A kind of lithium battery flexible packaging film and manufacture method thereof
Technical field
The present invention relates to a kind of composite soft packaging film and manufacture method thereof, particularly a kind of suitable cold stamping shaped lithium battery flexible packaging film.
Background technology
With the immediate prior art of the present invention be Janpanese Printing Co., Ltd on December 18th, 2000 in Chinese patents, application number is: 00806337.0, patent name is packaging material for polymer cell and manufacture method thereof, it discloses a kind of lithium battery flexible packaging film, form by basalis/bonding resin layer/chemical treatment layer/aluminium foil layer/chemical treatment layer/bonding resin layer/hot sealing layer, and innermost layer is that hot sealing layer is made of simple layer, described innermost layer is made of casting type polypropylene or polyethylene, because polyethylene and polypropylene belong to two kinds of different types of polymers, both different in kinds, even at high temperature also very difficult together compatible, the interface is apparent in view.So binder resin can only be selected sour modified polypropylene resin for use when hot sealing layer is polypropylene.Have following shortcoming like this: one, because sour modified polypropylene resin melt strength is little, so and molten refer to less processing difficulties; Two, feed stock cost height.
Summary of the invention
Content of the present invention provides the lithium battery flexible packaging film and the manufacture method thereof of a kind of low cost and easily processing.
For realizing above purpose, technical scheme of the present invention provides a kind of lithium battery flexible packaging film, by basalis, form for seven layers for doing multiple adhesive phase, chemical reversion processing layer, aluminium foil layer, chemical reversion processing layer, bonding resin layer and hot sealing layer, it is characterized in that, described hot sealing layer is multi-layer co-extruded structure, at least be made up of two layers of resin, one deck is a poly-vinyl resin at least, and one deck is an acrylic resin at least.
The another kind of lithium battery flexible packaging film that technical scheme of the present invention provides, form for six layers by basalis, dried multiple adhesive phase, aluminium foil layer, chemical reversion processing layer, bonding resin layer and hot sealing layer, it is characterized in that, described hot sealing layer is multi-layer co-extruded structure, at least form by two layers of resin, at least one deck is a poly-vinyl resin, and one deck is an acrylic resin at least.
It is polyethylene that described hot sealing layer is used for compound one side, and the another side that is used to seal is a polypropylene, and wherein the thickness of polyethylene layer is at least the 2-80 micron, and wherein the thickness of polypropylene layer is at least the 2-80 micron.
Described hot sealing layer can also be formed by adding at least one deck interlayer resin between polyethylene layer and the polypropylene layer.
Described interlayer resin is maleic anhydride modified poly-mer, perhaps the resin of the compound of the modifier of acrylic resin, poly-vinyl resin, these resins and these resins formation.
Described bonding resin layer is at least a resin in the modifier of the copolymer of copolymer, ethene and methacrylic acid derivative of sour modified polyvinyl resin, its polymers of ethylene-acrylic acid, metal ion crosslinked poly-vinyl resin, ethene and acrylic acid derivative and these resins.
The manufacture method of first kind of lithium battery flexible packaging film is characterized in that it comprises the following steps:
(1) with poly-vinyl resin, acrylic resin, moulding hot sealing layer once on the coextrusion casting machine;
(2) two-sided or single face carries out chromaking and handles and form and the chemical reversion processing layer with aluminium foil;
(3) carry out compound with doing multiple adhesive phase basalis and aluminium foil layer.
(4) bonding resin layer is extruded compound, with the polyethylene face and the bonding formation product of chemical reversion processing layer of hot sealing layer.
The manufacture method of second kind of lithium battery flexible packaging film is characterized in that it comprises the following steps:
(1) between polyethylene layer and polypropylene layer, adds one deck interlayer resin at least, moulding hot sealing layer once on the coextrusion casting machine;
(2) two-sided or single face carries out chromaking and handles and form and the chemical reversion processing layer with aluminium foil;
(3) carry out compound with doing multiple adhesive phase basalis and aluminium foil layer.
(4) bonding resin layer is extruded compound, with the polyethylene face and the bonding formation product of chemical reversion processing layer of hot sealing layer.
Hot sealing layer described in first kind and the second kind of lithium battery packaging film manufacture method also can adopt multi-layer co-extruded blow moulding production.
The manufacture method of the third lithium battery flexible packaging film is characterized in that it comprises the following steps:
(1) two-sided or single face carries out chromaking and handles and form and the chemical reversion processing layer with aluminium foil;
(2) carry out compound with doing multiple adhesive phase basalis and aluminium foil layer.
(3) with bonding resin layer resin, poly-vinyl resin, acrylic resin by multi-layer co-extruded compound and the bonding formation product of chemical reversion processing layer.
The present invention selects a kind of modified polyethylene material in order to improve both compatibilities, makes its microcosmic molecular structure close with polypropylene microcosmic molecular structure, realizes that in coextrusion is produced both is compatible; The present invention also provides another method, adds one deck interlayer at least between polyethylene layer and polypropylene layer.Each interlayer resin and it bonding both sides resin compatibility is all arranged.By interlayer poly-vinyl resin and acrylic resin are bonded together, sour modified polyvinyl resin is than hanging down more than 20% on the sour modified polypropylene resin comparative price.
Advantage of the present invention is that Costco Wholesale is low, and handling ease.
Description of drawings
Fig. 1 is basalis/dried multiple lithium battery flexible packaging film scheme drawing that adhesives/chemical treatment layer/aluminium foil layer/chemical treatment layer/bonding resin layer/hot sealing layer is made;
Fig. 2 is basalis/dried multiple lithium battery flexible packaging film scheme drawing that adhesives/aluminium foil layer/chemical treatment layer/bonding resin layer/hot sealing layer is made;
Fig. 3 is basalis/dried multiple lithium battery flexible packaging film scheme drawing that adhesives/chemical treatment layer/aluminium foil layer/chemical treatment layer/bonding resin layer/poly-vinyl resin layer/acrylic resin layer is made.
The specific embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1
As shown in Figure 1, be basalis/dried multiple lithium battery flexible packaging film scheme drawing that adhesives/chemical treatment layer/aluminium foil layer/chemical treatment layer/bonding resin layer/hot sealing layer is made; Described lithium battery flexible packaging film is made up of for 6 seven layers basalis 1, dried multiple adhesives 2, chemical reversion processing layer 3, aluminium foil layer 4, chemical reversion processing layer 3, bonding resin layer 5 and hot sealing layer.
Described basalis 1, aluminium foil layer 4, chemical treatment layer 3 can carry out processed by existing method; Basalis 1 is selected polyamide for use, and aluminium foil layer 4 is selected the soft aluminium foil of 45 micron thickness for use, and it is polyethylene that described hot sealing layer 6 is used for compound one side, selects the metallocene PE resin for use, and the another side that is used to seal is an acrylic resin; Bonding resin layer 5 is selected acrylic acid modified polyethylene for use.
The manufacture method of lithium battery flexible packaging film comprises the following steps:
(1) with the metallocene PE resin as composite surface, acrylic resin is as heat cover, once moulding on the coextrusion casting machine, and wherein the metallocene PE resin thickness is 10 microns, acrylic resin thickness is 20 microns, and the film gross thickness of production is 30 microns a hot sealing layer 6;
(2) two-sided or single face carries out chromaking and handles and form and chemical reversion processing layer 3 with aluminium foil;
(3) soft aluminium foil 4 and the 25 microns dried multiple adhesivess of polyamide 1 usefulness with 45 micron thickness carry out compound as bonding resin layer 2.
(4) extrude as bonding resin layer 5 with acrylic acid modified polyethylene compound, with hot sealing layer 6 polyethylene faces and chemical reversion processing layer 3 bonding formation products.
Embodiment 2
As shown in Figure 2, be basalis/dried multiple lithium battery flexible packaging film scheme drawing that adhesives/aluminium foil layer/chemical treatment layer/bonding resin layer/hot sealing layer is made, form for 6 six layers by basalis 1, dried multiple adhesives 2, aluminium foil layer 4, chemical reversion processing layer 3, bonding resin layer 5 and hot sealing layer.
The selection of material is the same with embodiment 1, and described hot sealing layer 6 is multi-layer co-extruded structure, and one deck is a poly-vinyl resin, and one deck is the acrylic resin layer, adds one deck interlayer resin between poly-vinyl resin and the acrylic resin.
The manufacture method of lithium battery flexible packaging film is characterized in that it comprises the following steps:
(1) with the metallocene PE resin as composite surface, acrylic resin is as heat cover, add one deck interlayer resin between metallocene PE resin and the acrylic resin, with multi-layer co-extruded blow moulding one-shot forming, wherein the metallocene PE resin thickness is 10 microns, acrylic resin thickness is 20 microns, and the film gross thickness of production is 30 microns a hot sealing layer 6;
(2) two-sided or single face carries out chromaking and handles and form and chemical reversion processing layer 3 with aluminium foil;
(3) soft aluminium foil 4 and the 25 microns dried multiple adhesivess 2 of polyamide 1 usefulness with 45 micron thickness carry out compound
(4) extrude as bonding resin layer 5 with acrylic acid modified polyethylene compound, with hot sealing layer 6 polyethylene faces and chemical reversion processing layer 3 bonding formation products.
Embodiment 3
As shown in Figure 3, be basalis/dried multiple lithium battery flexible packaging film scheme drawing that adhesives/chemical treatment layer/aluminium foil layer/chemical treatment layer/bonding resin layer/poly-vinyl resin layer/acrylic resin layer is made; Described lithium battery flexible packaging film is made up of for 7 eight layers basalis 1, dried multiple adhesives 2, chemical reversion processing layer 3, aluminium foil layer 4, chemical reversion processing layer 3, bonding resin layer 5, poly-vinyl resin layer 6 and acrylic resin layer.
Described basalis 1, aluminium foil layer 4, chemical treatment layer 3 can carry out processed by existing method; Basalis 1 is selected polyamide for use, and aluminium foil layer 4 is selected the soft aluminium foil of 45 micron thickness for use; Bonding resin layer 5 is selected acrylic acid modified polyethylene for use; The poly-vinyl resin layer is selected the metallocene PE resin for use, and the acrylic resin layer is selected the Co-polypropylene resin for use.
The manufacture method of lithium battery flexible packaging film comprises the following steps:
(1) the two-sided chromaking of carrying out of aluminium foil is handled formation and chemical reversion processing layer 3;
(2) basalis 1 and aluminium foil layer 4 being used for multiple adhesive phase 2 carries out compound.
(3) with bonding resin layer 5 resins, poly-vinyl resin 6, acrylic resin 7 by multi-layer co-extruded compound and chemical reversion processing layer 3 bonding formation products.
Measuring method:
After packing is finished, place the 60-90%RH climatic chamber to place 7 days in sample, confirm the whether layering of aluminium foil and internal layer.
Sample was placed after 7 days among the sample embodiment after tested, and aluminium foil and internal layer do not have layering.