CN1865324B - Low temperature resistant polyvinyl chloride salt film for anti-aging - Google Patents
Low temperature resistant polyvinyl chloride salt film for anti-aging Download PDFInfo
- Publication number
- CN1865324B CN1865324B CN2006100446874A CN200610044687A CN1865324B CN 1865324 B CN1865324 B CN 1865324B CN 2006100446874 A CN2006100446874 A CN 2006100446874A CN 200610044687 A CN200610044687 A CN 200610044687A CN 1865324 B CN1865324 B CN 1865324B
- Authority
- CN
- China
- Prior art keywords
- low temperature
- polyvinyl chloride
- salt film
- aging
- temperature resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a polyvinylchloride low temperature resistance and anti-aging salt film to prevent rainfall from diluting bittern, which comprises the following parts: (A) polyvinylchloride resins 100 parts; (B) 10-40PHR phthalandione dioctyl; (C) 10-40PHR terephthalic dioctyl; (D) 2-12 PHR adipinic dioctyl; (E) 2-5 PHR thermally-stabilized agent; (F) 1-4 PHR carbon black; (G) 0.1-40 PHR 2- hydroxyl-4- n-octyl oxide benzophenone (or 2- hydroxyl-4-methyl benzophenone); (H) 0.1-0.8 PHR 4, 4- isopropylidene bisphenol. The invention can be used in low temperature condition, which improvesthe salt film lifetime.
Description
One, technical field:
The present invention relates to a kind of polyvinyl chloride film of protecting salt pond bittern to use, particularly a kind of overcast and rainy covering prevents that on the salt pool surface rainwater from watering down the low temperature resistant polyvinyl chloride of bittern, salt film for anti-aging.
Two, background technology:
At present, the polyvinyl chloride salt film of known technology mainly is to be added auxiliary agents such as softening agent, stablizer, carbon black by polyvinyl chloride (PVC) RESINS, through the common polyvinyl chloride film that mixes, plastifies, makes after the processes such as calendering.Wherein, softening agent is based on dioctyl phthalate (DOP), and Octyl adipate (also available dioctyl sebacate replaces) is auxilliary as low temperature resistant softening agent, the plasticity of reinforced polyvinyl chloride resin.This be that the low temperature flexibility of film is very restricted under the Plasticising system of primary plasticizer with the dioctyl phthalate (DOP), film will hardening when envrionment temperature is lower than 5 ℃, the user just dare not folding and unfolding, in order to avoid film breaks.
Aspect the opposing ultraviolet ray ageing, the traditional salt film producer is existing mistaken ideas to the approach that ultraviolet ray destroys the salt film aspect the understanding: think that the salt film only in overcast and rainy use, can not be subjected to the direct projection of sunlight, so be subjected to the chance of ultraviolet ray infringement just few.Actually this is not so, though when cloudy day cloud layer stopped ultraviolet direct projection,, cloud layer but can strengthen ultraviolet diffuse-reflectance, so the salt film still can be subjected to ultraviolet destruction when cloudy.The ordinary salt film mainly with carbon black as ultraviolet screening agent, ultraviolet ray is intercepted, prevent its destruction to the polyvinyl chloride molecular chain, its effect is not fine, so have a greatly reduced quality the work-ing life of ordinary salt film.
Three, summary of the invention:
Purpose of the present invention is exactly the above-mentioned defective that exists at prior art, provide a kind of and aspect low temperature resistant, anti-aging, obtain abundant improved polyvinyl chloride salt film, thereby solve salt membrane product out of use situation under the lesser temps state, and effectively improve low temperature resistant polyvinyl chloride, the salt film for anti-aging in the work-ing life of salt film.
Its technical scheme is to comprise that following component is formulated: (A) 100 parts of weights of polyvinyl chloride (PVC) RESINS; (B) dioctyl phthalate (DOP) 10-40PHR; (C) dioctyl terephthalate 10-40PHR; (D) Octyl adipate 2-12PHR; (E) thermo-stabilizer 2-5PHR; (F) carbon black 1-4PHR; (G) Octabenzone or 2-hydroxy-4-methyl benzophenone 0.1-0.6PHR; (H) 4,4-isopropylidene bis-phenol 0.1-0.8PHR.
