CN1817979A - Non-benzene blending oil - Google Patents
Non-benzene blending oil Download PDFInfo
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- CN1817979A CN1817979A CN 200610038142 CN200610038142A CN1817979A CN 1817979 A CN1817979 A CN 1817979A CN 200610038142 CN200610038142 CN 200610038142 CN 200610038142 A CN200610038142 A CN 200610038142A CN 1817979 A CN1817979 A CN 1817979A
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- blending oil
- benzene
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Abstract
A non-benzene gold blending oil consists of resin, solvent and printing ink accessory. It has good viscosity and wetting ability, better transparency, quick drying and curing performances.
Description
Technical field
The present invention relates to a kind of blending oil, is to be used for being in harmonious proportion bronze, silver powder in the printing process, makes the material of printing gold and silver color ink, is particularly suitable for the gold and silver look printing blending oil in the yew paper, and it is made up of resin, solvent, ink addition agent.
Background technology
The same with other printing ink, the gold and silver China ink mainly also is made of pigment and low-melting ink vehicle two parts, and briefly, Jin Mo is formed by bronze and blending oil allotment, and Yin Mo is by aluminium powder and transfers silver oil (also being blending oil) allotment to form.Low-melting ink vehicle is the liquid component in the printing ink, and on the one hand, it is the carrier of pigment, and pulverous granules of pigments can be disperseed therein equably, and on the other hand, it makes pigment finally can anchor at the stock material surface also as a kind of tackiness agent.Low-melting ink vehicle has determined viscosity, viscosity, flowability and the drying property of printing ink to a great extent, and therefore, the quality of low-melting ink vehicle directly affects the performance of printing ink.The low-melting ink vehicle that is adopted in the gold and silver China ink is a kind of special stand linseed oil, is commonly referred to as blending oil or transfers silver oil, and generally its main component is resin, organic solvent subsidiary material.Traditional gold and silver look prints employed stand linseed oil, is the benzene solvent type, though this type of blending oil stable components can guarantee that the abundant dissolving of bronze, silver powder disperses, reach comparatively ideal printing effect, yet it must make solvent with benzene class material.Benzene is the bigger solvent of a kind of toxicity, and its harm is embodied in: the accumulation harm that (1) is healthy to the human consumer to the pollution (3) of environment to the infringement (2) of operative employee's health, particularly hemopoietic function.Volatilizedly fall though the benzene solvent that adds in the printing-ink is most of in drying course, finally on finished product, still have a certain amount of residually, accumulate over a long period the healthy generation of human consumer is endangered.
Yew paper (claiming cigarette tipping paper again) is that a kind of cigarette that is used for props up the special paper of using that is connected with filter stick.Yew paper is a kind of print product.Its manufacturing process is: on tipping base paper, be medium with printing ink, through polychrome printing, oven dry, gold stamping, operation such as cut and process.Traditional yew paper gold and silver look printing also is to adopt benzene solvent type blending oil.Traditional yew paper gold and silver look printing also is to adopt benzene solvent type blending oil, because yew paper directly contacts with people's oral cavity, thereby the security of its printing material just seems especially important.
Summary of the invention
The object of the present invention is to provide a kind of blending oil that does not contain benzene, be meant the blending oil that is applied on the yew paper especially, promptly adopt the blending oil that does not contain benzene, make yew paper containing benezene material not in printing process and behind the finished product, to stop of the harm of benzene class material, can guarantee good printing effect again simultaneously to human consumer's health and environment.
Its composition weight percent proportioning of blending oil of the present invention is; The n-propyl acetate of the dibutyl phthalate of 10%-40% acrylic resin, 5%-10% nitro-cotton resin, 1%-6% or dioctyl ester, 10%-40%, the ethyl acetate of 20%-40%, the stopping composition of 0.5%-3.5%, wherein stopping composition can be conventional pigment precast body or transparent pigment.
