CN1844000A - Permanent self-cleaning glass with visible light responsibility and preparation method thereof - Google Patents
Permanent self-cleaning glass with visible light responsibility and preparation method thereof Download PDFInfo
- Publication number
- CN1844000A CN1844000A CN 200610035099 CN200610035099A CN1844000A CN 1844000 A CN1844000 A CN 1844000A CN 200610035099 CN200610035099 CN 200610035099 CN 200610035099 A CN200610035099 A CN 200610035099A CN 1844000 A CN1844000 A CN 1844000A
- Authority
- CN
- China
- Prior art keywords
- glass
- cleaning
- titanium dioxide
- self
- sputtering
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005348 self-cleaning glass Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims description 19
- 239000011521 glass Substances 0.000 claims abstract description 68
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000004140 cleaning Methods 0.000 claims abstract description 26
- 238000004544 sputter deposition Methods 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000005245 sintering Methods 0.000 claims abstract description 12
- 238000000137 annealing Methods 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 239000010408 film Substances 0.000 claims description 35
- 239000004408 titanium dioxide Substances 0.000 claims description 14
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000010409 thin film Substances 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 238000005477 sputtering target Methods 0.000 claims description 3
- 239000013077 target material Substances 0.000 claims description 3
- PWKWDCOTNGQLID-UHFFFAOYSA-N [N].[Ar] Chemical compound [N].[Ar] PWKWDCOTNGQLID-UHFFFAOYSA-N 0.000 claims description 2
- 239000005543 nano-size silicon particle Substances 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 18
- 230000001699 photocatalysis Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 7
- 238000007146 photocatalysis Methods 0.000 abstract description 7
- 230000005855 radiation Effects 0.000 abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000006378 damage Effects 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 230000004298 light response Effects 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000005406 washing Methods 0.000 description 5
- 239000006210 lotion Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- -1 tungsten ion Chemical class 0.000 description 3
- 238000004506 ultrasonic cleaning Methods 0.000 description 3
- 238000005253 cladding Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical group C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000001443 photoexcitation Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
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- Surface Treatment Of Glass (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100350994A CN100551858C (en) | 2006-04-21 | 2006-04-21 | A kind of have visible light-responded permanent self-cleaning glass and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100350994A CN100551858C (en) | 2006-04-21 | 2006-04-21 | A kind of have visible light-responded permanent self-cleaning glass and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN1844000A true CN1844000A (en) | 2006-10-11 |
CN100551858C CN100551858C (en) | 2009-10-21 |
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CNB2006100350994A Expired - Fee Related CN100551858C (en) | 2006-04-21 | 2006-04-21 | A kind of have visible light-responded permanent self-cleaning glass and preparation method thereof |
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102126831A (en) * | 2010-11-29 | 2011-07-20 | 常州国基能源科技有限公司 | Cover plate glass of solar receiver and preparation method thereof |
CN102168247A (en) * | 2011-04-15 | 2011-08-31 | 河南大学 | Preparation method and application of TiO2/WO3 composite film |
CN102225849A (en) * | 2011-04-21 | 2011-10-26 | 常州大学 | Preparation method of glass surface antireflection film without sintering |
CN102515566A (en) * | 2011-11-07 | 2012-06-27 | 中山市格兰特实业有限公司火炬分公司 | Magnetron sputtering self-cleaning glass with visible light response, and preparation method thereof |
CN102649623A (en) * | 2011-02-28 | 2012-08-29 | 中国科学院理化技术研究所 | Anti-reflection super-hydrophilic self-cleaning anti-fog glass and preparation method thereof |
CN102950843A (en) * | 2012-11-29 | 2013-03-06 | 大连创达技术交易市场有限公司 | Automotive glass with anti-fog and self-cleaning functions |
CN101806444B (en) * | 2009-02-14 | 2014-01-22 | 海洋王照明科技股份有限公司 | Artistic lamp and processing method thereof |
CN105603715A (en) * | 2014-10-31 | 2016-05-25 | 广东欣丰科技有限公司 | Fabric structure color preparation method |
CN107200580A (en) * | 2017-06-21 | 2017-09-26 | 佛山市钜仕泰粉末冶金有限公司 | A kind of optical nano ceramic insulation glass for strengthening visible light-transmissive and preparation method thereof |
CN107604311A (en) * | 2017-08-10 | 2018-01-19 | 酒泉职业技术学院 | A kind of preparation method of automatically cleaning solar thermal collector antireflective coating |
CN108126681A (en) * | 2016-12-01 | 2018-06-08 | 通用汽车环球科技运作有限责任公司 | For enhancing titanium dioxide(TiO2)The nucleating layer of the photocatalytic activity of coating |
CN108980771A (en) * | 2018-09-27 | 2018-12-11 | 华域视觉科技(上海)有限公司 | Photocatalytic self-cleaning car light and automobile |
CN109769529A (en) * | 2019-01-31 | 2019-05-21 | 铜仁学院 | A kind of oil tea cultivation temperature control green house |
CN110894138A (en) * | 2019-01-30 | 2020-03-20 | 中山大学 | Environment-friendly automobile glass |
CN113636760A (en) * | 2021-09-02 | 2021-11-12 | 青岛理工大学 | Antifogging self-cleaning glass and preparation method thereof |
CN117210155A (en) * | 2023-09-15 | 2023-12-12 | 精一门(常州)光学薄膜有限公司 | Self-cleaning anti-pollution energy-saving film for building and preparation method thereof |
-
2006
- 2006-04-21 CN CNB2006100350994A patent/CN100551858C/en not_active Expired - Fee Related
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101806444B (en) * | 2009-02-14 | 2014-01-22 | 海洋王照明科技股份有限公司 | Artistic lamp and processing method thereof |
CN102126831A (en) * | 2010-11-29 | 2011-07-20 | 常州国基能源科技有限公司 | Cover plate glass of solar receiver and preparation method thereof |
CN102126831B (en) * | 2010-11-29 | 2013-04-24 | 常州国基能源科技有限公司 | Preparation method of cover plate glass of solar receiver |
CN102649623B (en) * | 2011-02-28 | 2014-03-12 | 中国科学院理化技术研究所 | Anti-reflection super-hydrophilic self-cleaning anti-fog glass and preparation method thereof |
CN102649623A (en) * | 2011-02-28 | 2012-08-29 | 中国科学院理化技术研究所 | Anti-reflection super-hydrophilic self-cleaning anti-fog glass and preparation method thereof |
CN102168247B (en) * | 2011-04-15 | 2012-10-03 | 河南大学 | Preparation method and application of TiO2/WO3 composite film |
CN102168247A (en) * | 2011-04-15 | 2011-08-31 | 河南大学 | Preparation method and application of TiO2/WO3 composite film |
CN102225849A (en) * | 2011-04-21 | 2011-10-26 | 常州大学 | Preparation method of glass surface antireflection film without sintering |
CN102515566A (en) * | 2011-11-07 | 2012-06-27 | 中山市格兰特实业有限公司火炬分公司 | Magnetron sputtering self-cleaning glass with visible light response, and preparation method thereof |
CN102515566B (en) * | 2011-11-07 | 2013-10-30 | 中山市格兰特实业有限公司火炬分公司 | Preparation method of magnetron sputtering self-cleaning glass with visible light response |
CN102950843A (en) * | 2012-11-29 | 2013-03-06 | 大连创达技术交易市场有限公司 | Automotive glass with anti-fog and self-cleaning functions |
CN105603715B (en) * | 2014-10-31 | 2018-03-30 | 广东欣丰科技有限公司 | A kind of preparation method of fabric construction color |
CN105603715A (en) * | 2014-10-31 | 2016-05-25 | 广东欣丰科技有限公司 | Fabric structure color preparation method |
CN108126681A (en) * | 2016-12-01 | 2018-06-08 | 通用汽车环球科技运作有限责任公司 | For enhancing titanium dioxide(TiO2)The nucleating layer of the photocatalytic activity of coating |
CN107200580A (en) * | 2017-06-21 | 2017-09-26 | 佛山市钜仕泰粉末冶金有限公司 | A kind of optical nano ceramic insulation glass for strengthening visible light-transmissive and preparation method thereof |
CN107200580B (en) * | 2017-06-21 | 2019-05-24 | 佛山市钜仕泰粉末冶金有限公司 | A kind of optical nano ceramic insulation glass and preparation method thereof enhancing visible light-transmissive |
CN107604311A (en) * | 2017-08-10 | 2018-01-19 | 酒泉职业技术学院 | A kind of preparation method of automatically cleaning solar thermal collector antireflective coating |
CN108980771A (en) * | 2018-09-27 | 2018-12-11 | 华域视觉科技(上海)有限公司 | Photocatalytic self-cleaning car light and automobile |
CN110894138A (en) * | 2019-01-30 | 2020-03-20 | 中山大学 | Environment-friendly automobile glass |
CN109769529A (en) * | 2019-01-31 | 2019-05-21 | 铜仁学院 | A kind of oil tea cultivation temperature control green house |
CN113636760A (en) * | 2021-09-02 | 2021-11-12 | 青岛理工大学 | Antifogging self-cleaning glass and preparation method thereof |
CN117210155A (en) * | 2023-09-15 | 2023-12-12 | 精一门(常州)光学薄膜有限公司 | Self-cleaning anti-pollution energy-saving film for building and preparation method thereof |
CN117210155B (en) * | 2023-09-15 | 2024-05-14 | 精一门(常州)光学薄膜有限公司 | Self-cleaning anti-pollution energy-saving film for building and preparation method thereof |
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Publication number | Publication date |
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CN100551858C (en) | 2009-10-21 |
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Assignee: JIEYANG HONGGUANG COATED GLASS CO., LTD. Assignor: Jinan University Contract record no.: 2010440000916 Denomination of invention: Permanent self-cleaning glass with visible light responsibility and preparation method thereof Granted publication date: 20091021 License type: Exclusive License Open date: 20061011 Record date: 20100708 |
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Owner name: JIEYANG HONGGUANG COATED GLASS CO., LTD. Free format text: FORMER OWNER: JINAN UNIVERSITY Effective date: 20120712 |
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Free format text: CORRECT: ADDRESS; FROM: 510630 GUANGZHOU, GUANGDONG PROVINCE TO: 522000 JIEYANG, GUANGDONG PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20120712 Address after: Guangdong Hongguang Industrial Park 522000 Xianqiao District of Rongcheng city in Jieyang Province Patentee after: JIEYANG HONGGUANG COATED GLASS CO., LTD. Address before: 510630 Guangdong city of Guangzhou province Tianhe District Shipai Patentee before: Jinan University |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091021 Termination date: 20160421 |
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CF01 | Termination of patent right due to non-payment of annual fee |