CN1807380A - Alcohol liquid phase catalytic oxidation method and catalyst reactivation method - Google Patents

Alcohol liquid phase catalytic oxidation method and catalyst reactivation method Download PDF

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CN1807380A
CN1807380A CNA200610033781XA CN200610033781A CN1807380A CN 1807380 A CN1807380 A CN 1807380A CN A200610033781X A CNA200610033781X A CN A200610033781XA CN 200610033781 A CN200610033781 A CN 200610033781A CN 1807380 A CN1807380 A CN 1807380A
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alcohol
catalyzer
catalyst
liquid phase
catalytic oxidation
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CN100424061C (en
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余皓
王红娟
彭峰
傅小波
冯景贤
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South China University of Technology SCUT
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

The invention provides a liquid-phase catalytic oxidation method for alcohol and catalyst recovery. Wherein, with nano RuO2 hydrate particle carried on nano carbon tube as catalyst, oxidating the alcohol into opposite aldehyde or ketone with molecular oxygen as oxidant; while, using H2O2 to recover the catalyst completely. Compared with prior art, this invention has high selectivity and activity, and avoids pollution and erosion.

Description

The liquid phase catalytic oxidation method of alcohol and the renovation process of catalyzer thereof
Technical field
The present invention relates to a kind of liquid phase catalytic oxidation method and catalyst regeneration process thereof of alcohol.
Background technology
Liquid alcohol oxidation system aldehydes or ketones is very important organic chemical reactions process, has a wide range of applications in the production of extensive chemical industry production and fine chemical product.Its reaction expression is as follows:
(R, R '=alkyl, aromatic base or hydrogen atom) traditional method for oxidation is to adopt strong oxidizers such as chromic acid, permanganic acid, because the toxicity of these oxygenants self and drawback such as can not recycle and reuse has caused very big harm to environment.Therefore people wish with oxygen or air as cleaning oxidizer, utilize the catalyzer of solid phase to realize the liquid phase catalytic oxidation of alcohols.
The alcohols catalyzed oxidation had the compound that active material mainly comprises metals such as Ru, Pd, Cu, Co, Cr, Os.Wherein Ru is easy to form organic complex, and organo-metallic Ru shows excellent selecting catalytic performance energy in numerous organic reactions.But because noble metal catalyst is difficult to separate in the homogeneous reaction, thereby make it use possibility hardly repeatedly, increased the cost of the difficulty and the process of technology.Therefore people wish that exploitation takes into account reactive behavior, heterogeneous alcohol catalytic oxidation process optionally.Present studies show that, in solid catalyst, precious metal such as Ru, Pt, Pd and compound thereof embody best catalytic activity.Wherein Ru is owing to superior performance, and cost of material is cheap relatively, especially comes into one's own.For solid catalyst, studies show that the RuO that comprises of pure oxidation activity based on Ru 2, Ru, Ru (OH) 3Deng.Theoretical investigation shows, these activity of such catalysts derive from Ru (110) crystal face and similar structures thereof, and (Over H.et al, Science 2000,287, p1474).Because nano level RuO 2Or its hydrate has similar microstructure, therefore embodies good alcohol catalysis oxidation activity.When with RuO 2(p2195), active and selectivity all has significantly to be improved for Zhan B.Z.et al, Journal Of The American Chemical Society 2003,125 to make nanoparticle.Above precious metal can be loaded to Al 2O 3, on the carrier such as hydrotalcite, hydroxyapatite, molecular sieve, but also there are many deficiencies in the catalyzer of these loadizations at present, for example active undesirable, diffusional limitation etc.In some cases, the coming off of active ingredient, sex change or leach and also may make catalyst deactivation.Wherein in use the inactivation of catalyzer is to contain a general difficult problem that is run in the noble metal catalyst use.
