CN1831161A - Deslagging agent for high performance deforming aluminium and aluminium alloy, prepn. method and application thereof - Google Patents

Deslagging agent for high performance deforming aluminium and aluminium alloy, prepn. method and application thereof Download PDF

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Publication number
CN1831161A
CN1831161A CN 200510009800 CN200510009800A CN1831161A CN 1831161 A CN1831161 A CN 1831161A CN 200510009800 CN200510009800 CN 200510009800 CN 200510009800 A CN200510009800 A CN 200510009800A CN 1831161 A CN1831161 A CN 1831161A
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China
Prior art keywords
aluminium
high performance
slagging agent
aluminium alloy
weight
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CN 200510009800
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CN100591782C (en
Inventor
吕新宇
李庆玉
吴欣凤
单长智
高振忠
王涛
卢载浩
张春波
王德满
郝志刚
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Northeast Light Alloy Co Ltd
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Northeast Light Alloy Co Ltd
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Priority to CN200510009800A priority Critical patent/CN100591782C/en
Publication of CN1831161A publication Critical patent/CN1831161A/en
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Publication of CN100591782C publication Critical patent/CN100591782C/en
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Abstract

The invention relates to high efficiency distortion aluminum and aluminum alloy sediment removing agent and the making method and the application. It is made up from NaCl 25-45wt%, KCl 30-50wt%, CaCl2 3-7wt%, AlCl3 1-6wt%, and Na3AIF 1-6wt%. The invention is suited to the condition of Mg content below 2%, and using temperature at 700-800 degree centigrade.

Description

High performance deforming aluminium and aluminium alloy slagging agent and making method and application
Technical field:
The minimizing of using when the present invention relates to the casting of a kind of aluminium and aluminium alloy smelting plays the slagging agent that touches with the air knot, the making method and the application thereof of slagging agent.
Background technology:
Aluminium is more active metal, it forms the slag inclusion of oxide compound during melting easily and absorbs gas under atmosphere, if these oxide compounds and gas enter ingot casting with solution, will form slag inclusion, oxide film, pore, loose or other defect, reduce physicals, the corrosion resistance of product, also can worsen the process industrial art performance of alloy, therefore, the oxidization burning loss that aluminium alloy needs to use a large amount of solvents to prevent the metal solution in fusion process and air-breathing, and can the degasification slagging-off.
Summary of the invention: the purpose of this invention is to provide a kind of high performance deforming aluminium and aluminium alloy slagging agent, reduce aluminium solution scaling loss, the present invention also comprises the making method and the application of this slagging agent.
Above-mentioned purpose realizes by following technical scheme:
High performance deforming aluminium and aluminium alloy slagging agent, described slagging agent is grouped into by following one-tenth: sodium-chlor 20-40, Repone K 25-45, sodium sulfate 1-5, yellow soda ash 1-5, zinc chloride 1-3, calcium chloride 2-5, Sodium Silicofluoride 2-10, Na 3AIF1-6, above proportioning is a ratio of weight and number.
Above-mentioned high performance deforming aluminium and aluminium alloy slagging agent also comprise hexachloroethane 2-5 in the described slagging agent, above proportioning is a ratio of weight and number.
Above-mentioned slagging agent is in high performance deforming aluminium and aluminium alloy smelting Application in Casting.
The making method of high performance deforming aluminium and aluminium alloy slagging agent, after according to above-mentioned ratio of weight and number raw material being prepared, mix by agitator, the solvent that mixes is put into roaster, dried 3-4 hour down at 300 ℃, pulverize again after the oven dry, after the pulverizing, sieve, then it is packed with the waterproof plastic bag.
This technical scheme has following beneficial effect:
1. generally contain 80% aluminium and 20% aluminum oxide in the scum silica frost,, wherein most aluminium is discharged, make slag become loose and dry if adopt the suitable slagging agent of tension force.Product of the present invention has rational surface tension and viscosity, can adsorb, dissolve the oxide residue in the solution, can be easy to again separate, effectively the aluminium in the slag be separated with the alloy solution, aluminium content in the scum silica frost is reduced greatly, almost the degree that does not have on the macroscopic view.
2. the material that contains solar heat protection material (as yellow soda ash, Sodium Silicofluoride) and dissolved oxygen aluminium among the present invention, these materials are emitted a large amount of heat when reaction, help when reaction, to increase wettability and penetrate the slag surface film oxide, from slag, isolate aluminium, when preventing hot substance reaction, generate silicon oxide and sodium oxide, increased the surface tension and the viscosity of solvent so again, made the separating effect of slag and aluminium liquid become better.Through repeatedly check, present slag has become the dried slag of loose canescence.
3. through check, the add-on of this product directly influences the quality of product, too little solvent, and then thermal discharge is few, the flux effect is bad, and flux is too many, and thermal discharge is many, produces a large amount of smog, can aggravate the scaling loss of aluminium, the add-on that the present invention adopts is aluminium liquid quality 0.2-1%, has reached best effect.
The specific embodiment of the present invention:
Embodiment 1:
High performance deforming aluminium and aluminium alloy slagging agent, described slagging agent is grouped into by following one-tenth: sodium-chlor 20, Repone K 25, sodium sulfate 1, yellow soda ash 1, zinc chloride 1, calcium chloride 2, Sodium Silicofluoride 2, Na 3AIF1, above proportioning is a ratio of weight and number.
Embodiment 2:
High performance deforming aluminium and aluminium alloy slagging agent, described slagging agent is grouped into by following one-tenth: sodium-chlor 40, Repone K 45, sodium sulfate 5, yellow soda ash 5, zinc chloride 3, calcium chloride 5, Sodium Silicofluoride 10, Na 3AIF6, hexachloroethane 2 above proportionings are ratio of weight and number.
Embodiment 3:
High performance deforming aluminium and aluminium alloy slagging agent is characterized in that: described slagging agent is grouped into by following one-tenth: sodium-chlor 30, Repone K 35, sodium sulfate 3, yellow soda ash 3, zinc chloride 2, calcium chloride 4, Sodium Silicofluoride 5, Na 3AIF4, hexachloroethane 5, above proportioning is a ratio of weight and number.
Embodiment 4:
The making method of above slagging agent, select component according to weight proportion and kind, because halogenide comprises muriatic salt and absorbs water easily or contain crystal water, and the formation bulk, need to pulverize filtration and carry out proportioning according to its content of effective, after according to ratio of weight and number raw material being prepared, mix by agitator, the solvent that mixes is put into roaster, dried 3-4 hour down at 300 ℃, the material after the oven dry often forms bulk again, need pulverize again, after the pulverizing, sieve, then plastic bag packaging is prevented suction.
In the fusion process of aluminium and aluminium alloy, under 700-800 ℃ of situation, this product is disperseed to be sprinkled in the aluminium solution uniformly, after stirring, it produces loose linen scum silica frost, and it is clawed the back check, and it is few wherein to contain aluminium.Effectively prevented the oxidization burning loss of metal solution and air-breathing thus, and can the degasification slagging-off.
This product is applicable to magnesium content less than 2%, under the use temperature 700-800 ℃ of situation, and the slagging agent of aluminium content in the minimizing slag that aluminium and aluminium alloy use when smelting founding.

