CN1803915A - Method for preparing defoaming, dehumidifying and drying mother stock for ABS(acrylonitrile- butadiene-styrene copolymer) plastic processing - Google Patents
Method for preparing defoaming, dehumidifying and drying mother stock for ABS(acrylonitrile- butadiene-styrene copolymer) plastic processing Download PDFInfo
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- CN1803915A CN1803915A CN 200510112383 CN200510112383A CN1803915A CN 1803915 A CN1803915 A CN 1803915A CN 200510112383 CN200510112383 CN 200510112383 CN 200510112383 A CN200510112383 A CN 200510112383A CN 1803915 A CN1803915 A CN 1803915A
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Abstract
The related preparation method for defoaming and dehumidifying masterbatch used in ABS plastic process comrpises: using CaO as the defoaming and dehumidifying agent, stearate as disperser for CaO, and both random copolymeric polypropylene and EPT rubber as surface modifier; blending, dispersing, and preparing the bead-shaped particles. This invention eliminates heat and dehumidification to reduce opposite investment and consumption even the comprehensive process cost greatly, and has bright application future in ABS process field.
Description
One, technical field
The present invention relates to a kind of preparation method of masterbatch, particularly relate to the preparation method of a kind of ABS (Acrylonitrile-butadiene-styrene Copolymer) plastic working with defoaming, dehumidifying and drying mother stock.
Two, background technology
ABS resin is to be formed by vinyl cyanide, divinyl and three kinds of monomer copolymerizations of vinylbenzene.ABS resin has rigidity, surface hardness and the height chemical stability of polyacrylonitrile concurrently, the good workability of polystyrene and glossiness, and the shock resistance of polyhutadiene, toughness and elasticity, be widely used in car industry and electric industry as universal thermoplastic engineering plastic.
The mechanical mechanics property of ABS plastic goods directly influences the ABS plastic Products Quality, and the factor that influences ABS plastic products machinery mechanical property comprises the control of product defect in the performance of ABS plastic starting material own and the ABS plastic product molding course of processing.
ABS plastic is a macromolecular material, and its goods processing normally prepares by melt extruding with last cooling forming.ABS plastic absorbs airborne moisture content easily, and these moisture content can be vaporized in the high temperature process process, makes the ABS plastic goods produce bubble and hole, causes the decline significantly of ABS plastic products machinery mechanical property.Usually in the processing,, mainly take before processing, to use the method for baking oven for heating baking dehumidifying in order to remove the moisture content in ABS plastic and other starting material.The method that adds heat abstraction moisture content, extra heating and dehumidification equipment need be acquired by plastic working enterprise, increases by one complete processing program and production human cost, consumes a large amount of electric energy, causes the comprehensive cost of ABS plastic goods to increase substantially.
The froth breaking dehumidifying masterbatch production technology that is used for polyolefin plastics, existing both at home and abroad patent documentation report.Because the singularity of the The Nomenclature Composition and Structure of Complexes of ABS resin is different with polyolefin plastics, the development difficulty of defoaming, dehumidifying and drying mother stock that is specifically designed to ABS plastic is bigger, and practical application is more rare.
Three, summary of the invention
The purpose of this invention is to provide a kind of energy elimination and absorb water vapor, the bubble that ABS plastic adds the generation in man-hour, can make ABS plastic before processing, avoid toasting the defoaming, dehumidifying and drying mother stock of drying and product properties raising.
The present invention is achieved in that
ABS (acrylonitrile-divinyl-styrol copolymer) plastic working is characterized in that comprising the preparation technology of defoaming, dehumidifying and drying agent, functional aid, vector resin, defoaming, dehumidifying and drying agent surface treatment method, defoaming, dehumidifying and drying mother stock with the preparation method of defoaming, dehumidifying and drying mother stock.The defoaming, dehumidifying and drying agent content is 70～83wt%, vector resin 5～20wt%, functional aid 5～21wt% in the defoaming, dehumidifying and drying mother stock.
Described defoaming, dehumidifying and drying agent is a calcium oxide.
Described vector resin is EVA (ethene-acetate ethylene copolymer), EAA (ethene-acrylic copolymer), MBS (methacrylic acid-divinyl-styrol copolymer), polystyrene, AS (vinyl cyanide-styrol copolymer), BS (divinyl-styrol copolymer), ABS (Acrylonitrile-butadiene-styrene Copolymer), PVAC (polyvinyl acetate), PS/PMAA segmented copolymer or graft copolymer, PA/PMAA segmented copolymer or graft copolymer, in ethylene-propylene rubber(EPR) and the chlorinatedpolyethylene one or both and two or more mixtures.
Described functional aid (1) coupling agent: one or both in silane coupling agent, titanate coupling agent, aluminate coupling agent, rare-earth coupling agent, the aluminium titanium composite coupler and two or more mixtures; (2) lubrication dispersing agent: one or both in paraffin, polyethylene wax, oxidized polyethlene wax, Poly Propylene Wax, lipid acid, soap, fatty amide, the fatty acid ester and two or more mixtures.(3) properties-correcting agent: one or both in atactic copolymerized polypropene, vinylbenzene-divinyl-styrol copolymer, ethene-octene copolymer elastomerics, the terpolymer EP rubber and two or more mixtures.The total content of functional aid is 4～13wt% in the masterbatch, and wherein coupling agent is that 1～3wt%, lubrication dispersing agent are that 2～8wt%, properties-correcting agent are 2～10wt%.
Described preparation method is made of following steps:
1. in high-speed mixer, processing is carried out coating the first time in defoaming, dehumidifying and drying agent surface with lubrication dispersing agent and coupling agent by high-speed stirring;
2. in high-speed mixer, under 100～120 degrees centigrade of high-speed stirring conditions, the defoaming, dehumidifying and drying agent is carried out coating second time processing with properties-correcting agent;
3. the back coats processing with vector resin for the third time to the defoaming, dehumidifying and drying agent;
4. compound joins in the pill tablets press through rubbing ball, granulation with the hands, sieving and make ABS (acrylonitrile-divinyl-styrol copolymer) plastic working defoaming, dehumidifying and drying mother stock.
The present invention utilizes calcium oxide and water reaction can generate calcium hydroxide, and calcium hydroxide decomposition reaction can not take place when Celsius more than 200 spend.Thereby utilize calcium oxide and the trace water in the ABS plastic in the ABS defoaming, dehumidifying and drying mother stock to react the trace water of eliminating among the ABS.
In the ABS plastic course of processing, other starting material do not need through preheating the technology of dehumidifying in ABS plastic and the prescription, only need efficient defoaming, dehumidifying and drying master batch of the present invention and ABS plastic etc. are mixed together evenly, directly melt molding processing, in the course of processing, but the calcium oxide rapid absorption vaporization moisture content strong to moisture content absorption, and react with water, eliminate steam fast, avoid plastics to produce cavitation damages such as bubble, guarantee the degree of compactness of plastics and high mechanical mechanics property.Saved heating and dehumidification technology in the common plastic working process, reduced the investment of plastic working business equipment, reduced production human cost and power consumption, reduced the comprehensive production cost of plastics, for the plastic working industry provides a kind of new high-quality functional master batch product.
Preparation technology of the present invention is simple, and preparation process does not have the three wastes and produces.The ABS defoaming, dehumidifying and drying mother stock of the present invention's preparation can be used for the froth breaking dehumidifying of ABS plastic injection-molded item and extrusion moulding product.
The invention has the beneficial effects as follows:
1, the baking drying need increase formal personnel's input of producing before before the ABS plastic processing that saves labour turnover traditional, and whole process of production need to continue artificial, and adopt the ABS plastic defoaming, dehumidifying and drying mother stock as long as simply can drop into processing after the mixing with the ABS plastic particle, do not need extra the input manually.
2, need not to increase roasting plant
The baking drying need be purchased roasting plant before traditional ABS plastic processing, and produces the equipment amortization expense, uses the ABS defoaming, dehumidifying and drying mother stock then not need other procuring equipment, does not have Abschreibungskosten.
3, save electric energy in a large number
The dry at least 120 degree electricity that need to consume per ton of baking use the ABS defoaming, dehumidifying and drying mother stock then not need additionally to increase power consumption before traditional ABS plastic processing.
4, reduce raw-material loss
The baking drying process moisture that can run off is generally 1～2% of weight before the processing of traditional ABS plastic, and uses the ABS defoaming, dehumidifying and drying mother stock to absorb total not loss of raw material weight behind the moisture content.
5, help cleaner production
Baking drying operation environment can produce noise and bisque pollution before traditional ABS plastic processing, thereby increases the labor insurance fees expenditure, uses the ABS defoaming, dehumidifying and drying mother stock then to make become between entire operation cleaning, health, few bisque.
6, enhance productivity
The baking drying equals to have increased drying process one before traditional ABS plastic processing, prolongs process period, and uses the ABS defoaming, dehumidifying and drying mother stock need not increase operation, saves process period, enhances productivity.
