Summary of the invention
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art part, a kind of recovery waste heat simultaneously and the emission-control equipment that removes pollutant are provided.This emission-control equipment can utilize the waste gas residual heat preheated air, can remove pernicious gases such as nitrogen oxides of exhaust gas again simultaneously, invests, raises the efficiency thereby save.
For achieving the above object, the technical solution used in the present invention is, a kind of recovery waste heat simultaneously and the emission-control equipment that removes pollutant, comprise the exhaust-gas treatment unit, the structure of exhaust-gas treatment unit is, one end of the first porous ceramics regenerator is connected with the port of export of the entrance point of first valve and second valve, the other end of the first porous ceramics regenerator is connected with the entrance point of the 3rd valve and the port of export of the 4th valve, one end of the second porous ceramics regenerator is connected with the port of export of the entrance point of the 5th valve and the 6th valve, the other end of the second porous ceramics regenerator is connected with the entrance point of the 7th valve and the port of export of the 8th valve, is coated with oxidation reduction catalyst at the bore area of the first porous ceramics regenerator and the second porous ceramics regenerator.
For achieving the above object, the present invention also can adopt following multiple technologies scheme.
First valve in the above-mentioned exhaust-gas treatment unit, second valve, the 5th valve and four valves of the 6th valve substitute with one first two-position four-way rotary valve or the 3rd valve, the 4th valve, the 7th valve and four valves of the 8th valve substitute with one second two-position four-way rotary valve.
First valve in the above-mentioned exhaust-gas treatment unit, second valve, the 5th valve and four valves of the 6th valve substitute with one first two-position four-way rotary valve, and the 3rd valve, the 4th valve, the 7th valve and four valves of the 8th valve substitute with one second two-position four-way rotary valve.
First valve in the above-mentioned exhaust-gas treatment unit, two valves of second valve substitute with one first two-position three way ball valve, the 5th valve and two valves of the 6th valve substitute with one second two-position three way ball valve or the 3rd valve, two valves of the 4th valve substitute with one the 3rd two-position three way ball valve, and the 7th valve and two valves of the 8th valve are alternative with one the 4th two-position three way ball valve.
First valve in the above-mentioned exhaust-gas treatment unit, two valves of second valve substitute with one first two-position three way ball valve, the 5th valve and two valves of the 6th valve substitute with one second two-position three way ball valve, the 3rd valve, two valves of the 4th valve substitute with one the 3rd two-position three way ball valve, and the 7th valve and two valves of the 8th valve substitute with one the 4th two-position three way ball valve.
First valve in the above-mentioned exhaust-gas treatment unit, second valve, the 5th valve and four valves of the 6th valve substitute with one first two-position four-way rotary valve, the 3rd valve, two valves of the 4th valve substitute with one the 3rd two-position three way ball valve, and the 7th valve and two valves of the 8th valve substitute with one the 4th two-position three way ball valve.
First valve in the above-mentioned exhaust-gas treatment unit, two valves of second valve substitute with one first two-position three way ball valve, the 5th valve and two valves of the 6th valve substitute with one second two-position three way ball valve, and the 3rd valve, the 4th valve, the 7th valve and four valves of the 8th valve substitute with one second two-position four-way rotary valve.
In the present invention, the quantity of described exhaust-gas treatment unit can be more than two or two.Described exhaust-gas treatment unit more than two or two can be identical structure, also can be different structures.
The present invention compared with prior art has following advantage:
1. the present invention can reclaim the industrial furnace waste gas residual heat, removes nitrogen oxide harmful in the waste gas simultaneously, and exhaust gas temperature can drop to below 150 ℃, NO
xRemoval efficiency can reach more than 85%, realizes that the industrial furnace waste gas residual heat reclaims and the integrated processing of pollutant removing, and it is over half that investment is saved.
2. in the present invention, the quantity of described exhaust-gas treatment unit can be more than two or two.By increasing the quantity of exhaust-gas treatment unit, promptly increase the quantity of regenerator, adapt to the requirement of different exhaust-gas treatment amounts, can guarantee that the stove combustion process is mild more and continuous.
The specific embodiment
Embodiment 1
By Fig. 1, Fig. 2 and shown in Figure 3, the present invention can comprise the exhaust-gas treatment unit, reducing agent NH
3 Storage tank 1, valve 2, industrial furnace 15, air-introduced machine 8 and air blast 9.
The structure of exhaust-gas treatment unit is, one end of the first porous ceramics regenerator 5 is connected with the port of export of the entrance point of first valve 3 and second valve 4, the other end of the first porous ceramics regenerator 5 is connected with the entrance point of the 3rd valve 6 and the port of export of the 4th valve 7, one end of the second porous ceramics regenerator 12 is connected with the port of export of the entrance point of the 5th valve 13 and the 6th valve 14, and the other end of the second porous ceramics regenerator 12 is connected with the entrance point of the 7th valve 10 and the port of export of the 8th valve 11; Bore area in the first porous ceramics regenerator 5 and the second porous ceramics regenerator 12 is coated with oxidation reduction catalyst.Oxidation reduction catalyst can be V
2O
5-WO
3, MoO
3And Au.
The entrance point of valve 2 is connected with the outlet of storage tank 1, the entrance point of second valve 4, the entrance point of the 6th valve 14 is connected with the port of export of valve 2, the port of export of first valve 3 is connected with the port of export of the 5th valve 13, the entrance point of the 4th valve 7 is connected with the entrance point of the 8th valve 11, the port of export of the 3rd valve 6 is connected with the port of export of the 7th valve 10, the combustion air inlet of the port of export of first valve 3 and industrial furnace 15 is connected, the port of export of valve 2 is connected with the waste gas outlet of industrial furnace 15, the entrance point of the 4th valve 7 is connected with the air outlet slit of air blast 9, the outlet of the 3rd valve 6.Above connection can link to each other by pipeline.
During normal the operation, second valve 4, the 3rd valve 6, the 8th valve 11 are connected with the exhaust gas entrance of air-introduced machine 8 with 13 beginnings of the 5th valve and open, simultaneously, first valve 3, the 4th valve 7, the 7th valve 10 and the 6th valve 14 are closed, the high-temp waste gas that industrial furnace 15 is discharged with storage tank 1 in the reducing agent NH that discharges
3Mix, enter the first porous ceramics regenerator 5 then, reducing agent NH
3Burst size by valve 2 control.Utilize the accumulation of heat effect of porous ceramic bodies to absorb heat, under the effect of catalyst, carry out reduction reaction simultaneously, discharge low temperature waste gas by air-introduced machine 8 then; Air blast 9 is sent extraneous combustion air into the second porous ceramics regenerator 12, with the heat storage heat-shift after, becoming high temperature air, to enter industrial furnace 15 combustion-supporting.
When the EGT of air-introduced machine 8 discharges rises to the temperature upper limit of a setting gradually, carrying out valve switches, second valve 4, the 3rd valve 6, the 8th valve 11 and the 5th valve 13 are closed, first valve 3, the 4th valve 7, the 7th valve 10 and the 6th valve 14 are opened, then industrial furnace 15 high-temp waste gas of discharging with storage tank 1 in the reducing agent NH that discharges by by-pass valve control 2
3After the mixing, enter the second porous ceramics regenerator 12, utilize the accumulation of heat effect of porous ceramic bodies to absorb heat, under the effect of catalyst, carry out reduction reaction simultaneously, discharge low temperature waste gas by air-introduced machine 8 then; Air blast 9 is sent extraneous combustion air into the first porous ceramics regenerator 5, with the heat storage heat-shift after, becoming high temperature air, to enter industrial furnace 15 combustion-supporting.
Above process is switched by valve cycle ground and is alternately carried out continuously.To guarantee that waste gas can be handled continuously.
Embodiment 2
By shown in Figure 4, be with the difference of Fig. 1: first valve 3, second valve 4, the 5th valve 13 and 14 4 valves of the 6th valve in the exhaust-gas treatment shown in Figure 1 unit substitute with one first two-position four-way rotary valve 16.
Embodiment 3
By shown in Figure 5, be with the difference of Fig. 1: the 3rd valve 6, the 4th valve 7, the 7th valve 10 and 11 4 valves of the 8th valve in the exhaust-gas treatment shown in Figure 1 unit substitute with one second two-position four-way rotary valve 17.
Embodiment 4
By shown in Figure 6, be with the difference of Fig. 1: first valve 3, second valve 4, the 5th valve 13 and 14 4 valves of the 6th valve in the exhaust-gas treatment shown in Figure 1 unit substitute with one first two-position four-way rotary valve 16, and the 3rd valve 6, the 4th valve 7, the 7th valve 10 and 11 4 valves of the 8th valve substitute with one second two-position four-way rotary valve 17.
First rotary valve 16 has four connectors, two connector a, b of first rotary valve 16 are connected with an end of the first porous ceramics regenerator 5, the second porous ceramics regenerator 12 respectively, the import c of first rotary valve 16 is connected with the waste gas outlet of industrial furnace 15, and the outlet d of first rotary valve 16 is connected with the combustion air of industrial furnace 15 inlet.
Second rotary valve 17 has four connectors, two connector e, f of second rotary valve 17 are connected with the other end of the first porous ceramics regenerator 5, the second porous ceramics regenerator 12 respectively, the import g of second rotary valve 17 is connected with the air outlet slit of air blast 9, and the outlet h of second rotary valve 17 is connected with the exhaust gas entrance of air-introduced machine 8.
The valve plate of first rotary valve 16, second rotary valve 17 can rotate by 90 degree, stops on two positions of A, B.
When the valve plate of first rotary valve 16, second rotary valve 17 rests on the A position simultaneously, the waste gas of industrial furnace 15 is discharged through air-introduced machine 8 by second rotary valve 17 through the first porous ceramics regenerator 5 by first rotary valve 16 again, and air again by first rotary valve 16 enters industrial furnace 15 by second rotary valve 17 through the second porous ceramics regenerator 12 by air blast 9.
When the valve plate of first rotary valve 16, second rotary valve 17 rests on the B position simultaneously, the waste gas of industrial furnace 15 is discharged through air-introduced machine 8 by second rotary valve 17 through the second porous ceramics regenerator 12 by first rotary valve 16 again, and air again by first rotary valve 16 enters industrial furnace 15 by second rotary valve 17 through the first porous ceramics regenerator 5 by air blast 9.
Present embodiment has reduced the quantity of valve, thereby has simplified structure of the present invention.
Embodiment 5
By shown in Figure 7, be with the difference of Fig. 1: first valve 3 in the exhaust-gas treatment shown in Figure 1 unit, 4 two valves of second valve substitute with one first two-position three way ball valve 28, and the 5th valve 13 and 14 2 valves of the 6th valve substitute with one second two-position three way ball valve 30.
Embodiment 6
By shown in Figure 8, be with the difference of Fig. 1: the 3rd valve 6 in the exhaust-gas treatment shown in Figure 1 unit, 7 two valves of the 4th valve substitute with one the 3rd two-position three way ball valve 29, and the 7th valve 10 and 11 2 valves of the 8th valve substitute with one the 4th two-position three way ball valve 31.
Embodiment 7
By shown in Figure 9, be with the difference of Fig. 1: first valve 3 in the exhaust-gas treatment shown in Figure 1 unit, 4 two valves of second valve substitute with one first two-position three way ball valve 28, the 5th valve 13 and 14 2 valves of the 6th valve substitute with one second two-position three way ball valve 30, the 3rd valve 6,7 two valves of the 4th valve substitute with one the 3rd two-position three way ball valve 29, and the 7th valve 10 and 11 2 valves of the 8th valve substitute with one the 4th two-position three way ball valve 31.
Embodiment 8
By shown in Figure 10, be with the difference of Fig. 1: first valve 3, second valve 4, the 5th valve 13 and 14 4 valves of the 6th valve in the exhaust-gas treatment shown in Figure 1 unit substitute with one first two-position four-way rotary valve 16, the 3rd valve 6,7 two valves of the 4th valve substitute with one the 3rd two-position three way ball valve 29, and the 7th valve 10 and 11 2 valves of the 8th valve substitute with one the 4th two-position three way ball valve 31.
Embodiment 9
By shown in Figure 11, be with the difference of Fig. 1: first valve 3 in the exhaust-gas treatment shown in Figure 1 unit, 4 two valves of second valve substitute with one first two-position three way ball valve 28, the 5th valve 13 and 14 2 valves of the 6th valve substitute with one second two-position three way ball valve 30, and the 3rd valve 6, the 4th valve 7, the 7th valve 10 and 11 4 valves of the 8th valve substitute with one second two-position four-way rotary valve 17.
Embodiment 10
By shown in Figure 12, be with the difference of Fig. 1: on the basis of Fig. 1, increased an exhaust-gas treatment unit.
The connection of the exhaust-gas treatment unit that increases newly is: being connected of the port of export of an end of the 3rd porous ceramics regenerator 18 and the entrance point of the 9th valve 25 and the tenth valve 24, the other end of the 3rd porous ceramics regenerator 18 is connected with the port of export of the entrance point of the 11 valve 20 and the 12 valve 21; One end of the 4th porous ceramics regenerator 19 is connected with the entrance point of the 13 valve 27 and the port of export of the 14 valve 26, and the other end of the 4th porous ceramics regenerator 19 is connected with the port of export of the entrance point of the 15 valve 22 and the 16 valve 23.
The bore area of the 3rd porous ceramics regenerator 18 and the 4th porous ceramics regenerator 19 is coated with oxidation reduction catalyst.
Second valve 4 in first exhaust-gas treatment unit, the 3rd valve 6, the 8th valve 11, the tenth valve 24 in the 5th valve 13 and second the exhaust-gas treatment unit, the 11 valve 20, the 16 valve 23, when the 13 valve 27 is opened, first valve 3 in first exhaust-gas treatment unit of while, the 4th valve 7, the 7th valve 10, the 9th valve 25 in the 6th valve 14 and second the exhaust-gas treatment unit, the 12 valve 21, the 15 valve 22, the 14 valve 26 is closed, the high-temp waste gas that industrial furnace 15 is discharged with storage tank 1 in the reducing agent NH that discharges by by-pass valve control 2
3After the mixing, enter the first porous ceramics regenerator 5 and the 3rd porous ceramics regenerator 18, utilize the accumulation of heat effect of porous ceramic bodies to absorb heat, under the effect of catalyst, carry out simultaneously reduction reaction, discharge by air-introduced machine 8 then, after air blast 9 was sent outside air into the second porous ceramics regenerator 12, the 4th porous ceramics regenerator 19 and heat storage heat-shift, becoming high temperature air, to enter industrial furnace 15 combustion-supporting.
When the EGT of air-introduced machine 8 discharges rises to the temperature upper limit of a setting gradually, switch, second valve 4 in first exhaust-gas treatment unit, the 3rd valve 6, the 8th valve 11, the tenth valve 24 in the 5th valve 13 and second the exhaust-gas treatment unit, the 11 valve 20, the 16 valve 23, the 13 valve 27 is closed, first valve 3 in first exhaust-gas treatment unit, the 4th valve 7, the 7th valve 10, the 9th valve 25 in the 6th valve 14 and second the exhaust-gas treatment unit, the 12 valve 21, the 15 valve 22, the 14 valve 26 is opened, then industrial furnace 15 high-temp waste gas of discharging with storage tank 1 in the reducing agent NH that discharges by by-pass valve control 2
3After the mixing, enter the second porous ceramics regenerator 12, the 4th porous ceramics regenerator 19, utilize the accumulation of heat effect of porous ceramic bodies to absorb heat, under the effect of catalyst, carry out simultaneously reduction reaction, discharge by air-introduced machine 8 then, after air blast 9 was sent outside air into the first porous ceramics regenerator 5, the 3rd porous ceramics regenerator 18 and heat storage heat-shift, becoming high temperature air, to enter industrial furnace 15 combustion-supporting.Above process is alternately carried out continuously, to guarantee that waste gas can be handled continuously.
Embodiment 11
By shown in Figure 13, the exhaust-gas treatment unit more than two or two can be different structures.
In above all embodiment, all be to be example with the industrial furnace, be suitable for all refinery device and boilers in fact.Be example still now, as in industrial furnace, having comprised by-pass valve control and reducing agent NH with the industrial furnace
3, the reducing agent NH among all embodiment then
3 Storage tank 1 and valve 2 just can save.