CN1871363A - 来自硫酸盐法的TiO2残渣的用途 - Google Patents
来自硫酸盐法的TiO2残渣的用途 Download PDFInfo
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- CN1871363A CN1871363A CNA200480022726XA CN200480022726A CN1871363A CN 1871363 A CN1871363 A CN 1871363A CN A200480022726X A CNA200480022726X A CN A200480022726XA CN 200480022726 A CN200480022726 A CN 200480022726A CN 1871363 A CN1871363 A CN 1871363A
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/04—Blast furnaces with special refractories
- C21B7/06—Linings for furnaces
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/02—Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/04—Making slag of special composition
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/04—Blast furnaces with special refractories
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
- C22B34/124—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors
- C22B34/125—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors containing a sulfur ion as active agent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Environmental & Geological Engineering (AREA)
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Abstract
本发明涉及来自硫酸盐法的TiO2残渣用于治金工艺中或者用作耐火材料的成分的用途。其中,无需将该TiO2残渣进一步与其他物质混合就进行干燥和添加。
Description
本发明涉及来自硫酸盐法的TiO2残渣的用途。
TiO2产品的残渣(TiO2残渣)在冶金工业中的应用是已知的。DE 4419816 C1公开了一种含钛添加剂,由TiO2残渣和其他物质组成。DE 19705996 C2公开了一种含TiO2的添加剂的制备方法,是将TiO2残渣和铁或铁化合物的混合物在200-1300℃下进行热处理。但是缺点是TiO2残渣与添加剂的其他每一组分的计量和混合烦琐。
DE 19830102 C1公开了利用盐酸盐法制备TiO2时产生的含TiO2的细颗粒残渣的用途。但其缺点是按照硫酸盐法制备TiO2时,没有产生这种细颗粒状的含TiO2残渣,因此其不能用于来自硫酸盐法的TiO2残渣。
本发明的目的是克服现有技术的不足,尤其是提供一种按照硫酸盐法生产TiO2产品时TiO2残渣的简单应用。
本发明的目的是通过将硫酸盐法TiO2残渣应用于冶金工艺中或者用作为耐火材料的成分而实现的,其中TiO2残渣无需进一步与其他物质混合就进行热处理和添加。
令人惊奇地发现,由硫酸盐法获得的TiO2残渣用于治金工艺中或作为耐火材料的成分与迄今为止由TiO2残渣和其他物质的混合物具有同样的所需功效。该TiO2残渣在进行热处理时可以不进行洗涤或者进行洗涤和中和。
对TiO2残渣的热处理优选在100-1300℃下进行。TiO2残渣可以以粉末状或者有形体的形式存在(例如通过烧结、成球、压块或压制而获得)。
经热处理(干燥)的TiO2残渣优选含有下列物质作为主成分(数据按重量%给出):
TiO2 35-70
SiO2 5-40
铁化合物 2-15
MgO 1-15
CaO 0.5-15
或者,经热处理(干燥)的TiO2残渣换算成氧化物具有下列主成分(数据按重量%给出):
TiO2 20-80
SiO2 2-30
Al2O3 0-15
Fe2O3 0-15
MgO 1-15
CaO 0-15
在优选的应用中,将经热处理的TiO2残渣吹入冶炼炉例如高炉或电熔融炉或冲天炉中,从而提高了耐火炉衬的耐久性。其他的应用是将TiO2残渣用作堵口泥和耐火材料。
下面借助实施例详细说明本发明的主题。
实施例1:为用于冶炼炉中而进行的硫酸盐法TiO2残渣的处理
将100吨压滤卸料(洗选残渣)在进口温度为650℃的回转管式炉中进行处理,该压滤卸料在洗选硫酸盐法TiO2产品时产生,并具有75重量%的固含量和53重量%的TiO2(按固含量计)。获得的细颗粒产品的残余湿度为0.5重量%。该产品具有非常好的流动性(Rieselfhigkeit)并且可借助于气动输送很容易地吹入冶炼炉(这里是高炉)中。
该产品具有下列组成(按重量%计):
TiO2 53
Fe2O3 5.9
SiO2 27.8
Al2O3 6.1
MgO 2.4
CaO 4.2。
Claims (7)
1、由硫酸盐法产生的TiO2残渣在冶金工艺中或者作为耐火材料成分的用途,其特征在于,该TiO2残渣无需进一步与其他物质混合就进行热处理和使用。
2、根据权利要求1的用途,其特征在于,TiO2残渣在100-1300℃下进行热处理。
3、根据权利要求1或2的用途,其特征在于,TiO2残渣是以粉末状或有形体的形式存在。
4、根据权利要求1-3中任一项的用途,其特征在于,TiO2残渣含有下列物质作为主成分(数据按重量%给出):
TiO2 35-70
SiO2 5-40
铁化合物 2-15
MgO 1-15
CaO 0.5-15。
5、根据权利要求1-3中任一项的用途,其特征在于,TiO2残渣换算成氧化物具有下列主成分(数据按重量%给出):
TiO2 20-80
SiO2 2-30
Al2O3 0-15
Fe2O3 0-15
MgO 1-15
CaO 0-15。
6、根据权利要求1-5中任一项的用途,其特征在于,将经干燥的TiO2残渣吹入冶炼炉中。
7、根据权利要求1-5中任一项的用途,其特征在于,将经干燥的TiO2残渣用于堵口泥(Stichlochmasse)。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10336650.4 | 2003-08-09 | ||
DE2003136650 DE10336650A1 (de) | 2003-08-09 | 2003-08-09 | Verwendung von TiO2-Rückständen aus dem Sulfatverfahren |
PCT/EP2004/008837 WO2005014867A2 (de) | 2003-08-09 | 2004-08-06 | Verwendung von tio2-rückständen aus dem sulfatverfahren |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1871363A true CN1871363A (zh) | 2006-11-29 |
CN1871363B CN1871363B (zh) | 2015-01-28 |
Family
ID=34089145
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200480022726.XA Expired - Fee Related CN1871363B (zh) | 2003-08-09 | 2004-08-06 | 来自硫酸盐法的TiO2残渣的用途 |
Country Status (7)
Country | Link |
---|---|
US (2) | US20060236894A1 (zh) |
EP (1) | EP1656461B1 (zh) |
CN (1) | CN1871363B (zh) |
BR (1) | BRPI0413434B1 (zh) |
DE (1) | DE10336650A1 (zh) |
PL (1) | PL1656461T3 (zh) |
WO (1) | WO2005014867A2 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101798234A (zh) * | 2010-02-12 | 2010-08-11 | 闫晓峰 | 一种碳氮化钛高炉护炉剂及其制备方法 |
CN102753301A (zh) * | 2009-12-28 | 2012-10-24 | 克利诺克斯股份有限公司 | 回收含钛副产物的方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2014201184B2 (en) * | 2006-08-02 | 2015-12-17 | Sachtleben Chemie Gmbh | Titanium-containing additive |
EP2444150A1 (de) * | 2010-10-22 | 2012-04-25 | crenox GmbH | Trägerkatalysator aus Aufschlussrückständen der titanylsulfathaltigen Schwarzlösung |
CN101988158B (zh) * | 2010-12-07 | 2012-11-07 | 东北大学 | 一种含钛废渣的综合利用方法 |
CN102139424A (zh) * | 2011-03-21 | 2011-08-03 | 北京工业大学 | 一种焊渣可循环利用的气保护药芯焊丝 |
US8809221B2 (en) | 2011-05-09 | 2014-08-19 | Reliance Industries Limited | Nitrogen containing external donor system for propylene polymerization |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19725021A1 (de) * | 1997-06-13 | 1998-12-24 | Bayer Ag | Sulfatarmer, neutraler, inerter, feinteiliger Füllstoff, Verfahren zu dessen Herstellung sowie dessen Verwendung |
CN1417165A (zh) * | 2002-12-15 | 2003-05-14 | 赵文厚 | 一种铝铬钛耐火材料 |
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US2456453A (en) * | 1944-03-20 | 1948-12-14 | Briggs Mfg Co | Insulation break detector |
US2476453A (en) * | 1947-08-19 | 1949-07-19 | Quebec Iron & Titanium Corp | Titaniferous material for producing titanium dioxide |
US3428427A (en) * | 1965-06-24 | 1969-02-18 | Quebec Iron & Titanium Corp | Process for producing a product high in titanium dioxide content |
US3942293A (en) * | 1971-09-20 | 1976-03-09 | Ppg Industries, Inc. | Metal oxide coated refractory brick |
JPS5732310A (en) * | 1980-08-05 | 1982-02-22 | Sumitomo Metal Ind Ltd | Method for repairing wall of blast furnace |
DE4027105A1 (de) * | 1990-08-28 | 1992-03-05 | Bayer Ag | Verfahren zur aufarbeitung von aufschlussrueckstaenden aus der titandioxidproduktion |
DE4304724C1 (de) * | 1993-02-17 | 1994-05-05 | Metallgesellschaft Ag | Titanhaltiger Zuschlagsstoff und dessen Verwendung zur Erhöhung der Haltbarkeit der feuerfesten Ausmauerung eines Ofens |
DE4419816C1 (de) * | 1994-06-07 | 1995-06-29 | Metallgesellschaft Ag | Titanhaltiger Zuschlagstoff und dessen Verwendung zur Erhöhung der Haltbarkeit der feuerfesten Ausmauerung eines Ofens und als Schlackenbildner |
DE4443083C2 (de) * | 1994-12-03 | 1998-03-26 | Metallgesellschaft Ag | Stichlochmasse und Verfahren zu deren Herstellung |
DE19538162C2 (de) * | 1995-10-12 | 1997-09-11 | Metallgesellschaft Ag | Verfahren zur Senkung des Schmelzpunktes der Restasche von Kohle |
US5830420A (en) * | 1995-11-21 | 1998-11-03 | Qit-Fer Et Titane Inc. | Method to upgrade titania slag and resulting product |
DE19705996C2 (de) * | 1997-02-17 | 1999-02-25 | Metallgesellschaft Ag | Verfahren zur Herstellung von Titandioxid enthaltendem Zuschlagstoff |
DE19830102C1 (de) * | 1998-07-06 | 1999-07-29 | Metallgesellschaft Ag | Verwendung eines bei der Herstellung von Titandioxid anfallenden feinkörnigen Produkts |
DE19925144C2 (de) * | 1999-06-02 | 2001-04-19 | Metallgesellschaft Ag | Verfahren zur Herstellung von Schaumschlacke |
RU2179583C1 (ru) * | 2000-11-28 | 2002-02-20 | Открытое акционерное общество "Северсталь" | Способ создания защитного гарнисажа в доменной печи |
DE10146871A1 (de) * | 2001-09-24 | 2003-04-24 | Sachtleben Chemie Gmbh | Stichlochmasse mit feinem TiO¶2¶, Verfahren zu deren Herstellung und deren Verwendung |
-
2003
- 2003-08-09 DE DE2003136650 patent/DE10336650A1/de not_active Ceased
-
2004
- 2004-08-06 US US10/566,595 patent/US20060236894A1/en not_active Abandoned
- 2004-08-06 BR BRPI0413434-6B1A patent/BRPI0413434B1/pt not_active IP Right Cessation
- 2004-08-06 CN CN200480022726.XA patent/CN1871363B/zh not_active Expired - Fee Related
- 2004-08-06 PL PL04741380T patent/PL1656461T3/pl unknown
- 2004-08-06 WO PCT/EP2004/008837 patent/WO2005014867A2/de active Application Filing
- 2004-08-06 EP EP04741380.2A patent/EP1656461B1/de not_active Not-in-force
-
2008
- 2008-12-15 US US12/334,876 patent/US20090118115A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19725021A1 (de) * | 1997-06-13 | 1998-12-24 | Bayer Ag | Sulfatarmer, neutraler, inerter, feinteiliger Füllstoff, Verfahren zu dessen Herstellung sowie dessen Verwendung |
CN1417165A (zh) * | 2002-12-15 | 2003-05-14 | 赵文厚 | 一种铝铬钛耐火材料 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102753301A (zh) * | 2009-12-28 | 2012-10-24 | 克利诺克斯股份有限公司 | 回收含钛副产物的方法 |
CN101798234A (zh) * | 2010-02-12 | 2010-08-11 | 闫晓峰 | 一种碳氮化钛高炉护炉剂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2005014867A2 (de) | 2005-02-17 |
US20060236894A1 (en) | 2006-10-26 |
DE10336650A1 (de) | 2005-02-24 |
BRPI0413434B1 (pt) | 2015-01-06 |
PL1656461T3 (pl) | 2014-03-31 |
EP1656461A2 (de) | 2006-05-17 |
CN1871363B (zh) | 2015-01-28 |
EP1656461B1 (de) | 2013-10-09 |
WO2005014867A3 (de) | 2005-06-23 |
US20090118115A1 (en) | 2009-05-07 |
BRPI0413434A (pt) | 2006-10-10 |
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