Embodiment one:
The ABS plastic defoaming, dehumidifying and drying mother stock, preparation method's step is as follows:
(1), gets 75 kilograms in the calcium oxide of ratio of weight and number, 17 kilograms of ABS resin, 1.5 kilograms of calcium stearates, 1.5 kilograms of aluminate coupling agents, 5 kilograms of atactic copolymerized polypropenes;
(2), the raw material of above-mentioned ratio of weight and number is put into the stirring mixing roll, when stirring material temperature to 100 ℃, become premix, then premix is put into the round bead shape particle that pellet processing machine twists into 5 millimeters of diameters, promptly make the ABS plastic defoaming, dehumidifying and drying mother stock.
Embodiment two:
The ABS plastic defoaming, dehumidifying and drying mother stock, preparation method's step is as follows:
(1), gets 70 kilograms in the calcium oxide of ratio of weight and number, 20 kilograms of ABS resin, 2 kilograms of Zinic stearass, 2 kilograms of titanate coupling agents, 6 kilograms of terpolymer EP rubbers;
(2), the raw material of above-mentioned ratio of weight and number is put into the stirring mixing roll, when stirring material temperature to 100 ℃, become premix, then premix is put into the round bead shape particle that pellet processing machine twists into 5 millimeters of diameters, promptly make the ABS plastic defoaming, dehumidifying and drying mother stock.
Claims (5)
1, ABS (acrylonitrile-butadiene-styrene copolymer) plastic working is characterized in that comprising the preparation technology of defoaming, dehumidifying and drying agent, functional aid, vector resin, defoaming, dehumidifying and drying agent surface treatment method, defoaming, dehumidifying and drying mother stock with the preparation method of defoaming, dehumidifying and drying mother stock.The defoaming, dehumidifying and drying agent content is 70～83wt%, vector resin 5～20wt%, functional aid 5～21wt% in the defoaming, dehumidifying and drying mother stock.
2, ABS according to claim 1 (acrylonitrile-butadiene-styrene copolymer) the plastic working preparation method of defoaming, dehumidifying and drying mother stock, it is characterized in that: the defoaming, dehumidifying and drying agent is a calcium oxide.
3, ABS according to claim 1 (acrylonitrile-butadiene-styrene copolymer) the plastic working preparation method of defoaming, dehumidifying and drying mother stock, it is characterized in that: vector resin is EVA (ethylene-vinyl acetate copolymer), EAA (ethylene-acrylic acid copolymer), MBS (Methacrylate-butadiene-styrene), polystyrene, AS (acrylonitritrile-styrene resin), BS (butadiene-styrene copolymer), ABS (acrylonitrile-butadiene-styrene copolymer), PVAC (polyvinyl acetate), PS/PMAA segmented copolymer or graft copolymer, PA/PMAA segmented copolymer or graft copolymer, in ethylene-propylene rubber(EPR) and the chlorinatedpolyethylene one or both and two or more mixtures.
4, ABS according to claim 1 (acrylonitrile-butadiene-styrene copolymer) plastic working is characterized in that: functional aid (1) coupling agent: one or both in silane coupling agent, titanate coupling agent, aluminate coupling agent, rare-earth coupling agent, the aluminium titanium composite coupler and two or more mixtures with the preparation method of defoaming, dehumidifying and drying mother stock; (2) lubrication dispersing agent: one or both in paraffin, polyethylene wax, oxidized polyethlene wax, Poly Propylene Wax, lipid acid, soap, fatty amide, the fatty acid ester and two or more mixtures.(3) properties-correcting agent: one or both in atactic copolymerized polypropene, styrene-butadiene-styrene multipolymer, ethylene-octene copolymer elastomerics, the terpolymer EP rubber and two or more mixtures.The total content of functional aid is 4～13wt% in the masterbatch, and wherein coupling agent is that 1～3wt%, lubrication dispersing agent are that 2～8wt%, properties-correcting agent are 2～10wt%.
5, according to the preparation method of the described ABS of claim 1～4 (acrylonitrile-butadiene-styrene copolymer) plastic working, it is characterized in that it is made of following steps with defoaming, dehumidifying and drying mother stock:
(1) in high-speed mixer, processing is carried out coating the first time in defoaming, dehumidifying and drying agent surface with lubrication dispersing agent and coupling agent by high-speed stirring;
(2) in high-speed mixer, under 100～120 degrees centigrade of high-speed stirring conditions, the defoaming, dehumidifying and drying agent is carried out coating second time processing with properties-correcting agent;
(3) back coats processing with vector resin for the third time to the defoaming, dehumidifying and drying agent;
(4) compound joins in the pill tablets press through rubbing ball, granulation with the hands, sieving and make ABS (acrylonitrile-butadiene-styrene copolymer) plastic working defoaming, dehumidifying and drying mother stock.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101123832A CN100366675C (en) | 2005-12-30 | 2005-12-30 | Method for preparing defoaming, dehumidifying and drying mother stock for ABS(acrylonitrile- butadiene-styrene copolymer) plastic processing |
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| CNB2005101123832A CN100366675C (en) | 2005-12-30 | 2005-12-30 | Method for preparing defoaming, dehumidifying and drying mother stock for ABS(acrylonitrile- butadiene-styrene copolymer) plastic processing |
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| CN1803915A true CN1803915A (en) | 2006-07-19 |
| CN100366675C CN100366675C (en) | 2008-02-06 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115609A (en) * | 2011-03-07 | 2011-07-06 | 周良文 | Dry type plastic material with moistureproof outer layer |
| CN102127247A (en) * | 2011-04-22 | 2011-07-20 | 连云港连连化学有限公司 | Environment-friendly defoaming masterbatch particles for rubber, and preparing and packaging methods thereof |
| CN103254546A (en) * | 2013-02-07 | 2013-08-21 | 胡君 | ABS color master batch and preparation process thereof |
| CN103627060A (en) * | 2012-08-21 | 2014-03-12 | 上海心尔新材料科技股份有限公司 | Long-acting defoaming dehumidifying drying master batch for plastic processing and preparation method thereof |
| CN104130495A (en) * | 2014-08-12 | 2014-11-05 | 廊坊华博环保材料有限公司 | Water removal master batch for plastic drip irrigation pipe or drip irrigation zone and preparation method of water removal master batch |
| CN104356520A (en) * | 2014-11-28 | 2015-02-18 | 山东阳谷华泰化工股份有限公司 | Calcium oxide pre-dispersion master colloidal particles as well as preparation method and application thereof |
| CN115301205A (en) * | 2022-09-19 | 2022-11-08 | 安徽工程大学 | Preparation method of sludge-based biochar granules and biochar granules |
Family Cites Families (3)
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| DE4408213B4 (en) * | 1994-03-11 | 2006-06-08 | Bayer Ag | ABS molding compounds with a light inherent color and improved thermostability and process for their preparation |
| DE19846244A1 (en) * | 1998-10-07 | 2000-04-13 | Basf Ag | Shaped body for the garden and animal husbandry area |
| CN1312217C (en) * | 2004-02-02 | 2007-04-25 | 山西新阳新材料有限公司 | Preparation method of ABS (acrilonitrile-butadiene-phenyl ethylene copolymer) functional filling mother particle |
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2005
- 2005-12-30 CN CNB2005101123832A patent/CN100366675C/en active Active
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115609A (en) * | 2011-03-07 | 2011-07-06 | 周良文 | Dry type plastic material with moistureproof outer layer |
| CN102127247A (en) * | 2011-04-22 | 2011-07-20 | 连云港连连化学有限公司 | Environment-friendly defoaming masterbatch particles for rubber, and preparing and packaging methods thereof |
| CN102127247B (en) * | 2011-04-22 | 2013-11-06 | 连云港连连化学有限公司 | Environment-friendly defoaming masterbatch particles for rubber, and preparing and packaging methods thereof |
| CN103627060A (en) * | 2012-08-21 | 2014-03-12 | 上海心尔新材料科技股份有限公司 | Long-acting defoaming dehumidifying drying master batch for plastic processing and preparation method thereof |
| CN103254546A (en) * | 2013-02-07 | 2013-08-21 | 胡君 | ABS color master batch and preparation process thereof |
| CN104130495A (en) * | 2014-08-12 | 2014-11-05 | 廊坊华博环保材料有限公司 | Water removal master batch for plastic drip irrigation pipe or drip irrigation zone and preparation method of water removal master batch |
| CN104130495B (en) * | 2014-08-12 | 2018-12-18 | 廊坊华博环保材料有限公司 | A kind of plastic drip irrigation tube or drip irrigation zone water removal masterbatch and preparation method thereof |
| CN104356520A (en) * | 2014-11-28 | 2015-02-18 | 山东阳谷华泰化工股份有限公司 | Calcium oxide pre-dispersion master colloidal particles as well as preparation method and application thereof |
| CN115301205A (en) * | 2022-09-19 | 2022-11-08 | 安徽工程大学 | Preparation method of sludge-based biochar granules and biochar granules |
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| CN100366675C (en) | 2008-02-06 |
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