Its composition weight percent proportioning of the preferred blending oil of the present invention is; The n-propyl acetate of the dibutyl phthalate of 20%-30% acrylic resin, 5%-10% nitro-cotton resin, 3%-6% or dioctyl ester, 30%-40%, the ethyl acetate of 17.5%-30%, the stopping composition of 1%-3.5%.
Resin, solvent, ink addition agent that above-mentioned weight percent proportioning is formed mix, can mix stirring reaction with the speed (guaranteeing that fully each component mixes) that is not less than 600 rev/mins at normal temperatures and pressures, through 1-3 hour, product is emitted filtration, obtains non-benzene blending oil.
The blending oil of the gravure gold and silver China ink of gained of the present invention our experiments show that to have following effect; 1: enough viscosity and wettability are arranged, can combine with bronze or silver powder well.2: transparency is very high, and the form and aspect to the gold and silver China ink do not exert an influence.3: also possessing has quick-drying and fast solidity, and the set-off phenomenon does not take place for Jin Mo or silver-colored ink print product, and the set-off phenomenon does not particularly definitely take place in very thin yew gold ink or silver-colored ink print.
Experimental technique wherein for example be yew paper in the printing process of golden silver color pattern and character, adopt the blending oil and the non-benzene kind solvent of the non-benzene class of the present invention series.Bronze silver powder is metal-powder, and the order number is the 800-1200 order, and solvent adopts n-propyl acetate.
Soak with n-propyl acetate earlier, bronze, solvent ratios are 1: 1-2; Soak the back and add non-benzene blending oil, the ratio of bronze, blending oil is 2-3: 8-7.After fully stirring, add solvent again and adjust to yew paper and print needed viscosity, last machine printing just can obtain above-mentioned effect conclusion through such yew paper print product is tested.
Embodiment
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Acrylic resin nitro-cotton resin dibutyl phthalate n-propyl acetate ethyl acetate stopping composition | 20％ 10％ 6％ 30％ 30％ 3.5％ | 25％ 8％ 4％ 32％ 28％ 1％ | 30％ 5％ 3％ 40％ 17.5％ 2％ |
| Embodiment 4 | Embodiment 5 | |
| Acrylic resin nitro-cotton resin dibutyl phthalate n-propyl acetate ethyl acetate stopping composition | 10％ 10％ 6％ 30.5％ 40％ 3.5％ | 40％ 5％ 3％ 30％ 20％ 2％ |
The effect of embodiment of the invention product can describe by three groups of contrast experiments that exemplify:
The black A of gold: common benzene solvent type blending oil+moon palace bronze (1200 order)
The black B of gold: embodiment 1+ moon palace bronze (1200 order)
The black C of gold: embodiment 2+ moon palace bronze (1200 order)
Each golden black proportioning is during printing: blending oil: bronze=7: 3, golden black viscosity is identical.Printing press is a CMR intaglio plate four-color machine, and printing element is the white tipping base papers of 35 grams.
Experimental result is as follows:
Wherein: the attachment fastness specimen is full version printing gold China ink.Test is measured the method for inspection by printing ink attachment fastness among the QJ/LKD34-2005 and is carried out.
The dissolvent residual test is HS/GC head space-vapor-phase chromatography by " by the residual solvent on the headspace analysis method detection wrapping material ".
By above-mentioned experiment as can be seen, non-benzene blending oil has residual extremely low, sticking power is high, printing effect the is good characteristics of benzene class material.
The yew paper product of the non-benzene blending oil product printing of adopting the foregoing description is carried out the paper dissolvent residual detect, and satisfied following requirement: the total content of residual solvent is no more than 50mg/m
2, wherein toluene, dimethylbenzene total amount≤0.2mg/m
2, the content of benzene≤0.01% in the blending oil.
