CN1884406A - Preparation method of nanometer functional powder dispersion for coil coating - Google Patents
Preparation method of nanometer functional powder dispersion for coil coating Download PDFInfo
- Publication number
- CN1884406A CN1884406A CN 200610026980 CN200610026980A CN1884406A CN 1884406 A CN1884406 A CN 1884406A CN 200610026980 CN200610026980 CN 200610026980 CN 200610026980 A CN200610026980 A CN 200610026980A CN 1884406 A CN1884406 A CN 1884406A
- Authority
- CN
- China
- Prior art keywords
- nano
- powder
- dispersion
- add
- coil coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 33
- 239000000843 powder Substances 0.000 title claims abstract description 27
- 238000000576 coating method Methods 0.000 title claims description 40
- 239000011248 coating agent Substances 0.000 title claims description 39
- 238000002360 preparation method Methods 0.000 title claims description 10
- 238000000034 method Methods 0.000 claims abstract description 20
- 238000000498 ball milling Methods 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 18
- 239000011858 nanopowder Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 12
- 238000005516 engineering process Methods 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical group [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims description 10
- 229940082004 sodium laurate Drugs 0.000 claims description 10
- 239000012756 surface treatment agent Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 9
- 238000003801 milling Methods 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 229920003180 amino resin Polymers 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229920000620 organic polymer Polymers 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 239000002952 polymeric resin Substances 0.000 abstract 2
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052601 baryte Inorganic materials 0.000 description 13
- 239000010428 baryte Substances 0.000 description 13
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 238000009775 high-speed stirring Methods 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 239000002987 primer (paints) Substances 0.000 description 5
- 239000004922 lacquer Substances 0.000 description 4
- 206010020843 Hyperthermia Diseases 0.000 description 3
- 239000010960 cold rolled steel Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000036031 hyperthermia Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 2
- 239000005543 nano-size silicon particle Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates the preparing method of nanometer powder dispersion. The dispersion comprises nanometer powder, dispersing auxiliary, organic polymer resin and solvent. The method comprises the following steps: using nanometer powder treated with surface processing agent, organic polymer resin and dispersing auxiliary as main material, ball milling, and sanding, emulsifying, dispersing and getting dispersion. The dispersion is added to improve the combination property.
Description
Technical field
The present invention relates to a kind of preparation method who is used for the nanometer functional powder dispersion of coil coating, belong to the organic resin coating manufacturing process technology field.
Background technology
Because specific surface area that nano-dispersed is mutually big and strong interfacial interaction produce quantum effect and surface effects, nano material is not only shown be different from general macroscopical performance of composites; Also may have property and function that stock blend does not possess, be used to prepare high-performance, the multifunctional material aspect has bright prospects.
The direction that nanotechnology is used in paint field has two: the one, improve the traditional coating performance, and utilize the rheological of coating and the particle diameter of filler to have certain relation, utilize nanotechnology can make the good nano paint of workability; Nanoparticle and exists the good interface bonding force because specific surface area is big between the organic resin matrix, thereby can improve the mechanical properties such as intensity, hardness, wear resistance, scoring resistance of original coating; The 2nd, the functional nano coating that preparation makes new advances is as military invisible coating, electrostatic shielding coating, nano antibacterial coating, nano-interface coating etc.
Chinese patent 1380369 and 1385483 has been described the coating for internal and external wall that is added with Nano filling, and Chinese patent 1375534 discloses a kind of imvite modified building coating.
Because the nature difference of nano-powder and organic polymer material is very big, has a large amount of interfaces, if do not add the quality consequence that processing directly adds the bringing on a disaster property of joining.The dispersiveness of nanoparticle in organic polymer coating is particularly important.The dispersing method of nano-powder has multiple, as mechanical dispersion method, the anti-agglomeration process of static, lyophilize powder dispersion method etc.
Bibliographical information is arranged, adopt ultrasonic vibration and nanometer CaCO
3Carry out two kinds of methods of silane coupling agent processing and improve nanometer CaCO
3Dispersion effect in Resins, epoxy; Detection shows that these two kinds of methods than the common dispersive better effects if that mixes, can realize nanometer CaCO
3Homodisperse in Resins, epoxy.Michael D.Kass publishes thesis at Maferials Letters and has reported in the aluminum oxide ball milling process and utilize action of ultrasonic waves and influence, has shown ball milling and ultrasonic wave coupling, can make the particle diameter of aluminum oxide littler, can improve dispersion effect.But these methods are complex process mostly, and preparation time is long, the nano-powder dispersion stabilization is the most not desirable.
Summary of the invention
The objective of the invention is to improve the deficiencies in the prior art part, a kind of nanometer functional powder dispersion for preparing in advance that is used for coil coating is provided, make coil coating have good dispersiveness and coating excellent properties.Another purpose of the present invention provides the preparation method of the nanometer functional powder dispersion that is used for coil coating.
The present invention is a kind of preparation method who is used for the nanometer functional powder dispersion of coil coating, it is characterized in that having following technological process and step:
A. in a certain amount of organic resin, add the nano-function powder of handling through organic surface treatment agent; Nano-function powder comprises any in nano barium sulfate, silicon oxide, titanium oxide, zinc oxide, nickel oxide, the aluminum oxide; Organic surface treatment agent is a sodium laurate, and the add-on of sodium laurate is 2.0～7.0% of a nano-powder weight; The amount that adds treated nano-function powder in organic resin is 28～32% of an organic resin weight; Add the dispersing auxiliary modified polyurethane again, the add-on of dispersion agent modified polyurethane is 10～30% of a nano-function powder weight
B. reinforced one by one, stir churning time 15～30 minutes one by one; Above-mentioned mixing solutions makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology; Finally make dispersion liquid.
Described organic resin is any in vibrin, Resins, epoxy, the aminoresin.
The median size of described nano-function powder is 30～50nm.
The dispersion liquid that the present invention makes only needs join in the lacquer process at coil coating and adds by 5～10% weight percents in use, can use behind the uniform mixing.The coating that final coil coating forms has good glossiness, the curved snappiness of T and erosion resistance after testing.In addition, the dispersiveness of nano-powder in coil coating also is significantly improved and improves.
Embodiment
After now embodiments of the invention being described in.
Embodiment 1
The processing step of present embodiment is as follows:
Be averaged the natural barite that particle diameter is 100nm, coat processing with organic surface treatment agent sodium laurate, its consumption is 4% of a natural barite nano-powder weight; Get 100 gram vibrin earlier, add 4.5 gram dispersing auxiliary polyurethane EFKA-4060, high-speed stirring 15 minutes; Add treated barite nano-powder by amount then, its add-on is 28% of organic vibrin weight, stirs 30 minutes again; Above-mentioned mixed solution makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology, finally makes dispersion liquid.
This dispersion liquid joined in the lacquer process in the 5wt% ratio at coil coating add, behind the uniform mixing the nanometer coil coating; This coating evenly is applied to cold-rolled steel coils, behind hyperthermia drying, gets color steel A, give over to benchmark test.
Embodiment 2
The processing step of present embodiment is as follows:
Be averaged the natural barite that particle diameter is 40nm, coat processing with organic surface treatment agent sodium laurate, its consumption is 4% of a natural barite nano-powder weight; Get 100 gram vibrin earlier, add 4.5 gram dispersing auxiliary polyurethane EFKA-4060, high-speed stirring 15 minutes; Add treated barite nano-powder by amount then, its add-on is 28% of organic vibrin weight, stirs 30 minutes again; Above-mentioned mixed solution makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology, finally makes dispersion liquid.
This dispersion liquid joined in the lacquer process in the 5wt% ratio at coil coating add, behind the uniform mixing the nanometer coil coating; This coating evenly is applied to cold-rolled steel coils, behind hyperthermia drying, gets color steel B, give over to benchmark test.
