CN1831517A - Miniature portable infrared spectrograph - Google Patents
Miniature portable infrared spectrograph Download PDFInfo
- Publication number
- CN1831517A CN1831517A CN 200610070845 CN200610070845A CN1831517A CN 1831517 A CN1831517 A CN 1831517A CN 200610070845 CN200610070845 CN 200610070845 CN 200610070845 A CN200610070845 A CN 200610070845A CN 1831517 A CN1831517 A CN 1831517A
- Authority
- CN
- China
- Prior art keywords
- mirror
- infrared
- room temperature
- light
- slit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000035945 sensitivity Effects 0.000 claims abstract description 3
- 238000001228 spectrum Methods 0.000 claims description 7
- 230000003595 spectral effect Effects 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- YBNMDCCMCLUHBL-UHFFFAOYSA-N (2,5-dioxopyrrolidin-1-yl) 4-pyren-1-ylbutanoate Chemical compound C=1C=C(C2=C34)C=CC3=CC=CC4=CC=C2C=1CCCC(=O)ON1C(=O)CCC1=O YBNMDCCMCLUHBL-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005269 aluminizing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000004446 light reflex Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 230000005616 pyroelectricity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
Images
Landscapes
- Spectrometry And Color Measurement (AREA)
- Radiation Pyrometers (AREA)
Abstract
A minimized and portable infrared spectrograph is composed of pulse infrared ray source, parabolic reflector, scanning micro - lens, flash grating, steering reflector, slit and high sensitivity of room temperature infrared unit detector. It features that a new light path system and pulse infrared ray source based on MEMS technology are applied on said spectrograph.
Description
Technical field
The invention belongs to the spectral measurement methods field, relate to a kind of microminiature portable infrared spectrograph based on scanning micro-mirror and pulse infrared light source.
Background technology
Infrared spectrometer has strong absorption characteristic spectrum owing to contain hydrogen group and carbon compound etc. near infrared and middle infrared spectral region, we utilize this character can determine the composition of material, and this makes infrared spectrometer in industry, agricultural, chemical industry, medicine and other fields extensive application.But the light splitting technology that existing infrared spectrometer adopts mainly comprises grating scanning type, Fourier formula, optical filtering chip, acousto-optic tunable etc., and deficiency is separately all arranged.
The raster scanning beam splitting system is to utilize grating as beam splitter, and by raster, and the polychromatic light of incident is decomposed into to be distributed in full wavely provides optional spectral width very narrow monochromatic light.This light splitting technology is full-fledged, is widely used, and major advantage is the wavelength band broadness, and is even in all band chromatic dispersion, and monochromatic wavelength can reach accurate control.But it has the following disadvantages: sweep velocity is slow, the wavelength poor reproducibility, and inner moving-member is many.
The Fourier transform spectrometer is the Fourier transform relation of utilizing between spectrum pixel interferogram and the spectrogram, by measuring interferogram and interferogram being carried out the spectral information that Fourier transform obtains object.Fourier transform spectrometer luminous flux is big, and the spectral resolution height is with the obvious advantage aspect weak radiation detection.But because the existence of index glass in the interferometer, the reliability of instrument is restricted, particularly using and placing environment strict demand is arranged instrument.And it cost an arm and a leg, bulky is mainly used in the laboratory.
Optical filtering chip spectrometer architecture is simple, but resolution is very low, only is suitable for special purposes.Acousto-optic tunable formula spectrometer resolution is higher, and volume is also less, but general wave spectrum scope is narrower, and costs an arm and a leg.
So infrared spectrometer is only the only way out to microminaturization, low cost, wide spectrum, high precision development.Utilize the micro-processing technology of MEMS and MOEMS to make the focus direction that the integrated miniature spectrometer is the microminiaturized development of spectrometer.The people such as F.Zimmer of Germany have proposed the near infrared spectrometer of a kind of spectral range of the MOEMS of use fabrication techniques at 900-2000nm, it is based on the scanning micro-mirror technology, but the surface of this micro mirror is the diffraction structure of aluminizing, the still grating that also promptly scans, but the problem of this mode maximum is the unusual difficulty of processing of used low-light grid, and patent employing micro mirror of the present invention is a plane mirror, is easier to processing.
Summary of the invention
The objective of the invention is to deficiency at the prior art existence, a kind of miniature portable infrared spectrograph is provided, it adopts a kind of brand-new light path system that is different from traditional sweep type spectrometer, change is based on the scheme of non-photon type choppers that detector adopts such as pyroelectricity or PbSe, directly adopt the pulse infrared light source of miniaturization, and adopt swing to scan based on the mode of the miniature planar catoptron of MEMS technology, thereby simplied system structure is really realized the microminiaturization of infrared spectrometer greatly.
Microminiaturized infrared spectrometer provided by the invention is made up of pulse infrared light source, parabolic mirror, scanning micro-mirror, blazed grating, steering reflection mirror, slit and room temperature infrared unit detector.Described pulse infrared light source places near the parabolic reflector mirror foci, place scanning micro-mirror in the parallel light path behind parabolic mirror, in the reflected light path of micro mirror, be right after blazed grating, but the oscillatory scanning micro mirror here both reflexed to the polychromatic light that parabolic mirror incident comes on the blazed grating, again the monochromatic collimated beam after the blazed grating beam split is reflexed to the enterprising line convergence of parabolic mirror, in assembling light path, a steering reflection mirror is set then, and near the focus of assembling, slit is set, slit is provided with room temperature infrared unit detector behind, the monochromatic light of telling incides on the room temperature infrared unit detector by slit, and realizes the scanning of monochromatic light on detector by the scanning micro-mirror swing.
System light path structure of the present invention is different from traditional scanning sub-ray spectrometer.Thereby conventional spectrometers is to realize beam split by rocking grating, and generally is the symmetrical structure realization beam split of adopting collimator objective respectively and assembling object lens.Light path among the present invention is only used a slice parabolic mirror, not only makees collimator objective but also assemble object lens, thereby and directly scans miniature planar catoptron in the parallel light path rather than raster realizes beam split.
Used pulse infrared light source is a kind of MEMS of having technology band parabolic mirror infrared light supply, and operation wavelength covers to middle infrared, so the service band of spectrometer can be selected different pulse infrared light sources and extend to mid and far infrared by near infrared.Pulse infrared light source is used diamond carbon thin film technique, heating and generation infrared radiation behind the galvanization.Its high emissivity, high thermal conductivity, and very low hot residence characteristics make it when high-frequency impulse is worked, and energy Fast Heating and cooling can be worked as the fast modulation element under continuous operation mode and pulse mode.And its parabolic mirror has been strengthened the axial infrared energy more than 10 times, has better advantage than other light source.And because the light-emitting area of this light source can be as small as 1-2mm
2, the occasion not high to resolution requirement can be saved slit fully, and structure is further simplified.The infrared pulse light source that adopts only is equivalent to thumb head size, has replaced traditional large-scale light source as the silit infrared light supply, thereby and can make full use of luminous energy according to the angle of divergence design corresponding optical system of light source.According to American I N OPTICS, the miniature pulse infrared light source of the RFIR-55 that INC provides, Frequency Adjustable output, the highest can be to 100Hz, from and saved bulky chopper assembly.
Said scanning micro-mirror is a kind of micro optical element based on the MEMS technological development, its essence is one can rotational angle plane mirror, not bright and take the report at research institute microtechnology center according to Germany, the micro mirror volume that they are produced only is equivalent to the size of a little eyeglass, but can realize the corner more than 10 °, and can reach higher sweep frequency.In system of the present invention, this micro mirror places parallel light path, both the polychromatic light that parabolic mirror incident is come reflexed on the grating, again the reflection of monochromatic light after the beam split on parabolic reflector, and can realize the scanning of monochromatic light on detector by swinging it.
Advantage of the present invention:
1, the novel beam split light path system of Cai Yonging, assembly is few, and is simple in structure, really realized the microminiaturization of infrared spectrometer.
2, adopt the miniature pulse infrared light source of MEMS technology, replaced traditional large-scale infrared light supply.
3, adopt the direct pulsed modulation of infrared light supply, reduced the chopper assembly in the conventional spectrometers system.
4, adopt swing to scan, rather than adopt the mode of scanning step motor grating based on the mode of the miniature planar catoptron of MEMS technology, simplied system structure greatly, volume is little, the precision height, stable performance is suitable for moving portable use.
5, incorporate miniaturized design thinking has realized the modular design of infrared spectrometer, and cheap.
Description of drawings
Fig. 1 is a structure principle chart of the present invention.
1 indicating impulse infrared light supply among the figure, the 2nd, parabolic mirror, 3 is scanning micro-mirror, the 4th, blazed grating, the 5th, steering reflection mirror, the 6th, slit, the 7th, room temperature infrared unit detector.
Embodiment
The invention will be further described below in conjunction with accompanying drawing
Referring to Fig. 1, this spectrometer is made up of pulse infrared light source 1, parabolic mirror 2, scanning micro-mirror 3, blazed grating 4, steering reflection mirror 5, slit 6, room temperature infrared unit detector 7.The modulated pulsed infrared light that pulse infrared light source 1 sends, be that the infrared beam that pointolite sends is regarded in very little being similar to of a beam divergence angle as, when light beam incides on the parabolic mirror 2, because pointolite can be regarded as on the focus of parabolic mirror 2, so light beam becomes parallel beam after reflecting through parabolic mirror 2; Directional light reflexes on the blazed grating 4 through scanning micro-mirror 3, by the grating diffration effect, continuous spectrum is broken down into the multi beam monochromatic collimated beam, these monochromatic collimated beams incide on the parabolic mirror 2 through scanning micro-mirror 3 again, and then assemble, in assembling light path, adopt steering reflection mirror 5 that the monochromatic light that reflects is turned to, and get at last through slit 6 on the photosurface of high sensitivity room temperature infrared detector 7.Then, the swing by scanning micro-mirror 3 drops on the detector photosurface different monochromatic luminous points successively, thereby has collected the energy signal of different wavelengths of light, and these signals input computing machines just can carry out spectrum identification processing.
Claims (4)
1. miniature portable infrared spectrograph, it is characterized in that: it is made up of pulse infrared light source (1), parabolic mirror (2), scanning micro-mirror (3), blazed grating (4), steering reflection mirror (5), slit (6) and room temperature infrared unit detector (7); Described pulse infrared light source (1) places near parabolic mirror 2 focuses, place scanning micro-mirror (3) in the parallel light path behind parabolic mirror (2), and in the reflected light path of scanning micro-mirror (3), be right after blazed grating (4), scanning micro-mirror (3) both reflexed to the polychromatic light that parabolic mirror (2) incident comes on the blazed grating (4), again the monochromatic collimated beam after blazed grating (4) beam split is reflexed to the enterprising line convergence of parabolic mirror (2), and in assembling light path, a steering reflection mirror (5) is set, behind steering reflection mirror (5), also near the focus of promptly assembling slit (6) is set, slit (6) is provided with room temperature infrared unit detector (7) behind, the monochromatic light of telling incides on the room temperature infrared unit detector (7) by slit (6), and realizes the scanning of monochromatic light on detector by the swing of scanning micro-mirror (3).
2. according to the described miniature infrared spectrometer of claim 1, it is characterized in that: pulse infrared light source (1) is the continuous infrared light supply of wide spectrum that adopts MEMS technology Frequency Adjustable.
3. according to the described miniature infrared spectrometer of claim 1, it is characterized in that: scanning micro-mirror (3) is based on the miniature planar catoptron of swinging of MEMS technology.
4. according to the described miniature infrared spectrometer of claim 1, it is characterized in that: described room temperature infrared unit detector is to adopt non-photon type high sensitivity room temperature infrared unit detector.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100708453A CN100443885C (en) | 2005-09-27 | 2006-03-14 | Miniature portable infrared spectrograph |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200510057297 | 2005-09-27 | ||
| CN200510057297.6 | 2005-09-27 | ||
| CNB2006100708453A CN100443885C (en) | 2005-09-27 | 2006-03-14 | Miniature portable infrared spectrograph |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1831517A true CN1831517A (en) | 2006-09-13 |
| CN100443885C CN100443885C (en) | 2008-12-17 |
Family
ID=36993934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100708453A Expired - Fee Related CN100443885C (en) | 2005-09-27 | 2006-03-14 | Miniature portable infrared spectrograph |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100443885C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103868596A (en) * | 2014-02-21 | 2014-06-18 | 中国科学院光电研究院 | Large-aperture space heterodyne interference spectral imaging method and spectrometer |
| CN104568826A (en) * | 2015-01-22 | 2015-04-29 | 天津大学 | Miniature solidified near-infrared spectroscopy based on linear variable filter |
| CN104880433A (en) * | 2015-06-09 | 2015-09-02 | 河南理工大学 | High-resolution MEMS (micro-electromechanical system) micromirror infrared spectrometer based on off-axis parabolic reflector |
| CN105092516A (en) * | 2014-10-24 | 2015-11-25 | 深圳莱特光电有限公司 | Digital light processing technology-based portable liquid food near infrared spectroscopy analyzer |
| CN105241966A (en) * | 2014-07-09 | 2016-01-13 | 中国石油化工股份有限公司 | Multi-component gas detection device |
| CN106442396A (en) * | 2016-08-26 | 2017-02-22 | 广西壮族自治区产品质量检验研究院 | Rapidly detecting method for bagasse saccharose content based on near infrared technology |
| CN108549125A (en) * | 2018-04-28 | 2018-09-18 | 西安柯莱特信息科技有限公司 | A kind of Multifunctional optical filter and its control method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101509869B (en) * | 2009-03-13 | 2011-06-08 | 重庆大学 | Visible-near-infrared spectrum detecting method and spectrometer based on programmable micro-lens array |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6008897A (en) * | 1999-01-19 | 1999-12-28 | National Research Council Of Canada | Method and apparatus for materials analysis by enhanced laser induced plasma spectroscopy |
| CN1195976C (en) * | 2002-07-30 | 2005-04-06 | 中国石油化工股份有限公司 | On-line near-infrared spectrograph |
| CN2676188Y (en) * | 2004-03-02 | 2005-02-02 | 江苏静安科技公司 | Portable near infrared spectrometer |
-
2006
- 2006-03-14 CN CNB2006100708453A patent/CN100443885C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103868596A (en) * | 2014-02-21 | 2014-06-18 | 中国科学院光电研究院 | Large-aperture space heterodyne interference spectral imaging method and spectrometer |
| CN103868596B (en) * | 2014-02-21 | 2015-10-14 | 中国科学院光电研究院 | A kind of large aperture space heterodyne interference spectrum formation method and spectrometer |
| CN105241966A (en) * | 2014-07-09 | 2016-01-13 | 中国石油化工股份有限公司 | Multi-component gas detection device |
| CN105092516A (en) * | 2014-10-24 | 2015-11-25 | 深圳莱特光电有限公司 | Digital light processing technology-based portable liquid food near infrared spectroscopy analyzer |
| CN104568826A (en) * | 2015-01-22 | 2015-04-29 | 天津大学 | Miniature solidified near-infrared spectroscopy based on linear variable filter |
| CN104880433A (en) * | 2015-06-09 | 2015-09-02 | 河南理工大学 | High-resolution MEMS (micro-electromechanical system) micromirror infrared spectrometer based on off-axis parabolic reflector |
| CN106442396A (en) * | 2016-08-26 | 2017-02-22 | 广西壮族自治区产品质量检验研究院 | Rapidly detecting method for bagasse saccharose content based on near infrared technology |
| CN108549125A (en) * | 2018-04-28 | 2018-09-18 | 西安柯莱特信息科技有限公司 | A kind of Multifunctional optical filter and its control method |
| CN108549125B (en) * | 2018-04-28 | 2021-08-06 | 湖北华鑫光电有限公司 | Multifunctional optical filter and control method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100443885C (en) | 2008-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100443885C (en) | Miniature portable infrared spectrograph | |
| US9804028B2 (en) | External cavity laser source | |
| CN101509869B (en) | Visible-near-infrared spectrum detecting method and spectrometer based on programmable micro-lens array | |
| CN105136293B (en) | A kind of MEMS micromirror micro spectrometer based on transmission grating | |
| CN101666681B (en) | Spectrometer using MOEMS movable blazed grating array | |
| CN111256821A (en) | Dual-wavelength Raman-fluorescence combined spectrometer | |
| US9989412B2 (en) | Low-noise spectroscopic imaging system | |
| CN101539457A (en) | Miniature spectrometer based on MEMS micro lens array | |
| US10365158B2 (en) | Low-noise spectroscopic imaging system | |
| CN102246015A (en) | Monochromator comprising variable wavelength selector in combination with tunable interference filter | |
| CN103196879A (en) | Laser-induced fluorescence spectrum detection device | |
| CN107238570B (en) | Micro spectrometer based on MEMS micro vibrating mirror, gas sensor and spectrum detection method | |
| EP1159588A1 (en) | Compact and robust spectrograph | |
| CN109520944A (en) | A kind of universal spectroscopic analysis system | |
| CN104880433A (en) | High-resolution MEMS (micro-electromechanical system) micromirror infrared spectrometer based on off-axis parabolic reflector | |
| CN211504404U (en) | Dual-wavelength excitation acquisition system applied to spectrometer | |
| US7149033B2 (en) | UV visual light beam combiner | |
| CN110553736A (en) | raman spectrometer | |
| CN110501074B (en) | High-flux wide-spectrum high-resolution coherent dispersion spectrum imaging method and device | |
| US20210033457A1 (en) | Micro Wideband Spectroscopic Analysis Device | |
| CN112798556B (en) | Non-collinear time-resolved pumping-detecting device and method for infrared and frequency spectrum | |
| CN112595416A (en) | Broadband infrared spectrometer | |
| CN1101544C (en) | Ultraviolet Raman spectrometer | |
| Fredericks et al. | Vibrational spectroscopy: instrumentation for infrared and Raman spectroscopy | |
| CN101251420A (en) | Novel double-movable-mirror interferometer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190821 Address after: 400030 Chongqing Shapingba District Yubei Road 131 Attached 14 Co-patentee after: Chongqing Major Intellectual Property Operations Co.,Ltd. Patentee after: Wen Zhiyu Address before: 400044 Shapingba street, Shapingba District, Chongqing, No. 174 Patentee before: Chongqing University |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081217 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |