-containing gas, reaction heat and the water that contains hydrogen.
In receiving the heap unit 300 of hydrogen-containing gas, hydrogen H 2Be supplied to anode 310 1 sides, to produce electrochemical oxidation reactions.Then, hydrogen H 2Be ionized and be hydrogen ion H +With electronics e -Thereby, oxidized.The hydrogen ion H that ionization goes out +Shift to negative electrode 330 through electrolytic film 320, electronics e -Shift to anode 310 through electrolytic film 320, thereby produce electric power, heat and water.The electric power that heap unit 300 produces is converted to alternating current (AC) by power supply changeover device 400, with the operation electronic product.
The connecting line 600 of water through being arranged between heap unit 300 and the water tank 500 contained in the water tank 500 flows into heap unit 300, thereby the heat that is produced by heap unit 300 heats.Water after the heating is discharged heap unit 300.The water of discharging contacts with heating panel 430 through branched pipe 700, is heated to higher temperature then, flows into water tank 500 subsequently.Carry out these processes repeatedly, thus contained water in the heating water tank quickly.In addition, compare with the air cooling method that uses in the fuel cell of prior art, do not use independent heat emission fan, heating panel 430 just can be cooled off quickly.
Because the present invention can be specifically embodied as various ways and does not break away from its spirit or inner characteristic, therefore be to be understood that: unless otherwise prescribed, the foregoing description is not subject to any aforementioned details, and should be explained widely in the spirit and scope that claims limited of enclosing; Therefore, fall into whole variations in the boundary of claims or its equivalent scope and revise the claims of all should being enclosed and contain.

Claims (5)

1, a kind of fuel cell with water-cooled power converter comprises:
Fuel supply unit is used to supply the fuel of certain ratio;
Reformer is used for producing the hydrogen-containing gas that comprises hydrogen by receiving fuel from this fuel supply unit;
The heap unit, the electrochemical reaction that is used between hydrogen-containing gas that produces by this reformer and the oxygen of supplying separately produces electric power and heat;
Water tank is connected to a side of this heap unit, and the heat that is used for utilizing this heap unit to produce heats the contained water of this water tank;
Power supply changeover device is connected to a side of this heap unit, and the power conversions that is used for this heap unit is produced is an alternating current, and this power supply changeover device has a plurality of heating panels; And
The forced heat radiation unit is used for forcing to cool off described heating panel and being used to heat the contained water of this water tank.
2, fuel cell as claimed in claim 1, wherein, this forced heat radiation unit is a branched pipe, and this branched pipe is from being used for the connecting line branch that this heap unit is connected with this water tank is come out, merge mutually with this connecting line through described heating panel then, thereby contact with described heating panel.
3, fuel cell as claimed in claim 2, wherein this branched pipe passes through described heating panel in the mode of zigzag.
4, fuel cell as claimed in claim 3, wherein, a plurality of patchholes are formed on a side of described heating panel, and increasing the contact area between described heating panel and this branched pipe, and this branched pipe inserts described a plurality of inserting in the hole.
5, a kind of fuel cell with water-cooled power converter comprises:
Fuel supply unit is used to supply the fuel of certain ratio;
Reformer is used for producing the hydrogen-containing gas that comprises hydrogen by receiving fuel from this fuel supply unit;
The heap unit, the electrochemical reaction that is used between hydrogen-containing gas that produces by this reformer and the oxygen of supplying separately produces electric power and heat;
Water tank is connected to a side of this heap unit;
Power supply changeover device is connected to a side of this heap unit, and the power conversions that is used for this heap unit is produced is an alternating current, and this power supply changeover device has a plurality of heating panels; And
Branched pipe, from being used for the connecting line branch that this heap unit is connected with this water tank is come out, the mode with zigzag merges with this connecting line mutually through described heating panel then.
CNA2006101213848A 2005-08-22 2006-08-21 Fuel cell with water-cooled power converter Pending CN1921202A (en)

Applications Claiming Priority (2)

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KR20050077000 2005-08-22

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EP (1) EP1758193A1 (en)
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US8921102B2 (en) * 2005-07-29 2014-12-30 Gpb Scientific, Llc Devices and methods for enrichment and alteration of circulating tumor cells and other particles
EP2589668A1 (en) 2006-06-14 2013-05-08 Verinata Health, Inc Rare cell analysis using sample splitting and DNA tags
US20080050739A1 (en) * 2006-06-14 2008-02-28 Roland Stoughton Diagnosis of fetal abnormalities using polymorphisms including short tandem repeats
US8137912B2 (en) 2006-06-14 2012-03-20 The General Hospital Corporation Methods for the diagnosis of fetal abnormalities
US20080070792A1 (en) 2006-06-14 2008-03-20 Roland Stoughton Use of highly parallel snp genotyping for fetal diagnosis
CA3069082C (en) 2008-09-20 2022-03-22 The Board Of Trustees Of The Leland Stanford Junior University Noninvasive diagnosis of fetal aneuploidy by sequencing
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JP3400220B2 (en) * 1995-11-30 2003-04-28 株式会社東芝 Fuel cell power generation equipment
DE19961825A1 (en) * 1999-12-21 2001-06-28 Valeo Klimasysteme Gmbh Cooling-heating circuit with two coolers
NL1014400C1 (en) * 2000-02-17 2001-08-20 Nedstack Holding B V Polymer electrolyte fuel cell based heat power generators.
JP2002075427A (en) * 2000-09-05 2002-03-15 Toyota Industries Corp Fuel cell power generation system
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US20070042238A1 (en) 2007-02-22
EP1758193A1 (en) 2007-02-28
RU2006130313A (en) 2008-02-27

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