Carbon nanotube is the novel nano-material that comes into one's own in recent years, and it all has good application prospects at aspects such as fiber reinforcement, nano electron devices.Recently, the application of carbon nanotube aspect support of the catalyst begins to get more and more people's extensive concerning.When with it during as support of the catalyst, the high-ratio surface that its small size caused provides sufficient room for load; The chemical reaction that carbon nano tube surface is abundant provides wide chemically modified possibility; The tubular structure of carbon nanotube uniqueness can weaken diffusional resistance greatly; Especially for the reaction that relates to electric transmission, the quantum electroconductibility of carbon nanotube uniqueness has original promoter action to catalyzed reaction.Therefore with nano level RuO 2Or its hydrate is carried on carbon nanotube highly active oxidation of alcohols catalyzer may be provided.
In disclosed patented technology, patent CN1286648, CN1454201 disclose solid-phase catalyst and have been used for the method for alcohols catalyzed oxidation, but do not relate to carbon nanotube loaded nanometer RuO 2Or the katalysis of its hydrate.(Arabale G.et al, Chemical Physics Letters 2003,376 p207) have reported carbon nanotube loaded RuO to document 2Technological method, but do not see that it is used for the report of alcohols catalyzed oxidation.Up to the present, still not with carbon nanotube loaded RuO 2And hydrate is used for the open report of liquid phase alcohols catalytic oxidation.Because the importance of inactivation problem in noble metal catalyst is used, patent CN1201405, CN1107757 disclose the renovation process of ruthenium catalyst.
Summary of the invention
The object of the present invention is to provide a kind of liquid phase catalytic oxidation method of alcohol, utilize the nanometer RuO of load on carbon nanotube 2Hydrate particles becomes corresponding aldehydes or ketones as catalyzer with oxidation of alcohols, avoids the environmental pollution and the equipment corrosion of traditional oxidant stoichiometry, and catalyzer such as can't reclaim at problem.
The invention still further relates to the renovation process of the catalyzer of described method employing.
The liquid phase catalytic oxidation method of alcohol of the present invention is characterized in that comprising the steps:
(1) substrate alcohol and the solvent with liquid phase contacts with the catalyzer of solid phase, and alcohol is 0.5～5: 1 with the weight ratio of catalyzer, forms solid-liquid two-phase suspension by stirring;
(2) feeding is warming up to 50～100 ℃, back flow reaction 0.5～10 hour as the air or oxygen of oxygenant in suspension;
(3) suspension that will react after finishing separates, and obtains the liquid phase catalytic oxidation product and the solid-phase catalyst of alcohol, and described catalyzer is carbon nanotube supported nanometer hydrated ru oxide.
In step (1), (2), oxidizing condition is: alcohol is 0.5～2: 1 with the weight ratio of catalyzer; 60～80 ℃ of temperature of reaction; Reaction times 2～6h.
Described alcohol is Fatty Alcohol(C12-C14 and C12-C18), cycloalkanol or aromatic alcohol.
The renovation process of the catalyzer that described method adopts is with used solid catalyst, slowly drips the hydrogen peroxide of mass concentration 28%, and hydrogen peroxide solution is 50～200: 1 with the catalyst weight ratio; Stirring also is warming up to 60～90 ℃, and back flow reaction 0.5～6h after filtration, obtains the regenerated catalyzer.
Hydrogen peroxide is 100～150: 1 with the catalyst weight ratio; Stirring also is warming up to 70～80 ℃, back flow reaction 2～4h.
Carbon nanotube loaded nanometer RuO of the present invention 2The charge capacity of Ru is 2%～50% in the hydrate catalyzer, can be by comprising the prepared in various methods of following process.Clear for illustrating, set forth a kind of carbon nanotube loaded nano hydrated RuO for preparing herein 2The concrete grammar of catalyzer, but should not regard limitation of the present invention as.Many wall/Single Walled Carbon Nanotube are joined in the ruthenium trichloride solution that contains dispersion agent PVP, PEG, SDS, CTAB etc.; At room temperature, mix with hydrogen peroxide; Be warming up to 50-100 ℃, back flow reaction 2～6h; Filtration, washing, drying make carbon nanotube loaded nano hydrated RuO 2
Adopt carbon nanotube loaded hydration RuO 2Catalyst oxidation liquid phase alcohol has high reaction activity and high and good reaction preference.Technology of the present invention is used for various typical Fatty Alcohol(C12-C14 and C12-C18), cycloalkanol, aromatic alcohol, when these alcohol are dissolved in the toluene, carry out liquid-phase catalytic oxidation, reaction product Agilent 6820 gas chromatographic analysiss that capillary column is housed, transformation efficiency after its 4 hours all can reach more than 99% selectivity 100% (table 1).And as the hydration RuO that adopts other preparing carriers 2During catalyzer, similarity condition is active down all not as carbon nanotube loaded hydration RuO 2Catalyzer (table 2).Reclaiming process of the present invention allows the recovery of catalyzer to reuse, catalyzer can separate by direct filtration, only need this catalyzer is carried out as manipulation of regeneration of the present invention, can make catalyzer recover initial activity fully, therefore can save the noble metal catalyst cost, reduce environmental pollution (Fig. 1).
Table 1
Figure A20061003378100051
Table 2
Catalyzer Reaction times Transformation efficiency Selectivity
Hydration ru oxide/CNT (the present invention is used) hydration ru oxide/mesoporous molecular sieve hydration ru oxide/alkaline alundum (Al2O3) hydration ru oxide/4A molecular sieve hydration ru oxide/activated carbon hydration ru oxide/acid alundum (Al2O3) hydration ru oxide/magnesia 1 hour 1 hour 1 hour 1 hour 1 hour 1 hour 1 hour 71.8％ 57.4％ 43.5％ 38.5％ 21.3％ 13.9％ 0.3％ ＞99％ ＞99％ ＞99％ ＞99％ ＞99％ ＞99％ ＞99％
The present invention compared with prior art has following advantage and effect:
(1) the present invention adopts carbon nanotube loaded RuO 2Hydrate is as catalyzer, can use molecular oxygen catalytic alcohol oxidation under the condition of gentleness, selectivity is good, the reactive behavior height, compare with catalyzer with the homogeneous oxidizing agent of generally adopting at present, separate easily, reusable, fields such as, biochemical industry synthetic for fine chemistry industry, medicine have superiority;
(2) the used catalyst system of the present invention has selectivity completely to the alcohols reaction substrate;
(3) catalyst regeneration process provided by the invention can make catalyzer recover active fully, can adapt to the requirement of long-term production, has saved the cost of noble metal catalyst;
(4) the used carbon nanotube loaded nano hydrated ru oxide catalyzer of the present invention, the hydration ru oxide catalyzer than reporting other carriers of use such as gac, molecular sieve, aluminium sesquioxide, magnesium oxide even load has higher catalytic effect.
Description of drawings
Fig. 1 the inventive method is used for the transformation efficiency design sketch of benzyl alcohol oxidation.
Embodiment
The liquid phase catalytic oxidation embodiment 1 of alcohol
0.05g phenylcarbinol (aromatic alcohol) is dissolved in the 3mL toluene, in solution, adds the carbon nanotube loaded hydration RuO of 0.1g 2Catalyzer, Ru charge capacity is 50% on it, alcohol is 0.5: 1 with the weight ratio of catalyzer.Under the situation of magnetic agitation, blast air; Be heated to 50 ℃, back flow reaction 10 hours.With Agilent6820 gas chromatographic analysis product component, product phenyl aldehyde selectivity is 100%, and the phenylcarbinol transformation efficiency is 95.8%.
The liquid phase catalytic oxidation embodiment 2 of alcohol
0.2g phenylcarbinol (aromatic alcohol) is dissolved in the 3mL toluene, in solution, adds the carbon nanotube loaded hydration RuO of 0.1g 2Catalyzer, Ru charge capacity is 10% on it, alcohol is 2: 1 with the weight ratio of catalyzer.
Under the situation of magnetic agitation, blast air; Be heated to 80 ℃, back flow reaction 2 hours.With Agilent 6820 gas chromatographic analysis product components, product phenyl aldehyde selectivity is 100%, and the phenylcarbinol transformation efficiency is 100%.
The liquid phase catalytic oxidation embodiment 3 of alcohol
0.5g phenylcarbinol (aromatic alcohol) is dissolved in the 3mL toluene, in solution, adds the carbon nanotube loaded hydration RuO of 0.1g 2Catalyzer, Ru charge capacity is 2% on it, alcohol is 5: 1 with the weight ratio of catalyzer.
Under the situation of magnetic agitation, blast oxygen; Be heated to 100 ℃, back flow reaction 0.5 hour.With Agilent6820 gas chromatographic analysis product component, product phenyl aldehyde selectivity is 100%, and the phenylcarbinol transformation efficiency is 72%.
The liquid phase catalytic oxidation embodiment 4 of alcohol
0.3g hexalin (cycloalkanol) is dissolved in the 3mL toluene, in solution, adds the carbon nanotube loaded hydration RuO of 0.1g 2Catalyzer, Ru charge capacity is 10% on it, alcohol is 3: 1 with the weight ratio of catalyzer.
Under the situation of magnetic agitation, blast oxygen and air mixture; Be heated to 60 ℃, back flow reaction 6 hours.With Agilent 6820 gas chromatographic analysis product components, product hexamethylene aldehyde selectivity is 100%, and the hexalin transformation efficiency is 95.8%.
The liquid phase catalytic oxidation embodiment 5 of alcohol
0.2g n-Heptyl alcohol (Fatty Alcohol(C12-C14 and C12-C18)) is dissolved in the 3mL toluene, in solution, adds the carbon nanotube loaded hydration RuO of 0.1g 2Catalyzer, Ru charge capacity is 15% on it, alcohol is 2: 1 with the weight ratio of catalyzer.
Under the situation of magnetic agitation, blast air; Be heated to 70 ℃, back flow reaction 4 hours.With Agilent 6820 gas chromatographic analysis product components, product enanthaldehyde selectivity 100%, the n-Heptyl alcohol transformation efficiency is 100%.
Catalyst regeneration embodiment 1
Solid catalyst, drying are filtered, isolated to reaction product among the liquid phase catalytic oxidation embodiment 2 of alcohol.The gained solid catalyst places the 10mL deionized water, slowly splashes into the hydrogen peroxide solution of concentration 28% with volume pump; Hydrogen peroxide solution is 200: 1 with the catalyst weight ratio; Stirring also is warming up to 60 ℃, and back flow reaction 6h after filtration, obtains the regenerated catalyzer.This solid catalyst is repeated the process of the liquid phase catalytic oxidation embodiment 2 of alcohol.With Agilent 6820 gas chromatographic analysis product components, product phenyl aldehyde selectivity is 100%, and the phenylcarbinol transformation efficiency is 100%.Catalyst activity recovers fully.
Catalyst regeneration embodiment 2
Solid catalyst, drying are filtered, isolated to reaction product among the liquid phase catalytic oxidation embodiment 3 of alcohol.The gained solid catalyst places the 10mL deionized water, slowly splashes into the hydrogen peroxide solution of concentration 28% with volume pump; Hydrogen peroxide solution is 50: 1 with the catalyst weight ratio; Stirring also is warming up to 90 ℃, and back flow reaction 0.5h after filtration, obtains the regenerated catalyzer.This solid catalyst is repeated the process of the liquid phase catalytic oxidation embodiment 3 of alcohol.With Agilent 6820 gas chromatographic analysis product components, product phenyl aldehyde selectivity is 100%, and the phenylcarbinol transformation efficiency is 72%.Catalyst activity recovers fully.
Catalyst regeneration embodiment 3
Solid catalyst, drying are filtered, isolated to reaction product among the liquid phase catalytic oxidation embodiment 4 of alcohol.The gained solid catalyst places the 10mL deionized water, slowly splashes into the hydrogen peroxide solution of concentration 28% with volume pump; Hydrogen peroxide solution is 100: 1 with the catalyst weight ratio; Stirring also is warming up to 70 ℃, and back flow reaction 4h after filtration, obtains the regenerated catalyzer.This solid catalyst is repeated the process of the liquid phase catalytic oxidation embodiment 4 of alcohol.With Agilent 6820 gas chromatographic analysis product components, product hexamethylene aldehyde selectivity is 100%, and the hexalin transformation efficiency is 95.8%.Catalyst activity recovers fully.
Catalyst regeneration embodiment 4
Solid catalyst, drying are filtered, isolated to reaction product among the liquid phase catalytic oxidation embodiment 5 of alcohol.The gained solid catalyst places the 10mL deionized water, slowly splashes into the hydrogen peroxide solution of concentration 28% with volume pump; Hydrogen peroxide solution is 150: 1 with the catalyst weight ratio; Stirring also is warming up to 80 ℃, and back flow reaction 2h after filtration, obtains the regenerated catalyzer.This solid catalyst is repeated the process of the liquid phase catalytic oxidation embodiment 5 of alcohol.With Agilent 6820 gas chromatographic analysis product components, product enanthaldehyde selectivity is 100%, and the n-Heptyl alcohol transformation efficiency is 100%.Catalyst activity recovers fully.

