CN1884666A - Washing machine washing method using electrolyzed salt water and salt water electrolysis device - Google Patents

Washing machine washing method using electrolyzed salt water and salt water electrolysis device Download PDF

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Publication number
CN1884666A
CN1884666A CN 200510035521 CN200510035521A CN1884666A CN 1884666 A CN1884666 A CN 1884666A CN 200510035521 CN200510035521 CN 200510035521 CN 200510035521 A CN200510035521 A CN 200510035521A CN 1884666 A CN1884666 A CN 1884666A
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washing
value
water
salt
brine
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CN 200510035521
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Chinese (zh)
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徐学增
顾乾坤
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Guangdong Kelong Electrical Appliances Co Ltd
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Guangdong Kelong Electrical Appliances Co Ltd
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Abstract

The invention discloses a washing method and salt electrolytic device, which comprises the following steps: preparing saturated edible salt; electrolyzing the saturated salt; transmitting the electrolytic salt in the washing groove; washing after the water in the washing groove reaches the regulated pH value and the water level reaches the needed height; adopting alkaline water to remove dirt and acid water to sterilize. The salt electrolytic device consists of edible salt tank and electrolytic groove, wherein the edible salt is loaded in the edible salt tank; the electrolytic groove contains anode chamber and cathode chamber, which is separated by positive ion exchanging film; the first electrode is set in the cathode chamber and the second electrode is set in the cathode chamber.

Description

Utilize the washing machine washing method and the saline electrolysis device of electrolytic brine
Technical field
The present invention relates to electric washer, relate in particular to a kind of washing methods and electrolytic brine device thereof that adopts electrolytic brine.
Background technology
At present, dirt, employing thimerosal that the washing machine overwhelming majority who sells on the market need adopt washing agent to remove on the clothing carry out disinfection, adopt softener that clothing is carried out submissive processing to clothing.The use of these articless for washing has increased the washing cost, and the sewage that gives off also has adverse effect to environment.
For this reason, part washing machine manufacturer (as Haier, Electrolux, Sanyo Electric etc.) all is being devoted to research and develop few usefulness or without the washing machine of washing agent, wherein utilizing electrolytic ionization water to assist washing is the research and development focuses.
For example, the applying date is that March 8, the patent No. in 2002 are that 02216055 Chinese utility model patent discloses " a kind of water treatment facilities that is used for washing machine ", this kind device proposes some viewpoints of utilizing brine electrolysis to wash, when but the proposition solution is connected with washing machine, buck is used for washed, and sour water is used for the technical problem of sterilization; The applying date is that July 31, application number in 2003 are that 0314341.1 Chinese invention patent application discloses " a kind of washing methods of the washing machine without washing agent ", this invention, just used common water to handle, the alkalescence that its electrolysis produced is not very strong, electrolysis time is very long simultaneously, and very the dirty linen clean result neither be fine; The applying date is that March 22, application number in 2002 are that 02115627.1 Chinese invention patent application discloses a kind of " using the washing methods of electrolytic sodium chloride aqueous solution as the washing machine washing agent ", it is to add loading electrode in wash bucket, the sodium chloride that adds in the entry during electrolysis laundry also carries out the scale removal decontamination with the hypochlorite ion that produces, but this application has only proposed a kind of design, lacks the specific embodiment.
Summary of the invention
Technical problem to be solved by this invention provides a kind of method that saturated aqueous common salt is carried out electrolysis and uses described brine electrolysis to wash, and reaches to remove the effect that dirt again can disinfection.
Another technical problem to be solved by this invention provides a kind of method and apparatus that can regulate the pH value of washings.
Another technical problem to be solved by this invention provides a kind ofly carries out the device of electrolysis to saturated aqueous common salt, and a kind of washing machine that this device is housed is provided.
According to an aspect of the present invention, a kind of washing machine washing method that utilizes electrolytic brine is provided, comprises: the preparation saturated aqueous common salt, described saturated aqueous common salt is carried out electrolysis, the brine electrolysis that generates is transported in the sink, washs after making water quality in the sink reach the pH value of regulation and make water level reach the needed height of washing.
As preferably, described washing comprises removes the dirt step, adopts alkaline water, and its pH value is 9.5-12.5, is preferably 12-12.2.
As preferably, described washing comprises the disinfection step, adopts acid water, and its pH value is 5-6.
As improvement, the described pH value that makes water quality in the sink reach regulation comprises: detect washings pH value, the required pH value of pH value and washing that records is compared, adjusts washing water quality to reach required pH value.
According to a further aspect of the invention, a kind of device of regulating washings pH value in the electrolytic brine washing machine sink is provided, comprises: be used to detect the pH value of washings checkout gear, be used for comparison means that the required pH value of the pH value that will record and washing compares, be used to adjust washing water quality to reach the regulator of required pH value.
According to another aspect of the invention, provide a kind of saline electrolysis device that is used for the electrolytic brine washing machine, comprise salt jar, electrolytic cell; In the described salt jar salt is housed, its top is provided with a running water water inlet, and the bottom is provided with a saturated brine delivery port, and the centre is provided with filter; Described electrolytic cell comprises anode chamber and cathode chamber, is separated by cation-exchange membrane; Be provided with first electrode in the anode chamber, be provided with second electrode in the cathode chamber; The anode chamber is provided with that the saturated brine water inlet, the cathode chamber that link to each other with salt jar saturated brine delivery port are provided with the outlet of running water water inlet and brine electrolysis, bottom, two Room all is provided with the delivery port that leads to drainpipe.
In accordance with a further aspect of the present invention, provide a kind of washing machine that the aforementioned salt apparatus for electrolyzing is installed, the water inlet pipe of the sink of described washing machine is led in the brine electrolysis outlet in the described saline electrolysis device.
Adopt method and apparatus of the present invention that clothing is washed, have the effect of removing dirt and disinfection, can realize the washing machine washing that need not washing agent on the practical significance, use very easyly, cost of use is low.Especially to environment and healthy protection aspect, significant.
Description of drawings
Figure 1 shows that the saline electrolysis device schematic diagram that is used for the electrolytic brine washing machine according to of the present invention;
Figure 2 shows that the chart of the comparison of the different electrolysis modes of saline solution.
The specific embodiment
In the clean ratio of " domestic electric washer national standard " GB/T4288-2003, energy-conservation, water saving, noise, moisture content, life-span 6 indexs, the clean ratio of washing machine is a most important index.Under situation without washing agent, guarantee enough pH values and certain Na ion ratio, be to improve the necessary condition of cleaning ratio.In order to satisfy these conditions, the present invention starts with from the mode of adding salt, and one-sided salt electrolysis mode has been determined in the electrolysis of water, only adds salt in the anode chamber of electrolytic cell.
Be illustrated in figure 1 as saline electrolysis apparatus structure schematic diagram of the present invention, comprise salt jar 1, electrolytic cell 8; In the described salt jar 1 salt 2 is housed, its top is provided with a running water water inlet 11, and the bottom is provided with a saturated brine delivery port 12, and the centre is provided with filter 13.Described electrolytic cell 8 comprises anode chamber and cathode chamber, is separated by cation-exchange membrane 5; Be provided with first electrode 3 in the anode chamber, be provided with second electrode 6 in the cathode chamber; The anode chamber is provided with that the saturated brine water inlet 83, the cathode chamber that link to each other with salt jar 1 saturated brine delivery port 12 are provided with running water water inlet 81 and electrolytic cleaning water out 7, bottom, two Room all are provided with the delivery port that leads to drainpipe 4.The water inlet pipe of the sink of washing machine is led in brine electrolysis outlet 7 in the apparatus for electrolyzing.As a kind of embodiment, the length of the polarity of described electrode, the size of Faradaic current, electrolysis time, the water supply of intake-outlet, water outlet can be controlled by independent control device; But, preferably be connected on the control device of washing machine and by its control as preferred.
The brine electrolysis performance that the different electrolysis modes of saline solution are obtained compares.Evidence, anode-side electrolyze table salt the brine electrolysis pH value that obtains more than 12, and ion ratio is more than 1.5, and clean ratio reaches 90% (see figure 2).
The barrier film of electrolytic cell adopts cation-exchange membrane.The anode chamber adds saline solution, and cathode chamber adds running water.Carrying out electrolysis under the condition like this, can make the Na ion penetrate into cathode chamber, and stop the Cl ion to pass through from the anode chamber.
Its operation principle is: during use, as long as press the button, saturated aqueous common salt can automatically add the anode chamber to from salt cellar, begins electrolysis then.Approximately through 10 minutes, the highly basic water that cathode chamber can be generated injects washtub, adds running water again and reaches designated water level and can wash.
Carry out for the second time rinsing, this moment, electrolysis went out acid water in electrolytic cell with the reversing of electrolytic cell, and this moment, hydrogen ion arrived negative electrode by exchange membrane, produced following reaction:
, acid water enters washtub, and a part of running water of going forward side by side is to reach the water level of setting, and the water inlet ratio of adjusting running water and acid water is finished whole washing process then to guarantee the concentration of acid water.
Show that according to test and actual the use this clean water has good clean result to greasy dirt, hand dirt, and is easy to use.Particularly because it does not contain any oxious component.
In addition, the device of regulating washings pH value in the washing machine sink also is installed in the washing machine, comprises: be used to detect the pH value of washings checkout gear, be used for comparison means that the required pH value of the pH value that will record and washing compares, be used to adjust washing water quality to reach the regulator of required pH value.
In one embodiment of the invention, the available electron circuit is realized measuring automatically pH value in the water and is controlled the switch of Inlet and outlet water electric control valve, realizes automatic draining and water inlet.For example, the pH value checkout gear can realize that sensor is sent to comparison means by electronic circuit with measurement data by the pH value sensor.Comparison means and regulator can realize on a microprocessor that with control program, measurement data compares with the pH value standard that is stored in the microprocessor after treatment in the microprocessor, and according to comparative result, microprocessor is controlled Inlet and outlet water.For example, in removing the dirt program, adopt alkaline water to wash, under certain water level, when pH value during greater than required value (as 12.5), the running water water intaking valve of sink is opened under the control of microprocessor, replenish fresh water, reach required value up to pH value; When pH value during less than required value (as 9.5), the brine electrolysis of electrolytic cell exports 7 valves and opens under the control of microprocessor, replenishes electrolyzed alkaline water, reaches required value up to pH value; When the water level in the sink surpassed the required water level of washing, unnecessary water opened and discharges by the draining valve of sink under the control of microprocessor.Same method is also used in the disinfection program that adopts acid water.
Draw the employing alkaline water through test and remove dirt, when its pH value was 9.5-12.2, clean effect was better.See Table one.
Table one:
PH value 9.5 10 10.5 11 11.5 12 12.2
Purification ratio 0.71 0.75 0.76 0.78 0.8 0.85 0.9
From table one as seen, when pH value during, purify the minimum standard 0.70 that specific energy all reaches " domestic electric washer national standard " GB/T4288-2003 regulation in the 9.5-12.5 scope.And at pH value is 12.2 o'clock, and purification ratio is best.
This maker uses very easy, and cost of use is also low especially, and work once cost is less than 7 fens.Especially to environment and healthy protection aspect, more significant.
In addition, can wash in conjunction with the washing machine intensity of control washing machine and/or the pH value of time and brine electrolysis, adopt method of the present invention, wash time was generally 8-52 minute.
As an embodiment, method of the present invention comprises to be handled running water, forms saturated aqueous common salt, enters electrolytic cell, and electrolysis goes out acid water and alkaline water in electrolytic cell, and alkaline water enters washtub, and acid water is discarded.After alkaline water is intake the water level that reaches setting and behind the pH value, normally wash then.
As another embodiment, method of the present invention comprises to be handled running water, forms saturated aqueous common salt, enters electrolytic cell, and electrolysis goes out acid water and alkaline water in electrolytic cell, and alkaline water enters washtub, and acid water is discarded; After alkaline water is intake the water level that reaches setting and behind the pH value, normally wash then; Carry out for the second time rinsing, this moment is with the reversing of electrolytic cell, electrolysis goes out acid water in electrolytic cell, acid water enters washtub, go forward side by side a part of running water to reach the water level of setting, the water inlet ratio of adjusting running water and acid water is finished whole washing process then to guarantee the concentration of acid water.
As another embodiment, method of the present invention comprises that running water by being treated as salt solution, enters electrolytic cell, and electrolysis goes out constant alkaline water of pH value and acid water in electrolytic cell, and alkaline water enters in the washtub, and acid water stores.After alkaline water reaches designated water level, normally wash; The rinsing of intaking for the second time, this moment, the acid water with storage was discharged in the washtub, and a part of running water of going forward side by side to be reaching the water level of setting, and the washings in this moment bucket are certain density acid water, play the function of cleaning virus killing in rinse cycle.

Claims (7)

1, a kind of washing machine washing method that utilizes electrolytic brine comprises: the preparation saturated aqueous common salt, described saturated aqueous common salt is carried out electrolysis, the brine electrolysis that generates is transported in the sink, washs after making water quality in the sink reach the pH value of regulation and make water level reach the needed height of washing.
2, washing methods according to claim 1, described washing comprise removes the dirt step, adopts alkaline water, and its pH value is 9.5-12.5.
3, washing methods according to claim 1, described washing comprises the disinfection step, adopts acid water, its pH value is 5-6.
4, washing methods according to claim 1, the described pH value that makes water quality in the sink reach regulation comprises: detect washings pH value, the required pH value of pH value and washing that records is compared, adjusts washing water quality to reach required pH value.
5, a kind of device of regulating washings pH value in the electrolytic brine washing machine sink comprises: be used to detect the pH value of washings checkout gear, be used for comparison means that the required pH value of the pH value that will record and washing compares, be used to adjust washing water quality to reach the regulator of required pH value.
6, a kind of saline electrolysis device that is used for the electrolytic brine washing machine comprises salt jar (1), electrolytic cell (8); Salt (2) is housed in the described salt jar (1), and its top is provided with a running water water inlet (11), and the bottom is provided with a saturated brine delivery port (12), and the centre is provided with filter (13); Described electrolytic cell (8) comprises anode chamber and cathode chamber, is separated by cation-exchange membrane (5); Be provided with first electrode (3) in the anode chamber, be provided with second electrode (6) in the cathode chamber; The anode chamber is provided with that the saturated brine water inlet (83), the cathode chamber that link to each other with salt jar (1) saturated brine delivery port (12) are provided with running water water inlet (81) and brine electrolysis outlet (7), bottom, two Room all is provided with the delivery port that leads to drainpipe (4).
7, a kind of washing machine that saline electrolysis device as claimed in claim 6 is installed, the sink of described washing machine is led in the brine electrolysis outlet (7) in the described saline electrolysis device.
CN 200510035521 2005-06-22 2005-06-22 Washing machine washing method using electrolyzed salt water and salt water electrolysis device Pending CN1884666A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103898732A (en) * 2014-04-22 2014-07-02 靳绍勇 Method for cleaning clothing in hospitals
CN105417640A (en) * 2015-12-11 2016-03-23 重庆领洁者节能环保科技有限公司 Strong-alkaline electrolyzed water production system
CN106216315A (en) * 2016-07-22 2016-12-14 四川港通医疗设备集团股份有限公司 A kind of supersonic wave cleaning process
CN106637842A (en) * 2017-01-13 2017-05-10 无锡小天鹅股份有限公司 Water feeding system for washing machine and washing machine with water feeding system
CN111164253A (en) * 2017-10-05 2020-05-15 伊莱克斯家用电器股份公司 Washing machine
CN111286921A (en) * 2019-11-11 2020-06-16 武桢 Cleaning device applying electrolyzed water, use method and application thereof
CN112263203A (en) * 2020-10-23 2021-01-26 珠海格力电器股份有限公司 Dish washer disinfection subassembly and dish washer
CN112274082A (en) * 2020-10-23 2021-01-29 珠海格力电器股份有限公司 Dish washing machine, control method and device of dish washing machine and storage medium
CN112603928A (en) * 2020-12-15 2021-04-06 上海安法生物科技有限公司 Disinfectant and detergent co-production method and disinfectant

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103898732A (en) * 2014-04-22 2014-07-02 靳绍勇 Method for cleaning clothing in hospitals
CN105417640A (en) * 2015-12-11 2016-03-23 重庆领洁者节能环保科技有限公司 Strong-alkaline electrolyzed water production system
CN106216315A (en) * 2016-07-22 2016-12-14 四川港通医疗设备集团股份有限公司 A kind of supersonic wave cleaning process
CN106637842A (en) * 2017-01-13 2017-05-10 无锡小天鹅股份有限公司 Water feeding system for washing machine and washing machine with water feeding system
CN111164253A (en) * 2017-10-05 2020-05-15 伊莱克斯家用电器股份公司 Washing machine
CN111286921A (en) * 2019-11-11 2020-06-16 武桢 Cleaning device applying electrolyzed water, use method and application thereof
CN112263203A (en) * 2020-10-23 2021-01-26 珠海格力电器股份有限公司 Dish washer disinfection subassembly and dish washer
CN112274082A (en) * 2020-10-23 2021-01-29 珠海格力电器股份有限公司 Dish washing machine, control method and device of dish washing machine and storage medium
CN112263203B (en) * 2020-10-23 2021-11-09 珠海格力电器股份有限公司 Dish washer disinfection subassembly and dish washer
CN112274082B (en) * 2020-10-23 2022-05-20 珠海格力电器股份有限公司 Dish washing machine, control method and device of dish washing machine and storage medium
CN112603928A (en) * 2020-12-15 2021-04-06 上海安法生物科技有限公司 Disinfectant and detergent co-production method and disinfectant

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