Claims (2)
1, a kind of non-benzene blending oil is characterized in that its composition weight percent proportioning is: the n-propyl acetate of the dibutyl phthalate of 10%-40% acrylic resin, 5%-10% nitro-cotton resin, 1%-6% or dioctyl ester, 10%-40%, the ethyl acetate of 20%-40%, the stopping composition of 0.5%-3.5%.
2,, it is characterized in that its composition weight percent proportioning is according to the described non-benzene blending oil of claim 1; The n-propyl acetate of the dibutyl phthalate of 20%-30% acrylic resin, 5%-10% nitro-cotton resin, 3%-6% or dioctyl ester, 30%-40%, the ethyl acetate of 17.5%-30%, the stopping composition of 1%-3.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100381422A CN100460473C (en) | 2006-01-27 | 2006-01-27 | Non-benzene blending oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100381422A CN100460473C (en) | 2006-01-27 | 2006-01-27 | Non-benzene blending oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1817979A true CN1817979A (en) | 2006-08-16 |
| CN100460473C CN100460473C (en) | 2009-02-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2006100381422A Active CN100460473C (en) | 2006-01-27 | 2006-01-27 | Non-benzene blending oil |
Country Status (1)
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| CN (1) | CN100460473C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100528985C (en) * | 2006-08-30 | 2009-08-19 | 西安理工大学 | Bronze ink prepared by copper zinc powder coated surface modifier and preparation method |
| CN102382503A (en) * | 2011-09-16 | 2012-03-21 | 广西真龙彩印包装有限公司 | Gravure non-benzene printing ink and manufacture method thereof |
| CN102608683A (en) * | 2012-04-13 | 2012-07-25 | 深圳市华星光电技术有限公司 | Reflector forming method and reflective liquid crystal display prepared by adopting method |
| CN103254687A (en) * | 2013-05-24 | 2013-08-21 | 东莞市锐达涂料有限公司 | High-temperature resistant ester-soluble printing ink |
| CN103711040A (en) * | 2013-11-25 | 2014-04-09 | 龙游特美纸制品有限公司 | Production method for cigarette white tipping paper |
| CN103711039A (en) * | 2013-11-25 | 2014-04-09 | 龙游特美纸制品有限公司 | Processing method for cigarette white tipping paper |
| CN103725086A (en) * | 2014-01-15 | 2014-04-16 | 云南侨通包装印刷有限公司 | High-performance water-based golden ink for gravure printing and preparation method thereof |
| US8913218B2 (en) | 2012-04-13 | 2014-12-16 | Shenzhen China Star Optoelectronics Technology Co., Ltd. | Method for forming reflector and reflective liquid crystal display manufactured with same |
| CN104403407A (en) * | 2014-12-09 | 2015-03-11 | 武汉虹之彩包装印刷有限公司 | Silver ink with good metal printing effect and printing process using silver ink |
| CN109354919A (en) * | 2018-10-22 | 2019-02-19 | 江苏泰格油墨有限公司 | A kind of antibacterial glazing varnish of cigarette tipping paper and preparation method thereof |
| CN116144215A (en) * | 2023-03-27 | 2023-05-23 | 湖南福瑞印刷有限公司 | High-gloss bright silver ink with transfer paper imitation effect and preparation method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1011242B (en) * | 1988-09-01 | 1991-01-16 | 孙国华 | A kind of water-based inks and its production and use |
| CN1069504A (en) * | 1992-07-16 | 1993-03-03 | 张展洪 | The production method of water soluble internal use nitrocellulose lacquer without benzene poison |
| JP2002363242A (en) * | 2001-06-11 | 2002-12-18 | Toyo Ink Mfg Co Ltd | Polyurethane resin, printing ink composition and printed product |
| CN1243802C (en) * | 2003-05-27 | 2006-03-01 | 王尔建 | Solvent type gold-mixed oil for gravure and flexible print |
-
2006
- 2006-01-27 CN CNB2006100381422A patent/CN100460473C/en active Active
