CN1785871A - Glass ceramic containing phosphorus lithium aluminium silicon and its preparation method - Google Patents
Glass ceramic containing phosphorus lithium aluminium silicon and its preparation method Download PDFInfo
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- CN1785871A CN1785871A CN 200510061302 CN200510061302A CN1785871A CN 1785871 A CN1785871 A CN 1785871A CN 200510061302 CN200510061302 CN 200510061302 CN 200510061302 A CN200510061302 A CN 200510061302A CN 1785871 A CN1785871 A CN 1785871A
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- oxide
- glass
- ceramic
- lithium aluminium
- containing phosphorus
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- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 title claims description 11
- OEMGCAOEZNBNAE-UHFFFAOYSA-N [P].[Li] Chemical compound [P].[Li] OEMGCAOEZNBNAE-UHFFFAOYSA-N 0.000 title claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 12
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000292 calcium oxide Substances 0.000 claims abstract description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000137 annealing Methods 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims abstract description 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910001947 lithium oxide Inorganic materials 0.000 claims abstract description 3
- 238000002425 crystallisation Methods 0.000 claims description 10
- 230000008025 crystallization Effects 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- JRIGVWDKYXCHMG-UHFFFAOYSA-N (5-arsoroso-2-hydroxyphenyl)azanium;chloride Chemical compound Cl.NC1=CC([As]=O)=CC=C1O JRIGVWDKYXCHMG-UHFFFAOYSA-N 0.000 claims description 3
- IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 claims description 3
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 3
- 229910000413 arsenic oxide Inorganic materials 0.000 claims description 3
- 229960002594 arsenic trioxide Drugs 0.000 claims description 3
- 229950008475 oxophenarsine Drugs 0.000 claims description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229910001392 phosphorus oxide Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 5
- 229910052744 lithium Inorganic materials 0.000 abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 17
- 229910010413 TiO 2 Inorganic materials 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052785 arsenic Inorganic materials 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000006018 Li-aluminosilicate Substances 0.000 description 1
- 229910008556 Li2O—Al2O3—SiO2 Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- -1 phosphonium ion Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
Landscapes
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention discloses a glass ceramic containing phosphorus, lithium, aluminium and silicone. Its composition contains: (by wt%) 70% of silicone dioxide, 4% of lithium oxide, 15% of aluminium oxide, 0.9%-1% of magnesium oxide, 1%-1.1% of zinc oxide, 0.4%-0.5% of calcium oxide, 0.2% of boron oxide, 1.8%-3.2% of titanium oxide, 2.0%-2.3% of zirconium oxide, 2%-2.1% of mixture of potassium oxide and sodium oxide, 0.1%-1.6% of phosphorus pentoxide and 0.8% of mixture of arsenium oxide and antimony oxide. Its preparation method includes the following steps: grinding all the above-mentioned components, uniformly mixing them to obtain mixed material, melting at 1550-1650deg.C, forming, annealing, nucleating for 1-4hr at 600-800deg.C, then heating to 700-1000deg.C, crystallizing for 1-12hr so as to obtain the invented product.
Description
Technical field
The present invention relates to a kind of glass-ceramic and preparation method thereof, specifically, glass-ceramic of particularly phosphorous lithium aluminium silicon and preparation method thereof.
Background technology
Glass-ceramic is the polycrystalline solid material that is made by LAS glass control crystallization, wherein lithium aluminium silicon series (Li
2O-Al
2O
3-SiO
2Be called for short LAS) be main a kind of glass-ceramic, because of it has super-low expansion, high strength, high thermal shock resistance, and be widely used in making astronomical telescope, cooker, tableware, electromagnetic oven panel, high temperature electric light source glass, microelectronics with substrate, laboratory with heating appliances, high-temperature heat exchanger, for goods such as silica glass, window pyrometer, radome.
About described lithium aluminium silicon series glass-ceramic, in each communiques such as publication number CN 1306946A, 1495144A, 1054957A, 1607191A, 1333194A, 1005710B, 1486947A, 1054957A, 1597586A, the patent No. 97104801.0, lithium aluminium silicon series glass-ceramic and manufacture method thereof are disclosed.
