CN1818036A - High-clean methanol composite gasoline for vehicle and production thereof - Google Patents
High-clean methanol composite gasoline for vehicle and production thereof Download PDFInfo
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- CN1818036A CN1818036A CN 200610020511 CN200610020511A CN1818036A CN 1818036 A CN1818036 A CN 1818036A CN 200610020511 CN200610020511 CN 200610020511 CN 200610020511 A CN200610020511 A CN 200610020511A CN 1818036 A CN1818036 A CN 1818036A
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Abstract
The invention is about the high clearing methanol compound petrol which is composed of the methanol, the petrol, the acetone, the isopropyl ether, the isopropanol, the isoamylol, the tert-butyl alcohol and the synthetic addition agent. The addition agent is modulated by the ZnO, the Na2O2, the ferrum naphthenate and the isopropyl nitrate. The compound petrol can solve the problem of the corrosivity to the red copper and the swelling to the rubber. It can be mixed with the normal petrol arbitrarily and not need to change the structure of the engine, also it can remove the carbon and the colloid of the engine. The cost of the technique is low and the operability is high.
Description
Technical field
The present invention relates to a kind of technical formula and modulator approach thereof of novel vehicle fuel, relate in particular to a kind of high-clean methanol composite gasoline for vehicle and preparation method thereof.
Background technology
The world today is to the dependence of the energy, especially to the dependence of the automobile-used energy, arrived inseparable degree, and limited oil reserves and produced quantity are difficult to satisfy the growing demand of people, and oil price grows to even greater heights, people can't bear the heavy load, even more serious is, exists the danger of oil starvation, oil-break at any time, is threatening the economic security of country.How to utilize existing resource, effectively integrate,, reduce single dependence, become people's common recognition oil to replenish and even to substitute existing petrochemical industry gasoline.China is like this, and countries in the world are also like this.
That methyl alcohol comes to this, also be the characteristics that tally with the national condition most, have one of alternate resources of development prospect most.The high-clean methanol composite gasoline for vehicle (calling methanol gasoline in the following text) that methyl alcohol and existing petrochemical industry gasoline are formed by the suitable proportion mixed dissolution, in the effect modulated of solubility promoter and synthetic additive, identical with existing petrochemical industry gasoline property, performance is close, and increase, can under the situation that does not change existing automobile engine system structure, directly use, also can mix use arbitrarily with existing petrochemical industry gasoline, compatible good, very convenient, and cost is cheaper.
At present, methanol content is that 15% following petrochemical industry gasoline content is ripe in the methanol gasoline more than 85% (being M15) technology, and has come into operation.If but its economic benefit and substitution of resources amplitude are unsatisfactory.For this reason, content is that the methanol gasoline technology, particularly content of 30%-70% is 50% methanol gasoline (being M50, down together) technology, just becomes people's favorite, thereby also becomes the emphasis of scientific research personnel's tackling key problem.
Annotate: this ratio methanol gasoline, scientific and technological content is the highest, the technical difficulty maximum, and value of exploiting and utilizing is also maximum, has strategic importance.
Summary of the invention
Purpose of the present invention, exactly in order to overcome the technology barrier of M50 methanol gasoline, provide a kind of sophisticated, can be mass-produced to realize the M50 high-clean methanol composite gasoline for vehicle product of industrialization.
