CN1851061A - Wood-bamboo composite cellulose viscose short fiber, and its preparing method - Google Patents
Wood-bamboo composite cellulose viscose short fiber, and its preparing method Download PDFInfo
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- CN1851061A CN1851061A CN 200610021061 CN200610021061A CN1851061A CN 1851061 A CN1851061 A CN 1851061A CN 200610021061 CN200610021061 CN 200610021061 CN 200610021061 A CN200610021061 A CN 200610021061A CN 1851061 A CN1851061 A CN 1851061A
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Abstract
The invention discloses the complex fibrin mucilage glue short fiber produced from the compounding fibrin new slurry derived from the combination of the wood and the bamboo, the original material slurry of the compounding fibrin mucilage glue short fiber is the compounding fibrin slurry produced by the percent of the below weight mixing percent: the wood: the bamboo= 1% - 99% : 99% - 1%; the producing process includes the below steps: the dipping, the grinding, the crushing, the etiolation, the melting, the filtrating, the becoming mature, the pulling off the dunk, the filature, the cutting, the refining, the drying and the forming the product; the invention extends the material source of the glue fiber; the compounding fiber produced by the filature is colorful and has the good chromaticity, the good ability of the moisture absorption and the wet removing and the good ability of the breathe freely, so it is the crude environmental protected product.
Description
Technical field:
The present invention relates to a kind of viscose staple fibre and preparation method thereof, particularly relating to a kind of is composite cellulose viscose short fiber of producing of one of raw material and preparation method thereof with wood, bamboo composite cellulose pulp.
Background technology:
At present, viscose staple fibre all is to be single raw material with native celluloses such as the cotton pulp dregs of rice, wood pulps, bagasse pulp, hemp dissolving pulp, bamboo pulps, a kind of regenerated celulose fibre of making through technical process such as dipping, squeezing, pulverizing, yellow, dissolving, filtration, maturation, deaeration, spinning, cut-out, refining, oven dry.The fabric that with the natural fabric is raw material possesses good hygroscopicity, dyeability and antistatic behaviour.Raising day by day along with people's living standard, requirement for fabric is also more and more higher, not only pursue comfortableness, pay attention to environmental protection more, antibiotic property and biocidal property etc., existing composite viscose fiber all be on spinning machine, carry out compound, rather than in the pulp production process, just directly carry out various raw materials compound, yet, the cotton pulp dregs of rice, wood pulps, the bagasse pulp, hemp dissolving pulp, the viscose of each single raw material production such as bamboo pulp, the performance dullness, have their own characteristics each, as skin affinity, the stiffness of fiber, the antibacterial bacteriostatic function, soft feeling, deodorization, gas permeability, coloring, humidity absorption and releases etc., therefore the viscose of single pulp production can't satisfy people's multiple demand.Find that through test plurality of raw materials is made the compound cellulose pulp, can improve the complementarity of fiber, maximizes favourable factors and minimizes unfavourable ones, and the premium properties of every kind of fiber is represented.Adopt this compound cellulose pulp that the natural compounding type that properties of product are strong, quality is high viscose staple fibre can be provided, satisfy the needs of the high-quality life of people.
Summary of the invention:
The purpose of this invention is to provide a kind of is high performance viscose staple fibre of raw material production and preparation method thereof with wood, bamboo composite cellulose pulp, the present invention is to be raw material so that mixed raw materials such as natural wood, bamboo wood are become composite cellulose pulp, has expanded the raw material sources of viscose.It is beautiful to make the composite fibre color and luster through spinning, and dyeability is good, and humidity absorption and release, gas permeability are better than various synthetic fiber especially, is a kind of fully natural green environment-friendly products.Technical scheme of the present invention is as follows:
A kind of wood, bamboo composite cellulose viscose short fiber is characterized in that: the raw material pulp is a compound cellulose pulp cotton, that the bamboo raw material is made according to following weight proportion combination: wood: bamboo=1%～99%: 99%～1%.
Composite cellulose viscose short fiber of the present invention is meant with the compound cellulose pulp to be the viscose staple fibre of raw material production, and its specification is as follows: do fracture strength: 〉=1.9CN/dtex
Wet breaking strength: 〉=1.0CN/dtex
Dried elongation at break: 〉=16%
Fineness deviation ratio :≤7%
Double-length rate :≤0.25%
Residual sulfur content :≤20mg/100g fiber.
Wood of the present invention, bamboo composite cellulose pulp are in wood, bamboo composite cellulose pulp production process natural wood raw material and bamboo material to be mixed and made into composite cellulose pulp
The technical indicator of compound cellulose pulp of the present invention is as follows: ash≤0.25%, moisture 10.0 ± 0.5%, iron content≤40ppm, fatty wax≤0.25%, chlorine-bearing compound≤0.25%, pectic substance pentosan≤0.25%, lignin≤0.25%, alpha cellulose 〉=85%, viscosity 〉=8.0mpa.s, whiteness 〉=60%, constant volume weight 120-1020g/m3 inhales base number 200-970%; Swelling capacity 80-300%.
A kind of composite cellulose pulp manufacture method of the present invention comprises the steps: condiment, boiling, washes material, making beating is discongested, removal of impurities washing, pre-acid, pre-chlorine, bleaching, acid treatment, removal of impurities washing, manufacture paper with pulp.A, condiment: condiment:, mix with wood, in the bamboo fibre raw material any two kinds or two or morely get the raw materials ready according to any proportioning; B, boiling: wood, bamboo are adopted soda process, sulfate process or sulfite cooking, press 5.0～35.0% of oven dry weight and add NaOH, Na
2S, Na
2SO
3, H
2SO
3In one or more, liquor ratio is 1: 1.0～9.5, boiling vacuumizes earlier, intensification number of times 〉=1 time, little steam bleeding number of times 〉=0 time; C, wash material; D, washing; E, making beating are discongested: employing beater or fluffer are pulled an oar or are discongested, weight in wet base 5～50 grams; F, removal of impurities washing; G, pre-acid: with the acid amount is 0.2～10.0% of slurry oven dry weight, concentration 1.0～15.0%, pre-acid time 〉=5min; H, pre-chlorine: chlorine dosage is 0.2～15.0% of a slurry oven dry weight, concentration 0.2～10.0%, pre-chlorine time 〉=15min; I, bleaching: the viscosity of bleaching disposed slurry is 8-35mpa.s, first fibre 〉=80.0%, whiteness 〉=60%; J, acid treatment: sulfuric acid or hydrochloric acid are pressed the slurry oven dry weight and are added 0.2～10.0%, and calgon is pressed the slurry oven dry weight and added 0.1～8.0%, processing time 〉=30min; K, removal of impurities washing; L, manufacture paper with pulp.Press 0.3～10% of oven dry weight before the described cooking process and add NaOH, liquor ratio is that 1: 1.0～9.5 pairs raw materials are precooked.The NaOH that adds a certain amount of concentration before the described washing procedure and be 5%-30% carries out alkali and analyses.On the basis of technique scheme, be further to reduce energy consumption and stable control quality, can also adopt one of following several technical measures or all: in the described precooking process, can add alkali lye, acid, water and carry out boiling, also can directly feed vapour cooking.In the described step boiling, boiling vacuumizes earlier, intensification number of times 〉=1 time, and little steam bleeding number of times 〉=0 time, heat up, temperature retention time≤800 minute in maximum temperature≤200 ℃ of at every turn heating up at every turn.In the described step boiling, for improving the first fibre, press down bubble, the big gun that disappears, and reduce black liquor COD and colourity, press the MA-1 auxiliary agent that 0.1～3.0% of slurry oven dry weight adds the production of Chongqing long-lived paper making additive factory.Described MA-1 auxiliary agent is a kind of anion surfactant, but the automated biological degraded.
The preparation method of a kind of composite cellulose viscose short fiber of the present invention comprises following processing step: mix the dregs of rice, dipping, squeezing, pulverizing, experienced, yellow, dissolving, filtration, maturation, deaeration, spinning, cut-out, refining, oven dry and finished product.
Dipping of the present invention, squeezing, pulverizing, experienced operation are meant: described dipping, squeezing, pulverizing, experienced operation are meant: the compound cellulose pulp is immersed under 20～55 ℃ temperature conditions in the alkali lye that concentration is 200～250g/L, again after the squeezer squeezing, pulverizing, reaching in the alkali fibre the fine content of first is 26～33%, and alkali content is 15～18%.
The yellow mode that yellow operation of the present invention adopts has dry xanthation, wet method yellow and dried, wet method yellow.After yellow, add the VIF-51/41 denaturant that improves viscose filtration performance and spinning property, effectively improve the strainability and the spinning property of compound cellulose viscose glue.
Spinning of the present invention, cut-out are to adopt the spinning of single or double short fiber spinning machine, cut off after the plasticizing drawing-off again.The viscose glue that the compound cellulose that spinning process adopted makes comprises following feature: α-cell (methylcellulose) content: α-cell (methylcellulose) content is: 7.8～9.2%; NaOH content is: 5.80～6.50%; Viscosity (falling ball method) is: 28～45 seconds; Degree of ripeness (10%NH4Cl value): 8.0～12.0ml.
The acid bath that spinning process adopted comprises following feature: H
2SO
4Content is: 100～150g/l; ZnSO
4Content is: 10～15g/l; Na
2SO
4Content is: 260～340g/l; The acid bath temperature is: 50～55 ℃.
Concise operation of the present invention is meant: staple fibre is moving forward on the wire netting or on grizzly bar continuously with cotton stratiform, and various treatment fluids (comprising water lotion, doctor solution, pickle, finish) flow out from the drip washing dish, and fiber is washed.
The present invention is owing to be directly to adopt mixed raw materials such as natural wood, bamboo wood to become composite cellulose pulp to be raw material, to have expanded the raw material sources of viscose.It is beautiful to make the composite fibre color and luster through spinning, and dyeability is good, and humidity absorption and release, gas permeability are better than various synthetic fiber especially, is a kind of fully natural green environment-friendly products.
The specific embodiment:
Embodiment 1
1.5D the cotton type of * 35mm has the production of photoreactivation cellulose viscose staple fibre:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 240g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 33% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 50 ℃
End product quality meets national artificial cotton QUALITY STANDARD.
Embodiment 2
1.5D the production of the unglazed composite cellulose viscose short fiber of the cotton type of * 35mm:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 240g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 33% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Tio
2Addition: 1.5% (to α-cell)
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 50 ℃
End product quality meets national artificial cotton QUALITY STANDARD.
Embodiment 3
1.5D the production of the painted composite cellulose viscose short fiber of the cotton type of * 35mm:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 240g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 33% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
The mill base addition: 1.5% (solid content is to α-cell) in the mill base
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 50 ℃
End product quality meets national artificial cotton QUALITY STANDARD.
Embodiment 4
1.5D the cotton type of * 35mm has the production of photoreactivation cellulose viscose staple fibre:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 30%: 70%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 245g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 34% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 51 ℃
End product quality meets national artificial cotton QUALITY STANDARD.
Embodiment 5
1.5D the production of the unglazed composite cellulose viscose short fiber of the cotton type of * 35mm:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 30%: 70%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 245g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 34% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Tio
2Addition: 1.5% (to α-cell)
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 51 ℃
End product quality meets national artificial cotton QUALITY STANDARD.
Embodiment 6
1.5D the production of the painted composite cellulose viscose short fiber of the cotton type of * 35mm:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 30%: 70%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 245g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 34% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
The mill base addition: 1.5% (solid content is to α-cell) in the mill base
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 51 ℃
End product quality meets national artificial cotton QUALITY STANDARD.
Embodiment 7
3D * 65mm wool type has the production of photoreactivation cellulose viscose staple fibre:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 240g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 33% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 50 ℃
End product quality meets national artificial wool QUALITY STANDARD.
Embodiment 8
The production of 3D * unglazed composite cellulose viscose short fiber of 65mm wool type:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 240g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 33% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Tio
2Addition: 1.5% (to α-cell)
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 50 ℃
End product quality meets national artificial wool QUALITY STANDARD.
Embodiment 9
The production of 3D * painted composite cellulose viscose short fiber of 65mm wool type:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 80%: 20%.
Impregnation technology:
Alkali liquid temperature: 40 ℃
Concentration of lye: 240g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 33% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
The mill base addition: 1.5% (solid content is to α-cell) in the mill base
Spinning technique:
H
2SO
4Concentration: 130g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 50 ℃
End product quality meets national artificial wool QUALITY STANDARD.
Embodiment 10
3D * 65mm wool type has the production of photoreactivation cellulose viscose staple fibre:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 30%: 70%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 245g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 34% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 51 ℃
End product quality meets national artificial wool QUALITY STANDARD.
Embodiment 11
The production of 3D * unglazed composite cellulose viscose short fiber of 65mm wool type:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 30%: 70%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 245g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 34% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
Tio
2Addition: 1.5% (to α-cell)
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 51 ℃
End product quality meets national artificial wool QUALITY STANDARD.
Embodiment 12
The production of 3D * painted composite cellulose viscose short fiber of 65mm wool type:
Raw material: become composite cellulose pulp with natural wood, bamboo mixed raw material, wherein: wood, bamboo proportion of raw materials are: 30%: 70%.
Impregnation technology:
Alkali liquid temperature: 35 ℃
Concentration of lye: 245g/l
Dip time: 80 minutes
Alkali is fine to be formed: α-cell content: 30%
NaOH content: 16.5%
The VIF-64 addition: 1.0% (to α-cell)
Yellow technology:
CS
2Addition: 34% (to α-cell)
Yellow temperature: 28 ℃
The yellow time: 50 minutes
Solution temperature: 8 ℃
The VIF-51/41 addition: 1.5% (to α-cell)
Spin preceding viscose glue:
α-cell content: 8.50%
NaOH content: 6.00%
Viscosity (falling ball method): 40 seconds
Degree of ripeness (10%NH4Cl value): 9.5ml
The mill base addition: 1.5% (solid content is to α-cell) in the mill base
Spinning technique:
H
2SO
4Concentration: 135g/l
Na
2SO
4Concentration: 300g/l
ZnSO
4Concentration: 12g/l
Acid bath temperature: 51 ℃
End product quality meets national artificial wool QUALITY STANDARD.
Claims (13)
1, a kind of wood, bamboo composite cellulose viscose short fiber is characterized in that: the raw material pulp is a compound cellulose pulp cotton, that the bamboo raw material is made according to following weight proportion combination: wood: bamboo=1%～99%: 99%～1%.
2, a kind of wood according to claim 1, bamboo composite cellulose viscose short fiber is characterized in that: be meant with the compound cellulose pulp to be the viscose staple fibre of raw material production, its specification is as described below:
Monofilament specification: (1～8D) * (28～150mm)
Kind: light, unglazed and painted staple fibre are arranged;
Fiber shape: circular saw dentation, flat and other odd-shaped cross section.
3, a kind of wood according to claim 1 and 2, bamboo composite cellulose viscose short fiber, it is characterized in that: its key technical indexes comprises:
Do fracture strength: 〉=1.9CN/dtex
Wet breaking strength: 〉=1.0CN/dtex
Dried elongation at break: 〉=16%
Fineness deviation ratio :≤7%
Double-length rate :≤0.25%
Residual sulfur content :≤20mg/100g fiber.
4, a kind of wood according to claim 3, bamboo composite cellulose viscose short fiber, it is characterized in that: the technical indicator of described compound cellulose pulp is as follows: ash≤0.25%, moisture 10.0 ± 0.5%, iron content≤40ppm, fat wax≤0.25%, chlorine-bearing compound≤0.25%, pectic substance pentosan≤0.25%, lignin≤0.25%, alpha cellulose 〉=85%, viscosity 〉=8.0mpa.s, whiteness 〉=60%, constant volume weight 120-1020g/m3 inhales base number 200-970%; Swelling capacity 80-300%.
5, a kind of wood according to claim 4, bamboo composite cellulose viscose short fiber is characterized in that: the manufacture method of described composite cellulose pulp comprises the steps: condiment, boiling, washes material, making beating is discongested, removal of impurities washing, pre-acid, pre-chlorine, bleaching, acid treatment, removal of impurities washing, manufacture paper with pulp.