The nucleus agent of lithium aluminium silicon series glass-ceramic at present is mainly TiO
2, in lithium aluminosilicate glass system, TiO
2Bigger solubleness is arranged in glass, and solubilized reaches 20% or higher; In addition, also help to reduce the viscosity of glass, promote the fusing of glass, make glass be easy to crystallization.But work as TiO
2When massfraction is excessive, may produce thick crystal grain, and the thermal expansivity of devitrified glass is increased; And TiO
2Can make the color yellowing of glass-ceramic, cause the color and luster quality to reduce.
Employing TiO is also arranged
2And ZrO
2As mixing the nucleus agent, result of study finds, has the physical strength of thinner crystal particle scale and Geng Gao than single with any prepared glass-ceramic in two kinds, but owing to ZrO
2Fusing point is very high, and the solubleness in glass is not high, makes it limited as the effect that improves forming core.
In recent years, the adding fluorochemical is arranged also, with it as nucleus agent or nucleus growth promotor, promote coring, the crystallization process of glass, can significantly reduce the recrystallization temperature and the crystallization power of glass, but also cause the too fast growth of crystal grain easily, and influence the structure and the performance of glass-ceramic.
P
2O
5Owing to have and from silicate network, to isolate the characteristic of phosphoric acid salt group, thereby can be used as the nucleus agent, be used as Li
2O-ZnO-SiO
2, Li
2O-PbO-SiO
2Deng the nucleus agent of glass system, also be used for the preparation of hydroxyapatite devitrified glass as nucleus agent and main composition.
Summary of the invention
At the deficiencies in the prior art part, the invention provides and a kind ofly can realize that grain-size reaches nano level, and the glass ceramic containing phosphorus lithium aluminium silicon that thermal expansivity is low, physical strength is high and preparation method thereof.
The present invention is to realize by such technical scheme for reaching above purpose: a kind of glass ceramic containing phosphorus lithium aluminium silicon is provided, and the weight percent of this glass-ceramic consists of: SiO
2(silicon-dioxide) 70%, Li
2O (Lithium Oxide 98min) 4%, Al
2O
3(aluminum oxide) 15%, MgO (magnesium oxide) 0.9%-1%, ZnO (zinc oxide) 1%-1.1%, CaO (calcium oxide) 0.4%-0.5%, B
2O
3(boron oxide) 0.2%, TiO
2(titanium oxide) 1.8%-3.2%, ZrO
2(zirconium white) 2.0%-2.3%, K
2O+Na
2O (mixture of potassium oxide and sodium oxide) 2%-2.1%, P
2O
5(five phosphorus oxide) 0.1%-1.6% and As
2O
3+ Sb
2O
3(mixture of arsenic oxide arsenoxide and weisspiessglanz) 0.8%.
Potassium oxide and sodium oxide be the weight ratio composition mixture arbitrarily, and wherein optimum weight ratio is: K
2O: Na
2O=1.1～1.
Arsenic oxide arsenoxide and weisspiessglanz be the weight ratio composition mixture arbitrarily.
The present invention also provides the preparation method of above-mentioned glass ceramic containing phosphorus lithium aluminium silicon: be configured to compound after grinding upper glass pottery moiety evenly, found moulding, annealing through 1550～1650 ℃; Through 600～800 ℃ of coring 1～4 hour, be warming up to 700～1000 ℃ of crystallization then and handled 1～12 hour again.
Glass ceramic containing phosphorus lithium aluminium silicon of the present invention and preparation method thereof obtains through scrutinizing, test the back the contriver.A kind of compound nucleus agent provided by the present invention is according to nucleus agent synergistic effect, at TiO
2And ZrO
2The basis on, introduce P
2O
5Form.On the one hand, utilize phosphonium ion P
5+Tetrahedral coordination and phosphoric acid salt network form ability, induce the glass phase-splitting, promote the nucleating course of glass; On the other hand, P
2O
5Can improve ZrO
2Solubleness, improve founding and ZrO of glass
2Nucleogenesis.
Glass-ceramic of the present invention is owing to adopt P
2O
5With TiO
2And ZrO
2Form compound nucleus agent, utilize " synergistic effect " of nucleus agent, impel a large amount of forming cores of glass, be equipped with accurate control coring, crystallization and thermal treatment process system, the control nucleus growth becomes crystal grain and grows up, and realizes that grain-size reaches nano level, and has low thermal expansivity and high physical strength.