Embodiment 3
The processing step of present embodiment is as follows:
Be averaged the nano-titanium oxide that particle diameter is 40nm, coat processing with organic surface treatment agent sodium laurate, its consumption is 4% of a nano-titanium oxide weight; Get 100 gram vibrin earlier, add 5.0 gram dispersing auxiliary polyurethane EFKA-4060, high-speed stirring 15 minutes; Add treated nano-titanium oxide powder by amount then, its add-on is 30% of organic vibrin weight, stirs 30 minutes again; Above-mentioned mixed solution makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology, finally makes dispersion liquid.
This dispersion liquid joined in the lacquer process in the 5wt% ratio at coil coating add, behind the uniform mixing the nanometer coil coating; This coating evenly is applied to cold-rolled steel coils, behind hyperthermia drying, gets color steel C, give over to benchmark test.
Embodiment 4
The processing step of present embodiment is as follows:
Be averaged the nano silicon oxide that particle diameter is 40nm, coat processing with organic surface treatment agent sodium laurate, its consumption is 4% of a nano silicon oxide weight; Get 100 gram vibrin earlier, add 5.0 gram dispersing auxiliary polyurethane EFKA-4060, high-speed stirring 15 minutes; Add treated nano silica powder by amount then, its add-on is 30% of organic vibrin weight, stirs 30 minutes again; Above-mentioned mixed solution makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology, finally makes dispersion liquid.
By above-mentioned same quadrat method, get color steel D, give over to benchmark test.
Embodiment 5
The processing step of present embodiment is as follows:
Be averaged the natural barite that particle diameter is 40nm, with organic surface treatment agent sodium laurate coated processing, its consumption is 4% of a barite nano-powder weight; Get 100 gram Resins, epoxy earlier, add 5.0 gram dispersing auxiliary polyurethane EFKA-4060, high-speed stirring 15 minutes; Add treated barite nano-powder by amount then, its add-on is 30% of a weight epoxy, stirs 30 minutes again; Above-mentioned mixed solution makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology, finally makes dispersion liquid.
By above-mentioned same quadrat method, get color steel E, give over to benchmark test.
Embodiment 6
The processing step of present embodiment is as follows:
Be averaged the natural barite that particle diameter is 40nm, coat processing with organic surface treatment agent sodium laurate, its consumption is 4% of a barite powder weight; Get 100 gram aminoresin earlier, add 5.0 gram dispersing auxiliary polyurethane EFKA-4060, high-speed stirring 15 minutes; Add treated barite nano-powder by amount then, its add-on is 30% of an aminoresin weight, stirs 30 minutes again; Above-mentioned mixed solution makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology, finally makes dispersion liquid.
By above-mentioned same quadrat method, get color steel F, give over to benchmark test.
In addition, in order opposing frequently, not to be coated with material samples " conventional color steel ", to make benchmark test simultaneously yet what be added with nano-function powder.
The performance index of each color steel sample paint coatings are as shown in table 1 below:
Each color steel sample coating performance index of table 1
| Numbering | Glossiness | Hardness | Scratch resistant | T is curved | Salt-fog resistant time (hour) |
| A | 45.2 | 2H | 0 | 3T | 552 |
| B | 47.3 | H | 0 | 3T | 800 |
| C | 46.5 | 2H | 0 | 3T | 720 |
| D | 43.5 | 2H | 0 | 3T | 700 |
| E | 40.1 | 2H | 0 | 3T | 680 |
| F | 42.3 | 2H | 0 | 3T | 650 |
| Conventional | 35.7 | 2H | 0 | 4T | 500 |
As can be known from the above table, compare with conventional coating, after adding nano-powder, paint film T bends value, gloss value and hardness value and all increases, especially salt-fog resistant time has obvious prolongation, illustrate that the coating paint film flexibility after nano powder modified improves, glossiness strengthens, and has better hardness and excellent corrosion resistance nature with time delay.