Above-mentioned thermo-stabilizer can be selected liquid stabilisers and the compound use of metallic soap class stablizer for use, at least a barium stearate or the lead stearate of being selected from of metallic soap class stablizer.
In plasticiser system, substitute the part dioctyl phthalate (DOP) with dioctyl terephthalate.In the photostabilizer system, add Octabenzone or 2-hydroxy-4-methyl benzophenone.
In the above-mentioned prescription: (1) substitutes dioctyl phthalate (DOP) with the part dioctyl terephthalate, because the special linear chain structure of dioctyl terephthalate molecule, its stable performance, low temperature resistant effect is better than dioctyl phthalate (DOP); The low temperature resistant softening agent Octyl adipate in prescription Central Plains continues to use.The thin film low temperature snappiness is by dioctyl terephthalate and the common realization of Octyl adipate; (2) adopt Octabenzone (or 2-hydroxy-4-methyl benzophenone) as UV light absorber in the photostabilizer system, under the prerequisite that carbon black effectively shields ultraviolet ray, strengthened the ultraviolet absorption of incident, effectively prevented the photooxidation resistance of film.
The invention has the beneficial effects as follows: low temperature resistant, anti-aging aspect obtains abundant improved polyvinyl chloride salt film, thereby solves salt membrane product out of use situation under the lesser temps state, and the work-ing life of effectively improving the salt film; The one, solved when winter temperature is lower than 5 ℃ can not folding and unfolding salt film problem; The 2nd, can make to prolong 2-3 in work-ing life of salt film.
Four, embodiment:
Embodiment 1: its prescription comprises that following component is formulated: (A) 100 parts of weights of polyvinyl chloride (PVC) RESINS; (B) dioctyl phthalate (DOP) 10PHR (resin by 100 parts of weights is the parts by weight of the other materials of benchmark, down together); (C) dioctyl terephthalate 10PHR; (D) Octyl adipate 2PHR; (E) thermo-stabilizer 2PHR; (F) carbon black 1PHR; (G) Octabenzone (or 2-hydroxy-4-methyl benzophenone) 0.1PHR; (H) 4,4-isopropylidene bis-phenol 0.1PHR.Wherein, thermo-stabilizer can be selected liquid stabilisers and the compound use of metallic soap class stablizer for use, at least a barium stearate or the lead stearate of being selected from of metallic soap class stablizer.
In addition, in plasticiser system, substitute the part dioctyl phthalate (DOP) with dioctyl terephthalate; In the photostabilizer system, add Octabenzone or 2-hydroxy-4-methyl benzophenone.
Embodiment 2: 100 parts of weights of (A) polyvinyl chloride (PVC) RESINS in the said components; (B) dioctyl phthalate (DOP) 40PHR; (C) dioctyl terephthalate 40PHR; (D) Octyl adipate 12PHR; (E) thermo-stabilizer 5PHR; (F) carbon black 4PHR; (G) Octabenzone (or 2-hydroxy-4-methyl benzophenone) 0.6PHR; (H) 4,4-isopropylidene bis-phenol 0.8PHR.
Embodiment 3: in the said components with reference to following table.
After 1 each component is weighed in the table one, stirred 5 minutes with homogenizer, under 165 ℃, plasticate then with Banbury mixer, carry out mixing in the open type plastic purificating set kind again, after forcing machine filters, roll into film by four-roll calender, the film after the moulding is shaped into desired product through drawing-off, expanding postcooling.The product low-temperature extension can reach 35%, and can reach more than 7 years work-ing life.
After weighing by each component of 2 in the table one, under 170 ℃ temperature, also can make the utility model product by the processing method of the foregoing description.
After weighing by each component of 3 in the table one, under 180 ℃ temperature, also can make this product by the processing method of the foregoing description.