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100528985C (en) * | 2006-08-30 | 2009-08-19 | 西安理工大学 | Bronze ink prepared by copper zinc powder coated surface modifier and preparation method |
| CN102382503A (en) * | 2011-09-16 | 2012-03-21 | 广西真龙彩印包装有限公司 | Gravure non-benzene printing ink and manufacture method thereof |
| US8913218B2 (en) | 2012-04-13 | 2014-12-16 | Shenzhen China Star Optoelectronics Technology Co., Ltd. | Method for forming reflector and reflective liquid crystal display manufactured with same |
| CN102608683A (en) * | 2012-04-13 | 2012-07-25 | 深圳市华星光电技术有限公司 | Reflector forming method and reflective liquid crystal display prepared by adopting method |
| CN103254687A (en) * | 2013-05-24 | 2013-08-21 | 东莞市锐达涂料有限公司 | High-temperature resistant ester-soluble printing ink |
| CN103254687B (en) * | 2013-05-24 | 2014-10-29 | 东莞市锐达涂料有限公司 | High-temperature resistant ester-soluble printing ink |
| CN103711040A (en) * | 2013-11-25 | 2014-04-09 | 龙游特美纸制品有限公司 | Production method for cigarette white tipping paper |
| CN103711039A (en) * | 2013-11-25 | 2014-04-09 | 龙游特美纸制品有限公司 | Processing method for cigarette white tipping paper |
| CN103725086A (en) * | 2014-01-15 | 2014-04-16 | 云南侨通包装印刷有限公司 | High-performance water-based golden ink for gravure printing and preparation method thereof |
| CN104403407A (en) * | 2014-12-09 | 2015-03-11 | 武汉虹之彩包装印刷有限公司 | Silver ink with good metal printing effect and printing process using silver ink |
| CN104403407B (en) * | 2014-12-09 | 2016-05-25 | 武汉虹之彩包装印刷有限公司 | The Yin Mo that a kind of type metal is effective and use the typography of this ink |
| CN109354919A (en) * | 2018-10-22 | 2019-02-19 | 江苏泰格油墨有限公司 | A kind of antibacterial glazing varnish of cigarette tipping paper and preparation method thereof |
| CN116144215A (en) * | 2023-03-27 | 2023-05-23 | 湖南福瑞印刷有限公司 | High-gloss bright silver ink with transfer paper imitation effect and preparation method and application thereof |
| CN116144215B (en) * | 2023-03-27 | 2024-03-15 | 湖南楠海科技有限公司 | High-gloss bright silver ink with transfer paper imitation effect and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100460473C (en) | 2009-02-11 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Likeda Packing Co., Ltd. Assignor: Yang Qingqing Contract fulfillment period: 2009.2.2 to 2015.2.1 Contract record no.: 2009330000299 Denomination of invention: Non-benzene blending oil Granted publication date: 20090211 License type: Exclusive license Record date: 20090218 |
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| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.2.2 TO 2015.2.1; CHANGE OF CONTRACT Name of requester: LIKEDA PACKING CO., LTD. Effective date: 20090218 |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170515 Address after: 325000 No. twelve, No. 458 Binhai Road, Wenzhou economic and Technological Development Zone, Wenzhou, Zhejiang Patentee after: WENZHOU LIKEDA PRINTING CO., LTD. Address before: 325000 Zhejiang Province, Wenzhou city Lucheng District East Court No. 16 Room 403 Patentee before: Yang Qingqing |
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| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address |
Address after: 325000 No. twelve, No. 458 Binhai Road, Wenzhou economic and Technological Development Zone, Zhejiang, China Patentee after: Zenghwa Packaging Co.,Ltd. Address before: 325000 No. twelve, No. 458 Binhai Road, Wenzhou economic and Technological Development Zone, Wenzhou, Zhejiang Patentee before: WENZHOU LIKEDA PRINTING INDUSTRY Co.,Ltd. |
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| CP03 | Change of name, title or address |