CN1884354A - Rubber material for metal and rubber composite shock-absorbent product - Google Patents

Rubber material for metal and rubber composite shock-absorbent product Download PDF

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Publication number
CN1884354A
CN1884354A CN 200610016938 CN200610016938A CN1884354A CN 1884354 A CN1884354 A CN 1884354A CN 200610016938 CN200610016938 CN 200610016938 CN 200610016938 A CN200610016938 A CN 200610016938A CN 1884354 A CN1884354 A CN 1884354A
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Prior art keywords
rubber
elastomeric material
absorbent product
agent
composite shock
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CN 200610016938
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Chinese (zh)
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CN100404601C (en
Inventor
姜海军
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Changchun Baozhuo Rail Rubber Technology Co Ltd
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Individual
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Abstract

The invention provides a rubber material for buffer composite with metal and rubber, comprising rubber, vulcanizing agent, accelerating agent, anti-aging agent, strengthening agent, active agent, elasticizer, filler and anticoking additive. The rubber material is characterized by good mechanical property, distinctive anti-aging property, strong adhesive strength between rubber and metal, permitted rubber creep range during usage, long coke burning time, and fast vulcanizing speed.

Description

Metal and rubber composite shock-absorbent product elastomeric material
Technical field:
The present invention relates to a kind of elastomeric material, especially relate to a kind of city rail and the metro vehicle bogie metal of damping and draw and the elastomeric material of rubber combined product.
Background technology:
In recent years, urban track traffic obtains promotion and application in the increasing city of China, and China's track traffic is quite high in the ratio of the amount of building, construction speed is also very fast, and rail traffic vehicles bogie part is the key component of car body, and the metal-rubber composite shock-absorbent product that bogie is used belongs to safety member, require product elastomeric material good mechanical property, the weatherability excellence, metal and rubber bonding strength height, the product dynamic fatigue of making is good, and the rubber creep is in allowed limits in the usage period for product.Because product is large-scale thick product, be fit to compression molding, requires vulcanization of rubber curve flatness good, time of scorch is long, and speed was fast when sizing material began to vulcanize.At present, the elastomeric material part ageing-resistant performance, adhesiveproperties and the product creep properties aspect that are used for this accessory all can not satisfy the vehicle operating requirement, can't bear powerful tension and compression, bending, torsional load.
Summary of the invention:
Technical problem to be solved by this invention provides anti-vibration article elastomeric material and preparation method thereof that a kind of ageing-resistant performance, adhesiveproperties and product creep properties aspect can both satisfy the vehicle operating requirement, and it can bear powerful tension and compression, bending, torsional load.
Elastomeric material of the present invention is made up of the raw material of following weight part:
Rubber 100 vulcanizing agents 0.3~5 promotor 1.0~3.0
Anti-aging agent 1.5~6.0 strengthening agents 15~75 promoting agents 4.0~8.0
Softening softening agent 3.0~25 weighting agents 0~30 scorch retarder 0~1.0.
Rubber comprises natural rubber 75~85 weight parts, chlorosulfonated polyethylene rubber 15~25 weight parts.
Vulcanizing agent comprises sulphur 0.3-3 weight part, vulcanization crosslinking agent 0-2.0 weight part.
Promotor comprises sulfenamide 1.0~2.0 weight parts, thiurams 0~1.0 weight part.
Anti-aging agent comprises chemical antiager 1.5~3.0 weight parts, physical antioxidant 0~3.0 weight part.
Strengthening agent comprises carbon black 15~60 weight parts, white carbon black 0~15 weight part.
Promoting agent comprises zinc oxide 3.0~5.0 weight parts, stearic acid 1.0~3.0 weight parts.
Softening plasticising material stuff comprises coumarone solid 3.0~5.0 weight parts, Stockholm tar 0~5.0 weight part, machine oil 0~15 weight part.
Weighting agent is a light calcium carbonate.
Scorch retarder is C.T.P.
Elastomeric material good mechanical property of the present invention, weatherability excellence, rubber and Bond Strength height, the product dynamic fatigue of making is good, and the rubber creep is in allowed band in the usage period for product, and vulcanization of rubber curve flatness is good, time of scorch is long, and speed was fast when sizing material began to vulcanize.
Description of drawings:
Fig. 1 is embodiment 1 a vulkameter laboratory report graphic representation;
Fig. 2 is embodiment 2 vulkameter laboratory report graphic representations;
Fig. 3 is embodiment 3 vulkameter laboratory report graphic representations;
Fig. 4 is embodiment 4 vulkameter laboratory report graphic representations;
Fig. 5 is embodiment 5 vulkameter laboratory report graphic representations.
Embodiment:
Embodiment 1
Adopt natural rubber and chlorosulfonated polyethylene as elastomeric material, press following weight part proportioning:
Rubber 100, wherein: natural rubber SCR-5 75, chlorosulfonated polyethylene-40 25
Vulcanizing agent 2.1, wherein: sulphur 0.6, vulcanization crosslinking agent 268 1.5
Promotor 2.1, wherein: sulfenamide NOBS 1.5, thiurams TT 0.6
Anti-aging agent 4.5, wherein: chemical antiager 4010NA 1.0, chemical antiager D
1.5, physical antioxidant-protection wax FLY-3 2.0
Strengthening agent semi-reinforcing hydrocarbon black 32.0
Promoting agent 6.3, wherein: zinc oxide 5.0, stearic acid 1.3
Softening softening agent-solid coumarone 4.0
Scorch retarder C.T.P 0.5.
The elastomeric material test-results
Sequence number Project Index Test method Measured value
1 Hardness (Shao Er A) degree 72±3 GB531 71
2 Breaking tenacity Mpa ≥18.0 GB528 25
3 300% stress at definite elongation Mpa ≥10.0 GB528 15
4 Tensile yield % ≥350 GB528 490
5 70 ℃ of 24h 25% of the permanent change of constant compression ≤30 GB7759 23
6 Shock elasticity % ≥45 GB1681 46
7 Temperature limit of brittleness ℃ ≤-50 GB1682 -50 is not disconnected
8 Metal and rubber adhesion intensity Mpa ≥5.0 GB11211 7.0
9 70 ℃ of 96h of test conditions Changes in hardness (Shao Er A) degree ≤6 GB3512 4
Breaking tenacity changes % ≥-10 GB3512 -8
Tensile yield changes % ≥-20 GB3512 -14.2
Its vulkameter laboratory report is seen Fig. 1.
Embodiment 2
Adopt natural rubber and chlorosulfonated polyethylene as elastomeric material, press following weight part proportioning:
Rubber 100, wherein: natural rubber SCR-5 85, chlorosulfonated polyethylene-40 15
Vulcanizing agent 3.7, wherein: sulphur 2.5, vulcanization crosslinking agent 268 1.2
Promotor 1.8, wherein: sulfenamide NOBS 1.5, sulfenamide CZ 0.3
Anti-aging agent 4.5, wherein: chemical antiager 4010NA 1.0, chemical antiager D
1.5, physical antioxidant-protection wax FLY-3 2
Strengthening agent 52.0, wherein: hard(carbon)black 42.0, white carbon black 10.0
Promoting agent 6.3, wherein: zinc oxide 5, stearic acid 1.3
Softening softening agent-solid coumarone 4.0.
The elastomeric material test-results
Sequence number Project Index Test method Measured value
1 Hardness (Shao Er A) degree 63~75 GB531 65
2 Breaking tenacity Mpa ≥18.0 GB528 25
3 300% stress at definite elongation Mpa ≥10.0 GB528 13
4 Tensile yield % ≥350 GB528 450
5 70 ℃ of 24h 25% of constant compression tension set ≤30 GB7759 23
6 Shock elasticity % ≥45 GB1681 46
7 Temperature limit of brittleness ℃ ≤-50 GB1682 -50 is not disconnected
8 Metal and rubber adhesion intensity Mpa ≥5.0 GB11211 7.2
9 70 ℃ of 96h of test conditions Changes in hardness (Shao Er A) degree ≤6 GB3512 4
Breaking tenacity changes % ≥-10 GB3512 -8
Tensile yield changes % ≥-20 GB3512 -15.6
Its vulkameter laboratory report is seen Fig. 2.