The principal crystalline phase of glass-ceramic of the present invention is β-triphane (Li
2OAl
2O
3NSiO
2, n 〉=4), crystal shape is spherical, and grain-size is between 20～100nm, and thermal expansivity is 5～21 * 10 in 30～600 ℃ of scopes
-7/ ℃, bending strength is 110～150MPa.
Embodiment
Embodiment 1: a kind of glass ceramic containing phosphorus lithium aluminium silicon, and its weight percent consists of:
SiO
2?70％、Li
2O?4％、Al
2O
3?15％、MgO?1％、ZnO?1.1％、CaO?0.5％、B
2O
3?0.2％、TiO
2?3.2％、ZrO
2?2％、K
2O?1.1％、Na
2O?1.0％、P
2O
5?0.1％、As
2O
30.4％、Sb
2O
3?0.4％。
Be configured to compound after grinding above-mentioned glass-ceramic moiety evenly, found moulding, annealing through 1550～1650 ℃; Through 720 ℃ of coring 1.5 hours, be warming up to 810 ℃ of crystallization then and handled 4 hours again; Obtain folding strength 110～150MPa, the coefficient of expansion 5～21 * 10
-7/ ℃ glass-ceramic, the spheric grain size is between 20～100nm.
Embodiment 2: a kind of glass ceramic containing phosphorus lithium aluminium silicon, and its weight percent consists of:
SiO
2?70％、Li
2O?4％、Al
2O
3?15％、MgO?0.9％、ZnO?1.1％、CaO?0.5％、B
2O
3?0.2％、TiO
2?2.5％、ZrO
2?2.1％、K
2O?1.1％、Na
2O?1.0％、P
2O
5?0.8％、As
2O
3?0.4％、Sb
2O
3?0.4％。
Be configured to compound by above-mentioned each component, found through 1550～1650 ℃, moulding, annealing again through 740 ℃ of coring 1.5 hours, is warming up to 870 ℃ of crystallization then and handled 8 hours, obtains folding strength 110～150MPa, the coefficient of expansion 5～21 * 10
-7/ ℃ glass-ceramic, the spheric grain size is between 20～100nm.
Embodiment 3: a kind of glass ceramic containing phosphorus lithium aluminium silicon, and its weight percent consists of:
SiO
2?70％、Li
2O?4％、Al
2O
3?15％、MgO?0.9％、ZnO?1％、CaO?0.4％、B
2O
3?0.2％、TiO
2?1.8％、ZrO
2?2.3％、K
2O?1.0％、Na
2O?1.0％、P
2O
5?1.6％、As
2O
3?0.4％、Sb
2O
3?0.4％。
Be configured to compound by above-mentioned each component, found through 1550～1650 ℃, moulding, annealing again through 760 ℃ of coring 1.5 hours, is warming up to 950 ℃ of crystallization then and handled 4 hours, obtains folding strength 110～150MPa, the coefficient of expansion 5～21 * 10
-7/ ℃ glass-ceramic, the spheric grain size is between 20～100nm.
At last, it is also to be noted that what more than enumerate only is several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (2)
1, a kind of glass ceramic containing phosphorus lithium aluminium silicon is characterized in that the weight percent of this glass-ceramic consists of: the mixture 0.8% of the mixture 2%-2.1% of silicon-dioxide 70%, Lithium Oxide 98min 4%, aluminum oxide 15%, magnesium oxide 0.9%-1%, zinc oxide 1%-1.1%, calcium oxide 0.4%-0.5%, boron oxide 0.2%, titanium oxide 1.8%-3.2%, zirconium white 2.0%-2.3%, potassium oxide and sodium oxide, five phosphorus oxide 0.1%-1.6% and arsenic oxide arsenoxide and weisspiessglanz.
2, a kind of preparation method of glass ceramic containing phosphorus lithium aluminium silicon as claimed in claim 1 is characterized in that: be configured to compound after grinding described glass-ceramic moiety evenly, found moulding, annealing through 1550～1650 ℃; Through 600～800 ℃ of coring 1～4 hour, be warming up to 700～1000 ℃ of crystallization then and handled 1～12 hour again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100613020A CN100352782C (en) | 2005-10-28 | 2005-10-28 | Glass ceramic containing phosphorus lithium aluminium silicon and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100613020A CN100352782C (en) | 2005-10-28 | 2005-10-28 | Glass ceramic containing phosphorus lithium aluminium silicon and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1785871A true CN1785871A (en) | 2006-06-14 |
| CN100352782C CN100352782C (en) | 2007-12-05 |
Family
ID=36783491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100613020A Expired - Fee Related CN100352782C (en) | 2005-10-28 | 2005-10-28 | Glass ceramic containing phosphorus lithium aluminium silicon and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100352782C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101234852B (en) * | 2008-01-16 | 2011-05-11 | 中南大学 | 0.3-5mum wave range infrared permeation high temperature resistant glass ceramic material and preparing method thereof |
| CN102643024A (en) * | 2012-04-10 | 2012-08-22 | 中原工学院 | Magnesium oxide (MgO)-silicon dioxide (SiO2)-aluminum oxide (Al2O3)-boron trioxide (B2O3)-potassium fluoride (KF) glass ceramic composite material adopting silicon carbide (SiC) as enhanced-phase and preparation method thereof |
| CN102936096A (en) * | 2012-11-14 | 2013-02-20 | 内蒙古科技大学 | Sm3+ glass doping brilliant glass ceramics and preparation method thereof |
| US9850172B2 (en) | 2014-10-23 | 2017-12-26 | Industrial Technology Research Institute | Ceramic powder, method of manufacturing the same, and method for laser sinter molding |
| CN110577365A (en) * | 2019-09-09 | 2019-12-17 | 深圳精匠云创科技有限公司 | Nanocrystalline glass ceramic and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4000500B2 (en) * | 1999-08-02 | 2007-10-31 | 日本電気硝子株式会社 | Li2O-Al2O3-SiO2 based crystallized glass and crystalline glass |
| JP3767260B2 (en) * | 1999-08-02 | 2006-04-19 | 日本電気硝子株式会社 | Li2O-Al2O3-SiO2 based crystallized glass and crystalline glass |
| JP2004075441A (en) * | 2002-08-14 | 2004-03-11 | Huzhou Daikyo Hari Seihin Yugenkoshi | Lithium oxide-alumina-silica-based crystalline glass and crystallized glass, and method of manufacturing the crystalline glass and the crystallized glass |
| US20040157720A1 (en) * | 2002-08-20 | 2004-08-12 | Nippon Electric Glass Co., Ltd. | Crystallized glass |
| CN1597586A (en) * | 2004-08-11 | 2005-03-23 | 河北邢台晶牛玻璃股份有限公司 | Production method of transparent microcrystal glass |
-
2005
- 2005-10-28 CN CNB2005100613020A patent/CN100352782C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101234852B (en) * | 2008-01-16 | 2011-05-11 | 中南大学 | 0.3-5mum wave range infrared permeation high temperature resistant glass ceramic material and preparing method thereof |
| CN102643024A (en) * | 2012-04-10 | 2012-08-22 | 中原工学院 | Magnesium oxide (MgO)-silicon dioxide (SiO2)-aluminum oxide (Al2O3)-boron trioxide (B2O3)-potassium fluoride (KF) glass ceramic composite material adopting silicon carbide (SiC) as enhanced-phase and preparation method thereof |
| CN102643024B (en) * | 2012-04-10 | 2014-04-02 | 中原工学院 | Magnesium oxide (MgO)-silicon dioxide (SiO2)-aluminum oxide (Al2O3)-boron trioxide (B2O3)-potassium fluoride (KF) glass ceramic composite material adopting silicon carbide (SiC) as enhanced-phase and preparation method thereof |
| CN102936096A (en) * | 2012-11-14 | 2013-02-20 | 内蒙古科技大学 | Sm3+ glass doping brilliant glass ceramics and preparation method thereof |
| US9850172B2 (en) | 2014-10-23 | 2017-12-26 | Industrial Technology Research Institute | Ceramic powder, method of manufacturing the same, and method for laser sinter molding |
| CN110577365A (en) * | 2019-09-09 | 2019-12-17 | 深圳精匠云创科技有限公司 | Nanocrystalline glass ceramic and preparation method thereof |
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