CN110833763B - Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification - Google Patents

Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification Download PDF

Info

Publication number
CN110833763B
CN110833763B CN201911289741.5A CN201911289741A CN110833763B CN 110833763 B CN110833763 B CN 110833763B CN 201911289741 A CN201911289741 A CN 201911289741A CN 110833763 B CN110833763 B CN 110833763B
Authority
CN
China
Prior art keywords
flue gas
air
desulfurization
dust removal
heat exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201911289741.5A
Other languages
Chinese (zh)
Other versions
CN110833763A (en
Inventor
余阳春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huanggang Huayao Zhongzhou Kiln Co ltd
Original Assignee
Huanggang Huayao Zhongzhou Kiln Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huanggang Huayao Zhongzhou Kiln Co ltd filed Critical Huanggang Huayao Zhongzhou Kiln Co ltd
Priority to CN201911289741.5A priority Critical patent/CN110833763B/en
Publication of CN110833763A publication Critical patent/CN110833763A/en
Application granted granted Critical
Publication of CN110833763B publication Critical patent/CN110833763B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/20Combinations of devices covered by groups B01D45/00 and B01D46/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/10Arrangements for using waste heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/20Arrangements for treatment or cleaning of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/204Carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/21Organic compounds not provided for in groups B01D2251/206 or B01D2251/208
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chimneys And Flues (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a production process and equipment for organic fume incineration, desulfurization, dust removal and denitration, which solve the problems of incomplete environmental pollution caused by organic fume purification in the prior art and are characterized in that: the organic matters in the flue gas are combusted through the incinerator, waste heat utilization is carried out on the combusted high-temperature flue gas, and the incinerated flue gas is treated through the processes of desulfurization, dust removal, denitration and the like, so that the flue gas reaches the standard and is emptied. Namely, an incinerator (2) is additionally arranged above the kiln (1), a smoke exhaust pipe (26) of the incinerator (2) is connected with a waste heat recycling device, a desulfurizing device (9), a dust removing device (10) and a denitration device through an air heat exchanger (3), and purified and standard smoke is sent into a smoke exhaust pipeline (12) through a smoke exhaust induced draft fan (13) and then is discharged into the air from a chimney (14). Has the advantages of reasonable structure, safe operation, comprehensive utilization, integrated purification, energy conservation, environmental protection and the like, and can be widely applied to the purification treatment of organic flue gas of various kilns.

Description

有机烟气焚烧、脱硫、除尘及脱硝的生产工艺及设备Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification

技术领域Technical Field

本发明属于工业热工设备领域,尤其是涉及到一种工业窑炉有机烟气焚烧、脱硫、除尘及脱硝的生产工艺及设备。The invention belongs to the field of industrial thermal equipment, and in particular relates to a production process and equipment for incineration, desulfurization, dust removal and denitrification of organic smoke from industrial kilns.

背景技术Background technique

近年来,工业窑炉的数量和规模不断扩大,现有的工业窑炉烟气直接排放或简易处理后排放,有的排放烟气中仍然含有有机物、有的排放烟气中硫超标、有的排放烟气中粉尘颗粒物超标、有的排放烟气中氮氧化物超标。产生有机烟气的刺激性气味影响居民正常的生活,烟气中大量热量被浪费,烟气中硫元素的排放会形成酸雨,烟气中颗粒的粉尘排放会造成雾霾;烟气中的高浓度氮氧化物排放会造成地球生态系统失衡等问题。总之,烟气排放会导致冬季北方的雾霾、南方气候的反常等一系列问题产生,严重影响人类的居住环境。所以国家也日益重视排放、环保方面的管理,因此工业窑炉的一体化烟气治理工艺及设备迫在眉睫。In recent years, the number and scale of industrial kilns have continued to expand. Existing industrial kilns directly discharge flue gas or discharge it after simple treatment. Some of the flue gas still contains organic matter, some of the flue gas contains excessive sulfur, some of the flue gas contains excessive dust particles, and some of the flue gas contains excessive nitrogen oxides. The pungent smell of organic flue gas affects the normal life of residents, a large amount of heat in the flue gas is wasted, the emission of sulfur elements in the flue gas will form acid rain, and the emission of particulate dust in the flue gas will cause haze; high concentrations of nitrogen oxides in the flue gas will cause problems such as imbalance in the earth's ecosystem. In short, flue gas emissions will cause a series of problems such as haze in the north in winter and abnormal climate in the south, which seriously affect the living environment of human beings. Therefore, the country is also paying more and more attention to the management of emissions and environmental protection, so the integrated flue gas treatment process and equipment of industrial kilns are imminent.

发明内容Summary of the invention

本发明的目的是为市场提供一种结构合理、运行安全、综合利用、一体净化、节能环保的有机烟气焚烧、脱硫、除尘及脱硝的生产工艺及设备。The purpose of the present invention is to provide the market with a production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification with reasonable structure, safe operation, comprehensive utilization, integrated purification, energy saving and environmental protection.

本发明的技术方案是:它是通过焚烧炉对烟气中的有机物进行二次燃烧,并对燃烧后的高温烟气进行余热利用,然后通过脱硫、除尘、脱硝等工艺对焚烧后的烟气进一步处理,使其达到排放标准后排入空中,其具体步骤如下:The technical solution of the present invention is: it uses an incinerator to perform secondary combustion on organic matter in the flue gas, and utilizes the waste heat of the high-temperature flue gas after combustion, and then further treats the flue gas after combustion through processes such as desulfurization, dust removal, and denitrification, so that it meets the emission standards and is discharged into the air. The specific steps are as follows:

(1)利用焚烧炉对烟气中的有机物进行二次焚烧使烟气中的有机物完全燃烧;(1) Use an incinerator to perform secondary incineration on the organic matter in the flue gas so that the organic matter in the flue gas is completely burned;

(2)将高温烟气通过空气换热器对焚烧炉的助燃风进行预热,将常温助燃风预热至450℃,将高温风送往焚烧炉助燃(理论及实践证明,助燃风每提高100℃,可节约燃料5%);(2) Preheat the combustion air of the incinerator by passing the high-temperature flue gas through an air heat exchanger, preheat the normal-temperature combustion air to 450°C, and send the high-temperature air to the incinerator for combustion (theoretical and practical results show that for every 100°C increase in the combustion air temperature, 5% of fuel can be saved);

(3)利用导热油换热器将高温烟气携带的热量对导热油进行预热,将常温导热油预热至180℃,然后输送至工业、能源、化工等行业使用;(3) Use the heat transfer oil heat exchanger to preheat the heat transfer oil with the heat carried by the high-temperature flue gas, preheat the normal temperature heat transfer oil to 180°C, and then transport it to the industry, energy, chemical industry and other industries for use;

(4)利用空空换热器将高温烟气对常温空气进行预热,预热至450℃,热风可用于车间采暖、产品干燥等;(4) Use air-to-air heat exchangers to preheat the high-temperature flue gas to 450°C. The hot air can be used for workshop heating, product drying, etc.

