CN1891788A - Biodiesel utilization catalyst exchange physical preparing process - Google Patents
Biodiesel utilization catalyst exchange physical preparing process Download PDFInfo
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- CN1891788A CN1891788A CNA2006100099915A CN200610009991A CN1891788A CN 1891788 A CN1891788 A CN 1891788A CN A2006100099915 A CNA2006100099915 A CN A2006100099915A CN 200610009991 A CN200610009991 A CN 200610009991A CN 1891788 A CN1891788 A CN 1891788A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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Abstract
The invention relates to physical preparation technology used to catalyst to make biological diesel oil. It includes the following steps: mixing carbonate, alkyl oxide, sodium ethylate, sodium iso-propoxide, manganic acid, diatomite, alumina, R silicon, with lecithin; heating; stirring; adding diatomite and alumina secondarily; liquating; and separating. It can used to improve the lubrication and combustion of the petroleum. And it has simple produce, convenient using, and low cost. Thus it is one of the substitutes of the world oil fuel.
Description
Affiliated field: the present invention relates to a kind of biofuel and utilize catalyst exchange physical preparing process.
Background technology: original have only the sewage after technology is washed to contain a large amount of phosphatide, glue fat, organic pigment: as carotene, chlorophyll and gossypol pigment etc., these raw materials all in the sewage after washing, must be handled, and do not handle environmental hazard big, treatment facility and medicine investment are very big, have increased the profit spending.
Summary of the invention: the purpose of this invention is to provide the biofuel that a kind of rotation radius is big, working accuracy is high and utilize catalyst exchange physical preparing process.The objective of the invention is to realize by following structure: the present invention utilizes catalyst exchange physical preparing process for a kind of biofuel: the raw material of employing is: A: soybean oil: comprise oil foot, industrial soya-bean oil, soya fatty acid B: rapeseed oil C: Oleum Gossypii semen D: vegetable and animals oils: sewer oil is swill oil E again: algal oil
Raw material and auxiliary material measure by ratio of weight and the number of copies: 100 parts of stock oils
Dewatering agent: yellow soda ash, sodium hydroxide: 0.02-0.05 part
Catalyzer: mangaic acid 0.1-0.3 part
Virahol 0.4-0.5 part
Exchanger carrier: sodium ethylate or ethanol, methyl alcohol 7-10 part
Degumming agent: silicon-dioxide or R silicon 0.2-0.4 part
Crystallization in motion agent: Yelkin TTS 0.3-0.5 part
Flocculating aids: 0.4 part in diatomite, 0.3 part in aluminum oxide
Step of preparation process is: 1, stock oil utilizes pump and 60m
3Jar for sleeping in adds dewatering agent: yellow soda ash, and sodium hydroxide, 80 ℃ of controlled temperature, twice dehydration circulates; 2, stock oil and exchanger carrier, catalyzer, Virahol, degumming agent, the crystallization in motion agent, flocculating aids mixes, retort is advanced in heating, synthetic diatomite and the aluminum oxide of adding of restir, R silicon stirs synthetic, 2 hours after twice filtration, temperature is 70 ℃-80 ℃, the equipment that slightly the takes off pressure type leaf-type filter SYL70 that thick de-oiling slag adopts, slightly taking off pressure is constant pressure, the essence that adopts is taken off equipment pressure type leaf-type filter SYL80 and is taken off slag, degreasing, come unstuck, bleaching tower is adopted in decolouring, and essence is taken off operating pressure 0.5MPA, 80 ℃-90 ℃, after filtering, employing Stainless Steel Wire Mesh 270 orders go out edible vegetable oil; 3, cryogenic refrigeration is adopted in dewaxing, utilizes professional oil refrigeration case, freezes-13 ℃-38 ℃; 4, the employing essence is chilled to-38 ℃ after taking off equipment pressure type leaf-type filter SYL80 dewaxing, depickling alkali again, enters essence and takes off; 5, essence is taken off: adopt the smart oil plant that produces after the equipment pressure type leaf-type filter SYL80 degreasing that takes off to enter the smart filter of cleaner; 6 cleaners and normal pressure mixing tank: oil plant adopts flight T type mixing tank to mix and is processed oil.
The present invention's oil good stability, free from environmental pollution, help environmental protection, cleaner is that the gasoline chemical industry purifies specific equipment, can make engine compression ignite energy property handy.Technology of the present invention is simple, and the disposable processing of used aluminum oxide is burnt as boiler oil in active earths, is safe from harm.The simple personnel selection of this equipment using method is few, and per tour has only 5 people, semi-automatic and manual use, this not exhaust of not blowdown of equipment body, pure environment-protective process is produced 150 tons, floor space is little, comprises that utility appliance is total to 3000 square metres of floor spaces, and main equipment is installed in factory building.The present invention uses carbonate and trialkylphosphine oxide, sodium ethylate, sodium isopropylate, mangaic acid, diatomite and aluminum oxide, R silicon, Yelkin TTS etc., through mix synthetic after, heated and stirred, secondary adds diatomite and aluminum oxide stirs, separate the fusion back.Become the renewable energy resources after the purifying of refrigeration high score height.Single with or and natural diesel oil blending B oil usefulness, it can improve the lubricated and burning of oil; It makes simple, and is easy to use, does not discharge sulfurous gas during burning, reaches nitrogenous objectionable impurities, can also improve the lubricity of natural oil, and the pollution that reduces environment reduces production costs, and is one of world oil fuel substitute.
Description of drawings
Fig. 1 is the present invention and mineral type diesel fuel characteristics deck watch
Embodiment:
Implement 1
The present invention utilizes catalyst exchange physical preparing process for a kind of biofuel, A: soybean oil: comprise oil foot, industrial soya-bean oil, soya fatty acid B: rapeseed oil C: Oleum Gossypii semen D: vegetable and animals oils: sewer oil is swill oil E again: algal oil
Raw material and auxiliary material measure by ratio of weight and the number of copies: 100 parts of stock oils
Dewatering agent: yellow soda ash, sodium hydroxide: 0.02-0.05 part
Catalyzer: mangaic acid 0.1-0.3 part
Virahol 0.4-0.5 part
Exchanger carrier: sodium ethylate or ethanol, methyl alcohol 7-10 part
Degumming agent: silicon-dioxide or R silicon 0.2-0.4 part
Crystallization in motion agent: Yelkin TTS 0.3-0.5 part
Flocculating aids: 0.4 part in diatomite, 0.3 part in aluminum oxide
Step of preparation process is: 1, stock oil utilizes pump and 60m
3Jar for sleeping in adds dewatering agent:
Yellow soda ash, sodium hydroxide, 80 ℃ of controlled temperature, twice dehydration circulates; 2, stock oil and exchanger carrier, catalyzer, Virahol, degumming agent, the crystallization in motion agent, flocculating aids mixes, retort is advanced in heating, synthetic diatomite and the aluminum oxide of adding of restir, R silicon stirs synthetic, 2 hours after twice filtration, temperature is 70 ℃-80 ℃, the equipment that slightly the takes off pressure type leaf-type filter SYL70 that thick de-oiling slag adopts, slightly taking off pressure is constant pressure, the essence that adopts is taken off equipment pressure type leaf-type filter SYL80 and is taken off slag, degreasing, come unstuck, bleaching tower is adopted in decolouring, and essence is taken off operating pressure 0.5MPA, 80 ℃-90 ℃, after filtering, employing Stainless Steel Wire Mesh 270 orders go out edible vegetable oil; 3, cryogenic refrigeration is adopted in dewaxing, utilizes professional oil refrigeration case, freezes-13 ℃-38 ℃; 4, the employing essence is chilled to-38 ℃ after taking off equipment pressure type leaf-type filter SYL80 dewaxing, depickling alkali again, enters essence and takes off; 5, essence is taken off: adopt the smart oil plant that produces after the equipment pressure type leaf-type filter SYL80 degreasing that takes off to enter the smart filter of cleaner; 6 cleaners and normal pressure mixing tank: oil plant adopts flight T type mixing tank to mix and is processed oil.Performance of the present invention as shown in Figure 1, the chemical molecular formula of prosene is 19H3602, natural oil is C20, biofuel is C19, is to substitute the best kind of diesel oil.
Adopt raw material A: soybean oil: the proportioning that comprises oil foot, industrial soya-bean oil, soya fatty acid: raw material and auxiliary material measure by ratio of weight and the number of copies: 100 parts of stock oils
Dewatering agent: yellow soda ash 0.01, sodium hydroxide: 0.01 part
Catalyzer: 0.1 part of mangaic acid
0.4 part of Virahol
Exchanger carrier: sodium ethylate 7-10 part
Degumming agent: 0.2 part of silicon-dioxide
Crystallization in motion agent: 0.3 part in Yelkin TTS
Flocculating aids: 0.3 part in diatomite, 0.3 part in aluminum oxide
Embodiment 2:
Adopt sewer oil to make raw material, sewer oil is swill oil again: composition is:
Raw material and auxiliary material measure by ratio of weight and the number of copies: 100 parts of stock oils
Dewatering agent: yellow soda ash 0.02, sodium hydroxide: 0.03 part
Catalyzer: 0.3 part of mangaic acid
0.5 part of Virahol
Exchanger carrier: 5 parts of ethanol 5, methyl alcohol
Degumming agent: 0.4 part of R silicon
Crystallization in motion agent: 0.5 part in Yelkin TTS
Flocculating aids: 0.4 part in diatomite, 0.3 part in aluminum oxide
The present embodiment processing step is constant, and is identical with embodiment 1.
Claims (1)
1, a kind of biofuel is utilized catalyst exchange physical preparing process, it is characterized in that: the raw material of employing is: A: soybean oil: comprise oil foot, industrial soya-bean oil, soya fatty acid B: rapeseed oil C: Oleum Gossypii semen D: vegetable and animals oils: sewer oil is swill oil E again: algal oil
Raw material and auxiliary material measure by ratio of weight and the number of copies: 100 parts of stock oils
Dewatering agent: yellow soda ash, sodium hydroxide: 0.02-0.05 part
Catalyzer: mangaic acid 0.1-0.3 part
Virahol 0.4-0.5 part
Exchanger carrier: sodium ethylate or ethanol, methyl alcohol 7-10 part
Degumming agent: silicon-dioxide or R silicon 0.2-0.4 part
Crystallization in motion agent: Yelkin TTS 0.3-0.5 part
Flocculating aids: 0.4 part in diatomite, 0.3 part in aluminum oxide
Step of preparation process is: 1, stock oil utilizes pump and 60m
3Jar for sleeping in adds dewatering agent: yellow soda ash, and sodium hydroxide, 80 ℃ of controlled temperature, twice dehydration circulates; 2, stock oil and exchanger carrier, catalyzer, Virahol, degumming agent, the crystallization in motion agent, flocculating aids mixes, retort is advanced in heating, synthetic diatomite and the aluminum oxide of adding of restir, R silicon stirs synthetic, 2 hours after twice filtration, temperature is 70 ℃-80 ℃, the equipment that slightly the takes off pressure type leaf-type filter SYL70 that thick de-oiling slag adopts, slightly taking off pressure is constant pressure, the essence that adopts is taken off equipment pressure type leaf-type filter SYL80 and is taken off slag, degreasing, come unstuck, bleaching tower is adopted in decolouring, and essence is taken off operating pressure 0.5MPA, 80 ℃-90 ℃, after filtering, employing Stainless Steel Wire Mesh 270 orders go out edible vegetable oil; 3, cryogenic refrigeration is adopted in dewaxing, utilizes professional oil refrigeration case, freezes-13 ℃-38 ℃; 4, the employing essence is chilled to-38 ℃ after taking off equipment pressure type leaf-type filter SYL80 dewaxing, depickling alkali again, enters essence and takes off; 5, essence is taken off: adopt the smart oil plant that produces after the equipment pressure type leaf-type filter SYL80 degreasing that takes off to enter the smart filter of cleaner; 6 cleaners and normal pressure mixing tank: oil plant adopts flight T type mixing tank to mix and is processed oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100099915A CN1891788A (en) | 2006-04-29 | 2006-04-29 | Biodiesel utilization catalyst exchange physical preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006100099915A CN1891788A (en) | 2006-04-29 | 2006-04-29 | Biodiesel utilization catalyst exchange physical preparing process |
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| CN1891788A true CN1891788A (en) | 2007-01-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNA2006100099915A Pending CN1891788A (en) | 2006-04-29 | 2006-04-29 | Biodiesel utilization catalyst exchange physical preparing process |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314748B (en) * | 2007-05-31 | 2012-05-30 | 中国石油化工股份有限公司 | Catalytic conversion method for vegetable fat and/or animal oil and fat |
| CN101705154B (en) * | 2009-11-11 | 2012-07-25 | 合肥工业大学 | Method for preparing ethyl ester biodiesel by cotton seed oil |
-
2006
- 2006-04-29 CN CNA2006100099915A patent/CN1891788A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314748B (en) * | 2007-05-31 | 2012-05-30 | 中国石油化工股份有限公司 | Catalytic conversion method for vegetable fat and/or animal oil and fat |
| CN101705154B (en) * | 2009-11-11 | 2012-07-25 | 合肥工业大学 | Method for preparing ethyl ester biodiesel by cotton seed oil |
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