CN1879944A - Processor for eliminating indoor organic volatile - Google Patents

Processor for eliminating indoor organic volatile Download PDF

Info

Publication number
CN1879944A
CN1879944A CNA2005100263559A CN200510026355A CN1879944A CN 1879944 A CN1879944 A CN 1879944A CN A2005100263559 A CNA2005100263559 A CN A2005100263559A CN 200510026355 A CN200510026355 A CN 200510026355A CN 1879944 A CN1879944 A CN 1879944A
Authority
CN
China
Prior art keywords
processor
filler
organic volatile
quartz burner
indoor organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2005100263559A
Other languages
Chinese (zh)
Inventor
张德麟
薛攀霆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNA2005100263559A priority Critical patent/CN1879944A/en
Priority to PCT/CN2006/001184 priority patent/WO2006128383A1/en
Publication of CN1879944A publication Critical patent/CN1879944A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultraviolet radiation
    • A61L9/205Ultraviolet radiation using a photocatalyst or photosensitiser
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/20Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
    • F24F8/22Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using UV light

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Catalysts (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention relates to a processor for eliminating the organic volatile, wherein the processor is embedded into the frame; it comprises at least one anatase nanometer titania metallic mesh skeleton stuff; the stuffs are parallel with space between them; and it comprises at least one ultraviolet tube inside the space or on the side surface of stuff; and it comprises at least on ventilate fan. The invention can treat the volatiles, as organic compound, etc.