(5)烟气中的硫及硫的化合物,利用脱硫装置,采用小苏打干法脱硫工艺,通过化学吸附去除烟气中的酸性污染物;(5) Sulfur and sulfur compounds in flue gas are removed by chemical adsorption using a desulfurization device and a baking soda dry desulfurization process;

(6)采用烟气除尘装置对脱硫后的烟气进行除尘,当含尘气体进入膜袋式除尘器时,由于重力的作用,比膜袋式除尘器更大、更重的粉尘沉降,落入灰斗中,通过滤料富含细尘气体,粉尘被堵塞,从而使净化后的气体进入脱后续工序;(6) Use flue gas dust removal equipment to remove dust from the flue gas after desulfurization. When the dust-laden gas enters the membrane bag filter, due to the effect of gravity, the dust that is larger and heavier than the membrane bag filter settles and falls into the ash hopper. The fine dust-rich gas passes through the filter material, and the dust is blocked, so that the purified gas enters the subsequent process of desulfurization;

(7)脱硫除尘后的烟气进入脱硝装置后,采用催化还原SCR法脱硝,利用氨、CO或碳氢化合物等作为还原剂,在氧气存在的条件下将烟气中的NO还原为N2;(7) After the flue gas after desulfurization and dust removal enters the denitrification device, the catalytic reduction SCR method is used for denitrification. Ammonia, CO or hydrocarbons are used as reducing agents to reduce NO in the flue gas to N2 in the presence of oxygen;

(8)利用排烟引风机将治理后的烟气进行排空,并且排烟引风机入口设有自动配冷风系统,保护排烟引风机。(8) The treated smoke is exhausted by a smoke exhaust fan, and an automatic cooling air system is provided at the inlet of the smoke exhaust fan to protect the smoke exhaust fan.

有机烟气焚烧、脱硫、除尘及脱硝的生产设备包括窑炉、排烟气管道、余热回收利用装置、脱硫装置、除尘装置和脱硝装置。在排烟气管道出口处的窑炉上方增设了焚烧炉,该焚烧炉的排烟管经过空气换热器通过弯管接头连接余热回收利用装置,余热利用回收装置的烟气出口管与脱硫装置的烟气进口管相连,脱硫装置的烟气出口通过连接管道与除尘装置的烟气进口管相连,除尘装置的烟气出口管通过管道与脱硝装置的烟气进口管相连,经过脱硝后的净化烟气通过排烟引风机送入排烟管道后自烟囱排入空中。The production equipment for incineration, desulfurization, dust removal and denitrification of organic flue gas includes a kiln, a flue gas pipeline, a waste heat recovery device, a desulfurization device, a dust removal device and a denitrification device. An incinerator is added above the kiln at the outlet of the flue gas pipeline. The flue gas exhaust pipe of the incinerator is connected to the waste heat recovery device through an air heat exchanger and a elbow joint. The flue gas outlet pipe of the waste heat recovery device is connected to the flue gas inlet pipe of the desulfurization device. The flue gas outlet of the desulfurization device is connected to the flue gas inlet pipe of the dust removal device through a connecting pipe. The flue gas outlet pipe of the dust removal device is connected to the flue gas inlet pipe of the denitrification device through a pipe. The purified flue gas after denitrification is sent into the flue gas pipeline through the exhaust fan and then discharged into the air from the chimney.

进一步的,所述焚烧炉是由“L”形圆筒炉体、大调节比烧嘴、导流中心柱、导流缩口和排烟管构成,“L”形圆筒炉体是在金属外壳内填耐火保温材料制作而成,其水平长筒体通过支撑座固定安装在窑炉顶部,垂直短筒体的端部设置了有机烟气入口与窑炉排烟气管道相连,导流中心柱垂直安装在垂直短筒体的中心,并在其对应的筒体上交错、沿切线方向安装大调节比烧嘴Ⅰ,在水平长筒体中部设置了导流缩口,并在该导流缩口后方的筒体上沿切线方向安装大调节比烧嘴Ⅱ,尾部设置了蜂窝陶隔墙,对炉内烟气进行导向,使之均匀通过内腔,末端排烟管经过空气换热器通过弯管接头与设置在地平面上的余热回收利用装置相连。Furthermore, the incinerator is composed of an "L"-shaped cylindrical furnace body, a large adjustment ratio burner, a guide center column, a guide constriction and a smoke exhaust pipe. The "L"-shaped cylindrical furnace body is made of a metal shell filled with refractory insulation material. The horizontal long cylinder is fixedly installed on the top of the kiln through a support seat. An organic smoke inlet is arranged at the end of the vertical short cylinder and is connected to the kiln smoke exhaust pipe. The guide center column is vertically installed at the center of the vertical short cylinder, and large adjustment ratio burners I are installed on the corresponding cylinder in an alternating and tangential direction. A guide constriction is arranged in the middle of the horizontal long cylinder, and a large adjustment ratio burner II is installed on the cylinder behind the guide constriction along the tangential direction. A honeycomb ceramic partition wall is arranged at the tail to guide the smoke in the furnace so that it passes through the inner cavity evenly. The terminal smoke exhaust pipe is connected to the waste heat recovery and utilization device arranged on the ground plane through an air heat exchanger and a bend pipe joint.

进一步的,在焚烧炉体设置导流缩口的前后水平筒体上分别设置了防爆/检修门,该防爆/检修门设置在筒体向上呈45º夹角处,并在筒体外壳对应处设置了防护栏。Furthermore, explosion-proof/maintenance doors are respectively provided on the front and rear horizontal cylinders of the incinerator body where the diversion constriction is provided. The explosion-proof/maintenance doors are provided at an angle of 45° upwards from the cylinder, and a guardrail is provided at a corresponding position of the cylinder shell.