The present invention's technology, realize in the following manner:
A kind of high-clean methanol composite gasoline for vehicle is characterized in that: be made up of following weight percentages:
Methyl alcohol 35-55%
90# petrochemical industry gasoline 35-55%
Acetone 1-3%
Isopropyl ether 1-5%
Virahol 1-3%
Primary isoamyl alcohol 1-3%
Trimethyl carbinol 1-3%
Cerous nitrate 1-3%
Synthetic additive 3-7%
This synthetic additive is made up of following weight percentages:
Active zinc flower accounts for the 10-25% of synthetic additive total amount
Sodium peroxide accounts for the 3-7% of synthetic additive total amount
Iron naphthenate accounts for the 5-10% of synthetic additive total amount
Isopropyl nitrate accounts for the 7-15% of synthetic additive total amount
Triethylamine accounts for the 15-25% of synthetic additive total amount
Dimethylbenzene accounts for the 30-40% of synthetic additive total amount
Described high-clean methanol composite gasoline for vehicle is characterized in that, optimum weight per-cent is:
Methyl alcohol 41.5%
90# petrochemical industry gasoline 41.5%
Acetone 1.5%
Isopropyl ether 3.5%
Virahol 1.5%
Primary isoamyl alcohol 1.5%
The trimethyl carbinol 1.5%
Cerous nitrate 2.5%
Synthetic additive 5%
Synthetic additive is by being made up of following weight percentages:
Active zinc flower accounts for 20% of synthetic additive total amount
Sodium peroxide accounts for 5% of synthetic additive total amount
Iron naphthenate accounts for 8% of synthetic additive total amount
Isopropyl nitrate accounts for 12% of synthetic additive total amount
Triethylamine accounts for 20% of synthetic additive total amount
Dimethylbenzene accounts for 35% of synthetic additive total amount
The high-clean methanol composite gasoline for vehicle making method:
(1) cerous nitrate and methyl alcohol are mixed in proportion, dissolve, and modulation generates mother liquor A;
(2) mother liquor A and petrochemical industry gasoline are mixed in proportion, dissolve, and modulation generates mother liquor B;
(3) acetone, isopropyl ether, Virahol, primary isoamyl alcohol and the trimethyl carbinol are added successively in proportion mixing among the mother liquor B, dissolving, modulation generates mother solution C;
(4) at last synthetic additive is slowly added in the mother solution C, after mixing, dissolving, continue again to stir 60 minutes, left standstill 30 minutes.
(5) detect attribute, performance perameter is adjusted to required standard, detects, promptly obtain the technology of the present invention product---high-clean methanol composite gasoline for vehicle after qualified.
The characteristics of the technology of the present invention:
The effect of acetone, Virahol, primary isoamyl alcohol, the trimethyl carbinol: stack performance, raising calorific value and octane value.And methyl alcohol and gasoline are ideally dissolved, be closely linked.
The effect of isopropyl ether, cerous nitrate: change the methyl alcohol physico-chemical property, to improve its startability, frost resistance and warming-up.
Synthetic additive effect: improve the dynamic performance of product, combustionproperty, clean-up performance, roadholding.Simultaneously, reject corrodibility and the swelling property of product to parts.
The present technique systematicness is good, good manufacturability, compatible good, good security, good economy performance, the feature of environmental protection are good.Low cost product has good startability, dynamic performance, combustionproperty, the capability of antidetonance, corrosion resistance, clean-up performance and rate of economizing gasoline; Thoroughly solved methanol gasoline original to red copper corrodibility and to the swelling property problem of rubber.Compare with existing petrochemical industry gasoline, rate of fuel consumption is low, and exhaust emissions obviously reduces, can mix use arbitrarily with existing petrochemical industry gasoline, need not to change existing vehicle engine system structure, and can effectively remove the carbon distribution and the colloid of engine, life-time service, the work-ing life that can improve engine.
Products production facility investment ratio is little, starts easily, and is workable.
Road test shows: the technology of the present invention product, and dynamic property and rate of fuel consumption are suitable with petrochemical industry gasoline, and combustionproperty and environmental-protecting performance then obviously are better than petrochemical industry gasoline; Not only motor vehicle exhaust reduces significantly, and removes colloid, carbon distribution, and life-time service can improve the working life of motor car engine.Be specially adapted to city and plains region.
Embodiment 1:
1, synthetic additive is by being made up of following weight percentages: weight unit Kg
Active zinc flower 20, sodium peroxide 5, iron naphthenate 8, isopropyl nitrate 12, triethylamine 20, dimethylbenzene 35, synthetic additive is made in blending;
2, get the raw materials ready: take by weighing methyl alcohol 500Kg, 90# petrochemical industry gasoline 500Kg, acetone 15Kg, isopropyl ether 35Kg, Virahol 15Kg, primary isoamyl alcohol 15Kg, trimethyl carbinol 15Kg, cerous nitrate 25Kg, synthetic additive 50Kg, arrangement is deposited stand-by respectively;
3, cerous nitrate (25Kg) and methyl alcohol (500Kg) mixing and stirring, dissolving generate mother liquor A;
4, get gasoline (500Kg) and mother liquor A mixing and stirring, dissolving, generate mother liquor B;
5, get acetone (15Kg), isopropyl ether (35Kg), Virahol (15Kg), primary isoamyl alcohol (15Kg), the trimethyl carbinol (15Kg) and add in proportion among the mother liquor B successively, stir, dissolve, generate mother solution C;
6, slowly add synthetic additive (50Kg) in the mother solution C at last, after mixing, dissolving, continue to stir again 60 minutes, leave standstill 30 minutes after, promptly obtain the technology of the present invention product---high-clean methanol composite gasoline for vehicle (technology quality index is equivalent to existing petrochemical industry gasoline 97#).
Embodiment 2:
1, synthetic additive formulation weight unit K g, active zinc flower 10, sodium peroxide 3, iron naphthenate 5, isopropyl nitrate 8, triethylamine 15, dimethylbenzene 35, synthetic additive is made in blending;
2, take by weighing methyl alcohol 350Kg, 90# petrochemical industry gasoline 400Kg, acetone 15Kg, isopropyl ether 20Kg, Virahol 12Kg, primary isoamyl alcohol 12Kg, trimethyl carbinol 12Kg, cerous nitrate 25Kg, synthetic additive 60Kg, arrangement is deposited stand-by respectively;
3, all the other steps are identical with embodiment 1.
Embodiment 3:
1, synthetic additive formulation weight unit K g, active zinc flower 23, sodium peroxide 6, iron naphthenate 10, isopropyl nitrate 15, triethylamine 23, dimethylbenzene 40, synthetic additive is made in blending;
2, take by weighing methyl alcohol 500Kg, 90# petrochemical industry gasoline 500Kg, acetone 20Kg, isopropyl ether 40Kg, Virahol 28Kg, primary isoamyl alcohol 28Kg, trimethyl carbinol 28Kg, cerous nitrate 28Kg, synthetic additive 60Kg, arrangement is deposited stand-by respectively;
3, all the other steps are identical with embodiment 1.
Claims (3)
1, a kind of high-clean methanol composite gasoline for vehicle is characterized in that, is made up of following weight percentages:
Methyl alcohol 35-55%
90# petrochemical industry gasoline 35-55%
Acetone 1-3%
Isopropyl ether 1-5%
Virahol 1-3%
Primary isoamyl alcohol 1-3%
Trimethyl carbinol 1-3%
Cerous nitrate 1-3%
Synthetic additive 3-7%
This synthetic additive is made up of following weight percentages:
Active zinc flower accounts for the 10-25% of synthetic additive total amount
Sodium peroxide accounts for the 3-7% of synthetic additive total amount
Iron naphthenate accounts for the 5-10% of synthetic additive total amount
Isopropyl nitrate accounts for the 7-15% of synthetic additive total amount
Triethylamine accounts for the 15-25% of synthetic additive total amount
Dimethylbenzene accounts for the 30-40% of synthetic additive total amount
According to the described high-clean methanol composite gasoline for vehicle of claim 1, it is characterized in that 2, optimum weight per-cent is:
Methyl alcohol 41.5%
90# petrochemical industry gasoline 41.5%
Acetone 1.5%
Isopropyl ether 3.5%
Virahol 1.5%
Primary isoamyl alcohol 1.5%
The trimethyl carbinol 1.5%
Cerous nitrate 2.5%
Synthetic additive 5.0%
Synthetic additive is made up of following weight percentages:
Active zinc flower accounts for 20% of synthetic additive total amount
Sodium peroxide accounts for 5% of synthetic additive total amount
Iron naphthenate accounts for 8% of synthetic additive total amount
Isopropyl nitrate accounts for 12% of synthetic additive total amount
Triethylamine accounts for 20% of synthetic additive total amount
Dimethylbenzene accounts for 35% of synthetic additive total amount
3, high-clean methanol composite gasoline for vehicle according to claim 1 is characterized in that the following steps of making method:
(1) cerous nitrate and methyl alcohol are mixed in proportion, dissolve, and modulation generates mother liquor A;
(2) mother liquor A and existing petrochemical industry gasoline are mixed in proportion, dissolve, and modulation generates mother liquor B;
(3) acetone, isopropyl ether, Virahol, primary isoamyl alcohol and the trimethyl carbinol are added successively in proportion mixing among the mother liquor B, dissolving, modulation generates mother solution C;