Detect through scanning electronic microscope, can find out, contain granules of pigments and some apertures of differing in size in the primer coating without the nano-function powder modification from photo; In primer coating, then find the primer coating of many uniform granules of pigments and streamline shape through the modification of nanometer natural barite.This explanation is passed through primer coating of nanometer natural barite modification than unmodified primer coating densification, its compactness height.This is because when nano-powder reaches good dispersion state in organic resin, utilize its volume effect can fill " structure aperture ", forms the almost dense coating of atresia, and the infiltration of stopping each corrosive medium in the environment.
Claims (3)
1. preparation method who is used for the nanometer functional powder dispersion of coil coating is characterized in that having following technological process and step:
A. in a certain amount of organic resin, add the nano-function powder of handling through organic surface treatment agent; Nano-function powder comprises any in nano barium sulfate, silicon oxide, titanium oxide, zinc oxide, nickel oxide, the aluminum oxide; Organic surface treatment agent is a sodium laurate, and the add-on of sodium laurate is 2.0～7.0% of a nano-powder weight; The amount that adds treated nano-function powder in organic resin is 28～32% of an organic resin weight; Add the dispersing auxiliary modified polyurethane again, the add-on of dispersion agent modified polyurethane is 10～30% of a nano-function powder weight
B. reinforced one by one, stir churning time 15～30 minutes one by one; Above-mentioned mixing solutions makes its homodisperse again through ball milling, sand milling, the emulsify at a high speed of routine and shake multinomial dispersing technology; Finally make dispersion liquid.
2. a kind of preparation method who is used for the nanometer functional powder dispersion of coil coating as claimed in claim 1 is characterized in that described organic resin is any in vibrin, Resins, epoxy, the aminoresin.
3. a kind of preparation method who is used for the nanometer functional powder dispersion of coil coating as claimed in claim 1, the median size that it is characterized in that described nano-function powder is 30～50nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100269808A CN100400610C (en) | 2006-05-26 | 2006-05-26 | Preparation method of nanometer functional powder dispersion for coil coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100269808A CN100400610C (en) | 2006-05-26 | 2006-05-26 | Preparation method of nanometer functional powder dispersion for coil coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1884406A true CN1884406A (en) | 2006-12-27 |
| CN100400610C CN100400610C (en) | 2008-07-09 |
Family
ID=37582715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100269808A Expired - Fee Related CN100400610C (en) | 2006-05-26 | 2006-05-26 | Preparation method of nanometer functional powder dispersion for coil coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100400610C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824239A (en) * | 2010-04-15 | 2010-09-08 | 河南许绝电工绝缘材料有限公司 | Surface processing method of powder material |
| CN101733030B (en) * | 2008-11-13 | 2011-12-14 | 上海沪正纳米科技有限公司 | Preparation method of nano sulfur slurry |
| CN102757609A (en) * | 2011-04-27 | 2012-10-31 | 比亚迪股份有限公司 | Composition capable of improving sand mark shielding performance of colored paint and preparation method thereof and colored paint containing composition |
| CN113604137A (en) * | 2021-04-03 | 2021-11-05 | 中海油常州涂料化工研究院有限公司 | Scratch-resistant epoxy modified polyester back paint for coiled material with high coating rate and preparation method thereof |
| CN116639723A (en) * | 2023-06-16 | 2023-08-25 | 南风化工(运城)集团有限公司 | Preparation method of modified submicron barium sulfate |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005036105A (en) * | 2003-07-15 | 2005-02-10 | Nippon Kayaku Co Ltd | Photosensitive resin composition and film with cured coating thereof |
| CN1571078B (en) * | 2004-05-13 | 2011-05-04 | 上海大学 | Method for preparing high throughflow nanometre composite lightning arrester valve plate |
| CN1281695C (en) * | 2004-12-06 | 2006-10-25 | 复旦大学 | Nanometer composite polyester resin paint with high solid content and low viscosity and its prepn |