进一步的,所述余热回收利用装置是由导热油换热器和空空换热器构成,所述导热油换热器的烟气进口与连接弯管接头的烟气管道相连,其烟气出口通过管道与空空换热器的烟气进口相连,空空换热器的烟气出口通过管道与脱硫装置的烟气进口相连。Furthermore, the waste heat recovery and utilization device is composed of a heat transfer oil heat exchanger and an air-to-air heat exchanger. The flue gas inlet of the heat transfer oil heat exchanger is connected to the flue gas pipe connected to the elbow joint, and its flue gas outlet is connected to the flue gas inlet of the air-to-air heat exchanger through a pipe, and the flue gas outlet of the air-to-air heat exchanger is connected to the flue gas inlet of the desulfurization device through a pipe.

进一步的,在导热油换热器处设置了旁路管道Ⅰ,并安装3套自动阀门,可以实现在线维护设备,而不影响整套生产线;在空空换热器旁设置了旁路管道Ⅱ,亦安装3套自动阀门,可以实现在线维护设备,而不影响整套生产线。Furthermore, a bypass pipe I was set up at the thermal oil heat exchanger, and 3 sets of automatic valves were installed, so that the equipment can be maintained online without affecting the entire production line; a bypass pipe II was set up next to the air-to-air heat exchanger, and 3 sets of automatic valves were also installed, so that the equipment can be maintained online without affecting the entire production line.

更进一步的,所述脱硫装置采用小苏打干法脱硫工艺;所述除尘装置采用金属膜袋式除尘器将烟气中的颗粒物质进行回收;所述脱硝装置采用选择性催化还原方法,该反应发生在装有催化剂的反应器里,烟气与喷入的氨在催化剂的作用下反应,实现脱出氮氧化合物,其中还原剂采用30%尿素溶液,催化剂采用SCR中低温催化剂。Furthermore, the desulfurization device adopts a baking soda dry desulfurization process; the dust removal device adopts a metal membrane bag dust collector to recover particulate matter in the flue gas; the denitrification device adopts a selective catalytic reduction method, and the reaction occurs in a reactor equipped with a catalyst. The flue gas reacts with the injected ammonia under the action of the catalyst to remove nitrogen oxides, wherein the reducing agent uses a 30% urea solution and the catalyst uses an SCR medium and low temperature catalyst.

本发明的有益效果是:由于将有机烟气进行二次焚烧后,通过脱硫、除尘、脱硝等工序使排放到空中的烟气符合排放标准,可广泛适用于工业窑炉烟气净化或生产过程中产生有机物、碳氢化合物、粉尘、二氧化硫及氮氧化物等污染物,是一种治理多污染物气体的综合方法。可实现对有机物、粉尘、二氧化硫及氮氧化物等污染物的彻底治理,尤其是涉及到处理各类成分复杂的烟气,工艺及设备稳定性高,设备及管道杜绝二次污染,自动化程度高,设备的布置及维护人性化等优点,使得工业窑炉企业的烟气排放的环保问题得到解决,具有广泛的实际应用价值。The beneficial effects of the present invention are as follows: after the organic flue gas is incinerated for the second time, the flue gas discharged into the air meets the emission standards through processes such as desulfurization, dust removal, and denitrification, and can be widely used in industrial kiln flue gas purification or production processes to produce organic matter, hydrocarbons, dust, sulfur dioxide, nitrogen oxides and other pollutants, and is a comprehensive method for treating multi-pollutant gases. It can achieve thorough treatment of pollutants such as organic matter, dust, sulfur dioxide and nitrogen oxides, especially when it comes to treating flue gas with complex components. It has the advantages of high process and equipment stability, no secondary pollution in equipment and pipelines, high degree of automation, and humanized equipment layout and maintenance, so that the environmental protection problem of flue gas emissions of industrial kiln enterprises is solved, and has a wide range of practical application value.

下面结合附图对本发明作进一步说明。The present invention will be further described below in conjunction with the accompanying drawings.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1为本发明工艺流程方框图;Fig. 1 is a flow chart of the process of the present invention;

图2为本发明俯视结构示意图;FIG2 is a schematic diagram of the top view of the structure of the present invention;

图3为本发明焚烧炉立面结构示意图;FIG3 is a schematic diagram of the vertical structure of the incinerator of the present invention;

图4为本发明焚烧炉俯视结构示意图;FIG4 is a schematic diagram of the top view of the incinerator of the present invention;

图5为本发明左视导流中心柱截面结构示意图;FIG5 is a schematic diagram of the cross-sectional structure of the guide center column of the present invention when viewed from the left;

图6为本发明导热油换热器主视结构示意图;FIG6 is a schematic diagram of the front view of the heat transfer oil heat exchanger of the present invention;

图7为本发明导热油换热器左视结构示意图;FIG7 is a schematic diagram of the left side structure of the heat transfer oil heat exchanger of the present invention;

图8为本发明导热油换热器俯视结构示意图;FIG8 is a schematic diagram of the top view of the heat transfer oil heat exchanger of the present invention;

图9为本发明空空换热器主视结构示意图;FIG9 is a schematic diagram of the front view of the air-to-air heat exchanger of the present invention;

图10为本发明空空换热器左视结构示意图;FIG10 is a left-side structural schematic diagram of the air-to-air heat exchanger of the present invention;

图11为本发明空空换热器俯视结构示意图;FIG11 is a schematic diagram of the top view of the air-to-air heat exchanger of the present invention;

图12为本发明脱硫、除尘、脱硝主视结构示意图;FIG12 is a schematic diagram of the main structure of the desulfurization, dust removal and denitrification of the present invention;

图13为本发明脱硫、除尘、脱硝左视结构示意图。FIG13 is a left-side structural schematic diagram of the desulfurization, dust removal and denitrification system of the present invention.

图中:1为窑炉,2为焚烧炉,3为空气换热器,4为烟气管道,5为导热油换热器,6为旁路管道Ⅰ,7为空空换热器,8为旁路管道Ⅱ,9为脱硫装置,10为除尘装置,11为脱硝装置,12为排烟管道,13为排烟引风机,14为烟囱,15为外壳,16为耐火保温材料,17为炉内腔,18为支撑座,19为导流中心柱,20为大调节比烧嘴Ⅰ,21为有机烟气入口,22为防爆/检修门,23为导流缩口,24为大调节比烧嘴Ⅱ,25为蜂窝陶隔墙,26为排烟管,27为烟气进口Ⅰ,28为烟气出口Ⅰ,29为导热油入口,30为导热油出口,31为油管,32为烟气进口Ⅱ,33为烟气出口Ⅱ,34为冷空气入口,35为热空气出口,36为清灰孔,37为烟气进口Ⅲ,38为小苏打喷入口,39为连接管道,40为灰斗,41为管道。In the figure: 1 is a kiln, 2 is an incinerator, 3 is an air heat exchanger, 4 is a flue gas duct, 5 is a heat transfer oil heat exchanger, 6 is a bypass duct I, 7 is an air-to-air heat exchanger, 8 is a bypass duct II, 9 is a desulfurization device, 10 is a dust removal device, 11 is a denitrification device, 12 is a smoke exhaust duct, 13 is a smoke exhaust induced draft fan, 14 is a chimney, 15 is an outer shell, 16 is a refractory insulation material, 17 is a furnace cavity, 18 is a support seat, 19 is a guide center column, 20 is a large adjustment ratio burner I, 21 is an organic smoke inlet, 22 is an explosion-proof/maintenance door, 23 is a flow guide shrinkage, 24 is a large adjustment ratio burner II, 25 is a honeycomb ceramic partition wall, 26 is a smoke exhaust pipe, 27 is a smoke inlet I, 28 is a smoke outlet I, 29 is a heat transfer oil inlet, 30 is a heat transfer oil outlet, 31 is an oil pipe, 32 is a smoke inlet II, 33 is a smoke outlet II, 34 is a cold air inlet, 35 is a hot air outlet, 36 is a ash cleaning hole, 37 is a smoke inlet III, 38 is a baking soda spray inlet, 39 is a connecting pipe, 40 is an ash hopper, and 41 is a pipe.

具体实施方式Detailed ways

有机烟气焚烧、脱硫、除尘及脱硝的生产工艺是通过焚烧炉对烟气中的有机物进行二次燃烧,并对燃烧后的高温烟气进行余热利用,然后通过脱硫、除尘、脱硝等工艺对焚烧后的烟气进一步处理,使其达到排放标准后排入空中,其具体步骤如下:The production process of organic flue gas incineration, desulfurization, dust removal and denitrification is to conduct secondary combustion of organic matter in the flue gas through the incinerator, and utilize the waste heat of the high-temperature flue gas after combustion, and then further treat the flue gas after incineration through desulfurization, dust removal, denitrification and other processes to make it meet the emission standards and then be discharged into the air. The specific steps are as follows:

(1)利用焚烧炉对烟气中的有机物进行二次焚烧使烟气中的有机物完全燃烧;(1) Use an incinerator to perform secondary incineration on the organic matter in the flue gas so that the organic matter in the flue gas is completely burned;

(2)将高温烟气通过空气换热器对焚烧炉的助燃风进行预热,将常温助燃风预热至450℃,将高温风送往焚烧炉助燃(理论及实践证明,助燃风每提高100℃,可节约燃料5%);(2) Preheat the combustion air of the incinerator by passing the high-temperature flue gas through an air heat exchanger, preheat the normal-temperature combustion air to 450°C, and send the high-temperature air to the incinerator for combustion (theoretical and practical results show that for every 100°C increase in the combustion air temperature, 5% of fuel can be saved);

(3)利用导热油换热器将高温烟气携带的热量对导热油进行预热,将常温导热油预热至180℃,然后输送至工业、能源、化工等行业使用;(3) Use the heat transfer oil heat exchanger to preheat the heat transfer oil with the heat carried by the high-temperature flue gas, preheat the normal temperature heat transfer oil to 180°C, and then transport it to the industry, energy, chemical industry and other industries for use;

(4)利用空空换热器将高温烟气对常温空气进行预热,预热至450℃,热风可用于车间采暖、产品干燥等;(4) Use air-to-air heat exchangers to preheat the high-temperature flue gas to 450°C. The hot air can be used for workshop heating, product drying, etc.

(5)烟气中的硫及硫的化合物,利用脱硫装置,采用小苏打干法脱硫工艺,通过化学吸附去除烟气中的酸性污染物;(5) Sulfur and sulfur compounds in flue gas are removed by chemical adsorption using a desulfurization device and a baking soda dry desulfurization process;

(6)采用烟气除尘装置对脱硫后的烟气进行除尘,当含尘气体进入膜袋式除尘器时,由于重力的作用,比膜袋式除尘器更大、更重的粉尘沉降,落入灰斗中,通过滤料富含细尘气体,粉尘被堵塞,从而使净化后的气体进入脱后续工序;(6) Use flue gas dust removal equipment to remove dust from the flue gas after desulfurization. When the dust-laden gas enters the membrane bag filter, due to the effect of gravity, the dust that is larger and heavier than the membrane bag filter settles and falls into the ash hopper. The fine dust-rich gas passes through the filter material, and the dust is blocked, so that the purified gas enters the subsequent process of desulfurization;

(7)脱硫除尘后的烟气进入脱硝装置后,采用催化还原SCR法脱硝,利用氨、CO或碳氢化合物等作为还原剂,在氧气存在的条件下将烟气中的NO还原为N2;(7) After the flue gas after desulfurization and dust removal enters the denitrification device, the catalytic reduction SCR method is used for denitrification. Ammonia, CO or hydrocarbons are used as reducing agents to reduce NO in the flue gas to N2 in the presence of oxygen;

(8)利用排烟引风机将治理后的烟气进行排空,并且排烟引风机入口设有自动配冷风系统,保护排烟引风机。(8) The treated smoke is exhausted by a smoke exhaust fan, and an automatic cooling air system is provided at the inlet of the smoke exhaust fan to protect the smoke exhaust fan.

