CN1908083A - Preparation method of long-acting aromatic printed matter and long-acting aromatic printed matter - Google Patents
Preparation method of long-acting aromatic printed matter and long-acting aromatic printed matter Download PDFInfo
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- CN1908083A CN1908083A CN 200610111654 CN200610111654A CN1908083A CN 1908083 A CN1908083 A CN 1908083A CN 200610111654 CN200610111654 CN 200610111654 CN 200610111654 A CN200610111654 A CN 200610111654A CN 1908083 A CN1908083 A CN 1908083A
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- diacrylate
- perfuming agent
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Abstract
The invention discloses a manufacturing method of long-effective odor printer, which is characterized by the following: adopting printing or coating method as the manufacturing method; lasting odor; fitting for large scale of manufacturing.
Description
Technical field
The present invention relates to a kind of production method of long-acting aromatic printed matter, and the long-acting aromatic printed matter that adopts this method to obtain.
Technical background
Open printed matter or packing box, fragrance assails the nostrils, and this is the thing that many printing practitioners yearn for.Generally take the way that sprays perfume over sth, but because the perfume volatilization is very fast, and after having sprayed perfume on the printed matter, fragrance only can keep several hours, fragrance will be all gone after one day.Spraying perfume over sth in addition to make the printed matter paper distortion, destroys the attractive in appearance and quality of printed matter.According to another the document introduction, general fragrance printing is that microcapsule spices is sneaked among the printing-ink, and microcapsule spices is that spices is wrapped up with macromolecular material, and fragrance can slowly distribute.According to the inventor's repetition test, owing to be printed with pressure, microcapsule spices is mixing stirring or is being easy to crush in printing process with printing ink, and spices is when the protection that does not have high molecule microcapsule, and fragrance can distribute very soon, can not keep long-acting aromatic.After mixing microcapsule spices in the printing-ink in addition, influence the printability of printing-ink, printing quality is descended, produce printing trouble.
Producing the high quality printing product that keep long-acting aromatic, is the problem that this patent need solve.
Summary of the invention
The objective of the invention is in order to overcome the defective that above-mentioned prior art exists, is will provide a kind of high printing quality can be arranged, and can keep the production method of the printed matter of long-acting aromatic again, and can produce high-quality long-acting aromatic printed matter.This method is with the method printing of ultraviolet light polymerization or be coated on any printed matter surface with spices.Because ultraviolet light polymerization speed is very fast, only just can dry film forming within 1 second, spices be not enclosed in by the film forming matter of ultraviolet light polymerization between paper and the ultraviolet light polymerization film before the volatilization, and spices is owing to cover with one deck polymeric membrane, fragrance meeting slow release is so fragrance can very persistent maintenance.If use the heated volatile drying and forming-film, when drying and forming-film, fragrance also can discharge along with heating totally, and fragrance can not keep for a long time.If the air drying film forming, because the time is oversize, when film formed, fragrance had been run away for a long time, can not keep for a long time.This also is to mix the be hard to keep major cause of fragrance of spices in the flexographic ink.
Film forming is water white film behind the ultraviolet light polymerization, can not influence the quality of printed matter, except fragrance is provided, can not exert an influence to print quality, therefore can produce high-quality long-acting aromatic printed matter with this method.
The present invention also provides the long-acting aromatic printed matter that adopts aforesaid method to obtain.
A kind of production method of long-acting aromatic printed matter, this method is to contain the photocuring perfuming agent printing of spices or to be coated on any printed matter surface, the photocuring perfuming agent is seen light generation photopolymerization reaction, and instantaneous solidification forms the printed matter of lasting fragrance at printed matter surface.
Wherein printing or being coated with used photocuring perfuming agent is the composition that can carry out photopolymerization reaction under rayed, and said composition contains following component and parts by weight:
(1) is used for the prepolymer resin of photopolymerization reaction: 10-80
(2) be used for the diluent monomer of photopolymerization reaction: 20-80
(3) Photoepolymerizationinitiater initiater: 2-20
(4) tensio-active agent: 0.01-10
(5) the microcapsule spices of various odor types: 2-50
(6) with the liquid perfume of the identical odor type of microcapsule spices: 2-30
Another object of the present invention provides a kind of ultraviolet light polymerization perfuming agent that can produce long-acting aromatic printed matter.
In the production method of long-acting aromatic printed matter of the present invention, the prepolymer resin that is used for photopolymerization reaction in the described photocuring perfuming agent is epoxy acrylate, polyester acrylate, propenoic methyl carbamate.
In the production method of long-acting aromatic printed matter of the present invention, the diluent monomer that is used for photopolymerization reaction in the described photocuring perfuming agent is acrylic ester compound such as Viscoat 295, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers Viscoat 295, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate, tripropylene glycol diacrylate, propylene glycol diacrylate, 1, the 4-butylene glycol diacrylate, polyoxyethylene glycol (200) diacrylate, polyoxyethylene glycol (400) diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, PDDA, 1,6 hexanediol diacrylate, the propoxylated glycerol triacrylate, the phthalic acid tripropylene glycol diacrylate, ethoxylated bisphenol a diacrylate and glytidyl methacrylate.
In the production method of long-acting aromatic printed matter of the present invention; Photoepolymerizationinitiater initiater is a st-yrax in the described photocuring perfuming agent; benzoin methyl ether; benzoin dimethylether; the Alpha-Methyl st-yrax; α-phenyl st-yrax; Benzoin ethyl ether; benzoin isobutyl ether; benzoin isobutyl ether; benzophenone; dibenzoyl; Michler's keton; to the phenyl benzophenone; halo acetophenone; Alpha-hydroxy-Alpha-Methyl Propiophenone; 2-hydroxyl-[4-(2-hydroxyl-oxethyl) phenyl]-2-methylacetone; 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholine-1-acetone; 1-hydroxy-cyclohexyl phenyl ketone; 2 or the 4-isopropyl thioxanthone; 2; 4,6-trimethylbenzoyl-diphenyl phosphine oxide.
In the production method of long-acting aromatic printed matter of the present invention, the tensio-active agent in the described photocuring perfuming agent is dimethyl silicone oil, diethyl silicone oil, polymethylphenyl siloxane fluid, organic silicon acrylic ester.
In the production method of long-acting aromatic printed matter of the present invention, the spices in the described photocuring perfuming agent be various odor types microcapsule spices and with the liquid perfume of the identical odor type of microcapsule spices.
Embodiment
Embodiment given below is for the present invention is described, rather than limits the invention.
Embodiment 1
The prescription of photocuring perfuming agent: epoxy acrylate 150g
Viscoat 295 500g
Benzophenone 80g
Dimethyl silicone oil 10g
Jasmine fragrance microcapsule spices 200g
Jasmine fragrance liquid perfume 60g
Above-mentioned six kinds of mixing of materials are stirred, to be mixed evenly after, be coated on any printed matter surface with the ultraviolet light polymerization roll coating apparatus, printed matter can keep the jasmine fragrance of half a year.
Because material viscosity is little very rare, is difficult for making microcapsules rupture during stirring, therefore can keep long-acting aromatic.
Embodiment 2:
The prescription of photocuring perfuming agent: epoxy acrylate 300g
Viscoat 295 300g
Benzophenone 80g
Dimethyl silicone oil 10g
Lemon flavor microcapsule spices 250g
Lemon flavor liquid perfume 60g
Above-mentioned six kinds of mixing of materials are stirred, to be mixed evenly after, be printed on any printed matter surface with the ultraviolet light polymerization screen printing apparatus, printed matter can keep the citrus scented more than a year.
Because material viscosity is little very rare, is difficult for making microcapsules rupture during stirring, silk screen printing pressure is little, and rete is thick, so the fragrance maintenance is more permanent.
Claims (13)
1, a kind of production method of long-acting aromatic printed matter, this method is to contain the photocuring perfuming agent printing of spices or to be coated on any printed matter surface, the photocuring perfuming agent is seen light generation photopolymerization reaction, and instantaneous solidification forms the printed matter of lasting fragrance at printed matter surface.
Wherein printing or being coated with used photocuring perfuming agent is the composition that can carry out photopolymerization reaction under rayed, and said composition contains following component and parts by weight:
(1) is used for the prepolymer resin of photopolymerization reaction: 10-80
(2) be used for the diluent monomer of photopolymerization reaction: 20-80
(3) Photoepolymerizationinitiater initiater: 2-20
(4) tensio-active agent: 0.01-10
(5) the microcapsule spices of various odor types: 2-50
(6) with the liquid perfume of the identical odor type of microcapsule spices: 2-30.
2, the production method of long-acting aromatic printed matter according to claim 1, the prepolymer resin that it is characterized in that being used in the described photocuring perfuming agent photopolymerization reaction are at least a of epoxy acrylate, polyester acrylate, propenoic methyl carbamate.
3, the production method of long-acting aromatic printed matter according to claim 1, it is characterized in that the diluent monomer that is used for photopolymerization reaction in the described photocuring perfuming agent is selected from acrylic ester compound such as Viscoat 295, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers Viscoat 295, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate, tripropylene glycol diacrylate, propylene glycol diacrylate, 1, the 4-butylene glycol diacrylate, polyoxyethylene glycol (200) diacrylate, olefin(e) acid ester in the polyoxyethylene glycol (400) two, diethylene glycol diacrylate, triethylene glycol diacrylate, PDDA, 1,6 hexanediol diacrylate, the propoxylated glycerol triacrylate, the phthalic acid tripropylene glycol diacrylate, at least a in ethoxylated bisphenol a diacrylate and the glytidyl methacrylate.
4; the production method of long-acting aromatic printed matter according to claim 1; it is characterized in that Photoepolymerizationinitiater initiater is selected from st-yrax in the described photocuring perfuming agent; benzoin methyl ether; benzoin dimethylether; the Alpha-Methyl st-yrax; α-phenyl st-yrax; Benzoin ethyl ether; benzoin isobutyl ether; benzoin isobutyl ether; benzophenone; dibenzoyl; Michler's keton; to the phenyl benzophenone; halo acetophenone; Alpha-hydroxy-Alpha-Methyl Propiophenone; 2-hydroxyl-[4-(2-hydroxyl-oxethyl) phenyl]-2-methylacetone; 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholine-1-acetone; 1-hydroxy-cyclohexyl phenyl ketone; 2 or the 4-isopropyl thioxanthone; 2; 4, at least a in 6-trimethylbenzoyl-diphenyl phosphine oxide.
5, the production method of long-acting aromatic printed matter according to claim 1 is characterized in that tensio-active agent in the described photocuring perfuming agent is selected from least a in dimethyl silicone oil, diethyl silicone oil, polymethylphenyl siloxane fluid, the organic silicon acrylic ester.
6, the production method of long-acting aromatic printed matter according to claim 1, it is characterized in that spices in the described photocuring perfuming agent be selected from various odor types microcapsule spices and with the liquid perfume of the identical odor type of microcapsule spices.
7, the long-acting aromatic printed matter that one of any described long-acting aromatic printed matter production method is made among the claim 1-6.
8, a kind of ultraviolet light polymerization perfuming agent that is used to produce long-acting aromatic printed matter includes following component and parts by weight:
(1) is used for the prepolymer resin of photopolymerization reaction: 10-80
(2) be used for the diluent monomer of photopolymerization reaction: 20-80
(3) Photoepolymerizationinitiater initiater: 2-20
(4) tensio-active agent: 0.01-10
(5) the microcapsule spices of various odor types: 2-50
(6) with the liquid perfume of the identical odor type of microcapsule spices: 2-30.
9, the ultraviolet light polymerization perfuming agent that is used to produce long-acting aromatic printed matter according to claim 8, the prepolymer resin that it is characterized in that being used in the described photocuring perfuming agent photopolymerization reaction are at least a of epoxy acrylate, polyester acrylate, propenoic methyl carbamate.
10, the ultraviolet light polymerization perfuming agent that is used to produce long-acting aromatic printed matter according to claim 8, it is characterized in that the diluent monomer that is used for photopolymerization reaction in the described photocuring perfuming agent is selected from acrylic ester compound such as Viscoat 295, ethoxylated trimethylolpropane triacrylate, pentaerythritol triacrylate, the polyethers Viscoat 295, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate, tripropylene glycol diacrylate, propylene glycol diacrylate, 1, the 4-butylene glycol diacrylate, polyoxyethylene glycol (200) diacrylate, polyoxyethylene glycol (400) diacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, PDDA, 1,6 hexanediol diacrylate, the propoxylated glycerol triacrylate, the phthalic acid tripropylene glycol diacrylate, at least a in ethoxylated bisphenol a diacrylate and the glytidyl methacrylate.
11; the ultraviolet light polymerization perfuming agent that is used to produce long-acting aromatic printed matter according to claim 8; it is characterized in that Photoepolymerizationinitiater initiater is selected from st-yrax in the described photocuring perfuming agent; benzoin methyl ether; benzoin dimethylether; the Alpha-Methyl st-yrax; α-phenyl st-yrax; Benzoin ethyl ether; benzoin isobutyl ether; benzoin isobutyl ether; benzophenone; dibenzoyl; Michler's keton; to the phenyl benzophenone; halo acetophenone; Alpha-hydroxy-Alpha-Methyl Propiophenone; 2-hydroxyl-[4-(2-hydroxyl-oxethyl) phenyl]-2-methylacetone; 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholine-1-acetone; 1-hydroxy-cyclohexyl phenyl ketone; 2 or the 4-isopropyl thioxanthone; 2; 4, at least a in 6-trimethylbenzoyl-diphenyl phosphine oxide.
12, the ultraviolet light polymerization perfuming agent that is used to produce long-acting aromatic printed matter according to claim 8 is characterized in that tensio-active agent in the described photocuring perfuming agent is at least a in dimethyl silicone oil, diethyl silicone oil, polymethylphenyl siloxane fluid, the organic silicon acrylic ester.
13, the ultraviolet light polymerization perfuming agent that is used to produce long-acting aromatic printed matter according to claim 8, it is characterized in that spices in the described photocuring perfuming agent be various odor types microcapsule spices and with the liquid perfume of the identical odor type of microcapsule spices.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610111654 CN1908083A (en) | 2006-08-21 | 2006-08-21 | Preparation method of long-acting aromatic printed matter and long-acting aromatic printed matter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610111654 CN1908083A (en) | 2006-08-21 | 2006-08-21 | Preparation method of long-acting aromatic printed matter and long-acting aromatic printed matter |
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| CN1908083A true CN1908083A (en) | 2007-02-07 |
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| CN 200610111654 Pending CN1908083A (en) | 2006-08-21 | 2006-08-21 | Preparation method of long-acting aromatic printed matter and long-acting aromatic printed matter |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104708903A (en) * | 2014-12-31 | 2015-06-17 | 上海孩子国科教设备有限公司 | Printing method and implementing device thereof |
| CN106676965A (en) * | 2016-06-06 | 2017-05-17 | 广州市正茂印刷有限公司 | Fragrance printing technique |
| CN107177301A (en) * | 2016-05-19 | 2017-09-19 | 湖北航天化学技术研究所 | A kind of sustainable slow-release fragrance anti-glare hardened film and its application |
| CN111955476A (en) * | 2020-09-03 | 2020-11-20 | 常熟理工学院 | LED light-cured pesticide microcapsule and preparation method thereof |
| CN112693246A (en) * | 2020-12-29 | 2021-04-23 | 浙江顺福印业有限公司 | Fragrant printing process |
-
2006
- 2006-08-21 CN CN 200610111654 patent/CN1908083A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104708903A (en) * | 2014-12-31 | 2015-06-17 | 上海孩子国科教设备有限公司 | Printing method and implementing device thereof |
| CN104708903B (en) * | 2014-12-31 | 2016-08-24 | 上海孩子国科教设备有限公司 | Method of printing and realize device |
| CN107177301A (en) * | 2016-05-19 | 2017-09-19 | 湖北航天化学技术研究所 | A kind of sustainable slow-release fragrance anti-glare hardened film and its application |
| CN106676965A (en) * | 2016-06-06 | 2017-05-17 | 广州市正茂印刷有限公司 | Fragrance printing technique |
| CN106676965B (en) * | 2016-06-06 | 2018-04-24 | 广州市正茂印刷有限公司 | A kind of fragrance art of printing |
| CN111955476A (en) * | 2020-09-03 | 2020-11-20 | 常熟理工学院 | LED light-cured pesticide microcapsule and preparation method thereof |
| CN112693246A (en) * | 2020-12-29 | 2021-04-23 | 浙江顺福印业有限公司 | Fragrant printing process |
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Application publication date: 20070207 |