Claims (4)

1. high performance deforming aluminium and aluminium alloy slagging agent, it is characterized in that: described slagging agent is grouped into by following one-tenth: sodium-chlor 20-40, Repone K 25-45, sodium sulfate 1-5, yellow soda ash 1-5, zinc chloride 1-3, calcium chloride 2-5, Sodium Silicofluoride 2-10, Na 3AIF1-6, above proportioning is a ratio of weight and number.
2. high performance deforming aluminium according to claim 1 and aluminium alloy slagging agent is characterized in that: comprise also in the described slagging agent that hexachloroethane 2-5, above proportioning are ratio of weight and number.
3. claim 1 or 2 described slagging agents are in high performance deforming aluminium and aluminium alloy smelting Application in Casting, and its consumption is the 0.2-1 of aluminium weight.
4. the making method of high performance deforming aluminium and aluminium alloy slagging agent, it is characterized in that: after according to above-mentioned ratio of weight and number raw material being prepared, mix by agitator, the solvent that mixes is put into roaster, dried 3-4 hour down at 300 ℃, pulverize again after the oven dry, after the pulverizing, sieve, then it is packed with the waterproof plastic bag.
CN200510009800A 2005-03-08 2005-03-08 Deslagging agent for high performance deforming aluminium and aluminium alloy, preparation method and application thereof Expired - Fee Related CN100591782C (en)

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CN100591782C CN100591782C (en) 2010-02-24

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199712A (en) * 2011-04-18 2011-09-28 湘乡市友好冶金材料有限公司 Lead residue reducing agent and preparation method thereof
CN102312104A (en) * 2011-10-14 2012-01-11 南南铝业股份有限公司 Refining agent for aluminium and aluminium alloy melting
CN102390917A (en) * 2010-06-08 2012-03-28 布卢姆工程公司 Method of Co-Firing Raw Glycerin in a Melting Furnace
CN103146944A (en) * 2013-03-19 2013-06-12 新昌县国威铝制品辅助材料有限公司 Aluminum or aluminum alloy melt slag removal agent
CN104046788A (en) * 2013-03-15 2014-09-17 通用汽车环球科技运作有限责任公司 Methods of reducing old oxides in aluminum castings
CN104651633A (en) * 2015-02-09 2015-05-27 江苏华企铝业科技有限公司 Aluminum alloy sodium removal agent and preparation method thereof
CN106191502A (en) * 2016-08-24 2016-12-07 株洲创林合金有限责任公司 Aluminum alloy smelting low-temperature refining slagging agent and preparation method thereof
CN108342602A (en) * 2018-04-13 2018-07-31 湖北金洋资源股份公司 A kind of aluminium alloy refining agent, preparation method and refinery practice
CN108504884A (en) * 2018-04-13 2018-09-07 湖北金洋资源股份公司 A kind of environment-friendly type refining agent, preparation method and refinery practice
CN108660331A (en) * 2018-04-13 2018-10-16 湖北金洋资源股份公司 A kind of Metal Melting refining agent, preparation method and refinery practice
CN109082556A (en) * 2018-04-13 2018-12-25 湖北金洋资源股份公司 A kind of smokeless refining agent, preparation method and refinery practice
CN109306412A (en) * 2018-12-20 2019-02-05 河北四通新型金属材料股份有限公司 A kind of aluminium and aluminium alloy high-efficiency environment friendly refining agent and preparation method thereof
CN109536765A (en) * 2019-01-25 2019-03-29 中山华钰有色冶金材料有限公司 Granular flux for aluminum alloy processing and preparation method thereof
CN111778409A (en) * 2020-06-23 2020-10-16 中国海洋大学 Production method of slag removing agent based on resource utilization of waste salt
CN115369269A (en) * 2022-08-08 2022-11-22 苏州市祥冠合金研究院有限公司 Efficient zinc alloy smelting slagging agent and use method thereof

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102390917A (en) * 2010-06-08 2012-03-28 布卢姆工程公司 Method of Co-Firing Raw Glycerin in a Melting Furnace
CN102199712B (en) * 2011-04-18 2013-03-06 湘乡市友好冶金材料有限公司 Lead residue reducing agent and preparation method thereof
CN102199712A (en) * 2011-04-18 2011-09-28 湘乡市友好冶金材料有限公司 Lead residue reducing agent and preparation method thereof
CN102312104A (en) * 2011-10-14 2012-01-11 南南铝业股份有限公司 Refining agent for aluminium and aluminium alloy melting
CN104046788B (en) * 2013-03-15 2017-10-24 通用汽车环球科技运作有限责任公司 The method for reducing old oxide in aluminium casting
CN104046788A (en) * 2013-03-15 2014-09-17 通用汽车环球科技运作有限责任公司 Methods of reducing old oxides in aluminum castings
CN103146944A (en) * 2013-03-19 2013-06-12 新昌县国威铝制品辅助材料有限公司 Aluminum or aluminum alloy melt slag removal agent
CN103146944B (en) * 2013-03-19 2015-04-15 新昌县国威铝制品辅助材料有限公司 Aluminum or aluminum alloy melt slag removal agent
CN104651633A (en) * 2015-02-09 2015-05-27 江苏华企铝业科技有限公司 Aluminum alloy sodium removal agent and preparation method thereof
CN104651633B (en) * 2015-02-09 2017-07-11 江苏华企铝业科技股份有限公司 A kind of sodium removing agent for aluminum alloy and preparation method thereof
CN106191502A (en) * 2016-08-24 2016-12-07 株洲创林合金有限责任公司 Aluminum alloy smelting low-temperature refining slagging agent and preparation method thereof
CN108342602A (en) * 2018-04-13 2018-07-31 湖北金洋资源股份公司 A kind of aluminium alloy refining agent, preparation method and refinery practice
CN108504884A (en) * 2018-04-13 2018-09-07 湖北金洋资源股份公司 A kind of environment-friendly type refining agent, preparation method and refinery practice
CN108660331A (en) * 2018-04-13 2018-10-16 湖北金洋资源股份公司 A kind of Metal Melting refining agent, preparation method and refinery practice
CN109082556A (en) * 2018-04-13 2018-12-25 湖北金洋资源股份公司 A kind of smokeless refining agent, preparation method and refinery practice
CN109306412A (en) * 2018-12-20 2019-02-05 河北四通新型金属材料股份有限公司 A kind of aluminium and aluminium alloy high-efficiency environment friendly refining agent and preparation method thereof
CN109536765A (en) * 2019-01-25 2019-03-29 中山华钰有色冶金材料有限公司 Granular flux for aluminum alloy processing and preparation method thereof
CN111778409A (en) * 2020-06-23 2020-10-16 中国海洋大学 Production method of slag removing agent based on resource utilization of waste salt
CN115369269A (en) * 2022-08-08 2022-11-22 苏州市祥冠合金研究院有限公司 Efficient zinc alloy smelting slagging agent and use method thereof

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