(4) at last synthetic additive is slowly added in the mother solution C, after mixing, dissolving, continue again to stir 60 minutes, left standstill 30 minutes; Promptly get the technology of the present invention product---high-clean methanol composite gasoline for vehicle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100205115A CN100516180C (en) | 2006-03-20 | 2006-03-20 | High-clean methanol composite gasoline for vehicle and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100205115A CN100516180C (en) | 2006-03-20 | 2006-03-20 | High-clean methanol composite gasoline for vehicle and production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1818036A true CN1818036A (en) | 2006-08-16 |
| CN100516180C CN100516180C (en) | 2009-07-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100205115A Expired - Fee Related CN100516180C (en) | 2006-03-20 | 2006-03-20 | High-clean methanol composite gasoline for vehicle and production thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914398A (en) * | 2010-08-25 | 2010-12-15 | 开滦能源化工股份有限公司 | Methanol gasoline additive for vehicles and preparation method thereof |
| US7854774B2 (en) | 2006-05-26 | 2010-12-21 | Amyris Biotechnologies, Inc. | Fuel components, fuel compositions and methods of making and using same |
| CN101195771B (en) * | 2007-12-19 | 2012-02-15 | 北京金鑫世纪电力环保科技有限公司 | Composite gasoline of methanol and method for producing the same |
| CN102911752A (en) * | 2012-11-08 | 2013-02-06 | 许建忠 | Methanol gasoline multipurpose additive and application thereof |
| US9200296B2 (en) | 2006-05-26 | 2015-12-01 | Amyris Inc. | Production of isoprenoids |
| CN105331404A (en) * | 2015-11-19 | 2016-02-17 | 福州顺升科技有限公司 | Environment-friendly gasoline additive and preparation method thereof |
| CN105670712A (en) * | 2014-11-21 | 2016-06-15 | 张淑芹 | High-clean low-carbon-emission liquid fuel |
| CN109536217A (en) * | 2018-12-26 | 2019-03-29 | 福建贵福新能源科技有限公司 | A kind of methanol gasoline and preparation method thereof |
-
2006
- 2006-03-20 CN CNB2006100205115A patent/CN100516180C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7854774B2 (en) | 2006-05-26 | 2010-12-21 | Amyris Biotechnologies, Inc. | Fuel components, fuel compositions and methods of making and using same |
| US9200296B2 (en) | 2006-05-26 | 2015-12-01 | Amyris Inc. | Production of isoprenoids |
| US10106822B2 (en) | 2006-05-26 | 2018-10-23 | Amyris, Inc. | Production of isoprenoids |
| CN101195771B (en) * | 2007-12-19 | 2012-02-15 | 北京金鑫世纪电力环保科技有限公司 | Composite gasoline of methanol and method for producing the same |
| CN101914398A (en) * | 2010-08-25 | 2010-12-15 | 开滦能源化工股份有限公司 | Methanol gasoline additive for vehicles and preparation method thereof |
| CN102911752A (en) * | 2012-11-08 | 2013-02-06 | 许建忠 | Methanol gasoline multipurpose additive and application thereof |
| CN102911752B (en) * | 2012-11-08 | 2014-09-03 | 许建忠 | Methanol gasoline multipurpose additive and application thereof |
| CN105670712A (en) * | 2014-11-21 | 2016-06-15 | 张淑芹 | High-clean low-carbon-emission liquid fuel |
| CN105331404A (en) * | 2015-11-19 | 2016-02-17 | 福州顺升科技有限公司 | Environment-friendly gasoline additive and preparation method thereof |
| CN105331404B (en) * | 2015-11-19 | 2018-07-31 | 任志清 | A kind of environment protection type gasoline additive and preparation method thereof |
| CN109536217A (en) * | 2018-12-26 | 2019-03-29 | 福建贵福新能源科技有限公司 | A kind of methanol gasoline and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100516180C (en) | 2009-07-22 |
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Effective date of registration: 20060907 Address after: 11G, five the Great Wall, Choi Choi Road, Shenzhen, Guangdong, Futian District Applicant after: Xiao Jun Co-applicant after: Lu Jun Co-applicant after: Gu Meiquan Address before: 11G, five the Great Wall, Choi Choi Road, Shenzhen, Guangdong, Futian District Applicant before: Gu Meiquan Co-applicant before: Xiao Jun Co-applicant before: Pu Yuequan |
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