CN1821295A - Wood-plastic composite material prepared from polyolefin (PE, PP)/oak powder/ionomer - Google Patents
Wood-plastic composite material prepared from polyolefin (PE, PP)/oak powder/ionomer Download PDFInfo
- Publication number
- CN1821295A CN1821295A CN 200610005590 CN200610005590A CN1821295A CN 1821295 A CN1821295 A CN 1821295A CN 200610005590 CN200610005590 CN 200610005590 CN 200610005590 A CN200610005590 A CN 200610005590A CN 1821295 A CN1821295 A CN 1821295A
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- China
- Prior art keywords
- wood
- preparation
- matrix material
- polyolefine
- novel wood
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- 239000000843 powder Substances 0.000 title claims abstract description 21
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 17
- 239000000463 material Substances 0.000 title claims abstract description 14
- 229920001587 Wood-plastic composite Polymers 0.000 title abstract description 10
- 239000011155 wood-plastic composite Substances 0.000 title abstract description 10
- 229920000554 ionomer Polymers 0.000 title 1
- 238000001125 extrusion Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 238000001746 injection moulding Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 7
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 claims abstract description 4
- 229920000831 ionic polymer Polymers 0.000 claims abstract description 3
- 229920003023 plastic Polymers 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 6
- 229920001903 high density polyethylene Polymers 0.000 claims description 4
- 239000004700 high-density polyethylene Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- 229920001179 medium density polyethylene Polymers 0.000 claims description 2
- 239000004701 medium-density polyethylene Substances 0.000 claims description 2
- 239000002023 wood Substances 0.000 abstract description 9
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000012438 extruded product Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229940089401 xylon Drugs 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention provides a preparation method of a novel wood-plastic composite material. The method is characterized in that polyolefin and wood powder are used as main materials, an ionic polymer (ethylene-methacrylic acid copolymer) is used as a compatilizer, the dosage proportion is 5-10% of the mass of a mixed material, the mixture is mixed in a high-speed mixer for 20-40 minutes, the temperature is controlled within 100 ℃, and extrusion molding or injection molding and the like are adopted. Compared with the prior art, the product obtained by the invention has the advantages of hard quality, high strength, strong binding power, good fluidity, high extrusion speed, smooth surface, wear resistance and high hardness. The product can be widely applied to interior materials such as doors and windows, floors, wall building materials, wooden fences, ships, trains, automobiles and the like.
Description
Affiliated technical field:
(PE PP)/oak powder/prepare the preparation method of wood plastic composite from aggressiveness, is that a kind of polyolefine and oak powder of adopting is the method that major ingredient prepares wood plastic composite specifically to the present invention relates to a kind of polyolefine.
Background technology:
The wood plastic composite that xylon, wood powder and thermoplastic polymer form is a kind of emerging advanced composite material that broad development and application prospect are arranged in the world today.Because it combines the advantage of plastics and timber, have long service life, attractive in appearance, renewable, cost is low, insect protected, anticorrosion, antiskid, can spray, than the hardness height of pure plastic prod, can equally with timber process, advantage such as bonding and fixing, so wood plastic composite is widely used in material of construction, marine material, fence material, furniture material, automotive material of door and window, floor, wall etc.Wood plastic composite is a kind of very effective means for solution forest reserves scarcity, petroleum resources worsening shortages.
Because wood powder and polyolefins plastics polarity differ bigger, cause the two consistency bad, and wood powder and the compound composite materials property that obtains of polyolefin resin is not ideal enough.Domestic and international research work at present all is to handle wood powder or directly add polyolefinic maleic anhydride grafts by coupling agent (silicane, titanate ester) to improve the interface compatibility of the two, has all played certain effect.But in the wood plastic composite actual production process, also to solve the problem such as slickness, processing fluidity, raising rate of extrusion of product surface, compatilizer or coupling agent general aspect addressing these problems can not obtain satisfied effect, and add the performance that other processing aid can influence the finished product.Therefore seek a kind of mechanical property that can either improve wood powder and polyolefinic interface compatibility, improve product, the auxiliary agent that can solve the various processing problems in the actual production simultaneously again is most important.
Summary of the invention:
Technical problem to be solved by this invention is: wood powder and polyolefins polarity differ bigger, and consistency is bad, and common wood-plastic composite goods bounding force is little, and surface flatness is relatively poor, and mobile bad.The present invention provides a kind of preparation method of novel wood-plastic matrix material for solving the problems referred to above in the prior art, and described preparation method is as follows:
With polyolefine and oak powder as major ingredient, with ionic polymer (for example ethylene-methacrylic acid copolymer) as compatilizer, the compatilizer consumption is 5～10% of a mixture quality, in homogenizer, mixed 20～40 minutes, temperature is controlled in 100 ℃, adopts extrusion moulding or injection moulding.
Further, polyolefine selects melt flow rate (MFR) at 0.5～7.0g/10min
Further, described polyolefine is a high density polyethylene(HDPE), new LDPE (film grade), linear low density of polyethylene, medium-density polyethylene, the reworked material of polypropylene and said polyolefins thereof.
Further, described forming technique is twin screw extruder extrusion moulding or injection moulding in injection moulding machine, or adopts existing plastics forming technique such as pressure forming.
The present invention and prior art contrast, and have the following advantages:
1. the required oak powder of this matrix material is the offal in the Oak Tree wood working, and used plastics promptly can be polyolefin resin finished product, the also reworked material of available waste polyolefine plastics.Be very significant to solving the wasting of resources and environmental problem undoubtedly.
2. because wood powder and polyolefine (polyethylene, polypropylene) polarity differs bigger, consistency is bad, the present invention adopts the compatilizer of high molecular polymer (ethylene-methacrylic acid copolymer) as both, improved processing fluidity greatly, improve the slickness of product surface, and helped the raising of extruded velocity, more helped the bonding of with other material compound or technologies such as coextrusion and compound pad pasting.
Embodiment
Embodiment 1
The PE/ oak powder/from aggressiveness=40/50/10, wherein the MFR of PE is 3.5g/10min, oak powder is 100 orders, with PE, oak powder, add homogenizer in proportion from aggressiveness and mix 80 ℃ of temperature, 20 minutes time, compound is in parallel parallel dual-screw extruding machine extrusion moulding, and the screw zones temperature is respectively 180 ℃, 190 ℃, 200 ℃, 185 ℃.Extruded velocity 2m/min, extruded product is smooth smooth, and composite property is: tensile strength 29.1MPa, shock strength 9.5kJ/m
2, flexural strength 40MPa, modulus in flexure 2050MPa.
Embodiment 2
The PP/ oak powder/from aggressiveness=40/50/10, the MFR of PP is 0.5g/10min, oak powder is 100 orders, with PP, oak powder, mix 100 ℃ of temperature in proportion in homogenizer from aggressiveness, time 30min, compound is through parallel parallel dual-screw extruding machine extruded product, and the screw zones temperature is: 190 ℃, and 200 ℃, 200 ℃, 185 ℃.Extruded velocity 1.5m/min, product surface is smooth smooth, tensile strength 33.2MPa, shock strength 8.5kJ/m
2, flexural strength 45MPa, modulus in flexure 2500MPa.
Claims (4)
1. the preparation method of a novel wood-plastic matrix material is characterized in that:
A. use polyolefine and oak powder as major ingredient, as compatilizer, usage ratio is 5～10% of a compound with ionic polymer (for example ethylene-methacrylic acid copolymer)
B. compound mixed in homogenizer 20～40 minutes, and temperature is controlled in 100 ℃, adopted extrusion moulding or injection moulding.
2. the preparation method of a kind of novel wood-plastic matrix material as claimed in claim 1, polyolefine selects melt-flow speed (MFR) at 0.5～7.0g/10min
3. the preparation method of a kind of novel wood-plastic matrix material as claimed in claim 1, it is characterized in that: described polyolefine is a high density polyethylene(HDPE), new LDPE (film grade), linear low density of polyethylene, medium-density polyethylene, the reworked material of polypropylene and said polyolefins thereof.
4. the preparation method of a kind of novel wood-plastic matrix material as claimed in claim 1 is characterized in that: described forming technique is twin screw extruder extrusion moulding or injection moulding in injection moulding machine, or adopts existing plastics forming technique such as pressure forming.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610005590 CN1821295A (en) | 2006-01-11 | 2006-01-11 | Wood-plastic composite material prepared from polyolefin (PE, PP)/oak powder/ionomer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610005590 CN1821295A (en) | 2006-01-11 | 2006-01-11 | Wood-plastic composite material prepared from polyolefin (PE, PP)/oak powder/ionomer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1821295A true CN1821295A (en) | 2006-08-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610005590 Pending CN1821295A (en) | 2006-01-11 | 2006-01-11 | Wood-plastic composite material prepared from polyolefin (PE, PP)/oak powder/ionomer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1821295A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7923477B2 (en) | 2006-01-20 | 2011-04-12 | Material Innovations Llc | Carpet waste composite |
| CN101497718B (en) * | 2008-12-26 | 2011-05-11 | 上海国成塑料有限公司 | Preparation and use of PP/PE environment friendly fense composite material |
| CN102307723A (en) * | 2008-12-19 | 2012-01-04 | 纤维复合有限责任公司 | Wood-plastic composites utilizing ionomer capstocks and methods of manufacture |
| CN103112071A (en) * | 2011-11-17 | 2013-05-22 | 上海通用汽车有限公司 | Automobile interior part and manufacturing method thereof |
| CN104418980A (en) * | 2013-08-29 | 2015-03-18 | 合肥杰事杰新材料股份有限公司 | Nickel-maleate-grafted polypropylene ionomer as well as preparation method and application thereof |
| CN104890340A (en) * | 2015-04-03 | 2015-09-09 | 太仓旭莱自动化机械有限公司 | Outdoor high-weatherability high-strength co-extrusion wood composite floor and manufacturing process thereof |
| CN105885171A (en) * | 2016-05-19 | 2016-08-24 | 合肥庭索环保材料有限公司 | Friction-resistant anti-oxidation floor and preparation method thereof |
| CN110172258A (en) * | 2019-05-30 | 2019-08-27 | 上海互见创意设计有限公司 | A kind of composite polyolefine material and preparation method thereof containing coffee grounds |
| CN111393716A (en) * | 2020-05-20 | 2020-07-10 | 深圳市科思飞科技有限公司 | Paper powder-containing polyolefin composite material and preparation method thereof |
| CN112679860A (en) * | 2020-12-15 | 2021-04-20 | 上海金发科技发展有限公司 | Special polypropylene composition for automobile hard plastic blasting instrument board and preparation method thereof |
| CN112745569A (en) * | 2020-12-08 | 2021-05-04 | 金发科技股份有限公司 | Injection molding grade polypropylene wood-plastic composite material and preparation method thereof |
| US11572646B2 (en) | 2020-11-18 | 2023-02-07 | Material Innovations Llc | Composite building materials and methods of manufacture |
-
2006
- 2006-01-11 CN CN 200610005590 patent/CN1821295A/en active Pending
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11773592B2 (en) | 2006-01-20 | 2023-10-03 | Material Innovations Llc | Carpet waste composite |
| US7923477B2 (en) | 2006-01-20 | 2011-04-12 | Material Innovations Llc | Carpet waste composite |
| US10294666B2 (en) | 2006-01-20 | 2019-05-21 | Material Innovations Llc | Carpet waste composite |
| US8278365B2 (en) | 2006-01-20 | 2012-10-02 | Material Innovations Llc | Carpet waste composite |
| US10822798B2 (en) | 2006-01-20 | 2020-11-03 | Material Innovations Llc | Carpet waste composite |
| US8455558B2 (en) | 2006-01-20 | 2013-06-04 | Material Innovations Llc | Carpet waste composite |
| US9637920B2 (en) | 2006-01-20 | 2017-05-02 | Material Innovations Llc | Carpet waste composite |
| US8809406B2 (en) | 2006-01-20 | 2014-08-19 | Material Innovations Llc | Carpet waste composite |
| CN102307723B (en) * | 2008-12-19 | 2014-06-04 | 纤维复合有限责任公司 | Wood-plastic composites utilizing ionomer capstocks and methods of manufacture |
| US9073295B2 (en) | 2008-12-19 | 2015-07-07 | Fiber Composites, Llc | Wood-plastic composites utilizing ionomer capstocks and methods of manufacture |
| US10875281B2 (en) | 2008-12-19 | 2020-12-29 | Fiber Composites Llc | Wood-plastic composites utilizing ionomer capstocks and methods of manufacture |
| CN102307723A (en) * | 2008-12-19 | 2012-01-04 | 纤维复合有限责任公司 | Wood-plastic composites utilizing ionomer capstocks and methods of manufacture |
| CN101497718B (en) * | 2008-12-26 | 2011-05-11 | 上海国成塑料有限公司 | Preparation and use of PP/PE environment friendly fense composite material |
| CN103112071A (en) * | 2011-11-17 | 2013-05-22 | 上海通用汽车有限公司 | Automobile interior part and manufacturing method thereof |
| CN103112071B (en) * | 2011-11-17 | 2015-09-16 | 上海通用汽车有限公司 | Automotive upholstery and manufacture method thereof |
| CN104418980B (en) * | 2013-08-29 | 2018-01-26 | 合肥杰事杰新材料股份有限公司 | A kind of maleic acid nickel graft polypropylene ionomer and preparation method and application |
| CN104418980A (en) * | 2013-08-29 | 2015-03-18 | 合肥杰事杰新材料股份有限公司 | Nickel-maleate-grafted polypropylene ionomer as well as preparation method and application thereof |
| CN104890340B (en) * | 2015-04-03 | 2017-03-15 | 太仓旭莱自动化机械有限公司 | A kind of outdoor high-weatherability high intensity co-extruded plastic-wood composite floor board and its manufacturing process |
| CN104890340A (en) * | 2015-04-03 | 2015-09-09 | 太仓旭莱自动化机械有限公司 | Outdoor high-weatherability high-strength co-extrusion wood composite floor and manufacturing process thereof |
| CN105885171A (en) * | 2016-05-19 | 2016-08-24 | 合肥庭索环保材料有限公司 | Friction-resistant anti-oxidation floor and preparation method thereof |
| CN110172258A (en) * | 2019-05-30 | 2019-08-27 | 上海互见创意设计有限公司 | A kind of composite polyolefine material and preparation method thereof containing coffee grounds |
| CN111393716A (en) * | 2020-05-20 | 2020-07-10 | 深圳市科思飞科技有限公司 | Paper powder-containing polyolefin composite material and preparation method thereof |
| CN111393716B (en) * | 2020-05-20 | 2022-03-11 | 深圳市科思飞科技有限公司 | Paper powder-containing polyolefin composite material and preparation method thereof |
| US11572646B2 (en) | 2020-11-18 | 2023-02-07 | Material Innovations Llc | Composite building materials and methods of manufacture |
| CN112745569A (en) * | 2020-12-08 | 2021-05-04 | 金发科技股份有限公司 | Injection molding grade polypropylene wood-plastic composite material and preparation method thereof |
| CN112679860A (en) * | 2020-12-15 | 2021-04-20 | 上海金发科技发展有限公司 | Special polypropylene composition for automobile hard plastic blasting instrument board and preparation method thereof |
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