CN1918227A - Nanoclay-containing composites and methods of making them - Google Patents
Nanoclay-containing composites and methods of making them Download PDFInfo
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- CN1918227A CN1918227A CN 200480029263 CN200480029263A CN1918227A CN 1918227 A CN1918227 A CN 1918227A CN 200480029263 CN200480029263 CN 200480029263 CN 200480029263 A CN200480029263 A CN 200480029263A CN 1918227 A CN1918227 A CN 1918227A
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- nanoclay
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Abstract
Description
Table 1 | ||||||
The enriched material prescription that is used for TPO | ||||||
Component, weight % | 1 | 2 | 3 | 4 | ||
Nanoclay | 40 | 40 | 40 | 40 | ||
PP-g-MAH | 10 | 10 | 10 | 10 | ||
The EO copolymer rubber | 15 | 10 | 5 | 0 | ||
PP | 35 | 40 | 45 | 50 | ||
Commercial source | ||||||
Component and purposes | The source | Trade mark | ||||
Nanoclay improves rigidity | Nanocor | 144P | ||||
Ethylene-octene copolymer improves impact | DuPont-Dow | EG8180 | ||||
PP-g-MAH (maleinization polypropylene), the dispersing nanometer clay | Crompton | PolyBond PBX5104 | ||||
PP (polypropylene) is as the enriched material carrier | ||||||
TPO (TPO) | Basell | CA387:Adflex KS311P; With Pro-Fax SG702 |
Table 2 | ||||
The enriched material preparation condition | ||||
Embodiment | 1 | 2 | 3 | 4 |
The enriched material mixing equipment | Werner ﹠ Pfleiderer ZSK 25 corotations change twin screw extruder | |||
The enriched material mixing temperature | 200℃ | |||
The enriched material mixing velocity | 1100rpm | |||
The interpolation order | Except that ethylene-octene copolymer, all components adds together, and the downstream adds the EO multipolymer, promptly thoroughly disperses the back to add in carrier at nanoclay and dispersion agent |
Table 3 | ||||
The TPO mixture | ||||
Embodiment | Enriched material | Weight % | TPO | Weight % |
Comparative examples A | -- | -- | CA387P | 100 |
5 | 1 | 20 | CA387P | 80 |
6 | 2 | 20 | CA387P | 80 |
7 | 3 | 20 | CA387P | 80 |
8 | 4 | 20 | CA387P | 80 |
Comparative example B | -- | -- | Pro-Fax SG702 | 100 |
9 | 1 | 20 | Pro-Fax SG702 | 80 |
10 | 2 | 20 | Pro-Fax SG702 | 80 |
11 | 3 | 20 | Pro-Fax SG702 | 80 |
12 | 4 | 20 | Pro-Fax SG702 | 80 |
Comparative example C | -- | -- | Adflex KS311P | 100 |
13 | 1 | 20 | Adflex KS311P | 80 |
14 | 2 | 20 | Adflex KS311P | 80 |
15 | 3 | 20 | Adflex KS311P | 80 |
16 | 4 | 20 | Adflex KS311P | 80 |
17 | 2 | 10 | Adflex KS311P | 90 |
Embodiment | ASTM D790(PSI) | ASTM D3837 (joule) | ||||||
Young's modulus | Yielding stress | Instrument impacts under the room temperature | 0 ℃ of instrument impacts | -30 ℃ of instruments impact | ||||
Peak value | Peak value | Peak value | Total amount | Peak value | Total amount | |||
Comparative examples A | 120000 | 3380 | 16.7 | 30.7 | 24.9 | 45 | ||
5 | 149000 | 3540 | 16.8 | 30.5 | 24.6 | 39.3 | ||
6 | 157000 | 3740 | 16.6 | 30.2 | 22.6 | 27 | ||
7 | 158000 | 3850 | 16.6 | 29.7 | 13.8 | 14.4 | ||
8 | 179000 | 4110 | 16.5 | 28.7 | 3.9 | 4.9 | ||
Comparative example B | 155000 | 4770 | 18.8 | 33.8 | 22.4 | 41.3 | ||
9 | 233000 | 5530 | 20.1 | 31.1 | 24.1 | 37.4 | ||
10 | 239000 | 5650 | 21.1 | 30.3 | 18.5 | 22.5 | ||
11 | 244000 | 5720 | 20.6 | 28.5 | ||||
12 | 258000 | 5980 | 20.6 | 24.3 | 11.5 | 12.1 | ||
Comparative example C | 78400 | 2530 | 13.8 | 25 | ||||
13 | 123000 | 3040 | 16.1 | 26.9 | ||||
14 | 130000 | 3220 | 15.7 | 26.4 | ||||
15 | 133000 | 3330 | 15.1 | 26.2 | ||||
16 | 149000 | 3540 | 15.4 | 25.4 | ||||
17 | 109000 | 3010 | 15.2 | 26.4 |
Table 4 | ||
Commercial source | ||
Component and purposes | The source | Trade mark |
Nanoclay improves rigidity | Nanocor | 144P |
Ethylene-octene copolymer improves impact | DuPont-Dow | EG8180 |
PP-g-MAH (maleinization polypropylene), the dispersing nanometer clay | Crompton | PolyBond PBX5104 |
Polypropylene (melt flow index 12) | Basell | Pro-Fax 6323 |
The blend of Irganox 1010 and Irgafos 168 processing stabilizers | Ciba | B-225 |
PP (melt flow index 60) | Various | PP 60MFI |
Table 5 | ||||||||||||||
Mixing equipment | Werner﹠Pfleiderer ZSK 25 corotations change twin screw extruder | |||||||||||||
Mixing temperature | 200℃ | |||||||||||||
Prescription and interpolation order | ||||||||||||||
Prescription A | Prescription B | Prescription C | Prescription D | Prescription E | Prescription F (contrast) | Prescription G | ||||||||
Component | Weight % | Component | Weight % | Component | Weight % | Component | Weight % | Component | Weight % | Component | Weight % | Component | Weight % | |
I.44P Nanomer | 12 | I.44P Nanomer | 12 | I.44P Nanomer | 12 | I.44P Nanomer | 12 | I.44P Nanomer | 12 | I.44P Nanomer | 12 | 1.44P Nanomer | 12 | |
Ingress's feeder 1 | ||||||||||||||
B-255 | 0.3 | B-255 | 0.3 | B-255 | 0.3 | B-255 | 0.3 | B-255 | 0.3 | B-255 | 0.3 | B-255 | 0.3 | |
PBX5104 | 9 | PBX5104 | 9 | PBX5104 | 9 | PBX5104 | 9 | PBX5104 | 9 | PBX5104 | 9 | PBX5104 | 9 | |
Profax6323 | 18.7 | Profax6323 | 9.35 | Profax6323 | 0 | Profax6323 | 38.7 | Profax6323 | 20 | Profax6323 | 58.7 | Profax6323 | 8.7 | |
PP 60MFI | 0 | PP 60MFI | 9.35 | PP 60MFI | 18.7 | PP 60MFI | 0 | PP 60MFI | 18.7 | Engage8180 | 20 | PP 60MFI | 0 | |
At lateral parts fed downstream device 2 | ||||||||||||||
Engage8180 | 20 | Engage8180 | 20 | Engage8180 | 20 | Engage8180 | 20 | Engage8180 | 20 | Engage8180 | 20 | |||
Profax6323 | 40 | Profax6323 | 40 | Profax6323 | 40 | Profax6323 | 20 | Profax6323 | 20 | Profax6323 | 50 |
Table 6 | |||||||||||||||
Ratio | Modulus in flexure (± standard deviation) | Modulus (± standard deviation) | Stress (± standard deviation) | Elongation % (± standard deviation) | The Izod impact machine (Notched Izod) (± standard deviation) of otch is arranged if having, fracture | ||||||||||
Embodiment | Prescription | Ratio * | Mixing velocity (rpm) | Input speed (Lbs/hr) | ASTM D790 (psi *1000) | ASTM D638 (psi *1000) | ASTM D638 (psi) | ASTM D638 (inch/inch) | ASTM D256 (ft-lb/inch) | ||||||
18 | A | 40/60 | 500 | 40 | 302 | ±10 | 388 | ±21 | 4600 | ±200 | 7.2 | ±0.2 | 5.3 | ±0.5 | Part |
19 | A | 40/60 | 1000 | 40 | 266 | ±2 | 355 | ±3 | 4330 | ±12 | 9.0 | ±0.1 | 10.3 | ±0.2 | Part |
20 | A | 40/60 | 1000 | 80 | 263 | ±8 | 349 | ±5 | 4170 | ±22 | 7.8 | ±0.1 | 6.3 | ±0.5 | Part |
21 | A | 40/60 | 500 | 80 | 228 | ±1 | 304 | ±5 | 3610 | ±29 | 7.3 | ±0.1 | 3.7 | ±0.2 | Part |
22 | B | 40/60 | 500 | 80 | 272 | ±1 | 360 | ±7 | 4250 | ±8 | 8.3 | ±0.1 | 8.3 | ±0.4 | Part |
23 | B | 40/60 | 1000 | 80 | 255 | ±4 | 347 | ±16 | 3809 | ±29 | 8.0 | ±0.3 | 6.9 | ±0.4 | Part |
24 | B | 40/60 | 1000 | 40 | 232 | ±3 | 355 | ±12 | 4080 | ±2 | 8.1 | ±0.1 | 2.2 | ±0.2 | Part |
25 | B | 40/60 | 500 | 40 | 254 | ±1 | 306 | ±7 | 3690 | ±6 | 7.8 | ±0.1 | 5.8 | ±0.1 | Part |
26 | C | 40/60 | 1000 | 40 | 246 | ±2 | 344 | ±5 | 3870 | ±45 | 9.0 | ±0.3 | 12.0 | ±0.9 | Non-cracking |
27 | C | 40/60 | 500 | 80 | 231 | ±2 | 309 | ±12 | 3480 | ±61 | 7.2 | ±0.1 | 6.7 | ±0.4 | Part |
28 | D | 60/40 | 500 | 40 | 280 | ±4 | 366 | ±12 | 4480 | ±30 | 7.8 | ±0.1 | 5.9 | ±0.4 | Part |
29 | D | 60/40 | 1000 | 40 | 266 | ±4 | 346 | ±5 | 4300 | ±6 | 8.9 | ±0.1 | 6.9 | ±0.2 | Part |
30 | D | 60/40 | 1000 | 80 | 241 | ±1 | 319 | ±7 | 3870 | ±15 | 8.3 | ±0.2 | 6.1 | ±0.3 | Part |
31 | D | 60/40 | 500 | 80 | 222 | ±2 | 284 | ±6 | 3480 | ±7 | 7.8 | ±0.1 | 4.3 | ±0.3 | Part |
32 | E | 60/40 | 1000 | 80 | 289 | ±3 | 378 | ±8 | 4480 | ±19 | 6.7 | ±0.1 | 4.5 | ±0.3 | Part |
33 | E | 60/40 | 1000 | 40 | 257 | ±1 | 332 | ±5 | 3970 | ±9 | 7.8 | ±0.1 | 6.6 | ±0.3 | Part |
Comparative Example D | F | 100/0 | 500 | 40 | 292 | ±2 | 383 | ±8 | 4500 | ±5 | 7.8 | ±0.2 | 7.0 | ±0.5 | Part |
Comparative Example E | F | 100/0 | 1000 | 40 | 243 | ±2 | 321 | ±9 | 3810 | ±13 | 9.6 | ±0.1 | 7.5 | ±0.4 | Part |
Comparative Example F | F | 100/0 | 1000 | 80 | 237 | ±1 | 313 | ±3 | 3720 | ±13 | 9.4 | ±0.2 | 6.7 | ±0.3 | Part |
34 | G | 30/70 | 1000 | 80 | 298 | ±1 | 390 | ±10 | 4470 | ±20 | 7.6 | ±0.1 | 7.2 | ±0.4 | Part |
Table 7 | |||||
The preparation of embodiment 35 | |||||
Component and purposes | Weight % | Trade mark | The source | ||
Nanoclay improves rigidity | 12 | 144P | Nanocor | ||
Propylene copolymer | 84.2 | Inspire 114 | Dow | ||
PP-g-MAH (maleinization polypropylene), the dispersing nanometer clay | 3 | PolyBond PBX5104 | Crompton | ||
Distearyl-sulfo--dipropionate | 0.5 | DSTDP | Various | ||
The blend of Irganox 1010 and Irgafos 168 processing stabilizers | 0.3 | B-225 | Ciba | ||
Table 8 | |||||
Additional parameter | Ratio | 40/60 | |||
Mixing velocity (rpm) | 1000 | ||||
Input speed (Pounds Per Hour) | 80 | ||||
Modulus in flexure (± standard deviation) | ASTM D790(psi *1000) | 323±1 | |||
Modulus (± standard deviation) | ASTM D638(psi *1000) | 401±7 | |||
Stress (± standard deviation) | ASTM D638(psi *) | 4790±14 | |||
Elongation % (± standard deviation) | ASTM D638 (inch/inch) | 8.4±0.2 | |||
The Izod impact machine (± standard deviation) that otch is arranged, if having, fracture | ASTM D256 (ft-lb/inch) | 5.9 ± 0.3, the part fracture |
Claims (12)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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US50967903P | 2003-10-08 | 2003-10-08 | |
US60/509,679 | 2003-10-08 | ||
US60/538,534 | 2004-01-22 | ||
US60/539,250 | 2004-01-26 |
Publications (1)
Publication Number | Publication Date |
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CN1918227A true CN1918227A (en) | 2007-02-21 |
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CN 200480029263 Pending CN1918227A (en) | 2003-10-08 | 2004-10-01 | Nanoclay-containing composites and methods of making them |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108779388A (en) * | 2016-03-22 | 2018-11-09 | 沙特阿拉伯石油公司 | The in-situ preparation of nanoclay drilling fluid |
-
2004
- 2004-10-01 CN CN 200480029263 patent/CN1918227A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108779388A (en) * | 2016-03-22 | 2018-11-09 | 沙特阿拉伯石油公司 | The in-situ preparation of nanoclay drilling fluid |
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Assignee: POLYONE POLYMER (SHANGHAI) CO., LTD. Assignor: PolyOne polymer Ltd. Contract fulfillment period: 2007.01.01 to 2019.05.19 Contract record no.: 2007990000060 Denomination of invention: Composite containing nano clay and preparation method thereof Granted publication date: unauthorized License type: General permission, cross licensing Record date: 20071008 Assignee: Puliwan polymer (Shenzhen) Co., Ltd. Assignor: PolyOne polymer Ltd. Contract fulfillment period: 2007.01.01 to 2019.05.19 Contract record no.: 2007990000061 Denomination of invention: Composite containing nano clay and preparation method thereof Granted publication date: unauthorized License type: General permission, cross licensing Record date: 20071008 Assignee: Polyone Polymer (Suzhou) Ltd. Assignor: PolyOne polymer Ltd. Contract fulfillment period: 2007.01.01 to 2019.05.19 Contract record no.: 2007990000062 Denomination of invention: Composite containing nano clay and preparation method thereof Granted publication date: unauthorized License type: General permission, cross licensing Record date: 20071008 |
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Free format text: COMMON LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.1.1 TO 2019.5.19 Name of requester: PLIVAN POLYMER ( SHENZHEN ) CO., LTD. Effective date: 20071008 Free format text: COMMON LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.1.1 TO 2019.5.19 Name of requester: PLIVAN POLYMER ( SHANGHAI ) CO., LTD. Effective date: 20071008 Free format text: COMMON LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.1.1 TO 2019.5.19 Name of requester: PLIVAN POLYMER ( SUZHOU) CO., LTD. Effective date: 20071008 |
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Open date: 20070221 |