CN1872931A - Ultraviolet solidified adhesive in use for sticking metal pin in liquid crystal display - Google Patents
Ultraviolet solidified adhesive in use for sticking metal pin in liquid crystal display Download PDFInfo
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- CN1872931A CN1872931A CN 200510073106 CN200510073106A CN1872931A CN 1872931 A CN1872931 A CN 1872931A CN 200510073106 CN200510073106 CN 200510073106 CN 200510073106 A CN200510073106 A CN 200510073106A CN 1872931 A CN1872931 A CN 1872931A
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- solidified adhesive
- ultraviolet solidified
- prepolymer
- light trigger
- ultraviolet
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Abstract
This invention relates to a UV-curing adhesive for binding the metal pins of liquid crystal displays. The adhesive comprises: prepolymer 30-80 wt. %, active monomer 10-60 wt. %, photo-initiator 1-10 wt. %, and accessory materials 0-10 wt. %. The adhesive has such advantages as high adhesiveness to metals and glass, good solvent resistance, good water-boiling resistance, high curing rate, low energy consumption and high productivity.
Description
Technical field
Patent of the present invention relates to a kind of ultraviolet solidified adhesive, and particularly a kind of ultraviolet solidified adhesive that is used for sticking metal pin in liquid crystal display is LCD pin glue or LCD folder PIN glue again.
Background technology
At present, domestic liquid crystal display device is the general ultraviolet solidified adhesive that adopts import when the bonded metal pin, and the ultraviolet solidified adhesive of domestic production seldom.The essentially consist of ultraviolet solidified adhesive is: (1) prepolymer; (2) reactive monomer; (3) light trigger; (4) auxiliary agent.The ultimate principle of ultraviolet solidified adhesive is: after tens of seconds, light trigger decomposes the generation radical makes its polymerizing curable to main gel, and makes it change reticulated structure into by linear structure in UV-irradiation.The ultraviolet solidified adhesive that is used for sticking metal pin in liquid crystal display, need stand following endurance test:
(1) boiling test: can not come off with manual glue after 100 ℃ * 8 hours;
(2) hot and humid endurance test: 80 ℃ * 90%RH * 400 hours;
(3) organic solvent-resistant test: in acetone, soaked 4 minutes respectively and alcohol in soak after 30 minutes not dry linting foam of glue;
But existing homemade ultraviolet solidified adhesive can't satisfy above-mentioned every requirement simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of novel ultraviolet solidified adhesive that is used for sticking metal pin in liquid crystal display, it can remedy the above-mentioned deficiency of existing homemade ultraviolet solidified adhesive.
Ultraviolet solidified adhesive of the present invention comprises: (1) prepolymer; (2) reactive monomer; (3) light trigger; (4) auxiliary agent, its each component concentration is (weight percent): prepolymer 30-80%; Reactive monomer 10-60%; Light trigger 1-10% auxiliary agent 0-10%.
Prepolymer described in the ultraviolet solidified adhesive of the present invention is aliphatic urethane acrylate and modified epoxy acrylic ester, as the M1800 of CN981, CN1963, CN966J75 and CN104, CN151 and the Taiwan Shi Mei company of SARTOMER company and M6200 etc.
Reactive monomer described in the ultraviolet solidified adhesive of the present invention is the simple function group acrylate, as isobornyl methacrylate, Rocryl 410 and hydroxyethyl methylacrylate etc.
Light trigger described in the ultraviolet solidified adhesive of the present invention is D-1173, I-184 and the TPO of vapour Bagong department.
Auxiliary agent described in the ultraviolet solidified adhesive of the present invention is a silane coupling agent, as domestic trade mark KH550, KH560 and KH570 etc.
The preparation method of ultraviolet solidified adhesive of the present invention is: the light trigger of 1-10% is dissolved in the acrylate monomer of 10-60%, be heated to 30-60 ℃, after treating that solid all dissolves, the prepolymer that adds 30-80%, continuation stirs under 30-60 ℃ of temperature, and the silane coupled agent aid that adds 0-10% at last mixes.
Specific implementation method
Embodiment 1:
Prescription is formed total weight parts
35 parts of urethane acrylates (CN1963 of SARTOMER company)
39 parts of epoxy acrylates (CN151 of SARTOMER company)
20 parts of hydroxyethyl methylacrylates (Beijing Orient chemical industry)
4 parts of light triggers (I-184 of CIBA company)
2 parts of silane coupling agents (KH560)
100 parts of total weight parts
Embodiment 2:
Prescription is formed total weight parts
40 parts of urethane acrylates (the Taiwan Shi Mei M1800 of company)
39 parts of epoxy acrylates (CN151 of SARTOMER company)
16 parts of hydroxyethyl methylacrylates (Beijing Orient chemical industry)
4 parts of light triggers (I-184 of CIBA company)
1 part of silane coupling agent (KH560)
100 parts of total weight parts
Blending process is as follows:
(1) urethane acrylate and epoxy acrylate were put into 30-60 ℃ of baking oven 3-4 hour, it is stand-by to reduce viscosity.
(2) add hydroxyethyl methylacrylate and light trigger, be heated to 30-60 ℃, be stirred to solid and dissolve fully.
(3) add preprepared urethane acrylate and epoxy acrylate then, under 30-60 ℃ of temperature, continue to stir 1-2 hour.
(4) add silane coupling agent at last, stirred 30-60 minute.
The ultraviolet solidified adhesive physical and mechanical properties for preparing sees the following form:
Glue performance before solidifying | Embodiment 1 | Embodiment 2 |
Outward appearance | Water white transparency | Water white transparency |
Viscosity (cps@25 ℃) | 13000 | 15000 |
Set time (S) | 5 | 5 |
Solidify back performance (2000-EC of DYMAX company UV-lamp is according to 60 seconds) | ||
Poach (hour) | ≥16 | ≥8 |
Hot and humid endurance test (80 ℃ * 90%RH * 400 hours) | By | By |
The organic solvent-resistant test | Well | Well |
Compression shear strength (MPa) | ≥10 | ≥10 |
Volume specific resistance (25 ℃, ohm-cm) | 8×10 15 | 8×10 15 |
Claims (6)
1. ultraviolet solidified adhesive, particularly a kind of ultraviolet solidified adhesive that is used for sticking metal pin in liquid crystal display, this ultraviolet solidified adhesive comprises: (1) prepolymer; (2) reactive monomer; (3) light trigger; (4) auxiliary agent, its each component concentration is (weight percent): prepolymer 30-80%; Reactive monomer 10-60%; Light trigger 1-10%; Auxiliary agent 0-10%.
2. ultraviolet solidified adhesive according to claim 1, it is characterized in that: prepolymer is aliphatic urethane acrylate and modified epoxy acrylic ester, as the M1800 of CN981, CN1963, CN966J75 and CN104, CN151 and the Taiwan Shi Mei company of U.S. SARTOMER company and M6200 etc.
3. ultraviolet solidified adhesive according to claim 1 is characterized in that: reactive monomer is the simple function group acrylate, as isobornyl methacrylate, Rocryl 410 and hydroxyethyl methylacrylate etc.
4. ultraviolet solidified adhesive according to claim 1 is characterized in that: light trigger is D-1173, I-184 and the TPO of vapour Bagong department.
5. ultraviolet solidified adhesive according to claim 1 is characterized in that: auxiliary agent is a silane coupling agent, as domestic trade mark KH550, KH560 and KH570 etc.
6. according to the described ultraviolet solidified adhesive of claim 1-5, its preparation method is: the light trigger of 1-10% is dissolved in the acrylate monomer of 10-60%, be heated to 30-60 ℃, after treating that solid all dissolves, the prepolymer that adds 30-80%, continuation stirs under 30-60 ℃ of temperature, and the silane coupled agent aid that adds 0-10% at last mixes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200510073106 CN1872931A (en) | 2005-05-31 | 2005-05-31 | Ultraviolet solidified adhesive in use for sticking metal pin in liquid crystal display |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200510073106 CN1872931A (en) | 2005-05-31 | 2005-05-31 | Ultraviolet solidified adhesive in use for sticking metal pin in liquid crystal display |
Publications (1)
Publication Number | Publication Date |
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CN1872931A true CN1872931A (en) | 2006-12-06 |
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CN 200510073106 Pending CN1872931A (en) | 2005-05-31 | 2005-05-31 | Ultraviolet solidified adhesive in use for sticking metal pin in liquid crystal display |
Country Status (1)
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CN (1) | CN1872931A (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101705072A (en) * | 2009-11-30 | 2010-05-12 | 北京海斯迪克新材料有限公司 | Ultraviolet curing glue for adhering and sealing FPC and plasma screen glass |
CN101851485A (en) * | 2010-05-18 | 2010-10-06 | 上海鼎道科技发展有限公司 | Light-curing adhesive used for adhering facade glass and preparation method thereof |
CN101984371A (en) * | 2010-08-24 | 2011-03-09 | 深圳市中显微电子有限公司 | Method for reducing electrocorrosion of liquid crystal display module |
CN101838505B (en) * | 2009-10-26 | 2012-07-18 | 东莞市派乐玛新材料技术开发有限公司 | Colored light-curing adhesive for adhering and sealing filled-words of metal keys and preparation method thereof |
CN103031106A (en) * | 2013-01-09 | 2013-04-10 | 王胜华 | Photocureable adhesion agent for bonding capacitive touch screen and preparation method of photocureable adhesion agent |
CN103087670A (en) * | 2013-01-09 | 2013-05-08 | 东莞优邦材料科技有限公司 | Ultraviolet and primary coat dual-curing touch screen adhesive |
CN103173137A (en) * | 2011-12-22 | 2013-06-26 | 汉高股份有限公司 | Ultraviolet-curable and moisture-curable adhesive composition |
CN103509508A (en) * | 2012-06-19 | 2014-01-15 | 比亚迪股份有限公司 | Liquid crystal thinning sealing adhesive and preparation method thereof |
CN104073214A (en) * | 2014-06-26 | 2014-10-01 | 深圳市奥普利斯光电有限公司 | UV glue for pasting dimming film and application method thereof |
CN105315954A (en) * | 2015-11-24 | 2016-02-10 | 苏州盖德精细材料有限公司 | Novel UV photo-curing adhesive and preparation method thereof |
CN103173137B (en) * | 2011-12-22 | 2016-12-14 | 汉高股份有限及两合公司 | Ultraviolet-curable and moisture-curable adhesive composition |
CN106433545A (en) * | 2016-09-08 | 2017-02-22 | 中国科学院深圳先进技术研究院 | Ultraviolet light-cured adhesive and preparation method and application thereof |
CN107163902A (en) * | 2017-06-21 | 2017-09-15 | 广州日高新材料科技有限公司 | Ultraviolet photo-curing cementing agent and its preparation method and application |
CN107459961A (en) * | 2017-06-29 | 2017-12-12 | 李德坤 | A kind of environment-friendly type UV glue and preparation method thereof |
CN112280440A (en) * | 2019-07-25 | 2021-01-29 | 上海飞凯光电材料股份有限公司 | UV adhesive coating, preparation method thereof and preparation method of coated workpiece |
-
2005
- 2005-05-31 CN CN 200510073106 patent/CN1872931A/en active Pending
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101838505B (en) * | 2009-10-26 | 2012-07-18 | 东莞市派乐玛新材料技术开发有限公司 | Colored light-curing adhesive for adhering and sealing filled-words of metal keys and preparation method thereof |
CN101705072A (en) * | 2009-11-30 | 2010-05-12 | 北京海斯迪克新材料有限公司 | Ultraviolet curing glue for adhering and sealing FPC and plasma screen glass |
CN101851485B (en) * | 2010-05-18 | 2014-04-16 | 上海鼎道科技发展有限公司 | Light-curing adhesive used for adhering facade glass and preparation method thereof |
CN101851485A (en) * | 2010-05-18 | 2010-10-06 | 上海鼎道科技发展有限公司 | Light-curing adhesive used for adhering facade glass and preparation method thereof |
CN101984371A (en) * | 2010-08-24 | 2011-03-09 | 深圳市中显微电子有限公司 | Method for reducing electrocorrosion of liquid crystal display module |
CN103173137B (en) * | 2011-12-22 | 2016-12-14 | 汉高股份有限及两合公司 | Ultraviolet-curable and moisture-curable adhesive composition |
CN103173137A (en) * | 2011-12-22 | 2013-06-26 | 汉高股份有限公司 | Ultraviolet-curable and moisture-curable adhesive composition |
CN103509508A (en) * | 2012-06-19 | 2014-01-15 | 比亚迪股份有限公司 | Liquid crystal thinning sealing adhesive and preparation method thereof |
CN103509508B (en) * | 2012-06-19 | 2015-11-25 | 深圳市比亚迪电子部品件有限公司 | Thinning sealing glue of a kind of liquid crystal and preparation method thereof |
CN103087670A (en) * | 2013-01-09 | 2013-05-08 | 东莞优邦材料科技有限公司 | Ultraviolet and primary coat dual-curing touch screen adhesive |
CN103031106A (en) * | 2013-01-09 | 2013-04-10 | 王胜华 | Photocureable adhesion agent for bonding capacitive touch screen and preparation method of photocureable adhesion agent |
CN104073214A (en) * | 2014-06-26 | 2014-10-01 | 深圳市奥普利斯光电有限公司 | UV glue for pasting dimming film and application method thereof |
CN105315954A (en) * | 2015-11-24 | 2016-02-10 | 苏州盖德精细材料有限公司 | Novel UV photo-curing adhesive and preparation method thereof |
CN106433545A (en) * | 2016-09-08 | 2017-02-22 | 中国科学院深圳先进技术研究院 | Ultraviolet light-cured adhesive and preparation method and application thereof |
CN106433545B (en) * | 2016-09-08 | 2019-08-13 | 中国科学院深圳先进技术研究院 | A kind of ultraviolet cured adhesive, preparation method and application |
CN107163902A (en) * | 2017-06-21 | 2017-09-15 | 广州日高新材料科技有限公司 | Ultraviolet photo-curing cementing agent and its preparation method and application |
CN107459961A (en) * | 2017-06-29 | 2017-12-12 | 李德坤 | A kind of environment-friendly type UV glue and preparation method thereof |
CN112280440A (en) * | 2019-07-25 | 2021-01-29 | 上海飞凯光电材料股份有限公司 | UV adhesive coating, preparation method thereof and preparation method of coated workpiece |
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