如图所示:有机烟气焚烧、脱硫、除尘及脱硝的生产设备包括窑炉1、排烟气管道、余热回收利用装置、脱硫装置、除尘装置和脱硝装置等,在排烟气管道出口处的窑炉1上方增设了焚烧炉2,该焚烧炉2的排烟管26经过空气换热器3通过弯管接头连接余热回收利用装置,余热利用回收装置的烟气出口管与脱硫装置9的烟气进口Ⅲ37相连,脱硫装置9的烟气出口通过连接管道39与除尘装置10的烟气进口管相连,除尘装置10的烟气出口管通过管道41与脱硝装置11的烟气进口管相连,经过脱硝后的净化烟气通过排烟引风机13送入排烟管道12后自烟囱14排入空中。所述焚烧炉2是由“L”形圆筒炉体、大调节比烧嘴、导流中心柱19、导流缩口23和排烟管26构成,“L”形圆筒炉体是在外壳15内填耐火保温材料(16)制作而成,其水平长筒体通过支撑座18固定安装在窑炉1顶部,垂直短筒体的端部设置了有机烟气入口21与窑炉排烟气管道相连,导流中心柱19垂直安装在垂直短筒体的中心,并在其对应的筒体上交错、沿切线方向安装大调节比烧嘴Ⅰ20,在水平长筒体中部设置了导流缩口23,并在该导流缩口后方的筒体上沿切线方向安装大调节比烧嘴Ⅱ24,尾部设置了蜂窝陶隔墙25,对炉内烟气进行导向,使之均匀通过内腔,末端排烟管26经过空气换热器3通过弯管接头与设置在地平面上的余热回收利用装置相连。在焚烧炉体设置导流缩口23的前后水平筒体上分别设置了防爆/检修门22,该防爆/检修门22设置在筒体向上呈45º夹角处,并在外壳15对应处设置了防护栏。所述余热回收利用装置是由导热油换热器5和空空换热器7构成,所述导热油换热器5的烟气进口Ⅰ27与连接弯管接头的烟气管道4相连,其烟气出口Ⅰ28通过管道与空空换热器7的烟气进口Ⅱ32相连,空空换热器7的烟气出口Ⅱ33通过管道与脱硫装置的烟气进口Ⅲ37相连。并在导热油换热器5处设置了旁路管道Ⅰ6,在空空换热器7旁设置了旁路管道Ⅱ8。所述脱硫装置9采用小苏打干法脱硫工艺;所述除尘装置10采用金属膜袋式除尘器将烟气中的颗粒物质进行回收;所述脱硝装置11采用选择性催化还原方法,该反应发生在装有催化剂的反应器里,烟气与喷入的氨在催化剂的作用下反应,实现脱出氮氧化合物,其中还原剂采用30%尿素溶液,催化剂采用SCR中低温催化剂。As shown in the figure: the production equipment for incineration, desulfurization, dust removal and denitrification of organic flue gas includes a kiln 1, an exhaust gas pipeline, a waste heat recovery device, a desulfurization device, a dust removal device and a denitrification device, etc. An incinerator 2 is added above the kiln 1 at the outlet of the exhaust gas pipeline. The exhaust pipe 26 of the incinerator 2 is connected to the waste heat recovery device through an elbow joint through an air heat exchanger 3. The flue gas outlet pipe of the waste heat recovery device is connected to the flue gas inlet III 37 of the desulfurization device 9. The flue gas outlet of the desulfurization device 9 is connected to the flue gas inlet pipe of the dust removal device 10 through a connecting pipe 39. The flue gas outlet pipe of the dust removal device 10 is connected to the flue gas inlet pipe of the denitrification device 11 through a pipe 41. The purified flue gas after denitrification is sent into the exhaust pipe 12 through the exhaust induced draft fan 13 and then discharged into the air from the chimney 14. The incinerator 2 is composed of an "L"-shaped cylindrical furnace body, a large adjustment ratio burner, a guide center column 19, a guide constriction 23 and a smoke exhaust pipe 26. The "L"-shaped cylindrical furnace body is made by filling a refractory heat-insulating material (16) in an outer shell 15. Its horizontal long cylinder is fixedly installed on the top of the kiln 1 through a support seat 18. An organic smoke inlet 21 is arranged at the end of the vertical short cylinder and is connected to the kiln smoke exhaust pipe. The guide center column 19 is vertically installed at the center of the vertical short cylinder, and a large adjustment ratio burner I 20 is staggered and installed on the corresponding cylinder along the tangential direction. A guide constriction 23 is arranged in the middle of the horizontal long cylinder, and a large adjustment ratio burner II 24 is installed on the cylinder behind the guide constriction along the tangential direction. A honeycomb ceramic partition wall 25 is arranged at the tail to guide the smoke in the furnace so that it passes through the inner cavity evenly. The end smoke exhaust pipe 26 is connected to the waste heat recovery and utilization device arranged on the ground plane through the air heat exchanger 3 and a bend pipe joint. Explosion-proof/inspection doors 22 are respectively provided on the front and rear horizontal cylinders of the incinerator body where the flow constriction 23 is provided. The explosion-proof/inspection doors 22 are provided at an angle of 45° upward from the cylinder, and a guardrail is provided at the corresponding position of the shell 15. The waste heat recovery device is composed of a heat transfer oil heat exchanger 5 and an air-to-air heat exchanger 7. The flue gas inlet Ⅰ27 of the heat transfer oil heat exchanger 5 is connected to the flue gas pipe 4 connected to the elbow joint, and its flue gas outlet Ⅰ28 is connected to the flue gas inlet Ⅱ32 of the air-to-air heat exchanger 7 through a pipe, and the flue gas outlet Ⅱ33 of the air-to-air heat exchanger 7 is connected to the flue gas inlet Ⅲ37 of the desulfurization device through a pipe. A bypass pipe Ⅰ6 is provided at the heat transfer oil heat exchanger 5, and a bypass pipe Ⅱ8 is provided next to the air-to-air heat exchanger 7. The desulfurization device 9 adopts a baking soda dry desulfurization process; the dust removal device 10 adopts a metal membrane bag dust collector to recover particulate matter in the flue gas; the denitrification device 11 adopts a selective catalytic reduction method, which occurs in a reactor equipped with a catalyst. The flue gas reacts with the injected ammonia under the action of the catalyst to remove nitrogen oxides, wherein the reducing agent uses a 30% urea solution and the catalyst uses an SCR medium and low temperature catalyst.