6, a kind of wood according to claim 5, bamboo composite cellulose viscose short fiber is characterized in that: the concrete operation of the manufacture method of described composite cellulose pulp is:
A, condiment:, mix with wood, in the bamboo fibre raw material any two kinds or two or morely get the raw materials ready according to any proportioning;
B, boiling: wood, bamboo are adopted soda process, sulfate process or sulfite cooking, press 5.0～35.0% of oven dry weight and add NaOH, Na
2S, Na
2SO
3, H
2SO
3In one or more, liquor ratio is 1: 1.0～9.5, boiling vacuumizes earlier, intensification number of times 〉=1 time, little steam bleeding number of times 〉=0 time;
C, wash material;
D, washing;
E, making beating are discongested: employing beater or fluffer are pulled an oar or are discongested, weight in wet base 5～50 grams;
F, removal of impurities washing;
G, pre-acid: with the acid amount is 0.2～10.0% of slurry oven dry weight, concentration 1.0～15.0%, pre-acid time 〉=5min;
H, pre-chlorine: chlorine dosage is 0.2～15.0% of a slurry oven dry weight, concentration 0.2～10.0%, pre-chlorine time 〉=15min;
I, bleaching: the viscosity of bleaching disposed slurry is 8-35mpa.s, first fibre 〉=80.0%, whiteness 〉=60%;
J, acid treatment: sulfuric acid or hydrochloric acid are pressed the slurry oven dry weight and are added 0.2-10.0%, and calgon is pressed the slurry oven dry weight and added 0.1～8.0%, processing time 〉=30min; L, removal of impurities washing; M, manufacture paper with pulp.Press 0.3～10% of oven dry weight before the described cooking process and add NaOH, liquor ratio is that 1: 1.0～9.5 pairs raw materials are precooked.Adding a certain amount of concentration before the described washing procedure and be 5%～30% NaOH carries out alkali and analyses;
Wherein: in the described precooking process, can add entry, acid, alkali and feed steam and carry out boiling;
In the described boiling step, boiling vacuumizes earlier, intensification number of times 〉=1 time, and little steam bleeding number of times 〉=0 time, heat up, temperature retention time≤800 minute in maximum temperature≤200 ℃ of at every turn heating up at every turn.
7, the preparation method of a kind of wood according to claim 6, bamboo composite cellulose viscose short fiber is characterized in that: comprise following processing step: dipping, squeezing, pulverizing, experienced, yellow, dissolving, filtration, maturation, deaeration, spinning, cut-out, refining, oven dry and finished product.
8, the preparation method of a kind of wood according to claim 7, bamboo composite cellulose viscose short fiber, it is characterized in that: described dipping, squeezing, pulverizing, experienced operation are meant: the compound cellulose pulp is immersed under 20～55 ℃ temperature conditions in the alkali lye that concentration is 200～250g/L, again after the squeezer squeezing, pulverizing, reaching in the alkali fibre the fine content of first is 26～33%, and alkali content is 15～18%.
9, the preparation method of a kind of wood according to claim 7, bamboo composite cellulose viscose short fiber is characterized in that: the yellow mode that described yellow operation adopts has dry xanthation, wet method yellow and dried, wet method yellow.
10, the preparation method of a kind of wood according to claim 7, bamboo composite cellulose viscose short fiber is characterized in that: described spinning, cut-out operation are to adopt the spinning of single or double short fiber spinning machine, cut off after the plasticizing drawing-off again.
11, the preparation method of a kind of wood according to claim 7, bamboo composite cellulose viscose short fiber, it is characterized in that: described refining procedure is that staple fibre is moving forward on the wire netting or on grizzly bar continuously with cotton stratiform, various treatment fluids flow out from the drip washing dish, and fiber is washed.
12, the preparation method of a kind of wood according to claim 7, bamboo composite cellulose viscose short fiber, it is characterized in that: the viscose glue that the compound cellulose that spinning process adopted makes comprises following feature: methylcellulose α-cell content is: 7.8～9.2%; NaOH content is: 5.80～6.50%; Viscosity is: 28～45 seconds; Degree of ripeness 10%NH4Cl value: 8.0～12.0ml.
13, according to the preparation method of claim 7 or 12 described a kind of wood, bamboo composite cellulose viscose short fiber, it is characterized in that: the acid bath that spinning process adopted comprises following feature: H
2SO
4Content is: 100～150g/l; ZnSO
4Content is: 10～15g/l; Na
2SO
4Content is: 260～340g/l; The acid bath temperature is: 50～55 ℃.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102393691A (en) * | 2011-09-27 | 2012-03-28 | 宜宾海丝特纤维有限责任公司 | Automatic control system in production of short fiber stock solution viscose |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102393691A (en) * | 2011-09-27 | 2012-03-28 | 宜宾海丝特纤维有限责任公司 | Automatic control system in production of short fiber stock solution viscose |
| CN102393691B (en) * | 2011-09-27 | 2013-12-11 | 宜宾海丝特纤维有限责任公司 | Automatic control system in production of short fiber stock solution viscose |
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