Description

A kind of processor of eliminating indoor organic volatile matter
Technical field
The present invention relates to gas treatment indoor or airtight or the semi-hermetic space is more specifically referred to a kind of processor of eliminating indoor organic volatile matter, this processor is embedded in picture frame or the similar frame structure mutually.
Background technology
People know, the air of long-term contact stain, can reduce human respiratory immunity, the incidence of disease of laryngitis, bronchitis, heart and lung diseases is increased, and have a large amount of contaminants of chemical origins at home indoor, as the material of harmful human bodies such as the shigella dysenteriae that taken up because of the generation moment cyclone of flushing the toilet in formaldehyde, benzene, dimethylbenzene, ammonia, sulfur dioxide, nitrogen dioxide, carbon monoxide, carbon dioxide, total volatile organism (TVOC), pellet (PM) and the lavatory and other bacterium.
Because organic volatile (VOC) is present in pesticide, hardwood clamping plate, adhesive, paint, plastics, carpet, wooden wallboard, parquet floor, decoration coating, facsimile machine, printer, cosmetics and washing agent etc., all there are these organic volatile contact scar things in various places with human living, office and environment of an activation associated.Newly-decorated indoor material needs about 5~6 years could discharge whole organic volatile contact scar things fully.Volatile organic matter total amount in sensing chamber of Environmental Protection Agency USA in 1989 reaches kind more than 900, and has listed indoor common organic volatile (VOC) also up to nearly hundred in World Health Organization's " just common recognition that the concern of indoor air pollutants is reached " in 1984 report.General new the sprucing up of China is detected content of formaldehyde by exceeding standard 6 times to 40 times, even higher, and these all directly can cause human respiratory tract and angiocardiopathy.Because indoor organic volatile matter is slow release; RT in indoor environment is very long; though can lean on indoor and the open air mode such as ventilation of windowing carries out; but still can't all remove; when indoor neonate or uncomfortable man-hour arranged, can cause disease, cancer, slow poisoning or acute poisonings such as childhood lymphoblastic leukemia, cardiopulmonary usually.
Can't be for a long time or the short-term public place of windowing and ventilating for hospital, restaurant, high-riser, dining room, indoor meeting room, market, interior of aircraft, train case, museum, the Art Museum or tunnel, gallery etc., exist the organic volatile gas of harm to be difficult to give out outdoor to human body, the people is bigger in the anelasticity of these public places, therefore the harm to human body is also just bigger, and the number of being encroached on is also many more.If be provided with specially eliminate these gases device in public in, easily be damaged, and not attractive in appearance.But careful people can find that these places often all are hung with picture frame or similar frame structure, how to utilize the existence conditions of public place to eliminate these organic volatile gas that people produces harm is then seemed very important.
Summary of the invention
The purpose of this invention is to provide a kind of processor of eliminating indoor organic volatile matter, this processor can be removed effectively and be present in the VOC gas of public place to person generation harm, also can protect processor not to be damaged preferably.
To achieve these goals, the present invention adopts following technical scheme:
A kind of processor of eliminating indoor organic volatile matter,
This processor is embedded in picture frame or the similar frame structure mutually and comprises:
The metal net shaped skeleton structure filler of several nanometer anatase titanias body, filler body be arranged side by side and the filler body between leave at interval;
At least one quartz burner, quartz burner place in the interval between the filler body or place the side of filler body.
The metal net shaped skeleton structure filler of described nanometer anatase titania body is strip shape body and is provided with one at least.
The metal net shaped skeleton structure filler of described nanometer anatase titania body is that a perpendicular or parallel cross sectional shape is irregular or regular polygonal column.
Described quartz burner is any of middle pressure ultraviolet lamp, high-pressure sodium lamp, black light lamp, ultraviolet germicidal lamp.
The wavelength of described quartz burner is between the 250nm-380nm.
A kind of processor of eliminating indoor organic volatile matter,
This processor is embedded in picture frame or the similar frame structure mutually and comprises:
The metal net shaped skeleton structure filler of several nanometer anatase titanias body, filler body be arranged side by side and the filler body between leave at interval;
At least one quartz burner, quartz burner place in the interval between the filler body or place the side of filler body;
At least one air guide fan, air guide fan are positioned at the side of picture frame or similar frame structure and are arranged side by side with the filler body.
Described air guide fan places a side or the two side ends of picture frame or similar frame structure.
The metal net shaped skeleton structure filler of described nanometer anatase titania body is strip shape body and is provided with one at least.
Described quartz burner is any of middle pressure ultraviolet lamp, high-pressure sodium lamp, black light lamp, ultraviolet germicidal lamp.
The wavelength of described quartz burner is between the 250nm-380nm.
In technique scheme of the present invention, this processor be embedded in picture frame or the similar frame structure mutually and comprise at least one metal net shaped skeleton structure filler of nanometer anatase titania body, filler body be arranged side by side and the filler body between leave at interval; At least one quartz burner, quartz burner place in the interval between the filler body or place the side of filler body.In addition, also comprise at least one air guide fan, the air guide fan is positioned at the side of picture frame or similar frame structure and is arranged side by side with the filler body.This processor can make full use of picture frame or the similar frame structure that the public place possesses and establish within it, come the VOC that the public place exists is handled, VOC is decomposed effectively apace by the nano titanium dioxide photocatalysis effect of the irradiation of the quartz burner in the processor, nanometer anatase titania is when removing various harmful substance, and its effect can't weaken or disappear; As long as lasting ultraviolet ray irradiation is arranged, nanometer anatase titania can constantly produce the valency chain structure of nominal price photon hole and then oxidation of organic compounds and the harmful inorganic matter of cut-out.The setting of air guide fan then can quicken to eliminate the VOC matter that the person is produced fatal harm.And all these are all blocked by picture frame or similar frame structure dexterously, have both protected the security of processor, do not lose the attractive in appearance of indoor or public place again.
Description of drawings
Fig. 1 is the example structure schematic diagram of processor of the present invention.
Fig. 2 is another example structure schematic diagram of processor of the present invention.
The specific embodiment
For further specifying above-mentioned purpose of the present utility model, technical scheme and effect, in conjunction with above-mentioned each figure the utility model is described in detail by the following examples.
Understand for the ease of the present invention being had better, below earlier the correlation of titanium dioxide is done following introduction:
The photocatalysis characteristic of titanium dioxide was found by Japanese Teng Yuzhao professor in 1972, has been obtained extensive studies and application so far.Light-catalysed basic principle is: after conductor oxidate (as titanium dioxide) nano particle is subjected to photon irradiation greater than the energy gap energy, electronics transits to conduction band from valence band, produced electron-hole pair, electronics has reproducibility, the hole has oxidisability, the OH-of hole and oxide semiconductor nanoparticle surface (hydroxide ion) reaction generates the very high OH free radical (hydroxyl free radical) of oxidisability, and active OH free radical can be the oxidation operation of many difficult degradations CO 2And H 2Inorganic matters such as O.Therefore, nano titanium oxide not only can be widely used in the photocatalytic degradation to waste water from dyestuff, agricultural chemicals waste water, surfactant, itrogenous organic substance, chloride, fluorine Lyons, industrial acid-washed waste water and oily waste water etc., and it is degraded to CO 2, H 2O and other little molecule inorganic matter; Simultaneously, can also be to airborne VOC (VOC), as formaldehyde, benzene, dimethylbenzene, ammonia, sulfur dioxide, nitrogen dioxide, carbon tetrachloride, trichloro-ethylene, tetrachloro-ethylene, chloroform, 1, the 2-dichloro-benzenes, 1,3-dichloro-benzenes, ethylbenzene, toluene are degraded.
The present invention based on principle be exactly can produce powerful redox when utilizing nanometer anatase titania to shine ultraviolet ray, the oxidation operation around the nanometer anatase titania can be decomposed or the molecular link chain of inorganic matter gas destroyed and then reach clean indoor air quality and sterilization effects.Guiding theory is to utilize that majority all hangs with picture frame or similar frame structure in the existing indoor or public place; the processor that can eliminate indoor organic volatile matter is installed in back in these picture frames or similar frame structure; the existing VOC matter that the person is produced fatal harm in like this can decontamination chamber or in the public place; and these processors all can also be blocked by picture frame or similar frame structure dexterously; protect the security of processor, do not lost the attractive in appearance of public place again.
Embodiment 1
Please earlier in conjunction with shown in Figure 1,
This processor comprises the metal net shaped skeleton structure filler of several nanometer anatase titanias body 4, at least one the quartz burner 5 that is embedded in mutually in picture frame or the similar frame structure, the metal net shaped skeleton structure filler of several nanometer anatase titanias body 4 is and is arranged side by side, and leaves between the filler body 4 at interval; Quartz burner 5 places in the interval between the filler body 4 or places the side of filler body.
The metal net shaped skeleton structure filler of described nanometer anatase titania body 4 is for strip shape body and be provided with one at least.
The metal net shaped skeleton structure filler of described nanometer anatase titania body 4 is that a perpendicular or parallel cross sectional shape is irregular or regular polygonal column, can be shone by quartz burner 5.
Embodiment 2
See also shown in Figure 2,
This processor comprises the metal net shaped skeleton structure filler of several nanometer anatase titanias body 4, at least one quartz burner 5, at least one the air guide fan 6 that is embedded in mutually in picture frame or the similar frame structure, the metal net shaped skeleton structure filler of several nanometer anatase titanias body 4 is and is arranged side by side, and leaves between the filler body 4 at interval; Quartz burner 5 places in the interval between the filler body 4 or places the side of filler body, air guide fan 6 places a side or the two side ends of picture frame or similar frame structure, as an air guide fan, then both can be installed on the air inlet of picture frame or similar frame structure, also can be installed on air outlet, the purpose that the air guide fan is installed is to accelerate circulation.Can certainly the air guide fan be installed respectively at air inlet and air outlet.
Air guide fan 6 is generally selected the small fan of micro motor for use, and it takes folk prescription to the air draught air inlet.
Equally,
The metal net shaped skeleton structure filler of described nanometer anatase titania body 4 is for strip shape body and be provided with one at least.
The metal net shaped skeleton structure filler of described nanometer anatase titania body 4 is that a perpendicular or parallel cross sectional shape is irregular or regular polygonal column, can be shone by quartz burner 5.
When concrete installation processor of the present invention, remove picture frame or similar frame structure 1 earlier, utilize the immobilization material 2 of picture frame or similar frame structure, and the single or double made by various materials such as metal or plastics and the ventilative frame 3 of multiaspect are installed, after this metal net shaped skeleton structure filler of nanometer anatase titania body 4 and quartz burner 5, air guide fan 6 are installed again.In Fig. 1 and Fig. 2, picture frame or similar frame structure are power line 7 behind.
Described ventilative frame 3 is the frame body that the cross-ventilation hole is arranged, and effectively shielding of ultraviolet irradiates outside the frame body.
In the above-described embodiment,
The quantity of quartz burner 5 can be set as required, and three fluorescent tubes, four fluorescent tubes etc. can be set.
Press any of ultraviolet lamp, high-pressure sodium lamp, black light lamp, ultraviolet germicidal lamp during described quartz burner 5 is selected for use, the ultraviolet light wavelength that quartz burner 5 sends is between 250nm~380nm.
Need to prove,
The metal net shaped skeleton structure filler of nanometer anatase titania body 4 is made up of two parts, a part is 12 stereo metal mesh skeleton structure sponge fillers, another part is exactly the frame structure that supports this filler, and 12 stereo metal mesh skeleton structure sponge fillers just are filled in the filler frame structure.Frame structure is that 12 stereo metal mesh skeleton structure sponge fillers are fixed and supported.The surface of 12 stereo metal mesh skeleton structure sponge fillers has loaded anatase titanium dioxide (Anatase is called for short the A type) titanium dioxide nano material, and firm structure, durable, difficult drop-off are stablized in formation.
The metal net shaped skeleton structure filler of nanometer anatase titania body 4 uses the dodecahedron stereo structure metal sponge material of the MetalfoamProducts Inc. MP-Ti-nano5 of company, leave the cavity air penetrability in the middle of the filler body and be not less than 99.97%, weight is not more than 10% of volume weight.
Quartz burner 5 is generally by supporting acquisition high frequency electric sources that provides such as inverter DC6V-12V or AC100 ~ 120V, AC220 ~ 240V, AC380 ~ 440V, by shining the different of intensity according to fluorescent tube length, power of lamp tube and ultraviolet wire spoke, its tube voltage can be by 100V to 1500V, or higher, frequency is generally more than the 20Khz.After having the metal net shaped skeleton structure filler of air process nano titanium oxide of VOC pollutant, VOC will be decomposed effectively apace by the nano titanium dioxide photocatalysis effect that ultraviolet ray is shone, being eliminated purifying air of VOC will discharge from the air outlet slit end, reach the potent filter effect of VOC in the air.And nanometer anatase titania is when removing various harmful substance, and its effect can't weaken or disappear; As long as lasting ultraviolet ray irradiation is arranged, nanometer anatase titania can constantly produce the valency chain structure of nominal price photon hole and then oxidation of organic compounds and the harmful inorganic matter of cut-out.
Certainly, those of ordinary skill in the art will be appreciated that, above embodiment is used for illustrating the present invention, and be not to be used as limitation of the invention, as long as in connotation scope of the present invention, all will drop in the scope of claims of the present invention variation, the modification of the above embodiment.

Claims (10)

1, a kind of processor of eliminating indoor organic volatile matter,
It is characterized in that,
This processor is embedded in picture frame or the similar frame structure mutually and comprises:
The metal net shaped skeleton structure filler of several nanometer anatase titanias body, filler body be arranged side by side and the filler body between leave at interval;
At least one quartz burner, quartz burner place in the interval between the filler body or place the side of filler body.
2, the processor of elimination indoor organic volatile matter as claimed in claim 1,
It is characterized in that:
The metal net shaped skeleton structure filler of described nanometer anatase titania body is strip shape body and is provided with one at least.
3, the processor of elimination indoor organic volatile matter as claimed in claim 1,
It is characterized in that:
The metal net shaped skeleton structure filler of described nanometer anatase titania body is that a perpendicular or parallel cross sectional shape is irregular or regular polygonal column.
4, the processor of elimination indoor organic volatile matter as claimed in claim 1,
It is characterized in that:
Described quartz burner is any of middle pressure ultraviolet lamp, high-pressure sodium lamp, black light lamp, ultraviolet germicidal lamp.
5, the processor of elimination indoor organic volatile matter as claimed in claim 4,
It is characterized in that:
The wavelength of described quartz burner is between the 250nm-380nm.
6, a kind of processor of eliminating indoor organic volatile matter,
It is characterized in that,
This processor is embedded in picture frame or the similar frame structure mutually and comprises:
The metal net shaped skeleton structure filler of several nanometer anatase titanias body, filler body be arranged side by side and the filler body between leave at interval;
At least one quartz burner, quartz burner place in the interval between the filler body or place the side of filler body;
At least one air guide fan, air guide fan are positioned at the side of picture frame or similar frame structure and are arranged side by side with the filler body.
7, the processor of elimination indoor organic volatile matter as claimed in claim 6,
It is characterized in that:
Described air guide fan places a side or the two side ends of picture frame or similar frame structure.
8, as the processor of claim 6 or 7 described elimination indoor organic volatile matters,
It is characterized in that:
The metal net shaped skeleton structure filler of described nanometer anatase titania body is strip shape body and is provided with one at least.
9, as the processor of claim 6 or 7 described elimination indoor organic volatile matters,
It is characterized in that:
Described quartz burner is any of middle pressure ultraviolet lamp, high-pressure sodium lamp, black light lamp, ultraviolet germicidal lamp.
10, as the processor of described elimination indoor organic volatile matter as described in the claim 9,
It is characterized in that:
The wavelength of described quartz burner is between the 250nm-380nm.
CNA2005100263559A 2005-06-01 2005-06-01 Processor for eliminating indoor organic volatile Pending CN1879944A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CNA2005100263559A CN1879944A (en) 2005-06-01 2005-06-01 Processor for eliminating indoor organic volatile
PCT/CN2006/001184 WO2006128383A1 (en) 2005-06-01 2006-06-01 A processor of eliminating inside organic volatile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2005100263559A CN1879944A (en) 2005-06-01 2005-06-01 Processor for eliminating indoor organic volatile

Publications (1)

Publication Number Publication Date
CN1879944A true CN1879944A (en) 2006-12-20

Family

ID=37481238

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2005100263559A Pending CN1879944A (en) 2005-06-01 2005-06-01 Processor for eliminating indoor organic volatile

Country Status (2)

Country Link
CN (1) CN1879944A (en)
WO (1) WO2006128383A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105056755A (en) * 2015-08-11 2015-11-18 江苏金工科技集团有限公司 Gaseous pollutant decomposer and decomposition method thereof
CN110193337A (en) * 2019-06-19 2019-09-03 上海第二工业大学 A kind of photochemical catalyst fiber felt fixed-bed type Photoreactor and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2921223A1 (en) * 2021-12-30 2022-08-22 Univ Madrid Politecnica Device and air purification method by photocatalytic oxidation (Machine-translation by Google Translate, not legally binding)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19740053A1 (en) * 1997-09-12 1999-03-18 Hofmann Kurt W Dipl Ing Fh Reactor for removing unpleasant smells and germs from (in)organic gases
DE29804680U1 (en) * 1998-03-16 1998-07-09 Hofmann Kurt W Dipl Ing Fh Air purification system using UV catalyst technology
CN1247164A (en) * 1999-09-06 2000-03-15 中国人民解放军沈阳军区联勤部卫生防疫队 Photochemical disinfector for drinking water and its making technology
CN1175921C (en) * 2002-11-18 2004-11-17 武汉理工大学 High adsorptivity light catalyzed air processor
CN2639769Y (en) * 2003-08-25 2004-09-08 文怡农 Air sterilizing, dust removing and purifying equipment
CN1587873A (en) * 2004-07-12 2005-03-02 金大盛 Sterilizing and deodorizing device and method for refrigerator

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105056755A (en) * 2015-08-11 2015-11-18 江苏金工科技集团有限公司 Gaseous pollutant decomposer and decomposition method thereof
CN110193337A (en) * 2019-06-19 2019-09-03 上海第二工业大学 A kind of photochemical catalyst fiber felt fixed-bed type Photoreactor and preparation method thereof

Also Published As

Publication number Publication date
WO2006128383A1 (en) 2006-12-07

Similar Documents

Publication Publication Date Title
CN1853759A (en) Air filter for eliminating volatile organic compound
CN111780276B (en) Efficient photoelectric-cycle alternate-sterilization air disinfection equipment
CN1834542A (en) Indoor air purifier using photocatalytic oxidation process
CN111692673A (en) Air disinfection and purification equipment
KR102334223B1 (en) air sterilizer equipped with air purifying function
CN1853760A (en) Light catalyst filter in computer
CN210448685U (en) Photocatalyst sterilizing device
KR101043967B1 (en) Air purifier for front door
CN1879944A (en) Processor for eliminating indoor organic volatile
CN109506308B (en) Air purifier
CN2841634Y (en) A kind of ozone and hydroxyl radical free radical generating apparatus
CN2837719Y (en) Indoor air purifier with photocatalytic oxidant
CN201032232Y (en) Indoor air pollution fast treating device
CN1876417A (en) Photo-catalytic processor for eliminating organic volatile in automobile
CN101204591A (en) Indoor air pollution fast control equipment
CN203389533U (en) Air purifier
TWI532958B (en) Photo-catalytic air filter and method for making the same
CN104258450A (en) Ceiling-type medical high-efficiency air disinfecting machine
CN215765623U (en) Photocatalysis purification disinfection and sterilization device
CN213514312U (en) Air purifying device
KR200396959Y1 (en) Device for Eliminating Noxious Gas
CN1533830A (en) Device for photo catalytic cleaning air and its method
CN2695784Y (en) Lampshade coated with photocatalysis film for purifying air
CN207407458U (en) A kind of light quantum air purifier
TWM604385U (en) Air purification device

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication