CN1880524A - Composite cellulose viscose filament yarn with composite cellulose pulp as raw materials made of wood and bamboo mixture and preparation method thereof - Google Patents
Composite cellulose viscose filament yarn with composite cellulose pulp as raw materials made of wood and bamboo mixture and preparation method thereof Download PDFInfo
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- CN1880524A CN1880524A CNA2006100838620A CN200610083862A CN1880524A CN 1880524 A CN1880524 A CN 1880524A CN A2006100838620 A CNA2006100838620 A CN A2006100838620A CN 200610083862 A CN200610083862 A CN 200610083862A CN 1880524 A CN1880524 A CN 1880524A
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- China
- Prior art keywords
- filament yarn
- wood
- pulp
- viscose filament
- bamboo
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- 229920000297 Rayon Polymers 0.000 title claims abstract description 95
- 229920002678 cellulose Polymers 0.000 title claims abstract description 85
- 239000001913 cellulose Substances 0.000 title claims abstract description 82
- 239000002994 raw material Substances 0.000 title claims abstract description 62
- 239000002131 composite material Substances 0.000 title claims abstract description 60
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 45
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 45
- 241001330002 Bambuseae Species 0.000 title claims abstract description 45
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 45
- 239000011425 bamboo Substances 0.000 title claims abstract description 45
- 239000002023 wood Substances 0.000 title claims description 43
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000203 mixture Substances 0.000 title claims description 4
- 238000000034 method Methods 0.000 claims abstract description 45
- 238000009987 spinning Methods 0.000 claims abstract description 34
- 238000007670 refining Methods 0.000 claims abstract description 8
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 74
- 239000003513 alkali Substances 0.000 claims description 32
- 239000000835 fiber Substances 0.000 claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 30
- 239000003292 glue Substances 0.000 claims description 30
- 238000004519 manufacturing process Methods 0.000 claims description 28
- 239000002253 acid Substances 0.000 claims description 25
- 238000005406 washing Methods 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 14
- 238000009835 boiling Methods 0.000 claims description 12
- 238000010298 pulverizing process Methods 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 239000000123 paper Substances 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 7
- 230000032050 esterification Effects 0.000 claims description 7
- 238000005886 esterification reaction Methods 0.000 claims description 7
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004061 bleaching Methods 0.000 claims description 6
- 235000013409 condiments Nutrition 0.000 claims description 6
- 238000010411 cooking Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229920003043 Cellulose fiber Polymers 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000010306 acid treatment Methods 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 4
- 238000010009 beating Methods 0.000 claims description 4
- 230000000740 bleeding effect Effects 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000003398 denaturant Substances 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- 229920006221 acetate fiber Polymers 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- AEMOLEFTQBMNLQ-BKBMJHBISA-N alpha-D-galacturonic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-BKBMJHBISA-N 0.000 claims description 2
- 238000004458 analytical method Methods 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000007844 bleaching agent Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000008025 crystallization Effects 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 239000011086 glassine Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229920005610 lignin Polymers 0.000 claims description 2
- 229920002521 macromolecule Polymers 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011859 microparticle Substances 0.000 claims description 2
- 230000008707 rearrangement Effects 0.000 claims description 2
- 230000008929 regeneration Effects 0.000 claims description 2
- 238000011069 regeneration method Methods 0.000 claims description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 2
- 230000008961 swelling Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 abstract description 6
- 244000025254 Cannabis sativa Species 0.000 abstract description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract description 3
- 235000009120 camo Nutrition 0.000 abstract description 3
- 235000005607 chanvre indien Nutrition 0.000 abstract description 3
- 239000011487 hemp Substances 0.000 abstract description 3
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- 240000000491 Corchorus aestuans Species 0.000 description 2
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- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
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- Artificial Filaments (AREA)
Abstract
The invention discloses a composite cellulose viscose filament and making method, which adopts cotton, hemp, bamboo as raw material pulp according to weight proportion of cotton, hemp, bamboo at 1-99 percent: 1-99 percent: 1-99 percent. The making method comprises the following steps: immersing; squeezing; grinding; etiolating; dissolving; filtering; debubbling; spinning; refining; drying.
Description
Technical field:
The present invention relates to a kind of viscose filament yarn and preparation method thereof, particularly relating to a kind of is composite cellulose viscose filament yarn of producing of one of raw material and preparation method thereof with the compound cellulose pulp.
Background technology:
At present, viscose all is to be single raw material with the cotton pulp dregs of rice or wood pulps or bamboo pulp etc., a kind of regenerated celulose fibre of making through technical process such as dipping, squeezing, pulverizing, yellow, dissolving, filtration, maturation, deaeration, spinning, refining, oven dry.The fabric that with the natural fabric is raw material possesses good hygroscopicity, dyeability and antistatic behaviour.Raising day by day along with people's living standard, requirement for fabric is also more and more higher, not only pursue comfortableness, pay attention to environmental protection more, antibiotic property and biocidal property etc., existing composite viscose fiber all is to carry out compound as the semi-continuous centrifugal spinning machine on spinning machine, rather than in the pulp production process, just directly carry out various raw materials compound, yet, the cotton pulp dregs of rice, wood pulps, hemp dissolving pulp, the viscose of each single raw material production such as bamboo pulp, the performance dullness, show that individual character is not outstanding, performance has nothing in common with each other, and has their own characteristics each, as skin affinity, the deflection of fiber, the antibacterial bacteriostatic function, the fiber soft feeling, deodorization, gas permeability, coloring, bounce-back property, humidity absorption and releases etc., therefore the viscose of single pulp production can't satisfy people's multiple demand.Find that after deliberation plurality of raw materials is made the compound cellulose pulp, can improve the various performances of fiber, maximizes favourable factors and minimizes unfavourable ones, and remedies each other, and the premium properties of every kind of fiber is represented.Adopt this compound cellulose pulp that the natural compounding type that production performance is many, moral character is high viscose can be provided, satisfy people and realize the living needs grow with each passing hour, and be the composite cellulose viscose filament yarn made of the raw material advantage of comprehensive various native celluloses comprehensively with the plain pulp of New-type composite fibre.
Summary of the invention:
The purpose of this invention is to provide a kind of is the high performance viscose filament yarn fiber and preparation method thereof of raw material production with the compound cellulose pulp, the present invention is to be raw material so that mixed raw materials such as natural wood, bamboo wood are become composite cellulose pulp, expand the raw material sources of viscose, solved the problem that production efficiency is low, cost is high.Beautiful through wood, bamboo composite gloss that spinning makes, have natural good coloring, bounce-back property, humidity absorption and release, gas permeability are better than various synthetic fiber especially, be a kind of fully natural green environment-friendly products, the antibacterial bacteriostatic deodorant function and the texture that have the uniqueness that simple use cotton pulp, wood pulp, jute pulp viscose do not have simultaneously, also can overcome independent use bamboo viscose intensity and the low problem of whiteness, and raw material is easy to get, production technology optimization, efficient height, cost are low, as required the advantage of comprehensive various native celluloses.
Technical scheme of the present invention is as follows:
A kind of composite cellulose viscose filament yarn is characterized in that: described raw material pulp is the compound cellulose pulp that wood, bamboo raw material are made according to following weight proportion combination: wood: bamboo=1%～99%: 1%～99%.
A kind of composite cellulose viscose filament yarn of the present invention is meant with the compound cellulose pulp to be the viscose filament yarn of raw material production, and its specification is as described below:
Fiber number specification: 40～8000D
Monofilament radical: 1～300
Include light, semimat, golden unglazed and painted silk; The strand shape comprises conventional silk, flat filament and other shaped filaments.
The technical indicator of described a kind of composite cellulose viscose filament yarn comprises:
Do fracture strength: 〉=1.65CN/dtex
Wet breaking strength: 〉=0.75CN/dtex
Dried elongation at break: 17%-22.0%
Fineness deviation ratio :≤2.5%
Whiteness: 〉=70%
Residual sulfur content :≤15mg/100g people silk
Lousiness leads after testing :≤8/megameter people silk
Wood of the present invention, bamboo composite cellulose pulp are in wood, bamboo composite cellulose pulp production process natural wood raw material and bamboo material to be mixed and made into composite cellulose pulp.
The technical indicator of compound cellulose pulp of the present invention is as follows: ash≤0.25%, moisture 10.0 ± 0.5%, iron content≤40ppm, fatty wax≤0.25%, chlorine-bearing compound≤0.25%, pectic substance pentosan≤0.25, lignin≤0.25, alpha cellulose 〉=85%, viscosity 〉=8.0mpa.s, whiteness 〉=60%, constant volume weight 120-1020g/m3 inhales base number 200-970%; Swelling capacity 80-300%.Range of application: acetate fiber, copper ammonia fibre, viscose filament yarn, day silk, viscose short-thread, glassine paper, carbon fiber, CMC etc.
A kind of composite cellulose pulp manufacture method of the present invention comprises the steps: condiment, washes material, washing, making beating are discongested, mixing, removal of impurities washing, pre-acid, pre-chlorine, bleaching, acid treatment, removal of impurities washing, manufacture paper with pulp.A, condiment:, adjust structure with wood, in the bamboo fibre raw material any two kinds or two or morely get the raw materials ready according to any proportioning; B, boiling: wood, bamboo are adopted soda process, sulfate process or sulfite cooking, press 5.0～35.0% of oven dry weight and add NaOH, Na
2S, Na
2SO
3, H
2SO
3In one or more, liquor ratio is 1: 1.0-9.5, boiling vacuumizes earlier, intensification number of times 〉=1 time, little steam bleeding number of times 〉=0. time; C, wash material; D, washing; E, making beating are discongested: employing beater or fluffer are pulled an oar or are discongested, weight in wet base 5-50 gram; F, mixing: above-mentioned slurry is mixed in stock tank, or mixing to a certain step of manufacturing paper with pulp from condiment.G, removal of impurities washing; H, pre-acid: with the acid amount is the 0.2-10.0% of slurry oven dry weight, concentration 1.0-15.0%, pre-acid time 〉=5min; I, pre-chlorine: chlorine dosage is the 0.2-15.0% of slurry oven dry weight, concentration 0.2-10.0%, pre-chlorine time 〉=15min; J, bleaching: the viscosity of bleaching disposed slurry is 8-35mpa.s, first fibre 〉=80.0%, whiteness 〉=60%; K, acid treatment: sulfuric acid or hydrochloric acid are pressed the slurry oven dry weight and are added 0.2-10.0%, and calgon is pressed the slurry oven dry weight and added 0.1-8.0%, processing time 〉=30min; L, removal of impurities washing; M, manufacture paper with pulp.The 0.3-10% that presses oven dry weight before the described cooking process adds NaOH, and liquor ratio is that 1: 1.0～9.5 pairs raw materials are precooked.The NaOH that adds a certain amount of concentration before the described washing procedure and be 5%-30% carries out alkali and analyses.On the basis of technique scheme, be further to reduce energy consumption and stable control quality, can also adopt one of following several technical measures or all: in the described precooking process, can add alkali lye, acid, water and carry out boiling, also can directly feed vapour cooking.In the described step boiling, boiling vacuumizes earlier, intensification number of times 〉=1 time, and little steam bleeding number of times 〉=0 time, heat up, temperature retention time≤800 minute in maximum temperature≤200 ℃ of at every turn heating up at every turn.In the described step boiling, for improving the first fibre, press down bubble, the big gun that disappears, and reduce black liquor COD and colourity, the 0.1-3.0% that press the slurry oven dry weight adds the MA-1 auxiliary agent of Chongqing long-lived paper making additive factory production.Described MA-1 auxiliary agent is a kind of anion surfactant, but the automated biological degraded.
The preparation method of a kind of composite cellulose viscose filament yarn of the present invention comprises following processing step: dipping, squeezing, pulverizing, yellow, dissolving, filtration, deaeration, spinning, refining, oven dry.
Described dipping, squeezing, pulverizing, experienced operation are meant: the compound cellulose pulp is immersed under 30～60 ℃ temperature conditions in the alkali lye that concentration is 180～280g/L, again after the squeezer squeezing, pulverizing, reaching in the alkali fibre the fine content of first is 25～35%, alkali content is 15～18%, and density is 100～150Kg/m
3Also add the VIF-64 modifying agent that can improve the compound cellulose reactivity worth during dipping.Adopt the secondary temperature elevation control method during dipping, improved the reactivity worth of compound cellulose, effectively improve its reaction effect.Use spray equipment to add the VIF-9 stabilizing agent that improves the compound cellulose degree of polymerization in the expressing process, make that to fall collecting process more uniform and stable, the fine stable polymerization degree homogeneous of alkali.2000～3000 rev/mins of pulverization rollers that rotate at a high speed of employing make compound cellulose alkali fibre obtain good crushing effect during pulverizing, guarantee the abundant of yellow reaction.Experienced operation is used the experienced machine of belt, guarantees that the alkali fibre that enters experienced machine carries out according to first in first out, makes the fine chain rupture of compound cellulose alkali even, the fine stable polymerization degree homogeneous of alkali.
Yellow of the present invention, dissolution process adopt dry method constant temperature yellow method, and dry method constant temperature yellow method is meant: the CS that adds α-cell (methylcellulose) 26-35% in the relative alkali fibre in the alkali fibre
2(carbon disulfide), yellow temperature are 26-32 ℃, and the yellow time is 30～80 minutes.Add CS
2Shi Caiyong circulating line and spray equipment evenly add, and make CS
2In compound cellulose alkali fibre, fully mix.After yellow, add the VIF-51/41 denaturant that improves viscose filtration performance and spinning property, effectively improve the strainability and the spinning property of compound cellulose viscose glue.The alkali lye total amount that yellow need add (forming calculating according to viscose glue) is divided 3 adding xanthating machines, and the last 30% pair of xanthating machine that adds total amount behind xanthating machine material clearancen washes.Adopt viscose grinder to grind after the yellow, under 6～15 ℃ temperature, dissolve, make viscose glue reach good solute effect.
Spinning process of the present invention is meant: will carry out regeneration, drawing-off, cellulose macromolecule crystallization and rearrangement, the wire strip forming of composite fibre cellulose fiber through the viscose glue of dissolving, deaeration, filtration with continuous spinning machine or semi-continuous spinning machine.
The viscose glue that the compound cellulose that spinning process adopted makes comprises following feature: α-cell (methylcellulose) content: 7.8-8.20%; NaOH content is: 5.90-6.25%; Viscosity (falling ball method) is: 28-45 second; Degree of ripeness (NH4Cl value): 8.6-11.0ml; Population (in every milliliter of viscose glue 〉=10 micro particles numbers) be :≤1500; The secondary blob of viscose is: (number in every milliliter of viscose glue) is :≤10; The viscose glue surface tension is: 40-50dynes/cm; Esterification degree: 35-45.Owing to adopted above-mentioned feature, the viscose glue that makes compound cellulose make has possessed good spinning properties, can produce high-quality viscose filament yarn.
The acid bath that spinning process adopted comprises following feature: H
2SO
4Content is: 130～150g/l; ZnSO
4Content is: 10-13g/l; Na
2SO
4Content is: 220～265g/l; The acid bath temperature is: 51～56 ℃; The acid bath surface tension is: 40～50dynes/cm.Used denaturant VIF-53 and VIF-10 in acid bath, stabilizing agent VIF-70 has effectively improved the acid bath characteristic, and acid bath is suitable for and the supporting spinning properties of compound cellulose viscose glue.
Concise operation of the present invention is meant: in washing facility spinning cake or strand are carried out desulfurization, bleach and oil.Ao's mixture VIF-80 that strengthens composite fibre cellulose fiber desulfurization performance and the hardening agent VIF-90 that strengthens discoloration have been used in the refining process.This method is adopted in refining, has effectively improved composite fibre cellulose fiber refining effect, and character such as fiber sulfur-bearing, whiteness are effectively improved.
The present invention has solved the problem that production efficiency is low, cost is high owing to be directly to adopt mixed raw materials such as natural wood, bamboo wood to become composite cellulose pulp to be raw material, to have expanded the raw material sources of viscose.Beautiful through wood, bamboo composite gloss that spinning makes, have natural good coloring, bounce-back property, humidity absorption and release, gas permeability are better than various synthetic fiber especially, be a kind of fully natural green environment-friendly products, the antibacterial bacteriostatic deodorant function and the texture that have the uniqueness that simple use cotton pulp, wood pulp, jute pulp viscose do not have simultaneously, also can overcome independent use bamboo viscose intensity and the low problem of whiteness, and raw material is easy to get, production technology optimization, efficient height, cost are low, as required the advantage of comprehensive various native celluloses.
The specific embodiment:
Embodiment 1
The production of 120D/30F composite cellulose viscose filament yarn:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 50%: 50%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 188g/l
Dip time: 100 minutes
Alkali is fine to be formed: α-cell content: 28%
NaOH content: 16.3%
The VIF-64 addition: 0.5% (to α-cell)
The VIF-9 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 35.5% (to α-cell)
Yellow temperature: 30 ℃
The yellow time: 70 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 2.0% (to α-cell)
Spin preceding viscose glue:
α-cell content: 7.85%
NaOH content: 6.15%
Viscosity (falling ball method): 48 seconds
Degree of ripeness (NH4Cl value): 11.8ml
Population: 350/ml viscose glue
Secondary blob of viscose: 7/ml viscose glue
Surface tension: 49dynes/cm
Esterification degree: 39%
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 220g/l
ZnSO
4Concentration: 10.5g/l
Acid bath temperature: 52 ℃
Surface tension: 40dynes/cm
Spinning head stretching: 9.5%
End product quality:
Do fracture strength: 1.95CN/dtex
Wet breaking strength: 1.10CN/dtex
Dried elongation at break: 19.8%
Fineness deviation ratio :+0.8%
Whiteness: 71.6%
Residual sulfur content: 8.5mg/100g people's silk
Regain: 12.3%
Close oily rate: 0.25%
Embodiment 2
The production of 600D/100F composite cellulose viscose filament yarn:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 48 ℃
Concentration of lye: 180g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 32.3%
NaOH content: 15.8%
The VIF-64 addition: 1.0% (to α-cell)
The VIF-9 addition: 1.3% (to α-cell)
Yellow technology:
CS
2Addition: 30.5% (to α-cell)
Yellow temperature: 26.5 ℃
The yellow time: 80 minutes
Solution temperature: 13 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.03%
NaOH content: 5.98%
Viscosity (falling ball method): 42 seconds
Degree of ripeness (NH4Cl value): 12.1ml
Population: 425/ml viscose glue
Secondary blob of viscose: 8/ml viscose glue
Surface tension: 41dynes/cm
Esterification degree: 35%
Spinning technique:
H
2SO
4Concentration: 138g/l
Na
2SO
4Concentration: 239g/l
ZnSO
4Concentration: 10.8g/l
Acid bath temperature: 55 ℃
Surface tension: 48dynes/cm
Spinning head stretching: 18%
End product quality:
Do fracture strength: 2.1CN/dtex
Wet breaking strength: 1.27CN/dtex
Dried elongation at break: 20.0%
Fineness deviation ratio :-1.1%
Whiteness: 72.5%
Residual sulfur content: 9.3mg/100g people's silk
Regain: 12.2%
Oil content: 0.2%
Embodiment 3
The production of the unglazed composite cellulose viscose filament yarn of 120D/30F:
Become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 20%: 80%.
Impregnation technology:
Alkali liquid temperature: 42 ℃
Concentration of lye: 216g/l
Dip time: 90 minutes
Alkali is fine to be formed: α-cell content: 29.6%
NaOH content: 16.3%
The VIF-64 addition: 1.2% (to α-cell)
The VIF-9 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 28.5% (to α-cell)
Yellow temperature: 31 ℃
The yellow time: 45 minutes
Solution temperature: 15 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 7.85%
NaOH content: 5.96%
Viscosity (falling ball method): 47 seconds
Degree of ripeness (NH4Cl value): 11.3ml
Population: 950/ml viscose glue
Secondary blob of viscose: 9/ml viscose glue
Surface tension: 44dynes/cm
Esterification degree: 38%
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 232g/l
ZnSO
4Concentration: 9.8g/l
Acid bath temperature: 551.5 ℃
Surface tension: 44dynes/cm
Spinning head stretching: 13.5%
End product quality:
Do fracture strength: 1.95CN/dtex
Wet breaking strength: 1.05CN/dtex
Dried elongation at break: 18.6%
Fineness deviation ratio :-0.8%
Whiteness: 74.3%
Residual sulfur content: 7.2mg/100g people's silk
Regain: 12.0%
Oil content: 0.2%
Embodiment 4:
The production of the unglazed composite cellulose viscose filament yarn of 120D/30F:
Become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 60%: 40%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 235g/l
Dip time: 75 minutes
Alkali is fine to be formed: α-cell content: 31.5%
NaOH content: 16.5%
The VIF-64 addition: 1.2% (to α-cell)
The VIF-9 addition: 1.2% (to α-cell)
Yellow technology:
CS
2Addition: 33.8% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 10 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.1%
NaOH content: 5.9%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (NH4Cl value): 8.5ml
Population: 950/ml viscose glue
Secondary blob of viscose: 5/ml viscose glue
Surface tension: 48dynes/cm
Esterification degree: 45%
Spinning technique:
H
2SO
4Concentration: 140g/l
Na
2SO
4Concentration: 236g/l
ZnSO
4Concentration: 11.5g/l
Acid bath temperature: 53 ℃
Surface tension: 49dynes/cm
Spinning head stretching: 12%
End product quality:
Do fracture strength: 2.1CN/dtex
Wet breaking strength: 1.27CN/dtex
Dried elongation at break: 20.0%
Fineness deviation ratio :-1.1%
Whiteness: 72.5%
Residual sulfur content: 9.3%
Regain: 12.2%
Oil content: 0.7mg/100g people's silk
Embodiment 5:
120D/30F has the production of photoreactivation cellulose viscose filament yarn:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 40%: 60%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 235g/l
Dip time: 75 minutes
Alkali is fine to be formed: α-cell content: 31.5%
NaOH content: 16.5%
The VIF-64 addition: 1.2% (to α-cell)
The VIF-9 addition: 1.2% (to α-cell)
Yellow technology:
CS
2Addition: 33.8% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 10 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.1%
NaOH content: 5.9%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (NH4Cl value): 8.5ml
Population: 950/ml viscose glue
Secondary blob of viscose: 5/ml viscose glue
Surface tension: 48dynes/cm
Esterification degree: 45%
Spinning technique:
H
2SO
4Concentration: 140g/l
Na
2SO
4Concentration: 236g/l
ZnSO
4Concentration: 11.5g/l
Acid bath temperature: 53 ℃
Surface tension: 49dynes/cm
Spinning head stretching: 12%
End product quality:
Do fracture strength: 2.1CN/dtex
Wet breaking strength: 1.27CN/dtex
Dried elongation at break: 20.0%
Fineness deviation ratio :-1.1%
Whiteness: 72.5%
Residual sulfur content: 9.3%
Regain: 12.2%
Oil content: 0.7mg/100g people's silk
Embodiment 6
As a same reason, for other end value points, can realize equally, and reach technique effect of the present invention.
Embodiment 7
120D/30F has the production of photoreactivation cellulose viscose filament yarn:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 1%: 99%.
Embodiment 8
The production of the unglazed composite cellulose viscose filament yarn of 120D/30F:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: the weight proportion proportioning of wood, bamboo raw material is: 99%: 1%.
On basis of the present invention, those of ordinary skill in this technical field can both obtain following relevant art enlightenment: becoming composite cellulose pulp to be not restricted to the listed raw material of the present invention with natural wood, bamboo mixed raw material, is that raw material is made composite cellulose viscose filament yarn of the present invention and is not limited only to the listed raw material of the present invention equally with the composite cellulose pulp.
On basis of the present invention, the those of ordinary skill in this technical field can be realized purpose of the present invention in conjunction with other known property general knowledge.
The present invention is not limited only to the literal statement of claim literal, above-mentioned being included in the scope of the present invention.
Claims (16)
1, being mixed and made into composite cellulose pulp with wood, bamboo wood is the composite cellulose viscose filament yarn that raw material is made, and it is characterized in that: described raw material pulp is the compound cellulose pulp that wood, bamboo raw material are made according to following weight proportion combination: wood: bamboo=1%～99%: 1%～99%.
2, a kind of composite cellulose viscose filament yarn according to claim 1 is characterized in that: be meant with the compound cellulose pulp to be the viscose filament yarn of raw material production, its specification is as described below:
Fiber number specification: 40～8000D
Monofilament radical: 1～300
Include light, semimat, full-dull and painted silk; The strand shape comprises conventional silk, flat filament and other shaped filaments.
3, a kind of composite cellulose viscose filament yarn according to claim 1, it is characterized in that: the technical indicator of described a kind of composite cellulose viscose filament yarn comprises:
Do fracture strength: 〉=1.65CN/dtex
Wet breaking strength: 〉=0.75CN/dtex
Dried elongation at break: 17%-22.0%
Fineness deviation ratio :≤2.5%
Whiteness: 〉=70%
Residual sulfur content :≤15mg/100g people silk
Lousiness leads after testing :≤8/megameter people silk.
4, a kind of composite cellulose viscose filament yarn according to claim 1 is characterized in that: described raw material pulp is the compound cellulose pulp that wood, bamboo raw material are made according to following weight proportion combination: wood 50%, bamboo 50%.
5, a kind of composite cellulose viscose filament yarn according to claim 1 is characterized in that: described raw material pulp is the compound cellulose pulp that wood, bamboo raw material are made according to following weight proportion combination: wood 80%, bamboo 20%.
6, a kind of composite cellulose viscose filament yarn according to claim 1 is characterized in that: described raw material pulp is the compound cellulose pulp that wood, bamboo raw material are made according to following weight proportion combination: wood 20%, bamboo 80%.
7, according to one of any described a kind of composite cellulose viscose filament yarn of claim 1-6, it is characterized in that: the preparation method of described a kind of composite cellulose viscose filament yarn comprises following processing step: dipping, squeezing, pulverizing, yellow, dissolving, grinding, filtration, deaeration, spinning, refining, oven dry.
8, a kind of composite cellulose viscose filament yarn according to claim 7, it is characterized in that: described dipping, squeezing, pulverizing, experienced operation are meant: the compound cellulose pulp is immersed under 30～60 ℃ temperature conditions in the alkali lye that concentration is 180～280g/L, again after the squeezer squeezing, pulverizing, reaching in the alkali fibre the fine content of first is 25～35%, alkali content is 15～18%, and density is 100～150Kg/m
3Wherein:
Adopt 2000～3000 rev/mins of pulverization rollers of rotation at a high speed during pulverizing;
Experienced operation is used the experienced machine of belt, guarantees that the alkali fibre that enters experienced machine carries out according to first in first out.
9, a kind of composite cellulose viscose filament yarn according to claim 7, it is characterized in that: described yellow, dissolution process adopt dry method constant temperature yellow method, and dry method constant temperature yellow method is meant: the CS that adds α-cell (methylcellulose) 26-35% in the relative alkali fibre in the alkali fibre
2(carbon disulfide), yellow temperature are 26-32 ℃, and the yellow time is 30～80 minutes; Adopt viscose grinder to grind after the yellow, under 6～15 ℃ temperature, dissolve.
10, a kind of composite cellulose viscose filament yarn according to claim 7, it is characterized in that: described spinning process is meant: will carry out regeneration, drawing-off, cellulose macromolecule crystallization and rearrangement, the wire strip forming of composite fibre cellulose fiber through the viscose glue of dissolving, deaeration, filtration with continuous spinning machine or semi-continuous spinning machine.
11, a kind of composite cellulose viscose filament yarn according to claim 7 is characterized in that: the viscose glue that the compound cellulose that spinning process adopted makes comprises following feature: α-cell (methylcellulose) content and is: 7.8-8.20%; NaOH content is: 5.90-6.25%; Viscosity (falling ball method) is: 28--45 second; Degree of ripeness (NH4Cl value): 8.6-11.0ml; Population (in every milliliter of viscose glue 〉=10 micro particles numbers) be :≤1500; The secondary blob of viscose is: (number in every milliliter of viscose glue) is :≤10; The viscose glue surface tension is: 40-50dynes/cm; Esterification degree: 35-45.
12, a kind of composite cellulose viscose filament yarn according to claim 7, it is characterized in that: the acid bath that spinning process adopted comprises following feature: H
2SO
4Content is: 130～150g/l; ZnSO
4Content is: 10-13g/l; Na
2SO
4Content is: 220～265g/l; The acid bath temperature is: 51～56 ℃; The acid bath surface tension is: 40～50dynes/cm.Denaturant VIF-53 and VIF-10 in acid bath, have been used, stabilizing agent VIF-70.
13, a kind of composite cellulose viscose filament yarn according to claim 7 is characterized in that: described concise operation is meant: in washing facility spinning cake or strand are carried out desulfurization, bleach and oil; Ao's mixture VIF-80 and hardening agent VIF-90 have been used in the refining process.
14, a kind of composite cellulose viscose filament yarn according to claim 1, it is characterized in that: the technical indicator of described compound cellulose pulp is as follows: ash≤0.25%, moisture 10.0 ± 0.5%, iron content≤40ppm, fat wax≤0.25%, chlorine-bearing compound≤0.25%, pectic substance pentosan≤0.25, lignin≤0.25, alpha cellulose 〉=85%, viscosity 〉=8.0mpa.s, whiteness 〉=60%, constant volume weight 120-1020g/m3 inhales base number 200-970%; Swelling capacity 80-300%.Range of application: acetate fiber, copper ammonia fibre, viscose filament yarn, day silk, viscose short-thread, glassine paper, carbon fiber, CMC.
15, according to claim 1 or 14 described a kind of composite cellulose viscose filament yarns, it is characterized in that: described a kind of composite cellulose pulp manufacture method comprises the steps: condiment, washes material, washing, making beating are discongested, mixing, removal of impurities washing, pre-acid, pre-chlorine, bleaching, acid treatment, removal of impurities washing, manufacture paper with pulp.
16, a kind of composite cellulose viscose filament yarn according to claim 14 is characterized in that:
A, condiment:, adjust structure with wood, in the bamboo fibre raw material any two kinds or two or morely get the raw materials ready according to any proportioning;
B, boiling: wood, bamboo are adopted soda process, sulfate process or sulfite cooking, press 5.0～35.0% of oven dry weight and add NaOH, Na
2S, Na
2SO
3, H
2SO
3In one or more, liquor ratio is 1: 1.0-9.5, boiling vacuumizes earlier, intensification number of times 〉=1 time, little steam bleeding number of times 〉=0 time;
C, wash material;
D, washing;
E, making beating are discongested: employing beater or fluffer are pulled an oar or are discongested, weight in wet base 5-50 gram;
F, mixing: above-mentioned slurry is mixed in stock tank, or mixing to a certain step of manufacturing paper with pulp from condiment;
G, removal of impurities washing;
H, pre-acid: with the acid amount is the 0.2-10.0% of slurry oven dry weight, concentration 1.0-15.0%, pre-acid time 〉=5min;
I, pre-chlorine: chlorine dosage is the 0.2-15.0% of slurry oven dry weight, concentration 0.2-10.0%, pre-chlorine time 〉=15min;
J, bleaching: the viscosity of bleaching disposed slurry is 8-35mpa.s, first fibre 〉=80.0%, whiteness 〉=60%;
K, acid treatment: sulfuric acid or hydrochloric acid are pressed the slurry oven dry weight and are added 0.2-10.0%, and calgon is pressed the slurry oven dry weight and added 0.1-8.0%, processing time 〉=30min; L, removal of impurities washing; M, manufacture paper with pulp.The 0.3-10% that presses oven dry weight before the described cooking process adds NaOH, and liquor ratio is that 1: 1.0～9.5 pairs raw materials are precooked.The NaOH that adds a certain amount of concentration before the described washing procedure and be 5%-30% carries out alkali and analyses;
Wherein: in the described precooking process, can add alkali lye, acid, water and carry out boiling, also can directly feed vapour cooking;
In the described step boiling, boiling vacuumizes earlier, intensification number of times 〉=1 time, and little steam bleeding number of times 〉=0 time, heat up, temperature retention time≤800 minute in maximum temperature≤200 ℃ of at every turn heating up at every turn;
In the described step boiling, the 0.1-3.0% that presses the slurry oven dry weight adds the MA-1 auxiliary agent that Chongqing long-lived paper making additive factory produces; Described MA-1 auxiliary agent is a kind of anion surfactant.
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|---|---|---|---|
| CNB2006100838620A CN100549252C (en) | 2006-05-08 | 2006-06-06 | Being mixed and made into composite cellulose pulp with wood, bamboo wood is composite cellulose viscose filament yarn and the preparation method that raw material is made |
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|---|---|---|---|
| CN200610020969.0 | 2006-05-08 | ||
| CN 200610020969 CN1844496A (en) | 2006-05-08 | 2006-05-08 | Composite cellulose viscose filament yarn with composite cellulose pulp as raw materials made of wood and bamboo mixture and preparation method thereof |
| CNB2006100838620A CN100549252C (en) | 2006-05-08 | 2006-06-06 | Being mixed and made into composite cellulose pulp with wood, bamboo wood is composite cellulose viscose filament yarn and the preparation method that raw material is made |
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|---|---|---|---|---|
| CN112011885A (en) * | 2020-08-31 | 2020-12-01 | 无锡恒诺纺织科技有限公司 | Viscose fiber knitted fabric manufacturing method |
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