-
2006
- 2006-05-26 CN CNB2006100269808A patent/CN100400610C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101733030B (en) * | 2008-11-13 | 2011-12-14 | 上海沪正纳米科技有限公司 | Preparation method of nano sulfur slurry |
| CN101824239A (en) * | 2010-04-15 | 2010-09-08 | 河南许绝电工绝缘材料有限公司 | Surface processing method of powder material |
| CN102757609A (en) * | 2011-04-27 | 2012-10-31 | 比亚迪股份有限公司 | Composition capable of improving sand mark shielding performance of colored paint and preparation method thereof and colored paint containing composition |
| CN113604137A (en) * | 2021-04-03 | 2021-11-05 | 中海油常州涂料化工研究院有限公司 | Scratch-resistant epoxy modified polyester back paint for coiled material with high coating rate and preparation method thereof |
| CN116639723A (en) * | 2023-06-16 | 2023-08-25 | 南风化工(运城)集团有限公司 | Preparation method of modified submicron barium sulfate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100400610C (en) | 2008-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Li et al. | Influences of modified nanoparticles on hydrophobicity of concrete with organic film coating | |
| CN1227309C (en) | nano transparent wear-resistant composite coating | |
| CN1078827C (en) | Process for formation of multilayer film | |
| CN110003774B (en) | Water-based anticorrosive paint based on carbon nano composite material and preparation method thereof | |
| JP5174313B2 (en) | Aqueous pigment pastes containing metal pigments and their use for the production of water-based coatings that impart effects | |
| KR101060946B1 (en) | Surface treatment composition of steel sheet containing carbon nanotubes, metal surface treatment method using the same, and steel plate with excellent electrical conductivity | |
| CN103987799B (en) | Corrosion-resistant, chip resistance and resistance to fuel composition | |
| CN1235992C (en) | Water high-weatherability nano external wall paint and its preparation method | |
| EP2011838B1 (en) | Coating composition comprising surface-treated multilayer carbon nanofibers and coated article | |
| CN1884406A (en) | Preparation method of nanometer functional powder dispersion for coil coating | |
| KR101261931B1 (en) | Resin Coating Method using of nano diamond particle | |
| CN1895820A (en) | Production of nano-SiO2 for coating carbonyl iron powder | |
| CN103232786A (en) | Solvent-free nanometer epoxy anticorrosive paint and preparation method thereof | |
| CN109627931B (en) | Outdoor silvery powder coating and preparation method thereof | |
| CN111040527A (en) | Heat-reflecting super-hydrophobic PVDF coating and preparation method thereof | |
| CN1740227A (en) | Nanometer composite acrylic resin with high solid content and low viscosity and the prepn of its coating | |
| CN110724406B (en) | Modified flaky silicon dioxide, scratch-resistant easy-to-clean hand feeling coating and preparation method thereof | |
| CN1710001A (en) | Electrostatic nano powder coating without chromization and phosphorization and its preparing method | |
| KR20070081683A (en) | Nano-titanium paints for preventing corroosion | |
| CN106085044A (en) | A kind of antimicrobial nano coating, preparation method and antimicrobial nano coatings | |
| CN1219125C (en) | Carbon fibre surface organic high-molecule=inorganic nano slurry and its preparationg method | |
| DE10248799B4 (en) | Particle-containing coating composition and method for coating surfaces | |
| CN1186414C (en) | Preparation method of high scratch resistance nano compound polyurethane paint | |
| CN112063253B (en) | Water-based chromium-free Dacromet coating and preparation method thereof | |
| US20040244649A1 (en) | Metal colloid luster color material and method of producing thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: GUANGDONG YINFAN CHEMISTRY Co.,Ltd. Assignor: Shanghai University Contract fulfillment period: 2008.8.18 to 2018.8.18 Contract record no.: 2009440001728 Denomination of invention: Preparation method of nanometer functional powder dispersion for coil coating Granted publication date: 20080709 License type: Exclusive license Record date: 20091027 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.8.18 TO 2018.8.18; CHANGE OF CONTRACT Name of requester: GUANGDONG YINFAN CHEMICAL CO., LTD. Effective date: 20091027 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080709 |