Embodiment 3
Adopt natural rubber and chlorosulfonated polyethylene as elastomeric material, press following weight part proportioning:
Rubber 100, wherein: natural rubber SCR-5 85, chlorosulfonated polyethylene-40 15
Vulcanizing agent 3.7, wherein: sulphur 2.5, vulcanization crosslinking agent 268 1.2
Promotor 1.8, wherein: sulfenamide NOBS 1.5, sulfenamide CZ 0.3
Anti-aging agent 2.5, wherein: chemical antiager 4010NA 1.0, chemical antiager D 1.5
Strengthening agent 59.0, wherein: hard(carbon)black 49.0, white carbon black 10.0
Promoting agent 6.3, wherein: zinc oxide 5, stearic acid 1.3
Softening softening agent-solid coumarone 4.0
The elastomeric material test-results
Sequence number Project Index Test method Measured value
1 Hardness (Shao Er A) degree 63~75 GB531 69
2 Breaking tenacity Mpa ≥18.0 GB528 26
3 300% stress at definite elongation Mpa ≥10.0 GB528 13
4 Tensile yield % ≥350 GB528 500
5 70 ℃ of 24h 25% of constant compression tension set ≤30 GB7759 22
6 Shock elasticity % ≥45 GB1681 47
7 Temperature limit of brittleness ℃ ≤-50 GB1682 -50 is not disconnected
8 Metal and rubber adhesion intensity Mpa ≥5.0 GB11211 7.4
9 70 ℃ of 96h of test conditions Changes in hardness (Shao Er A) degree ≤6 GB3512 4
Breaking tenacity changes % ≥-10 GB3512 -8
Tensile yield changes % ≥-20 GB3512 -16
Its vulkameter laboratory report is seen Fig. 3.
Embodiment 4
Adopt natural rubber and chlorosulfonated polyethylene as elastomeric material, press following weight part proportioning:
Rubber 100, wherein: natural rubber SCR-5 85, chlorosulfonated polyethylene-40 15
Vulcanizing agent sulphur 2.5
Promotor 2.0, wherein: sulfenamide NOBS 1.5, sulfenamide CZ 0.5
Anti-aging agent 2.5, wherein: chemical antiager 4010NA 1.0, chemical antiager D 1.5
Strengthening agent 42.0, wherein: semi-reinforcing hydrocarbon black 37.0, white carbon black 15.0
Promoting agent 6.3, wherein: zinc oxide 5, stearic acid 1.3
Soften softening agent 7.0 wherein: solid coumarone 4.0, Stockholm tar 3.0
Embodiment 4 elastomeric material test-results
Sequence number Project Index Test method Measured value
1 Hardness (Shao Er A) degree 63~75 GB531 62
2 Breaking tenacity Mpa ≥18.0 GB528 24
3 300% stress at definite elongation Mpa ≥10.0 GB528 11.0
4 Tensile yield % ≥350 GB528 620
5 70 ℃ of 24h 25% of constant compression tension set ≤30 GB7759 28
6 Shock elasticity % ≥50 GB1681 50
7 Temperature limit of brittleness ℃ ≤-50 GB1682 -50 is not disconnected
8 Metal and rubber adhesion intensity Mpa ≥5.0 GB11211 6.2
9 70 ℃ of 96h of test conditions Changes in hardness (Shao Er A) degree ≤6 GB3512 +5
Breaking tenacity changes % ≥-10 GB3512 -8.6
Tensile yield changes % ≥-20 GB3512 -18.9
Its vulkameter laboratory report is seen Fig. 4.
Embodiment 5
Adopt natural rubber and chlorosulfonated polyethylene as elastomeric material, press following weight part proportioning:
Rubber 100, wherein: natural rubber SCR-5 85, chlorosulfonated polyethylene-40 15
Vulcanizing agent sulphur 2.5
Promotor 2.0, wherein: sulfenamide NOBS 1.5, sulfenamide CZ 0.5
Anti-aging agent 2.5, wherein: chemical antiager 4010N 1.0, chemical antiager D 1.5
The general carbon black 18.0 of strengthening agent
Weighting agent light calcium carbonate 18.0
Promoting agent 6.3, wherein: zinc oxide 5, stearic acid 1.3
Soften softening agent 18.0 wherein: solid coumarone 5.0, Stockholm tar 5.0, machine oil 8.0
Embodiment 5 elastomeric material performances: operative norm TB/T2843-1997
Sequence number Project Index Test method Detected result
1 Hardness (Shao Er A) degree 55±3 GB531 54
2 Breaking tenacity Mpa ≥20 GB528 21
3 300% stress at definite elongation Mpa ≥7.0 GB528 7.0
4 Tensile yield % ≥500 GB528 630
5 70 ℃ of 24h 25% of constant compression tension set ≤30 GB7759 28
7 Temperature limit of brittleness ℃ ≤-50 GB1682 -50 is not disconnected
8 Metal and rubber adhesion intensity Mpa ≥4.0 GB11211 6.2
9 70 ℃ of 96h of test conditions Changes in hardness (Shao Er A) degree ≤6 GB3512 +5
Breaking tenacity changes % ≥-10 GB3512 -8
Tensile yield changes % ≥-15 GB3512 -12
Its vulkameter laboratory report is seen Fig. 5.

Claims (10)

1, a kind of metal and rubber composite shock-absorbent product elastomeric material is characterized in that: be made up of the raw material of following weight part:
Rubber 100 vulcanizing agents 0.3~5 promotor 1.0~3.0
Anti-aging agent 1.5~6.0 strengthening agents 15~75 promoting agents 4.0~8.0
Softening softening agent 3.0~25 weighting agents 0~30 scorch retarder 0~1.0.
2, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: rubber comprises natural rubber 75~85 weight parts, chlorosulfonated polyethylene rubber 15~25 weight parts.
3, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: vulcanizing agent comprises sulphur 0.3-3 weight part, vulcanization crosslinking agent 0-2.0 weight part.
4, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: promotor comprises sulfenamide 1.0~2.0 weight parts, thiurams 0~1.0 weight part.
5, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: anti-aging agent comprises chemical antiager 1.5~3.0 weight parts, physical antioxidant 0~3.0 weight part.
6, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: strengthening agent comprises carbon black 15~60 weight parts, white carbon black 0~15 weight part.
7, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: promoting agent comprises zinc oxide 3.0~5.0 weight parts, stearic acid 1.0~3.0 weight parts.
8, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: softening plasticising material stuff comprises coumarone solid 3.0~5.0 weight parts, Stockholm tar 0~5.0 weight part, machine oil 0~15 weight part.
9, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: weighting agent is a light calcium carbonate.
10, metal according to claim 1 and rubber composite shock-absorbent product elastomeric material is characterized in that: scorch retarder is C.T.P.
CNB2006100169388A 2006-06-14 2006-06-14 Rubber material for metal and rubber composite shock-absorbent product Active CN100404601C (en)

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Cited By (15)

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CN101913855A (en) * 2010-08-24 2010-12-15 中北大学 Preparation method of iron strontium oxide magnetic nanoparticles and magnetic damping rubber thereof
CN102093612A (en) * 2010-12-28 2011-06-15 山东美晨科技股份有限公司 Truck engine mounting rubber preparation raw material
CN102167850A (en) * 2011-05-23 2011-08-31 安徽中鼎泰克汽车密封件有限公司 Rubber spring material for automobile braking double-cavity serial brake valve and preparation method thereof
CN102398615A (en) * 2010-09-15 2012-04-04 溧阳市振大铁路设备有限公司 Horizontal buffer for bogie frame of train
CN102443201A (en) * 2011-09-13 2012-05-09 安徽盛运橡胶有限责任公司 Rubber coating layer of conveyor roller, and preparation method thereof
CN101195695B (en) * 2007-12-25 2012-06-27 东莞市福瑞德橡塑制品有限公司 Rubber composition, production method and shock-absorbing foot mat produced thereof
CN101576556B (en) * 2009-06-08 2012-09-12 江苏东峰电缆有限公司 Method for judging scorching of natural-tetraphene rubber compound
CN103665701A (en) * 2013-11-26 2014-03-26 际华三五一七橡胶制品有限公司 Novel composite resin-ancient pine resin and preparation method thereof
CN104341616A (en) * 2013-07-28 2015-02-11 安徽同丰橡塑工业有限公司 Flame-retardation ageing-resistant rubber cable material and preparation method thereof
CN104530502A (en) * 2014-12-31 2015-04-22 天津市中塘五金橡胶制品有限公司 Rubber material for shock absorbing bushing
CN104744739A (en) * 2013-12-31 2015-07-01 无锡市美峰橡胶制品制造有限公司 Formula of antifatigue natural rubber
CN109749150A (en) * 2019-02-19 2019-05-14 江苏骆氏减震件有限公司 A kind of high intensity yielding rubber
CN109957153A (en) * 2019-03-26 2019-07-02 中国化工集团曙光橡胶工业研究设计院有限公司 A kind of resilient cushion rubber material
CN112469795A (en) * 2018-07-26 2021-03-09 朗盛德国有限责任公司 Adhesive mixture for uncured rubber
CN112500648A (en) * 2020-07-23 2021-03-16 安徽睿驰精密部件有限公司 Processing technology of rubber material for damping sleeve

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CN101195695B (en) * 2007-12-25 2012-06-27 东莞市福瑞德橡塑制品有限公司 Rubber composition, production method and shock-absorbing foot mat produced thereof
CN101576556B (en) * 2009-06-08 2012-09-12 江苏东峰电缆有限公司 Method for judging scorching of natural-tetraphene rubber compound
CN101913855B (en) * 2010-08-24 2011-11-16 中北大学 Preparation method of iron strontium oxide magnetic nanoparticles and magnetic damping rubber thereof
CN101913855A (en) * 2010-08-24 2010-12-15 中北大学 Preparation method of iron strontium oxide magnetic nanoparticles and magnetic damping rubber thereof
CN102398615B (en) * 2010-09-15 2015-11-25 溧阳市振大铁路设备有限公司 The horizontal buffer of train bogie
CN102398615A (en) * 2010-09-15 2012-04-04 溧阳市振大铁路设备有限公司 Horizontal buffer for bogie frame of train
CN102093612A (en) * 2010-12-28 2011-06-15 山东美晨科技股份有限公司 Truck engine mounting rubber preparation raw material
CN102167850B (en) * 2011-05-23 2013-04-03 安徽中鼎泰克汽车密封件有限公司 Rubber spring material for automobile braking double-cavity serial brake valve and preparation method thereof
CN102167850A (en) * 2011-05-23 2011-08-31 安徽中鼎泰克汽车密封件有限公司 Rubber spring material for automobile braking double-cavity serial brake valve and preparation method thereof
CN102443201A (en) * 2011-09-13 2012-05-09 安徽盛运橡胶有限责任公司 Rubber coating layer of conveyor roller, and preparation method thereof
CN104341616A (en) * 2013-07-28 2015-02-11 安徽同丰橡塑工业有限公司 Flame-retardation ageing-resistant rubber cable material and preparation method thereof
CN103665701A (en) * 2013-11-26 2014-03-26 际华三五一七橡胶制品有限公司 Novel composite resin-ancient pine resin and preparation method thereof
CN104744739A (en) * 2013-12-31 2015-07-01 无锡市美峰橡胶制品制造有限公司 Formula of antifatigue natural rubber
CN104530502A (en) * 2014-12-31 2015-04-22 天津市中塘五金橡胶制品有限公司 Rubber material for shock absorbing bushing
CN112469795A (en) * 2018-07-26 2021-03-09 朗盛德国有限责任公司 Adhesive mixture for uncured rubber
CN109749150A (en) * 2019-02-19 2019-05-14 江苏骆氏减震件有限公司 A kind of high intensity yielding rubber
CN109957153A (en) * 2019-03-26 2019-07-02 中国化工集团曙光橡胶工业研究设计院有限公司 A kind of resilient cushion rubber material
CN112500648A (en) * 2020-07-23 2021-03-16 安徽睿驰精密部件有限公司 Processing technology of rubber material for damping sleeve

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Effective date of registration: 20200106

Address after: Wu Xing Cun Da Tang Jia, Kuancheng District, Changchun City, 130000 Jilin Province

Patentee after: Changchun Baozhuo rail Rubber Technology Co Ltd

Address before: 130052, 5-100-52, Datang Village, Wuxing village, Kuancheng District, Jilin, Changchun

Patentee before: Jiang Haijun

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