Claims (5)

1, a kind of liquid phase catalytic oxidation method of alcohol is characterized in that comprising the steps:
(1) substrate alcohol and the solvent with liquid phase contacts with the catalyzer of solid phase, and alcohol is 0.5～5: 1 with the weight ratio of catalyzer, forms solid-liquid two-phase suspension by stirring;
(2) feeding is warming up to 50～100 ℃, back flow reaction 0.5～10 hour as the air or oxygen of oxygenant in suspension;
(3) suspension that will react after finishing separates, and obtains the liquid phase catalytic oxidation product and the solid-phase catalyst of alcohol, and described catalyzer is carbon nanotube supported nanometer hydrated ru oxide.
2, method according to claim 1 is characterized in that oxidizing condition is in step (1), (2): alcohol is 0.5～2: 1 with the weight ratio of catalyzer; 60～80 ℃ of temperature of reaction; Reaction times 2～6h.
3, method according to claim 1 and 2 is characterized in that described alcohol is Fatty Alcohol(C12-C14 and C12-C18), cycloalkanol or aromatic alcohol.
4, the renovation process of the catalyzer that adopts according to the described method of one of claim 1-3 is characterized in that used solid catalyst is slowly dripped the hydrogen peroxide of mass concentration 28%, and hydrogen peroxide solution is 50～200: 1 with the catalyst weight ratio; Stirring also is warming up to 60～90 ℃, and back flow reaction 0.5～6h after filtration, obtains the regenerated catalyzer.
5, method according to claim 4 is characterized in that hydrogen peroxide and catalyst weight ratio are 100～150: 1; Stirring also is warming up to 70～80 ℃, back flow reaction 2～4h.
CNB200610033781XA 2006-02-23 2006-02-23 Alcohol liquid phase catalytic oxidation method and catalyst reactivation method Expired - Fee Related CN100424061C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
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WO2009079713A1 (en) * 2007-12-24 2009-07-02 The University Of Sydney Method of oxidising organic compounds
CN101890369A (en) * 2010-06-30 2010-11-24 重庆大学 Liquid-solid phase loaded catalyst used in production of acetic acid and preparation method thereof
CN101745411B (en) * 2008-12-17 2013-03-13 中国科学院大连化学物理研究所 Catalyst using ruthenium based halogen to substitute hydroxyapatite and preparation and application thereof
EP2957342A4 (en) * 2013-02-14 2016-10-19 Microbial Chem Res Found Catalyst and method for producing optically active anti-1,2-nitroalkanol compound
CN110368928A (en) * 2019-07-29 2019-10-25 陕西科技大学 A kind of catalyst and its preparation method and application for benzyl alcohol oxidation synthesizing benzaldehyde
CN112427035A (en) * 2020-11-24 2021-03-02 吉林大学 High-dispersion supported ruthenium hydroxide catalyst, preparation method and application thereof in selective oxidation of alcohol
CN112691655A (en) * 2020-12-23 2021-04-23 东莞理工学院 Controllable preparation method of defective carbon nanotube catalyst and application of catalyst in preparation of corresponding ketone by catalytic conversion of alcohol
CN115819201A (en) * 2022-11-22 2023-03-21 江苏万隆化学有限公司 Green synthesis process of o-chlorobenzaldehyde catalyzed by titanium silicalite molecular sieve

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Cited By (13)

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WO2009079713A1 (en) * 2007-12-24 2009-07-02 The University Of Sydney Method of oxidising organic compounds
CN101745411B (en) * 2008-12-17 2013-03-13 中国科学院大连化学物理研究所 Catalyst using ruthenium based halogen to substitute hydroxyapatite and preparation and application thereof
CN101890369A (en) * 2010-06-30 2010-11-24 重庆大学 Liquid-solid phase loaded catalyst used in production of acetic acid and preparation method thereof
CN101890369B (en) * 2010-06-30 2012-05-23 重庆大学 Liquid-solid phase loaded catalyst used in production of acetic acid and preparation method thereof
US9901913B2 (en) 2013-02-14 2018-02-27 Microbial Chemistry Research Foundation Catalyst and method for producing optically active anti-1,2-nitroalkanol compound
TWI607803B (en) * 2013-02-14 2017-12-11 公益財團法人微生物化學研究會 Catalyst, and method for producing optically active anti-1,2-nitroalkanol compound
EP2957342A4 (en) * 2013-02-14 2016-10-19 Microbial Chem Res Found Catalyst and method for producing optically active anti-1,2-nitroalkanol compound
CN110368928A (en) * 2019-07-29 2019-10-25 陕西科技大学 A kind of catalyst and its preparation method and application for benzyl alcohol oxidation synthesizing benzaldehyde
CN110368928B (en) * 2019-07-29 2022-05-17 陕西科技大学 Catalyst for synthesizing benzaldehyde by oxidizing benzyl alcohol and preparation method and application thereof
CN112427035A (en) * 2020-11-24 2021-03-02 吉林大学 High-dispersion supported ruthenium hydroxide catalyst, preparation method and application thereof in selective oxidation of alcohol
CN112691655A (en) * 2020-12-23 2021-04-23 东莞理工学院 Controllable preparation method of defective carbon nanotube catalyst and application of catalyst in preparation of corresponding ketone by catalytic conversion of alcohol
CN112691655B (en) * 2020-12-23 2023-05-30 东莞理工学院 Controllable preparation method of defective carbon nanotube catalyst and application thereof in preparing corresponding ketone by catalytic conversion of alcohol
CN115819201A (en) * 2022-11-22 2023-03-21 江苏万隆化学有限公司 Green synthesis process of o-chlorobenzaldehyde catalyzed by titanium silicalite molecular sieve

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