Table one
Claims (4)
1. a low temperature resistant polyvinyl chloride, salt film for anti-aging is characterized in that comprising that following component is formulated:
(A) 100 parts of weights of polyvinyl chloride (PVC) RESINS;
(B) dioctyl phthalate (DOP) 10-40PHR;
(C) dioctyl terephthalate 10-40PHR;
(D) Octyl adipate 2-12PHR;
(E) thermo-stabilizer 2-5PHR;
(F) carbon black 1-4PHR;
(G) Octabenzone or 2-hydroxy-4-methyl benzophenone 0.1-0.6PHR;
(H) 4,4-isopropylidene bis-phenol 0.1-0.8PHR.
2. low temperature resistant polyvinyl chloride according to claim 1, salt film for anti-aging, it is characterized in that: described thermo-stabilizer can be selected liquid stabilisers and the compound use of metallic soap class stablizer for use, at least a barium stearate or the lead stearate of being selected from of metallic soap class stablizer.
3. low temperature resistant polyvinyl chloride according to claim 1, salt film for anti-aging is characterized in that: substitute the part dioctyl phthalate (DOP) with dioctyl terephthalate in plasticiser system.
4. low temperature resistant polyvinyl chloride according to claim 1, salt film for anti-aging is characterized in that: add Octabenzone or 2-hydroxy-4-methyl benzophenone in the photostabilizer system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100446874A CN1865324B (en) | 2006-06-09 | 2006-06-09 | Low temperature resistant polyvinyl chloride salt film for anti-aging |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100446874A CN1865324B (en) | 2006-06-09 | 2006-06-09 | Low temperature resistant polyvinyl chloride salt film for anti-aging |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1865324A CN1865324A (en) | 2006-11-22 |
| CN1865324B true CN1865324B (en) | 2010-12-08 |
Family
ID=37424480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100446874A Expired - Fee Related CN1865324B (en) | 2006-06-09 | 2006-06-09 | Low temperature resistant polyvinyl chloride salt film for anti-aging |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1865324B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101864129B (en) * | 2010-07-21 | 2012-01-25 | 天津市天塑科技集团有限公司第四塑料制品厂 | Polyvinyl chloride geomembrane modified by nitrile-butadiene rubber |
| CN102344630A (en) * | 2011-08-15 | 2012-02-08 | 天津市天塑科技集团有限公司第四塑料制品厂 | Polyvinyl chloride salt film modified by butadiene nitrile rubber |
| CN102344629A (en) * | 2011-08-15 | 2012-02-08 | 天津市天塑科技集团有限公司第四塑料制品厂 | Polyvinyl chloride brine extraction-resistant membrane for anti-osmosis salt industry |
| CN103360695A (en) * | 2012-03-30 | 2013-10-23 | 中国石油化工股份有限公司 | Durable polyvinyl chloride salt membrane composition and preparation method thereof |
| CN103205019A (en) * | 2013-04-28 | 2013-07-17 | 江苏省金肯科技实业股份有限公司 | Thin film additive for salt, thin film for salt, and preparation method thereof |
| CN103497446A (en) * | 2013-09-25 | 2014-01-08 | 天津市天塑科技集团有限公司第四塑料制品厂 | Environmental-friendly polyvinyl chloride (PVC) extraction-resistant anti-seepage film and preparation method thereof |
| CN103756197B (en) * | 2014-01-26 | 2016-01-13 | 东莞市悠悠美居家居制造有限公司 | High definition transparent pvc film and preparation method thereof |
| JP6343725B2 (en) * | 2016-02-29 | 2018-06-13 | リンテック株式会社 | Base film for semiconductor processing sheet and semiconductor processing sheet |
| CN108164735A (en) * | 2018-01-20 | 2018-06-15 | 宁波华众和创工业设计有限公司 | A kind of anti-aging automobile film of scratch resistance and its manufacturing method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1087101A (en) * | 1993-11-30 | 1994-05-25 | 谭广成 | The manufacturing process of a kind of thermoplastic elastomer of polyvinyl-chloride and goods thereof |
| US6355711B1 (en) * | 1998-04-23 | 2002-03-12 | Exxonmobil Chemical Patents Inc. | High performance plasticizers from branched oxo alcohols |
| DE10356670A1 (en) * | 2003-12-04 | 2005-06-30 | Artemis Research Gmbh & Co. Kg | Polymer stabilizer comprises an amine, a glycidyl derivative, acrylate ester, a carbonyl compound, beta-keto ester, cyclic anhydride, lactone or carbonate ester and a perchlorate, perfluoroalkane sulfonate or sulfate ester salt |
-
2006
- 2006-06-09 CN CN2006100446874A patent/CN1865324B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1087101A (en) * | 1993-11-30 | 1994-05-25 | 谭广成 | The manufacturing process of a kind of thermoplastic elastomer of polyvinyl-chloride and goods thereof |
| US6355711B1 (en) * | 1998-04-23 | 2002-03-12 | Exxonmobil Chemical Patents Inc. | High performance plasticizers from branched oxo alcohols |
| DE10356670A1 (en) * | 2003-12-04 | 2005-06-30 | Artemis Research Gmbh & Co. Kg | Polymer stabilizer comprises an amine, a glycidyl derivative, acrylate ester, a carbonyl compound, beta-keto ester, cyclic anhydride, lactone or carbonate ester and a perchlorate, perfluoroalkane sulfonate or sulfate ester salt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1865324A (en) | 2006-11-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1865324B (en) | Low temperature resistant polyvinyl chloride salt film for anti-aging | |
| CN104327433B (en) | Preparation method of polyvinylidene fluoride-based thin film | |
| CN1227286C (en) | Soft PVCcalendered film and and its manufacture | |
| CN100529010C (en) | Coloured PVC waterproof roll and its preparation method | |
| CN104669747B (en) | A kind of waterproof roll and its preparation method | |
| CN102964719B (en) | Ultraviolet light resistant transparent polyvinyl chloride elastic calendered film and preparation method thereof | |
| CN107286501A (en) | A kind of high intensity high rush-resistant polyvinyl chloride waterproof roll and preparation method thereof | |
| CN102391596B (en) | Modified fluoride-containing resin slices for preparing solar photovoltaic back films and preparation method thereof | |
| CN103360695A (en) | Durable polyvinyl chloride salt membrane composition and preparation method thereof | |
| CN105934831A (en) | Humidity-resistant and heat-resistant solar cell backsheet and manufacturing method therefor | |
| CN106910788B (en) | A kind of high resistant water type solar energy backboard polyester film and preparation method thereof | |
| CN111423674A (en) | PVC film and processing technology thereof | |
| CN105647064A (en) | Weatherable PVC (polyvinyl chloride) plastic wallpaper and preparation method thereof | |
| CN105237914A (en) | PVC waterproof roll | |
| CN104672703B (en) | A kind of organic RE polymeric U crosslinking exposed conveying appliance waterproof roll and preparation method | |
| CN105377967A (en) | Method for manufacturing heat-shielding film, heat-shielding film, and heat-shielding curtain | |
| CN102827435A (en) | Polrvinyl chloride preservative film and preparation method thereof | |
| CN106117694B (en) | A kind of attapulgite activeness and quietness resists long-term ultraviolet ageing floating material masterbatch | |
| CN108682710A (en) | A kind of five-layer structure co-extrusion solar cell backboard and preparation method thereof containing PBT | |
| KR20180075941A (en) | PVC Compound Composition of Improved Weatherability and Method for Manufacturing The Same | |
| EP3475359A1 (en) | Hydrolysis stable compositions for films in solar cells | |
| CN107446269A (en) | transparent heat-insulating polyvinyl chloride adhesive tape and preparation method thereof | |
| CN103289228B (en) | A kind of ethylene-propylene rubber(EPR) modified PVC waterproof roll and manufacture craft thereof | |
| CN106009148A (en) | PE (poly ethylene) protection film material for automobile and preparation method thereof | |
| CN105418934B (en) | A kind of high transparency heat insulation type thermoplastic polyether ester and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101208 Termination date: 20170609 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |