CN1903169A - Natural flushing decoration material, prepn. method and use thereof - Google Patents
Natural flushing decoration material, prepn. method and use thereof Download PDFInfo
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- CN1903169A CN1903169A CN 200610036448 CN200610036448A CN1903169A CN 1903169 A CN1903169 A CN 1903169A CN 200610036448 CN200610036448 CN 200610036448 CN 200610036448 A CN200610036448 A CN 200610036448A CN 1903169 A CN1903169 A CN 1903169A
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Abstract
A natural flash material used for cosmetics is prepared from the scales of tropical seawater fish through enzymolyzing with phytoenzyme, defatting with defatting enzyme, filtering, centrifugal separation to obtain solid, and drying.
Description
Technical field
The present invention relates to a kind of fish scale with tropical seawater fish is natural flushing decoration material of feedstock production and its production and use.
Background technology
In the modern life of pursuing health and safety, people are more and more higher to the requirement of glittering material, flushing decoration material in particular for series cosmetics, not only relating to its result of use increases skin gloss, effectively modifies profile etc., but also all constantly paying close attention to the influence degree of these type of cosmetics to skin, this has brought great challenge to cosmetic industry.The glittering material that now is used for cosmetics on the market is the synthetic flash of light face material of surface clad or metal-oxide basically, though its flash of light degree height, because of its metallic pollution is serious, being used for cosmetics has potential significant damage to human body; The flash of light face material of synthetic changes the balance of the normal fungal component of skin table easily simultaneously, is used for cosmetics and exists the hidden danger that threatens human body skin health.In the flushing decoration material industry, the application of synthetic flash of light face material is subjected to a certain degree restriction because of its negative effect to human body.
Summary of the invention
It is natural flushing decoration material of feedstock production and its production and use that the object of the invention provides a kind of fish scale with tropical seawater fish.
Natural flushing decoration material provided by the present invention, be that fish scale with tropical seawater fish is a raw material, by the phytoenzyme enzymolysis, after the defatting enzyme defat, the centrifugal gained solid drying of its filter liquor is made, the mass percent that its finished product contains guanine is 85-95%, the outward appearance flashing powder that is silvery white in color, granularity≤100 sieve meshes.
The preparation method of this natural flushing decoration material comprises following processing step:
(1) fish scale with tropical seawater fish cleans 20-40min in ultrasonic cleaner, removes the impurity that is attached to the fish scale surface;
(2) get clean fish scale, add the q.s distilled water, transfer pH5-7 to just soaking the fish scale surface, add the phytoenzyme (mass percent) that accounts for fish scale immersion 0.2-0.4%, place 25-35 ℃ constant temperature oscillator, directional enzymatic 1-2 hour, after the hydrolysis with 50 eye mesh screens filter enzymolysis solution;
(3) above-mentioned enzymolysis solution is heated to 90-100 ℃, behind the enzyme denaturing, transfers pH8-12, add the defatting enzyme that accounts for enzymolysis solution 0.3-0.5% (mass percent), in temperature is 28-35 ℃ of scope defat 1-2 hour;
(4) solution after the above-mentioned defat is heated to 90-100 ℃, behind the enzyme denaturing, filters with 100 eye mesh screens, filter liquor is centrifugal under the 1000-2000rpm rotating speed, with the gained solid drying, is this natural flushing decoration material.
Can adopt papain or bromelain at the phytoenzyme described in the step (2).
Can adopt Greasex defatting enzyme or Erhazymlp defatting enzyme at the defatting enzyme described in the step (3).
In step (4), the solid of the centrifugal back of filter liquor gained carries out lyophilization at 68.70Pa under-20 ℃ of vacuum; Or the solid of the centrifugal back of filter liquor gained added behind the ethanol drying under reduced pressure in rotary evaporator.
The fish scale raw material of tropical seawater fish of the present invention can be marine products madai scale, Oncorhynchi scale, marine products cabrilla, marine products Squaliobarbus ourriculus scale, marine products Mugil cephalus scale, marine products yellow croaker scale or marine products Erythroculter ilishaeformis scale.
Prepared natural flushing decoration material crystalline solid exquisiteness, uniform particles, dispersibility and the chemical stability of the present invention is good, because of it has multiple interference of light effects such as reflection, transmission, refraction to light, has good reflective function, still can keep sparkling luster after adding other base materials to, human body is had no side effect, can be used as the adjuvant or the Application of Additives of cosmetics.For example, can be aspect the basic skin protection of cosmetics as the purposes of adjuvant or additive; Aspect color cosmetic as the purposes of adjuvant or additive.When as the adjuvant of the basic skin protection aspect of cosmetics or additive, the one-tenth deal of this natural flushing decoration material can account for 0.2%-0.6% (mass percent); When as the adjuvant of color cosmetic aspect or additive, the one-tenth deal of this natural flushing decoration material can account for 1%-3% (mass percent).
Beneficial effect of the present invention is as follows:
1. natural flushing decoration material of the present invention adopts the defatting enzyme defat, and specificity acts on greasy fat key, does not influence other nutritions, product safety, nontoxic, nonstaining property.
2. natural flushing decoration material of the present invention adopts the phytoenzyme directional enzymatic, and its enzymatic hydrolysate raciness can not produce abnormal flavour, makes product be applied to the adjuvant or the additive of cosmetics better.
3. natural flushing decoration material Main Ingredients and Appearance of the present invention is a guanine, is the environmental type marine organism material.Its crystalline solid exquisiteness, uniform particles, good dispersion add to when going in other base materials as adjuvant and to be difficult for cohering, assembling; And have multiple interference of light effects such as reflection, transmission, refraction, and have good reflective function, still can keep sparkling luster after adding other base materials to.
4. natural flushing decoration material chemical stability of the present invention is good, has difficult drop-off, colour-fast function, can be because of the time long or external environment influence and causing phenomenon such as fade cause aesthetic measure to descend.
5. natural flushing decoration material content of mineral substances of the present invention is abundant, wherein contain magnesium, copper, zinc, ferrum, manganese microelement, trace organic germanium, organic selenium etc. are of value to the material of human body aesthetic health care, not only have sun-proof antidotal function, also have the antiinflammatory sterilization and keep the equilibrated effect of the normal fungal component of skin table.The natural organic-compound of the germanium of trace, phosphorus, silicon, selenium etc. has blood circulation promoting in this natural flushing decoration material, and makes skin become smooth, plump, improves effects such as pigment and speckle.
6. natural flushing decoration material of the present invention is a raw material with tropic sea Water fish squama, because of the organic compound of trace and the factors such as nutrient ingredient of food of marine fish in contained various trace element, the sea water in the sea water, making fish scale with tropical seawater fish is that the flushing decoration material of raw material production has particularity, have multiple interference of light effects such as reflection, transmission, refraction, and good reflective function arranged, reach the effect of flicker radiance, in vision, produce a kind of function of sparkling luster.With tropic sea Water fish squama is raw material, cheap, make it have price material benefit advantage, this performance has determined natural flushing decoration material of the present invention to serve the consumer of various different levels in the cosmetics market popularly, can popularize comprehensively and promote on market.
The specific embodiment:
The invention will be further described below in conjunction with embodiment.But embodiment is not a limitation of the present invention.
Embodiment 1
Take by weighing the fresh or freezing marine products madai of 500g fish scale, add in the triangular flask of 1000ml, add an amount of distilled water, place ultrasonic cleaner, clean 20min, remove some impurity of fish scale surface attachment to just soaking the fish scale surface.The fish scale of cleaning is added an amount of distilled water, add the 1g papain after transferring pH5, be placed in 25 ℃ the constant temperature oscillator enzymolysis 2 hours.After the hydrolysis with 50 eye mesh screens filter enzymolysis solution, be heated to 90 ℃ of enzyme denaturing 10min.Enzymolysis solution is transferred pH8, add 1.5g Greasex defatting enzyme, defat was heated to 90 ℃ of enzyme denaturing 10min after 1 hour in 28 ℃ constant temperature oscillator.Filter with 100 eye mesh screens, leach solution with behind the 1000rpm centrifuge centrifugal 20min, the deposit that obtains is at 68.70Pa ,-20 ℃ of vacuum lyophilizations, preserve and promptly get the pure product of the natural flushing decoration material with sparkling luster, wherein contain guanine 91% (mass percent).
Embodiment 2
Take by weighing the fresh or freezing Oncorhynchi scale of 1000g, add in the triangular flask of 2000ml, add an amount of distilled water, place ultrasonic cleaner, clean 40min, remove some impurity of fish scale surface attachment to just soaking the fish scale surface.The fish scale of cleaning is added an amount of distilled water, add the 2g papain after transferring pH7, be placed in 35 ℃ the constant temperature oscillator enzymolysis 1 hour.After the hydrolysis with 50 eye mesh screens filter enzymolysis solution, be heated to 100 ℃ of enzyme denaturing 10min.Enzymolysis solution is transferred pH8, add 5g Greasex defatting enzyme, defat was heated to 100 ℃ of enzyme denaturing 10min after 2 hours in 30 ℃ constant temperature oscillator.Filter with 100 eye mesh screens, leach solution with behind the 2000rpm centrifuge centrifugal 15min, the deposit that obtains is at 68.70Pa ,-20 ℃ of vacuum lyophilizations, preserve and promptly get the pure product of the natural flushing decoration material with sparkling luster, wherein contain guanine 93% (mass percent).
Embodiment 3
Take by weighing the fresh or freezing marine products yellow croaker of 1500g scale, add in the triangular flask of 2000ml, add an amount of distilled water, place ultrasonic cleaner, clean 40min, remove some impurity of fish scale surface attachment to just soaking the fish scale surface.The fish scale of cleaning is added an amount of distilled water, add the 6g bromelain after transferring pH5, be placed in 35 ℃ the constant temperature oscillator enzymolysis 1 hour.After the hydrolysis with 50 eye mesh screens filter enzymolysis solution, be heated to 90 ℃ of enzyme denaturing 10min.Enzymolysis solution is transferred pH10, add the 4.5gErhazymlp defatting enzyme, defat was heated to 100 ℃ of enzyme denaturing 10min after 1 hour in 35 ℃ constant temperature oscillator.Filter with 100 eye mesh screens, after leaching the centrifugal 20min of solution usefulness 1000rpm centrifuge, the deposit that obtains is adding an amount of ethanol at 40 ℃, 50rpm rotary evaporation drying, preserve and promptly get the pure product of the natural flushing decoration material with sparkling luster, wherein contain guanine 89% (mass percent).
Embodiment 4
Take by weighing the fresh or freezing marine products Erythroculter ilishaeformis of 2000g scale, marine products yellow croaker scale, add in the triangular flask of 2000ml, add an amount of distilled water, place the ultrasonic cleaner of 50Khz to just soaking the fish scale surface, clean 40min, remove some impurity of fish scale surface attachment.The fish scale of cleaning is added an amount of distilled water, add the 4g bromelain after transferring pH6, be placed in 30 ℃ the constant temperature oscillator enzymolysis 2 hours.After the hydrolysis with 500 eye mesh screens filter enzymolysis solution, be heated to 100 ℃ of enzyme denaturing 10min.Enzymolysis solution is transferred pH12, add 10g Erhazymlp defatting enzyme, defat was heated to 100 ℃ of enzyme denaturing 10min after 2 hours in 30 ℃ constant temperature oscillator.Filter with 100 eye mesh screens, after leaching the centrifugal 15min of solution usefulness 2000rpm centrifuge, the deposit that obtains is adding an amount of ethanol at 45 ℃, 60rpm rotary evaporation drying, preserve and promptly get the pure product of the natural flushing decoration material with sparkling luster, wherein contain guanine 93% (mass percent).
Embodiment 5
With the natural flushing decoration material that obtains among the embodiment 4 as the adjuvant component, become natural flushing XIANGFEN honey by following formulated: the 2.5g zinc oxide, the 10g Pulvis Talci, 4.5g magnesium carbonate, 5g glycerol, 1.5g sodium carboxymethyl cellulose (high viscosity), 2g ethanol, an amount of nine rare water, 1g natural flushing decoration material, 72g deionized water.Collocation method is as follows:
Earlier essence is added in the magnesium carbonate, place in the container of sealing, make to absorb more than the 24h, take out then in the immigration blender, add powders such as Pulvis Talci, zinc oxide and natural flushing decoration material and stir 2-4h.After being heated to 70 ℃ in glycerol and the deionized water adding temperature control stirred reactor, soak sodium carboxymethyl cellulose with ethanol in addition, mixture moves in the temperature control stirred reactor, is stirred to colloid and dissolves fully.After cooling, add above-mentioned powder, the back that stirs gets final product by the grinder porphyrize.
This natural flushing XIANGFEN honey sense of touch is very fine and smooth, makes up with the back and feels soft and smooth careful, has the skin of increasing glossiness, effectively modifies profile, improves the effect of skin texture.
Embodiment 6
With the natural flushing decoration material that obtains among the embodiment 3 as the adjuvant component, become the natural flushing moisturizer by following formulated: oil phase raw material (7g octadecanol, 2.0g lanoline, 2.0g stearic acid, 5.0g squalane, the 6.0g2-octyldodecanol), water raw material (5.0g propylene glycol, 67.7g 0.3g natural flushing decoration material deionized water).Collocation method is as follows:
Oil phase raw material and water raw material add respectively be heated to 75 ℃ in the temperature control stirred reactor after, then oil phase is joined aqueous phase emulsifying, add at last after natural flushing decoration material homogenizes, cooling gets final product.
This natural flushing moisturizer adds flushing decoration material, and tool nutrition skin moistening function makes skin become smooth exquisiteness, high resilience and gloss.
Claims (8)
1. natural flushing decoration material, it is characterized in that the fish scale with tropical seawater fish is a raw material, by the phytoenzyme enzymolysis, after the defatting enzyme defat, the centrifugal gained solid drying of its filter liquor is made, the mass percent that its finished product contains guanine is 85-95%, the outward appearance flashing powder that is silvery white in color, granularity≤100 sieve meshes.
2. the preparation method of a natural flushing decoration material is characterized in that the fish scale with tropical seawater fish is a raw material, prepares by following processing step:
(1) fish scale is cleaned 20-40min in ultrasonic cleaner, remove the impurity that is attached to the fish scale surface;
(2) get clean fish scale, add the q.s distilled water, transfer pH5-7 to just soaking the fish scale surface, add the phytoenzyme that accounts for fish scale immersion mass percent 0.2-0.4%, place 25-35 ℃ constant temperature oscillator, directional enzymatic 1-2 hour, after the hydrolysis with 50 eye mesh screens filter enzymolysis solution;
(3) above-mentioned enzymolysis solution is heated to 90-100 ℃, behind the enzyme denaturing, transfers pH8-12, add the defatting enzyme that accounts for enzymolysis solution mass percent 0.3-0.5%, in temperature is 28-35 ℃ of scope defat 1-2 hour;
(4) solution after the above-mentioned defat is heated to 90-100 ℃, behind the enzyme denaturing, filters with 100 eye mesh screens, filter liquor is centrifugal under the 1000-2000rpm rotating speed, with the gained solid drying, is this natural flushing decoration material.
3. the preparation method of natural flushing decoration material according to claim 1 is characterized in that the phytoenzyme described in the step (2) is papain or bromelain.
4. the preparation method of natural flushing decoration material according to claim 1 is characterized in that the defatting enzyme described in the step (3) is Greasex defatting enzyme or Erhazymlp defatting enzyme.
5. the preparation method of natural flushing decoration material according to claim 1, the fish scale raw material that it is characterized in that described tropical seawater fish is marine products madai scale, Oncorhynchi scale, marine products cabrilla, marine products Squaliobarbus ourriculus scale, marine products Mugil cephalus scale, marine products yellow croaker scale or marine products Erythroculter ilishaeformis scale.
6. the preparation method of natural flushing decoration material according to claim 1 is characterized in that in the step (4), and the solid of the centrifugal back of filter liquor gained carries out lyophilization at 68.70Pa under-20 ℃ of vacuum.
7. the preparation method of natural flushing decoration material according to claim 1 is characterized in that in the step (4), and the solid of the centrifugal back of filter liquor gained adds behind the ethanol drying under reduced pressure in rotary evaporator.
8. the purposes of the described natural flushing decoration material of claim 1 is characterized in that as cosmetics adjuvant or Application of Additives.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100364484A CN100551353C (en) | 2006-07-11 | 2006-07-11 | A kind of preparation method of natural flushing decoration material |
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| CNB2006100364484A CN100551353C (en) | 2006-07-11 | 2006-07-11 | A kind of preparation method of natural flushing decoration material |
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| CN1903169A true CN1903169A (en) | 2007-01-31 |
| CN100551353C CN100551353C (en) | 2009-10-21 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105725109A (en) * | 2016-02-01 | 2016-07-06 | 佛山市聚成生化技术研发有限公司 | Preparation method of fish scale glue and prepared fish scale glue |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU899611A1 (en) * | 1980-05-21 | 1982-01-23 | Астраханский технический институт рыбной промышленности и хозяйства | Process for producing pearl paste from fish scale |
| CN1033827A (en) * | 1988-09-28 | 1989-07-12 | 云南大学 | A kind of method of from fish scale, extracting pearl essence |
| RU2020143C1 (en) * | 1991-06-28 | 1994-09-30 | Елена Николаевна Чертова | Process for producing natural nacreous and pearl pigments from fish scale |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105725109A (en) * | 2016-02-01 | 2016-07-06 | 佛山市聚成生化技术研发有限公司 | Preparation method of fish scale glue and prepared fish scale glue |
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Effective date of registration: 20191227 Address after: 526200 No.18, innovation Avenue, fine chemical industry zone, Jianggu Town, Sihui City, Zhaoqing City, Guangdong Province Patentee after: Guangdong Yuxin New Material Co., Ltd. Address before: 510301 No. 164 West Xingang Road, Guangdong, Guangzhou Patentee before: South-sea Ocean Inst., Chine Academy of Sciences |
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