以建造一条生产镁钙砖隧道窑烟气治理项目为例,它包括隧道窑1、焚烧炉2、空气换热器3、导热油换热器5、空空换热器7、脱硫装置9、除尘装置10、脱硝装置11、排烟管道12和排烟引风机13等设备组成。隧道窑煅烧制品产生的烟气,通过预热带侧墙的排烟洞然后在窑顶支烟道汇总,从焚烧炉2垂直端底部设置的有机烟气入口21送入,经过焚烧炉二级焚烧完全,产生的高温烟气通过空气换热器3将常温空气预热至450℃,将450℃热风送去焚烧炉2上设置的大调节比烧嘴助燃,高温烟气继续通过弯管接头连接的烟气管道4送往下道工序,利用高温烟气的热量对流经导热油换热器5内的导热油进行预热,将常温导热油预热至180℃,然后输送至工业、能源、化工等行业使用;中温烟气继续流往下道工序,经过空空换热器7,利用中温烟气对常温空气进行预热,预热至450℃,热风可用于车间采暖、产品干燥等;烟气继续流往下道工序,经过脱硫装置9,烟气中的硫及硫的化合物,采用小苏打干法脱硫,脱硫后形成的脱硫灰副产物进入除尘器收集下来,少部分通过返料槽进入脱硫塔循环利用,其余脱硫灰外排综合利用;烟气经过连接管道39流入除尘装置10,除尘装置10的气体净化方式为外滤式,含尘烟气由导流管进入各单元过滤室,并通过设备于灰斗中的烟气导流装置,由于设计中袋底离进风口上口垂直距离有足够、合理的净空,气流通过适当导流和自然流向分布,达到整个过滤室内气流分布均匀;含尘气体中的颗粒粉尘通过自然沉降分离后直接落入灰斗、其余粉尘在导流系统的引导下,随气流进入中箱体过滤区,吸附在除尘滤袋外表面;过滤除尘后的烟气经过脱硝装置11,该装置采用选择性催化还原方法,反应发生在装有催化剂的反应器里,烟气与喷入的氨在催化剂的作用下反应,实现脱出氮氧化合物;然后利用排烟引风机13将治理后的净化达标烟气送入排烟管道12后自烟囱排入空中,并且排烟引风机入口设有自动配冷风系统,保护排烟引风机。Take the construction of a tunnel kiln flue gas treatment project for producing magnesium-calcium bricks as an example, it includes a tunnel kiln 1, an incinerator 2, an air heat exchanger 3, a thermal oil heat exchanger 5, an air-to-air heat exchanger 7, a desulfurization device 9, a dust removal device 10, a denitrification device 11, a smoke exhaust duct 12 and a smoke exhaust fan 13. The smoke generated by the calcination of the products in the tunnel kiln passes through the smoke exhaust hole on the side wall of the preheating zone and then is collected in the branch flue on the top of the kiln. It is sent in from the organic smoke inlet 21 set at the bottom of the vertical end of the incinerator 2, and is completely incinerated in the second stage of the incinerator. The high-temperature smoke is preheated to 450°C by the air heat exchanger 3, and the 450°C hot air is sent to the large adjustment ratio burner set on the incinerator 2 for combustion assistance. The high-temperature smoke continues to be sent to the next process through the smoke duct 4 connected to the elbow joint, and the heat of the high-temperature smoke is convected through the heat transfer oil heat exchanger 5. The oil is preheated to 180°C, and then transported to the industry, energy, chemical industry and other industries for use; the medium-temperature flue gas continues to flow to the next process, passes through the air-to-air heat exchanger 7, and uses the medium-temperature flue gas to preheat the room-temperature air to 450°C. The hot air can be used for workshop heating, product drying, etc.; the flue gas continues to flow to the next process, passes through the desulfurization device 9, and the sulfur and sulfur compounds in the flue gas are desulfurized by baking soda dry method. The desulfurization ash by-product formed after desulfurization enters the dust collector for collection, and a small part enters the desulfurization through the return trough The flue gas flows into the dust removal device 10 through the connecting pipe 39. The gas purification method of the dust removal device 10 is external filtration. The dust-containing flue gas enters the filter chamber of each unit through the guide pipe and passes through the flue gas guide device installed in the ash hopper. Due to the vertical distance between the bottom of the bag and the upper mouth of the air inlet in the design, there is sufficient and reasonable clearance. The airflow is distributed through proper diversion and natural flow direction to achieve uniform airflow distribution in the entire filter chamber. The particulate dust in the dust-containing gas falls directly into the ash hopper after natural sedimentation separation, and the rest of the dust Under the guidance of the flow guide system, the dust enters the filtering area of the middle box along with the air flow and is adsorbed on the outer surface of the dust filter bag; the flue gas after filtering and dust removal passes through the denitrification device 11, which adopts a selective catalytic reduction method. The reaction occurs in a reactor equipped with a catalyst. The flue gas reacts with the injected ammonia under the action of the catalyst to remove nitrogen oxides; then the smoke exhaust fan 13 is used to send the treated purified flue gas that meets the standards into the smoke exhaust pipe 12 and then discharged into the air from the chimney, and an automatic cooling air distribution system is provided at the inlet of the smoke exhaust fan to protect the smoke exhaust fan.

本发明由于采用金属膜袋代替传统的布袋,不仅可以实现高温(350℃)除尘,而且解决了烟气除尘不到位,堵塞布袋及后续设备的隐患;(因烟气中可能含有石蜡等有机物,低温(90℃)时石蜡等有机物凝结,极易堵塞布袋)。多级余热回收利用装置(如焚烧炉助燃风预热系统、导热油换热系统、空空换热器系统等),实现烟气热量最大化利用;余热回收利用装置均配置旁路系统,即某设备故障时可在线更换,增强整个处理工艺及设备的稳定性和安全性。工艺的设计和设备的使用均以节能、环保为出发点;以低氮、环保排放为目的;是目前市场上工业窑炉领域烟气治理设备最为集中的一种生产工艺。Since the present invention uses metal film bags instead of traditional cloth bags, it can not only achieve high-temperature (350°C) dust removal, but also solves the hidden dangers of inadequate flue gas dust removal and clogging of cloth bags and subsequent equipment; (because the flue gas may contain organic matter such as paraffin, paraffin and other organic matter condense at low temperatures (90°C), which can easily clog the cloth bags). Multi-stage waste heat recovery and utilization devices (such as incinerator combustion air preheating system, thermal oil heat exchange system, air-to-air heat exchanger system, etc.) can maximize the utilization of flue gas heat; waste heat recovery and utilization devices are equipped with bypass systems, that is, they can be replaced online when a certain equipment fails, thereby enhancing the stability and safety of the entire processing process and equipment. The design of the process and the use of the equipment are based on energy saving and environmental protection; with low nitrogen and environmentally friendly emissions as the purpose; it is the most concentrated production process for flue gas treatment equipment in the field of industrial kilns on the market.

本发明所述有机烟气进入焚烧炉焚烧处理温度为800℃(因有机物成分不同,焚烧温度也有所区别);烟气焚烧炉的燃料可以是天然气,焦炉煤气,瓦斯气等其中的任意一种;余热利用设备包括空气换热器、导热油换热器,或者热水换热器等,但不限于以上设备。The organic flue gas of the present invention enters the incinerator for incineration at a temperature of 800°C (due to different organic components, the incineration temperature is also different); the fuel of the flue gas incinerator can be any one of natural gas, coke oven gas, and gas; the waste heat utilization equipment includes an air heat exchanger, a thermal oil heat exchanger, or a hot water heat exchanger, but is not limited to the above equipment.

Claims (6)

1. A production process for organic fume incineration, desulfurization, dust removal and denitration is characterized by comprising the following steps of: the organic matters in the flue gas are secondarily combusted through the incinerator, waste heat utilization is carried out on the combusted high-temperature flue gas, and then the incinerated flue gas is further treated through desulfurization, dust removal and denitration processes, so that the incinerated flue gas reaches the emission standard and is discharged into the air, and the method comprises the following specific steps:
(1) The incinerator is utilized to carry out secondary incineration on the organic matters in the flue gas so as to enable the organic matters in the flue gas to be completely combusted;
(2) Preheating combustion-supporting air of the incinerator by high-temperature flue gas through an air heat exchanger, preheating normal-temperature combustion-supporting air to 450 ℃, and delivering the high-temperature air to the incinerator for combustion supporting;
(3) Preheating heat conducting oil by utilizing a heat conducting oil heat exchanger, preheating normal-temperature heat conducting oil to 180 ℃, and then conveying the heat conducting oil to industries, energy sources and chemical industries for use;
(4) Preheating the high-temperature flue gas to the temperature of 450 ℃ by utilizing an air-air heat exchanger, wherein hot air can be used for workshop heating and product drying;
(5) Sulfur and sulfur compounds in the flue gas are removed by chemical adsorption by using a desulfurization device and adopting a baking soda dry desulfurization process;
(6) The flue gas dust removal device is adopted to remove dust from the desulfurized flue gas, when the dust-containing gas enters the membrane bag type dust remover, the dust larger and heavier than the membrane bag type dust remover is settled due to the action of gravity and falls into the ash bucket, and the dust is filled with fine dust-containing gas through the filter material, so that the purified gas enters the subsequent process;
(7) After the flue gas subjected to desulfurization and dust removal enters a denitration device, denitration is performed by adopting a catalytic reduction SCR method, ammonia, CO or hydrocarbon is used as a reducing agent, and NO in the flue gas is reduced into N2 in the presence of oxygen;
(8) The smoke after treatment is exhausted by using the smoke exhaust induced draft fan, and an automatic cold air distribution system is arranged at the inlet of the smoke exhaust induced draft fan to protect the smoke exhaust induced draft fan.
2. The utility model provides a production facility that organic flue gas burns, desulfurization, dust removal and denitration, it includes kiln (1), exhaust gas pipeline, waste heat recovery device, desulphurization unit, dust collector and denitrification facility, its characterized in that: an incinerator (2) is additionally arranged above a kiln (1) at the outlet of a smoke exhaust pipeline, the incinerator (2) is composed of an L-shaped cylindrical furnace body, a large-adjustment-ratio burner, a flow guiding central column (19), a flow guiding shrinkage port (23) and a smoke exhaust pipe (26), the L-shaped cylindrical furnace body is formed by filling a shell (15) with a fireproof heat insulation material (16), a horizontal long cylinder body of the L-shaped cylindrical furnace body is fixedly arranged at the top of the kiln (1) through a supporting seat (18), an organic smoke inlet (21) is arranged at the end part of a vertical short cylinder body and is connected with the smoke exhaust pipeline of the kiln, the flow guiding central column (19) is vertically arranged at the center of the vertical short cylinder body, the corresponding cylinder body is staggered, the large-adjustment-ratio burner I (20) is arranged in the tangential direction, the middle part of the horizontal long cylinder body is provided with a flow guiding shrinkage port (23), the cylinder body behind the flow guiding shrinkage port is arranged in the tangential direction, the tail part is provided with a honeycomb Tao Geqiang (25), the smoke in the kiln uniformly passes through an inner cavity, and the tail end smoke exhaust pipe (26) is connected with a waste heat recycling device through an elbow pipe (3) and is connected with a waste heat recycling device; the flue gas outlet pipe of the waste heat utilization recovery device is connected with a flue gas inlet III (37) of the desulfurization device (9), the flue gas outlet of the desulfurization device (9) is connected with a flue gas inlet pipe of the dust removal device (10) through a connecting pipeline (39), the flue gas outlet pipe of the dust removal device (10) is connected with a flue gas inlet pipe of the denitration device (11) through a pipeline (41), and purified flue gas after denitration is sent into a flue gas exhaust pipeline (12) through a flue gas exhaust draught fan (13) and then discharged into the air from a chimney (14).
3. The production equipment for organic fume incineration, desulfurization, dust removal and denitration according to claim 2, which is characterized in that: an explosion-proof/access door (22) is respectively arranged on the front horizontal cylinder body and the rear horizontal cylinder body of the incinerator body, the flow-guiding shrinkage opening (23) is arranged on the incinerator body, the explosion-proof/access door (22) is arranged at an included angle of 45 degrees upwards of the cylinder body, and a protective guard is arranged at the corresponding position of the shell (15).
4. A production facility for incineration, desulfurization, dust removal and denitration of organic fumes according to claim 2 or 3, characterised in that: the waste heat recycling device is composed of a heat conducting oil heat exchanger (5) and an air-air heat exchanger (7), a flue gas inlet I (27) of the heat conducting oil heat exchanger (5) is connected with a flue gas pipeline (4) connected with an elbow joint, a flue gas outlet I (28) of the heat conducting oil heat exchanger is connected with a flue gas inlet II (32) of the air-air heat exchanger (7) through a pipeline, and a flue gas outlet II (33) of the air-air heat exchanger (7) is connected with a flue gas inlet III (37) of the desulfurization device through a pipeline.
5. The production equipment for organic fume incineration, desulfurization, dust removal and denitration according to claim 4, wherein: a bypass pipeline I (6) is arranged at the heat conducting oil heat exchanger (5), and a bypass pipeline II (8) is arranged beside the air-air heat exchanger (7).
6. The production equipment for organic fume incineration, desulfurization, dust removal and denitration according to claim 5, wherein: the desulfurization device (9) adopts a baking soda dry desulfurization process; the dust removing device (10) adopts a metal film bag type dust remover to recycle the particulate matters in the flue gas; the denitration device (11) adopts a selective catalytic reduction method, the reduction reaction occurs in a reactor filled with a catalyst, the flue gas reacts with sprayed ammonia under the action of the catalyst to reduce oxynitride, wherein a 30% urea solution is adopted as a reducing agent, and an SCR medium-low temperature catalyst is adopted as the catalyst.
CN201911289741.5A 2019-12-16 2019-12-16 Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification Active CN110833763B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911289741.5A CN110833763B (en) 2019-12-16 2019-12-16 Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911289741.5A CN110833763B (en) 2019-12-16 2019-12-16 Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification

Publications (2)

Publication Number Publication Date
CN110833763A CN110833763A (en) 2020-02-25
CN110833763B true CN110833763B (en) 2024-05-31

Family

ID=69578711

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911289741.5A Active CN110833763B (en) 2019-12-16 2019-12-16 Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification

Country Status (1)

Country Link
CN (1) CN110833763B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113883530B (en) * 2020-07-01 2024-01-26 唐山惠川环保科技有限公司 Distributed comprehensive flue gas purification process system
CN112357891B (en) * 2020-10-22 2023-03-17 山东省冶金设计院股份有限公司 Method for shortening start-up time of desulfurization waste liquid and sulfur foam acid making
CN112263911B (en) * 2020-10-30 2025-03-18 南京依涛环保科技有限公司 Gas furnace ammonia-free low-temperature denitration device and method
CN112691540B (en) * 2020-12-15 2024-12-03 中冶京诚工程技术有限公司 Ultra-clean emission system for synergistic treatment of VOCs-containing waste gas and coke oven flue gas
CN113251813B (en) * 2021-06-25 2024-12-10 宁波太极环保设备有限公司 Incineration type flue gas purification system and method
CN115435595A (en) * 2022-09-20 2022-12-06 黄冈市中洲安信窑炉有限公司 Silver catalyst activation system device
CN116139685A (en) * 2023-01-03 2023-05-23 中冶南方都市环保工程技术股份有限公司 Treatment equipment and treatment methods for flue gas pollutants from general industrial solid waste incineration

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006220366A (en) * 2005-02-10 2006-08-24 Jfe Steel Kk Exhaust gas preheating apparatus and exhaust gas preheating method
CN102393147A (en) * 2011-08-23 2012-03-28 中冶赛迪工程技术股份有限公司 Comprehensive processing process for sintering smoke gas
CN104984640A (en) * 2015-07-13 2015-10-21 广西博世科环保科技股份有限公司 Comprehensive purification process of glass kiln smoke
CN106352363A (en) * 2016-08-31 2017-01-25 吕宜德 Industrial boiler low-nitric-oxide combustion and environment protection system and technological method
CN107166977A (en) * 2017-06-23 2017-09-15 江苏省冶金设计院有限公司 A kind of closed vessel furnace furnace gas is reclaimed and cleaning treatment system
JP2017177046A (en) * 2016-03-31 2017-10-05 三菱重工業株式会社 Exhaust gas treatment method and system
CN108392956A (en) * 2017-02-05 2018-08-14 鞍钢股份有限公司 Desulfurization and denitrification system and method for coke oven flue gas
CN211514091U (en) * 2019-12-16 2020-09-18 黄冈市华窑中洲窑炉有限公司 Production equipment for burning, desulfurizing, dedusting and denitrifying organic flue gas of industrial kiln

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104296543A (en) * 2014-09-24 2015-01-21 中科苏派能源科技靖江有限公司 Denitration and waste heat recovery integrated furnace

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006220366A (en) * 2005-02-10 2006-08-24 Jfe Steel Kk Exhaust gas preheating apparatus and exhaust gas preheating method
CN102393147A (en) * 2011-08-23 2012-03-28 中冶赛迪工程技术股份有限公司 Comprehensive processing process for sintering smoke gas
CN104984640A (en) * 2015-07-13 2015-10-21 广西博世科环保科技股份有限公司 Comprehensive purification process of glass kiln smoke
JP2017177046A (en) * 2016-03-31 2017-10-05 三菱重工業株式会社 Exhaust gas treatment method and system
CN106352363A (en) * 2016-08-31 2017-01-25 吕宜德 Industrial boiler low-nitric-oxide combustion and environment protection system and technological method
CN108392956A (en) * 2017-02-05 2018-08-14 鞍钢股份有限公司 Desulfurization and denitrification system and method for coke oven flue gas
CN107166977A (en) * 2017-06-23 2017-09-15 江苏省冶金设计院有限公司 A kind of closed vessel furnace furnace gas is reclaimed and cleaning treatment system
CN211514091U (en) * 2019-12-16 2020-09-18 黄冈市华窑中洲窑炉有限公司 Production equipment for burning, desulfurizing, dedusting and denitrifying organic flue gas of industrial kiln

Also Published As

Publication number Publication date
CN110833763A (en) 2020-02-25

Similar Documents

Publication Publication Date Title
CN110833763B (en) Production process and equipment for organic flue gas incineration, desulfurization, dust removal and denitrification
CN109794146B (en) Grate-rotary kiln SNCR/SCR denitration and active coke desulfurization combined system and process
CN205145971U (en) Coke oven flue gas desulfurization denitration dust removal integration system
CN104174287B (en) Partial flue gas denitration system and method for sintering machine
CN206701058U (en) A kind of waste heat of coke-oven flue gas and desulphurization denitration dust pelletizing system
CN107879585B (en) Sludge resource utilization device and method
CN110437849A (en) dry quenching coke and coke oven flue gas combined purification process and system
CN209885578U (en) Dust removal SOx/NOx control takes off white integration system
CN112915724A (en) Integrated removal system and method for multiple pollutants in flue gas
CN116764377A (en) Ultralow emission treatment system and method for tail gas of oil-fired boiler
CN106123613A (en) A glass kiln fume deep purification process
CN109453591B (en) Carbon black waste gas treatment process
CN106925108A (en) A kind of waste heat of coke-oven flue gas and desulphurization denitration dust pelletizing system
CN209828672U (en) Grate-rotary kiln SNCR/SCR denitration and active coke desulfurization combined system
CN114307574A (en) Flue gas purification system applied to biomass power plant
CN109260947A (en) A kind of recuperative heater flue gas denitrification system of two-stage accumulation of heat
CN111895799A (en) A multi-pollutant collaborative treatment system for heating furnace exhaust gas
CN205619331U (en) Waste incineration flue gas environmental protection processing system
CN211514091U (en) Production equipment for burning, desulfurizing, dedusting and denitrifying organic flue gas of industrial kiln
CN211358356U (en) An ultra-clean treatment system for VOCs in the chemical recovery area of a coking plant
CN210568374U (en) Combustible waste gas replaces coal fired boiler combustion air's system of utilizing
CN210855981U (en) CDQ and coke oven flue gas combined purification system
CN208366101U (en) A kind of tube furnace flue gas desulfurization and denitrification system
CN110694460A (en) Ultra-clean treatment system and method for VOCs in chemical product recovery area of coking plant
CN219161015U (en) Ultralow emission system of cement kiln flue gas pollutant

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant